Carbon, Titanium Dioxide, Glass, Or Silicon Dioxide Having Specified Crystalline Form Or Numerical Limitation Other Than Amount, E.g., Included Herein Are Particle Size, Shape, Etc., As Dnrm Patents (Class 524/847)
  • Patent number: 6160039
    Abstract: This invention relates to a process for the production of masterbatches which contain short fibres or pulps and which may be used for the production of polymer compositions or rubber compositions.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: December 12, 2000
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Harald Kleinknecht, Andreas Schuch, Iris Degen
  • Patent number: 6153679
    Abstract: Titanium oxide and a thermoplastic resin composition incorporated therewith, said titanium oxide being characterized by its property that it disperses into ethylene glycol (as a dispersing medium) to give a 13 wt % suspension which has a specific resistance higher than 7000 .OMEGA..multidot.cm and passes through a filter paper with a pore size of 6 .mu.m such that the filtration pressure does not exceed 100 kPa after filtration for 4 minutes at a flow rate of 1.73 cm.sup.3 /min.multidot.cm.sup.2.
    Type: Grant
    Filed: March 20, 1998
    Date of Patent: November 28, 2000
    Assignee: Toray Industries, Inc.
    Inventors: Tomio Kawaji, Ryosuke Asakura, Tomohiro Taniguchi
  • Patent number: 6149979
    Abstract: A process for the preparation of a photosensitive body surface coating material comprises hydrolytically condensing an alkoxysilane in a mixed solvent comprising an alcohol and water in the presence of finely divided silica. A polysiloxane resin is produced by heat curing the silane after its hydrolytic condensation. The polysiloxane resin has the formula: R.sup.1 SiO.sub.3/2, and R.sup.1 comprises fluorohydrocarbon groups. The photosensitive body surface coating material is not detrimental to the functionality required of the electrophotographic photosensitive bodies, has superior optical uniformity, has low surface energy, and has superior surface hardness.
    Type: Grant
    Filed: March 18, 1998
    Date of Patent: November 21, 2000
    Inventors: Nobuo Kushibiki, Kikuko Takeuchi, Hideki Kobayashi, Toru Masatomi
  • Patent number: 6136919
    Abstract: A method of preparing a pre-formed elastomer/filler composite of a diene-based elastomer and particulate filler dispersed therein by polymerizing monomers in the presence of said filler with a polymerization promoting catalyst in which at least a portion of said catalyst is pre-deposited on said filler. Such pre-formed elastomer composite is also contemplated as well as a rubber composition comprised of a blend of such pre-formed composite and at least one additional elastomer. Such filler may be, for example, precipitated silica, carbon black and/or a modified carbon black. A tire having a component of such composite or rubber composition such as, for example a tread, is also provided.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: October 24, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Rene Jean Zimmer, Friedrich Visel, Uwe Ernst Frank, Thierry Florent Edme Materne, Giorgio Agostini
  • Patent number: 6107435
    Abstract: A silica filled room temperature vulcanizing (RTV) composition, curable in the presence of moisture and having good adhesion to glass and ceramic materials. The RTV composition comprises (A) about 20 to 95 weight percent polymers comprising on average at least 1.2 hydroxysilyl chain terminations per molecule or on average at least 1.2 alkoxysilyl chain terminations per molecule; (B) about 0.05 to 1.4 weight percent of a titanium compound; (C) a sufficient amount of an aminofunctional alkoxysilane to provide a nitrogen concentration from about 0.01 to 2 weight percent; (D) about 0.5 to 40 weight percent of an alkoxysilane; and (E) about 3 to 40 weight percent of a silica filler.
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: August 22, 2000
    Assignee: Dow Corning Corporation
    Inventors: Richard Alan Palmer, Nick Evan Shephard
  • Patent number: 6103818
    Abstract: A resin composition containing components (A), (B), (C) and (D) wherein component (A) is a resin composition containing a thermoplastic polyimide resin, component (B) is carbon fiber, component (C) is mica, component (D) is an internal mold-releasing agent, and relative to 100 parts by weight of component (A), component (B) is from 1 to 80 parts by weight, component (C) 1 to 100 parts by weight, and component (D) is 0.1 to 50 parts by weight.
    Type: Grant
    Filed: August 7, 1998
    Date of Patent: August 15, 2000
    Assignees: Mitsui Chemicals, Inc., Minnesota Mining & Manufacturing Company
    Inventors: Atsushi Morita, Masaji Yoshimura, Hiroyasu Kido, Tomoaki Sato, Kouichi Sano, Denis Dean Springer, Daniel Patrick Sheehy
  • Patent number: 6039831
    Abstract: A hydrosilylation curable electrically conductive silicone elastomer composition containing an acrylic functional group containing organopolysiloxane such that when the compositon is used to adhere a semiconductor chip to a substrate and the composition is then irradiated with a high energy beam, the exposed periphery of the composition cures to the extent that migration of low molecular weight silicone species from the compositon, both before and during the hydrosilyation reaction, is minimized.A method for manufacturing a semiconductor device having improved reliability in which, during adhesion of a semiconductor chip to the substrate, package, etc., by means of this composition, decreases in wire bondability to the semiconductor chip or lead frame and adhesion defects between the semiconductor chip, substrate, package, or lead frame and the sealing resin can be inhibited.A semiconductor device manufactured by this method which has improved reliability.
