Phenolic Reactant Forming A Solid Polymer Or Sicp In The Presence Of A Nonreactant Material Patents (Class 524/876)
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Publication number: 20150086753Abstract: A norbornane-2-spiro-?-cycloalkanone-??-spiro-2?-norbornane-5,5?,6,6?-tetracarboxylic dianhydride represented by the following general formula (1): wherein the formula (1), n represents an integer of 0 to 12, and R1s, R2, R3 each independently represents a hydrogen atom or the like.Type: ApplicationFiled: June 12, 2014Publication date: March 26, 2015Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Toshihiko MATSUMOTO, Shinichi KOMATSU
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Publication number: 20150045505Abstract: Methods and formulations for distortional thermosets are disclosed that display enhanced composite mechanical performances and robust sorption resistance. The composition includes an epoxy resin of formula (I): and a diamine curing agent. The resultant distortional thermoset compositions possess superior out-life requirements and advantageous reaction kinetics for preparing prepreg compositions and materials.Type: ApplicationFiled: August 9, 2013Publication date: February 12, 2015Inventors: Stephen Christensen, Samuel J. Tucker, Jeffrey S. Wiggins
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Patent number: 8865833Abstract: A method of preparing a polycarbonate nanocomposite comprising forming a reactant mixture comprising a nanomaterial, a solvent, a dihydroxy compound and an activated carbonate; and polymerizing the dihydroxy compound and the activated carbonate in the presence of the solvent to form the polycarbonate nanocomposite is disclosed. Also disclosed are polycarbonate nanocomposites prepared in accordance with this method, and thermoplastic compositions comprising the polycarbonate nanocomposites. Also disclosed are polycarbonate compositions comprising the nanomaterial.Type: GrantFiled: July 14, 2010Date of Patent: October 21, 2014Assignee: Sabic Global Technologies B.V.Inventors: Amit Biswas, Dibakar Dhara, Raja Krishnamurthy, Edward Kung, Parnasree Maiti, Roopali Rai, Vaidyanath Ramakrishnan, Vitthal Abaso Sawant, Rajashekhar Shiddappa Totad, Sandeep Tyagi
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Publication number: 20140262021Abstract: Allyl-cyanoacrylate-containing compositions with an anhydride aromatic component, which when cured confers improved moisture resistance, are provided.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: Henkel Ireland LimitedInventors: Ciara Goff, Marisa Phelan, John Guthrie, Cormac Duffy, Sabine Horn, Christina Despotopoulou
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Publication number: 20140184997Abstract: Disclosed is a polyimide prepolymer, an alignment film and a method for preparing the same, as well as a liquid display device. The polyimide prepolymer has a repeating unit as shown in Formula (1) and is capped with a capping agent having a phenylethynyl group: wherein Ar is selected from one of the structures of the following Formulae (2) and (3): and n is an integer of between 3 and 8.Type: ApplicationFiled: September 19, 2012Publication date: July 3, 2014Inventors: Wei Yan, Dan Wang
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Patent number: 8748542Abstract: A synthetic polymer has a water-soluble or water-swellable polyurethane backbone and terminal groups and/or intermediate groups of blocks of hydrophobes of alkyl- or aryl compounds containing a polymerizable cyclic monomer or a polymerizable double bond (or alkene) group or derivatives thereof. The blocks of hydrophobes are composed of two or more units of the same or different hydrophobes. These synthetic polymers are used as rheology modifiers, especially in latex paints.Type: GrantFiled: June 18, 2009Date of Patent: June 10, 2014Assignee: Hercules IncorporatedInventors: Kirill N. Bakeev, De-Kai Loo, Angie H. Ma, Tuyen T. Nguyen, Jeffrey K. Politis
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Publication number: 20140054062Abstract: An insulating varnish forms an insulating coating film having a shape that corresponds to the shape of an opening of a die, having a uniform thickness. The insulating varnish is applied onto a surface of a conductor, subsequently passes through a die to remove the excess applied insulating varnish, and is then dried or baked to form an insulating coating film on the surface of the conductor. The insulating varnish has a viscosity of 10 Pa·s or more measured by a B-type viscometer at 30° C. The insulating varnish preferably contains no filler, and is preferably a polyimide precursor solution. Since the insulating varnish has a high viscosity, baking and solidification can be performed while maintaining a shape formed when the insulating varnish passes through a die.Type: ApplicationFiled: November 5, 2012Publication date: February 27, 2014Applicants: SUMITOMO ELECTRIC WINTEC, INC., SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventors: Kengo Yoshida, Masaaki Yamauchi, Masataka Shiwa, Yuji Hatanaka, Junichi Imai, Jun Sugawara, Toru Shimizu, Hideaki Saito, Yuudai Furuya
