Tetrabenzoporphyrazine Nucleus Containing, E.g., Phthalocyanine, Etc. Patents (Class 524/88)
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Patent number: 5177200Abstract: A colorant for natural or synthetic resinous or polymeric materials, having the formula A--[SO.sub.2 --N(R.sub.2)--Y].sub.1-4 ; wherein: R.sub.Type: GrantFiled: May 19, 1989Date of Patent: January 5, 1993Assignee: Milliken Research CorporationInventors: Edward W. Kluger, John W. Rekers, David J. Moody
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Patent number: 5169881Abstract: The present invention concerns a process for preparing a treated blend which contains pigment material dispersed in a continuous phase of water and a polyester material. The invention also concerns compositions prepared from such process. The polyester material of the treated blend is linear, contains a sulfomonomer, and has an average particle size of less than 1 .mu.m.Type: GrantFiled: May 6, 1991Date of Patent: December 8, 1992Assignee: Eastman Kodak CompanyInventors: Kimberly T. Peters, Stephen H. W. Wu
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Patent number: 5162518Abstract: Porphyrins of the formula ##STR1## in which the substituents have the meaning given in the description are obtained by heating compounds of the formula ##STR2## if appropriate in the presence of compounds of the formula ##STR3## The porphyrins are used as pigments.Type: GrantFiled: January 17, 1992Date of Patent: November 10, 1992Assignee: Bayer AktiengesellschaftInventors: Bernd Kaletta, Meinhard Rolf, Walther Wolf, David R. Terrell
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Patent number: 5162399Abstract: Disclosed is a process for preparing ink millbase by use of a polymer blend of compatible polyesters and acrylic polymers. The polyesters are water-dispersible as a result of sulfonate groups on the polyester backbone. Use of the polymer blend results in an improvement in pigment particle size reduction during grinding.Type: GrantFiled: January 9, 1991Date of Patent: November 10, 1992Assignee: Eastman Kodak CompanyInventors: Mahendra K. Sharma, Hieu D. Phan
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Patent number: 5155149Abstract: The present invention is directed to silicone polyurethane copolymers containing phosphorescent dye compounds wherein the copolymers are represented by the formula: ##STR1## wherein n is an integer ranging from 1 to about 30, and y, z, and w are integers ranging from 0 to about 40, wherein one of y, z, and w is at least one; and A is a diamide, B is a silicone block copolymer, D is a chain extender, and E is a phosphorescent porphyrin-type compound.Type: GrantFiled: October 10, 1991Date of Patent: October 13, 1992Assignee: BOC Health Care, Inc.Inventors: Beauford W. Atwater, Suzanne Klima
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Patent number: 5153069Abstract: A dispersing agent for dispersing solid particles in an organic liquid having the composition ##STR1## wherein ##STR2## is the residue of a polyester chain having a molecular weight of at least 1700, derived from a hydroxycarboxylic acid containing 16-22 carbon atoms, ##STR3## is the residue of a mono or polyamide having up to 12 amido bonds, which is amino terminated in both ends and wherein R.sub.1 and R.sub.2 are each independently hydrogen or alkyl or alkenyl containing up to 20 carbon atoms;Z is a salt of a carboxylic acid containing 8-18 carbon atoms and a diamine NHR.sub.3 --T--NH.sub.2 wherein T is alkylene or alkenylene containing 2-12 carbon atoms and optionally comprising one or more oxygen or nitrogen bridges and R.sub.3 is hydrogen or alkyl or alkenyl containing up to 20 carbon atoms;Q is a carboxylic acid containing 8-18 carbon atoms or a diamine NHR.sub.3 --T--NH.sub.2, wherein T and R.sub.3 are defined as above.Said dispersing agent can be used for preparing an easily dispersable pigment.Type: GrantFiled: March 5, 1991Date of Patent: October 6, 1992Assignee: Giuseppe CanestriInventor: Giuseppe Canestri
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Patent number: 5153244Abstract: The compression set values of elastomers prepared from organosiloxane compositions that cure by a platinum-catalyzed hydrosilylation reaction are substantially reduced by the presence in said compositions of a phthalocyanine compound or a metal derivative of such a compound, where the metal is copper, nickel, cobalt or iron.Type: GrantFiled: October 19, 1990Date of Patent: October 6, 1992Assignee: Dow Corning Toray Silicone Company, Ltd.Inventors: Hiroshi Akitomo, Akito Nakamura
