Abstract: The invention relates to polyolefin copolymers (I) 1

Abstract: Oligomers of the formula: [R3SiO½]m[O½Si(R2)O½]n[SiO{fraction (3/2)}R]o[SiO{fraction (4/2)}]p  (I) wherein each R is selected individually from the group consisting of B, R1,—OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated or aromatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1 or an acyl group; and each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from ether, polyether, ester, polyester, carbamate, polyurethane, isocyanurate, thioether, polysulfide

Abstract: By incorporating (A) a saturated hydrocarbon polymer having more than one alkenyl group capable of being hydrosilylated in each molecule and having a molecular weight of 2,000 to 50,000, (B) a component comprising a compound containing more than two silicon atom-bound hydrogen atoms, on average, in each molecule, (C) a compound having, within the molecule, one alkenyl group capable of being hydrosilylated, (D) a compound having, within the molecule, at least two alkenyl groups capable of being hydrosilylated and having a molecular weight less than 2,000, and (E) a hydrosilylation catalyst, a composition having good mechanical characteristics, a high gel fraction and a small heating loss can be obtained. As a result, the invention can provide a composition to secure the uniformity within a wide range of selection not depending on its viscosity, because it is markedly relaxed the restriction on SiH-containing compounds that are curing agents possibly becoming a cause of said insufficient curing.

Abstract: The present invention has its objects to provide a curable composition for coatings which can provide coatings or paint films excellent in acid resistance, scratch resistance, stain resistance and heat curability, with very good weather resistance and appearance; and coated articles and a resin composition obtained from the curable composition.

Abstract: A water-base resin has both excellent storage stability and excellent curability at room temperature, the water base resin being obtained by mixing a composite resin (C) and a polysiloxane (D), bringing about a condensation reaction partially between them if necessary, and thereafter dispersing or dissolving the resulting mixture or partially condensed product into a water-base medium, wherein the composite resin (C) comprises a polysiloxane segment (A) and a polymer segment (B), the polysiloxane segment (A) having at least one silicon atom selected from the group consisting of a silicon atom bearing at least one organic group having a total carbon number of at least 3 together with at least one hydrolyzable group and/or at least one hydroxyl group, a silicon atom bearing one hydrolyzable group or one hydroxyl group together with two groups selected from the group consisting of methyl groups and ethyl groups, and a silicon atom bearing at least one triorganosiloxy group together with at least one hydrolyzable

Abstract: A process for preparing blends of syndiotactic 1,2-polybutadiene and rubbery elastomers comprising the steps of (1) providing a mixture of high cis-1,4-polybutadiene rubber cement and 1,3-butadiene monomer, and (2) combining (a) an iron-containing compound, (b) a hydrogen phosphite, and (c) an organoaluminum compound to form a catalyst composition outside the presence of the mixture of rubber cement and monomer, and (3) adding the catalyst composition to the mixture and thereby polymerizing the 1,3-butadiene monomer into syndiotactic 1,2-polybutadiene within the rubber cement.

Abstract: A curable topcoat composition comprising (A) 100 to 30 parts by weight of a vinyl copolymer having a main chain substantially composed of a vinyl copolymer, having both at least one specific hydrolyzable silyl group and at least one hydroxyl group in its main chain end and/or side chain, and having a carbonato structure in its main chain and/or side chain, (B) 0.001 to 70 parts by weight of a hydroxyl group-containing compound having no hydrolyzable silyl group, and (C) a solvent, the total of the components (A) and (B) being 100 parts by weight. The coating films formed from the curable composition are excellent in acid resistance, scratch resistance, appearance and thermosetting property and, in particular, the composition can be suitably used as a top coat for automobiles.

