Contacting With Nonsilicon-containing Sicp, Nonsilicon-containing Spfi, Or Polymer Thereof; Or With Two Or More Solid Polymers Patents (Class 525/101)
  • Patent number: 6576706
    Abstract: A flame-retardant polycarbonate resin composition comprising either a resin mixture of a polycarbonate resin and a styrenic resin, a functional group-having silicone compound, and a fluoro-olefin resin; or a polycarbonate resin, a functional group-having silicone compound, and a core/shell-type, grafted rubbery elastomer; or a resin mixture of a polycarbonate resin and a styrenic resin, a fluoro-olefin resin, an inorganic filler, and a polycarbonate-polyorganosiloxane copolymer and/or a functional group-having silicone resin, which composition and its moldings, exhibit good flame retardance, good impact resistance, and good thermal stability.
    Type: Grant
    Filed: January 30, 2001
    Date of Patent: June 10, 2003
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Akio Nodera, Masahiro Kitayama
  • Patent number: 6576737
    Abstract: A curable composition comprising (A) a fluorinated amide compound having at least one alkenyl radical, (B) a fluorinated organohydrogensiloxane, (C) a platinum group compound, (D) a first organosiloxane having at least one SiH radical and at least one epoxy and/or trialkoxysilyl radical, and (E) a second organosiloxane having at least one SiH radical, at least one cyclic carboxylic anhydride residue, and at least one monovalent perfluorooxyalkyl or perfluoroalkyl radical cures into a fluorinated elastomer that not only has good solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability and electrical properties, but also firmly bonds to a variety of substrates including PPS, polyamide and polyimide resins.
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: June 10, 2003
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mikio Shiono, Takashi Matsuda, Masatoshi Arai
  • Patent number: 6562887
    Abstract: The present invention relates to a polycarbonate resin composition comprising 100 parts by weight of a polycarbonate resin, 0.05 to 5 parts by weight of a silicone oil (BH) having a dynamic viscosity of not less than 10,000 mm2/s at 25° C., and 0.5 to 25 parts by weight of a composite rubber (C) having such structure that the polyorganosiloxane rubber component and the polyalkyl (meth)acrylate rubber component are interlocked to form a unitary composite.
    Type: Grant
    Filed: February 24, 2000
    Date of Patent: May 13, 2003
    Assignee: Mitsubishi Engineering-Plastics Corporation
    Inventors: Yoshihiro Kurasawa, Naoto Obayashi, Takashi Miyajima
  • Patent number: 6555619
    Abstract: The present invention relates to amphiphilic copolymer networks comprising polyisobutylene segments and poly(alkylene glycol) segments. The polyisobutylene segments of the amphiphilic networks are physically crosslinked by hydrophobic forces. The amphiphilic networks have particular use as coatings for biological implants. Also provided is a process for preparing a physically crosslinked amphiphilic copolymer network comprising: providing a block copolymer comprising polyisobutylene segments and poly(alkylene glycol) segments; introducing the block copolymer into an aqueous solvent; and allowing the block copolymer to self-assemble into physically crosslinked a copolymer network.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: April 29, 2003
    Assignee: The University of Akron
    Inventors: Joseph P. Kennedy, Pious Kurian
  • Patent number: 6552118
    Abstract: An adhesive curable composition which comprises, as the main component, a vinyl polymer having at least one crosslinkable silyl group represented by the general formula (1). Said composition can be used as a sealing composition, a pressure sensitive adhesive composition and a coating composition.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: April 22, 2003
    Assignee: Kaneka Corporation
    Inventors: Masayuki Fujita, Masato Kusakabe, Kenichi Kitano
  • Patent number: 6541548
    Abstract: There is provided an aromatic polycarbonate resin composition which exhibits high flame retardancy without sacrificing melt-molding stability or melt fluidity when molding the resin composition. The flame retardant aromatic polycarbonate resin composition comprises a resin component (a) comprising an aromatic polycarbonate and optionally a styrene polymer, the resin composition having an aromatic polycarbonate content of 20% by weight or more; and 0.1 to 50 parts by weight of an organopolysiloxane (b) comprising a linear organopolysiloxane (b)i and a cyclic organopolysiloxane (b)ii, component (b)ii present in an amount of from 5 to 95% by weight based on the total weight of components (b)i and (b)ii.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: April 1, 2003
    Assignees: Wacker-Chemie GmbH, Asahi Kasei Kabushiki Kaisha
    Inventors: Richard Weidner, Hiroji Oda
  • Patent number: 6541109
    Abstract: Release coating formulations and release coatings derived therefrom that incorporate a blend of a silicone vinyl copolymer and a second polymer for which the release qualities are extremely stable over time. The silicone vinyl copolymer and the second polymer include complementary crosslinkable functionality allowing interpolymer crosslinks to be formed.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: April 1, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Ramesh C. Kumar, Elda T. G. Bloemendal, Bruce C. Schmidt
  • Patent number: 6534185
    Abstract: A coating composition comprising A) at least one hydroxyl-containing polyacrylate containing in copolymerized form at least one polysiloxane macromonomer as binder and B) at least one tris(alkoxycarbonylamino)triazine as crosslinking agent, and its use to produce multicoat clearcoats and multicoat topcoats.
