Electrodepositable Compositions Patents (Class 524/901)

Cross-Reference Art Collections

Electrostatic spray (Class 524/902)
  • Patent number: 5356529
    Abstract: Electrodepositable compositions comprising active hydrogen-containing ionic resins, capped polyisocyanate curing agents and triorganotin catalysts are disclosed. The catalysts are liquid, can be easily incorporated into the electrodepositable compositions and surprisingly exhibit good catalytic activity at low levels.
    Type: Grant
    Filed: May 3, 1993
    Date of Patent: October 18, 1994
    Assignee: PPG Industries, Inc.
    Inventors: V. Eswarakrishnan, Robert R. Zwack, Edward R. Coleridge
  • Patent number: 5346796
    Abstract: A homogeneous liquid composition, for use in the preparation of liquid toners containing at least one charge director and in which the electrical properties of the charge director(s) is/are stabilized, comprises: (1) insulating non-polar carrier liquid compatible with liquid toners for electrostatic imaging; (2) at least one charge director other than an amine salt; and (3) at least one stabilizing component in an amount effective to stabilize the electrical properties of said at least one charge director, said component being selected from non-quaternary amine salts and being soluble in the carrier, e.g. diethylammonium chloride and isopropylamine dodecylbenzenesulfonate. The invention further relates to liquid toners for electrostatic imaging comprise thermoplastic resin particles dispersed in an insulating non polar carrier liquid, preferably a hydrocarbon having a volume resistivity above 10.sup.9 ohm-cm and a dielectric constant below 3.
    Type: Grant
    Filed: July 20, 1992
    Date of Patent: September 13, 1994
    Assignee: Spectrum Sciences B.V.
    Inventor: Yaacov Almog
  • Patent number: 5338419
    Abstract: An electrodeposition bath comprising a urethane of the formulaR.sub.1 --NHCOO--R.sub.2in whichR.sub.1 is alkyl or a group of the formulaB.sub.1 --NH--B.sub.2 --[X--B.sub.3 ].sub.n --,R.sub.2 is a group of the formulae --(C.sub.2 H.sub.4 O).sub.y --R.sub.1, --(C.sub.3 H.sub.7 O).sub.y --R or of the formula ##STR1## R is C.sub.1 -C.sub.18 -alkyl, Y is a number from zero to 4,B.sub.1 is hydrogen, alkyl or a group of the formula--COOR.sub.2,B.sub.2 and B.sub.3 may be identical or different and are C.sub.2 -C.sub.14 -alkylene,n is an integer from 0 to 5,X is --0--, --S--, --NH--or >N--(C.sub.1 -C.sub.4) alkyl,R.sub.3 is hydrogen, alkyl, alkenyl, hydroxyalkyl, phenyl or alkylphenyl,R.sub.4 and R.sub.5 may be identical or different and are hydrogen or C.sub.1 -C.sub.4 -alkyl andA is a direct bond or one of the groups --O--, --CH.sub.2 O- or --CH.sub.2 OCO--.The inclusion of these urethanes in the electrodeposition bath brings about a reduction in the number of surface defects on galvanized surfaces.
    Type: Grant
    Filed: May 7, 1993
    Date of Patent: August 16, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Susanne Wehner, Heinz Klima, Michael Hoenel, Peter Ziegler, Gerd Walz
  • Patent number: 5331026
    Abstract: The present invention is directed to a process for producing an aqueous cathodic electrocoating composition comprisingA) mixingi) a powder comprising a dispersion of a pigment in a solid resinii) a principal resiniii) a crosslinker and optionallyiv) an additive selected from the group consisting of organic solvents, catalysts, wetting agents, conditioning agents, thickeners, rheology control agents, antioxidants, surfactants, leveling agents and mixtures thereofB) salting with an acid andC) dispersing in deionized water.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: July 19, 1994
    Assignee: BASF Corporation
    Inventors: James W. Benefiel, Peter D. Clark, Laura M. Lanni
  • Patent number: 5330627
    Abstract: A thermosetting coating composition containingA) one or more binders convertible into liquid or dissolved form at least at the curing temperature and containing acidic groups, basic groups or ionic groups of similar charge,B) one or more binders convertible into liquid or dissolved form at least at the curing temperature and containing basic groups where (A) contains acidic groups, acidic groups where (A) contains basic groups or ionic groups of like charge opposite to the charge of the ionic groups of (A), binder (B) being noninterdiffusible under storage and application conditions, but interdiffusible with binder (A) under hardening conditions, andC) optionally standard solvents, pigments and/or typical paint auxiliaries and/or additives which do not lead to any interdiffusion of the binders A) and B) under storage and application conditions,and a process for the production of coatings by application of the coating composition and subsequent thermal curing.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: July 19, 1994
    Assignee: Herberts G.m.b.H.