Abstract: Use of an effective amount of a specific combination of silicone compounds comprising the combination: of at least one functionalized polyorganosiloxane (abbreviated as POS) containing, per molecule, at least one functional siloxy unit (abbreviated as UN1) capable of binding chemically and/or physically with the hydroxylated surface sites of the silica particles, and of at least one functionalized organosilane (abbreviated as OS) containing, per molecule, at least one functional group (abbreviated as G1) capable of binding chemically and/or physically with the UN1 units and/or the hydroxylated sites of the silica particles and at least one other functional group (abbreviated as G2) capable of binding chemically and/or physically to the elastomer chains, as silica/elastomer coupling agent in the natural or synthetic elastomer compositions comprising a siliceous material as reinforcing filler intended for the manufacture of an article made of elastomer(s).

Abstract: An oligomer of the formula: [R3SiO1/2]m[O1/2Si(R2)O1/2]n[SiO3/2R]o[SiO4/2]p  (I) wherein each R is selected individually from the group consisting of R1, —OR2 and —OR3; each R1 is independently a substituted or unsubstituted hydrocarbon group; each R2 is a C1-C6 alkyl group or an acyl group; and each R3 is a independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that if R3 is alkenyl, there is no unsaturation within two carbon atoms adjacent to the oxygen atom of the —OR3 group; at least one R group is —OR3; at least one quarter of all R groups are —OR2 or —OR3; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10. The oligomer is a useful component of in insulation formulations for wire and cable used in underground locations.

Abstract: Blends of syndiotactic 1,2-polybutadiene and rubbery elastomers are prepared by a process that comprises polymerizing 1,3-butadiene monomer into syndiotactic 1,2-polybutadiene within a rubber cement of at least one rubbery elastomer by using an iron-based catalyst composition that is formed by combining an iron-containing compound, a hydrogen phosphite, and an organoaluminum compound.

Abstract: Solid blends of rubbery polymers and amorphous or crystalline polymers, said blends being free-flowing at temperatures lower than the glass transition temperature or crystalline melting temperature of the amorphous or crystalline polymer, are prepared by intimate mixing procedures. In general, said mixing conditions include high shear conditions sufficient to convert polymer A to dispersed particles coated with polymer B and produce a free-flowing blend.

Abstract: A composition is comprised of the following: a) a hydrolyzed or partially hydrolyzed alkoxysilane; b) a solvent consisting of an organic liquid or mixture of two or more organic liquids in which component (a) and component (c) are soluble and c) a cross linking prepolymer, oligomer, resin or mixtures thereof that forms a low dielectric constant crosslinked polymer. Preferred crosslinked polymers are of a arylcyclobutene or polyphenylene prepolymer, oligomer, resin or mixtures thereof. A coating may be made using the composition wherein the coating is comprised of a crosslinked polymer of a low dielectric crosslinking prepolymer, oligomer, resin or mixture thereof and a hydrolyzed or partially hydrolyzed alkoxysilane, said coating being adhered to a surface of a substrate wherein said surface is comprised of a first material that is a metal, ceramic or polymer and a second material that is (i) a metal, ceramic, or polymer and (ii) different than the first material.

Abstract: A process for the attachment of aromatic or heteroaromatic rings to a polymeric support via a silyl ether linkage is described. Such process involves the synthesis of a chlorodialkyl aryl or heteroarylsilane which is then coupled to a polymeric support via a hydroxyl functionality to form a polymer-bound silyl ether. Further modification provides a polymer-bound small organic molecule that is cleaved from the polymeric support under mild conditions to give an aryl or heteroaryl silanol or a compound in which the aryl or heteroaryl carbon-silicon bond is replaced with a carbon-hydrogen, carbon-halogen, carbon-hydroxyl, carbon-sulfur, or carbon—carbon bond. Such methods are useful for the preparation of a library of diverse aromatic and heteroaromatic compounds by both manual and automated synthesis.

Abstract: A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1  (I) ≡Si—OCOR2  (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.

Abstract: The present invention provides a sol-gel composition which comprises a mixture of a polyalkylene glycol-substituted trialkoxysilane (PAGTAS), a polyalkylene glycol and/or alkyl ether, a tetraalkoxysilane (TAOS), a hydrochloric acid, at least one organic solvent and/or a lithium salt, which mixture is optionally concentrated; a polymeric ion conductive film obtained by coating said compositions with a conventional solution processing method and solid electrochemical elements using the same. According to the present invention, a polymeric ion conductive film having no phase separation, strong adhesiveness for electrode, and ion conductivity of at least 1×10−4 S/cm at room temperature is provided.