    Type: Grant
    Filed: January 15, 1999
    Date of Patent: March 21, 2000
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Katsutoshi Mine, Osamu Mitani, Kazumi Nakayoshi, Rikako Tazawa
  • Patent number: 6020424
    Abstract: The present invention provides a screen printable thermosetting composition for forming thermally conductive interface and a method of using the same. The composition is used to promote the transfer of heat from a source of heat such as an electronic device to a heat dissipation device such as a heat sink. The composition comprises by weight from about 35% to about 75% of a thermal curing vinyl terminated siloxane material, from about 0.005% to about 5% catalyst, from about 10% to about 30% hydrocarbon solvent and from about 20% to about 70% conductive filler.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: February 1, 2000
    Assignee: Ferro Corporation
    Inventors: Jesus E. Osuna, Keith M. Mason, Vernon E. Stygar
  • Patent number: 6020415
    Abstract: A water based binder for use in a slurry for investment casting. The binder includes a mixture of a colloidal silica sol and at least one latex polymer. The latex polymer is preferably an acrylic latex or a styrene butadiene polymer (or a combination of these) which reduces the processing time between dips during shell mold making for investment casting. The latex polymer further lowers a critical concentration point or gelation point of the colloidal silica sol. The binder may be used as a primary binder or a backup binder in the shell mold making process. To make the slurry, the binder is combined with at least one refractory powder, preferably a refractory powder selected from the group of: alumino-silicates, fused silica, quartz silica, alumina, zircon, and zirconia.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: February 1, 2000
    Assignee: Remet Corporation
    Inventor: Manuel Guerra, Jr.
  • Patent number: 6005048
    Abstract: The organopolysiloxane compositions are prepared by mixing(1) organopolysiloxanes which contain on average at least 2 aliphatic carbon-carbon multiple bonds per molecule,(2) prehydrophobized oxidic reinforcing fillers having a carbon content, obtained by the hydrophobizing, of at least 0.5% by weight and(3) compounds which are chosen from(3a) silanol compounds of the formulaR--[SiR.sub.2 --O--].sub.a H (I)in whichR is identical or different monovalent, C.sub.1 - to C.sub.10 -hydrocarbon radicals which are free from aliphatic carbon-carbon multiple bonds anda has values from 1 to 10, and(3b) saturated C.sub.1 - to C.sub.18 -alkanols.
    Type: Grant
    Filed: November 1, 1996
    Date of Patent: December 21, 1999
    Assignee: Wacker-Chemie GmbH
    Inventors: Johann Schuster, Horst Muller, Johann Mersch, Heinrich Glocklhofer, Anton Maier
  • Patent number: 6005027
    Abstract: The present invention discloses blends of silanes and specific silicas, characterized in that when the blend is compounded into a rubber formulation even after 4 months of storage following formation of the blend, an unexpectedly high proportion of the silane present is available as a coupling and reinforcing agent for the rubber formulation. Over 80% and even over 90% of the silica can be extracted or described from the blend even 4 months after formation of the blend, and rubber formulation properties indicate high availability of the silane for coupling and reinforcement.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: December 21, 1999
    Assignee: Witco Corporation
    Inventors: Antoine Guillet, Remy Gauthier
  • Patent number: 6001918
    Abstract: A silicone gel composition comprising: (A) 100 parts by weight of an organopolysiloxane containing at least two alkenyl groups per molecule and having a viscosity of 0.01 to 100 Pa.s at 25.degree. C.; (B) an organopolysiloxane containing at least two silicon-bonded hydrogen atoms per molecule and having a viscosity of 0.001 to 10 Pa.s at 25.degree. C. in an amount sufficient to provide from 0.2 to 5 moles of silicon-bonded hydrogen atoms per one mole of alkenyl groups in component (A); (C) 0.01 to 15 parts by weight of a silica powder having a specific surface area of at least 50 m.sup.2 /g; (D) 0.0001 to 1.0 part by weight of a diamine compound represented by the following general formula: R.sup.1.sub.2 N--R.sup.2 --NR.sup.1.sub.2 wherein each R.sup.1 is independently a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R.sup.
