Contacting Solid Polymer From Ethylenic Reactants Only With Ethylenic Reactant Wherein Said Contacting Is Either Concurrent With Or Subsequent To Contacting Of Said Solid Polymer With The -n=c=x Reactant Or Polymer Thereof Patents (Class 525/126)
  • Patent number: 11208581
    Abstract: Thermally vulcanisable, meltable adhesives and processes have a meltable polybutadiene-polyurethane, ground sulphur and optionally at least one vulcanisation accelerator, at least one filling material, at least one epoxide resin, at least one tackifier resin, bitumen, at least one softener and further auxiliary and additive materials, wherein said adhesives and processes can be thermally vulcanised within a temperature range of 130° C. to 230° C., such that same, as well as an adhesive strip produced from same, can be used for adhesion and/or sealing in the automotive industry, as well as in structural work on oiled sheet metal, and in the painting line on e-coated or otherwise painted sheet metal, for example, for crimp fold adhesion, for crimp fold sealing, for seam sealing, for lining adhesion, for hole closure and much more.
    Type: Grant
    Filed: September 12, 2017
    Date of Patent: December 28, 2021
    Assignee: TESA SE
    Inventors: Sebastian Dietze, Kim Elsenbach, Frank Hannemann, Björn Zeysing, Uwe Schümann, Matthias Seibert, Katja Meyer, Bernd Dietz, Jasmin Flucke, Amy Kaus
  • Patent number: 10787583
    Abstract: A polymerizable liquid useful for the production of a three-dimensional object comprised of silicone, or a copolymer thereof, which includes at least one constituent selected from the group consisting of (i) a blocked or reactive blocked siloxane-containing prepolymer, (ii) a blocked or reactive blocked siloxane-containing polyisocyanate, and (iii) a blocked or reactive blocked siloxane-containing polyisocyanate chain extender. Methods of using the same in additive manufacturing processes such as continuous liquid interface production are also described.
    Type: Grant
    Filed: December 21, 2016
    Date of Patent: September 29, 2020
    Assignee: Carbon, Inc.
    Inventors: Jessica D. Drazba, Kai Chen, Jason P. Rolland
  • Patent number: 10174175
    Abstract: The present disclosure provides methods of improving adhesion of a non-di-(2-ethylhexyl)phthalate (DEHP) plasticized polyvinyl chloride (PVC) to an acrylic-based polymer or an ABS-based polymer. Such methods may comprise blending the acrylic-based polymer or ABS-based polymer with an impact modifier so that a rubber content in the acrylic-based polymer or ABS-based polymer is greater than 12% (w/w). Also provided are components of a device (e.g., a medical device) made by the disclosed methods.
    Type: Grant
    Filed: June 6, 2016
    Date of Patent: January 8, 2019
    Assignees: BAXTER INTERNATIONAL INC., BAXTER HEALTHCARE SA
    Inventors: Zehra Sibel Sevinc, Michael Tung Kiung Ling
  • Patent number: 9884976
    Abstract: Described are sealing primer compositions that can be used to reduce paint defects such as pops or vapor boil on painted plastic substrates, as well as related methods for sealing plastic substrates, and sealed plastic substrates. Sealing primer compositions of the invention include a functionalized polydiene polymer such as a hydroxylated or other functional-group-containing polybutadiene polymer.
    Type: Grant
    Filed: August 19, 2005
    Date of Patent: February 6, 2018
    Assignee: Red Spot Paint & Varnish Co., Inc.
    Inventors: Mark A Parker, David Keith Cannon
  • Patent number: 9574043
    Abstract: An elastomeric polymer, comprising (1) a hard segment in the amount of 10% to 60% by weight of the elastomeric polymer, wherein the hard segment includes a urethane, urea or urethaneurea; and (2) a soft segment in the amount of 40% to 90% by weight of the elastomeric polymer. The soft segment comprises (a) at least 2% by weight of the soft segment of at least one polyether macrodiol, and/or at least one polycarbonate macrodiol; and (b) at least 2% by weight of the soft segment of at least one polyisobutylene macrodiol and/or diamine.
