Halogen-containing Monomer Patents (Class 524/851)
  • Patent number: 10472535
    Abstract: A method for producing a fluorinated copolymer solution polymerizing a monomer mixture of a fluoro-olefin (A), a monomer (B) having a crosslinkable group and a monomer (C) having no fluorine atom and no crosslinkable group in the presence of an organic solvent and a compound having two or more piperidyl group represented by the formula (1):
    Type: Grant
    Filed: March 31, 2015
    Date of Patent: November 12, 2019
    Assignee: AGC Inc.
    Inventors: Shiro Ebata, Toshinori Tomita, Masakazu Ataku, Shun Saito, Sho Masuda
  • Publication number: 20150125695
    Abstract: A composition having at least one first component containing a perfluorinated aliphatic structure in which no more than six fluorine bearing carbons are connected in any single straight chain segment, in addition a group providing binding functionality to a surface to be treated or containing at least one polymerisable double bond or containing at least one cross-linkable group, and in addition a divalent radical containing at least one group capable of forming polar interactions or hydrogen bonds, and at least one second component containing a perfluorinated aliphatic structure in which no more than six fluorine bearing carbons are connected in any single straight chain segment and a moiety containing at least one group providing binding functionality to a surface to be treated or containing at least one polymerisable double bond or containing at least one cross-linkable group.
    Type: Application
    Filed: November 3, 2014
    Publication date: May 7, 2015
    Inventors: ERIC HUEBSCH, Noel Stephen Brabbs
  • Patent number: 8927649
    Abstract: A one part, storage stable polymerizable formulation is provided that includes an ethenically unsaturated polymerizable compound intermixed with a free radical polymerization initiator and an organic solvent. The organic solvent provides storage stability and upon evaporation of the solvent, the rate of polymerization of the compound accelerates independent of addition of a second part. The formulation includes at least 30 total weight percent solids upon cure. Optional additives to the formulation include at least one of a cure accelerator, a filler, a plasticizer, a colorant, and a cure inhibitor. A process for forming a polymerized coating on an article involves the application of this formulation to the substrate of an article and allowing sufficient time for the solvent to evaporate to form the polymerized coating on the article. The substrate of the article forms a corrosion barrier even without prior removal of a native corrosion layer on a surface of the substrate of the article.
    Type: Grant
    Filed: October 5, 2010
    Date of Patent: January 6, 2015
    Inventor: Ron Lewarchik
  • Publication number: 20140343219
    Abstract: There is provided a method of fabricating a composite material, the method comprising providing borehole solids originating from a borehole in the earth and embedding the borehole solids in a base material thereby forming the composite material, wherein the base material comprises a polymer. According to an embodiment, the borehole solids contain oil, e.g. on a surface thereof. The oil containing borehole solids may be preprocessed before embedding or may be directly embedded in the base material without preprocessing. Such embodiments allow for a recycling of oil contaminated borehole solids while providing a resource for a filler for polymers.
    Type: Application
    Filed: September 14, 2012
    Publication date: November 20, 2014
    Applicant: MONTANUNIVERSITÄT LEOBEN
    Inventors: Herbert Hofstätter, Clemens Holzer
  • Publication number: 20140154486
    Abstract: The present invention relates to an anti-reflective coating composition providing improved scratch resistance, a method for manufacturing an anti-reflective film using the same, and an anti-reflective film manufactured thereby. According to the present invention, provided are a composition that is able to form a coating layer having improved surface scratch resistance, while forming one or more layers by a single coating process, and an anti-reflective film manufactured by using the same.
    Type: Application
    Filed: September 28, 2012
    Publication date: June 5, 2014
    Applicant: LG Chem, Ltd.
    Inventors: Heon Kim, Joon-Koo Kang, Yeong-Rae Chang, Hye-Min Kim
  • Publication number: 20140147745
    Abstract: To provide a binder for a storage battery device, whereby good adhesion is obtainable, and it is possible to realize good charge and discharge characteristics in a secondary battery by well suppressing swelling of an electrode by an electrolytic solution. A binder for a storage battery device, which is made of a fluorinated copolymer comprising repeating units (a) derived from tetrafluoroethylene and repeating units (b) derived from propylene, wherein the molar ratio (a)/(b) is from 60/40 to 75/25, and the total of the repeating units (a) and (b) is at least 90 mol % in all repeating units.
