Monomer Is Carboxylic Acid Or Derivative Patents (Class 524/832)
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Patent number: 11891492Abstract: A method for manufacturing a foam rubber by foaming a polymer latex is provided, wherein the polymer latex used has a solids content of 60.0 wt % or more, comprises 0.001 to 1.0 part by weight of antifoaming agent relative to 100 parts by weight of polymer in the polymer latex, and has a viscosity at 25° C. of 370 cps or less when the solids content is controlled to 66.0 wt %.Type: GrantFiled: July 10, 2018Date of Patent: February 6, 2024Assignee: ZEON CORPORATIONInventors: Tomoya Taniyama, Hidekazu Haneda
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Patent number: 11767409Abstract: The invention relates to a hollow glass microsphere and polymer composite having enhanced viscoelastic and rheological properties.Type: GrantFiled: April 9, 2021Date of Patent: September 26, 2023Assignee: Tundra Composites, LLCInventors: Kurt Heikkila, Rodney Williams, John Kroll
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Patent number: 11760857Abstract: Provided is a method for producing a latex comprising hollow resin particles each with a high void ratio and a method for producing hollow resin particles each with a higher void ratio. In the method for producing the latex: a suspension treatment of the mixture liquid which comprises a monomer, a crosslinkable monomer, an oil-soluble polymerization initiator, a fat/fatty oil, a hydrocarbon solvent, a suspension stabilizer and an aqueous medium is carried out to prepare a suspension comprising monomer drops; a polymerization reaction of the suspension is carried out to prepare a precursor composition which comprises precursor particles each having a hollow portion including the hydrocarbon solvent.Type: GrantFiled: July 31, 2018Date of Patent: September 19, 2023Assignee: ZEON CORPORATIONInventors: Takashi Iga, Takeshi Hirata, Nozomi Yabuki
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Patent number: 11725085Abstract: This application relates to synthetic elastomeric articles, such as gloves, comprising the cured product of a synthetic latex composition, the synthetic latex composition comprising a synthetic carboxylated polymer and a cross-linking composition, the cross-linking composition comprising an aqueous solution of a negatively charged multivalent metal complex ion having a pH of at least 9.0. Also described are compositions for forming the articles, and methods for making the articles, based on the use of the described cross-linking composition. The articles, compositions and methods contain a second cross-linking agent comprising either (a) sulphur and a sulphur donor, (b) a multivalent metal oxide or ionic cross-linking agent, (c) sulphur, a sulphur donor and an ionic cross-linking agent, or (d) sulphur donor.Type: GrantFiled: June 22, 2020Date of Patent: August 15, 2023Assignee: SKINPROTECT CORPORATION SDN BHDInventors: Khon Pu Foo, Kumaresan Prabhakaran
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Patent number: 11649365Abstract: An ink contains an anionic compound, water, a photoacid generator, and one or more organic solvents containing at least one organic solvent having a solubility parameter of from 9 to 11.8 (J/cm3)1/2.Type: GrantFiled: July 2, 2021Date of Patent: May 16, 2023Assignee: Ricoh Company, Ltd.Inventor: Hiroshi Gotou
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Patent number: 11634558Abstract: An optical resin material for chromatic aberration correction is provided including at least 5% by mass of a compound (component A) represented by formula (1) or formula (3), in which R1 to R6 each independently represent a structure represented by formula (2), in which the broken line represents a binding site; n1 represents an integer of 0 to 3; n2 represents an integer of 0 or 1; n3 represents an integer of 0 to 4; R7 represents hydrogen, an acryl group, a methacryl group, a cyanoacryl group, a cyclic ether group, an allyl group, a propargyl group, a hydroxy group, an isocyanate group, chlorine, or an optionally branched alkyl group having 1 to 8 carbon atoms; and X represents an alkylene glycol chain having 2 to 7 carbon atoms or a lactone-modified ketone chain, in which R1 to R6 each independently represent a structure represented by formula (2).Type: GrantFiled: December 17, 2018Date of Patent: April 25, 2023Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kosuke Namiki, Sunao Nojima, Shoko Suzuki, Noriyuki Kato, Hiroshi Horikoshi
