With Two Or More Alcohol Hydroxyl Compounds Patents (Class 524/875)
  • Patent number: 5629402
    Abstract: This invention relates to coating compositions containing (A) a polyurethane system containing either a polyurethane containing ionic groups and polyethylene oxide units or a precursor thereof prepared from a blocked isocyanate prepolymer and a cross-linking agent and, optionally, (B) organic solvents. This invention further relates to the use of such coating compositions to prepare coatings that are permeable to water vapor.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: May 13, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Josef Pedain, Detlef-Ingo Schutze, Wilhelm Thoma, Klaus Nachtkamp
  • Patent number: 5621043
    Abstract: An elastomer composition, resistant to hydrocarbon fluid and water absorption, comprisinga) an isocyanate reactive component comprising a polypropylene ether polyol containing from about 5 percent to about 60 percent of a dispersion comprising a condensation or addition polymer,b) from about 5 percent to about 35 percent of an epoxy resin, andc) a polyurethane formed from said polypropylene ether polyol, having active hydrogen atoms and at least one isocyanate component in the presence of said dispersion and said epoxy resin,said polyurethane having an isocyanate index of less than 100, said elastomer composition exhibiting less than about 20 percent weight gain after being immersed in kerosene for 24 hours at 38.degree. C.
    Type: Grant
    Filed: August 2, 1995
    Date of Patent: April 15, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Thomas S. Croft
  • Patent number: 5614575
    Abstract: A sprayable polyurethane composition containing an isocyanate component and a polyol component is provided, wherein the polyol component includes a polyether polyol amine; a nitrogen-free hydoxy-terminated polyether; and a sucrose-polyether polyol. Preferably, these two components are combined while spraying them individually into a mold along with a fibrous-reinforcing material.
    Type: Grant
    Filed: April 24, 1995
    Date of Patent: March 25, 1997
    Assignee: RPG. Inc.
    Inventor: Rex R. Kotschwar
  • Patent number: 5563206
    Abstract: Aqueous polyurethane dispersions prepared in several stages by reactingA) aliphatic and/or aromatic di- and/or tri-isocyanates withB1) polyol mixtures containing dimer diols of 25 to 100% by weight of dimer diols and 0 to 75% by weight of other hydrophobic diols and/or polyols, the equivalent ratio of OH to NCO being 1:1.1 to 1:4, and simultaneously or subsequently withB2) chain-extending agents containing two terminal NCO-reactive groups, the chain-extending agents additionally containing either artionic or cationic groups or groups convertible into anionic or cationic groups by neutralization, the equivalent ratio of NCO-reactive groups to NCO groups theoretically still present after the reaction of A) with B1) being 1:0.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: October 8, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ulrich Eicken, Alfred Westfechtel, Rainer Hoefer, Roland Gruetzmacher
  • Patent number: 5521247
    Abstract: Aqueous coating agent including a water-dilutable mixture of binding agents ofI. 50 to 88 wt. % of a neutralised water-soluble reaction product including(A) 10 to 80 wt. % of a polyurethane resin with an acid number of 70 to 160, at least one terminal blocked isocyanate group devoid of free hydroxyl groups and fatty acid residues with more than 12 C-atoms and with a limiting viscosity number of 6.5 to 12.0 ml/g, measured in DMF at 20.degree. C., and(B) 20 to 90 wt. % of a polyester resin with an OH-number of 50 to 500, an acid number of less than 20, a limiting viscosity number of 8.0 to 13.0 ml/g, measured in DMF at 20.degree. C., with the reaction product having a limiting viscosity number of 13.5 to 18.0 ml/g measured in DMF at 20.degree. C.II. 10 to 40 wt. % of one or several blocked polyisocyanates not capable of being diluted with water, andIII. 2 to 30 wt. % of at least one amine resin by way of additional cross-linking agent.
