Abstract: The present invention relates to a silicone composition prepared by reacting a mixture comprising (i) mineral oil, (ii) a polyorganosiloxane, (iii) a silicon compound, and (iv) a catalytic amount of a catalyst. The compositions of this invention are resistant to phase separation and are useful as foam control compositions in foam producing systems.

Abstract: The present invention relates to a curable silicone composition comprising (A) an alkenyl-functional organopolysiloxane, (B) a siloxane-modified acrylic polymer, (C) an organohydrogenpolysiloxane, and (D) a hydrosilylation reaction catalyst. The curable silicone compositions of this invention cure into a highly oil-resistant and highly wear-resistant coating and are useful as base compositions for inks for silicone moldings, and are also useful for imparting release against pressure sensitive adhesives while maintaining a degree of printability.

Abstract: A removable coating composition comprises oxidized polyethylene wax, paraffin wax, and acrylic copolymer. A process of protecting surfaces comprises applying the coating composition in an aqueous emulsion to a surface and drying. The resulting coated surface is protected such that when graffiti is applied to the coated surface, the graffiti and coating are easily removed with hot water or steam.

Abstract: The invention provides a semiconductive silicone rubber composition comprising (A) an organopolysiloxane containing at least two aliphatic unsaturated groups, (B) reinforcing silica powder having a specific surface area of at least 50 m.sup.2 /g, (C) a conductive agent, (D) a hydrocarbon oil having a heat loss of up to 30% at 200.degree. C./4 hours, and (E) a curing agent. Cured silicone rubber of the composition has a resistance of 1.times.10.sup.3 to 1.times.10.sup.12 .OMEGA. which remains stable for long-term use. The semiconductive silicone rubber composition is appropriate as a semiconductive roll stock for the manufacture of charging rolls, transfer rolls and developing rolls in business machines.

Abstract: A significantly improved plasticizer-polymer composition embraces a polymer containing a di-, tri- and/or tetra- ethyl-, propyl- and/or butylbiphenyl plasticizer which constitutes the major proportion by weight of any other plasticizing/softening additive, provided that the polymer is not polyvinyl chloride and when the polymer is an elastomer or rubber, or is a polystyrene, said plasticizer is diisopropylbiphenyl and/or triisopropylbiphenyl, and when the polymer is of a plastisol, essentially no ester plasticizing additive is present. As well, a polymer fabrication composition comprises a monomer and/or oligomer component in combination with said plasticizer. A method for preparing the plasticizer-polymer composition and/or the fabrication composition comprises contacting the monomer and/or oligomer component with said plasticizer, mixing to provide a uniform mixture, and carrying out further processing as may be desired so as to optionally prepare the plasticized-polymer composition.

Abstract: A polyetherketone resin composition comprising 5-100 parts by weight of a carbon fiber having an average fiber diameter of 5-20 .mu.m and an average fiber length of 30-500 .mu.m per 100 parts by weight of a composition comprising 95-50% by weight of a polyetherketone and 5-50% by weight of a liquid crystal polyester, and a carrier for processing or treating a semi-conductor wafer molded from the above polyetherketone resin composition. Said composition is excellent in molding properties and said carrier is excellent in stiffness, dimensional stability and antistatic properties.The above liquid crystal polyester includes, for example, those consisting of repeating structural units (I), (II), (III) and (IV), shown below, in a molar ratio (II)/(I) of 0.2-1.0, a molar ratio ?(III)+(IV)!/(II) of 0.9-1.1 and a molar ratio (IV)/(III) of 0-1.0.

Abstract: The present invention provides a color concentrate comprising (a) at least one resin selected from the group consisting of a polymer of a diene, a rosin material, a coumarone-indene resin, a polymer of vinyl aromatic monomer having an M n of from about 500 to about 4000, a wax and a mixture of two or more thereof, (b) at least one resin selected from the group consisting of a copolymer of an olefin and an acrylate or a methacrylate, a polymer of a vinyl aromatic monomer having an M n of at least about 10,000 and a mixture thereof, and (c) at least one colorant.

Abstract: Aqueous, autocrosslinking polymer dispersion binders comprising polyhydrazides and carbonyl-containing polyurethane-vinyl hybrid polymers and also, if desired, conventional additives, are useful in base coatings, aqueous coatings, adhesives and printing inks.