Abstract: Hetero-telechelic polymers having the formula:FG--(Q).sub.d --Z--J--[A(R.sup.1 R.sup.2 R.sup.3)].sub.x (I)wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R.sup.1 R.sup.2 R.sup.3)].sub.x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.

Abstract: There is provided graft copolymer particles prepared by graft-polymerizing a vinyl monomer to a coagglomerated rubber, wherein said rubber is prepared by coagglomerating rubber particles of mixed latexes obtained by mixing (A) a silicone rubber latex with (B) an acrylic rubber latex and/or a conjugated diene rubber latex in such an amount as a silicone content is from 1 to 90% by weight based on the total rubber component. A physical property of a thermoplastic resin is improved using the graft copolymer particles. The thermoplastic resin composition using the graft copolymer particles is excellent in impact resistance, weather resistance, processability, thermal discoloration resistance and appearance of molded products.

Abstract: This invention provides novel protected, multi-functionalized multi-arm polymers, their optionally hydrogenated analogues and optionally deprotected analogues thereof, and processes for making these compounds. In the invention, monomers are polymerized using a protected functionalized initiator to form living polymer anions, the living anions coupled to form multi-arm polymers, additional monomer added to form additional polymer arms, and the multi-arm polymer functionalized using electrophiles.

Abstract: An improved process for the preparation of thermoplastic elastomers by hydrosilylation crosslinking, in which a hydrosilylation crosslinking agent with a low degree of polymerization and/or a hydrosilylation crosslinking agent diluted in oil is used.

Abstract: A polysiloxane having a siloxane structure of the following formulas (1) and (2): ##STR1## wherein, R.sup.1 is a C.sub.1 to C.sub.6 alkyl group or C.sub.1 to C.sub.21 acyl group, a is 1 to 200, b is 1 to 200, t is 2 or 3 and r is 1 to 100, and a rubber composition containing the same.

Abstract: A rubber composition, which contains a rubber mixture that can be vulcanized with a vulcanizing agent, which includes at least one rubber component, at least one filler, gel particles comprising a rubber, having a particle size between about 3.times.10.sup.-9 and about 1.times.10.sup.-6 m and a swelling index in toluene of about 1 to about 15 and whose surface has electrophilic centers, and a substance which acts as a coupling agent between the gel particles and which has the structure A--R--A, wherein A is a nucleophilic group, and R is a saturated or unsaturated hydrocarbon group. The rubber composition has improved hysteresis behavior in the vulcanized state so that when this rubber composition is used in tires, the rolling resistance is reduced and the wet slippage behavior is improved in relation to the conventional rubber compositions. A method of formulating the rubber composition as well as a composition useful for tire treads and vehicle tires containing the composition are disclosed.

Abstract: A monomer such as butadiene monomer and/or styrene monomer is polymerized using an organic lithium initiator, and the active terminal of a (co)polymer thus obtained is modified with a specific modifier having reactivity with a silica surface, e.g., .gamma.-glycidoxypropyl trimethoxysilane and .gamma.-methacryloxypropyl trimethoxysilane, and then the terminally-modified (co)polymer is mixed with a silica in an organic solvent. The rubber obtained can be used in a tire tread and the like.

Abstract: Radio frequency-transmissive compositions having reduced dissipation factors, microelectronic devices, and in particular, wireless radio frequency communication devices which utilize such compositions, and methods of forming the same are described. In one implementation, a liquid resin is provided and a solid organic polymer filler material is provided within the resin to impart a degree of radio frequency transmissivity which is greater than that of the resin alone, i.e. the composition has a reduced dissipation factor. An exemplary resin comprises epoxy and an exemplary filler material is a polytetrafluoroethylene powder. In another implementation, such composition is formed or applied over a substrate which includes an antenna formed thereon and cured to provide a solid coating. The substrate can also have integrated circuitry and a battery mounted thereon to provide a wireless communication device. In such a case, the composition can be formed over and cured atop the integrated circuitry and the battery.

