Two Or More N=c=x Containing Reactants (other Than Conventional Isomer Mixtures) Patents (Class 524/872)
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Patent number: 9637667Abstract: The present invention describes reaction products from 2,4?-diphenylmethane diisocyanate with a content of at least 95 wt. % of 2,4? isomer with at least one polyether-polyol and/or polyalkylene glycol with a molecular weight of less than 1,000 and/or one crystalline or partly crystalline or vitreously amorphous polyester-polyol and optionally polyester-polyols and/or polyether-polyols which are liquid at room temperature and have molecular weights of greater than 1,000 can be converted into adhesive compositions which have a very low content of monomeric diisocyanate of less than 0.5, preferably less than 0.25 wt. %. Such hot melt adhesive compositions have a high melt stability and a low viscosity, in addition to the low content of monomeric diisocyanate.Type: GrantFiled: April 12, 2004Date of Patent: May 2, 2017Assignee: Henkel AG & Co. KGaAInventors: Michael Krebs, Katja Brosa, Andreas Brenger, Uwe Franken, Christoph Lohr
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Publication number: 20150087774Abstract: The present invention relates to a composition comprising 10 to less than 50 wt.-% of at least one oligomeric polyisocyanate a-1) based on hexamethylene diisocyanate and more than 50 to 90 wt.-% of at least one polyisocyanate a-2) based on isophorone diisocyanate, comprising monomeric isophorone diisocyanate and at least one oligomeric isophorone diisocyanate, and an isocyanate-reactive component selected from the group consisting of polyester polyol, polyether polyol and mixtures thereof. It has been shown that the above mentioned mixture of the specific isocyanate group containing components improves the thermal and mechanical properties of a cured composition. Thus prepared molded articles are particularly suitable for the preparation of spectacle lenses, inter alia due to these properties.Type: ApplicationFiled: April 22, 2013Publication date: March 26, 2015Inventors: Dorota Greszta-Franz, Hans-Josef Laas, Hartmut Nefzger, Jens Krause
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Patent number: 8987375Abstract: A moisture-curable polyurethane formulation is provided capable of curing to form a reaction product, having high green strength and being dispensable from a caulking gun. The polyurethane formulation comprises at least one isocyanate-terminated prepolymer, at least one rheology modifier or filler, optionally monomeric/polymeric isocyanate, and at least one urea-based thixotropic additive added to the formulation or formed in situ, to provide greater than 1% of urea groups in the reaction product. A method for making a moisture-curable polyurethane formulation capable of curing to form a reaction product and methods of bonding materials together using the formulation are also provided.Type: GrantFiled: August 27, 2010Date of Patent: March 24, 2015Assignee: Construction Research & Technology GmbHInventors: Paula Bushendorf, John M. Davis, Michael Porsch
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Patent number: 8962750Abstract: Pebble or granular based elastomeric surfacing materials that include an aliphatic thermoplastic polyurethane based pebble or granule bonded together with a two-part aliphatic polyurethane binder are provided. In one embodiment, an A side of the two-part binder has at least one polyol, and a B side of the two-part binder has multiple isocyanates. The multiple isocyanates can include for example hydrogenated methylene diphenyldisocyanate and hexamethylene diisocyanate. The A side and the B side of the binder are utilized to bond the pebbles together to form a surface that can be either porous or non-porous. In another embodiment, an A side of a two-part binder includes multiple polyols. The multiple polyols can include for example esterified ricinoleic acid polyols and caprolactone polyols. The A side of the two-part binder can be combined with a B side of the two-part binder and pebbles to form a non-porous surface.Type: GrantFiled: July 10, 2012Date of Patent: February 24, 2015Assignee: Landscape Structures Inc.Inventor: Gerald M. Saluti
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Patent number: 8865287Abstract: A hybrid polymer composition and a method for forming it is provided, comprising a first part A comprising a polyurethane catalyst and an aldehyde resin pre-polymer and a second part B comprising a polyisocyanate pre-polymer and an aldehyde resin cure accelerator. Methods are also provided for forming a composite with a two part hybrid polymer composition and a fibrous web material.Type: GrantFiled: August 12, 2009Date of Patent: October 21, 2014Inventor: Robert A. Haupt
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Patent number: 8853299Abstract: Described herein, in the preferred embodiment, is a leonardite-based polyurethane resin binder that may be used, among other applications, as a binder in combination with foundry aggregate, e.g., sand, for molding or casting metal parts. The binders described herein comprise a humic substance, preferably leonardite, combined with a polymerizable polyol, an isocyanate, and a polymerization catalyst to make a polyurethane resin binder in situ in a foundry aggregate, such as sand. The lignite is mixed with the polymerizable polyol, thickening and dispersing agents as additives to improve the suspension quality and binder performance of the lignite-containing part of the binder components.Type: GrantFiled: October 6, 2009Date of Patent: October 7, 2014Assignee: Amcol International Corp.Inventors: Ashoke K. SenGupta, Vincent J. Losacco, Jerald W. Darlington, Jr.