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Publication number: 20130273254Abstract: A black matte polyimide film having inorganic particles and carbon particles is provided. The polyimide film has a thickness ranging from 12 ?m to 250 ?m. The polyimide film includes 1 wt % to 49 wt % of the carbon particles and 1 wt % to 49 wt % of the inorganic particles. Each of the carbon particles and the inorganic particles respectively has a particle size ranging from about 0.1 ?m to about 10 ?m. The polyimide film is characterized in that the 60° lustrousness is equal to or less than 60 Gloss Unit (GU). The thermal expansion coefficient (CTE) is equal to or less than 30 ppm/° C. The light transmittance is equal to or less than 10%. A method for manufacturing the polyimide film is disclosed as well.Type: ApplicationFiled: September 14, 2012Publication date: October 17, 2013Applicant: Mortech CorporationInventors: Yen-Huey Hsu, Der-Jen Sun
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Publication number: 20130216942Abstract: A polycarbonate composition for an electrophotographic photoreceptor coating, wherein the polycarbonate includes 1 to 100 mole percent of first units of the formula and 0 to 99 mole percent of one or more second units of the formula and wherein the polycarbonate has a weight average molecular weight of at least 50,000 g/mole, and a polydispersity index of 1 to 5.Type: ApplicationFiled: February 17, 2012Publication date: August 22, 2013Inventors: Mohd Shamsul Hairi bin Mohd SALLEH, James Franklin HOOVER, Andries J.P. VAN ZYL, Robert Dirk VAN DE GRAMPEL, Jan-Pleun LENS
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Publication number: 20130211005Abstract: Methods for making polymer particles in gel form via an emulsion and/or suspension process are provided. The method can include preparing a reactant mixture comprising a carrier fluid and a monomer component containing one or more phenolic compounds and optionally one or more crosslinking compounds, a mixture of Maillard reactants, or a combination thereof. The monomer component can polymerize to form the polymer particles in gel form. The reactant mixture can be located within a reactor having one or more inner surfaces in contact with the reactant mixture during polymerization of the monomer component. The one or more inner surfaces limit a release of metal, metal ions, or a combination thereof into the reactant mixture to produce the polymer particles in gel form containing less than 1 wt % metal atoms, metal ions, or a combination thereof, based on the total weight of the polymer particles in gel form.Type: ApplicationFiled: February 8, 2013Publication date: August 15, 2013Applicant: GEORGIA-PACIFIC CHEMICALS, LLCInventor: Georgia-Pacific Chemicals, LLC
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Publication number: 20130209812Abstract: Curable compositions comprising a benzoxazine component, a polyamine component and an ortho-dihydroxyaryl component are described. The compositions may be cured to produce compositions useful in coating, sealants, adhesive and many other applications.Type: ApplicationFiled: January 31, 2013Publication date: August 15, 2013Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventor: 3M INNOVATIVE PROPERTIES COMPANY
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Patent number: 8507602Abstract: A non-stick coating composition comprising a waterborne phenoxy resin, a crosslinker, and a silicone compound. The coating is substantially free of fluorocarbon resin. An article, such as aluminum, may be coated with the composition. The composition may be multi-layers, but only the layers other than the first layer includes the silicone compound. The invention includes the method for applying the coating or coatings.Type: GrantFiled: October 22, 2007Date of Patent: August 13, 2013Assignee: Whitford Worldwide CompanyInventors: Thomas J. Bate, Arthur Wachowski, Jan Wilhelm Ernst Moos
