Contacting Two Or More Solid Polymers Derived From Ethylenic Reactants Only With A -n=c=x Reactant Or Polymer Thereof; Or Contacting A Polymer Derived From An Ethylenic Reactant Only With A -n=c=x Reactant Or Polymer Thereof And Subsequently Adding Thereto A Solid Polymer Derived Only From Ethylenic Reactants Patents (Class 525/125)
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Patent number: 12138511Abstract: A formulation for making at least one element of a golf ball, wherein the formulation includes: (i) from 50 weight percent to 95 weight percent of a thermoplastic composition comprising: (1) at least one ethylene acid copolymer consisting essentially of copolymerized comonomers of: (A) ethylene, and (B) from 5 weight percent to 25 weight percent of at least one ?,?-ethylenically unsaturated carboxylic acid having from 3 carbon atoms to 8 carbon atoms, based on the total weight of monomers present in the ethylene acid copolymer; wherein the acid moieties of component (1) are neutralized to a level of from 25 percent to 220 percent; and (ii) from 5 weight percent to 50 weight percent of a crosslinked material having a gel content of at least 80 weight percent, wherein the crosslinked material is a crosslinked elastomer, a crosslinked rubber, or a blend of a crosslinked elastomer and a crosslinked rubber; a process for making the above formulation; at least one element of a multilayer golf ball and a process forType: GrantFiled: December 17, 2020Date of Patent: November 12, 2024Assignee: Dow Global Technologies LLCInventors: James R. De Garavilla, Keith C. Anderson
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Patent number: 11584820Abstract: A polymer blend is provided, which includes 100 parts by weight of a first polyolefin, 3 to 100 parts by weight of a thermoplastic polyurethane, and 3 to 10 parts by weight of a modified polyolefin. The modified polyolefin is formed by grafting maleic anhydride or acrylate onto a second polyolefin. The blend can be used to form fiber.Type: GrantFiled: July 2, 2020Date of Patent: February 21, 2023Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventor: Kuan-Yeh Huang
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Patent number: 11274203Abstract: A process for preparing a TPU alloy material through in-situ compatibilization includes: 1) adding a premixed TPU raw material to a feeding port of a twin-screw extruder; injecting a mixture of an alloy component and a dual-active substance into the twin-screw extruder through a lateral feeding port; adding an auxiliary reagent to the TPU raw material or the mixture of the alloy component and the dual-active substance, wherein the alloy component is a polyolefin or a thermoplastic polymer material having reactivity, wherein the dual-active substance is a substance containing a group reactive with the TPU raw material and a group reactive with the alloy component, and the auxiliary reagent includes an initiator; 2) controlling a temperature of a reaction zone of the twin-screw extruder at 50° C. to 250° C., and granulating an extruded material by underwater cutting; and 3) drying the granulated product to obtain the TPU alloy material.Type: GrantFiled: February 24, 2017Date of Patent: March 15, 2022Assignee: Miracll Chemicals Co., Ltd.Inventors: Zhensheng Zhan, Hongwei Song, Qingbo Zhao, Sheng Zhang, Guanglei Ren
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Patent number: 11248150Abstract: To provide an adhesive excellent in adhesion to a thermoplastic resin and an ethylene/vinyl alcohol copolymer. An adhesive comprising a hydrolyzate of a resin composition containing a thermoplastic resin (A), a copolymer (B) of ethylene and a vinyl ester and/or an acrylic acid ester having a vinyl ester and/or acrylic acid ester content higher by at least 5 mol % than (A); and a modified product having (A) grafted by (B), and an adhesive resin composition comprising it.Type: GrantFiled: May 17, 2017Date of Patent: February 15, 2022Assignee: TOSOH CORPORATIONInventors: Daisuke Kawato, Midori Takayama, Makoto Oodake, Shingo Kouda
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Patent number: 11142592Abstract: Polymerizable compositions are described which contain, as photoinitiator, at least one acyltin compound according to the general formula (I):Type: GrantFiled: September 4, 2017Date of Patent: October 12, 2021Assignee: Ivoclar Vivadent AGInventors: Norbert Moszner, Urs Karl Fischer, Peter Burtscher, Robert Liska, Patrick Knaack, Moritz Mitterbauer
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Patent number: 10208232Abstract: Disclosed is a crosslinked adhesive composition comprising a low Tg (meth)acrylate copolymer component, a high Tg (meth)acrylate copolymer component, and a hydrogenated hydrocarbon tackifier. This disclosure provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles that are particularly useful in the bonding of low surface energy (LSE) substrates.Type: GrantFiled: May 6, 2014Date of Patent: February 19, 2019Assignee: 3M Innovative Properties CompanyInventors: Shujun J. Wang, Zhong Chen, John R. Jacobsen, Peggy S. Willett, David J. Yarusso, Soyoung Kim