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Publication number: 20140212661Abstract: A two-coat barrier system employing a coating of a water-dispersible or solvent-soluble polyurethane resin with innate gas and moisture vapor barrier properties and an additional coating of a multivalent metal cation to enhance the overall barrier performance without the need to add fillers.Type: ApplicationFiled: March 28, 2002Publication date: July 31, 2014Applicant: SUN CHEMICAL CORPORATIONInventor: Sarfaraz Khan
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Publication number: 20140199491Abstract: Disclosed are one-component compositions that include: (1) an isocyanate-functional urethane acrylate and (2) a polyisocyanate containing allophanate and/or uretdione groups, wherein the one-component composition has a viscosity of less than or equal to about 500 mPas and an isocyanate content of greater than about 5% by weight, based on the weight of the one-component composition. Also disclosed are circuit boards and electronic components that are coated with such compositions.Type: ApplicationFiled: August 1, 2013Publication date: July 17, 2014Applicant: Allnex IP S.à.r.l.Inventors: Abdullah Ekin, Michael J. Dvorchak
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Publication number: 20130296490Abstract: Disclosed are polyurea compositions comprising the reaction products of a polyformal-isocyanate prepolymer and a curing agent comprising an amine. The compositions are useful as sealants in aerospace applications.Type: ApplicationFiled: July 3, 2013Publication date: November 7, 2013Inventors: Stephen J. Hobbs, Juexiao Cai, Marfi Ito, Renhe Lin
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Publication number: 20130203935Abstract: The invention relates to a crosslinking two-component polyurethane composition consisting of (i) a constituent A containing polyols and additives, and (ii) a constituent B containing between 100 and 65 wt. % of aromatic polyisocyanates, between 0 and 35 wt. % of aliphatic polyisocyanates, and between 0.05 and 3.0 wt. % of a retarder, and optionally additives, the mixed composition having a viscosity (EN ISO 2555) of between 100 mPas and 3000 mPas at 25° C., and the crosslinked composition having a glass transition temperature (Tg) of higher than 50° C. and a pot life of longer than 60 minutes. The two-component polyurethane composition is suitable as an adhesive and as a matrix substance for composite materials.Type: ApplicationFiled: March 14, 2013Publication date: August 8, 2013Applicant: Henkel AG & Co. KGaAInventor: Henkel AG & Co. KGaA
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Publication number: 20130158146Abstract: The invention relates to novel solvent-free, monomer-depleted polyisocyanate mixtures, and to the use thereof for producing light-resistant and weather-resistant polyurethane bodies with high optical refraction and low optical dispersion.Type: ApplicationFiled: July 15, 2011Publication date: June 20, 2013Applicant: BAYER INTELLECTUAL PROPERTY GMBHInventors: Dorota Greszta-Franz, Hans-Josef Laas, Reinhard Halpaap, Dieter Mager, Hans-Ulrich Meier-Westhues
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Publication number: 20120216952Abstract: A moisture-curable polyurethane formulation is provided capable of curing to form a reaction product, having high green strength and being dispensable from a caulking gun. The polyurethane formulation comprises at least one isocyanate-terminated prepolymer, at least one rheology modifier or filler, optionally monomeric/polymeric isocyanate, and at least one urea-based thixotropic additive added to the formulation or formed in situ, to provide greater than 1% of urea groups in the reaction product. A method for making a moisture-curable polyurethane formulation capable of curing to form a reaction product and methods of bonding materials together using the formulation are also provided.Type: ApplicationFiled: August 27, 2010Publication date: August 30, 2012Inventors: Paula Bushendorf, John M. Davis, Michael Porsch
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Publication number: 20120130016Abstract: The present invention provides two-component polyurethane compositions comprising, as one component, polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane or, preferably, a mixture of two or more of these, and of the isocyanurate of hexamethylene diisocyanate (HDI trimer), and, as the other component, a mix of a soft polyol having a hydroxyl functionality of from 2.5 to 5.0 and a molecular weight of from 500 to 3,000, and a hard polyol. Such compositions provide coatings, especially clear topcoats, which exhibit excellent scratch and mar and solvent resistance in addition to a good balance of hardness and flexibility without the need for increasing the volatile organic content (VOC) of the compositions. Also provided are compositions of a polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane with soft polyol which have lower VOCs.Type: ApplicationFiled: November 16, 2011Publication date: May 24, 2012Inventors: John N. ARGYROPOULOS, Debkumar BHATTACHARJEE, Donald C. SCHALL, Allen XU, Aaron YANG, Louie LUO
