Contacting Solid Polymer From Ethylenic Reactants Only With Ethylenic Reactant Wherein Said Contacting Is Either Concurrent With Or Subsequent To Contacting Of Said Solid Polymer With The -n=c=x Reactant Or Polymer Thereof Patents (Class 525/126)
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Patent number: 11208581Abstract: Thermally vulcanisable, meltable adhesives and processes have a meltable polybutadiene-polyurethane, ground sulphur and optionally at least one vulcanisation accelerator, at least one filling material, at least one epoxide resin, at least one tackifier resin, bitumen, at least one softener and further auxiliary and additive materials, wherein said adhesives and processes can be thermally vulcanised within a temperature range of 130° C. to 230° C., such that same, as well as an adhesive strip produced from same, can be used for adhesion and/or sealing in the automotive industry, as well as in structural work on oiled sheet metal, and in the painting line on e-coated or otherwise painted sheet metal, for example, for crimp fold adhesion, for crimp fold sealing, for seam sealing, for lining adhesion, for hole closure and much more.Type: GrantFiled: September 12, 2017Date of Patent: December 28, 2021Assignee: TESA SEInventors: Sebastian Dietze, Kim Elsenbach, Frank Hannemann, Björn Zeysing, Uwe Schümann, Matthias Seibert, Katja Meyer, Bernd Dietz, Jasmin Flucke, Amy Kaus
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Patent number: 10787583Abstract: A polymerizable liquid useful for the production of a three-dimensional object comprised of silicone, or a copolymer thereof, which includes at least one constituent selected from the group consisting of (i) a blocked or reactive blocked siloxane-containing prepolymer, (ii) a blocked or reactive blocked siloxane-containing polyisocyanate, and (iii) a blocked or reactive blocked siloxane-containing polyisocyanate chain extender. Methods of using the same in additive manufacturing processes such as continuous liquid interface production are also described.Type: GrantFiled: December 21, 2016Date of Patent: September 29, 2020Assignee: Carbon, Inc.Inventors: Jessica D. Drazba, Kai Chen, Jason P. Rolland
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Patent number: 10174175Abstract: The present disclosure provides methods of improving adhesion of a non-di-(2-ethylhexyl)phthalate (DEHP) plasticized polyvinyl chloride (PVC) to an acrylic-based polymer or an ABS-based polymer. Such methods may comprise blending the acrylic-based polymer or ABS-based polymer with an impact modifier so that a rubber content in the acrylic-based polymer or ABS-based polymer is greater than 12% (w/w). Also provided are components of a device (e.g., a medical device) made by the disclosed methods.Type: GrantFiled: June 6, 2016Date of Patent: January 8, 2019Assignees: BAXTER INTERNATIONAL INC., BAXTER HEALTHCARE SAInventors: Zehra Sibel Sevinc, Michael Tung Kiung Ling
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Patent number: 9884976Abstract: Described are sealing primer compositions that can be used to reduce paint defects such as pops or vapor boil on painted plastic substrates, as well as related methods for sealing plastic substrates, and sealed plastic substrates. Sealing primer compositions of the invention include a functionalized polydiene polymer such as a hydroxylated or other functional-group-containing polybutadiene polymer.Type: GrantFiled: August 19, 2005Date of Patent: February 6, 2018Assignee: Red Spot Paint & Varnish Co., Inc.Inventors: Mark A Parker, David Keith Cannon
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Patent number: 9574043Abstract: An elastomeric polymer, comprising (1) a hard segment in the amount of 10% to 60% by weight of the elastomeric polymer, wherein the hard segment includes a urethane, urea or urethaneurea; and (2) a soft segment in the amount of 40% to 90% by weight of the elastomeric polymer. The soft segment comprises (a) at least 2% by weight of the soft segment of at least one polyether macrodiol, and/or at least one polycarbonate macrodiol; and (b) at least 2% by weight of the soft segment of at least one polyisobutylene macrodiol and/or diamine.Type: GrantFiled: January 12, 2010Date of Patent: February 21, 2017Assignee: University of Massachusetts LowellInventors: Rudolf Faust, Umaprasana Ojha