    Inventors: Roland Grutter, Reiner Bohmert, Rolf Reinecke
  • Patent number: 5314594
    Abstract: An improved aqueous electrocoating composition having a binder of an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of an effective amount of an additive of an alkyl thioester or a polymeric product of an epoxy resin, polyalkylene glycol and a sugar to form an electrocoating composition that has significantly improved throwing power and provides a coating that has the necessary properties such as chip, solvent and corrosion resistance.
    Type: Grant
    Filed: December 9, 1992
    Date of Patent: May 24, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ding Y. Chung, Kenneth S. Kirshenbaum
  • Patent number: 5292832
    Abstract: Advanced epoxy cationic resins are prepared from an epoxy-based resin containing oxirane groups by converting at least some of the oxirane groups to cationic groups is improved by using as the epoxy-based resin a blend of (I) an epoxy-based resin obtained by reacting in the presence of a suitable catalyst (1) a diglycidylether of an oxyalkylated aromatic or cycloaliphatic diol, such as a condensation product of bisphenol A, ethylene oxide and epichlorohydrin, optionally (2) a diglycidylether of a dihydric phenol, for example a diglycidyl ether of bisphenol A, (3) a dihydric phenol such as bisphenol A, and optionally (4) a capping agent such as p-nonylphenol and (II) a different cationic epoxy-based resin. Such resin blends can be utilized in cathodic electrodeposition coating systems. Use of the diglycidylether of an oxyalkylated diol provides coating compositions with lower viscosity and produces deposition coatings of higher film build and better surface appearance than compositions without this component.
    Type: Grant
    Filed: January 5, 1993
    Date of Patent: March 8, 1994
    Assignee: The Dow Chemical Company
    Inventor: Richard A. Hickner
  • Patent number: 5281316
    Abstract: An improved aqueous electrocoating composition having a binder of an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of an effective amount of a blend of a zinc containing compound and a lead pigment to form an electrocoating composition that has significantly improved throwing power and provides a coating that has the necessary properties such as chip, solvent and corrosion resistance.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: January 25, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ding Y. Chung, Robert J. Sikora, John J. Vincent
  • Patent number: 5205916
    Abstract: An improved aqueous electrocoating composition having a binder of an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of an antioxidant additive which is a combination of a phenolic antioxidant and a sulfur-containing antioxidant. The additive reduces overbake yellowing of the composition and the intercoat delamination of the composition and the topcoat upon exterior exposure.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: April 27, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ding Y. Chung, Kenneth S. Kirshenbaum
  • Patent number: 5200461
    Abstract: Disclosed is a micro gel particle having an anionic charge for which it is electrodepositable by itself. The present invention provides a process for preparing an anionic micro gel particle dispersion comprising:emulsifying in an aqueous medium a resin composition comprising(A) 100 parts by weight of an anionic film-forming aqueous resin, and(B) 10 to 250 parts by weight of a thermosetting crosslinking agent which is self-crosslinked or crosslinked with said aqueous resin (A) in terms of condensation or addition reactionexcepting the combination of an acrylic resin and an alcoxylated methylol melamine; parts by weight being based on the solid content of the resin composition, andheating the resultant emulsion to above a crosslinkable temperature of said crosslinking agent (B).
    Type: Grant
    Filed: July 5, 1990
    Date of Patent: April 6, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Yasuyuki Tsuchiya, Kenshiro Tobinaga
  • Patent number: 5188716
    Abstract: A heat-curable coating composition for cathodic electrocoating which becomes water-thinnable on protonation with an acid contains(A) 50-95% by weight of a polycondensation or polyaddition product having an average molecular weight of from 500 to 20,000 and containing primary and/or secondary hydroxyl groups and primary, secondary and/or tertiary amino groups, and(B) 5-50% by weight of a crosslinking agent obtainable by reactinga) an aliphatic polyhydroxy compound andb) an aromatic polyhydroxy compound withc) an aliphatic and/or cycloaliphatic polyisocyanate andd) a blocking agent.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: February 23, 1993
    Assignee: BASF Lack + Farben Aktiengesellschaft
    Inventors: Thomas Schwerzel, Hans Schupp, Klaus Huemke, Dieter Faul, Ulrich Heimann
  • Patent number: 5185065
    Abstract: An electrocoating composition containing an epoxy amine adduct which is the reaction product of a polyepoxide resin and an amine, an acrylic amine resin and a blocked polyisocyanate crosslinking agent;wherein the composition is prepared by blending a first emulsion of the epoxy amine adduct and the blocked polyisocyanate crosslinking agent with a second emulsion of the acrylic amine resin and a blocked polyisocyanate crosslinking agent; where the first and second emulsions are each individually formed by blending the adduct or resin with the blocked crosslinking agent and then adding an organic acid to form a salt which forms a stable aqueous emulsion.
