Halogen-containing Monomer Patents (Class 524/851)
-
Patent number: 10472535Abstract: A method for producing a fluorinated copolymer solution polymerizing a monomer mixture of a fluoro-olefin (A), a monomer (B) having a crosslinkable group and a monomer (C) having no fluorine atom and no crosslinkable group in the presence of an organic solvent and a compound having two or more piperidyl group represented by the formula (1):Type: GrantFiled: March 31, 2015Date of Patent: November 12, 2019Assignee: AGC Inc.Inventors: Shiro Ebata, Toshinori Tomita, Masakazu Ataku, Shun Saito, Sho Masuda
-
Publication number: 20150125695Abstract: A composition having at least one first component containing a perfluorinated aliphatic structure in which no more than six fluorine bearing carbons are connected in any single straight chain segment, in addition a group providing binding functionality to a surface to be treated or containing at least one polymerisable double bond or containing at least one cross-linkable group, and in addition a divalent radical containing at least one group capable of forming polar interactions or hydrogen bonds, and at least one second component containing a perfluorinated aliphatic structure in which no more than six fluorine bearing carbons are connected in any single straight chain segment and a moiety containing at least one group providing binding functionality to a surface to be treated or containing at least one polymerisable double bond or containing at least one cross-linkable group.Type: ApplicationFiled: November 3, 2014Publication date: May 7, 2015Inventors: ERIC HUEBSCH, Noel Stephen Brabbs
-
Patent number: 8927649Abstract: A one part, storage stable polymerizable formulation is provided that includes an ethenically unsaturated polymerizable compound intermixed with a free radical polymerization initiator and an organic solvent. The organic solvent provides storage stability and upon evaporation of the solvent, the rate of polymerization of the compound accelerates independent of addition of a second part. The formulation includes at least 30 total weight percent solids upon cure. Optional additives to the formulation include at least one of a cure accelerator, a filler, a plasticizer, a colorant, and a cure inhibitor. A process for forming a polymerized coating on an article involves the application of this formulation to the substrate of an article and allowing sufficient time for the solvent to evaporate to form the polymerized coating on the article. The substrate of the article forms a corrosion barrier even without prior removal of a native corrosion layer on a surface of the substrate of the article.Type: GrantFiled: October 5, 2010Date of Patent: January 6, 2015Inventor: Ron Lewarchik
-
Publication number: 20140343219Abstract: There is provided a method of fabricating a composite material, the method comprising providing borehole solids originating from a borehole in the earth and embedding the borehole solids in a base material thereby forming the composite material, wherein the base material comprises a polymer. According to an embodiment, the borehole solids contain oil, e.g. on a surface thereof. The oil containing borehole solids may be preprocessed before embedding or may be directly embedded in the base material without preprocessing. Such embodiments allow for a recycling of oil contaminated borehole solids while providing a resource for a filler for polymers.Type: ApplicationFiled: September 14, 2012Publication date: November 20, 2014Applicant: MONTANUNIVERSITÄT LEOBENInventors: Herbert Hofstätter, Clemens Holzer
-
Publication number: 20140154486Abstract: The present invention relates to an anti-reflective coating composition providing improved scratch resistance, a method for manufacturing an anti-reflective film using the same, and an anti-reflective film manufactured thereby. According to the present invention, provided are a composition that is able to form a coating layer having improved surface scratch resistance, while forming one or more layers by a single coating process, and an anti-reflective film manufactured by using the same.Type: ApplicationFiled: September 28, 2012Publication date: June 5, 2014Applicant: LG Chem, Ltd.Inventors: Heon Kim, Joon-Koo Kang, Yeong-Rae Chang, Hye-Min Kim
-
Publication number: 20140147745Abstract: To provide a binder for a storage battery device, whereby good adhesion is obtainable, and it is possible to realize good charge and discharge characteristics in a secondary battery by well suppressing swelling of an electrode by an electrolytic solution. A binder for a storage battery device, which is made of a fluorinated copolymer comprising repeating units (a) derived from tetrafluoroethylene and repeating units (b) derived from propylene, wherein the molar ratio (a)/(b) is from 60/40 to 75/25, and the total of the repeating units (a) and (b) is at least 90 mol % in all repeating units.Type: ApplicationFiled: January 29, 2014Publication date: May 29, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Mizuna TOYODA, Takehiro KOSE, Hiroki NAGAI