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Publication number: 20130101862Abstract: A stable solution of a ring-opened polymer is provided. The stable solution can be prepared using the following steps: (d) adding an N,O-heterocyclic compound of formula I or II and a DOPO-based compound into an organic solvent to provide a reaction solution: wherein R1 to R3, W1, W2, m, n, p and q are as defined in the specification. (e) heating the reaction solution to carry out a ring-opening reaction to provide a polymer solution; and (f) cooling the polymer solution to obtain the stable solution, wherein the organic solvent is unreactive to the N,O-heterocyclic compound and the DOPO-based compound, and the amount of the DOPO-based compound is about 0.01 wt % to about 50 wt % based on the total weight of the N,O-heterocyclic compound and the DOPO-based compound. The stable solution is useful as a self-crosslinkable resin or a hardener for hardening epoxies.Type: ApplicationFiled: January 6, 2012Publication date: April 25, 2013Applicant: TAIWAN UNION TECHNOLOGY CORPORATIONInventor: Hsin-Ho Wu
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Patent number: 8367767Abstract: A friction lining for a wet clutch, in particular for a converter lockup, the clutch containing the ingredients—cellulose fibers, aramid fibers, fillers and a bonding agent. To provide a cost-effective friction lining suitable for the application under the conditions of a converter lockup clutch, it is proposed to admix powdered nutshell of percentage weight between 1% and 40%.Type: GrantFiled: March 1, 2010Date of Patent: February 5, 2013Assignee: Schaeffler Technologies AG & Co., KGInventors: Firoz Jafri, Martin Fuss, Michael Wilfong
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Publication number: 20120329945Abstract: The present invention relates to a curable composition, comprising specific meta-substituted aromatic compounds and at least one benzoxazine compound. In particular, the invention relates to the use of said meta-substituted aromatic compounds as curatives/catalysts for benzoxazine-containing compositions.Type: ApplicationFiled: April 27, 2012Publication date: December 27, 2012Applicant: Henkel AG & Co. KGaaInventors: Atsushi Mori, Atsushi Sudo, Takeshi Endo, Ryoichi Kudoh, Andreas Taden, Rainer Schoenfeld, Thomas Huver, Iris Christa Huver, Stefan Kreiling
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Publication number: 20120237753Abstract: A thermosetting composition comprising (a) at least one phosphorous-free dihydrobenzoxazine component; (b) at least a quaternary ammonium salt and (c) optionally a compound comprising at least an epoxy group is disclosed. Cured products made from these compositions have valuable chemical, physical and mechanical properties.Type: ApplicationFiled: September 23, 2010Publication date: September 20, 2012Applicant: Huntsman International LLCInventor: Frans Setiabudi
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PROCESS FOR CONTINUOUS PREPARATION OF A PREPOLYMER BASED ON PHENOLIC RESINS, OXAZOLINES AND EPOXIDES
Publication number: 20120121812Abstract: Process for the continuous preparation of prepolymers based on phenolic resin, an oxazoline component and an epoxide in the presence of a catalyst, including supplying the phenolic resin and the oxazoline component to an extruder in a stream A; a Lewis adduct of boron trifluoride or of aluminium trichloride, or arylsulphonic acids or alkylsulphonic acids, or latent arylsulphonic acids or latent alkylsulphonic acids, in a stream B, and the epoxide in a stream C, the infeed of stream A being situated, as seen in extrusion direction, before the infeed of stream C, these reactants are mixed at a reaction temperature of 120 to 200° C. with a residence time in the extruder of 3 seconds to 15 minutes, and then the product discharge of the extruder is cooled to a temperature of less than 45° C. within from 30 to 60 seconds.Type: ApplicationFiled: November 16, 2011Publication date: May 17, 2012Applicant: EVONIK DEGUSSA GmbHInventors: Marianne OMEIS, Franz-Albert von Itter, Thomas Weihrauch -
Publication number: 20110309293Abstract: A binder composition for electrodes relating to the present invention includes an ester compound derived from at least one type of tetracarboxylic acid, at least one type of compound having 3 or more amino groups, and an organic solvent. Furthermore, this binder composition for electrodes preferably contains at least one type of diamino compound. In addition, it is preferable to use a solvent with a boiling point ?250° C. in this binder composition for electrodes.Type: ApplicationFiled: March 5, 2010Publication date: December 22, 2011Applicant: I.S.T. CORPORATIONInventors: Koji Moriuchi, Yasuaki Takeda
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Patent number: 8003297Abstract: Polymeric material, containing a latent acid which can be converted to an acid by irradiation by a laser and optionally further ingredients.Type: GrantFiled: December 14, 2009Date of Patent: August 23, 2011Assignee: BASF SEInventor: Michael Heneghan