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Patent number: 9982077Abstract: The present disclosure provides high density polyethylene resins having good low temperature impact resistance. The resins are suitable for use in rotomolding application for large parts. The resin is a bi- or trimodal resin produced using solution phase polymerization in the presence of a single site catalyst.Type: GrantFiled: December 5, 2016Date of Patent: May 29, 2018Assignee: NOVA Chemicals (International) S.A.Inventors: Celine Bellehumeur, Mark Hoidas
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Patent number: 9796875Abstract: The invention relates to a coating composition comprising: a) at least one alkyd binder with an oil content of at least 45 wt % and at most 85 wt %, a modified alkyd binder, or a combination thereof; b) at least one amine or imine component selected from the group comprising: polyaspartic acids and esters thereof, (meth)acrylate/aspartate amines, aldimines, ketimines, and combinations thereof; and c) at least one isocyanate compound.Type: GrantFiled: August 17, 2012Date of Patent: October 24, 2017Assignee: PPG Europe BVInventors: John Weijnen, Joost De Wit
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Patent number: 9624372Abstract: In the belt according to the present invention, the whole or a part of a belt body is formed from a thermoplastic resin composition (C) comprising a thermoplastic resin (A) and a modified ethylene copolymer (B) dispersed and contained therein. The modified ethylene copolymer (B) is preferably a copolymer, modified with an unsaturated carboxylic acid or a derivative thereof, of ethylene with at least one monomer component selected from (i) olefin components except for ethylene, (ii) diene components and (iii) ester components having an ethylenically unsaturated group. The belt according to the present invention hardly causes abrasion, damage, cracks, breakage and the like on the belt body and is remarkably excellent in durability, even if the belt is used at a high load for a long time.Type: GrantFiled: March 29, 2012Date of Patent: April 18, 2017Assignee: NITTA CORPORATIONInventors: Takahiko Yoshida, Shoji Shimizu, Akihiko Matsumoto
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Patent number: 9493637Abstract: An object of the present invention is to provide a tire rubber composition capable of producing a studless tire that has excellent performance on ice and wear resistance, and to provide a studless tire using the composition. The tire rubber composition of the present invention is composed of 100 parts by mass of a diene type rubber (A), from 30 to 100 parts by mass of a carbon black and/or a white filler (B), from 0.3 to 30 parts by mass of a cross-linkable oligomer or polymer (C) that is not phase-soluble with the diene type rubber (A); and from 0.1 to 12 parts by mass of three dimensionally crosslinked fine particles (D) of 1 to 200 ?m average particle diameter.Type: GrantFiled: April 20, 2012Date of Patent: November 15, 2016Assignee: The Yokohama Rubber Co., Ltd.Inventors: Keisuke Maejima, Kazushi Kimura, Satoshi Mihara, Yayoi Akahori, Katsunori Shimizu
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Patent number: 9446564Abstract: Multiple layer laminates contain predominantly urethane-based polymeric materials in cap and base layers, and no significant amount of PVC. Under combustion conditions, the laminate releases substantially no harmful halogen-based bases, such as HCl or other toxic gases, and exhibits low toxicity and smoke generation.Type: GrantFiled: March 3, 2010Date of Patent: September 20, 2016Assignee: SCHNELLER LLCInventors: Robert G. Pierson, Henry C. Ashton, Robert L. Gray, Gilles Le Dû
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Patent number: 9404003Abstract: A polyamine curable, highly saturated nitrile rubber composition comprising 100 parts by weight of a polyamine curable, highly saturated nitrile rubber having an ?,?-ethylenically unsaturated nitrile monomer unit, a diene-based monomer unit, an ?,?-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and an ?,?-ethylenically unsaturated carboxylic acid ester monomer unit other than the ?,?-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and having an ?,?-ethylenically unsaturated nitrile monomer unit content of 22.0 to 24.5 wt. %, preferably 22.5 to 24.5 wt. %, and an iodine value of 120 or less, and 4 to 31 parts by weight of an aliphatic carboxylic acid diester compound of polyalkylene glycol. The polyamine curable, highly saturated nitrile rubber composition is used as a cure molding material of a sealing material that can be suitably used even in an environment in which the sealing material is exposed to polycyclic aromatic compound.Type: GrantFiled: April 5, 2013Date of Patent: August 2, 2016Assignee: NOK CorporationInventors: Ayako Aoyagi, Kenichi Uchida