-
Patent number: 8697801Abstract: A plastic pallet having a fire retardant. The fire retardant is prepared in an FR masterbatch before mixing with HDPE to form the pallet. In one embodiment, the FR masterbatch includes a brominated fire retardant, a hydrated mineral, antimony trioxide and a carrier resin. In some embodiments, the brominated fire retardant is a non-blooming brominated fire retardant such as poly pentabromobenzyl acrylate or ethylenebistetrabromophthalamide. The hydrated mineral advantageously enhances both the vapor phase and condensed phase fire retardant properties of the final product and may be magnesium hydroxide. In other embodiments, melamine pyrophosphate or a blend of melamine pyrophosphate and polyhydric compound may be substituted for the hydrated mineral or used as the sole fire retardant. The polyhydric compound may be bis-pentaerythritol phosphate alcohol. A method of manufacturing a plastic pallet is also disclosed.Type: GrantFiled: June 4, 2013Date of Patent: April 15, 2014Assignee: Primex Plastics CorporationInventor: Paul D. Zwick
-
Publication number: 20140051805Abstract: To provide a water/oil repellent composition with which an article which has favorable water/oil repellency and washing durability, and into which infiltration of a coating liquid can be suppressed, is obtained, and which presents a low environmental impact, its production method and an article having its surface treated with the composition. A water/oil repellent composition comprising a copolymer (X) having structural units based on the monomer (a) and structural units based on the monomer (b), and an aqueous medium, wherein the mass average molecular weight of the copolymer is at least 60,000, and the proportion of the structural units based on the monomer (a) is 60 to 95 mass %. Monomer (a): by (Z—Y)nX, wherein Z is a e.g. C1-6 polyfluoroalkyl group, Y is e.g. a bivalent organic group having no fluorine atom, n is 1 or 2, and X is a polymerizable unsaturated group. Monomer (b): vinyl chloride.Type: ApplicationFiled: October 21, 2013Publication date: February 20, 2014Applicant: Asahi Glass Company, LimitedInventors: Minako SHIMADA, Eiji Morimoto, Yuuichi OOmori
-
Publication number: 20140018499Abstract: A process is provided for polymerizing fluoromonomer in an aqueous medium, wherein a dispersion of essentially surfactant-free hydrocarbon-containing oleophilic nucleation sites is first formed in the aqueous medium, and then polymerization is commenced to form a dispersion of fluoropolymer particles at the oleophilic nucleation sites, wherein the nucleation sites can be derived from hydrocarbon-containing compound. The surfactant used to stabilize the fluoropolymer dispersion can also be hydrocarbon-containing.Type: ApplicationFiled: September 19, 2013Publication date: January 16, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: PAUL DOUGLAS BROTHERS, SUBHASH VISHNU GANGAL, DIPTI DILIP KHASNIS
-
Patent number: 8536270Abstract: To provide a resist composition including: at least one polymerizable compound having a viscosity of 100 mPa·s or less at 25° C.; a fluorine-containing compound A having a viscosity of 5,000 mPa·s or greater at 25° C., and a fluorine content of 10% by mass or greater; and a fluorine-containing compound B having a viscosity of 2,000 mPa·s or less at 25° C., and a fluorine content of 10% by mass or greater.Type: GrantFiled: March 25, 2010Date of Patent: September 17, 2013Assignee: FujiFilmInventor: Tadashi Omatsu
-
Patent number: 8535699Abstract: In order to provide a controlled-release insect-controlling resin molded product and a insect-controlling resin composition for making such a controlled-release insect-controlling resin molded product that have immediate effectiveness, residual effectiveness, and preservation stability and that are excellent in merchantability and manufacturing control, the present invention uses an insect-controlling resin composition including a polyvinyl chloride resin containing a non-vaporizable insect-controlling component and erucic acid.Type: GrantFiled: December 22, 2010Date of Patent: September 17, 2013Assignee: Sumika Life Tech, LimitedInventors: Shinobu Kawaguchi, Masayuki Tatsumi, Kiyoshi Mitsui, Masato Mizutani, Kouzi Noda
-
Patent number: 8461251Abstract: A method for producing a fluoroolefin copolymer solution, gives the copolymer solution good storage stability and suppressed coloration. The method for producing a fluoroolefin copolymer solution includes subjecting at least one fluoroolefin and at least one monomer other than the fluoroolefin to a solution polymerization in an organic solvent in the presence of potassium carbonate and hydrotalcite.Type: GrantFiled: July 20, 2011Date of Patent: June 11, 2013Assignee: Asahi Glass Company, LimitedInventors: Yuji Hara, Kiyoshi Kasahara, Shou Masuda