    Type: Application
    Filed: January 29, 2014
    Publication date: May 29, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Mizuna TOYODA, Takehiro KOSE, Hiroki NAGAI
  • Patent number: 8697801
    Abstract: A plastic pallet having a fire retardant. The fire retardant is prepared in an FR masterbatch before mixing with HDPE to form the pallet. In one embodiment, the FR masterbatch includes a brominated fire retardant, a hydrated mineral, antimony trioxide and a carrier resin. In some embodiments, the brominated fire retardant is a non-blooming brominated fire retardant such as poly pentabromobenzyl acrylate or ethylenebistetrabromophthalamide. The hydrated mineral advantageously enhances both the vapor phase and condensed phase fire retardant properties of the final product and may be magnesium hydroxide. In other embodiments, melamine pyrophosphate or a blend of melamine pyrophosphate and polyhydric compound may be substituted for the hydrated mineral or used as the sole fire retardant. The polyhydric compound may be bis-pentaerythritol phosphate alcohol. A method of manufacturing a plastic pallet is also disclosed.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: April 15, 2014
    Assignee: Primex Plastics Corporation
    Inventor: Paul D. Zwick
  • Publication number: 20140051805
    Abstract: To provide a water/oil repellent composition with which an article which has favorable water/oil repellency and washing durability, and into which infiltration of a coating liquid can be suppressed, is obtained, and which presents a low environmental impact, its production method and an article having its surface treated with the composition. A water/oil repellent composition comprising a copolymer (X) having structural units based on the monomer (a) and structural units based on the monomer (b), and an aqueous medium, wherein the mass average molecular weight of the copolymer is at least 60,000, and the proportion of the structural units based on the monomer (a) is 60 to 95 mass %. Monomer (a): by (Z—Y)nX, wherein Z is a e.g. C1-6 polyfluoroalkyl group, Y is e.g. a bivalent organic group having no fluorine atom, n is 1 or 2, and X is a polymerizable unsaturated group. Monomer (b): vinyl chloride.
    Type: Application
    Filed: October 21, 2013
    Publication date: February 20, 2014
    Applicant: Asahi Glass Company, Limited
    Inventors: Minako SHIMADA, Eiji Morimoto, Yuuichi OOmori
  • Publication number: 20140018499
    Abstract: A process is provided for polymerizing fluoromonomer in an aqueous medium, wherein a dispersion of essentially surfactant-free hydrocarbon-containing oleophilic nucleation sites is first formed in the aqueous medium, and then polymerization is commenced to form a dispersion of fluoropolymer particles at the oleophilic nucleation sites, wherein the nucleation sites can be derived from hydrocarbon-containing compound. The surfactant used to stabilize the fluoropolymer dispersion can also be hydrocarbon-containing.
    Type: Application
    Filed: September 19, 2013
    Publication date: January 16, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: PAUL DOUGLAS BROTHERS, SUBHASH VISHNU GANGAL, DIPTI DILIP KHASNIS
  • Patent number: 8535699
    Abstract: In order to provide a controlled-release insect-controlling resin molded product and a insect-controlling resin composition for making such a controlled-release insect-controlling resin molded product that have immediate effectiveness, residual effectiveness, and preservation stability and that are excellent in merchantability and manufacturing control, the present invention uses an insect-controlling resin composition including a polyvinyl chloride resin containing a non-vaporizable insect-controlling component and erucic acid.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: September 17, 2013
    Assignee: Sumika Life Tech, Limited
    Inventors: Shinobu Kawaguchi, Masayuki Tatsumi, Kiyoshi Mitsui, Masato Mizutani, Kouzi Noda
  • Patent number: 8536270
    Abstract: To provide a resist composition including: at least one polymerizable compound having a viscosity of 100 mPa·s or less at 25° C.; a fluorine-containing compound A having a viscosity of 5,000 mPa·s or greater at 25° C., and a fluorine content of 10% by mass or greater; and a fluorine-containing compound B having a viscosity of 2,000 mPa·s or less at 25° C., and a fluorine content of 10% by mass or greater.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: September 17, 2013
    Assignee: FujiFilm
    Inventor: Tadashi Omatsu
  • Patent number: 8461251
    Abstract: A method for producing a fluoroolefin copolymer solution, gives the copolymer solution good storage stability and suppressed coloration. The method for producing a fluoroolefin copolymer solution includes subjecting at least one fluoroolefin and at least one monomer other than the fluoroolefin to a solution polymerization in an organic solvent in the presence of potassium carbonate and hydrotalcite.
