Abstract: A curable white silicone composition that is capable of forming a cured product having a high optical reflectance as well as exceptional light resistance is provided. The curable white silicone composition includes (A) an organopolysiloxane having at least 2 alkenyl groups per molecule, (B) a cerium-containing organopolysiloxane, (C) a white pigment, and (D) a curing catalyst.

Abstract: Provided is a millable silicone rubber composition capable of yielding a silicone rubber (cured product) superior in heat resistance. The composition contains: (A) 100 parts by mass of an organopolysiloxane having at least two silicon atom-bonded alkenyl groups in one molecule, and having an average polymerization degree of not lower than 100; (B) 5 to 100 parts by mass of a reinforcing silica having a specific surface area of not smaller than 50 m2/g; (C) 0.01 to 10 parts by mass of a titanium oxide doped with a transition metal oxide of 0.01 to 5% by mass; (D) 0.01 to 10 parts by mass of a cerium oxide and/or a cerium hydroxide; and (E) 0.01 to 10 parts by mass of a curing agent.

Abstract: A curable silicone composition comprises: (A) an organopolysiloxane represented by a specific average unit formula; optionally, (B) an organopolysiloxane represented by a specific average unit formula; (C) an organohydrogenpolysiloxane represented by a specific average composition formula; and (D) a hydrosilylation catalyst. A curable hot-melt silicone is obtained by subjecting the curable silicone composition to a hydrosilylation reaction to a degree that does not form a cured product. The curable hot-melt silicone is non-flowable at 25° C. and has a melt viscosity at 100° C. of 5000 Pa·s or less. The curable silicone composition provides a cured product having excellent heat resistance and light resistance after being cured. The curable hot-melt silicone is non-flowable at room temperature, has low surface stickiness, and is readily melted by heating.

Abstract: The present invention is related to a surface control additive for a radiation curing system, the method for its preparation as well as its application. The surface control additive has the following structure: wherein A is wherein m is an integer from 0 to 400, n is an integer from 1 to 500, x is an integer from 0 to 800, p is an integer from 0 to 600, q is an integer from 1 to 800, R4 and R5 are H or CH3 respectively, R6 is H or a linear or a branched alkyl group containing 1-18 carbon atoms or an acyl group containing 2-5 carbon atoms. The surface control additive of the present invention is applied to radiation curing (UV/EB) paint and inks, enables the coatings to maintain non-adhesive and smooth for a long time, and minimizes transferable precipitates from a cured film. In addition, by using different combinations of EO and PO, the surface control additive of the present invention can adapt to a free selection from high-polarity aquosity to a low-polarity aliphatic hydrocarbon solvent system.

Abstract: A release sheet comprising a base material and a release agent layer formed on at least one surface of the base material by using a release agent composition; the release agent composition contains a first polydimethylsiloxane having at least two alkenyl groups in one molecule and a second polydimethylsiloxane having at least two hydrosilyl groups in one molecule; the release agent composition contains 0.40 to 5.25 mmol of the alkenyl groups and 7.00 to 120.00 mmol of the hydrosilyl groups in a total of 30 g of the first polydimethylsiloxane and the second polydimethylsiloxane; and a molar ratio (b/a) of the hydrosilyl groups (b) to the alkenyl groups (a) is 3.0 to 70.0. Consequently, it is possible to suppress the peeling force from increasing even when the release agent layer of the release sheet is exposed to the air for a long time.

Abstract: An addition curable self-adhesive silicone rubber composition comprising (A) an organopolysiloxane containing alkenyl at either end, (B) an organosilicon compound containing phenylene and SiH group, (C) an organohydrogenpolysiloxane containing two SiH groups, (D) an organohydrogenpolysiloxane containing at least three SiH groups, and (E) an addition reaction catalyst is integrally moldable with thermoplastic resins.

Abstract: The invention relates to an isocyanate-terminated polysiloxane material that can preferably be used as a curing agent, hardener or co-reactant in coatings. The invention further relates to a method of manufacturing the isocyanate-terminated polysiloxane material by partially hydrolyzing a methoxy-functional polysiloxane such as a methyl phenyl polysiloxane, and reacting it with a polyisocyanate to yield the isocyanate-terminated polysiloxane hardener. The hardener can preferably be used with any isocyanate-reactive functional group of another component to form coating systems, including acrylics, polyesters, epoxies and urethanes.