    Type: Grant
    Filed: December 29, 1993
    Date of Patent: May 28, 1996
    Assignee: Herberts G.m.b.H
    Inventors: Klaus Dobler, Michael Georgiadis, Wolfgang Goldner, Knut Graf
  • Patent number: 5506328
    Abstract: This invention relates to a process for coating a substrate comprising contacting the substrate with a low volatile organics, moisture curable, two-component coating composition comprising an admixture of an A-side and a B-side, said A-side comprising an aliphatic polyisocyanate having an isocyanate index relative to the number of isocyanate-reactive groups in said coating composition of at least about 200, preferably at least about 300, more preferably at least about 500, said B-side comprising a tertiary amine catalyst and optionally an isocyanate-reactive compound selected from the group consisting of monoahls, polyols, imines, oxazolidines, and combinations thereof, said coating composition optionally containing a solvent in an amount of less than about 45%, based upon the weight of the polyisocyanate in said coating composition, said coating composition having a viscosity as measured by ZAHN cup 2 of less than about 200 seconds, said composition being essentially free of any volatile mono- and di-isocyan
    Type: Grant
    Filed: May 24, 1993
    Date of Patent: April 9, 1996
    Assignee: Olin Corporation
    Inventors: Kiran B. Chandalia, Michael J. Morgan, James M. O'Connor, Stephen L. Goldstein
  • Patent number: 5455294
    Abstract: The present invention concerns a new, unconventional, mold-binding, water solidified polyurethane cast to be used in orthopedic departments for the correction of deformities, fixation of fractured limbs and joints, and mollification of affected parts, as well as the method of its preparation. The chief constituent, a polyurethane prepolymer, contains a stabilizer that can prolong appreciably the storage period of the cast material, maleic anhydride, and a mixed catalyst for control of hardening time, bis(2-morpholinoethoxy)ethane and anhydrous potassium carbonate.
    Type: Grant
    Filed: August 13, 1993
    Date of Patent: October 3, 1995
    Assignees: Wang Jian Zhang, Li Hai Sheng
    Inventor: Li H. Sheng
  • Patent number: 5422414
    Abstract: This invention relates to a polyurea-imide RIM composition, molded articles of a polyurea-imide RIM composition, and a method of forming a polyurea-imide molded article.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: June 6, 1995
    Assignee: ECP Enichem Polimeri Netherlands B.V.
    Inventor: Stuart B. Smith
  • Patent number: 5391614
    Abstract: This invention relates to a process for coating a substrate which comprises contacting the substrate with a low volatility organic (so-called "low VOC") coating composition having a viscosity as measured by ZAHN cup 2 of less than about 200 seconds and consisting essentially of at least one polyisocyanate prepolymer which is the reaction product of a polyisocyanate with an active hydrogen-containing compound selected from the group consisting of monoahls, polyols, imines, oxazolidines, and combinations thereof, a solvent in an amount of between 0% and 45% by weight based upon the amount of said polyisocyanate in said composition, and a tertiary amine catalyst, said composition being essentially free of any volatile mono- and di-isocyanates, and said composition being moisture curable upon exposure to atmospheric moisture. Also claimed is the coating composition itself.
    Type: Grant
    Filed: July 14, 1994
    Date of Patent: February 21, 1995
    Assignee: Olin Corporation
    Inventors: Kiran B. Chandalia, Michael J. Morgan, Michael M. Martinez, James M. O'Connor, Stephen P. Noe
  • Patent number: 5334673
    Abstract: The golf ball is made from a composition of a polyurethane prepolymer and a slow-reacting polyamine curing agent and/or a difunctional glycol. The slow-reacting polyamine curing agents and difunctional glycols are 3,5-dimethylthio-2,4-toluenediamine; 3,5-dimethylthio-2,6-toluenediamine; N,N'-dialkyldiamino diphenyl methane; trimethyleneglycol-di-p-aminobenzoate; polytetramethyleneoxide-di-p-aminobenzoate; 1,4-butanediol; 2,3-butanediol; 2,3-dimethyl-2,3-butanediol; ethylene glycol; and mixtures thereof.
    Type: Grant
    Filed: December 24, 1991
    Date of Patent: August 2, 1994
    Assignee: Acushnet Co.