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Patent number: 9334403Abstract: Moisture-curable, urethane-containing prepolymers containing urethanes incorporated into the prepolymer backbone and compositions thereof for use in sealant applications are disclosed. The prepolymers can be prepared by reacting an isocyanate-terminated urethane-containing adduct with a compound comprising a group reactive with an isocyanate group and at least one polyalkoxysilyl group. Compositions containing a moisture-curable, urethane-containing prepolymer and a moisture cure catalyst can be used to provide cured compositions exhibiting improved tensile strength. Compositions containing the prepolymers are useful in aerospace sealant applications.Type: GrantFiled: March 7, 2014Date of Patent: May 10, 2016Assignee: PRC-DeSoto International, Inc.Inventors: Raquel Keledjian, Renhe Lin
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Patent number: 8987374Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilizing side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.Type: GrantFiled: May 3, 2010Date of Patent: March 24, 2015Assignee: The Lubrizol CorporationInventors: Stuart Nicholas Richards, Andrew James Shooter
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Patent number: 8933146Abstract: The present invention describes the preparation of an aqueous polyurethane dispersion which is cured by radiation, and its use as binder.Type: GrantFiled: August 6, 2008Date of Patent: January 13, 2015Assignee: Bayer MaterialScience AGInventors: Stefan Sommer, Richard Kopp, Harald Blum, Christoph Irle, Jan Weikard, Erhard Luehmann
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Publication number: 20140329947Abstract: An acrylic-polyurethane hybrid sealant composition is provided with desirable physical and mechanical properties such as superior adhesion, tensile strength, rheology and bond strength. In particular, the sealant composition of the invention is formulated with isocyanate modified acrylic polymer The composition includes an acrylic pre-polymer, an isocyante functional monomer, a triacrylate as a cross-linker, and a catalyst. A process for preparing the composition is also provided. The hybrid sealant composition is well suited for sealing and bonding requirements in fabrication of articles such as window glazing, back bedding, construction, aerospace and appliances industries. A hybrid sealant composition is provided that develops adequate adhesion and bond strength equivalent to commercially available sealants when used in sealing and bonding applications and is readily formulated to be self- leveling. Articles so fabricated using the hybrid sealant composition are also provided.Type: ApplicationFiled: June 16, 2012Publication date: November 6, 2014Inventors: Nader Sahawneh, Mona Kulkarna, Nagesh Chitnavis, Subodh Deshpande
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Patent number: 8853295Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.Type: GrantFiled: February 12, 2010Date of Patent: October 7, 2014Assignee: ALLNEX IP S.a.r.L.Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
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Publication number: 20140249242Abstract: The present invention relates to a novel type of grafting or crosslinking method for (meth)acrylates in which the reaction is initiated by isocyanates and specific bases having an imine structure. Using this novel and specifically applicable method, polymers, particularly polyolefins having double bonds, may be grafted or crosslinked in a suitable reaction procedure. Furthermore, these unsaturated polymers may be used, following reaction with (poly)isocyanates, to prepare graft or block copolymers or also for the bonding of the modified unsaturated polyolefins to polyamides, polyesters, polycarbonates, polyimines or polyurethanes.Type: ApplicationFiled: August 24, 2012Publication date: September 4, 2014Applicant: Evonik Degussa GmbHInventors: Friedrich Georg Schmidt, Stefan Spange, Ingmar Polenz
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Patent number: 8822600Abstract: The present invention provides a method for producing a terminal acrylic-modified polybutadiene or terminal acrylic-modified hydrogenated polybutadiene that does not become white and turbid, without using an organotin compound. The production method of the present invention comprises reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organobismuth compound and a tetraalkoxyzirconium compound.Type: GrantFiled: September 20, 2011Date of Patent: September 2, 2014Assignee: Nippon Soda Co., Ltd.Inventor: Hiroki Hashimoto