    Type: Grant
    Filed: August 1, 1991
    Date of Patent: February 9, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ding Y. Chung, Allisa Gam, Robert A. Tessmer
  • Patent number: 5145568
    Abstract: An electrodepositable cationic electrocoating bath containing a nonaqueous pigment paste containing organic solvent. The use of an organic solvent in the place of an aqueous solvent minimizes or eliminates foaming in the process of making the pigment paste.
    Type: Grant
    Filed: December 18, 1990
    Date of Patent: September 8, 1992
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Ding Y. Chung, Tapan K. Debroy, Sioe-Heng A. Tjoe
  • Patent number: 5130004
    Abstract: A pigment paste suitable for use in cationic electrodeposition is disclosed. The pigment paste comprises a cationic resinous grinding vehicle derived from an epoxy resin containing both quaternary ammonium and ternary sulfonium salt groups. Also disclosed are cationic electrodeposition paints containing the pigment paste and the use of these paints in the process of cationic electrodeposition. The paste improves the stability of lead-containing cationic electrodeposition paints.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: July 14, 1992
    Assignee: PPG Industries, Inc.
    Inventors: Mark W. Johnson, Gregory J. McCollum
  • Patent number: 5114552
    Abstract: Curable electrocoating compositions and the use of these compositions in a method of electrodeposition are disclosed. The electrocoating compositions comprise an aqueous dispersion of an active hydrogen-containing ionic resin and a capped polyisocyanate in which the polyisocyanate comprises a mixture of a diphenyl-2,4'-diisocyanate, a diphenyl-4,4'-diisocyanate and optionally polyphenyl polyisocyanate in which the diphenyl-2,4'-diisocyanate comprises at least 5 percent by weight of a polyisocyanate mixture. The capped polyisocyanate mixture results in a more stable aqueous dispersion than comparable dispersions prepared with capped polyisocyanates derived from the more common diphenyl-4,4'-diisocyanate and mixtures of diphenyl-4,4'-diisocyanate with polyphenyl polyisocyanate.
    Type: Grant
    Filed: February 25, 1986
    Date of Patent: May 19, 1992
    Assignee: PPG Industries, Inc.
    Inventors: Gregory J. McCollum, George W. Mauer
  • Patent number: 5109040
    Abstract: Aqueous cathodic electrodeposition lacquer coating compositions are provided which comprise (A) certain water soluble synthetic resin binders containing amino groups; (B) crosslinking reagents which react with resin (A), and (C) certain soluble or insoluble transesterification catalysts for the crosslinking reagents. Methods of forming baked finish coatings which are cathodically deposited on electrically conductive surfaces using the lacquer coatings are also disclosed.
    Type: Grant
    Filed: March 21, 1990
    Date of Patent: April 28, 1992
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Helmut Honig, Kurt E. Jaeger, Klausjorg Klein, Dietrich Saatweber
  • Patent number: 5106469
    Abstract: A cationic resin suitable for use as a pigment grinding vehicle is disclosed. The cationic resin is derived from an epoxy resin and contains ternary sulfonium groups and alkyl phenoxide groups. Pigment pastes derived from this cationic resin can be used in a method of cationic electrodeposition where they provide for films with high build and good appearance.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: April 21, 1992
    Assignee: PPG Industries, Inc.
    Inventor: Mark W. Johnson
  • Patent number: 5098949
    Abstract: Disclosed is a novel curing system which is not associated with decomposition or production of low molecular materials. The curing system employs an aqueous composition which comprises (a) a compound having in one molecule at least two carbonylcyclic urea groups represented by the following formula (1) ##STR1## [wherein n is an integer of 0 to 5, X which may be the same or different and represents oxygen atom, a sulfur atom or --NR.sub.1 -- in which R.sub.1 is a hydrogen atom, an alkyl, hydroxyalkyl or alkylene group having 1 to 5 carbon atoms.] and (b) a basic resin which has a functional group reactive with an isocyanate group and is water soluble or water dispersible by neutralizing.