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Publication number: 20100324209Abstract: A polycarbonate copolymer contains: 0.1 to 50 mol % of a monomer unit represented by the following formula (1); and a monomer unit represented by the following formula (2). In the polycarbonate copolymer, the content of biphenols having a structure represented by the following formula (3) is 90 mass ppm or less. In the formula, R1 and R2 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom. In the formula: R3 and R4 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom; and X represents any one of bonding groups represented by —O—, —S—, SO—, —SO2—, —CO— and 9,9-fluorenylidene group. In the formula, R1 and R2 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 6 carbon atoms, an aryl group having 6 to 12 carbon atoms or a halogen atom.Type: ApplicationFiled: August 10, 2010Publication date: December 23, 2010Applicant: Idemitsu Kosan Co., Ltd.Inventors: Takaaki HIKOSAKA, Yasushi Hamada
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Publication number: 20100218982Abstract: It is an object of the present invention to provide an epoxy resin composition containing an epoxy compound, a low-molecular-weight phenol-modified polyphenylene ether and a cyanate compound as essential components, the epoxy resin composition having excellent dielectric characteristics and exhibiting high heat resistance while maintaining flame retardancy. To achieve this object, the epoxy resin composition of the present invention is a thermosetting resin composition composed of a resin varnish containing (A) an epoxy compound having a number-average molecular weight of 1000 or less and containing at least two epoxy groups in the molecule without containing any halogen atoms, (B) a polyphenylene ether having a number-average molecular weight of 5000 or less, (C) a cyanate ester compound, (D) a curing catalyst and (E) a halogen flame retardant, wherein all of the components (A) to (C) are dissolved in the resin varnish, while the component (E) is dispersed without being dissolved in the resin varnish.Type: ApplicationFiled: June 30, 2008Publication date: September 2, 2010Applicant: PANASONIC ELECTRIC WORKS CO., LTD.Inventors: Hiroaki Fujiwara, Masao Imai, Yuki Kitai
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Publication number: 20100160555Abstract: A resin composition comprising an epoxy compound denoted by the formula (1): wherein Ar1, Ar2 and Ar3 are the same or different and each denotes any one of divalent groups denoted by the following formulas: wherein R denotes a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and an epoxy compound denoted by the formula (2): wherein R5 denotes a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and Q2 denotes a single bond or a straight-chain alkylene group having 1 to 8 carbon atoms.Type: ApplicationFiled: March 25, 2008Publication date: June 24, 2010Inventors: Shinya Tanaka, Yoshitaka Takezawa
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Patent number: 7655380Abstract: Polymeric material, containing a latent acid which can be converted to an acid by irradiation by a laser and optionally further ingredients.Type: GrantFiled: February 13, 2009Date of Patent: February 2, 2010Assignee: Ciba Specialty Chemicals CorporationInventor: Michael Heneghan
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Patent number: 7645812Abstract: A poly(para-phenylenevinylene) (PPV) compound for forming a buffer layer of a thin film transistor represented by where R is a C1-C20 silyl group substituted with cyclohexyl or phenyl, m is an integer from 2 to 4, and n is an integer from 1 to 3,000; a composition for forming a buffer layer of a thin film transistor that is used to form the compound represented by formula 1 and includes a halo precursor polymer, a photobase generator, and a solvent; a thin film transistor including a buffer layer which is manufactured using the PPV compound; and a flat panel display including the thin film transistor. A patterned buffer layer can be formed under an organic semiconductor layer of an organic TFT by photolithography patterning using the silicon-containing PPV precursor. Accordingly, the alignment of the organic semiconductor layer of the organic TFT can be improved, and thereby, the characteristics of the organic TFT can be improved.Type: GrantFiled: January 26, 2006Date of Patent: January 12, 2010Assignee: Samsung Mobile Display Co., Ltd.Inventors: Taek Ahn, Min-Chul Suh, Jae-Bon Koo
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Patent number: 7550542Abstract: A synthetic polymer has a water-soluble or water-swellable polymer backbone and terminal groups and/or intermediate groups of blocks of hydrophobes of alkyl- or aryl compounds containing a polymerizable cyclic monomer or a polymerizable double bond (or alkene) group or derivatives thereof. The blocks of hydrophobes are composed of two or more units of the same or different hydrophobes. These synthetic polymers are used as rheology modifiers, especially in latex paints.Type: GrantFiled: January 7, 2005Date of Patent: June 23, 2009Assignee: Hercules IncorporatedInventors: Kirill N. Bakeev, De-Kai Loo, Angie H. Ma, Tuyen T. Nguyen, Jeffrey K. Politis