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Patent number: 8785556Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Durable, weatherable and scratch-resistant coatings are provided by compositions comprising a fluorinated component and an adhesion promoter compound. The adhesion promoter compound can include an alkoxy group, a furfuryl-containing ring structure, and a reactive group.Type: GrantFiled: April 30, 2012Date of Patent: July 22, 2014Assignee: Cytonix, LLCInventor: James F. Brown
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Patent number: 8772409Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polyalkenamer/functionalized organic modifier composition as a majority ingredient.Type: GrantFiled: September 14, 2012Date of Patent: July 8, 2014Assignee: Taylor Made Golf Company, Inc.Inventors: Hyun J. Kim, Hong G. Jeon
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Patent number: 8742059Abstract: A polymer precursor including a part which sequences an unsaturated bond having a ? electron orbit and a single bond alternately is disclosed. The polymer precursor has a first functional group and a second functional group which form a repeating unit constituting a polymer skeleton of an end product by an intramolecular reaction. At least a part of a conjugated state formed by the ? electron orbit in the molecule is disconnected or weakened due to a three-dimensional structure of the molecule and a transmittance with respect to an electromagnetic wave of at least one wavelength selected from the group consisting of 436 nm, 405 nm, 365 nm, 248 nm and 193 nm is improved.Type: GrantFiled: November 30, 2011Date of Patent: June 3, 2014Assignee: Dai Nippon Printing Co., Ltd.Inventor: Katsuya Sakayori
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Patent number: 8742022Abstract: Presently described are coating compositions comprising a polymerizable resin composition and a non-ionic unpolymerizable surfactant. In some embodiments, the coating comprises greater than 10 wt-% of non-ionic unpolymerizable surfactant. In other embodiments, the coating composition comprises an an additive comprising a silicone group or a fluorinated group and a hydrophobic group. Also described are articles comprising the cured coating compositions. In one embodiment, an article is described comprising a cured coating wherein the cured coating exhibits a property of an initially visible simulated fingerprint reducing in visibility in 1-20 minutes. Also described is a method of determining the fingerprint visibility of a coating composition and a polyacylate composition useful as an additive. In another embodiment a coated surface is described comprising a polymeric organic material comprising a plurality of pores wherein a portion of the pores are interconnected and comprise a lipophilic liquid.Type: GrantFiled: November 30, 2011Date of Patent: June 3, 2014Assignee: 3M Innovative Properties CompanyInventors: Richard J. Pokorny, Thomas P. Klun, Christopher B. Walker, Jr., David B. Olson, Joan M. Noyola, Michelle L. Toy, Evan L. Schwartz
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Patent number: 8735464Abstract: A radically curable polyurethane composite for dental restorations, including provisional restorations, includes polyurethane dimethacrylate prepolymers that have at least one flexible unit within a polyurethane dimethacrylate backbone, and one or more dimethacrylate monomers. Composite materials made with polyurethane dimethacrylate prepolymers of the invention exhibit superior and optimal properties of flexural strength and deflection-at-break relative to conventional dental resin composites. Composite materials of the invention also provide improved melt-resistance in response to the heat of grinding or finishing, thereby improving the fit of restorations made from the composite and preserving the finishing instruments. Methods of treating a tooth using the radically curable polyurethane composite and methods of making the polyurethane dimethacrylate prepolymers with flexible units is also provided. A kit including the radically curable polyurethane composite is also described.Type: GrantFiled: October 19, 2012Date of Patent: May 27, 2014Assignee: Pulpdent CorporationInventors: Sunny Skaria, Kenneth Berk