Abstract: There is provided a silicone rubber composition whose compression set in a higher temperature range, particularly at 200° C. or higher, in a silicone rubber to be obtained is sufficiently suppressed. A heat curable silicone rubber composition contains: (A) 100 parts by mass of a polyorganosiloxane having an average degree of polymerization of 500 to 20,000 and having two or more alkenyl groups in a molecule; (B) 5 to 100 parts by mass of a filler; (C) an effective amount of an organic peroxide; and (D) 0.06 to 15 parts by mass of a hydrous cerium oxide and/or a hydrous zirconium oxide each having one absorption band in 3300 to 3500 cm?1 and two or more absorption bands in 1300 to 1700 cm?1 in infrared absorption spectrum measurement.

Abstract: A curable composition and use thereof are provided. The composition can be useful in exhibiting excellent processability and workability, and providing a cured product which exhibits superior light extraction efficiency, crack resistance, hardness, thermal shock resistance, and adhesive properties, has superior reliability under severe conditions for a long period of time and prevents opacity and stickiness onto a surface thereof when cured. Also, the curable composition capable of preventing precipitation of an additive such as a fluorescent material or a photoconversion material and being formed into a cured product having excellent transparency even when the additive is added to the curable composition can be provided.

Abstract: An addition curable self-adhesive silicone rubber composition comprising (A) an organopolysiloxane containing alkenyl at either end, (B) an organosilicon compound containing phenylene and SiH group, (C) an organohydrogenpolysiloxane containing two SiH groups, (D) an organohydrogenpolysiloxane containing at least three SiH groups, and (E) an addition reaction catalyst is integrally moldable with thermoplastic resins.

Abstract: The invention relates to highly transparent organofunctional silicone copolymers, being self-dispersible in water without emulsifiers or protective colloid, being obtained by radically initiated solution polymerization of a) one or more ethylenically unsaturated organomonomers, and b) one or more siliconmacromeres, characterized in that c) one or more water soluble comonomeres are copolymerized in an organic solvent or solvent mixture.

Abstract: Described are compositions comprising a fluorine containing or fluorine and silicon containing polymer, with a reactive diluent, and optionally non-reactive oligomeric additives, crosslinkers, or inorganic particles, which upon curing provides coatings with a good balance of adhesion, mechanical properties, scratch resistance, low surface energy, repellency, and transparency. The compositions are useful as a topcoat, particularly in optical applications.

Abstract: The present invention relates to silicone rubber compositions and long-term-stress-resistant silicone elastomers obtained therefrom, which have excellent resistance to long-term dynamic mechanical stresses, and to their use.

Abstract: A curable adhesive composition kit and method of adhering substrates is provided having three basic adhesives and up to three additional optional adhesives. The basic adhesives include: at least one curable silicone end group-containing adhesive; at least one curable cyanoacrylate adhesive, and at least one curable epoxy adhesive. The optional adhesives can be one or more of the following: contact adhesive, urethane adhesive, polyvinylacetate adhesive, and pressure sensitive adhesive. The kit system also can have a selection guide for the adhesives in the system based on substrate types or substrate types and use conditions. Optionally a guide for using the adhesives in repairing adherends can be included in the kit. Also optionally the selection guide and/or the repair guide can be in an interactive program on a web site on a computer network such as the internet.

Abstract: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one nitroso inhibitor of the structure: wherein R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, nitro, nitroso, halogen, COOR wherein R is hydrogen or alkyl, alkyl, and heteroatom-substituted alkyl; or adjacent groups R1, R2, R3, and R4 can be taken together to form a substituted or unsubstituted fused six-membered ring. Also disclosed is a composition of matter comprising: A) an ethylenically unsaturated monomer and B) at least one nitroso compound of the above-described structure.

Abstract: The present invention relates to a specific process for preparing organosilane esters of the formula (I) and a composition comprising more than 98% by weight of organosilane esters of the formula (I) and less than 2.0% by weight of at least one hydrocarbon and to the use of such a composition as precursor for producing a layer or film having a dielectric constant of 1<??4.