    Type: Grant
    Filed: July 6, 1998
    Date of Patent: December 14, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hiroji Enami, Akihiro Nakamura, Yuji Hamada, Takeaki Saiki
  • Patent number: 5981682
    Abstract: A silicone composition curable to a silicone bonding agent that is suitable for use in manufacturing an optical memory element comprises:(A) 100 parts by weight of an organopolysiloxane having an average of at least two silicon-bonded alkoxy groups per molecule and an average of at least two silicon-bonded alkenyl groups per molecule, wherein the alkoxy groups and the alkenyl groups are in the same molecule;(B) an organohydrogenpolysiloxane having an average of at least two silicon-bonded hydrogen atoms per molecule, wherein the molar ratio of silicon-bonded hydrogen atoms in component (B) to silicon-bonded alkenyl groups in component (A) is from 0.3:1 to 20:1;(C) 0.01 to 20 parts by weight of a metal condensation reaction catalyst wherein the metal of said metal condensation reaction catalyst is selected from the group consisting of titanium, zirconium and aluminum; and(D) a catalytic amount of a hydrosilylation reaction catalyst. The composition is cured by an addition reaction and a condensation reaction.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: November 9, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventor: Masayuki Onishi
  • Patent number: 5973058
    Abstract: A silicone rubber composition that does not foam or evolve an unpleasant odor during its cure and that cures into low-surface-tack, non-yellowing silicone rubber moldings comprises:(A) polydiorganosiloxane gum with the average component formula R.sub.a SiO.sub.(4-a)/2 where R represents substituted and unsubstituted monovalent hydrocarbon groups and a is from 1.9 to 2.1,(B) microparticulate silica,(C) bis(ortho-methylbenzoyl)peroxide, and(D) bis(para-methylbenzoyl)peroxide,wherein the component (C) to component (D) weight ratio is from 1:9 to 8:2.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: October 26, 1999
    Assignee: Dow Corning Toray Silicone Co., LTD.
    Inventors: Katsuya Baba, Kazuo Hirai, Takao Matsushita
  • Patent number: 5973042
    Abstract: There is provided a highly water-absorptive polymer composition comprising:(A) 100 parts by weight of a highly water-absorptive polymer having a crosslinked structure, comprising as its constituent a carboxyl group and/or a carboxylate group; and(B) 0.05 to 10 parts by weight of an additive selected from the group consisting of an oxalic acid (salt) compound, a sulfate of a metal selected from titanium, zirconium and vanadium, and a crystalline or noncrystalline, high-purity particulate titania having a mean particle diameter of 1 .mu.m or less, a specific surface area of 10 m.sup.2 /g or more as determined by the Brunauer-Emmett-Teller method, and, when crystalline, a crystal structure of a mixed type of rutile and anatase.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: October 26, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kenji Yoshinaga, Shozo Kitagawa, Toshiko Nakamura, Miho Tanaka, Kiichi Ito
  • Patent number: 5969023
    Abstract: A curable silicone composition cures to form a silicone cured product with improved fire-retarding properties. The composition comprises a hydrosilylation-reaction curable silicone composition Fire-retarding properties are imparted to the composition using a silica powder with a specific surface area of not less than 50 sq. m/g and a diamine compound. The cured product is preferably a silicone gel.
    Type: Grant
    Filed: March 5, 1998
    Date of Patent: October 19, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hiroji Enami, Yuji Hamada, Takeaki Saiki
  • Patent number: 5965638
    Abstract: A structural mat matrix comprises (a) a substrate which consists essentially of from 80% to 99% by weight fiberglass fibers and from 20% to 1% by weight wood pulp and (b) a binder which consists essentially of from 80% to 95% by weight urea formaldehyde and from 20% to 5% by weight acrylic copolymer. The binder bonds the substrate fiberglass fibers and wood pulp together and comprises from 5% to 15% by weight of said matrix, preferably 10% by weight of the matrix.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: October 12, 1999
    Assignee: Elk Corporation of Dallas
    Inventor: Darrell Heine
  • Patent number: 5952419
    Abstract: A curable organosiloxane-polyisobutylene composition comprising 20 to 87 weight percent of a polyisobutylene comprising at least 2 alkenyl groups per molecule, 0.4 to 70 weight percent of a polyorganosiloxane comprising at least 2 silicon-bonded alkenyl groups per molecule, 7 to 50 weight percent of a treated reinforcing silica filler, an amount sufficient to cure the composition of an organohydrogensiloxane crosslinker, and a platinum-group metal hydrosilation catalyst in an amount sufficient to effect curing of the composition. Cured elastomers prepared from the compositions can have improved resistance to gas and vapor permeability.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: September 14, 1999
    Assignee: Dow Corning Corporation
    Inventors: Jon Vierling DeGroot, Jr., Carl Allen Fairbank, William James Schulz, Jr.