    Type: Grant
    Filed: June 18, 2001
    Date of Patent: March 18, 2003
    Assignee: BASF Coatings AG
    Inventors: Hubert Baumgart, Thomas Farwick, Ulrich Poth, Ulrike Röckrath, Andrea Zumbrink
  • Patent number: 6531525
    Abstract: An abherent composition which contains (A) a compound having C4-C20 perfluoro-alkyl or alkenyl group, (B) polytetrafluoroethylene having a number-average molecular weight of at most 500,000, and (C) at least one compound selected from the group consisting of a silicone oil, a silicone resin and a highly fluorinated compound having a boiling point of at least 100° C. except those included in the components (A) and (B), is disclosed. This composition prevents various articles from adhering to each other and is suitable as a mold release agent, an anti-blocking agent, a stripping agent for an electrical wire and the like.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: March 11, 2003
    Assignee: Daikin Industries, Ltd.
    Inventors: Masayuki Yamana, Tsukasa Aga
  • Patent number: 6528584
    Abstract: Multicomponent networks or membranes of the present invention have good mechanical properties that are permeable to water, hydrocarbons, and oxygen. The networks contain at least two and preferably at least three covalently combined domains, i.e., a hydrophilic, a lipophilic and an oxyphilic polymer segment, that give rise to a multicontinuous domain microstructure. At least one of these domains includes poly(ethylene glycol).
    Type: Grant
    Filed: April 12, 2001
    Date of Patent: March 4, 2003
    Assignee: The University of Akron
    Inventors: Joseph P. Kennedy, Pious V. Kurian
  • Publication number: 20030027928
    Abstract: Provided are polycarbonate resin compositions as described in (i) to (iii) below.
    Type: Application
    Filed: December 10, 1999
    Publication date: February 6, 2003
    Inventors: MASAYA OKAMOTO, AKIO NODERA, MASAHIRO KITAYAMA
  • Patent number: 6515041
    Abstract: A high energy radiation-curable composition comprising a partial hydrolysis-condensation product of (A) a mixture of an alkoxy containing organopolysiloxane and alkoxysilanes and (B) a multifunctional acrylate, and a resin molding coated with the composition. The composition forms coatings of superior curability, water repellency, water resistance, oil repellency, transparency, flexibility, and scratch resistance, especially on resin moldings.
    Type: Grant
    Filed: June 26, 2001
    Date of Patent: February 4, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Masayuki Hayashi, Hideki Kobayashi
  • Patent number: 6515043
    Abstract: An oligomer of the formula: [R3SiO½]m[O½Si(R2)O½]n[SiO{fraction (3/2)}R]o[SiO{fraction (4/2)}]p  (I) wherein each R is selected individually from the group consisting of R1, —OR2 and —OR3; each R1 is independently a substituted or unsubstituted hydrocarbon group; each R2 is a C1-C6 alkyl group or an acyl group; and each R3 is a independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that if R3 is alkenyl, there is no unsaturation within two carbon atoms adjacent to the oxygen atom of the —OR3 group; at least one R group is —OR3; at least one quarter of all R groups are —OR2 or —OR3; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10. The oligomer is a useful component of in insulation formulations for wire and cable used in underground locations.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: February 4, 2003
    Assignee: Crompton Corporation
    Inventors: Herbert B. Petty, Robert Pickwell
  • Publication number: 20030018130
    Abstract: A curable polymer composition capable of achieving rapid curing, reduced viscosity, high solids content, and a very low or zero volatile organic compound content includes a hyperbranched polymer having functional groups of a first type and a polymer having functional groups of a second type, wherein the functional groups of the second type are reactive with the functional groups of the first type under at least certain conditions. The composition can be cured to form a cross-linked nano-domained network comprising covalently bonded nanoscopic, hyperbranched domains which may be of the same or different chemical composition than the rest of the network. The cured compositions may exhibit high thermal stability, mechanical strength and toughness.