Abstract: Moisture curable compositions that include alkoxysilyl capped polymer compounds and alkylsilyl capped plasticizers adhesively cure to polyolefin substrates, including polyethylene and polyolefin substrates. The compositions are curable at room temperature or at temperatures greater than room temperature. The compositions further include an adhesion promoter, a filler or a moisture curing catalyst.

Abstract: Organosilicone and vinyl ester copolymers free from phase separation are prepared by copolymerizing at least one vinyl ester monomer with organosilicones containing difunctional silicone monomers and optionally a minor amount of monofunctional silicone monomers, in a non-aqueous solvent mixture containing at least one solvent with a transfer coefficient greater than 20·10?4 relative to vinyl acetate.

Abstract: The present invention includes a novel polyol prepolymer including either an aliphatic amine, cycloaliphatic amine, aromatic amine or a mixture of these with an epoxy functional silicone to produce the novel polyol prepolymer chain extender. In one aspect of the invention, the novel polyol prepolymer chain extender is reacted with an epoxy resin to produce a novel silicone modified epoxy resin having improved adhesion, chemical resistance, UV stability, and decreased shrinkage properties. In another aspect of the invention, the novel polyol prepolymer chain extender is reacted with an acrylic monomer to produce a novel silicone modified acrylic resin having improved adhesion, chemical resistance, UV stability, increased functionality, and decreased shrinkage properties. The present invention also provides for a novel solid surface material composition.

Abstract: The present invention relates to an adhesive and more particularly to a moisture curable adhesive. In one embodiment, the present invention includes a moisture curable adhesive comprising a polymer or copolymer including reactive silicon end groups; from about 0.01 to about 40 percent by weight of a clear filler that will not substantially interfere with the clarity of the adhesive; and from about 0.01 to about 10 percent by weight of a dehydrating agent. In another embodiment, the present invention includes a moisture curable adhesive comprising a copolymer including a reactive silicon group; from about 33 to about 85 percent by weight of a filler; and from about 0.01 to about 10 percent by weight of a dehydrating agent. The present invention is further directed to a method of joining two adherends.

Abstract: Disclosed is a UV curable coating composition comprising a (methyl)acryloxy or vinyl functionalized silane, silica and acrylate oligomer containing at least two acrylate groups.

Abstract: Disclosed is a UV curable coating composition comprising a (methyl)acryloxy or vinyl functionalized silane, silica and acrylate oligomer containing at least two acrylate groups.

Abstract: The present invention relates to curable alkenyl based silicone release coating compositions having improved adhesion to paper and polymeric substrates. Furthermore the present invention relates to the process for making a silicone release coating with improved adhesion to paper and polymeric substrates.

Abstract: A silicone rubber coating composition which cures into a silicone rubber having a tear strength of 25–50 kN/m and a peeling bond strength of 30–60 N/cm is suited for coating of hollow weave type air bags. A hollow weave type air bag coated with the coating composition can be instantaneously inflated while the bag prevents the silicone rubber film from being peeled from the base fabric, eliminates inflating gas leakage, and retains an acceptable inflation time.

Abstract: A silicone rubber composition comprising an organopolysiloxane component composed of (A) an organopolysiloxane gum having an alkenyl content of 0.001-2 mol % and (B) an organopolysiloxane gum having an alkenyl content of more than 2 mol % to 20 mol %, (C) microparticulate silica, (D) platinum or a platinum compound, (E) an organosilicon compound containing a nitrogenous organic group and an unsaturated hydrocarbon group and/or a benzotriazole, and (F) a curing agent cures into electrically insulating silicone rubber having a minimized tensile permanent set, improved mechanical strength, and tracking resistance.

Abstract: The present invention relates to a thermoconducting silicone composition having a viscosity at 25° C. before curing of 10-1,000 Pa·s, a method of installing the composition, and a heat dissipating structure comprising the silicone composition.

Abstract: The present invention relates to a biocompatible polymer composition, suitable for in vivo vessel repair, comprising a matrix pre-polymer, a filler and a curing agent, wherein said composition wherein said biocompatible polymer composition is curable in the presence of a curing catalyst at 37° C. to form a cured material with an elongation until rupture of at least 5% and an elastic modulus of at least 1 MPa.