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Publication number: 20130186292Abstract: Disclosed is a resin composition for a flexographic printing plate, comprising (Component A) a binder resin and (Component B) a compound represented by Formula (1) and/or Formula (2), Component B being contained at 1 to 50 parts by mass relative to 100 parts by mass of Component A, wherein in Formulae (1) and (2) R1 and R4 independently denote a hydrogen atom or a methyl group, R2 and R5 independently denote a divalent organic group having 1 to 20 carbons, and R3 and R6 independently denote a monovalent organic group having 1 to 20 carbons, R3 and R6 not comprising an ethylenically unsaturated group, a dialkoxysilyl group, or a trialkoxysilyl group.Type: ApplicationFiled: January 16, 2013Publication date: July 25, 2013Applicant: FUJIFILM CORPORATIONInventor: Fujifilm Corporation
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Publication number: 20130165586Abstract: The present invention provides a method for producing a terminal acrylic-modified polybutadiene or terminal acrylic-modified hydrogenated polybutadiene that does not become white and turbid, without using an organotin compound. The production method of the present invention comprises reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organobismuth compound and a tetraalkoxyzirconium compound.Type: ApplicationFiled: September 20, 2011Publication date: June 27, 2013Applicant: NIPPON SODA CO., LTD.Inventor: Hiroki Hashimoto
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Patent number: 8450419Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.Type: GrantFiled: August 24, 2010Date of Patent: May 28, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 8415425Abstract: Provided is a method for protecting the surface of a member to be processed, which comprises providing a protective film made of a photocurable resin composition for surface protection on the surface of the member to be processed, processing the member to be processed, and removing the protective film from the member to be processed, wherein the photocurable resin composition comprises (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton and (D) a photopolymerization initiator, which comprises from 1 to 50 parts by weight of (A), from 5 to 95 by mass of (B) and from 0.1 to 50 parts by mass of (C).Type: GrantFiled: March 30, 2012Date of Patent: April 9, 2013Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tomoyuki Kanai, Kazuhiro Oshima
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Publication number: 20130041067Abstract: A radically curable polyurethane composite for dental restorations, including provisional restorations, includes polyurethane dimethacrylate prepolymers that have at least one flexible unit within a polyurethane dimethacrylate backbone, and one or more dimethacrylate monomers. Composite materials made with polyurethane dimethacrylate prepolymers of the invention exhibit superior and optimal properties of flexural strength and deflection-at-break relative to conventional dental resin composites. Composite materials of the invention also provide improved melt-resistance in response to the heat of grinding or finishing, thereby improving the fit of restorations made from the composite and preserving the finishing instruments. Methods of treating a tooth using the radically curable polyurethane composite and methods of making the polyurethane dimethacrylate prepolymers with flexible units is also provided. A kit including the radically curable polyurethane composite is also described.Type: ApplicationFiled: October 19, 2012Publication date: February 14, 2013Applicant: PULPDENT CORPORATIONInventor: Pulpdent Corporation
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Patent number: 8372914Abstract: Urethane modified water-reducible alkyd resins ABCD, comprising moieties derived from polyhydric alcohols A, modified fatty acids B made h? grafting olefinically unsaturated carboxylic acids B2 onto fatty acids B1, ungrafted fatty acids C and polyfunctional isocyanates D, a process for their production, and a method of use thereof in coating bindersType: GrantFiled: February 20, 2006Date of Patent: February 12, 2013Assignee: Cytec Surface Specialties Austria GmbHInventors: Gerhard Reidlinger, Edmund Urbano, Ewald Zrin, Manfred Gogg, Johannes Scherz
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Patent number: 8362149Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.Type: GrantFiled: December 14, 2011Date of Patent: January 29, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