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Patent number: 9403972Abstract: Disclosed is a polyamine curable, highly saturated nitrile rubber composition having excellent cold resistance in the presence of a polycyclic aromatic compound; the composition comprising 100 parts by weight of a polyamine curable, highly saturated nitrile rubber having an ?,?-ethylenically unsaturated nitrile monomer unit, a diene-based monomer unit, an ?,?-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and an ?,?-ethylenically unsaturated carboxylic acid ester monomer unit other than the ?,?-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and having an ?,?-ethylenically unsaturated nitrile monomer unit content of 21.0 to 23.0 wt. %, preferably 21.0 to 22.5 wt. %, more preferably 21.0 to 22.0 wt. %, and an iodine value of 120 or less, and 4 to 31 parts by weight of an aliphatic carboxylic acid diester compound of polyalkylene glycol.Type: GrantFiled: April 5, 2013Date of Patent: August 2, 2016Assignee: NOK CorporationInventors: Ayako Aoyagi, Kenichi Uchida
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Patent number: 9006350Abstract: A selfbonding enamel containing resins which are capable of crosslinking with one another, comprising (A) 5 to 95 wt % of at least one resin with nucleophilic groups selected from the group consisting of OH, NHR, SH, C(O)NHR, carboxylate, CH-acidic groups and Carbanions, (B) 0 to 70 wt % of at least one amide group-containing resin and (C) 0 to 30 wt % of at least one polyurethane resin, (D) 0 to 30 wt % of at least one epoxy resin, (E) 5 to 95 wt % of at least one organic solvent, wherein the resins of either component (A) and/or, if component (B) is contained in the composition, component (B) contain ?-carboxy-?-oxocycloalkyl carboxylic acid amide groups the coatings of the selfbonding enamel have excellent adhesion to electrically conductive wires high sticking properties and high re-softening temperatures.Type: GrantFiled: December 13, 2007Date of Patent: April 14, 2015Assignee: Axalta Coating Systems IP Co., LLCInventors: Frank-Rainer Boehm, Michael Herm
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Patent number: 8987374Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilizing side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.Type: GrantFiled: May 3, 2010Date of Patent: March 24, 2015Assignee: The Lubrizol CorporationInventors: Stuart Nicholas Richards, Andrew James Shooter
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Publication number: 20150044459Abstract: The invention relates to the use of a composition comprising methyl methacrylate MMA, at least one elastomer and/or a core-shell polymer, and at least one radical former, as an adhesive, sealant or coating for gluing, sealing or coating substrates containing plasticized PVC.Type: ApplicationFiled: April 9, 2013Publication date: February 12, 2015Inventors: Heinz Meier, Markus Haufe, Josef Lussi, Elyes Jendoubi, Wilfried Carl
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Patent number: 8933146Abstract: The present invention describes the preparation of an aqueous polyurethane dispersion which is cured by radiation, and its use as binder.Type: GrantFiled: August 6, 2008Date of Patent: January 13, 2015Assignee: Bayer MaterialScience AGInventors: Stefan Sommer, Richard Kopp, Harald Blum, Christoph Irle, Jan Weikard, Erhard Luehmann
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Publication number: 20140343229Abstract: The invention provides functionalized block composites and crystalline block composites as compatibilizers. In particular, the invention provides compositions of at least three polymers and a compatibilizer. The compatibilizer comprises a functionalized olefin-based polymer formed from at least (A) and (B): (A) a crystalline block composite comprising: a block copolymer comprising a propylene-based crystalline block and crystalline ethylene-based block; a propylene-based crystalline polymer; and, a crystalline ethylene-based polymer; and (B) at least one functionalization agent or a functionalized olefin-based polymer formed from at least (A) and (B): (A) a crystalline block composite comprising: a block copolymer comprising a propylene-based crystalline block and crystalline ethylene-based block; a propylene-based crystalline polymer; and, a crystalline ethylene-based polymer; and (B) at least one functionalization agent.Type: ApplicationFiled: December 12, 2012Publication date: November 20, 2014Applicant: Dow Global Technologies LLCInventors: Ronald J. Weeks, Yushan Hu, Kim L. Walton, Gary R. Marchand, Michael D. Read, H. C. Silvis