Abstract: An oil composition which has a kinematic viscosity at 100.degree. C. of from 32 to 50 cSt and which contains less than 3 wt. percent polynuclear aromatic compounds is employed as a process oil for rubber compounds, especially aromatic rubbers. The process oil is compatible with aromatic rubbers but contains less toxic polynuclear aromatic compounds than conventional aromatic rubber process oils. Rubber products of acceptable quality are produced by the use of the said oil composition.

Abstract: A method of making polymeric particles of at least 1.0 micrometer which comprises forming at atmospheric conditions droplets of an ethylenically unsaturated monomer the monomer being liquid at standard conditions of 0.degree. C. and one atmosphere pressure, together with from about 0.01 to about 5 percent by weight, based on the weight of the monomer, of a nonreactive compound in an aqueous medium, the nonreactive compound having a solubility in water less than that of the ethylenically unsaturated monomer, the aqueous medium containing a surfactant or organic hydrophilic colloid, the monomer droplets being formed by using only sufficient energy to achieve a size of 1.0 micrometer or larger, and polymerizing the ethylenically unsaturated monomer.

Abstract: A significantly improved plasticizer-polymer composition embraces a polymer containing a di-, tri- and/or tetra- ethyl-, propyl- and/or butylbiphenyl plasticizer which constitutes the major proportion by weight of any other plasticizing/softening additive, provided that the polymer is not polyvinyl chloride and when the polymer is an elastomer or rubber, or is a polystyrene, said plasticizer is diisopropylbiphenyl and/or triisopropylbiphenyl, and when the polymer is of a plastisol, essentially no ester plasticizing additive is present. As well, a polymer fabrication composition comprises a monomer and/or oligomer component in combination with said plasticizer. A method for preparing the plasticizer-polymer composition and/or the fabrication composition comprises contacting the monomer and/or oligomer component with said plasticizer, mixing to provide a uniform mixture, and carrying out further processing as may be desired so as to optionally prepare the plasticized-polymer composition.

Abstract: A release modifier which comprises (i) a MQ resin consisting essentially of units of the formulae SiO.sub.2 and R.sub.3 SiO.sub.1/2 wherein R denotes a monovalent hydrocarbon group having up to 3 carbon atoms, a hydrogen atom, a c.sub.2-5 alkenyl group of the formula --R'CH.dbd.CH.sub.2, provided there is at least one group --R'CH.dbd.CH.sub.2 present per MQ molecule and (ii) a .alpha.,.omega.-diolefin having the general formula CH.sub.2 .dbd.CH--(CH.sub.2).sub.n --CH.dbd.CH.sub.2, wherein n denotes an integer with a value of from 4 to 18 gives improved release force over prior art controlled release additives. Also claimed is a solventless release composition based on siloxanes having SiH groups and a catalyst in addition to the release modifier.

Abstract: A release modifier for silicone release compositions comprising a MQ resin consisting essentially of units of the formulaeSiO.sub.2 (Q) and R.sub.3 SiO.sub.1/2 (M)wherein R denotes a monovalent hydrocarbon group having up to 3 carbon atoms, a hydrogen atom, an alkenyl group of the formula --R'CH.dbd.CH.sub.2 or an oxyalkenyl group of the formula --OR'CH.dbd.CH.sub.2, wherein R' denotes an alkylene group of from 4 to 12 carbon atoms, provided there is at least one group --R'CH.dbd.CH.sub.2 or one group --OR'CH.dbd.CH.sub.2 present per MQ molecule and that no more than 50% of all M units have such groups. Also claimed is a solventless release composition based on siloxanes having SiH groups and a catalyst in addition to the release modifier.

Abstract: Process for the manufacture of a polymeric object starting from a solution of a polymer in a solvent and comprising drawing a solvent-containing polymeric object, the solvent containing a first and a second component, the first component being more volatile than the second one and drawing being effected in the presence of the second component after removal of the first component, and a solution of a spinable polymer in a solvent containing two components, one of the components being more volatile than the other.