    Type: Grant
    Filed: December 29, 1989
    Date of Patent: March 24, 1992
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hiroyuki Sakamoto, Kenshiro Tobinaga, Noriyuki Tsuboniwa, Satoshi Urano, Yasuyuki Tsuchiya, Hirotoshi Umemoto
  • Patent number: 5093390
    Abstract: A process for preparing polymer non-aqueous dispersions to be formulated together with a binder component in coating compositions, which comprises the steps of: (1) emulsion polymerizing a hydroxy group containing .alpha.,.beta.-ethylenically unsaturated monomer, a polyfunctional .alpha.,.beta.-ethylenically unsaturated monomer and an .alpha.,.beta.-ethylenically unsaturated monomer different therefrom by using a water-soluble polymerization initiator, preferably a persulphate, in a soap free system or in the presence of an ester group containing anionic or cationic surfactant; adding an organic solvent, preferably comprising an amphipathic organic solvent, to a resultant polymer aqueous dispersion; and then adding a basic compound catalyst when the anionic surfactant is used or an acidic compound catalyst when the cationic surfactant is used, to thereby hydrolyze completely said surfactant and water-soluble polymerization initiator at a temperature not exceeding 95.degree. C.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: March 3, 1992
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Kishio Shibato, Fumio Sakurai, Atsuhiro Sakai, Toru Imai, Osamu Ohe
  • Patent number: 5066758
    Abstract: Carrier resin for pigment pastes, and its preparation and useThe invention relates to paste resins based on epoxide compounds, containing (a) specific quaternary ammonium groups, (b) OH groups and (c) isocyanate radicals which are bonded to the epoxy compound and of which at least 10 mol % are derived from a long-chain, monofunctional isocyanate having at least 8 carbon atoms, the average molecular weight (Mn) of these paste resins being 500 to 10,000. The invention furthermore relates to the preparation of these paste resins, to their use for pigment pastes and to these pigment pastes. Water-dilutable paints, in particular electrocoating paints which contain the pigment pastes according to the invention, give trouble-free surfaces and comparable film thicknesses, even on different substrates.
    Type: Grant
    Filed: July 26, 1989
    Date of Patent: November 19, 1991
    Assignee: Hoechst AG
    Inventors: Michael Honel, Peter Ziegler, Walter Sprenger, Wolfgang Wendt
  • Patent number: 5053307
    Abstract: Process for the preparation of toner particles for electrostatic liquid developers, which upon fusing to paper have a gloss .gtoreq.10 units over the paper gloss comprising:(A) dispersing at least one thermoplastic resin, at least one pigment, and a hydrocarbon liquid having a Kauri-butanol value of greater than 120 such that the dispersion contains 10% or more by weight solids by means of particulate media whereby the moving particulate media creates shear and/or impact while maintaining the temperature for 5 to 180 minutes in the vessel at a temperature of at least 15.degree. C. above the point at which the resin is plasticized or liquified by the hydrocarbon liquid and below that at which the hydrocarbon liquid boils and the resin and/or pigment decomposes,(B) continuing dispersion of the resin, pigment and hydrocarbon liquid as in Step (A) while maintaining the temperature for 5 to 180 minutes in the vessel at least 5.degree. C. below the point to at least 10.degree. C.
    Type: Grant
    Filed: April 26, 1990
    Date of Patent: October 1, 1991
    Assignee: DXImaging
    Inventors: William A. Houle, Gregg A. Lane, Carolyn C. Legere-Krongauz
  • Patent number: 5049249
    Abstract: A low temperature cure electrodepositable cathodic resin is disclosed. The resin is the reaction product of a polyepoxide amine adduct and a novel blocked crosslinking agent. The crosslinking agent of our invention is tetramethylxylene diisocyanate blocked with any suitable blocking agent. The resulting resin can be cured at relatively low temperatures (250.degree.-275.degree. F.), which potentially allows the use of the resin with articles containing plastics.
    Type: Grant
    Filed: August 30, 1989
    Date of Patent: September 17, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ding Y. Chung, Tapan K. DebRoy
  • Patent number: 5021502
    Abstract: An aqueous electrodeposition lacquer coating composition containing as binder(A) from 95 to 50% by weight of an organic externally crosslinkable synthetic resin binder containing primary and/or secondary hydroxyl groups and primary, secondary and/or tertiary amino groups and(B) from 5 to 50% by weight of a crosslinking agent mixture of(a) blocked isocyanates and(b) transesterifiable crosslinking agents containing more than two ester groups and(c) optionally up to 30% by weight of hydroxyfunctional resins.The invention also relates to the use of this electrodeposition coating composition for coating objects, particularly objects having electrically conductive surfaces.