    Type: Grant
    Filed: July 20, 2011
    Date of Patent: June 11, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Yuji Hara, Kiyoshi Kasahara, Shou Masuda
  • Patent number: 8227521
    Abstract: Fluoropolymer foams are prepared by mixing fluoropolymer resin with blowing agents and additives to produce foamable compounds at temperatures below the activation temperature of the blowing agent. The compounded material is expanded at temperatures above both the softening point of the fluoropolymer resin and the activation temperature of the blowing agent. The resulting fluoropolymer foam can be fabricated into any desired shape, such as pipes, sheets, tapes, blocks and rods, using techniques such as cutting, welding, thermoforming and adhesive bonding. Alternatively the fluoropolymer compound may be expanded directly into the desired shape, for example, by expanding the compound in a mold.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: July 24, 2012
    Assignee: Zotefoams PLC
    Inventors: Paul Jacobs, Roger Lock, Neil Witten
  • Patent number: 8183314
    Abstract: Provided are oil-in-water and water-in-oil emulsion compositions including from 0.01 to 5 wt % of a halogenated elastomer emulsifier, and optionally from to 0.5 wt % of a polyalkylene amine co-emulsifier. The emulsion compositions disclosed herein provide for increased interfacial elasticity and decreased interfacial tension at the oil-water interface to increase resistance to coalescence of dispersed water droplets of a water-in-oil emulsion or oil droplets of an oil-in-water emulsion. The emulsion compositions disclosed herein are suitable for lubricant applications due to their resistance to shear thinning.
    Type: Grant
    Filed: June 26, 2009
    Date of Patent: May 22, 2012
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Ramesh Varadaraj, Cornelius Hendrick Brons, David John Lohse
  • Publication number: 20120067908
    Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Compositions that include perfluorohexyl(meth)acrylate and a branched or high Tg monomer are provided as are articles coated with the polymerization product of the composition. Methods are also provided for forming hydrophobic coatings on articles.
    Type: Application
    Filed: August 16, 2011
    Publication date: March 22, 2012
    Applicant: CYTONIX, LLC
    Inventor: James F. BROWN
  • Publication number: 20120037835
    Abstract: To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency and post-air-drying water repellency to the surface of an article and which presents a low environmental impact, a method for its production and a method for treating an article. A water/oil repellent composition which comprises a copolymer having structural units based on the following monomer (a) and structural units based on the following monomer (b) and having a mass average molecular weight of at least 40,000, and a medium, is used. Monomer (a): a compound represented by (Z—Y)nX, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or the like, n is 1 or 2, and X is a polymerizable unsaturated group. Monomer (b): an olefin, a homopolymer of which has a glass transition temperature of from ?50° C. to 50° C.
    Type: Application
    Filed: October 21, 2011
    Publication date: February 16, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Nobuyuki OTOZAWA, Kazunori SUGIYAMA, Minako SHIMADA, Yuuichi OOMORI
  • Publication number: 20120037400
    Abstract: A composition that includes at least one crosslinkable monomer; at least one hydrophobic monomer; and at least one dielectric constant enhancing agent selected from dielectric enhancing monomers, ferroelectric particulates, and electroactive polymers. Coatings including the polymer of compositions, and articles including electrically isolating layers are also disclosed.
    Type: Application
    Filed: October 25, 2011
    Publication date: February 16, 2012
    Inventors: Lenwood L. Fields, Arthur W. Martin, Shawn M. O'Malley, Dean M. Thelen
  • Publication number: 20110275753
    Abstract: To provide a method for producing a fluoroolefin copolymer solution, whereby good storage stability of the copolymer solution is obtainable, and coloration of the solution can be suppressed, and a method for producing a coating composition. A method for producing a fluoroolefin copolymer solution, which comprises subjecting at least one fluoroolefin (a) and at least one monomer (b) other than the fluoroolefin (a) to a solution polymerization in an organic solvent in the presence of potassium carbonate and hydrotalcite.
    Type: Application
    Filed: July 20, 2011
    Publication date: November 10, 2011
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Yuji HARA, Kiyoshi Kasahara, Shou Masuda
  • Patent number: 7956143
    Abstract: Compositions for bonding substrate surfaces, particularly steel, aluminum, and urethane-primed galvanized steel, are disclosed. Desirably, the compositions include a stable emulsion including: (a) at least one curable (meth)acrylate component; (b) at least three different elastomeric polymers that are soluble and/or partially soluble in the (meth)acrylate component; and (c) optionally at least one elastomeric polymer that is not soluble in the (meth)acrylate component. Methods for preparing and methods for using these compositions also are disclosed.