  • Patent number: 5948856
    Abstract: Curable organosiloxane compositions that cure by a platinum group metal catalyzed hydrosilation reaction to yield machinable elastomers exhibiting a high resistance to erosion contain an alkenyl-functional organosiloxane copolymer as the reinforcing agent together with quartz and organic or inorganic microspheres as the non-reinforcing filler. The concentration and density of the microspheres are preferably within specified limits.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: September 7, 1999
    Assignee: Dow Corning Corporation
    Inventors: Donnie Ray Juen, Michael G. Krueger, Lawrence Joseph Rapson
  • Patent number: 5932668
    Abstract: Novel liquid organopolysiloxane resins of the average composition ?R.sup.1 Si(CH.sub.3).sub.2 O.sub.1/2 !.sub.a ?(CH.sub.3).sub.3 SiO.sub.1/2 !.sub.b ?R.sup.2 O.sub.1/2 !.sub.c ?R.sup.1 Si(CH.sub.3)O!.sub.d ?(CH.sub.3).sub.2 SiO!.sub.e ?SiO.sub.2 !,whereinR.sup.1 is a C.sub.2 -C.sub.8 -alkenyl group,R.sup.2 is an optionally substituted, linear or branched C.sub.1 -C.sub.8 -alkyl group or a mixture thereof,a+b+c+d+e is about 1 to 6,d+e is about 0 to 3,the resin has a viscosity of 0.1 to 1000 Pas at 25.degree. C., andthe alkenyl or vinyl content of the resin is in the range of 0.4 to 4 mmol/g,and their preparation by reacting at least one of tetraalkoxysilane and its partial hydrolyzate with at least one organosiloxane and a strong acid as catalyst in the presence of water and optionally an organic solvent at a temperature of about >40.degree. C. They are formulated into novel low viscosity polydiorganosiloxane compositions.
    Type: Grant
    Filed: August 21, 1996
    Date of Patent: August 3, 1999
    Assignee: GE Bayer Silicones GmbH & Co. KG
    Inventors: Robert Friebe, Hubertus Eversheim
  • Patent number: 5916937
    Abstract: A heat cured fluorosilicone rubber exhibiting improved compression set comprises N,N'-meta-phenylenedimaleimide.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: June 29, 1999
    Assignee: General Electric Company
    Inventor: Edwin R. Evans
  • Patent number: 5908592
    Abstract: A liquid silicone rubber base including (A) an alkenyl-containing organopolysiloxane, (B) a reinforcing silica filler, (C) a mixing assistant in the form of a silanol-containing compound, (E) an organohydrogen polysiloxane, (f) a platinum catalyst and optionally, (D) a wetting auxiliary catalyst is prepared by previously mixing 10-120 parts of component (A) with 1-35 parts of component (C) and 0-35 parts of component (D) to form a premix liquid, mixing the premix liquid with 100 parts of component (B) to form a premix power, and kneading the premix powder with the remainder of component (A). By adding a curing agent of organohydrogenpolysiloxane/platinum catalyst to the liquid silicone rubber base, there is obtained a liquid silicone rubber composition having improved fatigue endurance.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: June 1, 1999
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kenichi Kimura, Takeo Yoshida, Manabu Narumi, Masaya Arakawa
  • Patent number: 5908891
    Abstract: The present invention relates to a dispersible silicone composition comprising (I) a silicone composition prepared by reacting (i) a polyorganosiloxane, (ii) a silicon compound, optionally (iii) a finely divided filler, and (iv) a catalytic amount of a compound for promoting the reaction of the other components and (II) mineral oil. The mineral oil is effective as a dispersing agent for the silicone composition (I). The mineral oil-containing compositions are easier to handle, and produce less waste and its dispersion into mineral oil based formulations is more efficient.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: June 1, 1999
    Assignee: Dow Corning Corporation
    Inventors: Kenneth Christopher Fey, James Habermehl
  • Patent number: 5905101
    Abstract: The invention relates to an ablator composition for providing ablation protection after cure thereof. The. ablator composition includes the components of: (A) 100 parts by weight of a silicone elastomer composition which is curable to a silicone elastomer by addition reaction; (B) 50-200 parts by weight of an amorphous silica having an average diameter from 0.1 to 100 .mu.m; and (C) 1-15 parts by weight of a first fiber having an average length from 0.5 to 6 mm in a longitudinal direction thereof and an average diameter from 1 to 20 .mu.m. The first fiber is at least one of a carbon fiber and a synthetic quartz fiber. An ablating material prepared by curing the ablator composition is superior in heat insulation and substantially low in ablation rate, and thus protects a spacecraft or the like from a high temperature gas, for a long time.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: May 18, 1999
    Assignees: Nissan Motor Co., Ltd., Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Morio Ohashi, Hisao Okamoto
  • Patent number: 5902517
    Abstract: An electrically conductive polyacetal composition having improved toughness and flexibility, as well as good fluidity and processability. The composition includes an oxymethylene polymer, an elastomeric polyurethane, and an electrically conductive carbon black having a lower structure level (DBP absorption) and larger particle size (lower surface area) than conductive carbon blacks heretofore used in these compositions. The composition includes between about 65 and about 85 percent, by weight, of the oxymethylene polymer, between about 10 and about 20 percent, by weight, of the electrically conductive carbon black, and between about 10 and about 20 percent, by weight, of the elastomeric polyurethane. The electrically conductive carbon black has a surface area BET (N.sub.2) of between about 40 and about 100 m.sup.2 /g, and a pore volume, DBP absorption, of between about 150 and about 350 ml/100g.