    Type: Grant
    Filed: January 10, 1990
    Date of Patent: June 4, 1991
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Hans-Peter Patzschke, Peter W. Cerny, Dietrich Saatweber, Georg H. L. Hendrikx
  • Patent number: 5019621
    Abstract: Acrylate copolymers containing hydroxyl groups as additives for aqueous anionic paint systems for the purpose of preventing surface defects are described. The acrylate copolymers contain selected amounts of hydroxyl groups originating from hydroxyethyl (meth)acrylates or hydroxypropyl (meth)acrylates, in addition to carboxyl groups neutralizable with bases. The additives are used in amounts of from 0.1 to 2.0% by weight, calculated on solids content and based on the total solids content of the binder in the paint.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: May 28, 1991
    Assignee: Vianova Kunstharz, A.G.
    Inventors: Harald Rauch-Puntigam, Werner Staritzbichler, Peter Morre
  • Patent number: 5008327
    Abstract: An electrodeposition coating composition comprising a fluorine-containing copolymer, a curing agent and an aqueous medium, said composition having a fluorine ion content of not more than 15 ppm.According to the composition of the present invention, since a bad influence to electrodeposition due to fluorine ion can be remarkably inhibited, the excellent electrodeposited film can be obtained therefrom.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: April 16, 1991
    Assignees: Kansai Paint Co., Ltd., Daikin Industries, Ltd.
    Inventors: Shinji Shirai, Hiroyuki Negishi, Nobuyuki Tomihashi, Masayuki Yamane
  • Patent number: 4983266
    Abstract: This invention relates to an electrodeposition process which comprises electrodepositing onto a conducting substrate a coating composition comprising a self-crosslinking polymeric resin which has an average of at least two pendent hydroxy functional groups and an average of at least two pendent ester groups of the general formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen, alkyl, substituted alkyl or aryl groups; n is from about 1 to about 5; X is nitrogen, sulfur or phosphorus; and when X is nitrogen or phosphorus, R.sup.3 is hydrogen, lower alkyl, or an aryl group; R.sup.4 is lower alkyl or an aryl group; and when X is sulfur, R.sup.4 is nothing and R.sup.3 is either hydrogen, lower alkyl or aryl.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: January 8, 1991
    Assignee: The Sherwin-Williams Company
    Inventors: Goutam Gupta, Sherman J. Mels
  • Patent number: 4981887
    Abstract: To improve chip resistance of an alkyd-type electro-depositable coating composition, there may be added to the composition an ethylenically unsaturated, addition-polymerizable monomer or oligomer having a substantially linear backbone, having a molecular weight of at least about 150, and being reactive with fatty acid unsaturation of the alkyd.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: January 1, 1991
    Assignee: The Valspar Corporation
    Inventors: Philip J. Ruhoff, Rodney W. Stockstad, James A. Prevost, Larry B. Brandenburger, Robert B. Edenborg
  • Patent number: 4976836
    Abstract: Cathodic electrocoating compositions and processes are improved by the addition of at least 0.10% hydrogen peroxide by weight based on polymer to electrocoating composition.
    Type: Grant
    Filed: April 24, 1987
    Date of Patent: December 11, 1990
    Assignee: The Glidden Company
    Inventor: Eulogio D. Lazaro
  • Patent number: 4973541
    Abstract: The present invention provides a developer for developing electrostatic latent image which comprises capsule toners and carriers; said capsule toner having many wrinkles or hollows and upheavals and containing liquid in a shell, and the carriers have no sharp edge or a lower specific gravity, the image copied by the developer can be fixed by pressure under low temperature.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: November 27, 1990
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventors: Toshitaro Kohri, Junji Machida, Masahiro Anno
  • Patent number: 4973392
    Abstract: This invention relates to coating compositions which comprise a polymer having at least two hydroxy functional groups and a crosslinking agent having an average of at least two pendent ester groups of the general formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen, alkyl, substituted alkyl or aryl groups; n is from about 1 to about 5; X is nitrogen, sulfur or phosphorus; and when X is either nitrogen or phosphorus, R.sup.3 is hydrogen, lower alkyl, or an aryl group; R.sup.4 is lower alkyl or an aryl group; and when X is sulfur, R.sup.4 is nothing and R.sup.3 is either hydrogen, lower alkyl or aryl.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: November 27, 1990
    Assignee: The Sherwin-Williams Company
    Inventor: Goutam Gupta
  • Patent number: 4968729
    Abstract: Electrodepositable stable coating preparation essentially comprising a synthetic resin (A), which contains amino groups and, if appropriate, hydroxyl groups, a hardener (B) which is capable of transesterification and/or transamidation, water as diluent (C), if appropriate, organic solvents (D), and also the conventional coating additives and, if appropriate, hardening catalysts (E), wherein the organic solvents content is a maximum of 10% by weight, relative to the solids content.The invention furthermore relates to a process for the preparation of this coating preparation, which is distinguished by a low organic solvents content with good storage stability.