    Type: Grant
    Filed: May 23, 2005
    Date of Patent: June 7, 2011
    Assignee: Henkel Corporation
    Inventors: Bo Xia, James Murray, Charles Schuft
  • Publication number: 20110081541
    Abstract: A one part, storage stable polymerizable formulation is provided that includes an ethenically unsaturated polymerizable compound intermixed with a free radical polymerization initiator and an organic solvent. The organic solvent provides storage stability and upon evaporation of the solvent, the rate of polymerization of the compound accelerates independent of addition of a second part. The formulation includes at least 30 total weight percent solids upon cure. Optional additives to the formulation include at least one of a cure accelerator, a filler, a plasticizer, a colorant, and a cure inhibitor. A process for forming a polymerized coating on an article involves the application of this formulation to the substrate of an article and allowing sufficient time for the solvent to evaporate to form the polymerized coating on the article. The substrate of the article forms a corrosion barrier even without prior removal of a native corrosion layer on a surface of the substrate of the article.
    Type: Application
    Filed: October 5, 2010
    Publication date: April 7, 2011
    Inventor: Ron Lewarchik
  • Publication number: 20110015342
    Abstract: To provide a fluorinated elastic copolymer having high crosslinkability, having high flowability and excellent in the compression set and the resistance to bases, and its production process. A process for producing a fluorinated elastic copolymer, which comprises copolymerizing (a) tetrafluoroethylene and (b) propylene and as the case requires, (c) a perfluoro(alkyl vinyl ether) in the presence of an iodine compound represented by the formula RI2 (wherein R is a hydrocarbon group or perfluoroalkyl group having at least 3 carbon atoms) at a temperature of from 0° C. to 50° C., and a fluorinated elastic copolymer obtained by the production process.
    Type: Application
    Filed: September 28, 2010
    Publication date: January 20, 2011
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Takehiro KOSE, Mitsuru Seki, Hiroshi Funaki, Yasuhiko Matsuoka
  • Publication number: 20100246014
    Abstract: An antireflective film includes: a transparent substrate film; and at least one low refractive index layer, the low refractive index layer is formed with a composition containing: a fluorine-containing antifouling agent having a weight average molecular weight of less than 10,000 and a structure represented by the following formula (F); a polyfunctional monomer having a polymerizable unsaturated group; and (C) an inorganic particle, and a content of the fluorine-containing antifouling agent is 1% by weight or more and less than 25% by weight based on a total solid content of the coating composition: (Rf)-[(W)-(RA)n]m??Formula (F) wherein, Rf represents a (per)fluoroalkyl group or a (per)fluoropolyether group, W represents a connecting group, RA represents a functional group having a polymerizable unsaturated group, n represents an integer of from 1 to 3, and m represents an integer of from 1 to 3.
    Type: Application
    Filed: March 31, 2010
    Publication date: September 30, 2010
    Applicant: FUJIFILM Corporation
    Inventors: Miho ASAHI, Hiroyuki YONEYAMA, Daiki WAKIZAKA
  • Patent number: 7714038
    Abstract: Polyolefin waxes bearing (meth)acrylate groups, process for preparing them and their use.
    Type: Grant
    Filed: March 2, 2006
    Date of Patent: May 11, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietmar Haering, Bernhard Hauer, Thomas Pfeiffer, Andreas Fechtenkoetter, Harald Larbig, Erich Beck
  • Patent number: 7700698
    Abstract: A process of producing a ring-opening metathesis polymer characterized in that a treatment to decrease the amount of oxygen and/or peroxide in at least one kind of polymerization starting material is performed prior to the ring-opening metathesis polymerization reaction of a cyclic olefin performed in the presence of a ruthenium carbene complex (catalyst). Treatments to decrease the amount of oxygen and/or peroxide include applying an adsorbent to a polymerization starting material to remove oxygen and/or peroxide by adsorption, applying an antioxidant to a polymerization starting material to decompose oxygen or peroxide, and the like.
    Type: Grant
    Filed: February 7, 2006
    Date of Patent: April 20, 2010
    Assignee: Kuraray Co., Ltd.
    Inventors: Hideharu Iwasaki, Yasutaka Inubushi
  • Publication number: 20100021754
    Abstract: Aqueous polymer dispersion obtainable by emulsion polymerization of monomers in the presence of inorganic polymer particles (inorganic particles for short) which are dispersible in the aqueous phase without surface-active assistants.
    Type: Application
    Filed: December 11, 2007
    Publication date: January 28, 2010
    Applicant: BASF SE
    Inventors: Peter Schlichting, Marc Schroeder, Hermann Seyffer
  • Publication number: 20090291222
    Abstract: A copolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]m-L-C(O)—C(R)?CH2??(I) wherein R is H, Cl, F or CH3, L is O, S, NH, S—(CH2)rO, S—(CH2)rNH, OC(O)NH—CH2CH2O, NHC(O)NHCH2CH2O, S—(CH2)rOC(O)NHCH2CH2O, or S(CH2)rNHC(O)NHCH2CH2O, and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (II) a monomer of formula (II) (R2)2N—R3—O—C(O)—C(R)?CH2??(II) wherein R is H, Cl, F or CH3, each R2 is independently a C1 to C4 alkyl; and R3 is a divalent linear or branched C1 to C4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof.