    Type: Application
    Filed: September 16, 2002
    Publication date: January 23, 2003
    Inventors: Petar R. Dvornic, Jin Hu, Dale J. Meier, Robert M. Nowak
  • Patent number: 6497960
    Abstract: The resin composition for a skin member according to the present invention comprises a completely or partially crosslinked olefin thermoplastic elastomer (A) in an amount of 100 parts by weight, an organopolysiloxane (B) having a viscosity (JIS K2283, 25° C.) of not less than 1×106 cSt, preferably 1×106 to 1×108 cSt in an amount of 2 to 20 parts by weight, an organopolysiloxane (C) having a viscosity (JIS K2283, 25° C.) of not less than 10 cSt and less than 1×106 cSt in an amount of 0.5 to 5 parts by weight, and optionally, a polyolefin resin (D) in an amount of 5 to 150 parts by weight and/or a fluoropolymer (E) in an amount of 0.5 to 10 parts by weight. The other resin composition for a skin member according to the invention comprises a completely or partially crosslinked olefin thermoplastic elastomer (A) in an amount of 100 parts by weight, a fluoropolymer (E) in an amount of 0.
    Type: Grant
    Filed: July 20, 1999
    Date of Patent: December 24, 2002
    Inventors: Kyoko Kobayashi, Masato Karaiwa, Kunihiko Mizumoto, Akira Uchiyama
  • Patent number: 6498206
    Abstract: A resin composition suitable as an impact modifier for thermoplastic resins, which has an excellent blocking resistance improved without lowering the effect of improving the impact resistance and which comprises 100 parts by weight of a graft copolymer containing a hollow rubber component and at least two additives selected from the group consisting of 0.1 to 10 parts by weight of a higher fatter acid soap, 0.1 to 10 parts by weight of a crosslinked polymer of 0.1 to 100% by weight of a crosslinking monomer and 0 to 99.9% by weight of a vinyl monomer and 0.001 to 5 parts by weight of a silicone oil.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: December 24, 2002
    Assignee: Kaneka Corporation
    Inventors: Tosio Mizuta, Akio Sato, Tomomichi Hashimoto, Mitsuo Kakutani, Akira Takaki
  • Patent number: 6492475
    Abstract: The present invention relates to an ethylene-&agr;-olefin copolymer; a composition thereof; a film thereof; a polar group-containing resin material; and productions and use of the ethylene-&agr;-olefin copolymer. The ethylene-&agr;-olefin copolymer of the present invention is characterized in satisfying the following conditions (A) to (E): (A) a density in the range of 0.92 to 0.96 g/cm3; (B) a melt flow rate (MFR) in the range of 0.01 to 200 g/10 min; (C) a molecular weight distribution (Mw/Mn) in the range of 1.5 to 5.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: December 10, 2002
    Assignee: Japan Polyolefins Co., Ltd.
    Inventors: Toshiaki Egashira, Reiji Higuchi, Kazuyuki Sakamoto, Kimiya Miyoshi, Masahiro Wakayama, Tatsuo Yamaguchi, Fumio Asada, Sinji Miwa, Kenichi Hiraki, Masaaki Ikeda, Yoshimi Shimizu
  • Patent number: 6476132
    Abstract: A thermoplastic vulcanizate (TPV) from a blend of a first thermoplastic polyolefin, a second thermoplastic olefin and a rubber is described. The rubber is crosslinked with a hydrosilylation crosslinking agent. The second polyolefin includes at least one OR group pendant to a Si atom chemically attached via one or more intermediate molecules to said second polyolefin. R can be hydrogen or an alkyl of 1 to 8 carbon atoms. The OR groups can react with the hydrosilylation catalyst to reduce the compression set of the TPV.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: November 5, 2002
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Sabet Abdou-Sabet, Robert E. Medsker, Raman Patel
  • Patent number: 6451156
    Abstract: A pressure-sensitive adhesive sheets comprising a layer of a crosslinked pressure-sensitive adhesive, which is formed by an acrylic polymer made of a homopolymer or copolymer of a monomer containing a (meth)acrylate as a principal component, a silane coupling agent and a crosslinking agent, wherein a sol component of the crosslinked pressure-sensitive adhesive has a weight-average molecular weight of not less than 300,000 and a proportion of a low-molecular component having a molecular weight of not more than 100,000 in the sol component is not more than 15% by weight in the measurement of the molecular weight by the gel permeation chromatography method, which the sheet cause neither lifting nor formation of bubbles at the bonding interface even when exposed to severe conditions such as high temperature or high temperature and humidity in case a functional film is bonded/fixed to a display device, thus making it possible to maintain good appearance for a long period.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: September 17, 2002
    Assignee: Nitto Denko Corporation
    Inventors: Hiroaki Kishioka, Masahiro Ohura, Takao Yoshikawa
  • Patent number: 6447913
    Abstract: To provide a thermoplastic polyester resin composition which has a very good durability to alkaline solutions for a long period of time. That is, a thermoplastic polyester resin composition, wherein a thermoplastic polyester resin (A) is compounded with 1-25% by weight (in the total composition) of impact resistance rendering materials (B), 0.1-15% by weight (in the total composition) of a silicone compound and/or a fluorine compound (C), 1-50% by weight (in the total composition) of an inorganic filler (D), and 0.1-10% by weight of at least one polyfunctional compound (E) selected from the group consisting of an epoxy compound, an isocyanate compound and a carboxylic acid dianhydride. A molded article of the present invention has anti-stress properties even in a weld part thereof.