    Type: Grant
    Filed: April 20, 1989
    Date of Patent: November 6, 1990
    Assignee: Hoechst AG
    Inventor: Helmut Plum
  • Patent number: 4968577
    Abstract: The present invention provides a capsule toner having many wrinkles or hollows and upheavals and containing liquid in a shell, which is useful for toner for pressure fixation.
    Type: Grant
    Filed: August 18, 1989
    Date of Patent: November 6, 1990
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventors: Toshitaro Kohri, Junji Machida, Masahiro Anno
  • Patent number: 4960664
    Abstract: A toner for developing an electrostatic latent image containing a polyester resin binder obtained by condensation polymerization of a diol component and a mixture of acid components. The acid components are an aliphatic unsaturated dicarboxylic acid or an acid anhydride thereof and a polybasic carboxylic acid having not less than three carboxylic acid groups or an acid anhydride thereof. A ratio of the polybasic carboxylic acid having not less than three carboxylic acid groups or the acid anhydride thereof to the total acid components is in the range of from 5 mol % to less than 30 mol %.
    Type: Grant
    Filed: September 25, 1989
    Date of Patent: October 2, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroyuki Yamada, Hiroyuki Takagiwa, Hiroya Masaki, Takahira Kasuya, Jiro Takahashi, Masafumi Uchida, Satoru Ikeuchi
  • Patent number: 4946755
    Abstract: Disclosed is an electrophotographic magnetic toner comprising 40-80% binder resin, a waxy material such as a low molecular weight polypropylene or polyethylene, a charge control agent and 20-60% iron oxide having a number average particle size of 0.2-0.7 microns and wherein trivalent Fe is present in excess and wherein the iron oxide contains 16-25% FeO and about 75-84% Fe.sub.2 O.sub.3.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: August 7, 1990
    Assignee: Canon Kabushiki Kaisha
    Inventor: Sukejiro Inoue
  • Patent number: 4939060
    Abstract: A magnetic toner for developing electrostatic images, comprising at least a binder resin and a magnetic powder; the binder resin having 10 to 70 wt. % of a THF (tetrahydrofuran)-insoluble and a THF-soluble, the THF-soluble providing a molecular weight distribution in the chromatogram of GPC (gel permeation chromatography) thereof such that it provides a rate (Mw/Mn) of weight-average molecular weight (Mw)/number-average molecular weight (Mn).gtoreq.5, there are a peak in the molecular weight range of 2,000 to 10,000 and a peak or shoulder in the molecular weight range of 15,000 to 100,000 and a component having a molecular weight of 10,000 or smaller is contained in an amount of 10-50 wt. % based on the binder resin; the magnetic powder comprising spherical magnetic particles having a bulk density of 0.6 g/ml or larger.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: July 3, 1990
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Tomiyama, Seiichi Takagi, Ichiro Ohsaki, Satoshi Yasuda, Yoshihiko Hyosu
  • Patent number: 4939216
    Abstract: A heat-curable coating material for cathodic electrocoating is water-dilutable on protonation with an acid and contains(A) from 50 to 95% by weight of a polymer, polycondensate or polyadduct containing primary and/or secondary amino groups, as a binder, and(B) from 5 to 50% by weight of a crosslinking agent obtainable by reacting(a) a polyurethane with(b) formaldehyde or a formaldehyde-donating compound and(c) one or more secondary aliphatic amines.
    Type: Grant
    Filed: July 12, 1989
    Date of Patent: July 3, 1990
    Assignee: BASF Lacke+ Farben Aktengesellschaft
    Inventors: Dirk Lawrenz, Hans Schupp, Thomas Schwerzel
  • Patent number: 4935328
    Abstract: Electrostatic liquid developer having improved negative charging characteristics consisting essentially of(A) nonpolar liquid having a Kauri-butanol value of less than 30, present in a major amount,(B) thermoplastic resin particles having an average by area particle size of less than 10 .mu.m,(C) charge director compound, and(D) at least one soluble solid or liquid organic monofunctional amine compound of the formula: R.sub.n NH.sub.3-n wherein R is alkyl, cycloalkyl or alkylene, or substituted alkyl, the alkyl, cycloalkyl, alkylene or substituted alkyl group being of 1 to 50 carbon atoms, and n is an integer of 1 to 3.Optionally, a colorant, e.g., a pigment; metallic soap, adjuvant can be present. The electrostatic liquid developer is useful in copying, making proofs including digital color proofs, lithographic printing plates, and resists.