Abstract: A hardenable monomer composition useful for flooring composition, grouts, mortars and the like comprises a mixture of crosslinkable acrylic monomer, carbon black and/or polyester- or polyether-methane oligomer having at least two polymerizable double bonds and a paraffin oil.The monomer is preferably of the formula I ##STR1## and there is preferably present other monomers, particularly hydroxypropyl methacrylate.

Abstract: The composition of the present invention comprises a oil-resistant silicone rubber composition that undergoes little swelling even when used in regular or continuous contact with mineral oil-based lubricating oil such as engine oil and so forth. The oil-resistant silicone rubber composition comprises:(A) a dimethylsiloxane-3,3,3-trifluoropropylmethylsiloxane-methylvinylsiloxane copolymer gum that contains 0.001 to 5 mole percent methylvinylsiloxane unit,(B) a hydrocarbon oil or diorganopolysiloxane oil wherein the total in each diorganopolysiloxane oil molecule of the number of silicon-bonded hydrogen atoms and the number of functional groups reactive with component (A) or (C) is less than two,(C) a reinforcing filler, and(D) a curing agent in a quantity sufficient to cure the composition.

Abstract: A moisture-curable, substantially solvent-free and anhydrous blend of a bituminous material such as asphalt and a liquid prepolymer is disclosed, which blend when cured, results in an elastomer having excellent adhesion to surfaces exposed outdoors. The stability of the blend derives from asphalt being microdispersed in a dispersed phase within a continuous phase of the liquid prepolymer so that particles of asphalt are in the size range from 0.5 .mu.m to 100 .mu.m. The asphalt is treated to react all functional groups it may have because they may react with a functional group of the liquid prepolymer. The prepolymer is a polyurethane, a terpolymer of ethylene-propylene-diene, or a silicone. The microdispersion is stably maintained by a compatibilizer having opposed substantially polar and non-polar terminal portions, present in an amount in the range from 0.01 to 5 parts per 100 parts of the blend. The compatibilizer is chosen from (A) an ester of a C.sub.2 -C.sub.

Abstract: A silicone putty composition having high impact resilience immediately after preparation and providing a soft silicone putty having low plasticity is obtained by blending (1) a diorganosiloxane of the formula:R.sub.n SiO.sub.(4-n)/2wherein R is a substituted or unsubstituted monovalent hydrocarbon group and n is a number of from 1.98 to 2.02, (2) an organopolysiloxane having a terminal alkoxy group, (3) boric acid or boron oxide, and (4) liquid paraffin. The composition is suited for use in toys and dampers.

Abstract: The invention relates to novel gelloid composition comprising a crosslinked non-silicone polymer having an olefinic unsaturated content of less than 10 mole percent and having dispersed therein a liquid in an amount of from about 20% to about about 95% by weight based on the weight of the liquid and polymer and from 0 to 0.3 volume fraction of a filler, said cross-linked polymera) if derived from a solid, relatively high molecular weight polymer, having a gel fraction of at least about 50%, orb) if derived from a liquid, relatively low molecular weight polymer, having at least about 0.1 crosslinks per weight average molecule;said composition having a modulus of (1+2.5v+14.1v.sup.2)x dynes/cm.sup.2 wherein x is less than 5.times.10.sup.5 at 30.degree. C. and greater than 5.times.10.sup.2 at 90.degree. C., and v is the volume fraction of the filler, with the proviso that, if the crosslinked polymer is prepared from a solid high molecular eight polymer, the storage modulus at 140.degree. C.

Abstract: A coating slurry comprised of 42 percent silicon and 10 percent chromium metal powders; 45 percent lacquer base including toluene, xylene, and a polymeric binder; and 3 percent antisettling agent. After the slurry has been applied and then subjected to a high temperature vacuum processing, a ceramic coating is obtained which provides 3000.degree. F. high temperature oxidation protection for a refractory tantalum alloy substrate.

Abstract: Organopolysiloxane compositions that are storage-stable under anhydrous conditions, but curable into elastomeric state in the presence of moisture and, thus, are well suited as sealants and coatings and which particularly strongly adhere to substrates used in the construction industry, contain at least one .alpha., .omega.-dihydroxydiorganopolysiloxane polymer; at least one ketiminoxysilane crosslinking agent therefor; a bonding agent including admixture, or reaction product of, (i) an aminoorganosilicon compound containing a primary amine group, with (ii) an organosilicon compound containing an epoxy functional group; and, advantageously, a filler material and a curing catalyst.