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Publication number: 20080306210Abstract: The invention relates to new compositions having good binder properties, wetting properties and dispersing properties not only for virtually foam-free aqueous pigment preparations but also for solvent-borne and solvent-free pigment preparations with very good heat stability and weathering stability.Type: ApplicationFiled: November 6, 2006Publication date: December 11, 2008Inventors: Patrick Glockner, Evelyn Albrecht, Andreas Wenning
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Publication number: 20080293885Abstract: The present invention provides a reactive emulsion capable of exerting a superior cross-linking ability, while reducing an amount of expensive additionally polymerizable oxazoline to be used. The problem can be solved with a reactive emulsion containing a core part composed of fine particles of an acrylate-based emulsion and a shell part composed of a polymer containing an oxazoline group, locating around said core part.Type: ApplicationFiled: April 19, 2006Publication date: November 27, 2008Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Masakazu Morimoto, Naofumi Tsujino
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Patent number: 7199186Abstract: A carbon-phenol resin molding compound is provided, which is preferably used to obtain molded articles having high electrical and thermal conductivities as well as good mechanical strength. The resin molding compound is prepared by reacting a phenol with an aldehyde in the presence of a catalyst, while mixing them with a carbon powder such that a content of the carbon powder in the molding compound is 75 wt % or more. The catalyst is at least one selected from tertiary amines, carbonates, hydroxides and oxides of alkali metals or alkali earth metals.Type: GrantFiled: August 5, 2002Date of Patent: April 3, 2007Assignees: Lignyte Co., Ltd., Nippon Pillar Packing Co., Ltd.Inventors: Isamu Ide, Masanobu Nishikawa, Hisato Higuchi, Tsunemori Yoshida, Katsunori Sugita
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Patent number: 7150958Abstract: Polymeric material, containing a latent acid which can be converted to an acid by irradiation by a laser and optionally further ingredients.Type: GrantFiled: June 4, 2002Date of Patent: December 19, 2006Assignee: Ciba Specialty Chemicals CorporationInventor: Michael Heneghan
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Patent number: 7094843Abstract: Epoxy systems having improved shelf life are disclosed. The epoxy systems are suitable for use in a number of applications, including as an adhesive or as a sealant (e.g., as a component in a melt-sealing tape). Methods of making and using the epoxy systems are also disclosed.Type: GrantFiled: August 19, 2002Date of Patent: August 22, 2006Assignee: 3M Innovative Properties CompanyInventor: Scott R. Meyer
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Patent number: 6906129Abstract: A polymer scale preventive agent for use in the polymerization of a monomer containing an ethylenic double bond is provided. The agent includes (A) a condensation reaction product obtained by reacting an aldehyde compound and a hydroxynaphthalene-based compound in the presence of a reducing agent, and (B) a polymer compound containing a nitrogen atom. This agent is capable of forming a coating with satisfactory scale prevention properties on inner wall surfaces of a polymerization vessel with a single-stage application, enabling the production process time to be shortened and the productivity and quality of polymeric products improved.Type: GrantFiled: September 3, 2004Date of Patent: June 14, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Mikio Watanabe, Tadashi Amano
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Publication number: 20040198906Abstract: A process for preparing a fluorinated poly(arylene ether) comprising the repeating unit: 1Type: ApplicationFiled: May 17, 2004Publication date: October 7, 2004Inventors: Jianfu Ding, Futian Liu, Ming Zhou, Mei Li, Michael Day, Pascal Vuillaume
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Patent number: 6740706Abstract: The invention relates to an economical method of making a polymer having reduced VOCs and coating compositions containing such polymers. In one embodiment, the method of invention requires providing a reactant mixture (a), providing a solvent mixture (b) comprising a reactive component (c) which is substantially free of any heteroatoms and is not a crystalline solid at room temperature and comprises (i) from 12 to 72 carbon atoms, and (ii) at least two functional groups, and subjecting the reactant mixture (a) in the solvent mixture (b) to polymerization conditions sufficient to polymerize reactant mixture (a) to provide a mixture (d) of a polymer (a′) in solvent mixture (b), wherein reactive component (c) under the polymerization conditions is substantially nonreactive: (1) with the components of reactive mixture (a), (2) in the polymerization of reactant mixture (a) and (3) with the polymer (a′).Type: GrantFiled: December 7, 2001Date of Patent: May 25, 2004Assignee: BASF CorporationInventors: Walter H. Ohrbom, Robert D. Weise, James A. Laugal