    Type: Grant
    Filed: April 7, 1988
    Date of Patent: June 19, 1990
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Lyla M. El-Sayed, James R. Larson, Torence J. Trout
  • Patent number: 4933056
    Abstract: A cationic electrodepositable composition containing a resinous phase dispersed in an aqueous medium is disclosed. The resinous phase has basic nitrogen groups which are at least partially neutralized with sulfamic acid or a derivative thereof, that is, an acid of the formula: ##STR1## where R is H or C.sub.1 to C.sub.4 alkyl. The compositions are in the form of relatively small particle size aqueous dispersions, and when used in the process of cationic electrodeposition, enable the formation of thick films with high throwpower. Also, the use of sulfamic acid passivates the anode.
    Type: Grant
    Filed: September 26, 1988
    Date of Patent: June 12, 1990
    Assignee: PPG Industries, Inc.
    Inventors: Victor G. Corrigan, Steven R. Zawacky
  • Patent number: 4933380
    Abstract: An air-drying aqueous coating composition for eletrodeposition comprising[A] water-solubilized product or a water-dispersed product obtained by reacting (A-1) an epoxy resin and (A-2) a maleinized product of a (semi)drying oil fatty acid-modified vinyl polymer having an acid value of 10 to 200 in such proportions that the solids weight ratio of the component (A-1) to the component (A-2) is from 90/10 to 5/95, and[B] an amphoteric organic solvent having affinity for component [A].
    Type: Grant
    Filed: September 1, 1989
    Date of Patent: June 12, 1990
    Assignee: Kansai Paint Co.
    Inventors: Tetsuo Aihara, Yasuharu Nakayama, Shigeki Matsubara
  • Patent number: 4931157
    Abstract: An ungelled reaction product of a polyepoxide and an active hydrogen-containing material containing at least two active hydrogens per molecule is disclosed. The active hydrogen-containing material being a hydroxyalkyl-substituted urethane in which the hydroxy group is in the beta position to the urethane group. The reaction product is useful as a precursor in making cationic resins for use in cationic electrodeposition.
    Type: Grant
    Filed: February 18, 1988
    Date of Patent: June 5, 1990
    Assignee: PPG Industries, Inc.
    Inventors: Joseph T. Valko, Joseph E. Plasynski, Robert D. Miller
  • Patent number: 4921771
    Abstract: A toner for developing electrostatic images is disclosed which comprises a coloring agent, a styrene homopolymer or copolymer with a vinyl monomer or moners, and polypropylene having a number average molecular weight of about 3000 to 4000 in an amount between about 0.02 and 40 parts by weight per 100 parts by weight of the styrene homopolymer or copolymer.
    Type: Grant
    Filed: January 19, 1988
    Date of Patent: May 1, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Makoto Tomono, Noriyoshi Tarumi, Masayuki Sato
  • Patent number: 4916019
    Abstract: A cationic electrodeposition coating composition for forming a multilayer film, said composition comprising(A) an epoxy-type cationic electrodepositable resin which is an addition-reaction product formed between an epoxy resin and a basic amino compound, having a surface tension of 40 to 60 dynes/cm and being capable of forming a cathodically depositable aqueous bath by neutralization with an acid,(B) a non-ionic, non-selfcurable, film-forming resin having a surface tension of 25 to 45 dynes/cm, and(C) a blocked polyisocyanate compound as a curing agent,the weight ratio of resin (A) to resin (B) being from 60:40 to 98:2, and the surface tension of resin (A) being at least 5 dynes/cm higher than that of resin (B), and resin (A), resin (B) and the polyisocyanate compound (C) having substantially no ethylenically double bond.
    Type: Grant
    Filed: July 27, 1988
    Date of Patent: April 10, 1990
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Eisaku Nakatani, Akira Tominaga, Haruo Nagaoka, Yoichi Masubuchi, Masafumi Kume, Tadayoshi Hiraki
  • Patent number: 4913968
    Abstract: Water-compatible resins containing a residue of an aryl or cycloalkyl compound having a sufficiently bulky structure to raise the T.sub.g of a specified cured epoxy resin by more than 20.degree. C. The resins preferably are used in cathodic electrophoretically-depositable coating compositions.
    Type: Grant
    Filed: January 17, 1989
    Date of Patent: April 3, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Alphonsus V. Pocius
  • Patent number: 4900415
    Abstract: A low temperature cure electrodepositable cathodic resin is disclosed. The resin is the reaction product of a polyepoxide amine adduct and a novel blocked crosslinking agent. The crosslinking agent of our invention is tetramethylxylene diisocyanate blocked with any suitable blocking agent. The resulting resin can be cured at relatively low temperatures (250.degree.-275.degree. F.), which potentially allows the use of the resin with articles containing plastics.