    Type: Grant
    Filed: January 25, 2001
    Date of Patent: September 10, 2002
    Assignees: Polyplastics Co., LTD, Denso Corporation
    Inventors: Kazufumi Watanabe, Takayuki Ishikawa, Toru Katsumata, Tetsuya Hirose, Hiroyuki Wakabayashi
  • Patent number: 6420504
    Abstract: Radical-polymerizable organic group-containing branched siloxane-silalkylene copolymer represented by the general formula: {in the formula, Y is a radical-polymerizable organic group, R1 is 1-10 carbon alkyl or aryl, and X1 is a silyl-alkyl group represented by the following formula in the case when i=1: (in the formula, R1 is the same as aforesaid, R2 is 2-10 carbon alkylene, R3 is 1-10 carbon alkyl, and Xi+1 is a group selected from the group comprising a hydrogen atom, 1-10 carbon alkyl, aryl and the aforesaid silylalkyl group, i is an integer from 1 to 10, which indicates the generation number of the said silylalkyl group and ai is an integer from 0 to 3)}, silicone-containing organic polymer made by polymerizing the said copolymer and method for production thereof.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: July 16, 2002
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Makoto Yoshitake, Haruhiko Furukawa, Yoshitsugu Morita
  • Patent number: 6407158
    Abstract: The present invention relates to a water-soluble or water-dispersible polymeric salt, to a cosmetic or pharmacuetical composition which comprises at least one such polymeric salt, and to the use of the polymeric salts.
    Type: Grant
    Filed: March 20, 2000
    Date of Patent: June 18, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Son Nguyen Kim, Axel Sanner, Peter Hössel
  • Patent number: 6407166
    Abstract: A vulcanizate that has improved damping properties where the vulcanizate is prepared by the steps comprising blending an unsaturated damping additive within a vulcanizable composition of matter, wherein the vulcanizable composition of matter includes a vulcanizable elastomer, and effecting vulcanization of the elastomer.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: June 18, 2002
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz, Edward D. Kelley, Tatsuro Hamada, Michael W. Hayes
  • Patent number: 6407165
    Abstract: A method for increasing the damping properties of tire rubber comprising the steps of adding an unsaturated damping additive to a vulcanizable composition of matter, and processing the vulcanizable composition of matter containing the damping additive into tire rubber.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: June 18, 2002
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor J. Foltz, Michael W. Hayes, Peyman Pakdel
  • Publication number: 20020068796
    Abstract: There is disclosed a pneumatic tire having a rubberized component comprising:
    Type: Application
    Filed: July 24, 2001
    Publication date: June 6, 2002
    Inventors: Uwe Ernst Frank, Friedrich Visel, Thierry Florent Edme Materne, Rene Jean Zimmer, Wolfgang Lauer, Marc Weydert, Thomas Schildbach, Annette Lechtenbohmer, Maurice Peter Catharina Jozef Klinkenberg
  • Patent number: 6395856
    Abstract: Oligomers of the formula: [R3SiO1/2]m[O1/2Si(R2)O1/2]n[SiO3/2R]o[SiO4/2]p  (I) wherein each R is selected individually from the group consisting of B, R1, —OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated aliphatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1, an aromatic hydrocarbon group or an acyl group; each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from aromatic hydrocarbon, ether, ester, carbamate, thioether, polysulfide, blocked mercaptan, amide, epoxy, cyano an
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: May 28, 2002
    Assignee: Crompton Corporation
    Inventors: Herbert E. Petty, Robert Pickwell, Frederick D. Osterholtz, Shiu-Chin Huang Su
  • Patent number: 6376607
    Abstract: Improved powder coating compositions containing novel polysiloxanes having various reactive functional groups are disclosed. The compositions are particularly useful as thermosetting powder coating compositions where they provide excellent filiform corrosion resistance.