-
Patent number: 8227521Abstract: Fluoropolymer foams are prepared by mixing fluoropolymer resin with blowing agents and additives to produce foamable compounds at temperatures below the activation temperature of the blowing agent. The compounded material is expanded at temperatures above both the softening point of the fluoropolymer resin and the activation temperature of the blowing agent. The resulting fluoropolymer foam can be fabricated into any desired shape, such as pipes, sheets, tapes, blocks and rods, using techniques such as cutting, welding, thermoforming and adhesive bonding. Alternatively the fluoropolymer compound may be expanded directly into the desired shape, for example, by expanding the compound in a mold.Type: GrantFiled: November 12, 2008Date of Patent: July 24, 2012Assignee: Zotefoams PLCInventors: Paul Jacobs, Roger Lock, Neil Witten
-
Patent number: 8183314Abstract: Provided are oil-in-water and water-in-oil emulsion compositions including from 0.01 to 5 wt % of a halogenated elastomer emulsifier, and optionally from to 0.5 wt % of a polyalkylene amine co-emulsifier. The emulsion compositions disclosed herein provide for increased interfacial elasticity and decreased interfacial tension at the oil-water interface to increase resistance to coalescence of dispersed water droplets of a water-in-oil emulsion or oil droplets of an oil-in-water emulsion. The emulsion compositions disclosed herein are suitable for lubricant applications due to their resistance to shear thinning.Type: GrantFiled: June 26, 2009Date of Patent: May 22, 2012Assignee: Exxonmobil Research and Engineering CompanyInventors: Ramesh Varadaraj, Cornelius Hendrick Brons, David John Lohse
-
Publication number: 20120067908Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Compositions that include perfluorohexyl(meth)acrylate and a branched or high Tg monomer are provided as are articles coated with the polymerization product of the composition. Methods are also provided for forming hydrophobic coatings on articles.Type: ApplicationFiled: August 16, 2011Publication date: March 22, 2012Applicant: CYTONIX, LLCInventor: James F. BROWN
-
Publication number: 20120037835Abstract: To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency and post-air-drying water repellency to the surface of an article and which presents a low environmental impact, a method for its production and a method for treating an article. A water/oil repellent composition which comprises a copolymer having structural units based on the following monomer (a) and structural units based on the following monomer (b) and having a mass average molecular weight of at least 40,000, and a medium, is used. Monomer (a): a compound represented by (Z—Y)nX, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or the like, n is 1 or 2, and X is a polymerizable unsaturated group. Monomer (b): an olefin, a homopolymer of which has a glass transition temperature of from ?50° C. to 50° C.Type: ApplicationFiled: October 21, 2011Publication date: February 16, 2012Applicant: Asahi Glass Company, LimitedInventors: Nobuyuki OTOZAWA, Kazunori SUGIYAMA, Minako SHIMADA, Yuuichi OOMORI
-
Publication number: 20120037400Abstract: A composition that includes at least one crosslinkable monomer; at least one hydrophobic monomer; and at least one dielectric constant enhancing agent selected from dielectric enhancing monomers, ferroelectric particulates, and electroactive polymers. Coatings including the polymer of compositions, and articles including electrically isolating layers are also disclosed.Type: ApplicationFiled: October 25, 2011Publication date: February 16, 2012Inventors: Lenwood L. Fields, Arthur W. Martin, Shawn M. O'Malley, Dean M. Thelen
-
Publication number: 20110275753Abstract: To provide a method for producing a fluoroolefin copolymer solution, whereby good storage stability of the copolymer solution is obtainable, and coloration of the solution can be suppressed, and a method for producing a coating composition. A method for producing a fluoroolefin copolymer solution, which comprises subjecting at least one fluoroolefin (a) and at least one monomer (b) other than the fluoroolefin (a) to a solution polymerization in an organic solvent in the presence of potassium carbonate and hydrotalcite.Type: ApplicationFiled: July 20, 2011Publication date: November 10, 2011Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Yuji HARA, Kiyoshi Kasahara, Shou Masuda
-