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Patent number: 11597839Abstract: The present invention relates to formulations for use in 3-D printing using radiation from visual display screens. The formulations comprise titanocene photoinitators and co-initiators. The invention also relates to methods of forming 3-D objects using said formulations.Type: GrantFiled: September 23, 2016Date of Patent: March 7, 2023Assignee: PHOTOCENTRIC LIMITEDInventor: Paul Holt
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Patent number: 11560463Abstract: The present disclosure relates to a novel cross-linking agent compound and a polymer prepared using the same. Specifically, the present disclosure relates to a cross-linking agent compound having a novel structure and excellent in cross-linking and pyrolysis, and a polymer prepared using the same.Type: GrantFiled: November 20, 2018Date of Patent: January 24, 2023Inventors: Won Taeck Lim, Wonmun Choi, Gicheul Kim, Ki Hyun Kim
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Patent number: 11155729Abstract: This invention relates to a graft copolymer comprising: a) a macromonomer, wherein the macromonomer comprises in polymerized form a first monoethylenically unsaturated monomer selected from a group consisting of esters of methacrylic acid and acrylic acid with straight or branched alcohols having 1 to 3 carbon atoms and no more than 5 mole % an addition fragmentation chain transfer agent; and b) at least one side chain on the macromonomer, wherein the at least one side chain comprises at least 95 wt.-% of acrylic acid in polymerized form, and its use for improving the dirt pick-up resistance of a paint or coating.Type: GrantFiled: April 26, 2017Date of Patent: October 26, 2021Assignee: Clariant International Ltd.Inventors: Prerana Maruti Patil, Smita Amit Gholam, Ketan Sunil Kulkarni
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Patent number: 11104808Abstract: The present invention relates to an energy curable aqueous composition (X) comprising (a) Water; (b) At least a water-insoluble ethylenically unsaturated compound (A); (c) At least one (meth)acrylic polymer (B1) containing ionic functional groups that are at least partly neutralized by a neutralizing agent (C) and/or at least one (meth)acrylic hybrid (B2) containing ionic functional groups that are at least partly neutralized by a neutralizing agent (C); and (d) At least one nonionic emulsifier (D) comprising alternating polyalkylene oxide segments, said nonionic emulsifier (D) having an HLB value of at least 4.5. Materials of the invention are suitable for the preparation of inks, overprint varnishes or coating compositions.Type: GrantFiled: October 18, 2017Date of Patent: August 31, 2021Assignee: ALLNEX BELGIUM S.A.Inventors: Elodie Siband, Stephan Peeters
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Patent number: 11031599Abstract: The invention features an electrochemical cell having an anode and a cathode; wherein at least one of the anode and cathode includes a solid ionically conducting polymer material that can ionically conduct hydroxyl ions.Type: GrantFiled: December 20, 2019Date of Patent: June 8, 2021Assignee: IONIC MATERIALS, INC.Inventors: Michael A. Zimmerman, Alexei B. Gavrilov, Ting Liu
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Patent number: 10954345Abstract: Provided is a method of preparing a polymer polyol including steps of (a) respectively batchwise feeding a polyol and a monomer in a weight ratio of 40 to 60:40 to 60 into a reactor to prepare a mixture; and (b) polymerizing the mixture for 1 to 5 hours to prepare monodispersed particles.Type: GrantFiled: March 4, 2019Date of Patent: March 23, 2021Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Gi Jung Kim, Seul Gi Kim, Seung Moo Huh
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Patent number: 10826144Abstract: An electrochemical cell system is configured to utilize an oxidant reduction electrode module containing an oxidant reduction electrode mounted to a housing to form a gaseous oxidant space therein that is immersed into the ionically conductive medium. A fuel electrode is spaced from the oxidant reduction electrode, such that the ionically conductive medium may conduct ions between the fuel and oxidant reduction electrodes to support electrochemical reactions at the fuel and oxidant reduction electrodes. A gaseous oxidant channel extending through the gaseous oxidant space provides a supply of oxidant to the oxidant reduction electrode, such that the fuel electrode and the oxidant reduction electrode are configured to, during discharge, oxidize the metal fuel at the fuel electrode and reduce the oxidant at the oxidant reduction electrode, to generate a discharge potential difference therebetween for application to a load.Type: GrantFiled: August 28, 2018Date of Patent: November 3, 2020Assignee: FORM ENERGY, INC.Inventors: Cody Friesen, Ramkumar Krishnan, Michael Mihalka, Grant Friesen, Andrew Goodfellow