    Type: Grant
    Filed: January 12, 2010
    Date of Patent: February 21, 2017
    Assignee: University of Massachusetts Lowell
    Inventors: Rudolf Faust, Umaprasana Ojha
  • Patent number: 9334403
    Abstract: Moisture-curable, urethane-containing prepolymers containing urethanes incorporated into the prepolymer backbone and compositions thereof for use in sealant applications are disclosed. The prepolymers can be prepared by reacting an isocyanate-terminated urethane-containing adduct with a compound comprising a group reactive with an isocyanate group and at least one polyalkoxysilyl group. Compositions containing a moisture-curable, urethane-containing prepolymer and a moisture cure catalyst can be used to provide cured compositions exhibiting improved tensile strength. Compositions containing the prepolymers are useful in aerospace sealant applications.
    Type: Grant
    Filed: March 7, 2014
    Date of Patent: May 10, 2016
    Assignee: PRC-DeSoto International, Inc.
    Inventors: Raquel Keledjian, Renhe Lin
  • Patent number: 8987374
    Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilizing side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: March 24, 2015
    Assignee: The Lubrizol Corporation
    Inventors: Stuart Nicholas Richards, Andrew James Shooter
  • Patent number: 8933146
    Abstract: The present invention describes the preparation of an aqueous polyurethane dispersion which is cured by radiation, and its use as binder.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: January 13, 2015
    Assignee: Bayer MaterialScience AG
    Inventors: Stefan Sommer, Richard Kopp, Harald Blum, Christoph Irle, Jan Weikard, Erhard Luehmann
  • Publication number: 20140329947
    Abstract: An acrylic-polyurethane hybrid sealant composition is provided with desirable physical and mechanical properties such as superior adhesion, tensile strength, rheology and bond strength. In particular, the sealant composition of the invention is formulated with isocyanate modified acrylic polymer The composition includes an acrylic pre-polymer, an isocyante functional monomer, a triacrylate as a cross-linker, and a catalyst. A process for preparing the composition is also provided. The hybrid sealant composition is well suited for sealing and bonding requirements in fabrication of articles such as window glazing, back bedding, construction, aerospace and appliances industries. A hybrid sealant composition is provided that develops adequate adhesion and bond strength equivalent to commercially available sealants when used in sealing and bonding applications and is readily formulated to be self- leveling. Articles so fabricated using the hybrid sealant composition are also provided.
    Type: Application
    Filed: June 16, 2012
    Publication date: November 6, 2014
    Inventors: Nader Sahawneh, Mona Kulkarna, Nagesh Chitnavis, Subodh Deshpande
  • Patent number: 8853295
    Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: October 7, 2014
    Assignee: ALLNEX IP S.a.r.L.
    Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
  • Publication number: 20140249242
    Abstract: The present invention relates to a novel type of grafting or crosslinking method for (meth)acrylates in which the reaction is initiated by isocyanates and specific bases having an imine structure. Using this novel and specifically applicable method, polymers, particularly polyolefins having double bonds, may be grafted or crosslinked in a suitable reaction procedure. Furthermore, these unsaturated polymers may be used, following reaction with (poly)isocyanates, to prepare graft or block copolymers or also for the bonding of the modified unsaturated polyolefins to polyamides, polyesters, polycarbonates, polyimines or polyurethanes.
    Type: Application
    Filed: August 24, 2012
    Publication date: September 4, 2014
    Applicant: Evonik Degussa GmbH
    Inventors: Friedrich Georg Schmidt, Stefan Spange, Ingmar Polenz
  • Patent number: 8822600
    Abstract: The present invention provides a method for producing a terminal acrylic-modified polybutadiene or terminal acrylic-modified hydrogenated polybutadiene that does not become white and turbid, without using an organotin compound. The production method of the present invention comprises reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organobismuth compound and a tetraalkoxyzirconium compound.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: September 2, 2014
    Assignee: Nippon Soda Co., Ltd.
    Inventor: Hiroki Hashimoto
  • Patent number: 8785556
    Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Durable, weatherable and scratch-resistant coatings are provided by compositions comprising a fluorinated component and an adhesion promoter compound. The adhesion promoter compound can include an alkoxy group, a furfuryl-containing ring structure, and a reactive group.