Abstract: The hydrosilylation of terminal double bonds in polypropylene (PP) or other polymers is effected in the melt phase. The double bonds were created by peroxide initiated degradation of PP in an extruder or a batch mixer. A hydride terminated polydimethylsiloxane is employed as a model substance to investigate the feasibility of hydrosilylating the terminal double bonds of the degraded polypropylene. The reaction may be carried out in three different reactors, namely a hot press, a batch mixer and a screw extruder. Two different reaction mechanisms may be used to effect the hydrosilylation reaction, namely a radical chain addition mechanism and a platinum catalysed mechanism with a colloid forming catalyst, platinum divinyltetramethyldisiloxane (Karstedt's catalyst). Catalytic amounts of a peroxide initiator are able to initiate the addition of silanes to the double bonds of the degraded polypropylene. Both reactions, namely degradation and hydrosilylation, may be performed simultanously.

Abstract: A curable rubber composition comprises of a silicone rubber (A) and an ethylene-.alpha.-olefin-polyene amorphous copolymer (B) containing as the polyene component a norbornene compound having at least one kind of vinyl terminal group represented by 5-vinyl-2-norbornene or 5-methylene-2-norbornene. The rubber composition is speedily cured, if said components (A) and (B) are mixed by the A/B mixing ratio of 98/2-2/98 (% by weight) and kneaded in the presence of an organic peroxide. A vulcanizate rubber excelling in mechanical strength, water resistance and thermal aging resistance can be manufactured from said composition, since its crosslink density can be enhanced without impairing processing properties. Additionally, said composition entails reduced mold fouling phenomenon in the molding operation. Vulcanizate rubber thereby obtained can be advantageously used as industrial parts and electric parts.

Abstract: Disclosed is a curable resin which comprises at least one polymer selected from polymers each independently having a polymer chain represented by the following formula (I): ##STR1## wherein A to F are monomer units constituting a main chain of the polymer and are arranged in any order, and a to f are, respectively, wt % of A to F, based on the total weight of A to F; wherein each A is independently selected from cyclic olefin monomer units having no reactive group, each B is independently selected cyclic conjugated diene monomer units having no reactive group, each C to F is independently selected from comonomer units having no reactive group, and copolymerizable with A and B, wherein Q.sub.1 to Q.sub.6 are reactive groups, and wherein the average total number (J) of Q.sub.1 to Q.sub.6 of the at least one polymer satisfies: 1.ltoreq.(J).ltoreq.4, the polymer having an ME of from 1,000 to 5,000,000. A resin composition containing the curable resin is also disclosed.

Abstract: The invention relates to linear copolymers containing alpha-olefin and divinylbenzene comonomer units and to a process for preparing the copolymers, the copolymers having a mole ratio of unsaturation/divinylbenzene (TUS/DOU) between 0.8 and 1.1, a molecular weight distribution of less than 4, and a homogeneous composition distribution, and having the structural formula ##STR1## in which R is a linear or branched C.sub.1 to C.sub.10 alkyl group or a phenyl or alkyl-substituted phenyl group, x+y is the mole % of alpha-olefin units in the copolymer, z is the mole % of divinylbenzene units in the copolymer, the sum of x+y is from 50 to 99.9, and the sum of x+y+z is 100. The copolymers are prepared in the presence of a bridged metallocene catalyst having a spacial opening at the metal active site of between 135 and 105.degree. for reacting with only one of the two vinyl groups in the divinylbenzene comonomer, which assures the formation of linear copolymers without detectable branching structure.

Abstract: A highly branched polymer in the form of a comb, star, nanogel and structural combinations thereof in which a plurality of polyolefin arms formed of polymers of 1-alkenes are attached to a backbone having repeating units containing aliphatic groups, aromatic groups, heteroatom-containing groups and combinations thereof.