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Patent number: 10559827Abstract: The invention features an electrochemical cell having an anode and a cathode; wherein at least one of the anode and cathode includes a solid ionically conducting polymer material that can ionically conduct hydroxyl ions.Type: GrantFiled: May 25, 2017Date of Patent: February 11, 2020Assignee: Ionic Materials, Inc.Inventors: Michael A. Zimmerman, Alexei B. Gavrilov, Ting Liu
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Patent number: 10513619Abstract: An ink includes a solvent and a resin, wherein the storage elastic modulus G1 of an ink film obtained by drying the ink is 2.0×108-5.0×108 Pa at 20 degrees C. as measured by a dynamic viscoelasticity measuring method and the ratio (G2/G1) of the storage elastic modulus G1 to the storage elastic modulus G2 of the ink film measured at 80 degrees C. by the dynamic viscoelasticity measuring method is 0.30-0.85.Type: GrantFiled: October 19, 2016Date of Patent: December 24, 2019Assignee: Ricoh Company, Ltd.Inventors: Satoyuki Sekiguchi, Daisuke Asahina, Yuusuke Fujita
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Patent number: 10442951Abstract: The present invention provides an economical route to environmentally friendly polymeric coatings with a high content of raw materials from renewable resources. These polymeric coatings offer performance characteristics that are competitive with conventional coating systems. The unique polymers on which this invention is based are copolymers of triglyceride oils, such as soybean oil, linseed oil, or another natural oil, with a vinyl compound, such as an acrylate or methacrylate, or a vinyl aromatic monomer. The present invention more specifically discloses a water dispersible, self-crosslinkable prepolymer composition which is comprised of a triglyceride oil having appended thereto (1) hydroxyl groups, (2) epoxy groups, (3) moieties which contain at least one aldehyde group or at least one ketone group, and (4) moieties which contain at least one vinyl and/or substituted vinyl group. In one embodiment of this invention the moiety which contains at least one vinyl group is derived from maleic anhydride.Type: GrantFiled: November 28, 2016Date of Patent: October 15, 2019Assignee: Lubrizol Advanced Materials, Inc.Inventor: Anthony D. Pajerski
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Patent number: 10266709Abstract: The present invention is directed to energy curable offset conductive inks and hybrid offset conductive ink compositions that contain an oxidative curable ink and the energy curable offset conductive ink. The conductive inks and ink compositions exhibit low levels of resistance and hence have superior conductivity.Type: GrantFiled: May 19, 2015Date of Patent: April 23, 2019Assignee: SUN CHEMICAL CORPORATIONInventors: Ramasamy Krishnan, Mark Schneider, Dan Rubik, Kacy Schultz, Juanita Parris
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Patent number: 9957338Abstract: The present invention relates to a novel method for solvent-free preparation of a polymer of (meth)acrylic acid in solution, said polymer having a molecular weigh of less than 8,000 g/mol and a polydispersity index (PI) of 2 to 5 by radical polymerization.Type: GrantFiled: November 17, 2014Date of Patent: May 1, 2018Assignee: COATEXInventor: Jean-Marc Suau
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Patent number: 9862790Abstract: The present invention provides polyvinyl acetal fine particles for an aqueous dispersion which exhibit excellent dispersion stability in a water-containing dispersion medium, and allow for formation of a film having sufficient mechanical strength and flexibility without voids and non-uniform structures such as irregularities, and an aqueous dispersion of the polyvinyl acetal fine particles for an aqueous dispersion. The polyvinyl acetal fine particles for an aqueous dispersion, adapted for use as dispersoids in an aqueous dispersion, the polyvinyl acetal fine particles including a polyvinyl acetal resin with an ionic functional group, and having a volume average particle size of 10 nm to 100 ?m, and a CV value of a volume-based particle size distribution of at most 40%.Type: GrantFiled: September 19, 2016Date of Patent: January 9, 2018Assignee: SEKISUI CHEMICAL CO., LTD.Inventor: Yasuharu Nagai