Abstract: The present invention discloses a silicone rubber with improved adhesive properties; a composite structure in which a base member formed from a synthetic resin or metal is bonded firmly and directly to silicone rubber; a denture in which a biocompatible silicone rubber is firmly bonded to a section of a denture bed that contacts the body; and a method for making the denture. Methyl methacrylate is added to a linear polysiloxane and polymerized in a predetermined molding cavity, and methyl polymethacrylate is formed on at least the surface of the molded silicone rubber. The silicone rubber resulting from this process provides superior adhesive properties. A section of a base member, such as a main unit or an auxiliary member of a product, that is to be bonded with silicone rubber is extended into the predetermined molding cavity. The molding cavity is filled with a linear polysiloxane to which a monomer is added. This results in a composite structure in which silicone rubber is bonded to the base member.

Abstract: A composition that can be used to prepare a thermal interface material includes: A) a curable matrix having a curing temperature, B) a metal filler having a low melting point, optionally C) a spacer, and optionally D) a conductive filler. The temperature at which component B) commences softening is less than the curing temperature of component A). A thermal interface material is prepared by: 1) interposing the composition between an electronic component and a heat spreader to form a bondline, 2) heating the composition to a temperature higher than the temperature at which component B) commences softening but less than the curing temperature of component A) and optionally applying pressure to the composition, and 3) heating the composition to a temperature greater than or equal to the curing temperature of component A). The average particle size of component B) is greater than or equal to the bondline thickness.

Abstract: A liquid form addition curable silicone rubber composition for forming a fluororesin covered fixing roller is provided. This composition includes (a) 100 parts by weight of an organopolysiloxane with at least two alkenyl groups bonded to non-terminal silicon atoms; (b) an organohydrogenpolysiloxane with at least two silicon-bonded hydrogen atoms, in a sufficient quantity to produce a molar ratio of silicon-bonded hydrogen atoms within said constituent (b) relative to silicon-bonded alkenyl groups within said constituent (a) of 0.4 to 5.0; (c) an effective quantity of a platinum based catalyst; (d) 0.1 to 10 parts by weight of dry process silica; and (e) 0.05 to 5 parts by weight of a cyclic diorganopolysiloxane with at least three silicon-bonded alkenyl groups. This composition is used for formation of the silicone rubber layer of a fixing roller made up of a metal core, a silicone rubber layer on the core, and a fluorine based coating provided on the rubber layer.

Abstract: An aqueous dispersion which is excellent in storage stability, and can form a coating film excellent in leveling properties, anti-checking properties, water resistance, etc., transparent and high in hardness, which is obtained by mixing and emulsifying (A) at least one selected from an organosilane represented by (R1)4−n—(Si)—(OR2)n, a hydrolysate of the organosilane and a partial condensation product of the hydrolysate, (B) a radical polymerizable monomer, (C) an emulsifier and (D) a hydrolytic catalyst for component (A) to reduce the particle size of an emulsion, as well as to allow hydrolysis of component (A) to proceed, and adding (E) a radical polymerization initiator to allow polymerization of component (B) to proceed, has a concentration of alcohols having a boiling point of 100° C. or less of 0.1 to 2.0 wt %, and further contains (F) a component having ultraviolet absorption and/or light stabilization action as needed.

Abstract: There are disclosed alkoxysilyl functional silicone based materials that are thermodynamically stable, methods for making them and their uses. The methods comprise cross-linking of reactants that are dispersed in a diluent.

Abstract: The invention discloses an efficient and convenient method for the preparation of an aqueous emulsion of an organopolysiloxane having long-chain alkyl groups bonded to the silicon atoms. Instead of dispersing and emulsifying an organopolysiloxane modified in advance with long-chain alkyl groups in an aqueous medium, as is the case in the prior art method, an organohydrogenpolysiloxane having silicon-bonded hydrogen atoms and a long-chain &agr;-olefin compound are co-emulsified in an aqueous medium containing a surface active agent and this aqueous emulsion is heated under agitation with addition of a catalytic platinum compound so as to effect the in situ hydrosilation reaction between the silicon-bonded hydrogen atoms in the organohydrogenpolysiloxane and the ethylenically unsaturated bonds in the &agr;-olefin compound. The aqueous emulsion prepared by the inventive method exhibits excellent stability against long-term storage, dilution with water and mechanical shearing force.