Abstract: A functionalized polymer prepared by a process comprising the steps of preparing a solution of a cyclic amine compound, an organolithium compound, and from 3 to about 300 equivalents, based upon one equivalent of lithium, of a monomer selected from the group including diene monomers, vinyl aromatic monomers, and mixtures thereof, where the cyclic amine compound is defined by the formula where R.sub.2 is selected from the group consisting of an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups, N is a nitrogen atom, and H is a hydrogen atom, thereby forming a polymerization initiator having the formula where Li is a lithium atom, SOL is a divalent hydrocarbon group having from 3 to about 300 polymerized monomeric units, y is from 0.5 to about 3, and A is a cyclic amine radical derived from the cyclic amine, charging the solution containing (A)Li(SOL)y with from about 0.

Abstract: The presence in curable polyolefin compositions of a moisture curable organosilicon compound containing at least one alkenyloxy group bonded to the silicon atoms improves the adhesion to a variety of substrates that is developed during the curing reaction of polyolefin compositions cured by a hydrosilation reaction. The organosilicon compound is preferably a reaction product of ingredients comprising 1) a silane or bis-silylalkane containing at least three silicon-bonded moisture-reactive groups per molecule and 2) an organic compound containing at least one carbinol group and at least one ethylenically unsaturated group.

Abstract: The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising (a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed of a vinyl aromatic compound and at least one polymeric block (B) composed of a conjugated diene compound, or a hydrogenated block copolymer, (b) 20 to 300 parts by weight of a non-aromatic softening agent for rubber, (c) 1 to 100 parts by weight of a peroxide-crosslinking type olefinic resin or a copolymeric rubber containing said resin, and (d) 10 to 150 parts by weight of a peroxide-decomposition type olefinic resin or a copolymer containing said resin, characterized in that the process comprises a step of heat-processing component (a), component (b), at least a part of component (c) and a part of component (d) in the presence of an organic peroxide to cause crosslinking, and a subsequent step of blending these with the remaining part of component (d) and, if any, the remaining part of component

Abstract: A composition comprises (A) a syndiotactic styrene-based resin and (C) rubber polymer particles such as graft copolymers, butadiene or isoprene block copolymers optionally hydrogenated and/or modified with maleic anhydride, and other rubbers, and, optionally, (B) a thermoplastic resin such as a polycarbonate, and/or (D) a filler such as glass fibers.

Abstract: A functionalized polymer includes a polymer chain carrying at least one functional group selected from alkyl, dialkyl and cycloalkyl amine radicals having the general formula ##STR1## and cyclic amine radicals having the general formula ##STR2## where R.sub.1 is an alkyl, cycloalkyl or aralkyl having from 1 to about 12 carbon atoms, and R.sub.2 is an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups. The invention also provides products based upon such polymers.

Abstract: It is an object of the invention to improve the adhesive property of a curable composition mainly comprising a reactive silyl group-containing saturated hydrocarbon polymer when applied to various adherends and to improve the weathering-resistant adhesive property of said composition when applied to various glass products, in particular heat ray-reflecting glass products.The present invention relates to a curable composition which comprises (A) a saturated hydrocarbon polymer containing at least one silicon-containing group having a hydroxyl group or hydrolyzable group bound to the silicon atom and capable of crosslinking by forming a siloxane bond, (B) a silane coupling agent and (C) a compound containing, within the molecule thereof, an unsaturated group capable of polymerizing upon reaction with atmospheric oxygen and/or a photopolymerizing substance.

Abstract: Terminally functionalized silicone copolymers prepared using protected functionalized initiators and processes for preparing the same. The silicone copolymers includes protected, functionalized silicone diene and/or alkenylsubstituted aromatic copolymers, such as mono-functional, homotelechelic, heterotelechelic, macromonomer, and radial copolymers. The protected functionalized copolymers can be optionally deprotected to afford functionalized silicone diene and/or alkenylsubstituted aromatic copolymers.