    Inventor: Shenshen Wu
  • Patent number: 5326820
    Abstract: The present invention relates to coating agents based on hydroxyl-containing binders and isocyanate-containing crosslinking agents, in which coating agentsI.) the binder comprisesA1) 5 to 80% by weight of at least one polyester or one alkyd resin having an OH number from 0 to 200 mg of KOH/g and an acid number from 0 to 200 mg of KOH/g,A2) 95 to 20% by weight of at least one polyacrylate having an OH number from 30 to 250 mg of KOH/g and an acid number from 0 to 50 mg of KOH/g,the sum of the weight proportions of components (A1) and (A2) being in each case 100% by weight, andII.) the binder is obtainable from1.) at least one polycondensation resin whose acid component comprises 5 to 100 mol % of cycloaliphatic polycarboxylic acids and/or esterifiable derivatives thereof,2.) at least one polyacrylate, at least some of which has been prepared in the presence of the polycondensation resin obtained in the first process step and3.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: July 5, 1994
    Assignee: BASF Lacke+Farben Aktiengesellschaft
    Inventors: Peter Hoffmann, Werner-Alfons Jung, Michael Brunnemann
  • Patent number: 5286831
    Abstract: The present invention directed to an at least substantially pore-free polyurethane prepared by reacting at least one polyisocyanate and a component containing a partial carboxylic acid ester which is the reaction product of a carboxylic acid and an at least trihydric alcohol in quantities such that at least one of the hydroxyl groups of said alcohol is not esterified.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: February 15, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Bernhard Hess, Klaus Prater, Heinrich Heine, Joachim Franke, Hans-Dieter Jakob
  • Patent number: 5278223
    Abstract: The invention relates to optionally solventless two-component polyurethane surfacers containing finely divided fillers in a high pigment volume concentration based on a polyfunctional isocyanate component (B) and a polyol component (A) which is liquid at room temperature and which consists of mixture components containing isocyanate-reactive hydroxyl groups with an at least predominant content of branched-chain polyols (A1) containing ester and ether groups, which contains at least a proportion of the finely divided fillers and, optionally, the additives and which, for application, is mixed with the isocyanate component (B) and applied as a mixture which can still be processed by shaping.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: January 11, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernhard Gruenewaelder, Bernhard Parent, Hermann Kluth, Juergen Wegner, Werner Haller
  • Patent number: 5210127
    Abstract: Novel powders useful in the slush molding process are produced by reacting an emulsion of either an isocyanate or an isocyanate reactive material with either an isocyanate reactive material or an isocyanate, depending upon the nature of the component used to make the emulsion in the presence of an at least partially blocked isocyanate and an organic carrier. The final reaction product is subsequently removed from the carrier.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: May 11, 1993
    Assignees: Bayer Aktiengesellschaft, Miles Inc.
    Inventors: Joachim Werner, Walter Meckel, Ulrich Liman, Dirk Wegener, Werner Rasshofer, James W. Rosthauser
  • Patent number: 5194487
    Abstract: The present invention relates to a two-component, aqueous polyurethane coating composition which may be cured at ambient temperature and which containsI) an isocyanate-reactive component containingA) aqueously dispersed polyurethane wherein the polyurethane hasa) an average hydroxy functionality of at least 1.8,b) a total content of urethane andurea groups, calculated as --NH--CO--, of 9 to 20% by weight, based on the weight of the polyurethane,c) sufficient chemically incorporated anionic groups andd) ethylene oxide units incorporated within terminal and/or lateral polyether chainsto maintain the polyurethane stably dispersed in water, andB) 5 to 20%, based on the weight of components I and II, of a polyol which has a molecular weight of 62 to 1000 and may contain ether groups andII) a water dispersible polyisocyanate havinga) an isocyanate content of 2 to 30% by weight, based on the weight of the polyisocyanate,b) an average functionality of at least 1.
    Type: Grant
    Filed: August 14, 1992
    Date of Patent: March 16, 1993
    Assignee: Miles Inc.
    Inventor: Patricia B. Jacobs
  • Patent number: 5187225
    Abstract: The sealant compound of this invention comprises polyurethane resin or its precursor mixed with vapor grown carbon fiber. In the compound, whisker-shaped carbon fibers with high tensile strength intertwine and form lattices. In addition, carbon fibers are anchored in the polyurethane resin. Consequently, the compound of this invention has more tensile strength than the conventional compound containing black carbon. Thus the seal consisting of the compound of this invention has high adhesion and sealing effects.
    Type: Grant
    Filed: October 27, 1989
    Date of Patent: February 16, 1993
    Assignee: Kitagawa Industries Co., Ltd.
    Inventor: Hiroji Kitagawa
  • Patent number: 5118728
    Abstract: A spray polyurea elastomer is made in combination with a filler material by spraying together two reactive elastomers and dispensing filler material into the spray pattern.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: June 2, 1992
    Assignee: Texaco Chemical Company
    Inventor: Dudley J. Primeaux
  • Patent number: 5091444
    Abstract: A moisture-curing hot-melt composition comprising at least one isocyanate-terminated polyurethane prepolymer has improved sag-resistance while retaining high extrudability and is characterised in that the composition includes 1-17 wt %, preferably 3-6 wt %, of hydrophobic, siloxane-coated, fumed silica.Especially effective polyurethane hot-melt adhesive compositions are prepared containing 4-5 wt % of the hydrophobic, siloxane-coated fumed silica.
    Type: Grant
    Filed: February 12, 1990
    Date of Patent: February 25, 1992
    Assignee: Bostik, Inc.