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Publication number: 20140329097Abstract: An adhesive composition that includes: one or more polyester polyether copolymers of formula I: wherein Nu is a predominately cyclic nucleus and R1 is randomly selected from either a C2-6 alkylene or an amorphous, long-chain polyether subunit including a polyoxyalkylene group; one or more polyisocyanate prepolymers that includes the reaction product of: one or more polyols; and a polyfunctional isocyanate having a functionality of more than about 2; polymeric MDI; and a first aromatic or aromatic-aliphatic polymer tackifying resin having a softening point of equal to or greater than about 100° C.Type: ApplicationFiled: July 21, 2014Publication date: November 6, 2014Inventors: Marietta B. Helmeke, Jeffery G. Schmierer, Theresa Unze-Schmierer
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Patent number: 8853295Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.Type: GrantFiled: February 12, 2010Date of Patent: October 7, 2014Assignee: ALLNEX IP S.a.r.L.Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
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Publication number: 20140272425Abstract: A moisture-curable hot melt adhesive which is excellent in light resistance and durability against high temperature and high humidity. The moisture-curable hot melt adhesive includes a urethane prepolymer having an isocyanate group at the end and an acrylic based polymer, wherein the urethane prepolymer contains chemical structures derived from a polycarbonate polyol and a non-crystalline polyesterpolyol. The moisture-curable hot melt adhesive can be used to produce an automobile interior material since no deterioration occurs even under sunlight, or under severe high temperature and high humidity conditions in the summer season.Type: ApplicationFiled: June 2, 2014Publication date: September 18, 2014Inventor: Tsuyoshi Tamogami
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Publication number: 20140231008Abstract: Moisture curable hot melt adhesive compositions that contain functionally modified polyolefins and have improved green strength before set are prepared without using added crystalline polyester polyol.Type: ApplicationFiled: April 25, 2014Publication date: August 21, 2014Applicant: Henkel AG & Co. KGAAInventor: Yongxia Wang
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Patent number: 8742059Abstract: A polymer precursor including a part which sequences an unsaturated bond having a ? electron orbit and a single bond alternately is disclosed. The polymer precursor has a first functional group and a second functional group which form a repeating unit constituting a polymer skeleton of an end product by an intramolecular reaction. At least a part of a conjugated state formed by the ? electron orbit in the molecule is disconnected or weakened due to a three-dimensional structure of the molecule and a transmittance with respect to an electromagnetic wave of at least one wavelength selected from the group consisting of 436 nm, 405 nm, 365 nm, 248 nm and 193 nm is improved.Type: GrantFiled: November 30, 2011Date of Patent: June 3, 2014Assignee: Dai Nippon Printing Co., Ltd.Inventor: Katsuya Sakayori
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Patent number: 8735464Abstract: A radically curable polyurethane composite for dental restorations, including provisional restorations, includes polyurethane dimethacrylate prepolymers that have at least one flexible unit within a polyurethane dimethacrylate backbone, and one or more dimethacrylate monomers. Composite materials made with polyurethane dimethacrylate prepolymers of the invention exhibit superior and optimal properties of flexural strength and deflection-at-break relative to conventional dental resin composites. Composite materials of the invention also provide improved melt-resistance in response to the heat of grinding or finishing, thereby improving the fit of restorations made from the composite and preserving the finishing instruments. Methods of treating a tooth using the radically curable polyurethane composite and methods of making the polyurethane dimethacrylate prepolymers with flexible units is also provided. A kit including the radically curable polyurethane composite is also described.Type: GrantFiled: October 19, 2012Date of Patent: May 27, 2014Assignee: Pulpdent CorporationInventors: Sunny Skaria, Kenneth Berk
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Publication number: 20140142251Abstract: The present invention relates to a method for producing a filled elastomer wherein a rubber composition is produced by mixing I) raw rubber, II) cross linking agent, III) filler, IV) isocyanate terminated polymer composition and optionally V) further additives and cross linking of the rubber composition. The present invention further relates to a filled elastomer obtainable according to said method and the use of filled elastomers according to the invention as shoe sole.Type: ApplicationFiled: July 4, 2012Publication date: May 22, 2014Applicant: BASF SEInventors: Dong Liang, Weihua Ye, Yong Lu, Zhen Tong, Zhaohui Chen