Patent number: 7956143Abstract: Compositions for bonding substrate surfaces, particularly steel, aluminum, and urethane-primed galvanized steel, are disclosed. Desirably, the compositions include a stable emulsion including: (a) at least one curable (meth)acrylate component; (b) at least three different elastomeric polymers that are soluble and/or partially soluble in the (meth)acrylate component; and (c) optionally at least one elastomeric polymer that is not soluble in the (meth)acrylate component. Methods for preparing and methods for using these compositions also are disclosed.Type: GrantFiled: May 23, 2005Date of Patent: June 7, 2011Assignee: Henkel CorporationInventors: Bo Xia, James Murray, Charles Schuft
-
Publication number: 20110081541Abstract: A one part, storage stable polymerizable formulation is provided that includes an ethenically unsaturated polymerizable compound intermixed with a free radical polymerization initiator and an organic solvent. The organic solvent provides storage stability and upon evaporation of the solvent, the rate of polymerization of the compound accelerates independent of addition of a second part. The formulation includes at least 30 total weight percent solids upon cure. Optional additives to the formulation include at least one of a cure accelerator, a filler, a plasticizer, a colorant, and a cure inhibitor. A process for forming a polymerized coating on an article involves the application of this formulation to the substrate of an article and allowing sufficient time for the solvent to evaporate to form the polymerized coating on the article. The substrate of the article forms a corrosion barrier even without prior removal of a native corrosion layer on a surface of the substrate of the article.Type: ApplicationFiled: October 5, 2010Publication date: April 7, 2011Inventor: Ron Lewarchik
-
Publication number: 20110015342Abstract: To provide a fluorinated elastic copolymer having high crosslinkability, having high flowability and excellent in the compression set and the resistance to bases, and its production process. A process for producing a fluorinated elastic copolymer, which comprises copolymerizing (a) tetrafluoroethylene and (b) propylene and as the case requires, (c) a perfluoro(alkyl vinyl ether) in the presence of an iodine compound represented by the formula RI2 (wherein R is a hydrocarbon group or perfluoroalkyl group having at least 3 carbon atoms) at a temperature of from 0° C. to 50° C., and a fluorinated elastic copolymer obtained by the production process.Type: ApplicationFiled: September 28, 2010Publication date: January 20, 2011Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Takehiro KOSE, Mitsuru Seki, Hiroshi Funaki, Yasuhiko Matsuoka
-
Publication number: 20100246014Abstract: An antireflective film includes: a transparent substrate film; and at least one low refractive index layer, the low refractive index layer is formed with a composition containing: a fluorine-containing antifouling agent having a weight average molecular weight of less than 10,000 and a structure represented by the following formula (F); a polyfunctional monomer having a polymerizable unsaturated group; and (C) an inorganic particle, and a content of the fluorine-containing antifouling agent is 1% by weight or more and less than 25% by weight based on a total solid content of the coating composition: (Rf)-[(W)-(RA)n]m??Formula (F) wherein, Rf represents a (per)fluoroalkyl group or a (per)fluoropolyether group, W represents a connecting group, RA represents a functional group having a polymerizable unsaturated group, n represents an integer of from 1 to 3, and m represents an integer of from 1 to 3.Type: ApplicationFiled: March 31, 2010Publication date: September 30, 2010Applicant: FUJIFILM CorporationInventors: Miho ASAHI, Hiroyuki YONEYAMA, Daiki WAKIZAKA
-
Patent number: 7714038Abstract: Polyolefin waxes bearing (meth)acrylate groups, process for preparing them and their use.Type: GrantFiled: March 2, 2006Date of Patent: May 11, 2010Assignee: BASF AktiengesellschaftInventors: Dietmar Haering, Bernhard Hauer, Thomas Pfeiffer, Andreas Fechtenkoetter, Harald Larbig, Erich Beck
-
Patent number: 7700698Abstract: A process of producing a ring-opening metathesis polymer characterized in that a treatment to decrease the amount of oxygen and/or peroxide in at least one kind of polymerization starting material is performed prior to the ring-opening metathesis polymerization reaction of a cyclic olefin performed in the presence of a ruthenium carbene complex (catalyst). Treatments to decrease the amount of oxygen and/or peroxide include applying an adsorbent to a polymerization starting material to remove oxygen and/or peroxide by adsorption, applying an antioxidant to a polymerization starting material to decompose oxygen or peroxide, and the like.Type: GrantFiled: February 7, 2006Date of Patent: April 20, 2010Assignee: Kuraray Co., Ltd.Inventors: Hideharu Iwasaki, Yasutaka Inubushi
-