    Inventors: Herbert Bauer, Heinz G. Gilch, Walter Rath, Use Schumann
  • Patent number: 5045590
    Abstract: Disclosed is a construction material containing bitumen comprising (A) a polyol component, the polyol component consisting essentially of (a-1) a hydroxy-polyoxyalkylene ether of bisphenol A and/or bisphenol F, and (a-2) an aliphatic polyol, (B) a polyisocyanate component, (C) a bitumen, and/or (D) an aggregate. The construction material has improved water-proof and mechanical properties.
    Type: Grant
    Filed: July 19, 1989
    Date of Patent: September 3, 1991
    Assignee: Dainippon Ink and Chemicals
    Inventors: Masatoshi Motomura, Ichiro Muramatsu, Noboru Okoshi, Yoshitami Araki, Takahiko Ito, Toru Sato
  • Patent number: 5041467
    Abstract: This invention relates to a method of producing particulate polymers. This production method is characterized in that a mixture of an isocyanate compound containing two or more isocyanato groups per molecule and a surfactant containing two or more hydroxyl groups per molecule is emulsified and allowed to cure in a dispersing medium which does not dissolve the isocyanate compound without use of a protective colloid. According to the production method of the invention, there occurs no aggregation of polymer particles during and after the curing reaction.
    Type: Grant
    Filed: September 4, 1990
    Date of Patent: August 20, 1991
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Hironori Kataoka, Kazuhito Jinno, Tokiko Yamashita
  • Patent number: 5036118
    Abstract: Molded polyurethanes and/or polyureas are filled with a mica filler having a thickness of less than about 1.5 micrometer and an aspect ratio of greater than about 40. The surfaces of these compositions exhibit a distinctness of image when painted that is within about 10 DOI units of the distinctness of image of similarly painted steel. The compositions also exhibit improved physical properties.
    Type: Grant
    Filed: May 23, 1990
    Date of Patent: July 30, 1991
    Assignee: The Dow Chemical Company
    Inventor: Eloy C. Martinez
  • Patent number: 5032627
    Abstract: An in situ polymerized thermplastic resin incorporating hollow glass spheres, which are incorporated during polymerization of the resin, and a method of making a concentrate of hollow glass spheres dispersed in a thermoplastic resin with minimal sphere fracture by adding the spheres during polymerization of the resin.
    Type: Grant
    Filed: March 31, 1989
    Date of Patent: July 16, 1991
    Assignee: The B. F. Goodrich Company
    Inventors: Gary F. Wilson, Yona Eckstein
  • Patent number: 5010133
    Abstract: A high pressure method of molding polyurethane articles is described. A polyurethane material is formed from a cross-linkable polymer comprising the reaction product of a polyol and polyisocyanate, said polymer containing a high activation temperature catalyst and a high surface area filler. The material is processed to a gum state suitable for high pressure molding. The material and process are particularly suitable for forming small, intricately shaped articles. Such articles are also described.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: April 23, 1991
    Inventor: Alan R. Seville
  • Patent number: 4985491
    Abstract: This invention relates to a method of fabricating a polyurethane sealant composition employing a polyether triol having a molecular weight of between about 5,000 and about 30,000 and having a level of end group unsaturation of no greater than 0.04 milliequivalents per gram of triol, wherein the triol is fabricated in the presence of a double metal cyanide catalyst. The triol is reacted, alone or in admixture with a diol, with a polyisocyanate to produce an isocyanate-terminated prepolymer. The prepolymer is then chain-extended to produce the desired sealant.
    Type: Grant
    Filed: October 5, 1989
    Date of Patent: January 15, 1991
    Assignee: Olin Corporation
    Inventor: John W. Reisch
  • Patent number: 4985490
    Abstract: The present invention is directed to a process for the direct production of a pigmented thermoplastic polyurethane powder in finely divided form by(a) reacting with agitation at an overall equivalent ratio of isocyanate groups to isocyanate reactive groups of about 0.5 to 1.1(i) a surfactant-stabilized emulsion of fine droplets of a first reactant which has an average of about two isocyanate or isocyanate reactive groups in admixture with at least one pigment with(ii) a second reactant which contain an average of about two isocyanate or isocyanate reactive groups,in an inert organic liquid in which the first reactant, the pigment and the powder are substantially insoluble or immiscible to form particles of the powder which are protected from agglomeration by the surfactant, and(b) separating the particles of the powder from the inert organic liquid.The present invention is also directed to the pigmented thermoplastic polyurethane powders obtained by this process.