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Patent number: 6462109Abstract: The present invention relates to surfactantless latex compositions. More particularly, the present invention pertains to surfactantless latex compositions comprising sulfo-polyester polymers wherein the compositions have a continuous phase comprising water, diol, polyol or a mixture thereof. Still further, the present invention provides methods of making polymer blends comprising a condensation polymer and a latex polymer whereby the latex polymer is derived from a surfactantless latex composition comprising sulfo-polyester polymers. Polymer blends made by such methods are also provided.Type: GrantFiled: September 22, 2000Date of Patent: October 8, 2002Assignee: Eastman Chemical CompanyInventors: Mahendra Kumar Sharma, Linda Jane Adams
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Patent number: 6291598Abstract: A polymerized material produced by the polymerization of an organic amide monomer in the presence of an organic carbonate and a process for the preparation thereof. The process comprises the steps of: heating an amount of the organic anide monomer to a temperature above its melting point; first mixing an amount of an anionic initiator with at least a portion of the amount of heated organic amide mnonomer to produce an amount of activated monomer, wherein the anionic initiator is not comprised of an alkali metal; second mixing an amount of the organic carbonate with at least a portion of the amount of heated organic amide monomer to produce an amount of dissolved organic carbonate; and polymerizing the amounts of heated organic amide monomer and activated monomer in the presence of the amount of dissolved organic carbonate to produce the polymerized material.Type: GrantFiled: October 18, 1999Date of Patent: September 18, 2001Inventors: Michael C. Williams, Nai-Hong Li, Yatin Sankholkar
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Patent number: 6159405Abstract: A fire resistant phenolic resole-resorcinol novolac system for a pultrusion process, having a much improved pot life of the two part mixture, lower emissions during processing and a much better surface finish of the pultruded composite when compared to a similar existing system. A method of making a phenolic resole for pultrusion including, but not limited to, the use of modified phenols such as p-phenyl phenol and nonyl phenol.Type: GrantFiled: April 29, 1999Date of Patent: December 12, 2000Assignee: Borden Chemical, Inc.Inventor: John G. Taylor
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Patent number: 5861446Abstract: A coated sand composition for light-alloy casting includes refractory particles blended with phenol resin, bromide and adsorbent which adsorbs decomposition product gas from the bromide.Type: GrantFiled: March 22, 1996Date of Patent: January 19, 1999Assignee: Mazda Motor CorporationInventors: Yoshiro Ikeoka, Toshisaburo Kimura, Toshitada Onoda
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Patent number: 5856375Abstract: Broadly, the present invention relates to furan no-bake foundry binders where bisphenol A tar (BPAT) is used to replace a portion of the furfuryl alcohol and any conventional filler optionally included in for binder formulation. Reduction in the amount of furfuryl alcohol in the foundry binder formulation may lead to a reduction in the cost and an improvement in early strength of these formulations. Accordingly, in a furan no-bake foundry binder of a resin derived from a major proportion of furfuryl alcohol and optionally fillers, the improvement which comprises at least a fraction of said furfuryl alcohol being bisphenol A tar. Bisphenol A tar also can replace at least a fraction of any filler included in the binder formulation.Type: GrantFiled: January 4, 1996Date of Patent: January 5, 1999Assignee: Ashland, Inc.Inventors: Ken K. Chang, Michael C. Clingerman, Michelle L. Lott, James T. Schneider