    Type: Grant
    Filed: October 28, 1996
    Date of Patent: May 11, 1999
    Assignee: Cabot Corporation
    Inventor: Alain Thielen
  • Patent number: 5891548
    Abstract: A curable silicone is used to encapsulate porous, photoluminescing silica nanoparticles having three-dimensional, web-like structures. The encapsulation protects the silica nanoparticles, preserves their photoluminescent effect, and can be used as a coating. The composition is used to prepare articles of manufacture by casting it on a substrate such as glass or a silicon wafer and curing it. Special effects can be obtained by using a mask on the substrate prior to deposit of nanoparticles and curing the silicone matrix.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: April 6, 1999
    Assignee: Dow Corning Corporation
    Inventors: Daniel Graiver, Udo C. Pernisz
  • Patent number: 5891951
    Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration and filler as main components. Styrene-based resins of mainly syndiotactic configuration include polystyrene, poly(alkylstyrene), poly(halogenated styrene), poly(alkoxystyrene), styrene copolymers comprised of polymerized units of at least of styrene, alkylstyrene, halogenated styrene and alkoxystyrene, and mixtures thereof.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 6, 1999
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 5883153
    Abstract: There is provided a fluoride-ion sustained release pre-formed glass ionomer filler comprising a powdery reaction product of polyalkenoic acid with a fluorine-containing glass, and a method of producing the same. There is also provided a dental composition containing the filler. The fluoride-ion sustained release pre-formed glass ionomer filler is long capable of releasing fluoride ions in the presence of water without involving disintegration. The dental composition of the invention is useful particularly for prevention of dental caries and like trouble.
    Type: Grant
    Filed: July 15, 1997
    Date of Patent: March 16, 1999
    Assignee: Shofu Inc.
    Inventors: Thomas Arwel Roberts, Kozo Miyai, Kunio Ikemura, Kiyomi Fuchigami, Toshio Kitamura
  • Patent number: 5880194
    Abstract: A curable composition which contains an alkenyl group containing polyorganosiloxane, an organosilicon compound having two silicon-bonded hydrogen atoms, a hydrosilylation reaction catalyst, and a glass frit, which is suitable, upon cure, for use as a firewall sealant.
    Type: Grant
    Filed: September 9, 1997
    Date of Patent: March 9, 1999
    Assignee: Dow Corning Corporation
    Inventors: Khristopher E. Alvarez, Ann W. Norris, Michael J. Watson
  • Patent number: 5877256
    Abstract: The instant invention pertains to a liquid silicone rubber coating composition for application to air bags that is comprised of (A) a diorganopolysiloxane having at least 2 alkenyl groups in each molecule, (B) an organopolysiloxane resin, (C) an inorganic filler, (D) an organohydrogenpolysiloxane having at least 2 silicon-bonded hydrogen atoms in each molecule, (E) a platinum group metal catalyst, and (F) an epoxy group-containing organosilicon compound. The liquid silicone rubber coating composition of the instant invention is capable of coating synthetic air bag fabrics without the use of a diluting solvent and at the same time that has an excellent adhesion to and infiltrability into synthetic air bag fabrics.
    Type: Grant
    Filed: January 22, 1993
    Date of Patent: March 2, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Akito Nakamura, Yuichi Tsuji
  • Patent number: 5872170
    Abstract: A hydrosilylation curable electrically conductive silicone elastomer composition containing an acrylic functional group-containing organopolysiloxane such that when the composition is used to adhere a semiconductor chip to a substrate and the composition is then irradiated with a high energy beam, the exposed periphery of the composition cures to the extent that migration of low molecular weight silicone species from the composition, both before and during the hydrosilyation reaction, is minimized.A method for manufacturing a semiconductor device having improved reliability in which, during adhesion of a semiconductor chip to the substrate, package, etc., by means of this composition, decreases in wire bondability to the semiconductor chip or lead frame and adhesion defects between the semiconductor chip, substrate, package, or lead frame and the sealing resin can be inhibited.A semiconductor device manufactured by this method which has improved reliability.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: February 16, 1999
    Assignee: Down Corning Toray Silicone Co., Ltd.