    Type: Grant
    Filed: April 30, 2012
    Date of Patent: July 22, 2014
    Assignee: Cytonix, LLC
    Inventor: James F. Brown
  • Patent number: 8772409
    Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polyalkenamer/functionalized organic modifier composition as a majority ingredient.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: July 8, 2014
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 8742059
    Abstract: A polymer precursor including a part which sequences an unsaturated bond having a ? electron orbit and a single bond alternately is disclosed. The polymer precursor has a first functional group and a second functional group which form a repeating unit constituting a polymer skeleton of an end product by an intramolecular reaction. At least a part of a conjugated state formed by the ? electron orbit in the molecule is disconnected or weakened due to a three-dimensional structure of the molecule and a transmittance with respect to an electromagnetic wave of at least one wavelength selected from the group consisting of 436 nm, 405 nm, 365 nm, 248 nm and 193 nm is improved.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: June 3, 2014
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventor: Katsuya Sakayori
  • Patent number: 8742022
    Abstract: Presently described are coating compositions comprising a polymerizable resin composition and a non-ionic unpolymerizable surfactant. In some embodiments, the coating comprises greater than 10 wt-% of non-ionic unpolymerizable surfactant. In other embodiments, the coating composition comprises an an additive comprising a silicone group or a fluorinated group and a hydrophobic group. Also described are articles comprising the cured coating compositions. In one embodiment, an article is described comprising a cured coating wherein the cured coating exhibits a property of an initially visible simulated fingerprint reducing in visibility in 1-20 minutes. Also described is a method of determining the fingerprint visibility of a coating composition and a polyacylate composition useful as an additive. In another embodiment a coated surface is described comprising a polymeric organic material comprising a plurality of pores wherein a portion of the pores are interconnected and comprise a lipophilic liquid.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: June 3, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Richard J. Pokorny, Thomas P. Klun, Christopher B. Walker, Jr., David B. Olson, Joan M. Noyola, Michelle L. Toy, Evan L. Schwartz
  • Patent number: 8735464
    Abstract: A radically curable polyurethane composite for dental restorations, including provisional restorations, includes polyurethane dimethacrylate prepolymers that have at least one flexible unit within a polyurethane dimethacrylate backbone, and one or more dimethacrylate monomers. Composite materials made with polyurethane dimethacrylate prepolymers of the invention exhibit superior and optimal properties of flexural strength and deflection-at-break relative to conventional dental resin composites. Composite materials of the invention also provide improved melt-resistance in response to the heat of grinding or finishing, thereby improving the fit of restorations made from the composite and preserving the finishing instruments. Methods of treating a tooth using the radically curable polyurethane composite and methods of making the polyurethane dimethacrylate prepolymers with flexible units is also provided. A kit including the radically curable polyurethane composite is also described.
    Type: Grant
    Filed: October 19, 2012
    Date of Patent: May 27, 2014
    Assignee: Pulpdent Corporation
    Inventors: Sunny Skaria, Kenneth Berk
  • Publication number: 20130186292
    Abstract: Disclosed is a resin composition for a flexographic printing plate, comprising (Component A) a binder resin and (Component B) a compound represented by Formula (1) and/or Formula (2), Component B being contained at 1 to 50 parts by mass relative to 100 parts by mass of Component A, wherein in Formulae (1) and (2) R1 and R4 independently denote a hydrogen atom or a methyl group, R2 and R5 independently denote a divalent organic group having 1 to 20 carbons, and R3 and R6 independently denote a monovalent organic group having 1 to 20 carbons, R3 and R6 not comprising an ethylenically unsaturated group, a dialkoxysilyl group, or a trialkoxysilyl group.
    Type: Application
    Filed: January 16, 2013
    Publication date: July 25, 2013
    Applicant: FUJIFILM CORPORATION
    Inventor: Fujifilm Corporation
  • Publication number: 20130165586
    Abstract: The present invention provides a method for producing a terminal acrylic-modified polybutadiene or terminal acrylic-modified hydrogenated polybutadiene that does not become white and turbid, without using an organotin compound. The production method of the present invention comprises reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organobismuth compound and a tetraalkoxyzirconium compound.
    Type: Application
    Filed: September 20, 2011
    Publication date: June 27, 2013
    Applicant: NIPPON SODA CO., LTD.
    Inventor: Hiroki Hashimoto
  • Patent number: 8450419
    Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.