Publication number: 20100021754Abstract: Aqueous polymer dispersion obtainable by emulsion polymerization of monomers in the presence of inorganic polymer particles (inorganic particles for short) which are dispersible in the aqueous phase without surface-active assistants.Type: ApplicationFiled: December 11, 2007Publication date: January 28, 2010Applicant: BASF SEInventors: Peter Schlichting, Marc Schroeder, Hermann Seyffer
-
Publication number: 20090291222Abstract: A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)?CH2??(I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)?CH2??(II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.Type: ApplicationFiled: May 20, 2008Publication date: November 26, 2009Applicant: E. I. du Pont de Nemours and CompanyInventors: Weiming Qiu, Anilkumar Raghavanpillai, Peter Michael Murphy, Jessica Louise Flatter
-
Patent number: 7601765Abstract: The present invention relates to processes for preparing actinic-radiation-curable and/or dual-cure poly(meth)acrylates by preparing a poly(meth)acrylate containing hydroxy-functional side chains and transesterifying or esterifying the poly(meth)acrylate containing hydroxy-functional side chains with a (meth)acrylate or (meth)acrylic acid. The present invention further relates to the actinic-radiation-curable and/or dual-cure poly(meth)acrylates themselves and to the use of the actinic-radiation-curable and/or dual-cure poly(meth)acrylates in the preparation of dispersions or as a component in coating formulations and topcoats comprising at least one actinic-radiation-curable and/or dual-cure poly(meth)acrylate.Type: GrantFiled: November 5, 2003Date of Patent: October 13, 2009Assignee: BASF Coatings AGInventors: Heinz-Peter Rink, Susanne Neumann, Uwe Meisenburg, Karl-Heinz Joost, Dietmar Häring, Bernhard Hauer
-
Publication number: 20090192263Abstract: The present invention provides prepolymers based on poly(alkyl ethers) having terminal trifluorovinyl aromatic containing groups and polymers produced from such prepolymers. The prepolymers and polymers are useful as biomedical devices such as contact lenses or intraocular lenses.Type: ApplicationFiled: April 9, 2009Publication date: July 30, 2009Inventors: Derek Schorzman, Joseph C. Salamone
-
Publication number: 20080221266Abstract: The invention pertains to a process to polymerize one or more monomers wherein one or more initiators and optionally one or more surfactants are added to a polymerization mixture when the pressure in the polymerization reactor is dropping. This process allows a shorter polymerization time due to a higher pressure drop rate at the end of the polymerization reaction. Moreover, the cooling capacity of the polymerization reactor is used more efficiently.Type: ApplicationFiled: March 7, 2008Publication date: September 11, 2008Applicant: Akzo Nobel N.V.Inventors: Lambertus MEULENBRUGGE, Koen Antoon Kornelis VANDUFFEL, Hans WESTMIJZE
-
Patent number: 7317060Abstract: Suspensions of PBBMA, characterized in that they comprise PBBMA in the form of finely ground particles and contain suspending agents chosen from among xanthene gums, anionic or nonionic purified, sodium modified montmorilonite, naphthalene sulfonic acid-formaldehyde condensate sodium salt, sodium or calcium or ammonium salts of sulfonated lignin, acrylic acids/acrylic acids ester copolymer neutralized-sodium polycarboxyl, and wetting agents chosen from among alkyl ether, alkylaryl ether, fatty acid diester and sorbitan monoester types, polyoxyethylene (POE) compounds.Type: GrantFiled: August 11, 2004Date of Patent: January 8, 2008Assignee: Bromine Compounds Ltd.Inventors: Gad Friedman, Emanuel Buchbinder, Nurit Kornberg
-
Patent number: 7232867Abstract: There is provided a process for producing a vinyl chloride-based polymer, in which a suspension polymerization of either vinyl chloride monomer, or a mixture of vinyl chloride monomer and another copolymerizable monomer, is conducted in a polymerization vessel fitted with a reflux condenser, the process including the steps of: (A) adding to the reaction mixture a high-activity, oil-soluble polymerization initiator, with a 10-hour half life temperature of no more than 40° C. at a concentration of 0.1 mol/L in benzene, for a specified time within a period from the commencement of heat removal using the reflux condenser through to completion of the polymerization, and (B) adding an antioxidant either continuously or intermittently to the reaction mixture at least during the period from the commencement of addition of the high-activity, oil-soluble polymerization initiator through to completion of that addition.Type: GrantFiled: December 21, 2004Date of Patent: June 19, 2007Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Makoto Ooura, Tadashi Amano
-