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Patent number: 8349951Abstract: Polymers are disclosed that include a structure having the formula wherein, R1 is independently selected from a C2-10 n-alkylene group, a C2-6 branched alkylene group, a C6-8 cycloalkylene group, a C6-10 alkylcycloalkylene group, —[(—CH2—)p—X—]q—(—CH2—)r—, or —[(—CH2—)p—X—]q—(—CH2—)r—, wherein at least one —CH2— unit is substituted with a methyl group, wherein p is an integer having a value ranging from 2 to 6, q is an integer having a value ranging from 1 to 5, r is an integer having a value ranging from 2 to 10, and X is selected from O, S, and —NR—, wherein R is hydrogen or methyl; R2 denotes a structure derived from allyl (meth)acrylate or a multi-functional (meth)acrylate; R3 is independently selected from hydrogen and an alkyl group; n is an integer having a value ranging from 1 to 60; and m is a rational number having a value ranging from 0 to 10.Type: GrantFiled: May 31, 2005Date of Patent: January 8, 2013Assignee: PRC DeSoto International, Inc.Inventors: Suresh Sawant, Chandra Bhushan Rao, Jak H. Aklian
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Patent number: 8338526Abstract: To provide an environmentally-friendly curable resin composition for surface protection, having a high adhesive strength and being capable of forming a protective film which will readily be removed in the film form without adhesive residue in water on a member to be processed, a photocurable adhesive using it, a method for temporarily fixing a member, and a method for removing a protective film. A curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, and (C) a resin having a cyclopentadiene skeleton. Further, a curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton, and (D) a photopolymerization initiator.Type: GrantFiled: July 12, 2011Date of Patent: December 25, 2012Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tomoyuki Kanai, Kazuhiro Oshima
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Patent number: 8288476Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.Type: GrantFiled: February 26, 2010Date of Patent: October 16, 2012Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Publication number: 20120095168Abstract: A method for controlling the physical state of an ultra-high molecular weight polymer to make the ultra-high molecular weight polymer suitable for further processing, and related polymers compositions methods and systems, wherein the method comprises combining a catalyst, monomers, and an additive, for a time and under condition to allow synthesis of a nascent polymer and co-crystallization of the nascent polymer with the additive.Type: ApplicationFiled: October 18, 2011Publication date: April 19, 2012Inventors: Julia A. KORNFIELD, Artemis AILIANOU, Sara RONCA, Sanjay RASTOGI, Giuseppe FORTE
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Patent number: 8106125Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.Type: GrantFiled: August 27, 2008Date of Patent: January 31, 2012Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
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Publication number: 20110316661Abstract: It is an objective of the present invention to provide a highly adhesive unsaturated polyester resin composition for fixing or immobilizing coils. There is provided an unsaturated polyester resin composition for adhesion of a coil, which includes the ingredients of: A) an unsaturated polyester resin and/or a vinyl ester resin; B) a monomer including a vinyl group as a polymerizable substituent at at least one end thereof; C) an isocyanate; and D) a polymerization initiator.Type: ApplicationFiled: June 23, 2011Publication date: December 29, 2011Inventors: Takahito MURAKI, Satoru Amou, Tomio Iwasaki
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Publication number: 20110269868Abstract: To provide an environmentally-friendly curable resin composition for surface protection, having a high adhesive strength and being capable of forming a protective film which will readily be removed in the film form without adhesive residue in water on a member to be processed, a photocurable adhesive using it, a method for temporarily fixing a member, and a method for removing a protective film. A curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, and (C) a resin having a cyclopentadiene skeleton. Further, a curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton, and (D) a photopolymerization initiator.Type: ApplicationFiled: July 12, 2011Publication date: November 3, 2011Applicant: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tomoyuki KANAI, Kazuhiro Oshima