    Type: Application
    Filed: May 20, 2008
    Publication date: November 26, 2009
    Applicant: E. I. du Pont de Nemours and Company
    Inventors: Weiming Qiu, Anilkumar Raghavanpillai, Peter Michael Murphy, Jessica Louise Flatter
  • Patent number: 7601765
    Abstract: The present invention relates to processes for preparing actinic-radiation-curable and/or dual-cure poly(meth)acrylates by preparing a poly(meth)acrylate containing hydroxy-functional side chains and transesterifying or esterifying the poly(meth)acrylate containing hydroxy-functional side chains with a (meth)acrylate or (meth)acrylic acid. The present invention further relates to the actinic-radiation-curable and/or dual-cure poly(meth)acrylates themselves and to the use of the actinic-radiation-curable and/or dual-cure poly(meth)acrylates in the preparation of dispersions or as a component in coating formulations and topcoats comprising at least one actinic-radiation-curable and/or dual-cure poly(meth)acrylate.
    Type: Grant
    Filed: November 5, 2003
    Date of Patent: October 13, 2009
    Assignee: BASF Coatings AG
    Inventors: Heinz-Peter Rink, Susanne Neumann, Uwe Meisenburg, Karl-Heinz Joost, Dietmar Häring, Bernhard Hauer
  • Publication number: 20090192263
    Abstract: The present invention provides prepolymers based on poly(alkyl ethers) having terminal trifluorovinyl aromatic containing groups and polymers produced from such prepolymers. The prepolymers and polymers are useful as biomedical devices such as contact lenses or intraocular lenses.
    Type: Application
    Filed: April 9, 2009
    Publication date: July 30, 2009
    Inventors: Derek Schorzman, Joseph C. Salamone
  • Publication number: 20080221266
    Abstract: The invention pertains to a process to polymerize one or more monomers wherein one or more initiators and optionally one or more surfactants are added to a polymerization mixture when the pressure in the polymerization reactor is dropping. This process allows a shorter polymerization time due to a higher pressure drop rate at the end of the polymerization reaction. Moreover, the cooling capacity of the polymerization reactor is used more efficiently.
    Type: Application
    Filed: March 7, 2008
    Publication date: September 11, 2008
    Applicant: Akzo Nobel N.V.
    Inventors: Lambertus MEULENBRUGGE, Koen Antoon Kornelis VANDUFFEL, Hans WESTMIJZE
  • Patent number: 7317060
    Abstract: Suspensions of PBBMA, characterized in that they comprise PBBMA in the form of finely ground particles and contain suspending agents chosen from among xanthene gums, anionic or nonionic purified, sodium modified montmorilonite, naphthalene sulfonic acid-formaldehyde condensate sodium salt, sodium or calcium or ammonium salts of sulfonated lignin, acrylic acids/acrylic acids ester copolymer neutralized-sodium polycarboxyl, and wetting agents chosen from among alkyl ether, alkylaryl ether, fatty acid diester and sorbitan monoester types, polyoxyethylene (POE) compounds.
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: January 8, 2008
    Assignee: Bromine Compounds Ltd.
    Inventors: Gad Friedman, Emanuel Buchbinder, Nurit Kornberg
  • Patent number: 7232867
    Abstract: There is provided a process for producing a vinyl chloride-based polymer, in which a suspension polymerization of either vinyl chloride monomer, or a mixture of vinyl chloride monomer and another copolymerizable monomer, is conducted in a polymerization vessel fitted with a reflux condenser, the process including the steps of: (A) adding to the reaction mixture a high-activity, oil-soluble polymerization initiator, with a 10-hour half life temperature of no more than 40° C. at a concentration of 0.1 mol/L in benzene, for a specified time within a period from the commencement of heat removal using the reflux condenser through to completion of the polymerization, and (B) adding an antioxidant either continuously or intermittently to the reaction mixture at least during the period from the commencement of addition of the high-activity, oil-soluble polymerization initiator through to completion of that addition.