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Patent number: 8728352Abstract: An electrical connection material between conductors includes about 40 wt % to about 80 wt % of a urethane-modified acrylate resin, based on a total weight of the electrical connection material, the electrical connection material exhibiting, after curing, a tensile elongation of about 100% to about 500% and a yield point strain of about 10% to about 50% in a stress-strain curve.Type: GrantFiled: September 16, 2011Date of Patent: May 20, 2014Assignee: Cheil Industries, Inc.Inventors: Sang Sik Bae, Kyoung Soo Park, Kyoung Hun Shin, Kang Bae Yoon
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Patent number: 8653191Abstract: The invention provides a composition comprising at least the following: an olefin multi-block interpolymer, a functionalized olefin-based polymer, and a thermoplastic polyurethane. The invention also provides for articles prepared from the inventive compositions and for methods for making the same.Type: GrantFiled: June 30, 2008Date of Patent: February 18, 2014Assignee: Dow Global Technologies LLCInventors: Patricia Ansems, Ashish Batra
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Patent number: 8609766Abstract: The invention provides a composition comprising at least the following: A) a thermoplastic polyurethane; B) an elastomer; C) a polydiene-based polyurethane or a polydiol-based polyurethane; D) a polyoctenamer; and E) a resin selected from the group consisting of the following: i) an indene-coumarone resin, ii) an aromatic hydrocarbon resin, and iii) an aliphatically modified aromatic hydrocarbon resin.Type: GrantFiled: June 23, 2011Date of Patent: December 17, 2013Assignee: Dow Global Technologies LLCInventor: Cristiano Betté
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Publication number: 20130303697Abstract: Methods for making golf balls having a cover made from a polyurea composition are provided. The golf balls include a rubber core and intermediate layer made from an olefin-based ionomer composition. The methods for making the polyurea composition involve preparing an amine-terminated first polymer by reacting isocyanate compound A with a stoichiometric excess of polyamine. The first prepolymer is reacted with a stoichiometric excess of isocyanate compound B to form an isocyanate-terminated second prepolymer. The second prepolymer is then reacted with a chain extender.Type: ApplicationFiled: July 15, 2013Publication date: November 14, 2013Inventors: Michael Michalewich, Brian Comeau, David A. Bulpett, Shawn Ricci
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Publication number: 20130280456Abstract: The rubber mixtures according to the invention, containing uncrosslinked, double-bond-containing rubbers (A), crosslinked rubber particles (B) and multifunctional isocyanates (C), wherein the amount of component (B) in the mixture is from 1 to 150 parts by weight and the amount of multifunctional isocyanates (component C) is from 1 to 100 parts by weight, in each case based on 100 parts by weight (phr) of the rubber component (A), may be used in the production of rubber vulcanates and molded rubber bodies of any kind, the vulcanates produced therefrom having an advantageous combination of mechanical properties, such as tensile stress at 300% elongation, ultimate elongation, tear resistance and abrasion resistance.Type: ApplicationFiled: June 14, 2013Publication date: October 24, 2013Inventors: Werner OBRECHT, Martin MEZGER
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Publication number: 20130225330Abstract: A golf ball having a relatively larger, lower density inner core, and a relatively thinner, higher density outer core such that the ball has a relatively large moment of inertia (MOI) to generate an improved spin rate profile. The inner core is a blend of highly neutralized acid polymer and metallocene-catalyzed polymer, and the golf ball has a cover surrounding the inner layers. Also, an “on demand” method and system for making such golf balls.Type: ApplicationFiled: February 27, 2012Publication date: August 29, 2013Applicant: NIKE, INC.Inventors: Seisuke Tomita, Thomas J. Kennedy, III
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Publication number: 20130064996Abstract: Disclosed herein is a method for recycling synthetic turf that includes combining a plurality of synthetic turf fragments with additives to form a mixture and extruding the mixture. The method produces a recycled material suitable for use as infill in a synthetic turf. Accordingly, an infill for synthetic turf and a synthetic turf including that infill are disclosed herein.Type: ApplicationFiled: November 8, 2012Publication date: March 14, 2013Inventor: Larry Mashburn