    Type: Grant
    Filed: August 24, 2010
    Date of Patent: May 28, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8415425
    Abstract: Provided is a method for protecting the surface of a member to be processed, which comprises providing a protective film made of a photocurable resin composition for surface protection on the surface of the member to be processed, processing the member to be processed, and removing the protective film from the member to be processed, wherein the photocurable resin composition comprises (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton and (D) a photopolymerization initiator, which comprises from 1 to 50 parts by weight of (A), from 5 to 95 by mass of (B) and from 0.1 to 50 parts by mass of (C).
    Type: Grant
    Filed: March 30, 2012
    Date of Patent: April 9, 2013
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tomoyuki Kanai, Kazuhiro Oshima
  • Publication number: 20130041067
    Abstract: A radically curable polyurethane composite for dental restorations, including provisional restorations, includes polyurethane dimethacrylate prepolymers that have at least one flexible unit within a polyurethane dimethacrylate backbone, and one or more dimethacrylate monomers. Composite materials made with polyurethane dimethacrylate prepolymers of the invention exhibit superior and optimal properties of flexural strength and deflection-at-break relative to conventional dental resin composites. Composite materials of the invention also provide improved melt-resistance in response to the heat of grinding or finishing, thereby improving the fit of restorations made from the composite and preserving the finishing instruments. Methods of treating a tooth using the radically curable polyurethane composite and methods of making the polyurethane dimethacrylate prepolymers with flexible units is also provided. A kit including the radically curable polyurethane composite is also described.
    Type: Application
    Filed: October 19, 2012
    Publication date: February 14, 2013
    Applicant: PULPDENT CORPORATION
    Inventor: Pulpdent Corporation
  • Patent number: 8372914
    Abstract: Urethane modified water-reducible alkyd resins ABCD, comprising moieties derived from polyhydric alcohols A, modified fatty acids B made h? grafting olefinically unsaturated carboxylic acids B2 onto fatty acids B1, ungrafted fatty acids C and polyfunctional isocyanates D, a process for their production, and a method of use thereof in coating binders
    Type: Grant
    Filed: February 20, 2006
    Date of Patent: February 12, 2013
    Assignee: Cytec Surface Specialties Austria GmbH
    Inventors: Gerhard Reidlinger, Edmund Urbano, Ewald Zrin, Manfred Gogg, Johannes Scherz
  • Patent number: 8362149
    Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: January 29, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
  • Patent number: 8349951
    Abstract: Polymers are disclosed that include a structure having the formula wherein, R1 is independently selected from a C2-10 n-alkylene group, a C2-6 branched alkylene group, a C6-8 cycloalkylene group, a C6-10 alkylcycloalkylene group, —[(—CH2—)p—X—]q—(—CH2—)r—, or —[(—CH2—)p—X—]q—(—CH2—)r—, wherein at least one —CH2— unit is substituted with a methyl group, wherein p is an integer having a value ranging from 2 to 6, q is an integer having a value ranging from 1 to 5, r is an integer having a value ranging from 2 to 10, and X is selected from O, S, and —NR—, wherein R is hydrogen or methyl; R2 denotes a structure derived from allyl (meth)acrylate or a multi-functional (meth)acrylate; R3 is independently selected from hydrogen and an alkyl group; n is an integer having a value ranging from 1 to 60; and m is a rational number having a value ranging from 0 to 10.
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: January 8, 2013
    Assignee: PRC DeSoto International, Inc.
    Inventors: Suresh Sawant, Chandra Bhushan Rao, Jak H. Aklian
  • Patent number: 8338526
    Abstract: To provide an environmentally-friendly curable resin composition for surface protection, having a high adhesive strength and being capable of forming a protective film which will readily be removed in the film form without adhesive residue in water on a member to be processed, a photocurable adhesive using it, a method for temporarily fixing a member, and a method for removing a protective film. A curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, and (C) a resin having a cyclopentadiene skeleton. Further, a curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton, and (D) a photopolymerization initiator.
    Type: Grant
    Filed: July 12, 2011
    Date of Patent: December 25, 2012
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tomoyuki Kanai, Kazuhiro Oshima
  • Patent number: 8288476
    Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: October 16, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Publication number: 20120095168
    Abstract: A method for controlling the physical state of an ultra-high molecular weight polymer to make the ultra-high molecular weight polymer suitable for further processing, and related polymers compositions methods and systems, wherein the method comprises combining a catalyst, monomers, and an additive, for a time and under condition to allow synthesis of a nascent polymer and co-crystallization of the nascent polymer with the additive.