    Type: Grant
    Filed: February 9, 2000
    Date of Patent: April 23, 2002
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Ronald R. Ambrose, Truman F. Wilt, Anthony M Chasser, John R. Schneider
  • Patent number: 6375789
    Abstract: Powder coating formulations include as a component thereof a silane formula I: where R1 is a hydrocarbon, acyl, alkylsilyl or alkoxysilyl group; R2 is a monovalent hydrocarbon group; R3 is alkylene, optionally interrupted with one or more ether oxygen atoms; a is 0 or 1; Z is a direct bond or a divalent organic linking group; X is an m-valent organic group or H; and m is 1-20. The silanes are useful as crosslinkers, property modifiers and/or adhesion promoters. Powder adhesives may be similarly formed with silanes of formula I.
    Type: Grant
    Filed: April 12, 2000
    Date of Patent: April 23, 2002
    Assignee: Crompton Corporation
    Inventors: Lawrence E. Katz, Hebert E. Petty, Shiu-Chin Huang Su, Bruce A. Waldman
  • Patent number: 6365699
    Abstract: A curable composition and process of applying the composition and the resulting composite coatings provide improved resistance to acid etch and mar. The curable composition has (a) about 30 to 90 percent by weight, based on total weight of resin solids, of a film-forming composition selected from the group consisting of: (i) a polyepoxide and a polyacid crosslinking agent; (ii) an acrylosilane polymer, an acrylic polyol polymer, and optionally an alkylated melamine-formaldehyde crosslinking agent; and (iii) a polyisocyanate and a polymer having at least one group that is reactive with isocyanate; and (b) about 10 to 70 percent by weight, based on total weight of resin solids, of a tricarbamoyl triazine compound of the formula: C3N3(NHCOXR)3 wherein X is nitrogen, oxygen, sulfur, phosphorus, or carbon, and R is a lower alkyl group having 1 to 12 carbon atoms, or mixtures of lower alkyl groups.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: April 2, 2002
    Assignee: PPG Industries Ohio, Inc.
    Inventors: George W. Mauer, James A. Meier, Lynne R. Stahl
  • Patent number: 6365672
    Abstract: A process for making a polysiloxane block copolymer which is built up from units of the formula [A] [B], in which A is a polymeric block built up from radically polymerisable monomer, and B is a polysiloxane block, the process comprising the steps of polymerising a radically polymerisable monomer in the presence of an atom transfer radical initiator to form an polymer which is end-functionalized with a leaving group capable of nucleophilic substitution by nucleophilic end-groups on a polysiloxane, and reacting the polymer with a polysiloxane having nucleophilic end-groups so that a polysiloxane block copolymer is formed via a nucleophilic displacement reaction between the end-groups on the polysiloxane and leaving groups on the polymer respectively. Also provided is a cosmetic and personal care composition, such as a hair styling composition, comprising the polysiloxane block copolymer as described above.
    Type: Grant
    Filed: May 23, 2000
    Date of Patent: April 2, 2002
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Gerald Adams, Ezat Khoshdel, Anthony Moretta, Yvonne Christine Plant, Euan Stuart Reid
  • Patent number: 6359081
    Abstract: A functional block copolymer useful as a compatibilizing agent for a blend of a condensation polymer and vinyl polymer comprises segments of a condensation polymer and a vinyl polymer derived from a reactive functional group-containing monomer or a functions-imparting monomer such as ultraviolet absorption or flame retardant functions. The block copolymer can further include a segment of a lower cohesive energy polymer. The condensation or vinyl polymer segment, or the lower cohesive energy polymer segment contains azo or peroxide groups which act as a polymerization initiator for the copolymerization of the vinyl monomer forming the vinyl polymer segment.
    Type: Grant
    Filed: April 19, 2000
    Date of Patent: March 19, 2002
    Assignees: Takiron Co., Ltd., Osaka Municipal Government
    Inventors: Masayuki Shimada, Yasuyuki Agari, Yoichiro Makimura
  • Patent number: 6355757
    Abstract: The invention is directed to essentially saturated hydrocarbon polymer composition comprising essentially saturated hydrocarbon polymers having A) a backbone chain, B) a plurality of essentially hydrocarbyl sidechains connected to A), said sidechains each having a number-average molecular weight of from 2500 Daltons to 125,000 Daltons and a MWD by SEC of 1.0-3.5; and having A) a Newtonian limiting viscosity (&eegr;0) at 190° C. at least 50% greater than that of a linear olefinic polymer of the same chemical composition and weight average molecular weight, preferably at least twice as great as that of said linear polymer, B) a ratio of the rubbery plateau modulus at 190° C. to that of a linear polymer of the same chemical composition less than 0.5, preferably <0.3, C) a ratio of the Newtonian limiting viscosity (&eegr;0) to the absolute value of the complex viscosity in oscillatory shear (&eegr;*)at 100 rad/sec at 190° C.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: March 12, 2002
    Assignee: ExxonMobil Chemical Patents, Inc.