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Patent number: 9695298Abstract: A chlorosulfonated polyethylene latex, which is safe for living bodies and the environment and can be used as a latex component in a resorcin-formalin-latex adhesive, contains an aqueous dispersion medium, chlorosulfonated polyethylene, and an emulsifying agent of a polyoxyalkylene alkyl ether sulfate of formula (I) below and a fatty acid salt. The latex is excellent in standing stability and mechanical stability. In formula (I), R1, R2, n, and M represent an alkyl group of 6 to 20 carbon atoms, hydrogen or a methyl group, an integer of 2 to 40, and an alkali metal, respectively.Type: GrantFiled: April 2, 2012Date of Patent: July 4, 2017Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Jun Sakata, Hiromasa Miyazaki, Taiji Matsukawa
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Patent number: 9682362Abstract: The purpose of the present invention is to provide a process for stably and continuously producing a water-absorbing resin, specifically, a process for stably and continuously producing a water-absorbing resin, the process including a gas absorbing step in which a gas discharged from a step of producing a water-absorbing resin is efficiently and persistently absorbed. A main point of this process for producing a water-absorbing polyacrylic acid (salt) resin further including a step of absorbing a gas discharged from a production step of the water-absorbing polyacrylic acid (salt) resin in water having a pH of 7 to 11 and a polyvalent metal ion content of 100 ppm or less or a step of absorbing the gas in water having a pH of 7 to 11, the pH of the water having been adjusted by mixing a water having an electric conductivity of 500 (?S/cm) or less at 25° C. with an alkali compound.Type: GrantFiled: November 14, 2014Date of Patent: June 20, 2017Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Makoto Nagasawa, Jiro Sano, Yoshiki Katada, Kunihiko Ishizaki
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Patent number: 9410030Abstract: Addition-fragmentation agents of the formula are disclosed having the following functional groups: 1) a labile addition-fragmentation group that can cleave and reform to relieve strain, 2) at least two surface-binding functional groups that associate with the surface of a substrate.Type: GrantFiled: November 4, 2013Date of Patent: August 9, 2016Assignee: 3M Innovative Properties CompanyInventors: Guy D. Joly, Ahmed S. Abuelyaman, Ann R. Fornof, Bradley D. Craig, Larry R. Krepski, William H. Moser, Serkan Yurt, Joel D. Oxman
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Patent number: 9404008Abstract: Polymer compositions for elastomeric coatings or sealants provide excellent balance properties between elongation to break, early water resistance, alkaline resistance and adhesion on unpolar substrates. The composition is free of volatile and toxic monomer such as acrylonitrile, or substituted acrylonitrile.Type: GrantFiled: February 15, 2012Date of Patent: August 2, 2016Assignee: HEXION INC.Inventors: François Simal, David Vanaken, Jijun Wang
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Publication number: 20150118556Abstract: A binder composition for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery including the same. The binder composition includes lithium polyacrylate and a solvent and has a viscosity of about 500 cps to about 5000 cps.Type: ApplicationFiled: August 29, 2014Publication date: April 30, 2015Inventors: Chang-Ui Jeong, Byung-Joo Chung, Nam-Seon Kim, Yang-soo Kim, Kwang-Sik Choi
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Patent number: 9005397Abstract: The invention relates to an aqueous polymer dispersion comprising an anionic water-soluble dispersion polymer comprising in polymerized form a monomer mixture comprising (i) one or more anionic monomers, (ii) a first non-ionic vinyl monomer which is acrylamide, and (iii) at least one second non-ionic vinyl monomer; a water-soluble salt and a stabilizer, wherein the water soluble salt is present in an amount of at least 2.0% by weight, based on the total weight of the dispersion. The invention further relates to a process for producing the aqueous polymer dispersion, use of the aqueous polymer dispersion as a flocculating agent in papermaking or for water purification, and a process for producing paper which comprises adding one or more drainage and retention aids comprising the aqueous polymer dispersion to an aqueous suspension containing cellulosic fibers and then dewatering the obtained suspension.Type: GrantFiled: August 19, 2009Date of Patent: April 14, 2015Assignees: Akzo Nobel N.V., Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung E.V.Inventors: Christian Przybyla, Oliver Struck, André Laschewsky, Bernd-Reiner Paulke