    Inventors: Katsutoshi Mine, Osamu Mitani, Kazumi Nakayoshi, Rikako Tazawa
  • Patent number: 5869559
    Abstract: A structured composite pigmentary material comprises composite particles consisting of an association of at least one titanium dioxide particle and at least one non-film-forming organic polymer particle wherein the particles are held in association as a result of a positive surface charge on the titanium dioxide particles and a negative surface charge on the polymeric particles, the composition of the composite being such that the ratio by volume of polymeric particles to titanium dioxide particles is in the range 0.3:1 to 0.6:1. An aqueous paint composition and a method of preparing the structured composite pigmentary material are described.
    Type: Grant
    Filed: February 3, 1997
    Date of Patent: February 9, 1999
    Assignee: Tioxide Group Services Limited
    Inventors: Leslie Ainsley Simpson, Daniel James Rutherford, Keith Robson, Michael John Trendell
  • Patent number: 5866648
    Abstract: A long fiber-reinforced polymer alloy resin composition (C) is provided which is obtained by blending a master batch (A) containing a long fiber reinforcement (a2) having a length of 3 to 30 mm in a resin matrix of a polyamide resin (a1), with a substantially polymer-alloyed resin diluent (B) obtained by melt kneading 45 to 20% by weight of a crystalline polyolefin resin (b1) and 55 to 80% by weight of a polyamide resin (b2), the crystalline polyolefin resin (b1) containing a modified olefin crystalline polymer (b11) having been substantially modified with unsaturated carboxylic acids. In this resin composition (C), the amount of the long fiber reinforcement (a2) is in the range of 10 to 60% by weight, and the amount of the crystalline polyolefin resin (b1) in resin components ((a1)+(b1)+(2)) other than the long finer reinforcement (a2) is in the range of 20 to 45% by weight. This resin composition (C) is excellent in tensile strength and particularly excellent in repeated impact resistance properties.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: February 2, 1999
    Assignee: Chisso Corporation
    Inventors: Koichi Saito, Takashi Shimpuku, Rikio Yonaiyama
  • Patent number: 5866653
    Abstract: A curable silicone rubber composition comprising (A) organopolysiloxane comprising at least 2 silicon atom-bonded alkenyl groups in each molecule described by formula R.sub.a SiO.sub.(4-a)/2, where R represents a substituted or unsubstituted monovalent hydrocarbon group and a is a number from 1.95 to 2.05; (B) fine powdery silica; (C) a reaction mixture of (a) a platinum compound and (b) a compound containing an alkynyl group and an alcoholic hydroxy group in each molecule; and (D) a curing agent. The present invention is also a manufacturing method of curable silicone rubber composition. The curable silicone rubber compositions have an excellent flame-retarding property and good tracking resistance and other electrical properties.
    Type: Grant
    Filed: December 15, 1997
    Date of Patent: February 2, 1999
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Takao Matsushita, Osamu Takuman
  • Patent number: 5861453
    Abstract: The present invention relates to a silicone composition prepared by reacting a mixture comprising (i) mineral oil, (ii) a polyorganosiloxane, (iii) a silicon compound, and (iv) a catalytic amount of a catalyst. The compositions of this invention are resistant to phase separation and are useful as foam control compositions in foam producing systems.
    Type: Grant
    Filed: January 28, 1997
    Date of Patent: January 19, 1999
    Assignees: Dow Corning Corporation, Dow Corning S.A.
    Inventors: Teresa Lynn Datz-Siegel, Kenneth Christopher Fey, Jacqueline L'Hostis, Franck A Renauld
  • Patent number: 5854343
    Abstract: The organopolysiloxane compositions are prepared by(1) organopolysiloxanes, and(2) prehydrophobicized oxidic stiffening fillers being blended and kneaded in a kneading machine 1 having at least two kneading chambers 2 which are arranged in series next to one another, each contain two axially parallel kneading tools 3 drivable so as to corotate or counterrotate, and communicate with one another via openings 5 through which passage is possible transversely to the axes 4 of the kneading tools 3, the first kneading chamber 2 having a charging port 6 and the final kneading chamber 2 having a discharge port 7.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: December 29, 1998
    Assignee: Wacker-Chemie GmbH
    Inventors: Johann Schuster, Helmut Wohrl, Johann Mersch, Horst Muller, Peter Webeck
  • Patent number: 5847037
    Abstract: Novel mixtures containing in the anhydrous state at least one polysiloxane, at least one reactive extender, at least one unreactive pigment and/or an unreactive extender, at least one lamellar or fibrous solid, at least one reactive (oligo)silane, optionally together with further additives, to a production process and to the use thereof.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: December 8, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jan Mazanek, Karl-Heinz Kasler, Gebhard Wagner
  • Patent number: 5843340