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Patent number: 5153260Abstract: A resin composition comprising a photo-polymerizable resin and a filler having an average particle size of 0.05-20 .mu.m can be used to be photo-polymerized to yield a light control sheet which may have a thickness of 100 .mu.m or less. Therefore, the resin composition makes it possible to lower the heat generation and curing distorting during a curing step and to make small the necessary amount of the composition for preparing a light control sheet.Type: GrantFiled: November 27, 1990Date of Patent: October 6, 1992Assignees: Sumitomo Chemical Company, Limited, Nippon Sheet Glass Co., Ltd.Inventors: Masahiro Ueda, Kazumitsu Kawamura, Tetsuro Oono, Shinichi Takemura
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Patent number: 5135972Abstract: Colorants and compositions containing the same, including polymeric substrates, especially polyurethane foams which are tinted or deeper colored with the colorants which have the general formula: ##STR1## wherein R.sub.2 is selected from hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or Y; A is a nonionic metallophthalocyanine chromophore which can be substituted or unsubstituted; Z is an arylene moiety; each D or D' is selected from a covalent bond or a linking group consisting of or containing at least one of --O--, --S--, --N(R.sub.3)--, or --N(SO.sub.2 R.sub.4)-- as the linking moiety, wherein R.sub.4 is unsubstituted or substituted alkyl, cycloaliphatic or aryl, and R.sub.3 is R.sub.Type: GrantFiled: July 15, 1991Date of Patent: August 4, 1992Assignee: Milliken Research CorporationInventors: Edward W. Kluger, John W. Rekers, Max A. Weaver
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Patent number: 5106533Abstract: A dispersion and a method therefor wherein the dispersion has composition A or B, whereinA is a nonaqueous dispersion comprising pigment particles having an average size of less than 0.1 micrometer dispersed in an organic medium, andB is an aqueous dispersion comprising certain classes of inorganic pigment particles having an average size of less than 0.1 micrometer dispersed in an aqueous medium, wherein said classes of inorganic pigment particles are selected from the group consisting of metal oxides and metal salts.Type: GrantFiled: March 14, 1991Date of Patent: April 21, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: William A. Hendrickson, Robin E. Wright, Richard C. Allen, James A. Baker, William M. Lamanna
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Patent number: 5102213Abstract: A solid state form of a dye-solution absorption filter is disclosed. Physical vapor depositable (i.e., evaporable) dyes are codeposited with a polyester matrix in a vacuum system to randomly disperse dye molecules in a solid dilutant. The dyes are selected to absorb at the wavelengths of interest. Dilution in a transparent matrix affords narrow band absorption and good out of band transmittance. Multilayer configurations allow absorption of a plurality of wavelengths. The filter coating conforms to curved and sharply contoured surfaces and layers only 10 microns thick afford very high absorptance.Type: GrantFiled: February 28, 1990Date of Patent: April 7, 1992Assignee: Honeywell Inc.Inventors: James C. Lee, David Greenlaw, Sau K. Lo
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Patent number: 5102980Abstract: Provided are novel polyester compositions containing copper phthalocyanine sulfonamide colorants copolymerized therein. Also provided are amorphous color concentrates, partially-crystalline color concentrates and semi-crystalline color concentrates. These polyester compositions are particularly useful for use as colored packaging materials and for colorants for personal, medical, and home care products where non-extractability of the colorant residue is important.Type: GrantFiled: April 1, 1991Date of Patent: April 7, 1992Assignee: Eastman Kodak CompanyInventors: James J. Krutak, Max A. Weaver, Clarence A. Coates, William W. Parham, Terry A. Oldfield, Wayne P. Pruett, Samuel D. Hilbert