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Publication number: 20150057406Abstract: The architectural compositions, such as paints and stains, include an additive comprising a plurality of latex particles added to an existing mixture of opacifying pigments and a film-forming binder as an admixture. Each latex particle is made from a latex polymer copolymerized with a polymerizable surfactant. The latex polymer is a non-film forming polymer at ambient temperatures.Type: ApplicationFiled: November 3, 2014Publication date: February 26, 2015Inventors: Gary Dandreaux, Ashley Brewer, Caleb Jardel, Paulina Ogorzalek, Luz Clarena Shavel, Robert Sheerin
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Patent number: 8933169Abstract: The invention relates to pulverulent core/shell polymers for the preparation of a plastisol, which have surprisingly low water absorption. The invention further relates to the plastisol pastes which are prepared from these polymers and likewise have low water absorption and additionally possess good storage stability, good mechanical properties and good plasticizer compatibility. The core/shell polymers consist of latex particles having a primary particle size of at least 250 nm, the core consisting of methyl methacrylate, (meth)acrylic esters with C2 to C8 or aromatic alcohol radicals and optionally further monomers, and the shells(s) comprising, in addition to these components, also amides of (meth)acrylic acid and/or amine-substituted alkyl esters of (meth)acrylic acid.Type: GrantFiled: July 12, 2005Date of Patent: January 13, 2015Assignee: Kaneka Belguim N.V.Inventors: Jan Hendrik Schattka, Gerd Loehden
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Patent number: 8920933Abstract: An autoxidisable aqueous varnish composition comprising: a) film forming polymer latex binder system comprising, on a non-vol basis, i) 40-60 wt % soft autoxidisable polymer particles of Fox Tg less than 5° C., ii) 60-40 wt % hard polymer particles of Fox Tg at least 40° C. wherein the soft autoxidisable polymer particles comprise at least 60 wt % gel b) a carrier liquid comprising at least 50 wt % water and an amount of a volatile organic material of from 0 to 2 wt % when calculated on the total liquid varnish composition, c) optionally pigment at a pigment to binder weight ratio up to 0.05:1 calculated on a non-vol basis.Type: GrantFiled: June 15, 2010Date of Patent: December 30, 2014Assignee: Akzo Nobel Coatings International B.V.Inventors: Hugues Straub, Manish Sarkar, Barry Norman Osborn, James Stephen Wixey
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Patent number: 8901264Abstract: To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability.Type: GrantFiled: September 9, 2010Date of Patent: December 2, 2014Assignee: Asahi Glass Company, LimitedInventors: Kazunori Sugiyama, Toyomichi Shimada, Nobuyuki Otozawa, Yuuichi Oomori, Minako Shimada
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Publication number: 20140349367Abstract: Degradable and biologically inert hydrogel networks are described. The hydrogel networks are crosslinked and based on a biocompatible polymer that is chain extended with hydrophobic segments that include no more than 5 hydrophobic monomers to form a macromonomer that is then crosslinked to form a network that includes individual micelles throughout the crosslinked network. The hydrophobic segments of the macromonomer as well as other potentially toxic materials such as crosslink initiators can be sequestered in the micelles to better control degradation characteristics of the network as well as prevent toxicity to developing cellular structures of the network.Type: ApplicationFiled: April 24, 2014Publication date: November 27, 2014Applicant: University of South CarolinaInventor: Esmaiel Jabbari
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Patent number: 8877864Abstract: The invention provides an anionic dispersion polymerization process, wherein the polymerization is improved by an organic isothiocyanate, such as methyl isothiocyanate.Type: GrantFiled: October 14, 2011Date of Patent: November 4, 2014Assignee: Kemira OyjInventors: Rosa Carceller, Ari Juppo