Abstract: The present invention is directed to a process for the direct production of a pigmented thermoplastic polyurethane powder in finely divided form by(a) reacting with agitation at an overall equivalent ratio of isocyanate groups to isocyanate reactive groups of about 0.5 to 1.1(i) a surfactant-stabilized emulsion of fine droplets of a first reactant which has an average of about two isocyanate or isocyanate reactive groups in admixture with at least one pigment with(ii) a second reactant which contain an average of about two isocyanate or isocyanate reactive groups,in an inert organic liquid in which the first reactant, the pigment and the powder are substantially insoluble or immiscible to form particles of the powder which are protected from agglomeration by the surfactant, and(b) separating the particles of the powder from the inert organic liquid.The present invention is also directed to the pigmented thermoplastic polyurethane powders obtained by this process.

Abstract: Organopolysiloxane compositions that are storage-stable under anhydrous conditions, but curable into elastomeric state in the presence of moisture and, thus, are well suited as sealants and coatings and which particularly strongly adhere to substrate used in the construction industry, contain at least one .alpha., .omega.-dihydroxydiorganopolysiloxane polymer; at least one acyloxysilane crosslinking agent therefor; a bonding agent including admixture, or reaction product of, (i) an aminoorganosilicon compound containing a primary amine group, with (ii) an organosilicon compound containing an epoxy functional group; and, advantageously, a filler material and a curing catalyst.

Abstract: An addition or condensation cross-linking molding or lining compound based on silicones comprising(a) an organo polysiloxane containing reactive end groups,(b) a catalyst,(c) a filler, and(d) an isoparaffin having 8 to 24 carbon atoms.The compounds being particularly useful as dental molding compositions.

Abstract: An article and process for splicing electrical wires that are to be exposed to an adverse environment. The article includes a connector, an insulating sleeve adapted to retain the connector, and an encapsulant. The encapsulant, which is disposed within the insulating sleeve, has a cone penetration value of 100 to 350 (10.sup.-1 mm) and an ultimate elongation of at least 200%.

Abstract: Copolymers adapted for use as stabilizers in dispersions and stable dispersions, including crosslinked dispersions containing microgel particles, prepared therefrom. Stabilizer bears pendent ethylenic unsaturation capable of reacting with monomers employed in random copolymerization used to make the dispersion polymer. Stabilizer comprises a random copolymer segment of ethylenically unsaturated monomers, some of which are characterized in that homopolymers thereof would be substantially insoluble in the organic liquid used to form the stable dispersion and some of which are characterized in that homopolymers thereof would be substantially soluble in the organic liquid used to form the stable dispersion.

Abstract: A cyclic olefin extended polyurethane system comprising the reaction product of an isocyanate terminated polyisocyanate with a polyol in the presence of a cyclic olefin extender and, optionally, a liquid ester or other type of extender. Said polyurethane systems are cured, crosslinked, non-spewing, grease compatible, and reenterable. This extended polyurethane is further characterized as having superior insulating properties so that it can be used for repairing, encapsulation or reclaiming electrical or telephone cables as well as hard volume encapsulants for general elastomer use. The extended polyurethane is comprised of a defined polyurethane, novel extender combinations, and optionally, a coupling agent.

Abstract: Impact styrene polymers, prepared in stratified polymerizers wherein one polymerizing zone is recirculated and a solvent is employed, can have improved environmental stress crack resistance when an aliphatic hydrocarbon is utilized as solvent rather than an aromatic or cycloaliphatic solvent.

Abstract: Slurries of cross linked carboxyl acid polymers in petroleum base liquids such as mineral spirits are readily obtained by a solvent exchange process wherein a slurry of cross-linked carboxylic acid polymer in the organic liquid it was polymerized in, said liquid having a boiling point below that of the mineral spirits, is heated to a temperature to distill off the polymerization organic liquid while replacing this organic material with the mineral spirits, which may be done simultaneously while essentially maintaining constant volume if desired.