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Publication number: 20120040094Abstract: The present invention provides a composition comprising a solvated aromatic amine and a liquid carrier, wherein said solvated aromatic amine is the reaction product of an aromatic amine and at least one of any anhydride, an isocyanate or an acid in the liquid carrier. The present invention also provides a method of preparing a composition comprising a solvated aromatic amine and a liquid carrier, said method comprising the steps of providing a reaction mixture comprising: a) an aromatic amine; b) at least one of an anhydride, an isocyanate or an acid; and c) a liquid carrier; and heating the reaction mixture at an elevated temperature to provide the solvated aromatic amine in the liquid carriers. The present invention further provides the use of the compositions for the preparation of the curable compounds and for gasoline resistant coatings.Type: ApplicationFiled: April 16, 2010Publication date: February 16, 2012Applicant: CROSSLINK TECHNOLOGY, INC.Inventors: John Ulcar, Ackah Toffey
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Publication number: 20110151127Abstract: The present invention concerns a composition of polyisocyanates comprising a composition of hydrophilic polyisocyanates consisting of at least one hydrophilic (poly)isocyanate, comprising an isocyanate part and a hydrophilic group, said hydrophilic group being of monofunctional polyoxyalkylene type and being attached to the isocyanate part via a function containing a chain of formula and a composition of polyisocyanates consisting of a composition consisting of a mixture of at least one (poly)isocyanate with at least one compound having an ionic function, said mixture being characterized in that it comprises 2% to 15% of said compound and 50% to 98% of (poly)isocyanate.Type: ApplicationFiled: June 3, 2009Publication date: June 23, 2011Inventors: Jean-Marie Bernard, Philippe Olier
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Publication number: 20110151180Abstract: A hybrid polymer composition and a method for forming it is provided, comprising a first part A comprising a polyurethane catalyst and an aldehyde resin pre-polymer and a second part B comprising a polyisocyanate pre-polymer and an aldehyde resin cure accelerator. Methods are also provided for forming a composite with a two part hybrid polymer composition and a fibrous web material.Type: ApplicationFiled: August 12, 2009Publication date: June 23, 2011Inventor: Robert A. Haupt
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Patent number: 7834102Abstract: The invention is an composition comprising a) one or more isocyanate functional polyether based prepolymers; b) one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of from about 45 to about 59° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more nonconductive carbon blacks; e) one or more catalysts for the reaction of isocyanates moieties with hydroxyl groups. In a preferred embodiment the composition of the invention further comprises one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of about 60 to about 90° C.Type: GrantFiled: August 25, 2006Date of Patent: November 16, 2010Assignee: Dow Global Technologies Inc.Inventors: Lirong Zhou, Daniel P. Heberer
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Publication number: 20100152381Abstract: A prepolymer system has a monomeric isocyanate content of no greater than about 10% by weight based on 100 parts by weight of the prepolymer system. The prepolymer system comprises a diluent component and a prepolymer component different than and separate from the diluent component. The diluent component has an excess of isocyanate (NCO) functional groups, and comprises the reaction product of a monohydric isocyanate-reactive component and an excess of a first isocyanate component. The first isocyanate component comprises monomeric isocyanates reactive with the monohydric isocyanate-reactive component. The prepolymer component also has an excess of NCO functional groups, and comprises the reaction product of a polyol component and an excess of a second isocyanate component. The prepolymer system can be used to prepare foams via reaction with water. The foams have low density and have excellent adhesion and sound dampening properties for use in cavities of automobile bodies.Type: ApplicationFiled: December 12, 2008Publication date: June 17, 2010Inventors: Thomas G. Savino, Nikolay Lebedinski, Rajesh Kumar, Calvin T. Peeler
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Publication number: 20100029847Abstract: The invention relates to innovative compositions containing polyisocyanates containing allophanate groups and polyamines, preferably aromatic diamines, and optionally further polyisocyanates, preferably polyisocyanates containing uretdione groups, and also their use for producing quick-curing polyurea coatings.Type: ApplicationFiled: August 4, 2009Publication date: February 4, 2010Applicant: Bayer MaterialScience AGInventors: Michael Mager, Malte Homann, Andreas Aus Der Wieschen