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Patent number: 5056426Abstract: A strapping band or binding strap for use in connection with automatic strapping or binding machines or apparatus for strapping or binding packaged articles or stacks of articles by means of at least one closed loop of the strapping band or binding strap, comprises the fabrication thereof from a suitable thermoplastic material which has a suitable nucleation agent added thereto. The agent serves as a camber effect inhibitor so as to suppress any camber effect from being imposed or impressed upon or generated within the binding strap or strapping band by means of the roller conveyors conventionally incorporated within the looping frame of the automatic strapping or binding machine or apparatus.Type: GrantFiled: January 25, 1990Date of Patent: October 15, 1991Assignee: Signode System GmbHInventor: Hans Warych
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Patent number: 5055498Abstract: The solid marking composition of the invention includes from about 15% up to about 50% by weight of a polyethylene resin component having a specific gravity in the range of from about 0.95 up to about 0.96. In addition, the composition of the invention includes from about 20% up to about 55% by weight of a compatible plasticizer, and from about 3% up to about 20% by weight active material of a pigment. Optionally, the composition may include a pigment dispersing agent, such as a fatty acid. Further additives which may advantageously employed include extenders or fillers, oxidation stabilizers, UV stabilizers, and mold release agents. The composition of the invention is fabricated into marking instruments having unexpectedly improved eraseability, ease of application, barrel breaking strength, and tip breaking strength, while eliminating bloom entirely.Type: GrantFiled: June 19, 1990Date of Patent: October 8, 1991Assignee: Binney & Smith Inc.Inventor: Armand E. Brachman
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Patent number: 5049600Abstract: Excellent color stabilization as well as fiber integrity is obtained in bright sunlight and at relatively high temperature, in polyolefin (PO) articles pigmented with phthalocyanine pigments, by combining the pigment with two `large molecule` primary stabilizers, the first a hindered amine light stabilizer (HALS) and the second a metal-organic phosphonate. The first contains at least one triazine ring, and each substitutable position on each triazine ring is substituted with an oxo-piperazinyl group; the second is a 2.1 complex of an alkylated phenol phosphonate with a Group VIII or Group IIA metal, e.g. a metal bis[O-alky(3,5-di-t-butyl-4-hytdroxybenzyl)] phosphonate ("35-DHBP"). Stabilization of the PO's color is obtained for as long as the PO articles themselves are stabilized by the combination of primary stabilizers. With the combination, phthalocyanine pigmented articles are not only thermooxidatively and light-stabilized, but there is exceptionally low color fade.Type: GrantFiled: January 23, 1990Date of Patent: September 17, 1991Assignee: The B. F. Goodrich CompanyInventor: George Kletecka
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Patent number: 5041477Abstract: An oligomeric aromatic pigment dispersant is the reaction product of a diisocyanate and a diol or diamine. The oligomeric dispersant is comprised of at least 25 weight percent of a compound of the formula: ##STR1## wherein n is an integer of from 3 to 15, AR is a residual aromatic connecting group, DI is a residual organic connecting group, CAP is a capping moiety, and X is a residual connecting group selected from the group consisting of: ##STR2## The oligomeric aromatic dispersant has at least 3 aromatic "heads" and 2 aliphatic or rosin "tails".Type: GrantFiled: September 7, 1989Date of Patent: August 20, 1991Assignee: BASF CorporationInventor: Byron G. Hays
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Patent number: 5039339Abstract: Disclosed is a novel blend of a water-dissipatable polyester material and an acrylic polymer. The acrylic polymer must be compatible with the polyester and can be optionally styrenated. The polyester is exemplified in having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-soldiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 44 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof.The polymer blends are useful for preparing ink compositions having improved block resistance and water resistance.Type: GrantFiled: September 7, 1990Date of Patent: August 13, 1991Assignee: Eastman Kodak CompanyInventors: Hieu D. Phan, Gary W. Carrier, Rebecca R. Stockl, Frank J. Tortorici, R. Gary Wulf