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Publication number: 20110262675Abstract: The present invention provides a photo-curable transfer sheet by which an optical information recording medium having small thickness and high capacity can be advantageously prepared, the photo-curable transfer layer of the sheet cured in the production of the optical information recording medium having excellent adhesion to the reflective layer such silver alloy and easy peeling property from the stamper to easily bring about the transfer layer having an uneven surface such as pits, etc accurately formed along an uneven surface of the stamper. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer and a reactive diluent having a photopolymerizable functional group, and the reactive diluent has at least one hydroxyl group and an acryloyl group and/or methacryloyl group, the total of acryloyl group and/or methacryloyl group being at least two.Type: ApplicationFiled: August 31, 2006Publication date: October 27, 2011Applicant: BRIDGESTONE CORPORATIONInventors: Takato Inamiya, Hideki Kitano, Hidefumi Kotsubo, Kenji Murayama
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Publication number: 20110043737Abstract: The invention relates to an acrylic adhesive composition, more particularly, to an adhesive composition which: specifies the contents of a (meth)acrylic ester-based monomer and an aromatic group-containing monomer of an acrylic copolymer as a composition having little or no difference of birefringence; has excellent durability; and can reduce light leakage due to flexure by mixing a crosslinkable functional group-containing acrylic copolymer (A) and an acrylic copolymer (B) which does not contain the crosslinkable functional group, in a ratio of 1:9 to 5:5.Type: ApplicationFiled: January 12, 2009Publication date: February 24, 2011Applicant: LG CHEM, LTD.Inventors: Se Ra Kim, Kee Young Kim, Sung Soo Yoon, Min Ki Lee, No Ma Kim, In Cheon Han
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Patent number: 7803874Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.Type: GrantFiled: July 18, 2006Date of Patent: September 28, 2010Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Publication number: 20100105827Abstract: A method for producing a modified conjugated diene polymer includes a step (A) carrying out a primary modification reaction that reacts a heterocumulene compound having two or more specific functional groups with a conjugated diene polymer having a vinyl content of below 10% and a cis-1,4-bond content of 75% or more and possessing an active end to obtain a primary-modified conjugated diene polymer, and a step (B) carrying out a secondary modification reaction that reacts an active hydrogen-containing compound that includes one or more functional groups selected from the group consisting of an amino group, an imino group, a mercapto group, and a hydroxyl group with the primary-modified conjugated diene polymer to obtain a secondary-modified conjugated diene polymer. The method can produce a modified conjugated diene polymer that exhibits low heat build-up (low fuel consumption) and excellent wear resistance.Type: ApplicationFiled: December 27, 2007Publication date: April 29, 2010Applicant: JSR CORPORATIONInventors: Ryouji Tanaka, Kouichirou Tani, Takuo Sone, Toshihiro Tadaki
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Patent number: 7700689Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.Type: GrantFiled: May 31, 2006Date of Patent: April 20, 2010Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 7700662Abstract: The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.Type: GrantFiled: March 30, 2007Date of Patent: April 20, 2010Assignee: Bayer MaterialScience AGInventors: Michael Ludewig, Jan Weikard, Nicolas Stoeckel, Wolfgang Fischer
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Publication number: 20100093924Abstract: The invention relates to a synthetic resin, based on partly cross-linked poly(meth)acrylate-urethane-(meth)acrylates in urethane(meth)acrylates, obtainable by: (a) provision of (meth)acrylate monomers (I), which have no groups reactive to isocyanate groups and (meth)acrylate monomers (II), with (a) group(s) reactive to isocyanate groups, (b) polymerization of the (meth)acrylate monomers (I) and (II) to give a poly(meth)acrylate (III), with groups reactive to isocyanate groups, (c) reaction of the poly(meth)acrylate (III) with an isocyanate compound (IV), with more than one isocyanate group, in such a manner that 5 to 40% of the isocyanate groups of the isocyanate compound (IV) react with the above groups reactive to isocyanate groups, whereby partial cross-linking of (III) with an increase in weight average molecular weight by a factor of 2 to 20 occurs, in which one given (IV) reacts with more than one of the isocyanate groups thereof with more than one given (III) and (d) reaction of the compound obtained iType: ApplicationFiled: January 11, 2006Publication date: April 15, 2010Inventors: Andreas Lerschmacher, Siegfried Krause, Peter Kuhlmann, Klaus Hock