    Inventors: Cesar A. Garcia-Franco, David J. Lohse, Robert A. Mendelson, Lewis J. Fetters, Scott T. Milner, Nikos Hadjichristidis, David W. Mead
  • Patent number: 6355352
    Abstract: A fuser member comprising a support and a layer overlying the support, the layer including a fluorocarbon thermoplastic random copolymer, a curing agent having a bisphenol residue, a particulate filler containing zinc oxide, an aminosiloxane, and antimony-doped tin oxide particles, the cured fluorocarbon thermoplastics random copolymer having subunits of: -(CH2CF2)x-, -(CF2CF(CF3)y-, and -(CF2CF2)z-, wherein x is from 1 to 50 or 60 to 80 mole percent, y is from 10 to 90 mole percent, z is from 10 to 90 mole percent, and x+y+z equal 100 mole percent.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: March 12, 2002
    Assignee: NexPress Solutions LLC
    Inventors: Jiann H. Chen, Joseph A. Pavlisko, Charles C. Anderson
  • Publication number: 20020028879
    Abstract: A powder coating composition of a solid particulate film-forming mixture including (a) a carbamate group-containing polymer having a glass transition temperature of at least 30° C.; and (b) a curing agent having functional groups reactive with the carbamate functional groups of the polymer. Also provided is a multi-component composite coating composition characterized by a pigmented basecoat deposited from a pigmented film-forming composition and a substantially pigment-free top coat applied over the basecoat. The top coat is deposited from the powder coating composition. A method of forming a wrinkled coating on a substrate is further provided where a curable powder coating composition is prepared from a solid particulate film-forming mixture, applied to a substrate and thermally cured to form a continuous coating having a wrinkled surface. The solid particulate film-forming mixture includes (a) a carbamate functional group-containing polymer having a glass transition temperature at least 30° C.
    Type: Application
    Filed: September 4, 2001
    Publication date: March 7, 2002
    Inventors: Anthony M. Chasser, Paul H. Lamers, John R. Schneider, Ronald R. Ambrose
  • Patent number: 6348544
    Abstract: The present invention is directed to a tintable coating composition, comprising an admixture of: (A) about 2 to about 80 wt % of a carboxylated urethane polymer dispersion mixture made from 1,6-hexanediol and 4,4-methylenebis(cyclohexylisocyanate); (B) about 5 to about 65 wt % of a hydroxylated methylmethacrylate acrylic polymer emulsion; (C) about 0.1 to about 3 wt % of a crosslinking agent, the crosslinking agent comprising an aziridine-based crosslinking compound; and (D) optionally, about 0.5 wt % to about 25 wt % of a solvent; all percentages based on the total weight of the coating composition. The coating composition of the present invention may be used as a clear coating, or may include a decorative component such as dyes, pigments, colorants, metal flakes, metal powders, glass flakes, glass powders, and combinations thereof, that add a decorative or colored characteristic to the disclosed coating composition.
    Type: Grant
    Filed: May 10, 2000
    Date of Patent: February 19, 2002
    Assignee: Olin Corporation
    Inventor: Efraim Sagiv
  • Patent number: 6344521
    Abstract: Terminally functionalized silicone triblock copolymers prepared using protected functionalized initiators and processes for preparing the same. The silicone triblock copolymers includes protected, functionalized silicone diene and/or alkenylsubstituted aromatic copolymers. The protected functionalized copolymers can be optionally deprotected to afford functionalized silicone diene and/or alkenylsubstituted aromatic copolymers.
    Type: Grant
    Filed: January 10, 2000
    Date of Patent: February 5, 2002
    Assignee: FMC Corporation
    Inventors: James Anthony Schwindeman, Robert James Letchford
  • Patent number: 6333368
    Abstract: A curable composition useful in water-based paints comprises a water-based product obtained by dispersing or dissolving in water a vinyl polymer (II) containing tertiary amino and/or acidic groups which have been neutralized by an acidic or basic compound, an epoxy and hydrolysable silyl groups-containing compound (B), and a hydrolysable silyl and/or silanol groups-containing compound (F).
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: December 25, 2001
    Assignee: Dainippon Ink & Chemicals, Inc.