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Publication number: 20090159196Abstract: A process for preparing polyurethane carpet backings uses a filled polyurethane-forming composition that contains a mixture of certain metal acetylacetonate and sulfur-containing organotin catalysts. The mixture of catalysts is particularly beneficial in instances where the composition is processed at temperatures of above 30 to about 500 C, as long pot life is provided together with a rapid thermally-induced cure.Type: ApplicationFiled: March 19, 2007Publication date: June 25, 2009Applicant: DOW GLOBAL TECHNOLOGIES INC.Inventor: Randall C. Jenkines
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Publication number: 20090012230Abstract: The instant invention is a sealant composition comprising an ultra-high solid polyurethane dispersion comprising. The ultra-high solid polyurethane dispersion comprises (1) a first component comprising a first polyurethane prepolymer or a first polyurethane prepolymer emulsion, (2) a second component comprising a media phase selected from the group consisting of a second polyurethane prepolymer emulsion, a low solid content polyurethane dispersion, a seed latex, and combinations thereof; and (3) a chain extender. The ultra-high solid polyurethane dispersion has at least a solid content of at least 65 percent by weight of solid content, based on the total weight of the ultra-high solid polyurethane dispersion, and a viscosity of less than 5000 cps at 20 rpm at 21° C. using spindle #4 with Brookfield viscometer.Type: ApplicationFiled: December 19, 2007Publication date: January 8, 2009Inventors: Erdem Bedri, Debkumar Bhattacharjee, Yi Jin, Bindushree Radhakrishnan, Hermann W. Wentz
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Patent number: 7101950Abstract: The invention is an composition comprising a) one or more isocyanate functional polyether based prepolymers; b) one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of from about 45 to about 59° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more nonconductive carbon blacks; e) one or more catalysts for the reaction of isocyanates moieties with hydroxyl groups. In a preferred embodiment the composition of the invention further comprises one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of about 60 to about 90° C.Type: GrantFiled: August 19, 2004Date of Patent: September 5, 2006Assignee: Dow Global Technologies Inc.Inventors: Lirong Zhou, Daniel P. Heberer
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Patent number: 6992134Abstract: The present invention relates to a polyurethane surface and more specifically to a polyurethane surface derived from the catalyzed reaction of equivalent volumes of a polyisocyanate component and an active hydrogen component. The two-component system achieves optimal gel time and cure response for application as an athletic surface having an isocyanate index between about 105 and 115. Moreover, the present invention achieves these results with a 1:1 by volume two-component system, which minimizes mixing errors during application of the surface.Type: GrantFiled: October 29, 2002Date of Patent: January 31, 2006Inventor: Tim Croley
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Patent number: 6767959Abstract: A filler containing adhesive is described that also in the presence of large amounts of conductive fillers such as low or non-oxidized carbon black shows good antenna impedance. Said adhesive is characterized by the presence of polycarbonate prepolymers, in particular prepolymers containing a group or formula I: wherein R represents linear or branched, saturated or unsaturated aliphatic radical, a saturated or unsaturated cycloaliphatic radical, an araliphatic radical, or an aromatic radical with 3 to 10 carbon atoms, and n=1 to 8, preverably 2 to 5.Type: GrantFiled: January 2, 2002Date of Patent: July 27, 2004Assignee: Sika AG, Vorm. Kaspar Winkler & Co.Inventors: Bernhard Bosshard, Michael Schlumpf
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Publication number: 20030018124Abstract: A coating composition containing about 40-90% by weight of film forming binder and 10-60% by weight of an organic liquid carrier; wherein the binder contains aboutType: ApplicationFiled: July 9, 2001Publication date: January 23, 2003Inventors: Robert J. Barsotti, Laura Ann Lewin, Christopher Scopazzi
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Publication number: 20020198317Abstract: The present invention relates to a novel process for the production of a water soluble polymer dispersion from vinylamide monomers, and, more particularly, polymers formed from N-vinylformamide monomers.Type: ApplicationFiled: July 29, 2002Publication date: December 26, 2002Inventors: Dodd W. Fong, Manian Ramesh, Anthony G. Sommese
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Patent number: 6420493Abstract: A two component chemically thermoset composite resin matrix for use in composite manufacturing processes includes a solvent free polyisocyanate component and a solvent free polyol component. The solvent free polyisocyanate component is either an aromatic polyisocyanate, an aliphatic polyiscyanate or a blend of both. The solvent free polyol component is either a polyether polyol, a polyester polyol or a blend of both. The polyisocyanate component and the polyol component are in relative proportions in accordance with an OH/NCO equivalent ratio of 1:1 to 1:2. The components form a relatively low cost polyurethane composite resin having a useful range of physical properties, without the emission of volatile organic compounds during curing.Type: GrantFiled: June 26, 2000Date of Patent: July 16, 2002Assignee: Resin Systems Inc.Inventors: Gail Ryckis-Kite, David Slaback