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Patent number: 5032640Abstract: The description is given of a composition, which can be added to the bituminous binder during the preparation of the bituminous conglomerate used for paving roads, for giving the conglomerate high mechanical characteristics and resistance to high and low temperatures.Type: GrantFiled: June 23, 1989Date of Patent: July 16, 1991Inventor: Marco Fachini
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Patent number: 5030669Abstract: A dispersion and a method therefor wherein the dispersion has composition A or B, whereinA is a nonaqueous dispersion comprising pigment particles having an average size of less than 0.1 micrometer dispersed in an organic medium, andB is an aqueous dispersion comprising certain classes of inorganic pigment particles having an average size of less than 0.1 micrometer dispersed in an aqueous medium, wherein said classes of inorganic pigment particles are selected from the group consisting of metal oxides and metal salts.Type: GrantFiled: May 15, 1990Date of Patent: July 9, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: William A. Hendrickson, Robin E. Wright, Richard C. Allen, James A. Baker, William M. Lamanna
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Patent number: 4996252Abstract: Disclosed is a novel blend of a water-dissipatable polyester material and an acrylic polymer. The acrylic polymer must be compatible with the polyester and can be optionally styrenated. The polyester is exemplified in having an acid component of from about 70 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof.The polymer blends are useful for preparing ink compositions having improved block resistance and water resistance.Type: GrantFiled: July 28, 1988Date of Patent: February 26, 1991Assignee: Eastman Kodak CompanyInventors: Hieu D. Phan, Gary W. Carrier, Rebecca R. Stockl, Frank J. Tortorici, R. Gary Wulf
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Patent number: 4981888Abstract: A pigmented thermoplastic resin composition comprising:(A) a thermoplastic resin;(B) a metal phthalocyanine pigment; and(C) 0.5 to 30% by weight, based on the weight of the pigment (B), as agent imparting heat stability to component (B), of a sulphonated imidomethyl phthalocyanine having the formula I: ##STR1## wherein Pc is a phthalocyanine residue optionally substituted by up to 4 chlorine or bromine atoms;M is hydrogen or a metal capable of forming a metal phthalocyanine;m is a vlaue within the range of from 0.05 to 1.0;n is a value within the range of from 0.1 to 4.0; andX is a residue such that, in combination with the group ##STR2## it form a 5-, 6- or 7-membered cyclic imide.Type: GrantFiled: May 15, 1989Date of Patent: January 1, 1991Assignee: Ciba-Geigy CorporationInventors: Robert Langley, Colin D. Campbell
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Patent number: 4978362Abstract: A thermoplastic resin composition is provided which contains a thermoplastic resin and a colorant in the form of a polyalkyleneoxy-trifluoromethyl aniline colorant provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said resin, said colorant having the formula: ##STR1## wherein R.sub.1 is selected from H, a lower alkyl group containing from 1 to about 10 carbon atoms, CH.sub.2 Cl, CH.sub.2 Br, CH.sub.2 OH, phenyl or ##STR2## wherein R.sub.4 is H or a lower alkyl group containing from 1 to about 9 carbon atoms; R.sub.2 is H, CF.sub.3, a lower alkyl group containing from 1 to about 9 carbon atoms, Cl or Br; R.sub.3 is an aromatic or heteroaromatic containing group, and n is an integer from 2 to about 75.Type: GrantFiled: October 11, 1988Date of Patent: December 18, 1990Assignee: Milliken Research CorporationInventors: Edward W. Kluger, John W. Rekers
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Patent number: 4963600Abstract: A method for minimizing the inherent yellowness of any kind of clear coating is disclosed. This method involves the addition of very small amounts of blue pigments or dyes to the clear coating so that chroma neutralization occurs. The chroma neutralization results in a clear coat which is crystal clear in appearance.Type: GrantFiled: December 19, 1988Date of Patent: October 16, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Joseph F. Coughlin