    Abstract: Conductive polyphenylene ether-polyamide compositions having excellent ductility are prepared by melt blending polyphenylene ether, an unsaturated impact modifying polymer and a functionalizing compound in an initial step, optionally in combination with a portion of the polyamide, and subsequently melt blending with the remainder of the polyamide and conductive carbon black having a low volatiles content. A mixture of polyamides, illustrated by mixtures of polyamide-6 and polyamide-66, is employed.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: December 1, 1998
    Assignee: General Electric Company
    Inventors: Norberto Silvi, William R. Haaf, Mark Giammattei, Robert Hossan, Thomas J. Stanley, William D. Richards
  • Patent number: 5827921
    Abstract: A novel silicone-based coating composition in the form of an aqueous emulsion is proposed which is capable of giving a rubber-like cured coating film of excellent mechanical strengths and flexibility on the surface of various substrate materials exhibiting high adhesive bonding thereto. The composition comprises:(a) water as the dispersion medium of the emulsion; and(b) a combination of the ingredients as the dispersed phase comprising:(A) 100 parts by weight of an organopolysiloxane having, in a molecule, at least two alkenyl groups bonded to the silicon atoms;(B) from 0.05 to 20 parts by weight of an organohydrogen polysiloxane having, in a molecule, at least two hydrogen atoms directly bonded to the silicon atoms;(C) from 1 to 100 parts by weight of a colloidal silica or a polyorganosilsesquioxane;(D) from 0.5 to 20 parts by weight of a reaction product of an amino group-containing organosilane compound and a carboxylic acid anhydride compound; and(E) from 0.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: October 27, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshihito Osawa, Sachiko Nezu, Yoshinobu Takahashi, Satoshi Kuwata
  • Patent number: 5824730
    Abstract: The invention relates to a water based binder for use in a slurry for investment casting. The binder includes a mixture of a colloidal silica sol and at least one latex polymer. The latex polymer is preferably an acrylic latex or a styrene butadiene polymer (or a combination of these) which reduces the processing time between dips during shell mold making for investment casting. The latex polymer further lowers a critical concentration point or gelation point of the colloidal silica sol. The binder may be used as a primary binder or a backup binder in the shell mold making process. To make the slurry, the binder is combined with at least one refractory powder, preferably a refractory powder selected from the group of: alumino-silicates, fused silica, quartz silica, alumina, zircon, and zirconia.
    Type: Grant
    Filed: August 13, 1993
    Date of Patent: October 20, 1998
    Assignee: Remet Corporation
    Inventor: Manuel Guerra, Jr.
  • Patent number: 5798412
    Abstract: A process in which carbon is used to catalyze production of alkylene glycols from alkylene oxides and water. Using this process, carbon may be employed to selectively catalyze the hydrolysis of alkylene oxides, such as ethylene oxide, to monoalkylene gylcols, such as monoethylene glycol. Typically, activated carbon is employed. Suitable forms of activated carbon or other carbon material include powders, granulates, extruded shapes, or mixtures thereof. The process may be carried out as a continuous or batch reaction process.
    Type: Grant
    Filed: July 16, 1997
    Date of Patent: August 25, 1998
    Assignee: Huntsman Petrochemical Corporation
    Inventors: John R. Sanderson, Edward T. Marquis
  • Patent number: 5789485
    Abstract: The present invention relates to a curable silicone composition comprising (A) an alkenyl-functional organopolysiloxane, (B) a siloxane-modified acrylic polymer, (C) an organohydrogenpolysiloxane, and (D) a hydrosilylation reaction catalyst. The curable silicone compositions of this invention cure into a highly oil-resistant and highly wear-resistant coating and are useful as base compositions for inks for silicone moldings, and are also useful for imparting release against pressure sensitive adhesives while maintaining a degree of printability.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: August 4, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Akihiko Kobayashi, Takayoshi Otomo, Hiroaki Yoshida
  • Patent number: 5777002
    Abstract: A method for preparing organopolysiloxane bases with high levels of fillers. The present inventors have found that by mixing the components of the base at a temperature below about 60.degree. C. for a period of time sufficient to effect essentially a homogeneous blend, a base composition is formed which can be further blended with a platinum group metal-containing catalyst, an organohydrogensiloxane, and optionally an inhibitor to form a curable liquid silicone rubber (LSR) composition. The curable LSR composition has improved flow characteristics and improved shelf life when compared to similar materials where the base is prepared at temperatures above about 60.degree. C. The improved flow characteristics allows larger quantities of fillers to be incorporated into the curable LSR composition while still maintaining acceptable flow characteristics.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: July 7, 1998
    Assignee: Dow Corning Corporation
    Inventors: Lori Jean Conway, Thomas Edward Gray, Phillip Joseph Griffith, William James Schulz, Jr.