    Type: Application
    Filed: October 18, 2011
    Publication date: April 19, 2012
    Inventors: Julia A. KORNFIELD, Artemis AILIANOU, Sara RONCA, Sanjay RASTOGI, Giuseppe FORTE
  • Patent number: 8106125
    Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: January 31, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
  • Publication number: 20110316661
    Abstract: It is an objective of the present invention to provide a highly adhesive unsaturated polyester resin composition for fixing or immobilizing coils. There is provided an unsaturated polyester resin composition for adhesion of a coil, which includes the ingredients of: A) an unsaturated polyester resin and/or a vinyl ester resin; B) a monomer including a vinyl group as a polymerizable substituent at at least one end thereof; C) an isocyanate; and D) a polymerization initiator.
    Type: Application
    Filed: June 23, 2011
    Publication date: December 29, 2011
    Inventors: Takahito MURAKI, Satoru Amou, Tomio Iwasaki
  • Publication number: 20110269868
    Abstract: To provide an environmentally-friendly curable resin composition for surface protection, having a high adhesive strength and being capable of forming a protective film which will readily be removed in the film form without adhesive residue in water on a member to be processed, a photocurable adhesive using it, a method for temporarily fixing a member, and a method for removing a protective film. A curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, and (C) a resin having a cyclopentadiene skeleton. Further, a curable resin composition for surface protection, comprising (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton, and (D) a photopolymerization initiator.
    Type: Application
    Filed: July 12, 2011
    Publication date: November 3, 2011
    Applicant: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tomoyuki KANAI, Kazuhiro Oshima
  • Publication number: 20110262675
    Abstract: The present invention provides a photo-curable transfer sheet by which an optical information recording medium having small thickness and high capacity can be advantageously prepared, the photo-curable transfer layer of the sheet cured in the production of the optical information recording medium having excellent adhesion to the reflective layer such silver alloy and easy peeling property from the stamper to easily bring about the transfer layer having an uneven surface such as pits, etc accurately formed along an uneven surface of the stamper. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer and a reactive diluent having a photopolymerizable functional group, and the reactive diluent has at least one hydroxyl group and an acryloyl group and/or methacryloyl group, the total of acryloyl group and/or methacryloyl group being at least two.
    Type: Application
    Filed: August 31, 2006
    Publication date: October 27, 2011
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Takato Inamiya, Hideki Kitano, Hidefumi Kotsubo, Kenji Murayama
  • Publication number: 20110043737
    Abstract: The invention relates to an acrylic adhesive composition, more particularly, to an adhesive composition which: specifies the contents of a (meth)acrylic ester-based monomer and an aromatic group-containing monomer of an acrylic copolymer as a composition having little or no difference of birefringence; has excellent durability; and can reduce light leakage due to flexure by mixing a crosslinkable functional group-containing acrylic copolymer (A) and an acrylic copolymer (B) which does not contain the crosslinkable functional group, in a ratio of 1:9 to 5:5.
    Type: Application
    Filed: January 12, 2009
    Publication date: February 24, 2011
    Applicant: LG CHEM, LTD.
    Inventors: Se Ra Kim, Kee Young Kim, Sung Soo Yoon, Min Ki Lee, No Ma Kim, In Cheon Han
  • Patent number: 7803874
    Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.
    Type: Grant
    Filed: July 18, 2006
    Date of Patent: September 28, 2010
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Publication number: 20100105827
    Abstract: A method for producing a modified conjugated diene polymer includes a step (A) carrying out a primary modification reaction that reacts a heterocumulene compound having two or more specific functional groups with a conjugated diene polymer having a vinyl content of below 10% and a cis-1,4-bond content of 75% or more and possessing an active end to obtain a primary-modified conjugated diene polymer, and a step (B) carrying out a secondary modification reaction that reacts an active hydrogen-containing compound that includes one or more functional groups selected from the group consisting of an amino group, an imino group, a mercapto group, and a hydroxyl group with the primary-modified conjugated diene polymer to obtain a secondary-modified conjugated diene polymer. The method can produce a modified conjugated diene polymer that exhibits low heat build-up (low fuel consumption) and excellent wear resistance.