    Type: Grant
    Filed: April 12, 1989
    Date of Patent: January 15, 1991
    Assignees: Bayer Aktiengesellschaft, Mobay Corporation
    Inventors: James W. Rosthauser, Walter Meckel, Werner Rasshofer
  • Patent number: 4956439
    Abstract: Modified polyurethane products, exhibiting good physical strength and excellent heat resistance, and especially improved heat sag properties, are prepared by blending a polyol component containing at least 1% of at least one polynuclear aromatic polyol or a derivative thereof, or a mononuclear diol or a derivative thereof, at a temperature of 100.degree.-180.degree. C., to form a first liquid component; admixing the first liquid component with a second liquid component containing a diisocyanate or polyisocyanate, one of the two liquid components containing a catalyst; and reacting and molding the admixture in a mold kept at a temperature of from 80.degree.-140.degree. C. by reaction injection molding.
    Type: Grant
    Filed: September 8, 1989
    Date of Patent: September 11, 1990
    Inventors: Shen-Nan Tong, Shih-Jung Tsai, Jyi-Shang Lii
  • Patent number: 4906673
    Abstract: A composition capable of providing a polyurethane resin having an improved lipophilic property which comprises an organic polyisocyanate compound, and a polyol component containing a polyether polyol having at least 10% by weight of units of an alkylene oxide having 6 or more carbon atoms, the polyether polyol having an excellent compatibility with an aliphatic hydrocarbon compound or with a hydroxy-terminated diene polymer, its hydrogenation product and a hydroxy-terminated olefin polymer.
    Type: Grant
    Filed: June 17, 1988
    Date of Patent: March 6, 1990
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Shigeo Mori, Chuzo Isoda
  • Patent number: 4900776
    Abstract: A plywood-patching composition is provided based on a noncellular polyurethane elastomer prepared by reacting a polyether or polyester polyol with a polyisocyanate in the presence of a catalytic amount of a substantially anhydrous potassium salt of a carboxylic acid having from 2 to about 20 carbon atoms, and process for preparing same. The catalysts utilized are relatively non-toxic, yet they promote rapid polymerization with essentially no foaming for a wide variety of non-cellular polyurethane elastomeric applications, particularly in plywood-patch applications where even small amounts of foaming is deleterious to the properties thereof.
    Type: Grant
    Filed: December 1, 1988
    Date of Patent: February 13, 1990
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Frank Bock, Mahfooz Ahmad, Frederick C. Dupre, Jr.
  • Patent number: 4896598
    Abstract: A process for printing an image on the surface of an article. The process provides a thixotropic thermal curable ink in a recess of a printing plate which is a facsimile of the image to be printed on the article. The ink is adapted to adhere to the printing plate upon contact therewith. The ink is adapted to conform to the facsimile of the image formed in the recess of said printing plate upon application stress to the ink.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: January 30, 1990
    Assignee: Automated Industrial Systems
    Inventor: Charles S. Leech, Jr.
  • Patent number: 4863994
    Abstract: Disclosed are novel active hydrogen compositions comprising: (1) a polymeric polyol; (2) a low equivalent weight cross-linking polyol; (3) optionally a second polyol having an equivalent weight up to about 500; and (4) a sufficient amount of a monohydric alcohol of equivalent weight up to about 1,500 to provide a monophase low viscosity blend.Also disclosed are the molded polyurethanes produced from the above compositions, and, particularly high strength mat molded reaction injection molded parts.
    Type: Grant
    Filed: June 24, 1988
    Date of Patent: September 5, 1989
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Nelson, Douglas P. Waszeciak
  • Patent number: 4857364
    Abstract: The intumescent compositions according to the invention are reaction mixtures which are obtained on mixing and reacting the following components:(A) specific polyether polyols,(B) specific polyester polyols,(C) specific phosphorus-containing polyols,(D) inert desiccants,(E) dehydratable fillers,(F) other inorganic auxiliaries and fillers,(G) catalysts and(H) polyisocyanates.
    Type: Grant
    Filed: December 14, 1987
    Date of Patent: August 15, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventor: Wulf von Bonin
  • Patent number: 4851457
    Abstract: A process for making sand cores or molds is disclosed; the completed cores and molds as well as a binder for holding the sand particles together. The resin binder is used in the process and in the finished product comprising lignin dissolved in a suitable solvent reacted on or cured with an isocyanate material. Curing can be accomplished by the use of an amine along with a catalyst if desired. A polyether polyol may be integrated with the lignin to vary the physical characteristics of the binder.