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Patent number: 6365679Abstract: A two component polyurethane clear coat for use with golf balls includes a polyol component and a polyisocyanate component. The polyol component includes a polyester polyol resin containing a neopentyl glycol resin. A mixture of silane and aziridine is also preferably included in the polyol component. The polyisocynanate component includes a mixture of an isocyanate trimer of hexamethylene diisocyanate and a biuret of hexamethylene diisocyanate. The polyol and polyisocyanate components preferably include two solvents forming a blend selected from the group of ethyl acetate, butyl acetate, propyleneglycolmonomethylether acetate, toluene and xylene. The coating may be applied directly to golf ball covers with a variety of chemistries without the need of a primer or basecoat. The clear coat provides superior adhesion and abrasion resistance in addition to improving the drying and curing characteristics.Type: GrantFiled: February 1, 2000Date of Patent: April 2, 2002Assignee: Callaway Golf CompanyInventors: Steven C. Crast, Ramon B. Dineros, Michael G. Lucero
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Publication number: 20010003717Abstract: The present invention provides a coating material for a golf ball. The coating material comprises a polyol(1) containing a urethane polyol and a polyisocyanate. The urethane polyol is produced by the reaction between a diisocyanate and a polyol(2) containing as an essential ingredient a diol and a triol at the triol/diol equivalent ratio of 0.2 to 3. The urethane polyol has Mw of 4000 to less than 10000. The coating material is dryable in a short time at low temperatures and forms a coating layer having excellent resistance to scuffing and adhesion to a golf ball main body.Type: ApplicationFiled: July 23, 1999Publication date: June 14, 2001Inventors: KIYOTO MARUOKA, AKIHIRO NAKAHARA
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Patent number: 6177508Abstract: A composition suitable for slush molding is disclosed. The composition comprises a thermoplastic polyurethane elastomer (A) having a number average molecular weight of 10,000 to 50,000, a glass transition point of not higher than −35° C. and a heat softening initiation temperature of 100 to 160° C.; a plasticizer (B); a blocked polyisocyanate (C); a pigment (D); and a blocking inhibitor (E) comprising a resin powder which is not heat-softened even at 160° C. and has an average particle diameter of not more than 10 &mgr;m. The composition has a wide mold temperature range, and provides a molded article excellent in properties at low temperature, anti-fogging, thermal aging resistance and light aging resistance.Type: GrantFiled: July 2, 1999Date of Patent: January 23, 2001Assignees: Sanyo Chemical Industries, Ltd., Toyota Jidosha Kabushiki KaishaInventors: Hideki Ohmori, Yoshitsugu Takai, Junzo Ukai, Hideo Nishimura, Kazuo Kobayashi
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Patent number: 6160076Abstract: The present invention relates to a composition being an aqueous dispersion of a polyurethane in water, said composition comprising water and the reaction product of (a) a water-dispersible isocyanate-terminated polyurethane prepolymer having an NCO content of between 2.1 and 10% by weight, (b) an organic polyisocyanate adduct mixture comprising a polyisocyanate dimer and a polyisocyanate trimer and having an average isocyanate functionality of between 2.1 and 4.0, and (c) an amine chain extender having a specified ratio of NH2 relative to the NCO index of the polyisocyanate adduct mixture. Also disclosed is a process for preparing this composition, and a method for coating a substrate with the composition.Type: GrantFiled: January 23, 1995Date of Patent: December 12, 2000Assignee: ARCO Chemical Technology, L. P.Inventors: John W. Reisch, Richard J. Feegel, Curtis P. Smith
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Patent number: 6090906Abstract: There are provided a polycarbodiimide copolymer having a main structure represented by the following formula (1): ##STR1## wherein R.sub.1 is an isocyanate residue; R.sub.2 is a polyfunctional liquid rubber residue; X is a urethane bond, an amide bond or a urea bond; p is an integer of 5 to 50; q is an integer of 1 to 5; and r is 0 or 1; and a process for producing the above polycarbodiimide copolymer, which comprises reacting a polyfunctional liquid rubber with an organic diisocyanate in excess of the rubber and then subjecting the diisocyanate components in the reaction system to carbodiimization using a carbodiimidization catalyst. The polycarbodiimide copolymer alleviates the problems of the prior art, has the excellent heat resistance inherently possessed by polycarbodiimide resins, is improved, as compared with conventional polycarbodiimide resins, in thermoformability under heating and pressure when made into a solid such as a powder or granules, and causes no blistering under heating.Type: GrantFiled: March 16, 1999Date of Patent: July 18, 2000Assignee: Nisshinbo Industries, Inc.Inventors: Satoshi Amano, Norimasa Nakamura