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Patent number: 5731249Abstract: The object of the present invention is to provide a spray-on (gunning) refractory composition having high anti-stripping property, adhesive strength and corrosion resistant property suitable even for high temperature operation in steelmaking furnace. To refractory materials, resol type phenolic resin powder, being in semi-melting state at 80.degree. C. to 500.degree. C. and having weight average molecular weight of 1,000 to 15,000 and residual monomer of not more than 1,000 ppm, or phenol-formaldehyde resin powder, being in heat melting, self-hardening state at 100.degree. C. to 500.degree. C., having weight average molecular weight of 1,000 to 15,000 and residual monomer of not more than 1,000 ppm, and containing reactive methylol group by 6 to 9 weight %, said phenol-formaldehyde resin powder being added by 2 to 10 weight %, and pitch with high softening point of 100.degree. C. to 500.degree. C. being added by 2 to 10 weight %.Type: GrantFiled: November 4, 1996Date of Patent: March 24, 1998Assignee: Shinagawa Refractories Co., Ltd.Inventors: Hiroyuki Sugimoto, Tasuku Matsuda, Koichi Tanaka, Hiroshi Takenaka
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Patent number: 5710206Abstract: A gel or gelloid composition contains (a) more than 50% by weight (based on total polymer content) of a block copolymer containing relatively hard blocks and relatively elastomeric blocks; (b) a polyphenylene ether; and (c) at least 500 parts by weight of an extender liquid per 100 parts by weight of the block copolymer, which liquid extends and softens the elastomeric blocks of the block copolymer. The polyphenylene ether is present in an amount sufficient to increase the softening or melting temperature of the gel or gelloid composition over that of the same composition without polyphenylene ether. The gel or gelloid composition is useful for sealing applications.Type: GrantFiled: March 4, 1996Date of Patent: January 20, 1998Assignee: Raychem LimitedInventors: Jane Valarie Francis, Noel Marchel Michiel Overbergh, Jan Lodewijk M. F. G. Vansant
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Patent number: 5602226Abstract: The yield of fully substituted, multidimensional aromatic hubs in the condensation of hydroxyl and acid halide functionalities is improved by adding a thallium catalyst, such as thallium ethoxide (T1-OC.sub.2 H.sub.5), in the solvent.Type: GrantFiled: June 6, 1995Date of Patent: February 11, 1997Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard, Ronald R. Stephenson
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Patent number: 5574127Abstract: Associative thickeners of the present invention are water soluble polymer compositions that have a backbone of poly(acetal- or ketal-polyether) with ends that are capped with hydrophobic groups. They are prepared by copolymerizing an alpha, omega-diol, -di,thiol or-diamino polyether with a gem-dihalide compound in the presence of a base to form an alpha, omega-diol, -dithiol or -diamino poly(acetal- or ketal-polyether) which in turn is reacted with hydrophobic reagents to form the final product. These associative thickeners are used in film forming coating compositions, such as latex paints.Type: GrantFiled: April 5, 1995Date of Patent: November 12, 1996Assignee: AqualonInventor: Arjun C. Sau
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Patent number: 5419923Abstract: A method for manufacturing tracing paper, comprising coating a plastic film with a coating material. The coating material comprises a solvent system, adhesives, writable inorganic pigments and surfactants. The solvent system contains 50-80% by weight of aliphatic solvent and 20-50% by weight of aromatic solvent. The coating material includes 20-60% by weight of solid components. The inorganic pigments are in an amount of 30-60% based on the weight of the solid components of the coating material.Type: GrantFiled: February 16, 1994Date of Patent: May 30, 1995Assignee: Shinkong Synthetic Fiber Corp.Inventors: Jeremiah Chen, C. C. Chang
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Patent number: 5310784Abstract: An electromagnetic wave shielding material comprises a composite carbon-resin compound obtained by reacting to proceed polymerization of a resin forming material with carbon powder intermixed therewith. The resulting compound has carbon powder substantially uniformly dispersed in the resin and exhibit superior electromagnetic wave shielding effect, in addition to good fire resistance. The resin may be phenol, melamine, furan or the like, and the carbon powder is preferred to be incorporated at a content of not less than 40% of the total weight.Type: GrantFiled: June 29, 1992Date of Patent: May 10, 1994Assignee: Lignyte Co., Ltd.Inventors: Isamu Ide, Hisato Higuchi, Masanobu Nishikawa, Shigehisa Ishihara, Shuichi Kawai
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Patent number: 5202189Abstract: The specification discloses fire retardant composites which are curable at ambient temperatures and based on resorcinol-formaldehyde resins having specified molar ratios of phenol and aldehyde and specific viscosities.Type: GrantFiled: February 13, 1989Date of Patent: April 13, 1993Inventor: Lawrence E. Shea