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Publication number: 20100055068Abstract: The invention features grafted polymer systems for use in medical devices and/or for the delivery of active agents. The grafted polymers include at least one transport moiety, a linear backbone segment, and a pendant segment.Type: ApplicationFiled: April 13, 2007Publication date: March 4, 2010Applicant: INTERFACE BIOLOGICS INCORPORATEDInventors: Paul J. Santerre, Roseita Esfand, Meilin Yang
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Publication number: 20100036056Abstract: The present invention relates to the radical cold curing of synthetic resins based on poly(meth)acrylate-urethane(meth)acrylates in urethane(meth)acrylates and optionally (meth)acrylates and/or reactive diluents using suitable additives, and also the use of these radically cold-curable synthetic resins as binding agents in radically cold-curable mixtures, as well as the organic synthetic glasses/plastics, synthetic glass/plastic workpieces and composite materials and workpieces obtained from these mixtures by radical cold curing, and also the production and use of these same mixtures, organic synthetic glasses/plastics, synthetic glass/plastic workpieces and composite materials and workpieces.Type: ApplicationFiled: October 5, 2007Publication date: February 11, 2010Applicant: ASHLAND-SÜDCHEMIE KERNFEST GMBHInventors: Peter Kuhlmann, Andreas Lehrschmacher, Klaus Houck
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Publication number: 20090324961Abstract: UV curable urethane(meth)acrylate polymers of Formula (1), where: R1 and R? are each independently hydrogen or C1-20hydrocarbo, R2, R?2, R3 and R4 are each independently optionally substituted divalent organo group, and p is an integer from about 6 to about 100 which are useful as laminating and/or pressure sensitive adhesives are disclosed as is methods of making them. The oligomers/polymers comprise a urethane extended backbone formed by reacting diisocyanates with polyols derived from rubber oligomers/polymers.Type: ApplicationFiled: April 28, 2006Publication date: December 31, 2009Inventors: Victor Lu, Jeffrey Wang
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Patent number: 7495057Abstract: The invention relates to resin compositions that contains as components: (A) a monomer with at least one ethylenic unsaturation and with an isocyanate reactive group, (B) an ethylenically unsaturated monomer that can react with component (A) by means of radical polymerization, (C) a polyisocyanate that can react with component (A) by means of a polyurethane reaction and that on average has at least 1.75 isocyanate groups, (D) a catalyst for the radical polymerization, and that also contains (E) a thermoplastic polymer with an average molecular weight of at least 10,000 Dalton. The invention also relates to a process for the preparation of moulded articles from such resin compositions, as well as the moulded articles themselves.Type: GrantFiled: April 8, 2002Date of Patent: February 24, 2009Assignee: DSM IP Assets B.V.Inventors: Adrianus J De Koning, Markus R Luesken, Peter Dijkink
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Patent number: 7419703Abstract: The invention provides heat-curable thixotropic mixtures containing carbamate and/or allophanate groups, including at least one oligomer and/or polymer containing at least one of carbamate and allophanate groups, and at least one thixotropic agent that is a urea derivative preparable by reacting at least one amine and/or water with at least one isocyanate in the presence of at least one amino resin. The invention further provides processes for preparing the mixtures and coating materials, adhesives and sealing compounds prepared from the mixtures.Type: GrantFiled: August 26, 2005Date of Patent: September 2, 2008Assignee: BASF Coatings AGInventors: Hubert Baumgart, Michael A Gessner, Bruce Oermann, Paul J Harris