    Type: Grant
    Filed: February 16, 1988
    Date of Patent: July 25, 1989
    Inventor: Kenneth R. Kurple
  • Patent number: 4833177
    Abstract: A method for preparing polymer microparticles which are stably dispersed in a nonaqueous medium involves:(a) mixing into a nonaqueous medium a polymerizable component at least 20 percent of which is insoluble in the nonaqueous medium, said polymerizable component comprising at least one polymerizable species;(b) subjecting the mixture of (a) to stress sufficient to particulate the mixture;(c) polymerizing the polymerizable component within each particle under conditions sufficient to produce polymer microparticles stably dispersed in the nonaqueous medium, said polymer microparticles being insoluble in the nonaqueous medium and the nonaqueous medium being substantially free of dissolved polymer, said polymer microparticles further characterized in that less than 20 percent of the polymer microparticles have a mean diameter greater than 5 microns.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: May 23, 1989
    Assignee: PPG Industries, Inc.
    Inventors: Dennis L. Faler, Gregory J. McCollum, James B. O'Dwyer, Marvis E. Hartman
  • Patent number: 4816509
    Abstract: Water-swellable moisture-curing one-package polyurethane sealant which includes (1) a water-swellable polyurethane prepolymer having 1.5-10% terminal NCO group content obtained by reacting polyisocyanate with polyoxyalkylenepolyol having 50-90% of oxyethylene units based on polyalkylene chain molecular weight (2) non water-swellable polyurethane prepolymer having terminal NCO groups obtained by reacting polyisocyanate with polyoxyalkylenepolyol having 3-4 carbon atom oxyalkylene units, and (3) a filler. The sealant exhibits has been improved storage stability.
    Type: Grant
    Filed: January 29, 1986
    Date of Patent: March 28, 1989
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Takuo Fukushima, Yasumasa Hayashida, Jinichi Omi
  • Patent number: 4783502
    Abstract: A stable, nonaqueous polyurethane microparticle dispersion is characterized in that less than 20 percent of the polymer microparticles have a mean diameter greater than 5 microns, further characterized in that at a total solids content of 60 percent the Brookfield viscosity is less than 1000 centipoise measured at 50 RPM using a number 3 spindle at 25.degree. C., the polyurethane being prepared from reactants which are substantially free of acrylic polymer and the polyurethane being further characterized in that it is substantially free of unreacted polyisocyanate monomer.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: November 8, 1988
    Assignee: PPG Industries, Inc.
    Inventors: Dennis L. Faler, Gregory J. McCollum, James B. O'Dwyer, Marvis E. Hartman
  • Patent number: 4752637
    Abstract: A binder for use in the preparation of a synthetic board from cellulosic and/or lignocellulosic material comprising an organic polyisocyanate and a mixture of reactive hydrogen-containing compounds having an average of more than one reactive hydrogen atom per molecule, the mixture containing an ester and/or an amide having a hydrocarbon content sufficient to bring about enhanced board release in the board-forming process and to contribute to superior moisture resistance in the finished board.
    Type: Grant
    Filed: August 11, 1986
    Date of Patent: June 21, 1988
    Assignee: Jim Walter Research Corp.
    Inventor: Michael G. Israel
  • Patent number: 4748201
    Abstract: An aromatic, isocyanate-base, polyurethane polymer and a process for preparing the polymer. The process comprises reacting, such as by spraying onto a substrate or an open mold, a caprolactone polyol with a methylene dipara phenylene isocyanate in the presence of a catalytic amount of a metallo catalyst, and a fast-curing and cross-linking amount of a curing agent comprising a polyalkanol amine, particularly a triethanol amine, to provide a fast-reaction aliphatic poilyurethane polymer. The reaction of difunctional caprolactone polyols with low functionality MDI in the presence of a tin catalyst and triethanol amine provides for flexible and rigid polymer films of substantially no porosity.
    Type: Grant
    Filed: March 28, 1986
    Date of Patent: May 31, 1988
    Assignee: Urylon Development, Inc.
    Inventor: Stuart B. Smith
  • Patent number: 4748192
    Abstract: An aliphatic, isocyanate-base, polyurethane polymer and a process for preparing the polymer. The process comprises reacting, such as by spraying onto a substrate or an open mold, a caprolactone polyol with an aliphatic isocyanate in the presence of a catalytic amount of a metallo catalyst, and also in the presence of a fast-curing amount of a curing agent comprising an amine, particularly a triethanol amine, to provide a fast-reaction aliphatic urethane polymer which is a clear, easily color-pigmented polymer.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: May 31, 1988
    Assignee: Urylon Development, Inc.