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Patent number: 5177143Abstract: The invention relates to novel gelloid composition comprising a crosslinked non-silicone polymer having an olefinic unsaturated content of less than 10 mole percent and having dispersed therein a liquid in an amount of from about 20% to about about 95% by weight based on the weight of the liquid and polymer and from 0 to 0.3 volume fraction of a filler, said cross-linked polymera) if derived from a solid, relatively high molecular weight polymer, having a gel fraction of at least about 50%, orb) if derived from a liquid, relatively low molecular weight polymer, having at least about 0.1 crosslinks per weight average molecule;said composition having a modulus of (1+2.5v+14.1v.sup.2)x dynes/cm.sup.2 wherein x is less than 5.times.10.sup.5 at 30.degree. C. and greater than 5.times.10.sup.2 at 90.degree. C., and v is the volume fraction of the filler, with the proviso that, if the crosslinked polymer is prepared from a solid high molecular eight polymer, the storage modulus at 140.degree. C.Type: GrantFiled: February 27, 1990Date of Patent: January 5, 1993Assignee: Raychem CorporationInventors: Rong J. Chang, Lester T. Toy
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Patent number: 5116900Abstract: An aqueous coating composition for glass fibers is provided which contains a polycarbonate precursor material and a water soluble film former or binder. The resulting coated glass fibers have excellent flexibilty with little or no powdering of the coating composition off the fibers.Type: GrantFiled: February 13, 1990Date of Patent: May 26, 1992Assignee: Owens-Corning Fiberglas CorporationInventors: Martin C. Flautt, Leonard J. Adzima
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Patent number: 5075414Abstract: A fire resistant resin for use as a binder in reinforced plastics and a resultant reinforced plastic includes the reaction product of (a) at least one resorcinol component selected from the group consisting of resorcinol and resorcinol formaldehyde novolak resin, and (b) a phenolic resole resin. The reaction may be achieved in the presence of an alkaline catalyst.A method of making a fire resistant resin binder for reinforced plastics and the method of making such reinforced plastics including, (a) at least one resorcinol component selected from the group consisting of resorcinol and resorcinol formaldehyde novolak resin, and (b) a phenolic resole resin. The reaction may be achieved in the presence of an alkaline catalyst.Type: GrantFiled: September 4, 1990Date of Patent: December 24, 1991Assignee: Indspec Chemical CorporationInventor: Theodore H. Dailey, Jr.
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Patent number: 5075413Abstract: A fire resistant resin for use as a binder in reinforced plastics and a resultant reinforced plastic includes the reaction product of (a) at least one resorcinol component selected from the group consisting of resorcinol and resorcinol formaldehyde novolak resin, and (b) a phenolic resole resin. The reaction may be achieved in the presence of an alkaline catalyst.A method of making a fire resistant resin binder for reinforced plastics and the method of making such reinforced plastics including, (a) at least one resorcinol component selected from the group consisting of resorcinol and resorcinol formaldehyde novolak resin, and (b) a phenolic resole resin. The reaction may be achieved in the presence of an alkaline catalyst.Type: GrantFiled: September 4, 1990Date of Patent: December 24, 1991Assignee: Indspec Chemical CorporationInventor: Theodore H. Dailey, Jr.
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Patent number: 5011886Abstract: The inventive concept is to condense the phenol formaldehyde resins to a higher molecular weight than usual so far. Subsequent addition of urea thereto reduces viscosity to normal levels and increases solid content.The added urea does not take part in condensation reaction but partly reacts in the alkaline medium with formaldehyde to methylol urea (in a so called equilibrium reaction), which is formaldehyde donor for the phenol formaldehyde crosslinking reaction during the pressing of the particle board.The present invention relates to a process for producing modified phenolic resin bonding agents, characterized by preparing as known per se phenol-formaldehyde resins with a viscosity of more than 300 mPa.s (at 20.degree. C.Type: GrantFiled: February 26, 1990Date of Patent: April 30, 1991Assignee: Rwe-Dea Aktiengesellschaft fur Mineraloel und ChemieInventors: Adolf Buschfeld, Matthias Lattekamp, Gerd Ripkens, Hans Schittek