    Type: Grant
    Filed: December 21, 2004
    Date of Patent: June 19, 2007
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Makoto Ooura, Tadashi Amano
  • Patent number: 6872332
    Abstract: Suspensions of PBBMA, characterized in that they comprise PBBMA in the form of finely ground particles and contain suspending agents chosen from among xanthane gums, anionic or nonionic purified, sodium modified montmorilonite, naphthalene sulfonic acid-formaldehyde condensate sodium salt, sodium or calcium or ammonium salts of sulfonated lignin, acrylic acids/acrylic acids ester copolymer neutralized—sodium polycarboxyl, and wetting agents chosen from among alkyl ether, alkylaryl ether, fatty acid diester and sorbitan monoester types, polyoxyethylene (POE) compounds.
    Type: Grant
    Filed: June 11, 2001
    Date of Patent: March 29, 2005
    Assignee: Bromine Compounds Ltd.
    Inventors: Gad Friedman, Emanuel Buchbinder, Nurit Kornberg
  • Publication number: 20040225060
    Abstract: It is to provide a production process by which gelation can be prevented, in a case where a solvent is removed from a curable fluororesin to obtain a chief material resin, and then coating additives such as a curing agent are mixed to produce a powder coating composition, or in a case where a curable fluororesin, a curing agent and various additives are dissolved or dispersed in a solvent to prepare a raw material solution, and the solvent is removed from the raw material solution to directly produce a powder coating material.
    Type: Application
    Filed: June 9, 2004
    Publication date: November 11, 2004
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Masaru Yamauchi, Toru Ishida
  • Patent number: 6716914
    Abstract: An expanded cellular ethylenic polymer product is provided from an irradiated, noncross-linked linear ethylenic polymer. Linear ethylenic polymers can be irradiated at ambient conditions sufficient to introduce branching in the polymer in the absence of detectable cross-linking as indicated by the absence of gels. The irradiated linear ethylenic polymer is compatible with highly branched low density polyethylene and, when mixed therewith, produces a resin having a single broad based melting temperature range as determined by direct scanning calorimetry, which indicates that the polymers in the mixture have similar crystallization behavior suitable for producing low density foams by extrusion foaming. The linear polymers can be obtained from recycled shrink wrap film. Low densities of from 0.7 to less than 4 pcf can be achieved. The foams typically have improved tear resistance as compared to previous products prepared from low density polyethylene, at comparable low densities.
    Type: Grant
    Filed: June 4, 2003
    Date of Patent: April 6, 2004
    Assignee: Sealed Air Corporation (U.S.)
    Inventors: Nelson E. Malwitz, Natarajan S. Ramesh, Shau-Tarng Lee
  • Patent number: 6528582
    Abstract: A one-step, in-situ, process for producing a high solids content emulsion or dispersion of partially or totally crosslinked urea formaldehyde (UF), melamine formaldehyde (MF), or melamine urea formaldehyde (MUF) resin droplets or particles, by forming a reaction mixture of (i) aqueous formaldehyde (formalin), (ii) at least one water-soluble protective colloid, (iii) water and (iv) optionally a surfactant, and mixing the reaction mixture in a reaction vessel; optionally adjusting the initial pH of the reaction mixture according to a desired value as needed; adding (i) urea or substituted urea, (ii) melamine or substituted melamine, or (iii) a mixture thereof, to the reaction mixture; and heating the reaction mixture to a temperature at which condensation takes place between the (i) urea or substituted urea, (ii) the melamine or substituted melamine, or (iii) the mixture thereof, and the formaldehyde to form a urea formaldehyde, melamine formaldehyde or melamine urea formaldehyde resin, and holding the reaction
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: March 4, 2003
    Assignee: Neste Resins Canada
    Inventors: Kwok Tang, Guomin Bian, Leena Matilainen, Sinikka Ingelin
  • Patent number: 5952468
    Abstract: A new family of tumor rejection antigen precursors, and the nucleic acid molecules which code for them, are disclosed. These tumor rejection antigen precursors are referred to as TAGE tumor rejection antigen precursors, and the nucleic acid molecules which code for them are referred to as TAGE coding molecules. Various diagnostic and therapeutic uses of the coding sequences and the tumor rejection antigens, and their precursor molecules are described.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: September 14, 1999
    Assignee: Ludwig Institute for Cancer Research
    Inventors: Pierre van der Bruggen, Thierry Boon-Falleur
  • Patent number: 5298562
    Abstract: Free radical-curable halogenated polyethylene polymer compositions, which are crosslinked with the aid of a crosslinking monomer selected from the group consisting of calcium diacrylate and calcium dimethacylate coagents and, optionally an alkyl aminoalkyl phenol vulcanization inhibitor, are provided. The compositions of the invention yield cured rubber articles with markedly improved tensile strength and scorch resistance. Processes for producing a cured rubber article from the disclosed free radical-curable elastomeric compositions and cured compositions prepared from such curable compositions are also provided.