Patent number: 6872332Abstract: Suspensions of PBBMA, characterized in that they comprise PBBMA in the form of finely ground particles and contain suspending agents chosen from among xanthane gums, anionic or nonionic purified, sodium modified montmorilonite, naphthalene sulfonic acid-formaldehyde condensate sodium salt, sodium or calcium or ammonium salts of sulfonated lignin, acrylic acids/acrylic acids ester copolymer neutralized—sodium polycarboxyl, and wetting agents chosen from among alkyl ether, alkylaryl ether, fatty acid diester and sorbitan monoester types, polyoxyethylene (POE) compounds.Type: GrantFiled: June 11, 2001Date of Patent: March 29, 2005Assignee: Bromine Compounds Ltd.Inventors: Gad Friedman, Emanuel Buchbinder, Nurit Kornberg
-
Publication number: 20040225060Abstract: It is to provide a production process by which gelation can be prevented, in a case where a solvent is removed from a curable fluororesin to obtain a chief material resin, and then coating additives such as a curing agent are mixed to produce a powder coating composition, or in a case where a curable fluororesin, a curing agent and various additives are dissolved or dispersed in a solvent to prepare a raw material solution, and the solvent is removed from the raw material solution to directly produce a powder coating material.Type: ApplicationFiled: June 9, 2004Publication date: November 11, 2004Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Masaru Yamauchi, Toru Ishida
-
Patent number: 6716914Abstract: An expanded cellular ethylenic polymer product is provided from an irradiated, noncross-linked linear ethylenic polymer. Linear ethylenic polymers can be irradiated at ambient conditions sufficient to introduce branching in the polymer in the absence of detectable cross-linking as indicated by the absence of gels. The irradiated linear ethylenic polymer is compatible with highly branched low density polyethylene and, when mixed therewith, produces a resin having a single broad based melting temperature range as determined by direct scanning calorimetry, which indicates that the polymers in the mixture have similar crystallization behavior suitable for producing low density foams by extrusion foaming. The linear polymers can be obtained from recycled shrink wrap film. Low densities of from 0.7 to less than 4 pcf can be achieved. The foams typically have improved tear resistance as compared to previous products prepared from low density polyethylene, at comparable low densities.Type: GrantFiled: June 4, 2003Date of Patent: April 6, 2004Assignee: Sealed Air Corporation (U.S.)Inventors: Nelson E. Malwitz, Natarajan S. Ramesh, Shau-Tarng Lee
-
Patent number: 6528582Abstract: A one-step, in-situ, process for producing a high solids content emulsion or dispersion of partially or totally crosslinked urea formaldehyde (UF), melamine formaldehyde (MF), or melamine urea formaldehyde (MUF) resin droplets or particles, by forming a reaction mixture of (i) aqueous formaldehyde (formalin), (ii) at least one water-soluble protective colloid, (iii) water and (iv) optionally a surfactant, and mixing the reaction mixture in a reaction vessel; optionally adjusting the initial pH of the reaction mixture according to a desired value as needed; adding (i) urea or substituted urea, (ii) melamine or substituted melamine, or (iii) a mixture thereof, to the reaction mixture; and heating the reaction mixture to a temperature at which condensation takes place between the (i) urea or substituted urea, (ii) the melamine or substituted melamine, or (iii) the mixture thereof, and the formaldehyde to form a urea formaldehyde, melamine formaldehyde or melamine urea formaldehyde resin, and holding the reactionType: GrantFiled: March 30, 2001Date of Patent: March 4, 2003Assignee: Neste Resins CanadaInventors: Kwok Tang, Guomin Bian, Leena Matilainen, Sinikka Ingelin
-
Patent number: 5952468Abstract: A new family of tumor rejection antigen precursors, and the nucleic acid molecules which code for them, are disclosed. These tumor rejection antigen precursors are referred to as TAGE tumor rejection antigen precursors, and the nucleic acid molecules which code for them are referred to as TAGE coding molecules. Various diagnostic and therapeutic uses of the coding sequences and the tumor rejection antigens, and their precursor molecules are described.Type: GrantFiled: September 25, 1998Date of Patent: September 14, 1999Assignee: Ludwig Institute for Cancer ResearchInventors: Pierre van der Bruggen, Thierry Boon-Falleur
-
Patent number: 5298562Abstract: Free radical-curable halogenated polyethylene polymer compositions, which are crosslinked with the aid of a crosslinking monomer selected from the group consisting of calcium diacrylate and calcium dimethacylate coagents and, optionally an alkyl aminoalkyl phenol vulcanization inhibitor, are provided. The compositions of the invention yield cured rubber articles with markedly improved tensile strength and scorch resistance. Processes for producing a cured rubber article from the disclosed free radical-curable elastomeric compositions and cured compositions prepared from such curable compositions are also provided.Type: GrantFiled: August 19, 1991Date of Patent: March 29, 1994Assignee: Sartomer Company, Inc.Inventors: Gary W. Ceska, C. Richard Costin, Thomas W. Hazell, Walter R. Nagel, Albert S. Tuccio