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Publication number: 20130046034Abstract: A process for creating polyolefin blends from waste streams with controlled rheological properties can include processing a waste stream to make a mixture comprising a mixture comprising polypropylene and polyethylene and compounding the mixture with one or more peroxides or nitroxides to produce a polyolefin blend. For example, a process can include: determining the required melt flow rate of the end product; determining the ratio of polyethylene to polypropylene to achieve the required melt flow rate; effecting a separation of polypropylene from polyethylene to achieve the desired composition; determining the amount of peroxide or peroxide concentrate required to increase the melt flow rate to the required level; melt compounding the mixture; evaluating the melt flow rate of the product; and adjusting the composition of polyethyelene and polypropylene or the amount of peroxide added if necessary to achieve the required melt flow rate.Type: ApplicationFiled: August 15, 2012Publication date: February 21, 2013Applicant: MBA POLYMERS, INC.Inventors: Brian L. Riise, Hyung Baek
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Patent number: 8362149Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.Type: GrantFiled: December 14, 2011Date of Patent: January 29, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
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Publication number: 20120276380Abstract: A cured adhesive composition comprising: (a) a copolymer comprising the reaction product of: 65 to 94.5 wt % of a C?8#191 acrylate ester, 0.5 to 5 wt % of a polar cross-linkable monomer, and 5-30 wt % of a non polar monomer, wherein the copolymer has a weight average molecular weight of 400,000 to 2,200,000 grains/mole; (b) 30 to 70 parts of a hydrogenated hydrocarbon tackifier per 100 parts of the copolymer; and (c) 0.01 to 3 parts (solid/solid) of a cross-linking agent per 100 parts of the copolymer wherein the cured adhesive has a peel value greater than 6 N/cm when tested according to FINAT test method No. 2 on a low density polyethylene; and further wherein the cured adhesive has a shear value greater than 2000 minutes when tested according to FINAT test method No. 8 on low density polyethylene. The cured adhesive of this disclosure is found to exhibit excellent adhesion to low surface energy substrates.Type: ApplicationFiled: December 15, 2010Publication date: November 1, 2012Inventors: Steffen Traser, Francois C. D'Haese
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Publication number: 20120261071Abstract: The invention relates to cured (meth)acrylate based adhesive composition, comprising at least two co-continuous phases of interpenetrating networks and at least two types of polymeric inclusions, in which one of the co-continuous phases comprises a polymer or copolymer based on at least one acrylic or methacrylic acid monomer or a derivative thereof. These compositions exhibit better facture toughness, especially at low temperatures.Type: ApplicationFiled: June 29, 2012Publication date: October 18, 2012Applicant: Huntsman International LLCInventors: Pauline Goodall Barker, Dimiter Lubomirov Kotzev
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Patent number: 8236895Abstract: Disclosed is a finish paint composition having a hydroxyl group containing resin (A) comprising a hydroxyl group value of 80 to 220 mgKOH/g, a glass transition temperature of ?50° or above but below 0° C., and 25 to 55 mass% of units of 4-hydroxybutyl (meth)acrylate origin, a hydroxyl group containing resin (B) with a hydroxyl group value of 80 to 220 mgKOH/g, and a glass transition temperature of 0 to 50° C., and a crosslinking agent (C) comprising polyisocyanate compound having isocyanate groups, wherein the proportions of hydroxyl group containing resin (A) and hydroxyl group containing resin (B) are, as a ratio of solid fraction masses, from 95/5 to 50/50, and the proportion of isocyanate groups of the crosslinking agent (C) with respect to the hydroxyl groups in total of the hydroxyl group containing resin (A) and the hydroxyl group containing resin (B), as the NCO/OH mol ratio, is 0.5 to 1.5.Type: GrantFiled: August 22, 2008Date of Patent: August 7, 2012Assignees: BASF Coatings Japan Ltd., BASF Coatings GmbHInventors: Hitoshi Taniguchi, Hiroyuki Takagi, Eishi Tsukamoto, Andreas Poppe, Björn Feldmann, Julia Melzer, Sabine Holtschulte, Karl-Heinz Joost