    Inventors: Nobuo Harui, Masataka Ooka
  • Patent number: 6323277
    Abstract: Oligomers of the formula: [R3SiO½]m[O½Si(R2)O½]n[SiO{fraction (3/2)}R]o[SiO{fraction (4/2)}]p  (I) wherein each R is selected individually from the group consisting of B, R1,—OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated or aromatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1 or an acyl group; and each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from ether, polyether, ester, polyester, carbamate, polyurethane, isocyanurate, thioether, polysulfide
    Type: Grant
    Filed: March 11, 1999
    Date of Patent: November 27, 2001
    Assignee: Witco Corporation
    Inventors: Herbert E. Petty, Robert Pickwell
  • Patent number: 6319976
    Abstract: A polymer blend containing (1) about 1% to about 98% of a graft copolymer comprising a backbone of a propylene polymer material having graft polymerized thereto monomers selected from (a) at least one vinyl aromatic compound and an unsaturated carboxylic acid and b) at least one vinyl aromatic compound and an anhydride of an unsaturated acid or its acid form, wherein the polymerized monomers are present in an amount of about 10 to about 95 parts per hundred parts of the propylene polymer material, (2) about 99% to about 2% of at least one polyamide resin, and (3) about 5% to about 90% of a broad molecular weight distribution propylene polymer material. The composition optionally also contains about 2% to about 30% of one or more rubber components, and an additive to improve the scratch and mar resistance of the composition.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: November 20, 2001
    Assignee: Montell Property Company BV
    Inventors: Anthony J. DeNicola, Jr., Tam T. M. Phan
  • Patent number: 6320010
    Abstract: By incorporating (A) a saturated hydrocarbon polymer having more than one alkenyl group capable of being hydrosilylated in each molecule and having a molecular weight of 2,000 to 50,000, (B) a component comprising a compound containing more than two silicon atom-bound hydrogen atoms, on average, in each molecule, (C) a compound having, within the molecule, one alkenyl group capable of being hydrosilylated, (D) a compound having, within the molecule, at least two alkenyl groups capable of being hydrosilylated and having a molecular weight less than 2,000, and (E) a hydrosilylation catalyst, a composition having good mechanical characteristics, a high gel fraction and a small heating loss can be obtained. As a result, the invention can provide a composition to secure the uniformity within a wide range of selection not depending on its viscosity, because it is markedly relaxed the restriction on SiH-containing compounds that are curing agents possibly becoming a cause of said insufficient curing.
    Type: Grant
    Filed: March 27, 2000
    Date of Patent: November 20, 2001
    Assignee: Kaneka Corporation
    Inventors: Masashi Sakaguchi, Yoshimichi Yamanaka, Hidenari Tsunemi
  • Patent number: 6309730
    Abstract: A releasing film comprising: a base film produced from a polyethylene naphthalate, and a releasing layer formed on one or both sides of the base film, wherein the polyethylene naphthalate contains naphthalenedicarboxylic acid as the main acid component and ethylene glycol as the main glycol component and further contains a manganese compound, a phosphorus compound and an antimony compound in Mn, P and Sb amounts satisfying all of the following formulas (1) to (3): 0.7≦Mn≦1.6  (1) 0.5≦Mn/P≦1.2  (2) 0.7≦Sb≦2.2  (3) (wherein Mn is moles of manganese element per 106 g of acid component; P is moles of phosphorus element per 106 g of acid component; and Sb is moles of antimony element per 106 g of acid component), and the base film has a surface center line average roughness (Ra) of 2 to 50 nm.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: October 30, 2001
    Assignee: Teijin Limited
    Inventor: Hiroyuki Sumi
  • Patent number: 6294607
    Abstract: An ultra-high solids coating composition is disclosed. The composition comprises a polyol blend of a liquid acrylic polyol and a resinous polyol. The polyol blend is crosslinked with a multifunctional isocyanate, melamine, or silane to form a variety of coatings. The coating composition has a significantly higher solid % than that is formulated from a single resin that has similar composition of the combination of the polyol blend. The coatings include less than about 35% by weight of an organic solvent.