Abstract: 3-methacryloxy- and 3-acryloxyisobutylalkoxysilanes of the general formula (I) and R is a linear alkyl radical having from 1 to 4 carbon atoms, R1 is a linear or branched alkyl radical having from 1 to 3 carbon atoms, and m is 0 or 1.

Abstract: Polyolefin thermoplastic elastomers are disclosed which are prepared by; (I) mixing (A) a thermoplastic resin comprising more than 50 percent by volume of a polyolefin resin, said thermoplastic resin having a softening point of 23° C. to 300° C.

Abstract: Acylphosphine initiators used in making ophthalmic lenses are stabilized by the addition of an acid to the monomer mix used to make the lenses.

Abstract: High levels of treated fumed silica, processing fluid and high molecular weight silicone polymer are continuously compounded into a homogeneous silica filled heat-vulcanizable silicone composition by forming a premix in a continuous annular layer mixer and continuously discharging the premix into a compounding apparatus for compounding to form the filled heat-vulcanizable silicone composition.

Abstract: A silicone rubber composition useful for keypads comprising a silicone rubber base produced by mixing under heat (A) a cross-linkable diorganopolysiloxane and (B) 20 to about 250 parts by weight calcium carbonate powder per 100 parts by weight of component (A), and (C) a curing agent consisting of (i) an organic peroxide or (ii) an organohydrogenpolysiloxane and a platinum catalyst in an amount sufficient to effect cure of the composition.

Abstract: An organic silicone resin powder having a tabular shape the aspect ratio of which is greater than about 1 and comprising a copolymer produced by polymerization reaction between an organopolysiloxane containing at least one reactive group and at least one kind of monomer or oligomer capable of reacting to said reactive group, which can fully achieve its excellent effects when mixed in cosmetic materials, waxes and coating colors, especially in cosmetic materials.

Abstract: Oligomers of the formula: [R3SiO½]m[O½Si(R2)O½]n[SiO{fraction (3/2)}R]o[SiO{fraction (4/2)}]p  (I) wherein each R is selected individually from the group consisting of B, R1,—OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated or aromatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1 or an acyl group; and each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from ether, polyether, ester, polyester, carbamate, polyurethane, isocyanurate, thioether, polysulfide

Abstract: A water-base resin has both excellent storage stability and excellent curability at room temperature, the water base resin being obtained by mixing a composite resin (C) and a polysiloxane (D), bringing about a condensation reaction partially between them if necessary, and thereafter dispersing or dissolving the resulting mixture or partially condensed product into a water-base medium, wherein the composite resin (C) comprises a polysiloxane segment (A) and a polymer segment (B), the polysiloxane segment (A) having at least one silicon atom selected from the group consisting of a silicon atom bearing at least one organic group having a total carbon number of at least 3 together with at least one hydrolyzable group and/or at least one hydroxyl group, a silicon atom bearing one hydrolyzable group or one hydroxyl group together with two groups selected from the group consisting of methyl groups and ethyl groups, and a silicon atom bearing at least one triorganosiloxy group together with at least one hydrolyzable

Abstract: A silicone resin-containing emulsion composition is prepared by emulsion polymerizing a solution containing a water-insoluble silanol group-bearing silicone resin and a radical polymerizable vinyl monomer and substantially free of an organic solvent. The emulsion may further contain a film-forming assistant having a boiling point of at least 100.degree. C. and soluble or uniformly dispersible in water. The emulsion can be coated and cured into a film having mar resistance, weather resistance, and chemical resistance.

Abstract: A silicone rubber composition that has excellent discharge and flow characteristics prior to its cure and that cures into a highly transparent silicone rubber comprises:(A) polyorganosiloxane,(B) microparticulate silica,(C) methyloligosiloxane endblocked at one molecular chain terminal by silanol and endblocked at the other terminal by trimethylsiloxy, and(D) a curing agent.