    Type: Application
    Filed: December 27, 2007
    Publication date: April 29, 2010
    Applicant: JSR CORPORATION
    Inventors: Ryouji Tanaka, Kouichirou Tani, Takuo Sone, Toshihiro Tadaki
  • Patent number: 7700689
    Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: April 20, 2010
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 7700662
    Abstract: The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: April 20, 2010
    Assignee: Bayer MaterialScience AG
    Inventors: Michael Ludewig, Jan Weikard, Nicolas Stoeckel, Wolfgang Fischer
  • Publication number: 20100093924
    Abstract: The invention relates to a synthetic resin, based on partly cross-linked poly(meth)acrylate-urethane-(meth)acrylates in urethane(meth)acrylates, obtainable by: (a) provision of (meth)acrylate monomers (I), which have no groups reactive to isocyanate groups and (meth)acrylate monomers (II), with (a) group(s) reactive to isocyanate groups, (b) polymerization of the (meth)acrylate monomers (I) and (II) to give a poly(meth)acrylate (III), with groups reactive to isocyanate groups, (c) reaction of the poly(meth)acrylate (III) with an isocyanate compound (IV), with more than one isocyanate group, in such a manner that 5 to 40% of the isocyanate groups of the isocyanate compound (IV) react with the above groups reactive to isocyanate groups, whereby partial cross-linking of (III) with an increase in weight average molecular weight by a factor of 2 to 20 occurs, in which one given (IV) reacts with more than one of the isocyanate groups thereof with more than one given (III) and (d) reaction of the compound obtained i
    Type: Application
    Filed: January 11, 2006
    Publication date: April 15, 2010
    Inventors: Andreas Lerschmacher, Siegfried Krause, Peter Kuhlmann, Klaus Hock
  • Publication number: 20100055068
    Abstract: The invention features grafted polymer systems for use in medical devices and/or for the delivery of active agents. The grafted polymers include at least one transport moiety, a linear backbone segment, and a pendant segment.
    Type: Application
    Filed: April 13, 2007
    Publication date: March 4, 2010
    Applicant: INTERFACE BIOLOGICS INCORPORATED
    Inventors: Paul J. Santerre, Roseita Esfand, Meilin Yang
  • Publication number: 20100036056
    Abstract: The present invention relates to the radical cold curing of synthetic resins based on poly(meth)acrylate-urethane(meth)acrylates in urethane(meth)acrylates and optionally (meth)acrylates and/or reactive diluents using suitable additives, and also the use of these radically cold-curable synthetic resins as binding agents in radically cold-curable mixtures, as well as the organic synthetic glasses/plastics, synthetic glass/plastic workpieces and composite materials and workpieces obtained from these mixtures by radical cold curing, and also the production and use of these same mixtures, organic synthetic glasses/plastics, synthetic glass/plastic workpieces and composite materials and workpieces.
    Type: Application
    Filed: October 5, 2007
    Publication date: February 11, 2010
    Applicant: ASHLAND-SÜDCHEMIE KERNFEST GMBH
    Inventors: Peter Kuhlmann, Andreas Lehrschmacher, Klaus Houck
  • Publication number: 20090324961
    Abstract: UV curable urethane(meth)acrylate polymers of Formula (1), where: R1 and R? are each independently hydrogen or C1-20hydrocarbo, R2, R?2, R3 and R4 are each independently optionally substituted divalent organo group, and p is an integer from about 6 to about 100 which are useful as laminating and/or pressure sensitive adhesives are disclosed as is methods of making them. The oligomers/polymers comprise a urethane extended backbone formed by reacting diisocyanates with polyols derived from rubber oligomers/polymers.
    Type: Application
    Filed: April 28, 2006
    Publication date: December 31, 2009
    Inventors: Victor Lu, Jeffrey Wang
  • Patent number: 7495057
    Abstract: The invention relates to resin compositions that contains as components: (A) a monomer with at least one ethylenic unsaturation and with an isocyanate reactive group, (B) an ethylenically unsaturated monomer that can react with component (A) by means of radical polymerization, (C) a polyisocyanate that can react with component (A) by means of a polyurethane reaction and that on average has at least 1.75 isocyanate groups, (D) a catalyst for the radical polymerization, and that also contains (E) a thermoplastic polymer with an average molecular weight of at least 10,000 Dalton. The invention also relates to a process for the preparation of moulded articles from such resin compositions, as well as the moulded articles themselves.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: February 24, 2009
    Assignee: DSM IP Assets B.V.