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Patent number: 6018012Abstract: A two component polyurethane top coat for use with golf balls includes a polyol component and a polyisocyanate component. The polyol component includes a polyester polyol resin containing a neopentyl glycol resin. A mixture of silane and aziridine is also preferably included in the polyol component. The polyisocyanate component includes a mixture of an isocyanate trimer of toluene diisocyanate (TDI) and a biuret of hexamethylene diisocyanate (HDI). The polyol and polyisocyanate components preferably include a two solvents forming a blend selected from the group consisting of ethyl acetate, butyl acetate, propyleneglycolmonomethylether acetate, toluene, or xylene. The coating can be applied directly to golf ball covers with a variety of chemistries without the need of a primer or basecoat. The top coat provides superior adhesion and abrasion resistance in addition to improving the drying and curing characteristics.Type: GrantFiled: July 20, 1998Date of Patent: January 25, 2000Assignee: Callaway Golf CompanyInventors: Steven C. Crast, Ramon Buella Dineros
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Patent number: 5894071Abstract: Two-component adhesive-, sealing- or coating compositions are being described which are separately packed, and comprise the component A and the component D, whereby the component A is curing as soon as it gets in touch with water or the component D which contains the curing agent for the component A.The component D can be, or a component B containing an ingredient which is curing at the contact of water, or, possibly, at the contact with the component A, orthe component D can also be a mixture of solid matter and a volatile ingredient which is causing the cross-linking of the component A.The advantage of the novel two-component systems is that the component D is working as a curing agent for the component A, however, a surplus thereof is, or self-curing, or it does not leave a nuissance residue in the cured composition.Type: GrantFiled: December 6, 1996Date of Patent: April 13, 1999Assignee: Sika AG, vorm. Kaspar Winkler & Co.Inventors: Peter Merz, Norman E. Blank, Hans-Peter Tschan, Reinhard Ernst Wappmann, Lutz Zabel
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Patent number: 5693696Abstract: A modified polyurethane structionally incorporating filler having active hydrogen groups on a surface thereof into a polyurethane polymer. The filler is first fluidized with a polyol and then reacted with a linking component having an organo reactive group that is reactive with an isocyanate. Polyisocyanate and additional polyol are added to the reaction mixture such that the isocyanate reacts with the linking component and the polyol to form a polymer wherein the filler is an integral unit in the polymer. The resultant modified polyurethane has good dynamic properties and is surprisingly resilient. Preferred fillers are sand, clay talc and mixtures thereof.Type: GrantFiled: January 16, 1996Date of Patent: December 2, 1997Assignee: MCP Industries, Inc.Inventors: Thomas M. Garrett, Indulis Gruzins
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Patent number: 5661216Abstract: A coating composition based on amines, aldimines and isocyanates which forms a polyurea coating or film. These coating compositions are especially useful in the automotive refinish industry due to the cure rate at ambient conditions. The coatings of these compositions can be useful for obtaining low VOC (Volatile Organic Content) levels.Type: GrantFiled: July 31, 1995Date of Patent: August 26, 1997Assignee: BASF CorporationInventors: Thomas J. Laginess, Sudhakar Dantiki, Brian P. Koevenig, Rajnikant P. Shah
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Patent number: 5521247Abstract: Aqueous coating agent including a water-dilutable mixture of binding agents ofI. 50 to 88 wt. % of a neutralised water-soluble reaction product including(A) 10 to 80 wt. % of a polyurethane resin with an acid number of 70 to 160, at least one terminal blocked isocyanate group devoid of free hydroxyl groups and fatty acid residues with more than 12 C-atoms and with a limiting viscosity number of 6.5 to 12.0 ml/g, measured in DMF at 20.degree. C., and(B) 20 to 90 wt. % of a polyester resin with an OH-number of 50 to 500, an acid number of less than 20, a limiting viscosity number of 8.0 to 13.0 ml/g, measured in DMF at 20.degree. C., with the reaction product having a limiting viscosity number of 13.5 to 18.0 ml/g measured in DMF at 20.degree. C.II. 10 to 40 wt. % of one or several blocked polyisocyanates not capable of being diluted with water, andIII. 2 to 30 wt. % of at least one amine resin by way of additional cross-linking agent.Type: GrantFiled: December 29, 1993Date of Patent: May 28, 1996Assignee: Herberts G.m.b.HInventors: Klaus Dobler, Michael Georgiadis, Wolfgang Goldner, Knut Graf