-
Patent number: 5296575Abstract: Improved monodisperse spheroidal particle latices of vinyl chloride polymers, e.g., having particle sizes ranging from 0.17 to 0.8 .mu.m or from 0.5 to 1.2 .mu.m, are produced by aqueous emulsion polymerization of vinyl chloride monomer, whether in a single stage or in two stages, in the absence of surface-active agent, in the presence of at least 0.2% by weight of at least one water-soluble alkali metal or ammonium persulfate initiator, and also in the presence of at least one water-soluble auxiliary compound that is a solvent for vinyl chloride, in such amount that the solubility of vinyl chloride in the aqueous phase at 25.degree. C. at atmospheric pressure is at least 1.5 g/l.Type: GrantFiled: September 26, 1991Date of Patent: March 22, 1994Assignee: AtochemInventors: Jacques Grossoleil, Patrick Kappler, Nicolas Krantz
-
Patent number: 5278223Abstract: The invention relates to optionally solventless two-component polyurethane surfacers containing finely divided fillers in a high pigment volume concentration based on a polyfunctional isocyanate component (B) and a polyol component (A) which is liquid at room temperature and which consists of mixture components containing isocyanate-reactive hydroxyl groups with an at least predominant content of branched-chain polyols (A1) containing ester and ether groups, which contains at least a proportion of the finely divided fillers and, optionally, the additives and which, for application, is mixed with the isocyanate component (B) and applied as a mixture which can still be processed by shaping.Type: GrantFiled: March 27, 1992Date of Patent: January 11, 1994Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernhard Gruenewaelder, Bernhard Parent, Hermann Kluth, Juergen Wegner, Werner Haller
-
Patent number: 5272204Abstract: Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer in situ in a polyol in the presence of inner-olefin containing at least 5 carbon atoms, are of lower viscosity and can provide polyurethanes having improved properties. Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer, in situ in a polyol in the presence of an azo compound and a peroxide having a 10 hours half-life period temperature which is lower by at least 10.degree. C. than that of the azo compound, have improved stability even at higher styrene content.Type: GrantFiled: May 31, 1991Date of Patent: December 21, 1993Assignee: Sanyo Chemical Industries, Ltd.Inventors: Keiichi Akimoto, Takeshi Sumita, Masahiro Matsuoka
-
Patent number: 5204427Abstract: A reaction solution comprising a mixture of tricyclopentadiene, a norbornene monomer with at least 3 rings in its backbone, a 5-alkenyl-2-norbornene pot life adjusting agent along with a molybdenum type catalyst system gives prolonged pot life without extending time to exotherm (e.g., smoking time). By utilizing this reaction solution it is possible to bulk polymerize reinforced or unreinforced articles in a mold via ring-opening polymerization. Articles so obtained have good outward appearance and excellent physical properties.Type: GrantFiled: May 24, 1991Date of Patent: April 20, 1993Assignee: Nippon Zeon Co., Ltd.Inventors: Masao Torii, Tomoo Sugawara, Kin-ichi Okumura, Motoyuki Yamato
-
Patent number: 5061749Abstract: One-pack type heat pre-curable moisture-curing sealant composition which comprises as the main component(A) a urethane prepolymer having a content of an active free isocyanate group (NCO) of 0.5 to 13% by weight which is prepared by reacting a polyol and an excess amount of an aromatic polyisocyanate compound, and(B) a vinyl polymer containing a siloxy group, and as an additive(C) a filler in an amount of 20 to 50% by weight based on the whole weight of the sealant, and(D) a plasticizer in an amount of 5 to 30% by weight based on the whole weight of the sealant, which can be precured at a comparatively lower temperature within a short period of time and cured with moisture in air and is useful for adhering various parts in automobile and construction industries without a temporary holding means.Type: GrantFiled: July 26, 1990Date of Patent: October 29, 1991Assignee: Sunstar Giken Kabushiki KaishaInventors: Masahiro Ito, Yukio Hayashi
-