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Publication number: 20140309369Abstract: The present invention relates to a process for preparing a polymer latex that includes comprising polymerizing one or more ethylenically unsaturated aromatic monomers and one or more conjugated diene monomers in the presence of a hydroperoxide chain transfer agent and sulfur-containing chain transfer agent, wherein the sulfur-containing chain transfer agent is added after the hydroperoxide chain transfer agent. It further relates to the polymer latex thus obtained, to a composition comprising the polymer latex and to the use of the polymer latex or polymer latex composition in a carpet backing, paper coating, or fiber fabric pre-impregnation process.Type: ApplicationFiled: August 23, 2012Publication date: October 16, 2014Applicant: STYRON EUROPE GMBHInventors: Bernard Fouchet, Etienne Lazarus, Nicolas Tissier, Ursula Seiler, Donato Ventresca
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Publication number: 20140275350Abstract: The invention relates to coating compositions, treated reinforced fibers, reinforced asphalt and portland cement concrete and methods for producing the same. The coating compositions include monomer, prepolymer or mixtures thereof, and graft initiator. The monomer and/or prepolymer include at least one functional group selected from the group consisting of hydroxyl, carboxyl, amino and ester. The graft initiator includes metallic salt.Type: ApplicationFiled: March 13, 2014Publication date: September 18, 2014Applicant: FORTA CORPORATIONInventors: Jeffrey B. Lovett, Clifford Norman MacDonald, Daniel T. Biddle
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Patent number: 8822572Abstract: A process for aqueous, free-radically initiated, continuous emulsion polymerization of A) at least one vinyl ester and optionally at least one (meth)acrylic ester, B) ethylene, and C) 0 to 10% by weight of one or more ethylenically unsaturated, functionalized comonomers, in the presence of 3.0 to 12.5% by weight of one or more emulsifiers, where at least 50% by weight are nonionic emulsifiers, and 0 to 10% by weight of one or more protective colloids, in a stirred tank cascade with at least two pressure reactors connected in series and with at least one low-pressure reactor connected downstream.Type: GrantFiled: July 7, 2011Date of Patent: September 2, 2014Assignee: Wacker Chemie AGInventors: Jessica Hain, Udo Kotschi, Hans-Peter Weitzel
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Patent number: 8754150Abstract: The invention relates to a copolymer which can be used as a superplasticizer for hydraulic binders and comprises 30 to 47 mol % of a (meth)allyl alcohol polyether derivative structural unit and 53 to 70 mol % of a maleic acid derivative structural unit.Type: GrantFiled: January 12, 2009Date of Patent: June 17, 2014Assignee: Construction Research & Technology GmbHInventors: Silke Flakus, Klaus Lorenz, Gerhard Albrecht, Helmut Mack, Angelika Hartl, Martin Winklbauer, Petra Wagner, Barbara Wimmer, Christian Scholz
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Patent number: 8703876Abstract: A process for producing water-absorbing polymer particles, wherein at least one inorganic phosphoric acid and/or salt thereof and at least one organic 2-hydroxy acid and/or salt thereof is added, where the phosphorus in the inorganic phosphoric acid has an oxidation number of less than +V and the organic 2-hydroxy acid does not have any ethylenically unsaturated groups, and also the water-absorbing polymer particles obtainable by the process according to the invention.Type: GrantFiled: March 4, 2011Date of Patent: April 22, 2014Assignee: BASF SEInventors: Norbert Herfert, Thomas Daniel, Bootsara Parchana
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Patent number: 8658733Abstract: A process for the preparation of monodisperse polymer particles which are formed by contacting monomers with aqueous dispersions comprising monodisperse swellable seed polymers/oligomers, and initiating polymerization in the presence of a steric stabilizer. The resulting swollen seed particles are characterized by the particle mode diameter.Type: GrantFiled: October 10, 2012Date of Patent: February 25, 2014Assignee: Life Technologies ASInventors: Arne Jorgedal, Elin Aksnes, Geir Fonnum, Astrid Molteberg, Rolf Nordal, Henning Pettersen, Tollef Taarneby, Solveig Staale, Ellen Weng, Finn Hansen, Silje Nordbo, Oddvar Aune, Arvid Berge, John Bjorgum, Turid Ellingsen, John Ugelstad
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Patent number: 8653183Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent.Type: GrantFiled: June 22, 2010Date of Patent: February 18, 2014Assignee: BASF SEInventors: Keith E. Gutowski, Walter H. Ohrbom, David Cranfill, Donald H. Campbell