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Patent number: 4957987Abstract: Color concentrates comprising a colorant such as a pigment and a polymeric binder and polymeric binders therefor, said polymeric binders comprising:(a) 70-90 percent of methyl methacrylate, by weight of the polymer;(b) 10-20 percent of methyl acrylate; and(c) from 0 to 10 percent of at least one free radically polymerizable monomer of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl and R.sub.2 is a moiety carrying a functonal group.Type: GrantFiled: April 25, 1988Date of Patent: September 18, 1990Assignee: Rohym GmbHInventors: Manfred Krieg, Hans Lichtenstein, Ludwig Hosch, Guenther Ittmann
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Patent number: 4937274Abstract: A coating composition comprising metallic flake pigments having an average thickness of 0.5 to 1.5.mu. and an average diameter of 10 to 45.mu., selected from the group consisting of aluminium flakes, bronze flakes, tin flakes, gold flakes, silver flakes, titanium flakes, stainless steel flakes, nickel flakes, copper flakes, their alloyed metal flakes, plastic-coated metal flakes and flake phthalocyanine blue, and ultra-fine particles having an average particle diameter of 5 to 400 m.mu., the weight ratio of said flake pigments to ultra-fine particles being 1:0.05 to 1:12, uniformly dispersed in a thermosetting resin vehicle. The present coating composition is useful as a top coat and especially as a base coat composition for 2-coat-1-bake coating system for automobile body, appliance or the like, resulting an excellent metallic effect and decorative interference color effect.Type: GrantFiled: July 6, 1988Date of Patent: June 26, 1990Assignee: Nippon Paint Co., Ltd.Inventors: Masamichi Arima, Gorou Nagao, Fumikazu Matsuda
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Patent number: 4935166Abstract: A solid state form of a dye-solution absorption filter is disclosed. Physical vapor depositable (i.e., evaporable) dyes are codeposited with a polyester matrix in a vacuum system to randomly disperse dye molecules in a solid dilutant. The dyes are selected to absorb at the wavelengths of interest. Dilution in a transparent matrix affords narrow band absorption and good out of band transmittance. Multilayer configurations allow absorption of a plurality of wavelengths. The filter coating conforms to curved and sharply contoured surfaces and layers only 10 microns thick afford very high absorptance.Type: GrantFiled: September 17, 1985Date of Patent: June 19, 1990Inventors: James C. Lee, David Greenlaw, Sau K. Lo
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Patent number: 4883714Abstract: An aqueous printing ink or its semi-aqueous or non-aqueous concentrate exemplified as comprising a substantially homogeneous system of the components:(1) from about 4 to about 80 weight % of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from about 1 to about 60 weight % of pigment material;(3) from substantially none to about 90 weight % of water; and(4) from about 0.05 to about 30.0 weight % of polyvinyl alcohol.Type: GrantFiled: January 9, 1989Date of Patent: November 28, 1989Assignee: Eastman Kodak CompanyInventors: Rebecca R. Stockl, Kenneth R. Barton, Melvin A. Caldwell
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Patent number: 4855344Abstract: An aqueous printing ink or its semiaqueous or substantially nonaqueous concentrates exemplified as comprising a substantially homogeneous system of the components:(1) from about 4 to about 90 weight % of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from none to about 70 weight % of pigment material;(3) from about 0.01 to about 90 weight % of water; and(4) one or more acetylacetonates of the formula M[CH--(COCH.sub.3).sub.2 ].sub.n wherein M is Al, Zr, Ni, Ca, V, or Fe, and n is the chemical valence of M, the weight ratio of polyester to total acetylacetonates being from about 10,000/1 to about 10/1.Type: GrantFiled: May 16, 1988Date of Patent: August 8, 1989Assignee: Eastman Kodak CompanyInventors: David L. Nealy, Louis A. Wilkin, Fred D. Barlow, Jr.