    Type: Grant
    Filed: August 19, 1991
    Date of Patent: March 29, 1994
    Assignee: Sartomer Company, Inc.
    Inventors: Gary W. Ceska, C. Richard Costin, Thomas W. Hazell, Walter R. Nagel, Albert S. Tuccio
  • Patent number: 5296575
    Abstract: Improved monodisperse spheroidal particle latices of vinyl chloride polymers, e.g., having particle sizes ranging from 0.17 to 0.8 .mu.m or from 0.5 to 1.2 .mu.m, are produced by aqueous emulsion polymerization of vinyl chloride monomer, whether in a single stage or in two stages, in the absence of surface-active agent, in the presence of at least 0.2% by weight of at least one water-soluble alkali metal or ammonium persulfate initiator, and also in the presence of at least one water-soluble auxiliary compound that is a solvent for vinyl chloride, in such amount that the solubility of vinyl chloride in the aqueous phase at 25.degree. C. at atmospheric pressure is at least 1.5 g/l.
    Type: Grant
    Filed: September 26, 1991
    Date of Patent: March 22, 1994
    Assignee: Atochem
    Inventors: Jacques Grossoleil, Patrick Kappler, Nicolas Krantz
  • Patent number: 5278223
    Abstract: The invention relates to optionally solventless two-component polyurethane surfacers containing finely divided fillers in a high pigment volume concentration based on a polyfunctional isocyanate component (B) and a polyol component (A) which is liquid at room temperature and which consists of mixture components containing isocyanate-reactive hydroxyl groups with an at least predominant content of branched-chain polyols (A1) containing ester and ether groups, which contains at least a proportion of the finely divided fillers and, optionally, the additives and which, for application, is mixed with the isocyanate component (B) and applied as a mixture which can still be processed by shaping.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: January 11, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernhard Gruenewaelder, Bernhard Parent, Hermann Kluth, Juergen Wegner, Werner Haller
  • Patent number: 5272204
    Abstract: Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer in situ in a polyol in the presence of inner-olefin containing at least 5 carbon atoms, are of lower viscosity and can provide polyurethanes having improved properties. Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer, in situ in a polyol in the presence of an azo compound and a peroxide having a 10 hours half-life period temperature which is lower by at least 10.degree. C. than that of the azo compound, have improved stability even at higher styrene content.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: December 21, 1993
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Keiichi Akimoto, Takeshi Sumita, Masahiro Matsuoka
  • Patent number: 5204427
    Abstract: A reaction solution comprising a mixture of tricyclopentadiene, a norbornene monomer with at least 3 rings in its backbone, a 5-alkenyl-2-norbornene pot life adjusting agent along with a molybdenum type catalyst system gives prolonged pot life without extending time to exotherm (e.g., smoking time). By utilizing this reaction solution it is possible to bulk polymerize reinforced or unreinforced articles in a mold via ring-opening polymerization. Articles so obtained have good outward appearance and excellent physical properties.
    Type: Grant
    Filed: May 24, 1991
    Date of Patent: April 20, 1993
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Masao Torii, Tomoo Sugawara, Kin-ichi Okumura, Motoyuki Yamato
  • Patent number: 5061749
    Abstract: One-pack type heat pre-curable moisture-curing sealant composition which comprises as the main component(A) a urethane prepolymer having a content of an active free isocyanate group (NCO) of 0.5 to 13% by weight which is prepared by reacting a polyol and an excess amount of an aromatic polyisocyanate compound, and(B) a vinyl polymer containing a siloxy group, and as an additive(C) a filler in an amount of 20 to 50% by weight based on the whole weight of the sealant, and(D) a plasticizer in an amount of 5 to 30% by weight based on the whole weight of the sealant, which can be precured at a comparatively lower temperature within a short period of time and cured with moisture in air and is useful for adhering various parts in automobile and construction industries without a temporary holding means.