Abstract: A release coating composition containing about 50 to about 75 wt. % of an epoxy functional silicone; about 8 to about 25 wt. % of a reactive solvent; about 5 to about 25 wt. % of a reactive diluent; about 6 to about 12 wt. % of a wax-treated silica powder; and, about 2 to about 4 wt. % of a photoinitiator is disclosed. The composition is useful in preparing a low-gloss release coating for use on linerless labels.

Abstract: A method for manufacturing of a silicone rubber base composition in a mass-like form, comprises:(A) preparing a freely flowable powdered silicone rubber composition comprising(a) a cross-linkable polydiorganosiloxane with a viscosity of at least 1.times.10.sup.5 mPa.s at 25.degree. C. and(b) an inorganic filler, and(B) continuously kneading and massing the powdered silicone rubber composition in a multiple-stage siding shear-type single-screw extruder.This method provides for continuous preparation of a silicone rubber base compound without the use of a dual-screw mixer-extruder having a large length to diameter ratio, without abrasive wear of screws and cylinders with such inorganic fillers as diatomaceous earth power, quartz or a similar large-grain and hard powders, without blackening of the mixed silicone rubber composition, and without production problems associated with the use of large quantities of fumed silica, sedimentary silica, or a similar reinforcing silica.

Abstract: The organopolysiloxane compositions are prepared by mixing(1) organopolysiloxanes which contain on average at least 2 aliphatic carbon-carbon multiple bonds per molecule,(2) prehydrophobized oxidic reinforcing fillers having a carbon content, obtained by the hydrophobizing, of at least 0.5% by weight and(3) compounds which are chosen from(3a) silanol compounds of the formulaR--[SiR.sub.2 --O--].sub.a H (I)in whichR is identical or different monovalent, C.sub.1 - to C.sub.10 -hydrocarbon radicals which are free from aliphatic carbon-carbon multiple bonds anda has values from 1 to 10, and(3b) saturated C.sub.1 - to C.sub.18 -alkanols.

Abstract: Oraganopolysiloxanes of the general formula ##STR1## where R.sup.1 =identical or different aliphatic or aromatic hydrocarbon radicals,R.sup.2 =CH.sub.2 CH.sub.2 O(CR.sup.4 R.sup.5).sub.x OC(O)CR.sup.6 .dbd.CHR.sup.7, whereR.sup.4, R.sup.5, R.sup.6 and R.sup.7can be identical or different radicals and are each a H or alkyl radical, branched or unbranched, having up to a total of 6 C atoms and x has a value from 3 to 11, where --(CR.sup.4 R.sup.5)-- can also be a cyclic aliphatic or aromatic radical,R.sup.3 =R.sup.2 or R.sup.1,a=0 to 50 andb=0 to 500,but at least one radical R.sup.2 is attached terminally and/or laterally.

Abstract: A silicone resin-containing emulsion composition is prepared by emulsion polymerizing a solution containing a water-insoluble silanol group-bearing silicone resin and a radical polymerizable vinyl monomer and substantially free of an organic solvent. The emulsion may further contain a film-forming assistant having a boiling point of at least 100.degree. C. and soluble or uniformly dispersible in water. The emulsion can be coated and cured into a film having mar resistance, weather resistance, and chemical resistance.

Abstract: A highly productive, continuous method for the production of room-temperature-curable organopolysiloxane compositions is obtained by continuously feeding 100 parts by weight of a diorganopolysiloxane with a viscosity at 25.degree. C. of 0.1 to 500 Pa.

Abstract: One-package room-temperature-curable silicone elastomer compositions that do not slump prior to their cure, that provide a suitable processing or working time, that do not crack or fissure during their cure even when deformed by an external force, and that do not yellow during storage or after curing are prepared by mixing (A) the reaction mixture of(a) hydroxyl-terminated diorganopolysiloxane and(b) alkyl-containing oximosilaneor optionally (b) alonewith (B) the reaction mixture of(a) hydroxy-terminated diorganopolysiloxane and(c) vinyl-functional oximosilaneand by thereafter mixing in(C) inorganic filler.