  • Patent number: 5770640
    Abstract: Finishing agents comprise the combination of an alkoxysilane surface active agent, a silanol condensing catalyst, and a nonaqueous liquid or solid medium, or the combination of an alkoxysilane surface active agent, an acid catalyst and a liquid or solid medium. In the latter embodiment, it is preferred that at least one of the alkoxysilane surface active agent and the acid catalyst be microencapsuled. The finishing agent permits formation of chemically adsorbed protecting films. Such protecting films are used for substrates of such equipments as electronics products, electric domestic products, automobiles, industrial equipment, mirrors, lenses for glasses and the like. The protecting films have a durability and heat, weather and abrasion resistance, and also water and oil repellent properties.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: June 23, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 5767193
    Abstract: Provided are a non-foaming curable silicone elastomer composition and a method of preparing such a composition: with the composition comprising (A) 100 parts by weight of an organopolysiloxane mixture constituted at least of 90-10 parts by weight of organopolysiloxanes (i) containing, in a molecule, at least two alkenyl groups and substantially no silicon-attached hydroxyl group and having their kinematic viscosity in the range of 100 to 100,000 centistokes (cSt) at 25.degree. C. and 10-90 parts by weight of organopolysiloxanes (ii) containing, in a molecule, at least one hydroxyl group attached directly to a silicon atom and at least one alkenyl group attached directly to a silicon atom and having their kinematic viscosity in the range of 100 to 100,000 cSt at 25.degree. C.; (B) organohydrogenpolysiloxanes having in each molecule at least 3 hydrogen atoms attached directly to silicon atoms in an amount that the organohydrogenpolysiloxanes afford 0.4-10.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: June 16, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Kouichi Tanaka
  • Patent number: 5767185
    Abstract: High performance silicone rubber windshield wiper blades are provided as a result of molding a tintable platinum group metal catalyzed silicone compositions having an intrinsic viscosity of less than 1.3. Improved lubricity with respect to windshield wiper glass is achieved by a molding procedure which effects a transfer such as a migration, or diffusion of release agent, for example polytetrafluoroethylene, into the surface of the silicone rubber windshield wiper blade.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: June 16, 1998
    Assignee: Specialty Silicone Products, Inc.
    Inventor: Ned J. Reo
  • Patent number: 5760104
    Abstract: A binder solution of a phenolic novolak resin in solvent, preferably furfuryl alcohol containing at least one chemical agent such as amines containing one to five, preferably two to four, nitrogen atoms, glycerine or mixtures thereof. Preferably, the binder solution contains about 0.2 to about 1.5 weight percent water. The binder solution is for binding refractory objects, preferably those containing doloma (calcined dolomite) aggregate. Methods of mixing these ingredients and using the mixture are also disclosed. Bricks made from the doloma aggregate mixed with the binder solution show good ambient temperature green strength and enhanced modulus of rupture after curing and coking.
    Type: Grant
    Filed: July 9, 1997
    Date of Patent: June 2, 1998
    Assignee: Borden Chemical, Inc.
    Inventor: Arthur Harry Gerber
  • Patent number: 5719220
    Abstract: A highly filled, curable composition comprising (A) an addition polymerizable organic liquid which on curing forms a solid polymer, (B) 20 to 80% by volume of a finely divided particulate inorganic filler having a weight average particle size of less than 50 microns but not having a BET surface area of more than 30 m.sup.2 .multidot.cm.sup.-3, and (C) 0.05 to 0.5% by weight of a polydimethylsiloxane and molded composite articles produced therefrom are disclosed. Such articles exhibit improved resilience to thermal shock.
    Type: Grant
    Filed: October 4, 1996
    Date of Patent: February 17, 1998
    Assignee: Imperial Chemical Industries PLC
    Inventor: Neil Kirtley
  • Patent number: 5712337
    Abstract: A hardenable composition suitable for flooring and for coating concrete surfaces comprising(a) an acrylic binder comprising a (meth)acrylic ester of the formula ##STR1## where R.sub.1 is C.sub.2-6 alkylene, n is 0-3 and R.sub.2 is a radical of an aromatic or alicyclic dicarboxylic acid ester or a dicyclopentenyl radical, n being 0 only when R.sub.2 is a dicyclopentenyl radical, and(b) a component which is one or both (preferably both) of carbon black and a polyfunctional aliphatic or aromatic polyester- or polyether- urethane oligomer. The composition also preferably comprises aggregate such as sand. The compositions have excellent impact resistance and flexural strength.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: January 27, 1998
    Assignee: MBT Holding AG
    Inventor: Karoly Discho
  • Patent number: 5702809
    Abstract: The aqueous composition for antistatic layer according to the invention comprises vanadium pentoxide and a polyurethane which includes no sulfonated groups and which is stable in an acidic medium, the weight ratio of vanadium pentoxide to polyurethane preferably being between 1:200 and 5:1. Polymeric supports coated with such a composition can be used for transparencies for photocopy, for mounting supports in the field of printing, or in photographic or magnetic products and in packaging.
    Type: Grant
    Filed: June 10, 1996
    Date of Patent: December 30, 1997
    Assignee: Eastman Kodak Company
    Inventors: Jean-Pierre Tixier, Annie Francoise Armande Legrand