    Type: Grant
    Filed: July 26, 1990
    Date of Patent: October 29, 1991
    Assignee: Sunstar Giken Kabushiki Kaisha
    Inventors: Masahiro Ito, Yukio Hayashi
  • Patent number: 4950710
    Abstract: A composite comprising the reaction product of a filler having a reactive hydroxylated surface, a monomer or polymer containing carboxyl groups, and an organoaluminum compound, the organoaluminum compound being reacted with said hydroxylated surface and with said monomer or polymer. A preferred composite is made by reacting aluminum sec-butoxide with fiberglass and acrylic acid and methyl methacrylate under polymerization conditions.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: August 21, 1990
    Assignee: Aluminum Company of America
    Inventor: Max E. Roha
  • Patent number: 4933388
    Abstract: Solutions of copolymers of the tetrafluoroethylene/ethylene typeCopolymer solutions comprising tetrafluoroethylene, ethylene and, as appropriate, further .alpha.-olefinic monomers in low-molecular-weight polymers of chlorotrifluoroethylene are described. They can be used for coatings, impregnations, cast films and for the production of fibers and filaments by gel spinning.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: June 12, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Peter Blickle, Friedhelm Gundert, Klaus Hintzer, Gernot Lohr, Werner Schwertfeger
  • Patent number: 4748224
    Abstract: Highly oxygen permeable hard and semi-hard contact lenses are made from the copolymer of ethylenically unsaturated siloxane ester, ethylenically unsaturated fluorocarbon ester and ethylenically unsaturated sulfone monomer and methods for the polymerization thereof.
    Type: Grant
    Filed: June 6, 1986
    Date of Patent: May 31, 1988
    Assignee: Maureen J. DeVou
    Inventor: Nick N. Novicky
  • Patent number: 4741865
    Abstract: Polymer systems can be rendered flame retardant by adding a source of halogen and particles of antimony pentoxide that have been dried from colloidal dispersions that have been treated with certain metal ions. The properties of the polymer are conserved when the colloidal dispersion is treated with ions of metals that have insoluble antimonates before drying to form a powder.
    Type: Grant
    Filed: May 7, 1986
    Date of Patent: May 3, 1988
    Assignee: Nyacol Products, Inc.
    Inventors: Donald P. Kintz, Stephen N. Davis
  • Patent number: 4716195
    Abstract: A process for the preparation of a vinyl chloride polymer latex having particles with a mean diameter between about 0.2 and 0.8 .mu.m and containing at least one organosoluble polymerization initiator comprising dispersing in an aqueous reaction medium also containing parabenzoquinone, at least one monomer, at least one anionic emulsifier and optionally at least one nonionic emulsifier, and from about 0.004 to 0.16% by weight, with respect to said at least one monomer, of said initiator expressed in terms of active oxygen, polymerizing said at least one monomer at a desired polymerization temperature, .theta..sub.1, and continuously adding parabenzoquinone to said aqueous reaction medium during the polymerization when the temperature .theta..sub.2 of the reaction medium is such that the difference .theta..sub.2 -.theta..sub.1 exceeds a value from 0.degree. to +5.degree. C.
    Type: Grant
    Filed: September 2, 1986
    Date of Patent: December 29, 1987
    Assignee: Societe d'Extrusion et de Transformation
    Inventor: Daniel Brulet
  • Patent number: 4666976
    Abstract: When a solution of liquid allylic-functional material and bromoxylenol blue is polymerized using a thermally decomposable polymerization initiator, the color imparted by the bromoxylenol blue is brilliant yellow.
    Type: Grant
    Filed: April 16, 1986
    Date of Patent: May 19, 1987
    Assignee: PPG Industries, Inc.
    Inventor: Michael S. Misura
  • Patent number: 4645788
    Abstract: The cold resistance of chloroprene rubber can be improved by blending an ester derived from a specified glycol component and a specified fatty acid component without any adverse effect upon the other physical and chemical properties of the rubber. This ester is not extracted with oily matters such as oil or grease, so that the resulting chloroprene rubber composition hardly exhibits a decrease in cold resistance even after extraction with oily matters.
    Type: Grant
    Filed: December 6, 1985
    Date of Patent: February 24, 1987
    Assignees: Kao Corporation, Toyoda Gosei Co. Ltd.
    Inventors: Tadaoki Okumoto, Rikizo Nakata, Masayoshi Ichikawa, Masaaki Tsuchihashi, Koichi Sakai
  • Patent number: 4460715
    Abstract: A stable copolymer dispersion is prepared by addition copolymerization of (1) a monomeric adduct of an active hydrogen compound, e.g., a polyether polyol, and an acrylyl compound such as methacryloyl chloride with (2) ethylenically unsaturated monomer(s), e.g., styrene or a mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound such as a polyether polyol. The molar ratio of acrylyl moiety to active hydrogen compound is less than 0.1:1. The resulting dispersion has a controlled particle size and a viscosity such that it is suitably employed in the production of polyurethane foams.
    Type: Grant
    Filed: November 10, 1981
    Date of Patent: July 17, 1984
    Assignee: The Dow Chemical Company
    Inventors: Dwight K. Hoffman, Robert F. Harris, Nancy B. Tefertiller, Randall C. Rains