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Patent number: 5484832Abstract: A modified polyurethane structionally incorporating silica into a polyurethane polymer. The silica is first fluidized with a polyol and then reacted with a linking component having an organo reactive group that is reactive with an isocyanate. Polyisocyanate and additional polyol are added to the reaction mixture such that the isocyanate reacts with the linking component and the polyol to form a polymer wherein the silica is an integral unit in the polymer. The resultant modified polyurethane has good dynamic properties and is surprisingly resilient.Type: GrantFiled: December 14, 1993Date of Patent: January 16, 1996Assignee: MCP Industries, Inc.Inventors: Thomas M. Garrett, Indulis Gruzins
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Patent number: 5444117Abstract: The present invention relates to a coating composition having an improved pot life without a corresponding increase in dry time when cured under ambient conditions which containsa) a polyisocyanate component,b) an aldimine based on the reaction product of a polyamine having 2 or more primary amino groups with an aldehyde corresponding to the formula:O.dbd.CHCH(R.sub.1)(R.sub.2)wherein R.sub.1 and R.sub.2 may be the same or different and represent optionally substituted hydrocarbon radicals, or R.sub.1 and R.sub.2 together with the .beta.-carbon atom form a cycloaliphatic or heterocyclic ring andc) 0.1 to 15 weight percent, based on the total weight of the coating composition, of a water-adsorbing zeolite,wherein components a) and b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups to aldimine groups of 0.5:1 to 20:1.Type: GrantFiled: February 9, 1994Date of Patent: August 22, 1995Assignee: Bayer CorporationInventors: Robert A. Wade, Terrell D. Wayt
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Patent number: 5387644Abstract: A hardenable monomer composition useful for flooring composition, grouts, mortars and the like comprises a mixture of crosslinkable acrylic monomer, carbon black and/or polyester- or polyether-methane oligomer having at least two polymerizable double bonds and a paraffin oil.The monomer is preferably of the formula I ##STR1## and there is preferably present other monomers, particularly hydroxypropyl methacrylate.Type: GrantFiled: December 14, 1993Date of Patent: February 7, 1995Assignee: Sandoz Ltd.Inventor: Karoly Discho
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Patent number: 5331044Abstract: The present invention deals with low temperature impact resistant, easily flowing, thermoplastic polyurethane elastomer compositions, comprising:A) 5-95 parts by weight of at least one thermoplastic polyurethane elastomer (A) having a Shore A hardness less hah 95; andB) 95-5 parts by weight of at least one thermoplastic polyurethane elastomer (B) having a Shore A hardness greater than 98, whereby the parts by weight of (A) and (B) total 100 parts by weight; andC) 0-60 weight percent based on the weight of (A) and (B) of a reinforcing filler.The products are prepared by melting together polyurethane elastomers (A) and (B) at temperatures of from 140.degree.-250.degree. C., preferably in an extruder, and are most preferred for the preparation of ski boots and injection molded articles for motor vehicles.Type: GrantFiled: February 7, 1990Date of Patent: July 19, 1994Assignee: BASF AktiengesellschaftInventors: Deitrich Lausberg, Rolf Steinberger, Walter Heckmann, Harald Schulz
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Patent number: 5288797Abstract: A one-part moisture curable polyurethane adhesive composition comprises a blend of polyurethane prepolymers and one or more additives which unexpectedly improve the sag resistance and mechanical properties of the formulation. The final adhesive composition retains good stability in the absence of moisture for an extended period between manufacture and application of the adhesive, and has a relatively rapid and consistent cure rate in the presence of atmospheric moisture. The final cured composition exhibits good mechanical properties and generally is unaffected by ambient application and cure conditions.Type: GrantFiled: March 19, 1993Date of Patent: February 22, 1994Assignee: Tremco Ltd.Inventors: Hamdy Khalil, Witek Majewski, George Nickel, George Wypych, Jeffrey D. van Heumen
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Patent number: 5210127Abstract: Novel powders useful in the slush molding process are produced by reacting an emulsion of either an isocyanate or an isocyanate reactive material with either an isocyanate reactive material or an isocyanate, depending upon the nature of the component used to make the emulsion in the presence of an at least partially blocked isocyanate and an organic carrier. The final reaction product is subsequently removed from the carrier.Type: GrantFiled: October 21, 1992Date of Patent: May 11, 1993Assignees: Bayer Aktiengesellschaft, Miles Inc.Inventors: Joachim Werner, Walter Meckel, Ulrich Liman, Dirk Wegener, Werner Rasshofer, James W. Rosthauser