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Patent number: 4847316Abstract: Compositions useful as printing inks or as dry or wet concentrates for the preparation of inks, comprising substantially homogenous blends of from about 0.1 to about 50.0 wt. % water dispersible polyurethane, and conversely from about 99.9 to about 50.0 wt. % water dispersible polyester, and preferably containing from about 1.0 to about 95.0 wt. % of a solvent system comprising water or water admixed with cosolvent, the cosolvent comprising up to about 30.0 wt. % of the solvent system. These blends show exceptionally marked improvements in certain physical properties such as: stability of viscosity to ambient and process conditions; linearity of viscosity change with water dilution; consistency of viscosity for a great variety of pigments; and greatly improved shelf-life (no significant polymer segregation of layering). Such properties greatly enhance the utility of these blends for use in pigmented or dyed printing inks and in other substrate coating formulations which may or may not contain colorants.Type: GrantFiled: February 2, 1988Date of Patent: July 11, 1989Assignee: Eastman Kodak CompanyInventors: Martin F. Schick, William C. Hickman, Gary T. Clark, Rebecca R. Stockl
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Patent number: 4839414Abstract: A pigment dispersion and its use for the preparation of coating compounds are described. The dispersion contains a pigment, solvent and pigment dispersing agent. The pigment dispersing agent is a copolymer containing OH groups, obtainable by the reaction of:(A) 80 to 95% by weight of a copolymer of:(a) 0.5 to 40% by weight of N,N-di-Cl to 4-alkylamino-C.sub.1 to .sub.8 -alkyl(meth)acrylamides and/or a mixture of N,N-di-C to 4-alkylamino-C.sub.1 to 8 -alkyl(meth)acrylates and N-substituted (meth)acrylamides and/or (meth)acrylamide in which the ratio of amino(meth)acrylates to amido(meth)acrylates should be in the range of from 1:2 to 2:1,(b) 10 to 40% by weight of hydroxy-C.sub.2-8 -alkyl (meth)acrylates and(c) 20 to 89.5% by weight of copolymerizable, .alpha., .beta.-olefinically unsaturated compounds with(B) 5 to 20% by weight of a polyisocyanate containing unmasked and optionally also masked isocyanate groups as well as biuret, urethane or isocyanurate groups.Type: GrantFiled: August 18, 1987Date of Patent: June 13, 1989Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Klaus Bederke, Thomas Brock, Hermann Kerber, Paul Rupieper
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Patent number: 4830670Abstract: This invention relates to an erasable ballpoint pen ink before being cured, especially one which can be easily erased by using an eraser directly after it is written on paper, but which, after a longer period of time, becomes cured. The erasable ballpoint pen ink comprises an alcohol soluble pigment, a carrier, solvent and glycerol in such a way that the above mentioned components are in the weight-percentage ratio as follows, when the total weight of the ink is 100%: alcohol soluble pigment 10-20%, carrier 40-70%, solvent 15-35%, and glycerol 3-15%.Type: GrantFiled: June 18, 1987Date of Patent: May 16, 1989Inventor: Jackson M. Danyu
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Patent number: 4826898Abstract: A colored polypropylene resin comprising a polypropylene resin, a carbon black pigment and a copper phthalocyanine pigment, said colored polypropylene resin further comprising 0.Type: GrantFiled: March 29, 1988Date of Patent: May 2, 1989Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Takumi Hirosawa, Yuzo Hirayama, Keiki Sagara, Mituhiro Isomichi, Junichi Kumabe
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Patent number: 4820755Abstract: This invention provides polymers containing radiochromic hindered phenolic stabilizers which are characterized by including a blue compound which interacts with the hindered phenolic during irradiation to provide a color change indicative of sterility.Type: GrantFiled: August 18, 1987Date of Patent: April 11, 1989Assignee: American Cyanamid CompanyInventor: Joseph R. Webster
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Patent number: 4816386Abstract: A novel near-infrared sensitive phthalocyanine-polymer composition comprises a substituted aluminum phthalocyanine and a polymer wherein substituted aluminum phthalocyanine dimers and/or dimer aggregates which are responsible to the near-infrared sensitivity, are included.The near-infrared sensitive phthalocyanine-polymer composition has useful characteristics:(A) when the near-infrared sensitive phthalocynaine-polymer composition is heated above the T.sub.g (Glass Transition Temperature) of the polymer either by direct heating and by absorbing irradiated light energy, optical properties of said near-infrared sensitive phthalocyanine-polymer composition; absorbance and/or reflectivity, are capable of being changed,(B) the thermal change of optical properties of the near-infrared sensitive phthalocyanine-polymer composition can be fixed by further heating above the T.sub.f (Thermal Fixation Temperature) higher than the T.sub.Type: GrantFiled: January 5, 1987Date of Patent: March 28, 1989Assignee: Toray Industries, Inc.Inventors: Tetsuya Gotoh, Tosiyuki Kondoh, Mutsuo Aoyagi