Abstract: There is disclosed a moisture-curable elastomer composition obtained by dynamic heat treatment of a mixture comprising(a) an ethylene-.alpha.-olefin-unconjugated diene copolymer rubber,(b) a silicon-based crosslinking agent having two or more SiH groups within the molecule,(c) a hydrosilylation catalyst and(d) a hydrolyzable silane group-containing thermoplastic resin. Also disclosed is an elastomer composition resulting from molding of the above elastomer composition, followed by contacting with water, preferably in the presence of a silanol catalyst, to thereby cause crosslinking of the hydrolyzable silane group-containing thermoplastic resin. The elastomer composition of the present invention is excellent in rubber elasticity at high temperatures, low temperature impact resistance and oil resistance and have good moldability.

Abstract: A rubber composition which has a reduced hysteresis making it particularly suitable for use as a tread of a tire having reduced rolling resistance, including silica as predominant reinforcing filler and at least one diene polymer bearing, as a chain end, a silanol functional group or a polysiloxane block which has a silanol end.

Abstract: Diene polymers or copolymers having improved balance between raw polymer viscosity and mixed compound viscosity, useful in tire tread compositions having highly balanced wet traction, rolling resistance, and traction in ice and snow, and fracture properties in the cured and white carbon reinforced states are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from hydrocarboxysilane compounds. The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using hydrocarboxysilane compounds.

Abstract: A flame retardant resin composition comprises a silicone resin having specific structure and weight-average molecular weight and a non-silicone resin having aromatic-ring. The silicone resin has R.sub.2 SiO.sub.1.0 units and RSiO.sub.1.5 units. The weight-average molecular weight of the silicone resin is in the range of not less than 10,000 to not more than 270,000. R is hydrocarbon group.

Abstract: There is provided a rubber composition and a rubber article for pharmaceutical chemicals or medical treatments, obtained by forming and cross-linking this rubber composition, the rubber article having very excellent properties which can be adapted to the standard test values of various official documents, required in this field, and can further satisfy the test items having lately become an important problem from the pharmaceutical standpoint. This rubber composition comprises 0.3 to 3.5 parts by weight of an organic peroxide cross-linking agent, 0.3 to 4 parts by weight of an organic compound having at least 2 maleimide groups in one molecule and optionally, 0.6 to 30 parts by weight of an organosilicone compound per 100 parts by weight of a isobutylene-isoprene copolymer rubber.

Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of at least one .alpha.-olefin, (b) from 30 to 70 weight percent of at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.

Abstract: A silicone release composition having a non-gloss, i.e., matte finished, surface and a linerless label incorporating the silicone release composition. The release composition includes a crosslinked silicone-based polymer having microparticles of a polymeric wax at least partially embedded therein. The polymeric wax may be polytetrafluoroethylene, polypropylene or other polyolefin, or a hydrocarbon-based wax. The microparticles of polymeric wax cause incidental light to scatter upon reflection, giving the release composition surface matte appearance. This makes the release composition particularly useful for linerless labels on which bar coded information will be printed. Also, a method for producing linerless label stock. The method includes mixing an uncured silicone material with microparticles of a polymeric wax. The mixture is coated onto a substrate and exposed to UV radiation to cure or crosslink the silicone around the microparticles of wax.

Abstract: A fine fiber-reinforced elastomer composition (A) having a high elastic modulus, mechanical strength and creep resistance includes (a) 100 parts by weight of elastic component having a glass-transition temperature of 0.degree. C. or less, (b) 30 to 500 parts by weight of a polyolefin component and (c) 10 to 500 parts by weight of a polyamide component dispersed in the fine fiber form in the matrix consisting of the components (a) and (b), these components (a), (b) and (c) being chemically bonded to each other through a binding agent (d), for example, a silane coupling agent, and is useful for producing an elastic material having a high elastic modulus, an excellent fatigue resistance and a high isotropy, by admixing an additional elastic component (B) to the elastomer composition (A).