    Inventor: Stuart B. Smith
  • Patent number: 4738999
    Abstract: Compositions comprising elastomeric polyurethane prepolymers comprising the reaction product of at least one diisocyanate selected from the group consisting of p-phenylene diisocyanate, m-phenylene diisocyanate, 1,4-cyclohexyl diisocyanate, tetramethylxylyl diisocyanate and dimethylphenyl diisocyanate and at least one polyol or polythiol characterized by the presence of two hydroxyl or thiol groups or one hydroxy and one thiol group; a monomeric diol or dithiol curing agent and vein forcing fiber are especially useful for preparing fiber-reinforced composite structures, especially for dynamic applications.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: April 19, 1988
    Assignee: Lord Corporation
    Inventors: Donald R. Blenner, Karen M. Bond, Alan J. Hannibal
  • Patent number: 4738989
    Abstract: An aliphatic, isocyanate-base, polyurethane polymer and a process for preparing the polymer. The process comprises reacting, such as by spraying onto a substrate or an open mold, a caprolactone polyol with an aliphatic polyisocyanate in the presence of a catalytic amount of a metallo catalyst, and also in the presence of a fast-curing amount of a curing agent comprising an amine, particularly an aromatic diamine, such as diethyl toluene diamine, to provide a fast-reaction aliphatic polyurethane polymer.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: April 19, 1988
    Assignee: Urylon Development, Inc.
    Inventor: Stuart B. Smith
  • Patent number: 4721751
    Abstract: A polymerizable ethylenically unsaturated urea urethane polymer dispersed in a polymerizable ethylenically unsaturated compound is prepared by a process which comprises reacting a polyisocyanate, at least a portion of which is a diisocyanate, with a polyfunctional amine containing primary and/or secondary amino groups in the presence of:(a) a polyol, at least a portion of which is a polymeric polyol containing ethylenic unsaturation and having a carbon to oxygen ratio of at least 4/1;(b) a diluent which is an ethylenically unsaturated compound free of active hydrogens; and(c) an active hydrogen containing polymerizable ethylenically unsaturated compound; under conditions sufficient to form a polymerizable ethylenically unsaturated urea urethane polymer dispersed in a polymerizable ethylenically unsaturated compound.The aforedescribed urea urethane polymer dispersions are particularly useful in formulating curable compositions suitable for use as adhesives and sealants.
    Type: Grant
    Filed: March 26, 1987
    Date of Patent: January 26, 1988
    Assignee: PPG Industries, Inc.
    Inventors: Raymond F. Schappert, Joseph M. Makhlouf, Michael M. Chau
  • Patent number: 4719277
    Abstract: In a process for the production of linear segmented polyurethane by simultaneous reaction of macrodiols, low-molecular diols as chain-lengthener and aromatic diisocyanate, in a solvent in the presence of catalyst, and in the presence of catalytic amounts of a magnesium or calcium salt, an aromatic carboxylic acid macrodiol, monomeric, lower-molecular diol and aromatic diisocyanate are reacted, the macrodiol being used in such amounts as to adjust in the prepared polyurethane a weight ratio of soft segment to hard segment of about 4:1 to 1:4. Preferred embodiments include reaction at temperature from about 70.degree. to 120.degree. C.; use of an inert solvent; and having the concentration of starting material amount to about 10-40% by weight relative to the mixture of starting material and solvent. Also provided are polyurethanes obtained according to this process, having a molecular non-uniformity from 2 to 7.
    Type: Grant
    Filed: July 9, 1982
    Date of Patent: January 12, 1988
    Assignee: AKZO NV
    Inventors: Joachim Behnke, Christoph Josefiak
  • Patent number: 4661099
    Abstract: The present disclosure is concerned with self-adhesive sheet-like structures made by adhering an adhesive polyurethane gel material to a supporting substrate and the utilization of such structures in the medical field to adhere materials such as plasters, wound dressings and appliances to the human body, and in other fields to connect articles, such as the parts of a fractured or cracked object, to one another by means of an adhesive bond. The gel is formed by immobilizing a high molecular weight polymeric polyol in the matrix of a covalently crosslinked polyurethane which is prepared by reacting polyisocyanates having an isocyanate functionality of at least 2 with higher molecular weight polyhydroxyl compounds having a hydroxyl functionality of at least 3. These reactants are selected in accordance with the following formula which relates the isocyanate number, K, (isocyanate to hydroxyl equivalents ratio times 100) to the average functionalities of the polyisocyanates (F.sub.