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Patent number: 8227544Abstract: This invention is directed to a coating composition comprising an coating composition comprising a crosslinkable composition and a crosslinking composition. The crosslinkable composition comprises an acrylic polyol wherein the acrylic polyol comprises at least 40 percent by weight of at least one linear or branched C8 or higher alkyl acrylate monomer and at least one polyester extended acrylate monomer. The coating composition is suitable for use as a basecoat and can be used in a 3-wet paint process that eliminates the primer curing booth.Type: GrantFiled: February 24, 2009Date of Patent: July 24, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Delson Jayme Trindade, Peter William Uhlianuk
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Publication number: 20120171480Abstract: An adhesive composition and an optical member using the same, the adhesive composition providing an adhesive having a storage modulus of about 8×105 to about 1×108 dyne/cm2 and a gel fraction of about 83% to about 95% as defined by Equation 1: Gel fraction (%)=(A/B)×100,??[Equation 1] in Equation 1, A is a mass measured after dissolving the adhesive at 23° C. for 48 hours in a solvent and then drying for 24 hours, and B is an initial mass.Type: ApplicationFiled: September 23, 2011Publication date: July 5, 2012Inventors: Woo Jin JEONG, Chul Jeong, Ri Ra Jung, Hee Yeon Ki
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Patent number: 8207268Abstract: A thixotropic agent comprising a first polyurea reaction product of a first polyisocyanate with a first amine and a second polyurea reaction product of a second polyisocyanate with a second amine different from the first polyurea reaction product precipitated in the presence of the colloidal particles of the first reaction product.Type: GrantFiled: June 28, 2006Date of Patent: June 26, 2012Assignee: Nuplex Resins B.V.Inventor: Richard Hendrikus Gerrit Brinkhuis
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Patent number: 8198370Abstract: The present invention relates to a substrate coated with a coating composition wherein the coating composition comprises a crosslinkable component and the crosslinkable component is a mixture of two different and optionally three different acrylic polymers. Each acrylic polymer has functional groups present that are reactive with a crosslinking component. The functional groups present on each polymer have different rates of reactivity with the crosslinking component.Type: GrantFiled: December 29, 2008Date of Patent: June 12, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Patricia Mary Ellen Sormani, James William O'Neil
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Publication number: 20120080068Abstract: An electrical connection material between conductors includes about 40 wt % to about 80 wt % of a urethane-modified acrylate resin, based on a total weight of the electrical connection material, the electrical connection material exhibiting, after curing, a tensile elongation of about 100% to about 500% and a yield point strain of about 10% to about 50% in a stress-strain curve.Type: ApplicationFiled: September 16, 2011Publication date: April 5, 2012Inventors: Sang Sik BAE, Kyoung Soo Park, Kyoung Hun Shin, Kang Bae Yoon
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Publication number: 20120083574Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.Type: ApplicationFiled: December 14, 2011Publication date: April 5, 2012Applicant: BRIDGESTONE SPORTS CO., LTD.Inventors: Yoshinori EGASHIRA, Jun SHINDO, Eiji TAKEHANA, Hiroyuki NAGASAWA
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Patent number: 8106125Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.Type: GrantFiled: August 27, 2008Date of Patent: January 31, 2012Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
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Publication number: 20120000599Abstract: Provided is a adhesive and an adhesive sheet which exhibit excellent chip-holding properties during dicing and from which chips can be easily stripped during pick up, even when considering changes over time. It is a adhesive composition which contains both (A) a (meth)acrylic acid ester copolymer component that has functional-group containing monomer units and a weight average molecular weight of less than 350,000 and (B) a (meth)acrylic ester copolymer component that has functional-group containing monomer units and a weight average molecular weight of 350,000 to 2,000,000 at a weight ratio of 10:90 to 90:10, and further contains 0.5 to 20 parts by mass of a crosslinking agent per 100 parts by mass of components (A) and (B) in total, the crosslinking agent being a crosslinking agent that reacts with both the functional groups of the component (A) and the functional groups of the component (B).Type: ApplicationFiled: February 9, 2010Publication date: January 5, 2012Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Tomomichi Takatsu, Masashi Kume