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Patent number: 8546482Abstract: This invention provides stable aqueous compositions including stable coating compositions, and methods of their production. The stable aqueous compositions and stable aqueous coating compositions comprise one or more emulsion-polymerized addition polymer, one or more carboxylesterase enzyme, and one or more carboxylesterase deactivating agent, such that the ester hydrolysis activity in the composition is less than 0.010 micromole/minute, and wherein the aqueous composition has a headspace volatile organic compound (VOC) content, as measured by headspace gas chromatography-mass spectrometry (GC-MS) at 33° C., of less than 10 ppm of organic carboxylester with a normal boiling point of less than 150° C. and more than 50 ppm of mono-alcohol with a formula molecular weight of less than 76.Type: GrantFiled: December 10, 2010Date of Patent: October 1, 2013Assignee: Rohm and Haas CompanyInventors: James Bohling, Paul F. Doll, David L. Frattarelli, Kathleen R. Manna, Alvin M. Maurice
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Patent number: 8541524Abstract: Process of controlled free-radical polymerization in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer using molecular iodine and at least one oxidant whose solubility in water is at least 10 g/l for the synthesis of the first block of the block copolymer.Type: GrantFiled: July 4, 2007Date of Patent: September 24, 2013Assignee: Solvay (Societe Anonyme)Inventors: Christophe Fringant, Yves Vanderveken, Patrick Lacroix-Desmazes, Jeff Tonnar
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Patent number: 8530574Abstract: The present invention provides aqueous finely divided polymer dispersions which at low temperatures are film-forming, exhibit good blocking resistance in a formulation, even at elevated temperatures, and display a low foam tendency, processes for preparing them, and their use as binders for coating substrates.Type: GrantFiled: July 19, 2010Date of Patent: September 10, 2013Assignee: BASF SEInventors: Roelof Balk, Franca Tiarks, Arno Tuchbreiter
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Patent number: 8519212Abstract: The present invention provides a production process by which a water-absorbent resin of excellent quality can be obtained at a low cost by reasonable steps in aqueous solution polymerization. The process for producing a water-absorbent resin comprises the step of polymerizing an aqueous solution of water-absorbent resin-forming monomers including acrylic acid and/or its sodium salt as major components, wherein: (1) the aqueous solution has a monomer component concentration of not less than 45 weight %; (2) the polymerization is carried out while water is evaporated so that the ratio (concentration ratio) between a solid component concentration in a hydropolymer as formed by the polymerization and a solid component concentration in the aqueous monomer solution will not be less than 1.10; and (3) the solid component concentration in the hydropolymer as formed by the polymerization is not more than 80 weight %.Type: GrantFiled: May 11, 2010Date of Patent: August 27, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Yorimichi Dairoku, Yoshio Irie, Shinichi Fujino, Yasuhiro Fujita, Takashi Azumi, Kunihiko Ishizaki
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Patent number: 8513378Abstract: The present invention provides a method for producing a water-absorbing resin powder. The method includes a polymerization step, a drying step, a pulverization step, a classification step, and a surface cross-linking step. It further includes an additional step, performed before the surface cross-linking step, in which at least part of the classified polymer is supplied again to the same or a different pulverization step. The circulation pulverization ratio in the pulverization step is higher than 1.50.Type: GrantFiled: September 16, 2010Date of Patent: August 20, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Sayaka Machida, Kazushi Torii, Yoko Shirai, Hiroyuki Ikeuchi, Kunihiko Ishizaki
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Patent number: 8513353Abstract: A copolymer defines interconnected pores and comprises polymerized monomers. The monomers comprise a first monomer more hydrophilic than 2-hydroxyethyl methacrylate (HEMA), and a second monomer as hydrophilic as, or less hydrophilic than, HEMA. In a method of forming a polymer, a bicontinuous microemulsion comprising water, a surfactant, and a combination of monomers copolymerizable for forming a porous copolymer is provided. The combination of monomers comprises the first and second monomers. The monomers in the bicontinuous microemulsion are polymerized to form the porous copolymer. The first monomer may comprise N-vinylpyrrolidone (NVP) or methacrylic acid (MAA). The second monomer may comprise HEMA or methyl methacrylate (MMA).Type: GrantFiled: March 19, 2009Date of Patent: August 20, 2013Assignee: Agency for Science, Technology and ResearchInventors: Edwin Pei Yong Chow, Jackie Y. Ying