    Type: Grant
    Filed: November 8, 1984
    Date of Patent: April 28, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Miklos von Bittera, Dietmar Schapel, Ulrich von Gizycki, Roland Rupp
  • Patent number: 4640950
    Abstract: A polyurethane resin composition which comprises (1) a polyurethane prepolymer in the form of liquid or solution, (2) colloidal silica and (3) a siloxane compound having a polyoxyethylene chain in the molecule maintains an excellent thixotropy even after solvents and additives are added and kneaded as the case may be.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: February 3, 1987
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Kenichi Nishino, Atsuo Kobayashi, Sachio Higashi, Shinichiro Yamamoto, Kiyoshi Yasuda
  • Patent number: 4622360
    Abstract: Removable water-borne urethane resin coating composition comprising polyurethane resin containing carboxyl groups and/or carboxylate groups and polyvalent metal complex as a cross-linking agent and method for removing the coating formed by using the removable water-borne urethane resin coating composition which comprises treating said coating with a ligand containing alkaline solution and removing the coating.The coating formed by using the composition is superior in water resistance, recoatability, detergent resistance, black heel mark resistance, abrasion resistance and service life.
    Type: Grant
    Filed: November 6, 1985
    Date of Patent: November 11, 1986
    Assignees: Yuho Chemicals Inc., Mitsui Toatsu Chemical Inc.
    Inventors: Tadashi Gomi, Kenji Sakata, Ichiro Aoyama, Nobuo Sono
  • Patent number: 4618635
    Abstract: Described herein are compositions comprising the reaction product of a polyol, a multi-functional isocyanate, a lactone-acrylate adduct and an hydroxyalkyl acrylate. These compositions are suitable for use as curable coatings.
    Type: Grant
    Filed: May 17, 1985
    Date of Patent: October 21, 1986
    Assignee: Union Carbide Corporation
    Inventors: Claiborn L. Osborn, Joseph V. Koleske, Kenneth Drake
  • Patent number: 4551498
    Abstract: A novel polyether polyurethane polymer comprising the reaction product of an organic diisocyanate and a linear polyhydroxyl polyether having a molecular weight of less than 8000 and from 0.01 to 1%, by weight, of finely-divided inorganic particles is described, together with a process for producing a cast elastomer by reacting this polymer with a cross-linking or chain-extending agent.
    Type: Grant
    Filed: May 3, 1984
    Date of Patent: November 5, 1985
    Assignee: Mobay Chemical Corporation
    Inventors: Robert P. Yeater, Richard S. Pantone, James N. Rieck
  • Patent number: 4533598
    Abstract: A cyclic olefin extended polyurethane system comprising the reaction product of an isocyanate terminated polyisocyanate with a polyol in the presence of a cyclic olefin extender and, optionally, a liquid ester or other type of extender. Said polyurethane systems are cured, crosslinked, non-spewing, grease compatible, and reenterable. This extended polyurethane is further characterized as having superior insulating properties so that it can be used for repairing, encapsulation or reclaiming electrical or telephone cables as well as hard volume encapsulants for general elastomer use. The extended polyurethane is comprised of a defined polyurethane, novel extender combinations, and optionally, a coupling agent.
    Type: Grant
    Filed: November 18, 1983
    Date of Patent: August 6, 1985
    Assignee: CasChem, Inc.
    Inventors: William J. Downey, Melvin Brauer
  • Patent number: 4528319
    Abstract: Novel, high solids urethane clearcoat compositions having improved flow characteristics by the incorporation of a flow control system composed of urea thixotrope/silica additives. The urea thixotrope constituent is prepared by reacting a polyether polyol with a stoichiometric excess of a saturated cyclic aliphatic polyisocyanate to produce isocyanate-terminated prepolymers. These prepolymers are then modified by reaction with an ethanolamine to form urea endcapped thixotropes which are compatible in structure with any urethane clearcoat system. A combination of one of these urea thixotropes and a finely divided transparent silica is used effectively to reduce sagging of high solids urethane clearcoat systems. In fact, the combination of the two components produces a synergistic effect which is greater than that expected from any one of the components in the flow control system.
    Type: Grant
    Filed: July 20, 1984
    Date of Patent: July 9, 1985
    Assignee: General Motors Corporation
    Inventors: Robert A. Ottaviani, William T. Short, Donald J. Hart
  • Patent number: 4522969
    Abstract: A novel, heat curable, liquid polymer composition is disclosed which comprises a modified polyurethane oligomer containing terminal ethylenic unsaturation, a free radical generating catalyst, and at least one additional component selected from a reinforcing agent and a filler. The cured composition demonstrates desirable impact properties and is particularly useful in automotive body constructions.
    Type: Grant
    Filed: March 20, 1984
    Date of Patent: June 11, 1985
    Assignee: Olin Corporation
    Inventors: James M. O'Connor, Donald L. Lickei, Michael L. Rosin