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Publication number: 20110316661Abstract: It is an objective of the present invention to provide a highly adhesive unsaturated polyester resin composition for fixing or immobilizing coils. There is provided an unsaturated polyester resin composition for adhesion of a coil, which includes the ingredients of: A) an unsaturated polyester resin and/or a vinyl ester resin; B) a monomer including a vinyl group as a polymerizable substituent at at least one end thereof; C) an isocyanate; and D) a polymerization initiator.Type: ApplicationFiled: June 23, 2011Publication date: December 29, 2011Inventors: Takahito MURAKI, Satoru Amou, Tomio Iwasaki
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Patent number: 8034876Abstract: There are provided an organic fiber-reinforced composite resin composition which is good in fiber dispersion, excellent in appearance, excellent in mechanical properties such as tensile elongation at break or impact strength and easy in thermal recycle; and a molded article obtained therefrom. An organic fiber-reinforced composite resin composition comprising (a) 60 to 95% by weight of a polyolefin resin (provided that an acid-modified polyolefin resin is excluded) and (b) 40 to 5% by weight (provided that (a)+(b)=100% by weight) of organic fiber to which a polar resin (provided that an acid-modified polyolefin resin is excluded) is attached, or an organic fiber-reinforced composite resin composition comprising organic fiber in an amount of 10 to 200 parts by weight based on 100 parts by weight of a polyolefin resin and having an Izod impact strength at ?40° C. of 10 kJ/m2 or more, and further, an organic fiber-reinforced composite resin molded article obtained therefrom.Type: GrantFiled: November 6, 2007Date of Patent: October 11, 2011Assignees: Mitsubishi Chemical Corporation, Teijin Fibers LimitedInventors: Masatoshi Oomori, Takayuki Itou, Takakazu Yoshihara, Taku Kitade
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Patent number: 8022141Abstract: In a golf ball composed of a core and a cover having a plurality of layers that encloses the core, at least a first layer of the cover is formed primarily of a heated mixture of (A) a metal ion neutralization product of an olefin-unsaturated carboxylic acid copolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer, (B) at least one type of olefin-unsaturated carboxylic acid copolymer and/or olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having the same content of unsaturated carboxylic acid as component A, and (C) a thermoplastic polyurethane elastomer; and at least one other cover layer adjoining the at least first cover layer is formed primarily of a non-ionomeric thermoplastic elastomer.Type: GrantFiled: April 20, 2009Date of Patent: September 20, 2011Assignee: Bridgestone Sports Co., Ltd.Inventor: Rinya Takesue
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Publication number: 20110105673Abstract: Compositions for forming molded articles, particularly, shells for automotive applications are made up of an aliphatic thermoplastic urethane/urea elastomer and, optionally, one or more copolymers, such as an olefin-containing or styrene containing copolymer. These compositions may be used to form a powder, pellets, microspheres or minibeads which may then be cast to form air bag door and instrument panel cover skins which may meet automotive deployment and weathering requirements.Type: ApplicationFiled: August 8, 2008Publication date: May 5, 2011Applicant: Bayer MaterialScience LLCInventors: William M. Humphrey, Paul Drago, Terry L. Anderson
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Patent number: 7923510Abstract: Heat-activable adhesive sheet of an adhesive comprising a blend of at least three synthetic nitrile rubber compositions S1, S2 and S3, each of which comprises at least one synthetic nitrile rubber, and at least one reactive resin which is capable of crosslinking with itself, with other reactive resins and/or with the nitrile rubbers of synthetic rubber compositions S1, S2 and S3, in which a) the blend of the heat-activable sheet being microphase-separated, characterized by at least three different glass transition temperatures in a DSC, b) at least one of said glass transition temperatures being greater than 10° C. and at least one of said glass transition temperature lower than ?20° C., c) the nitrile rubber or rubbers S1 having an acrylonitrile fraction of greater than/equal to 35%, d) the nitrile rubber or rubbers S2 having an acrylonitrile fraction of greater than 25% and less than 35%, e) the nitrile rubber S3 having an acrylonitrile fraction of less than/equal to 25%.Type: GrantFiled: July 27, 2006Date of Patent: April 12, 2011Assignee: teas SEInventors: Marc Husemann, Frank Hannemann, Matthias Koop, Thilo Dollase, Thorsten Krawinkel