Patent number: 4950710Abstract: A composite comprising the reaction product of a filler having a reactive hydroxylated surface, a monomer or polymer containing carboxyl groups, and an organoaluminum compound, the organoaluminum compound being reacted with said hydroxylated surface and with said monomer or polymer. A preferred composite is made by reacting aluminum sec-butoxide with fiberglass and acrylic acid and methyl methacrylate under polymerization conditions.Type: GrantFiled: February 8, 1988Date of Patent: August 21, 1990Assignee: Aluminum Company of AmericaInventor: Max E. Roha
-
Patent number: 4933388Abstract: Solutions of copolymers of the tetrafluoroethylene/ethylene typeCopolymer solutions comprising tetrafluoroethylene, ethylene and, as appropriate, further .alpha.-olefinic monomers in low-molecular-weight polymers of chlorotrifluoroethylene are described. They can be used for coatings, impregnations, cast films and for the production of fibers and filaments by gel spinning.Type: GrantFiled: December 27, 1988Date of Patent: June 12, 1990Assignee: Hoechst AktiengesellschaftInventors: Peter Blickle, Friedhelm Gundert, Klaus Hintzer, Gernot Lohr, Werner Schwertfeger
-
Patent number: 4748224Abstract: Highly oxygen permeable hard and semi-hard contact lenses are made from the copolymer of ethylenically unsaturated siloxane ester, ethylenically unsaturated fluorocarbon ester and ethylenically unsaturated sulfone monomer and methods for the polymerization thereof.Type: GrantFiled: June 6, 1986Date of Patent: May 31, 1988Assignee: Maureen J. DeVouInventor: Nick N. Novicky
-
Patent number: 4741865Abstract: Polymer systems can be rendered flame retardant by adding a source of halogen and particles of antimony pentoxide that have been dried from colloidal dispersions that have been treated with certain metal ions. The properties of the polymer are conserved when the colloidal dispersion is treated with ions of metals that have insoluble antimonates before drying to form a powder.Type: GrantFiled: May 7, 1986Date of Patent: May 3, 1988Assignee: Nyacol Products, Inc.Inventors: Donald P. Kintz, Stephen N. Davis
-
Patent number: 4716195Abstract: A process for the preparation of a vinyl chloride polymer latex having particles with a mean diameter between about 0.2 and 0.8 .mu.m and containing at least one organosoluble polymerization initiator comprising dispersing in an aqueous reaction medium also containing parabenzoquinone, at least one monomer, at least one anionic emulsifier and optionally at least one nonionic emulsifier, and from about 0.004 to 0.16% by weight, with respect to said at least one monomer, of said initiator expressed in terms of active oxygen, polymerizing said at least one monomer at a desired polymerization temperature, .theta..sub.1, and continuously adding parabenzoquinone to said aqueous reaction medium during the polymerization when the temperature .theta..sub.2 of the reaction medium is such that the difference .theta..sub.2 -.theta..sub.1 exceeds a value from 0.degree. to +5.degree. C.Type: GrantFiled: September 2, 1986Date of Patent: December 29, 1987Assignee: Societe d'Extrusion et de TransformationInventor: Daniel Brulet
-
Patent number: 4666976Abstract: When a solution of liquid allylic-functional material and bromoxylenol blue is polymerized using a thermally decomposable polymerization initiator, the color imparted by the bromoxylenol blue is brilliant yellow.Type: GrantFiled: April 16, 1986Date of Patent: May 19, 1987Assignee: PPG Industries, Inc.Inventor: Michael S. Misura
-
Patent number: 4645788Abstract: The cold resistance of chloroprene rubber can be improved by blending an ester derived from a specified glycol component and a specified fatty acid component without any adverse effect upon the other physical and chemical properties of the rubber. This ester is not extracted with oily matters such as oil or grease, so that the resulting chloroprene rubber composition hardly exhibits a decrease in cold resistance even after extraction with oily matters.Type: GrantFiled: December 6, 1985Date of Patent: February 24, 1987Assignees: Kao Corporation, Toyoda Gosei Co. Ltd.Inventors: Tadaoki Okumoto, Rikizo Nakata, Masayoshi Ichikawa, Masaaki Tsuchihashi, Koichi Sakai
-
Patent number: 4460715Abstract: A stable copolymer dispersion is prepared by addition copolymerization of (1) a monomeric adduct of an active hydrogen compound, e.g., a polyether polyol, and an acrylyl compound such as methacryloyl chloride with (2) ethylenically unsaturated monomer(s), e.g., styrene or a mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound such as a polyether polyol. The molar ratio of acrylyl moiety to active hydrogen compound is less than 0.1:1. The resulting dispersion has a controlled particle size and a viscosity such that it is suitably employed in the production of polyurethane foams.Type: GrantFiled: November 10, 1981Date of Patent: July 17, 1984Assignee: The Dow Chemical CompanyInventors: Dwight K. Hoffman, Robert F. Harris, Nancy B. Tefertiller, Randall C. Rains