    Type: Grant
    Filed: November 23, 1988
    Date of Patent: February 13, 1990
    Assignee: E. I. Du Pont de Nemours & Company
    Inventors: Ding Yu Chung, Tapan K. DebRoy
  • Patent number: 4895673
    Abstract: Disclosed is an emulsion having a discontinuous phase which comprises at least two compounds of different structural formula selected from the group consisting of solvent-soluble polymers, oligomers, and monomers dissolved in an organic solvent, and a discontinuous phase which comprises an organic non-solvent for the compounds. A method of coating a conductor with a polymeric alloy is also disclosed. The conductor is immersed in the emulsion and a direct current is applied between the conductor and the emulsion sufficient to cause the discontinuous phase of the emulsion to migrate to the conductor and deposit on it. The conductor is removed from the emulsion and is dried and the deposit is cured.
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: January 23, 1990
    Assignee: Westinghouse Electric Corp.
    Inventors: William M. Alvino, Ram S. Raghava
  • Patent number: 4891111
    Abstract: Cationic electrocoating compositions comprising a cationic electrodepositable resin and particular hydroxyl-free, alkylated polyethers dispersed in an aqueous medium are disclosed. Due to the presence of the polyethers, the compositions electrodeposit at high film builds with good smoothness. However, the polyethers do not result in detrimental effects with regard to the properties of the compositions such as rupture voltage and corrosion resistance of the resultant electrodeposited film. Also, the particular polyethers readily incorporate in the electrodeposition bath, are non-volatile and do not significantly build up in the electrodeposition bath during the electrodeposition process.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: January 2, 1990
    Assignee: PPG Industries, Inc.
    Inventors: Gregory J. McCollum, Robert R. Zwack, Roger L. Scriven
  • Patent number: 4883572
    Abstract: A method for preparing an advanced epoxy cationic resin from an epoxy-based resin containing oxirane groups by converting at least some of the oxirane groups to cationic groups is improved by using as the epoxy-based resin a blend of (I) an epoxy-based resin obtained by reacting in the presence of a suitable catalyst (1) a diglycidylether of an aliphatic diol which diol is essentially free of ether oxygen atoms, such as a condensation product of 1,4-butanediol and epichlorohydrin, optionally (2) a diglycidylether of a diphenol, or example a diglycidyl ether of disphenol A, (3) a diphenol such as bisphenol A, and optionally (4) a capping agent such as p-nonylphenol and (II) a different cationic opoxy-based resin. Such resin blends can be utilized in cathodic electrodeposition coating systems.
    Type: Grant
    Filed: July 2, 1987
    Date of Patent: November 28, 1989
    Assignee: The Dow Chemical Company
    Inventors: Nancy A. Rao, Richard A. Hickner
  • Patent number: 4877502
    Abstract: A coating composition which is a uniformly dispersed admixture ofA. a fluid carrier; andB. a homopolymer or copolymer containing monomer units of the formula ##STR1## wherein R.sub.1 and R.sub.2 are preferably hydroxyalkyl and the polymer has a preferred average molecular weight in the range of from about 5,000 to about 30,000; andC. a poly(epoxide).
    Type: Grant
    Filed: July 18, 1988
    Date of Patent: October 31, 1989
    Assignee: Hoechst Celanese Corporation
    Inventors: Donna L. Keene, Darrell D. Hicks
  • Patent number: 4872961
    Abstract: Cathodic electrodepositable coating compositions comprising an aqueous dispersion of (1) at least one cationic epoxy-based resin, (2) at least one blocked isocyanate crosslinker, and (3) a solvent system containing one or more organic solvents are improved by (a) employing a blocked isocyanate crosslinker which deblocks at a temperature of less than about 160.degree. C., and (b) employing as the solvent system, one which is substantially free of any organic solvent which will react with isocyanate groups at the temperature employed to cure said coating.
    Type: Grant
    Filed: August 28, 1987
    Date of Patent: October 10, 1989
    Assignee: The Dow Chemical Company
    Inventors: John M. McIntyre, Kenneth W. Anderson, Nancy A. Rao, Richard A. Hickner
  • Patent number: 4869796
    Abstract: An electrodeposition coating composition comprising (a) a water-dispersible, electrically depositable binder resin and (b) water-insoluble, internally crosslinked polymer microparticles having a particle size from 0.01 to 2 microns, said polymer microparticles bearing on their surfaces physically adhered or covalently bound thereto an amphoionic group of the formula: ##STR1## wherein R represents an unsubstituted or substituted C.sub.1 -C.sub.6 alkylene or phenylene, A is --COOH or --SO.sub.3 H.
    Type: Grant
    Filed: August 5, 1987
    Date of Patent: September 26, 1989
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Kazunori Kanda, Hisaichi Muramoto, Koichi Saito, Shinichi Ishikura