Abstract: An improved process for the preparation of thermoplastic elastomers by hydrosilylation crosslinking, in which a platinum containing hydrosilylation catalyst is used in combination with oil which is substantially free of materials which have the chemical behavior of a Lewis base. A crosslinked rubber component is obtained in the thermoplastic elastomer composition.

Abstract: Block copolymers are described which comprise alternating blocks of (A) a polysiloxane; and (B) a copolymer of a 1,3-conjugated diene and a monovinyl aromatic compound. The block copolymers can be prepared by reacting a polysiloxane with a dilithiated copolymer of a conjugated diene and a monovinyl aromatic compound and thereafter neutralizing the reaction product with a protonic acid or a polyfunctional alkyl silane or silicon tetrachloride. Cured elastomer compositions exhibiting surface release characteristics are obtained by curing a mixture comprising the above-described block copolymer in the presence of a curing system comprising a peroxide and sulfur. Multilayer elastomer structures useful in manufacturing articles from elastomeric materials also are described wherein at least a portion of an outer layer of the multilayer elastomer structure has release characteristics and comprises the cured block copolymers of the present invention.

Abstract: The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising (a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed of a vinyl aromatic compound and at least one polymeric block (B) composed of a conjugated diene compound, or a hydrogenated block copolymer, (b) 20 to 300 parts by weight of a non-aromatic softening agent for rubber, (c) 1 to 100 parts by weight of a peroxide-crosslinking type olefinic resin or a copolymeric rubber containing said resin, and (d) 10 to 150 parts by weight of a peroxide-decomposition type olefinic resin or a copolymer containing said resin, characterized in that the process comprises a step of heat-processing component (a), component (b), at least a part of component (c) and a part of component (d) in the presence of an organic peroxide to cause crosslinking, and a subsequent step of blending these with the remaining part of component (d) and, if any, the remaining part of component

Abstract: The present invention relates to compounds composed essentially of a linear, cyclic or branched polyorganosiloxane having, per molecule, at least 3 siloxy units, including at least one siloxy functional unit of formula: ##STR1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical, X contains an N,N'-di- and/or trisubstituted phenylenediamine functional group, bonded to the silicon via an Si-(hydrocarbon linking unit)-N and/or Si-(hydrocarbon linking unit)-C bond, and a is a number chosen from 0, 1 and 2. The present invention also relates to the use of such compounds as antiozonants for rubbers and in particular for rubber compositions for tires.

Abstract: This invention relates to the preparation of an addition curable composition having self adhesion to substrates. The addition curable composition comprises an organic polymer having on average at least 1.4 alkenyl groups per molecule, a crosslinker having on average at least 1.4 hydrosilyl groups per molecule, a platinum group metal containing catalyst, an alkoxy silicon compound and a titanium compound having Ti--O--C bonds. Another embodiment of this invention is a method of adhering the addition curable composition to a substrate surface.

Abstract: The reduction of hysteresis in a silica-filled, vulcanized elastomeric compound is produced by mixing diene monomer and optionally monovinyl aromatic monomer with a lithium amine initiator and, optionally, a modifier; effecting polymerization conditions; terminating polymerization with an amino group producing terminator to form an amine functionalized diene elastomer; compounding the amine functionalized diene elastomer with an amorphous silica filler and a vulcanization agent; and, effecting vulcanization. A pneumatic tire tread stock incorporating the vulcanized elastomer compound exhibits decreased rolling resistance in the tire.

Abstract: A .Iadd.cord and fabric for a .Iaddend.power transmission belt comprised of a belt body having a tooth portion and made of a rubber stock of hydrogenated nitrile having a Mooney viscosity at 100.degree. C. of at least 90, whereby the internally generated heat of the belt body during use in a high temperature environment is suppressed. A cashew-modified phenol resin layer is formed at the outermost layer of the cords .Iadd.and fabric .Iaddend.for bonding with the belt body. The cords are embedded in the longitudinal direction of the belt body.