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Patent number: 5187225Abstract: The sealant compound of this invention comprises polyurethane resin or its precursor mixed with vapor grown carbon fiber. In the compound, whisker-shaped carbon fibers with high tensile strength intertwine and form lattices. In addition, carbon fibers are anchored in the polyurethane resin. Consequently, the compound of this invention has more tensile strength than the conventional compound containing black carbon. Thus the seal consisting of the compound of this invention has high adhesion and sealing effects.Type: GrantFiled: October 27, 1989Date of Patent: February 16, 1993Assignee: Kitagawa Industries Co., Ltd.Inventor: Hiroji Kitagawa
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Patent number: 5118728Abstract: A spray polyurea elastomer is made in combination with a filler material by spraying together two reactive elastomers and dispensing filler material into the spray pattern.Type: GrantFiled: October 24, 1988Date of Patent: June 2, 1992Assignee: Texaco Chemical CompanyInventor: Dudley J. Primeaux
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Patent number: 5091444Abstract: A moisture-curing hot-melt composition comprising at least one isocyanate-terminated polyurethane prepolymer has improved sag-resistance while retaining high extrudability and is characterised in that the composition includes 1-17 wt %, preferably 3-6 wt %, of hydrophobic, siloxane-coated, fumed silica.Especially effective polyurethane hot-melt adhesive compositions are prepared containing 4-5 wt % of the hydrophobic, siloxane-coated fumed silica.Type: GrantFiled: February 12, 1990Date of Patent: February 25, 1992Assignee: Bostik, Inc.Inventors: Herbert Bauer, Heinz G. Gilch, Walter Rath, Use Schumann
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Patent number: 5011903Abstract: An encapsulating and patching elastomer for concrete repairs including a two component urethane system including a polyol reacted with a diisocyanate or a mixture of diisocyanates and a hindered amine, and an aggregate filler. The elastomer polyester filler has a hardness of over 50 on the Shore A scale. The subject invention further provides a method of making an encapsulating and patching elastomer for concrete repairs, the method including the steps of dissolving the two component urethane system with the hindered amine. The mixture is applied as a film or patch to a concrete surface. The mixture is cured at ambient temperature for 48 to 72 hours to an elastomer having a hardness of over 50 on the Shore A scale.Type: GrantFiled: January 7, 1988Date of Patent: April 30, 1991Assignee: Peterson Elastomers, Inc.Inventors: Frank M. Lymburner, Charles M. Peterson
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Patent number: 5010133Abstract: A high pressure method of molding polyurethane articles is described. A polyurethane material is formed from a cross-linkable polymer comprising the reaction product of a polyol and polyisocyanate, said polymer containing a high activation temperature catalyst and a high surface area filler. The material is processed to a gum state suitable for high pressure molding. The material and process are particularly suitable for forming small, intricately shaped articles. Such articles are also described.Type: GrantFiled: September 29, 1989Date of Patent: April 23, 1991Inventor: Alan R. Seville
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Patent number: 4906722Abstract: Thermosetting reactive systems, comprising(a) at least one epoxide resin,(b) at least one isocyanate resin,(c) a reaction accelerator of the formula I ##STR1## in which R.sup.1 is --(CR.sup.4 R.sup.5).sub.n - with n=2-24, phenylene or naphthylene which is unsubstituted or mono- or poly-substituted by halogen, nitro, C.sub.1 -C.sub.4 -alkyl, C.sub.1-C.sub.4 alkoxy or C.sub.3 -C.sub.8 dialkylaminoalkyl, or a radical of the formulae ##STR2## R.sup.2 and R.sup.3 independently of one another are C.sub.1-C.sub.12 alkyl, phenyl or naphthyl which are unsubstituted or mono- or poly-substituted by halogen, nitro, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.1 -C.sub.4 alkoxy, or also C.sub.7 -C.sub.13 aralkyl, or in which R.sup.2 and R.sup.3, together with the N atom to which they are linked, form a 5-membered, 6-membered or 7-membered heterocyclic ring, and R.sup.4 and R.sup.5 independently of one another are hydrogen or C.sub.1 -C.sub.Type: GrantFiled: November 21, 1988Date of Patent: March 6, 1990Assignee: Ciba-Geigy CorporationInventors: Sameer H. Eldin, Alfred Renner
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Patent number: 4812356Abstract: A one-component coating composition of35 to 60 wt.-% isocyanate prepolymer8 to 15 wt.-% plasticizer0.3 to 2 wt.-% antisettling agent2 to 10 wt.-% flaky extender5 to 25 wt.-% colorant pigments1 to 3 wt.-% moisture-binding agent, and10 to 20 wt.-% aliphatic estersprovides, on a flexible substrate such as artifical leather, plastic film, paper, roofing felt, polyurethane hard and soft foams, metal foils, concrete and the like, an extraordinarily elastic, tightly adherent coating film of high covering power and light resistance. Furthermore, it has good resistance to abrasion and to weathering, even to aggressive media such as sea water and chemicals.Type: GrantFiled: March 11, 1987Date of Patent: March 14, 1989Assignees: BGB-Gesellschaft Reinmar John, Rainer-Leo Meyer, Meyer geb. KlofferInventors: Rainer-Leo Meyer, Reinmar John, Rolf Nagel, Gunter Muller