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Patent number: 8481642Abstract: The present invention relates to a process for the preparation of hydrothermal hybrid material, in particular coal-like hybrid material from biomass. The process involves the heating of a reaction mixture comprising water, biomass and a copolymerizable compound, wherein the copolymerizable compound is added when preparing the reaction mixture, in a variant of the process, the biomass is converted to activated biomass in a first step, and the copolymerization of the activated biomass and a copolymerizable compound to give the hydrothermal, preferably coal-like, hybrid material is started by adding a polymerization initiator. The invention also relates to the hydrothermal hybrid materials obtainable by the processes as such, e.g. to aqueous dispersions thereof. By incorporating copolymerizable compounds, e.g. petrochemical compounds in the structure of the hydrothermal hybrid materials, the physical properties of the materials and the preparation process thereof can be controlled.Type: GrantFiled: June 22, 2009Date of Patent: July 9, 2013Assignee: CSL Carbon Solutions Ltd.Inventors: Markus Antonietti, Maria Magdalena Titirici, Rezan Demir Cakan
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Patent number: 8461253Abstract: Disclosed are coating compositions that can be one-component, ambient curable, and waterborne. The coating compositions comprise acrylic copolymer resin particles comprising carbonyl functional groups and a crosslinking agent comprising functional groups, such as hydrazide groups, that are reactive with carbonyl groups.Type: GrantFiled: January 15, 2010Date of Patent: June 11, 2013Assignee: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Mark S. Gaston, Brian K. Rearick, Irina G. Schwendeman, Venkateshwarlu Kalsani, Hongying Zhou, Michael J. Ziegler
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Publication number: 20130102702Abstract: A process for aqueous, free-radically initiated, continuous emulsion polymerization of A) at least one vinyl ester and optionally at least one (meth)acrylic ester, B) ethylene, and C) 0 to 10% by weight of one or more ethylenically unsaturated, functionalized comonomers, in the presence of 3.0 to 12.5% by weight of one or more emulsifiers, where at least 50% by weight are nonionic emulsifiers, and 0 to 10% by weight of one or more protective colloids, in a stirred tank cascade with at least two pressure reactors connected in series and with at least one low-pressure reactor connected downstream.Type: ApplicationFiled: July 7, 2011Publication date: April 25, 2013Applicant: Wacker Chemie AGInventors: Jessica Hain, Udo Kotschi, Hans-Peter Weitzel
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Publication number: 20130087167Abstract: A dampening fluid useful in offset ink printing applications contains water and a surfactant whose structure can be altered. The alteration in structure aids in reducing accumulation of the surfactant on the surface of an imaging member. The surfactant can be decomposed, switched between cis-trans states, or polymerizable with ink that is subsequently placed on the surface.Type: ApplicationFiled: October 7, 2011Publication date: April 11, 2013Applicants: Xerox Corporation, Palo Alto Research Center IncorporatedInventors: Naveen Chopra, Peter Gordon Odell, Steven E. Ready, Eric Peeters, Timothy D. Stowe, Ashish Pattekar, David K. Biegelsen
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Patent number: 8410232Abstract: Esters of itaconic acid are polymerized in aqueous medium in the presence of seed particles. The seed particles may absorb the monomer and provide for polymerization to a desired particle size. The polymers that are produced may be employed in adhesives, paints, and paper formulations.Type: GrantFiled: December 16, 2010Date of Patent: April 2, 2013Assignee: University of New HampshireInventor: Yvon Durant
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Patent number: 8399579Abstract: A process for preparing stable aqueous dispersions of composite particles.Type: GrantFiled: March 31, 2010Date of Patent: March 19, 2013Assignee: BASF SEInventors: Bas Lohmeijer, Harm Wiese, Ekkehard Jahns