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Patent number: 4812141Abstract: A colored thermoplastic resin composition is provided which comprises a thermoplastic resin and a colorant in the form of an alkyleneoxy-substituted chromophore group provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said thermoplastic resin. A process for preparing colored thermoplastic resins is also provided.Type: GrantFiled: March 17, 1988Date of Patent: March 14, 1989Assignee: Milliken Research CorporationInventors: Alan S. Baumgartner, Patrick D. Moore, Richard A. VanDahm
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Patent number: 4801634Abstract: Pigmentary copper phthalocyanine is prepared by converting crude copper phthalocyanine by methods known per se in the presence of trichlorophenoxy copper phthalocyanine. The resulting pigment is heat resistant and solvent resistant.Type: GrantFiled: June 22, 1987Date of Patent: January 31, 1989Assignee: Ciba-Geigy CorporationInventors: Robert Langley, John D. Stewart, Arthur S. Walls
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Patent number: 4801638Abstract: Pigmentary copper phthalocyanine is prepared by converting crude copper phthalocyanine by methods known per se in the presence of trichlorophenoxy copper phthalocyanine. The resulting pigment is heat resistant and solvent resistant.Type: GrantFiled: June 22, 1987Date of Patent: January 31, 1989Assignee: Ciba-Geigy CorporationInventors: Robert Langley, John D. Stewart, Arthur S. Walls
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Patent number: 4759801Abstract: A method for preparing a pigment preparation comprising kneading a pigment presscake (comprising a pigment and water and/or one or more organic liquids) at a temperature in the range 80.degree. to 200.degree. C. under vacuum together with a thermoplastic material, thereby at the same time removing the water and/or any organic liquids present. These preparations are useful for coloring polymeric material.Type: GrantFiled: July 10, 1986Date of Patent: July 26, 1988Assignee: Sandoz Ltd.Inventors: Jurgen Goldmann, Bansi L. Kaul
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Patent number: 4740543Abstract: A plastic vehicular instrument panel which is excellent in impact resistance, heat resistance, fabrication efficiency and appearance. The instrument panel is formed of a plastic material comprising as main components specified crystalline propylene-ethylene block copolymer ranging from 50 to 70 weight %, specified glass fibers ranging from 20 to 30 weight %, specified ethylene-propylene copolymer rubber ranging from 15 to 20 weight %, specified pigment ranging from 2 to 5 parts by weight relative to 100 parts by weight of total of the propylene-ethylene block copolymer, the glass fiber, and the ethylene-propylene copolymer rubber.Type: GrantFiled: August 8, 1986Date of Patent: April 26, 1988Assignee: Nissan Motor Co., Ltd.Inventors: Yoshio Matsuno, Hidehisa Watanabe
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Patent number: 4732570Abstract: A colored thermoplastic resin composition is provided which comprises a thermoplastic resin and a colorant in the form of an alkyleneoxy-substituted chromophore group provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said thermoplastic resin. A process for preparing colored thermoplastic resins is also provided.Type: GrantFiled: June 23, 1986Date of Patent: March 22, 1988Assignee: Milliken Research CorporationInventors: Alan S. Baumgartner, Patrick D. Moore, Richard A. VanDahm
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Patent number: 4731400Abstract: A thermoplastic resin composition having excellent transparency and a high ultraviolet transmittance and free from a reddish color is obtained from a polymer or copolymer of 4-methyl-1-pentene and a blue pigment. Preferably, the composition further comprises a black pigment and/or a red pigment.Type: GrantFiled: December 16, 1985Date of Patent: March 15, 1988Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Hiromi Shigemoto
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Patent number: 4643678Abstract: A dental application fluid for the inspection of tooth contacts and prosthetic works comprising an organic, polymeric adhesive (such as shellac), a massive component (such as titanium oxide), and a colored pigment (such as heliogen blue) all dispersed or dissolved in an alcoholic solvent.Type: GrantFiled: January 30, 1985Date of Patent: February 17, 1987Assignee: Prodent Ges. Fuer Zahnmed. Bedarfsartikel mbHInventor: Jens M. Hansen