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Patent number: 7358306Abstract: Curable (per)fluoropolyether polyurethanes obtained by reaction in a first step of a) (per)fluoropolyether diols having a number average molecular weight from 2,000 to 5,000; with b) diisocyanates of formula OCN—R—NCO ??(VIA) wherein R is a hydrogenated and/or fluorinated radical; in a second step with the compound c) saturated or unsaturated aliphatic hydrogenated diols, (alkyl)cycloaliphatic, aromatic; oligomers or polymers of butadiene with a number average molecular weight from 500 to 4,000 having end hydroxyl groups; provided that: when the diisocyanate b) is used and the radical R in formula (VIA) is: —Ph—CH2—Ph—, the hydrogenated diols c) are optional; when the radical R has a meaning different from that above mentioned, at least one of the used hydrogenated diols c) is selected from those belonging to the c2)-c6) groups; the sum of the equivalents of the compounds a) and c) being equal to the equivalents of the compound b).Type: GrantFiled: June 20, 2002Date of Patent: April 15, 2008Assignee: Ausimont S.p.A.Inventors: Stefano Turri, Sergio Novelli, Anna Staccione
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Publication number: 20070282069Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.Type: ApplicationFiled: May 31, 2006Publication date: December 6, 2007Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 7193000Abstract: A golf ball comprising a core and a cover is disclosed. At least a layer of the golf ball is made from an elastomer composition comprising a least one polydiene rubber and at least one moisture scavenger, such as p-toluene sulfonyl isocyanate. The moisture scavenger is generally present in the elastomer composition in an amount of 10 phr or less, and particularly from 0.1 to 5 phr, by weight of the elastomer.Type: GrantFiled: May 15, 2004Date of Patent: March 20, 2007Assignee: Acushnet CompanyInventor: Joseph B. Mayer
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Patent number: 7144955Abstract: Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.Type: GrantFiled: October 27, 2003Date of Patent: December 5, 2006Assignees: Bayer MaterialScience LLC, Bayer MaterialScience AGInventors: Scott A. Grace, Michael J. Dvorchak, Richard R. Roesler, Dinesh Pethiyagoda, Michael K. Jeffries, Jan Weikard
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Patent number: 7037972Abstract: A multicomponent system curable thermally and with actinic radiation (dual cure), comprising (A) at least one component comprising at least one constituent containing at least one isocyanate-reactive functional group and at least one functional group having at least one bond which can be activated with actinic radiation, and at least one vinylaromatic-allyl alcohol copolymer, and (B) at least one component comprising at least one polyisocyanate, and its use as a coating material, adhesive and sealing compound.Type: GrantFiled: September 26, 2001Date of Patent: May 2, 2006Assignee: BASF Coatings AGInventors: Egbert Nienhaus, Bernhard Lettmann
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Patent number: 6906136Abstract: A UV-curable composition is disclosed. The composition comprises a crosslinking agent, a hydroxyalkyl acrylate or methacrylate, and an acrylic polyol. The crosslinking agent is selected from the group consisting of multifunctional isocyanates, melamines, and silanes. The acrylic polyol comprises recurring units of an allylic alcohol. The composition can be irradiated to be solidified and then fully cured by the urethane, melamine, or silane reactions. Alternatively, the composition can be cured by the urethane, melamine, or silane reactions, and then fully cured by radiation. The invention provides low VOC but high performance coatings. More importantly, the invention provides a UV-curable system without the need for acrylated oligomers.Type: GrantFiled: April 22, 2003Date of Patent: June 14, 2005Assignee: Arco Chemical Technology, L.P.Inventors: Daniel B. Pourreau, Shanti P. Patel, L. Joseph Junker, Wei Wang, Stephen H. Harris, Shao-Hua Guo
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Compatibilizing agent, radical polymerizable resin composition, molding material, and molded article
Patent number: 6897258Abstract: An object of the present invention is to provide a practical compatibilizing agent which makes it possible to convert the resin mixture into a homogeneous resin mixture free from separation and to eliminate defects caused by separation on molding by prevention of the separation between the radical polymerizable unsaturated resin and low profile additive, which could have not been attained by the prior art.Type: GrantFiled: January 10, 2003Date of Patent: May 24, 2005Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Akira Takano, Takashi Yasumura