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: September 25, 2001
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Shao-Hua Guo, Daniel B. Pourreau, Wei Wang
  • Patent number: 6291021
    Abstract: A highly weathering-resistant coating material exhibits an excellent water resistance and water repellency. The coating material contains a vinyl-type polymer that contains a pendant carbosiloxane dendrimer structure. The coating material is used on construction materials, buildings and structures undercoated with an organic coating material, automobiles, railroad rolling stock, ships, aircraft, and bridges, commercial and industrial plants, and electrical and electronic instruments and devices.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: September 18, 2001
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yoshitsugu Morita, Haruhiko Furukawa, Takayuki Aso
  • Patent number: 6288163
    Abstract: A paint composition includes from about 1 to about 41% by volume of a silicone caulking, from about 1 to about 41% by volume of mineral spirits and from about 18 to about 98% by volume of a paint. The paint composition provides good repellency against graffiti and is not sacrificial in nature.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: September 11, 2001
    Inventor: Louis-Marie Joseph Martin
  • Patent number: 6277481
    Abstract: An adhesive composition comprising a pressure sensitive adhesive component (A), a thermosetting adhesive component (B) and a compound (C) obtained by addition/condensation reaction of a polysiloxane oligomer with a silane coupling agent. This composition is excellent in storage stability and can bond metals, etc. with large bonding strength. Further, sheeting thereof enables simplifying bonding steps.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: August 21, 2001
    Assignee: Lintec Corporation
    Inventors: Takashi Sugino, Hideo Senoo, Yasukazu Nakata
  • Patent number: 6274671
    Abstract: This invention relates to a coating resin composition including an acrylic resin (A) having a hydroxyl group and an alicyclic epoxy group attached to side chains thereof, an alicyclic epoxy resin (B) having an epoxy equivalent weight of 100-1000, an organoalkoxy silane compound (C) having a glycidyl group and a hydrolyzable alkoxy silane group contained in one molecule thereof, and an aluminum chelate compound (D). The composition is stably storable, highly curable at low temperature (80° C. or below) and capable of producing a highly weatherable coating, and is useful particularly as a coating resin composition of a one-pack type and a coating derivable therefrom. The composition also exhibits various superior coating performance characteristics (bonding, appearance, weathering resistance, chemical resistance, solvent resistance and the like) in a well-balanced state.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: August 14, 2001
    Assignee: Toray Industries, Inc.
    Inventors: Ichiji Kageishi, Yoshitaka Osanai, Yumi Ando
  • Patent number: 6274672
    Abstract: Improved powder coating compositions containing novel polysiloxanes having various reactive functional groups are disclosed. The compositions are particularly useful as thermosetting powder coating compositions where they provide excellent filiform corrosion resistance.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: August 14, 2001
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Ronald R. Ambrose, Truman F. Wilt, Anthony M. Chasser, John R. Schneider
  • Patent number: 6268456
    Abstract: A sprayable coating composition that contains at least one soluble film-forming silicon-containing compound having, on average, more than one fuctionalized silicon group, a volatile organic carrier, a polymer microparticle component, and a catalyst; a substrate coated with the composition; a process for coating the substrate to provide a protective finish; the finish-protected substrate; certain oligomeric compounds and a process therefor.
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: July 31, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Basil V. Gregorovich, Isidor Hazan, Robert Rudolph Matheson, Lech Wilczek
  • Patent number: 6268440
    Abstract: A water-base resin has both excellent storage stability and excellent curability at room temperature, the water base resin being obtained by mixing a composite resin (C) and a polysiloxane (D), bringing about a condensation reaction partially between them if necessary, and thereafter dispersing or dissolving the resulting mixture or partially condensed product into a water-base medium, wherein the composite resin (C) comprises a polysiloxane segment (A) and a polymer segment (B), the polysiloxane segment (A) having at least one silicon atom selected from the group consisting of a silicon atom bearing at least one organic group having a total carbon number of at least 3 together with at least one hydrolyzable group and/or at least one hydroxyl group, a silicon atom bearing one hydrolyzable group or one hydroxyl group together with two groups selected from the group consisting of methyl groups and ethyl groups, and a silicon atom bearing at least one triorganosiloxy group together with at least one hydrolyzable
    Type: Grant
    Filed: January 29, 1999
    Date of Patent: July 31, 2001
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Shin-ichi Kudo, Hiroshi Kinoshita, Masataka Ooka
  • Patent number: 6261642
    Abstract: This invention provides a thermosetting high solids coating composition comprising: (A) a copolymer prepared by polymerizing monomer components comprising (a) 30 to 50 wt. % of vinyltrimethoxysilane and/or vinyltriethoxysilane, (b) 5 to 15 wt. % of N-methylol(meth)acrylamide alkyl ether and (c) 35 to 65 wt. % of another polymerizable unsaturated monomer, (B) a hydroxyl-containing resin having a hydroxyl value of 10 to 200 mg KOH/g, and (C) a curing catalyst. This invention further provides a method for forming a topcoat using said composition. The composition of the invention achieves the following remarkable effects: it forms a coating film excellent in acid resistance and scratch resistance, and it is superior in storage stability and recoat adhesion.
    Type: Grant
    Filed: January 7, 2000
    Date of Patent: July 17, 2001
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Kenichi Nagai, Masaaki Saika, Haruhiko Aida, Motoshi Yabuta, Hiroshi Igarashi, Yasumasa Okumura