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Patent number: 4640690Abstract: A colored thermoplastic resin composition is provided which comprises a thermoplastic resin and a colorant in the form of an alkyleneoxy-substituted chromophore group provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said thermoplastic resin. A process for preparing colored thermoplastic resins is also provided.Type: GrantFiled: September 13, 1985Date of Patent: February 3, 1987Assignee: Milliken Research CorporationInventors: Alan S. Baumgartner, Patrick D. Moore, Richard A. VanDahm
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Patent number: 4639272Abstract: A liquid colorant for ABS resins is described, comprising 100 parts by weight of a pigment or dye and 25 to 2,000 parts by weight of a liquid polyester, and having a viscosity of 1,500 poises or less at room temperature. This liquid polyester is prepared mainly from an aliphatic dicarboxylic acid and a dihydric alcohol, and usually has a viscosity of 10 to 1,500 poises at room temperture. The liquid colorant has advantages such as (1) the dispersibility of the pigment is good, (2) the colorant can be weighed precisely, (3) the colorant does not deteriorate the appearence of the molded article, and (4) the colorant does not deteriorate the physical properties of the molded article.Type: GrantFiled: June 26, 1985Date of Patent: January 27, 1987Assignees: Toyo Ink Mfg., Co., Ltd., Toyoto Jidosha Kabushiki KaishaInventors: Masashi Ito, Toshio Ohashi, Katsumi Ui
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Patent number: 4602052Abstract: A rubber composition containing carbon black as a reinforcing filler and a quaternary ammonium salt as a coupling agent and a method of making it are disclosed.Type: GrantFiled: September 17, 1984Date of Patent: July 22, 1986Assignee: Amoco CorporationInventors: Kenneth E. Weber, Dirk Oberlin
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Patent number: 4598105Abstract: A rubber composition containing carbon black and a second particulate filler of kaolin, metakaolin, talc, pyrophyllite coal, coke, graphite or metal carbonate filler and a method of making it are disclosed.Type: GrantFiled: September 17, 1984Date of Patent: July 1, 1986Assignee: Amoco CorporationInventors: Kenneth E. Weber, Dirk Oberlin
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Patent number: 4590235Abstract: A high-solids enamel coating on a substrate can give metallic glamor comparable to that imparted by conventional lacquer coatings containing metallic-flakes when the amount of metallic flake pigment in the enamel coating composition is increased over conventional amounts with a proportional increase in the amount of chromatic pigments.Type: GrantFiled: April 8, 1985Date of Patent: May 20, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Daniel J. Troy
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Patent number: 4548968Abstract: A process for preparing a resin extended pigment from crude pigment is disclosed. The process involves dry premilling the crude pigment with the resin followed by comilling the pre-milled pigment with the resin in the presence of water under alkaline conditions.Type: GrantFiled: June 1, 1984Date of Patent: October 22, 1985Assignee: Ciba Geigy CorporationInventor: Edward E. Jaffe
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Patent number: 4543128Abstract: Coloring compositions comprising an aqueous paste or dispersion of a filler which has been dyed with a water-soluble polycationic dyestuff, preferably together with a binding agent, are used in the coating of paper and the fixing, dyeing and printing of non-woven fabrics, including tissue paper.Type: GrantFiled: August 23, 1983Date of Patent: September 24, 1985Assignee: Sandoz Ltd.Inventors: Juerg Troesch, Walter Portmann
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Patent number: RE32261Abstract: Solid copolymers are produced by copolymerizing a mixture of: (A) at least 30% by weight of a monomer having the formula: ##STR1## wherein R.sub.1 is H or CH.sub.3 and R.sub.2 is an alkyl radical containing from 1 to 14 carbon atoms; (B) from 3 to 20% by weight of an ethylenic .alpha.,.beta. unsaturated carboxylic acid or anhydride thereof, or from 3 to 40% by weight of glycidyl acrylate or glycidyl methacrylate; and (C) from 0 to 67% by weight of a monomer copolymerizable with said monomers (A) and (B). Preferably, the mixture is first bulk-polymerized until conversion to the copolymer is from 10 to 80% by weight and the polymerization is completed by suspension-polymerization. Thermosetting solid coating compositions are produced by mixing a major proportion of a solid copolymer so produced with a minor proportion of a cross-linking compound or with an epoxy resin containing at least 2 epoxy radicals in the molecule in presence of a tertiary amine curing accelerator.Type: GrantFiled: March 19, 1979Date of Patent: October 7, 1986Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Kuniomi Hirota, Akio Masumoto, Hiroshi Ozawa, Nobuki Kobayashi, Teruo Honda