    Inventors: Adrianus J De Koning, Markus R Luesken, Peter Dijkink
  • Patent number: 7419703
    Abstract: The invention provides heat-curable thixotropic mixtures containing carbamate and/or allophanate groups, including at least one oligomer and/or polymer containing at least one of carbamate and allophanate groups, and at least one thixotropic agent that is a urea derivative preparable by reacting at least one amine and/or water with at least one isocyanate in the presence of at least one amino resin. The invention further provides processes for preparing the mixtures and coating materials, adhesives and sealing compounds prepared from the mixtures.
    Type: Grant
    Filed: August 26, 2005
    Date of Patent: September 2, 2008
    Assignee: BASF Coatings AG
    Inventors: Hubert Baumgart, Michael A Gessner, Bruce Oermann, Paul J Harris
  • Patent number: 7358306
    Abstract: Curable (per)fluoropolyether polyurethanes obtained by reaction in a first step of a) (per)fluoropolyether diols having a number average molecular weight from 2,000 to 5,000; with b) diisocyanates of formula OCN—R—NCO ??(VIA) wherein R is a hydrogenated and/or fluorinated radical; in a second step with the compound c) saturated or unsaturated aliphatic hydrogenated diols, (alkyl)cycloaliphatic, aromatic; oligomers or polymers of butadiene with a number average molecular weight from 500 to 4,000 having end hydroxyl groups; provided that: when the diisocyanate b) is used and the radical R in formula (VIA) is: —Ph—CH2—Ph—, the hydrogenated diols c) are optional; when the radical R has a meaning different from that above mentioned, at least one of the used hydrogenated diols c) is selected from those belonging to the c2)-c6) groups; the sum of the equivalents of the compounds a) and c) being equal to the equivalents of the compound b).
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: April 15, 2008
    Assignee: Ausimont S.p.A.
    Inventors: Stefano Turri, Sergio Novelli, Anna Staccione
  • Publication number: 20070282069
    Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.
    Type: Application
    Filed: May 31, 2006
    Publication date: December 6, 2007
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 7193000
    Abstract: A golf ball comprising a core and a cover is disclosed. At least a layer of the golf ball is made from an elastomer composition comprising a least one polydiene rubber and at least one moisture scavenger, such as p-toluene sulfonyl isocyanate. The moisture scavenger is generally present in the elastomer composition in an amount of 10 phr or less, and particularly from 0.1 to 5 phr, by weight of the elastomer.
    Type: Grant
    Filed: May 15, 2004
    Date of Patent: March 20, 2007
    Assignee: Acushnet Company
    Inventor: Joseph B. Mayer
  • Patent number: 7144955
    Abstract: Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: December 5, 2006
    Assignees: Bayer MaterialScience LLC, Bayer MaterialScience AG
    Inventors: Scott A. Grace, Michael J. Dvorchak, Richard R. Roesler, Dinesh Pethiyagoda, Michael K. Jeffries, Jan Weikard
  • Patent number: 7037972
    Abstract: A multicomponent system curable thermally and with actinic radiation (dual cure), comprising (A) at least one component comprising at least one constituent containing at least one isocyanate-reactive functional group and at least one functional group having at least one bond which can be activated with actinic radiation, and at least one vinylaromatic-allyl alcohol copolymer, and (B) at least one component comprising at least one polyisocyanate, and its use as a coating material, adhesive and sealing compound.
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: May 2, 2006
    Assignee: BASF Coatings AG
    Inventors: Egbert Nienhaus, Bernhard Lettmann
  • Patent number: 6906136
    Abstract: A UV-curable composition is disclosed. The composition comprises a crosslinking agent, a hydroxyalkyl acrylate or methacrylate, and an acrylic polyol. The crosslinking agent is selected from the group consisting of multifunctional isocyanates, melamines, and silanes. The acrylic polyol comprises recurring units of an allylic alcohol. The composition can be irradiated to be solidified and then fully cured by the urethane, melamine, or silane reactions. Alternatively, the composition can be cured by the urethane, melamine, or silane reactions, and then fully cured by radiation. The invention provides low VOC but high performance coatings. More importantly, the invention provides a UV-curable system without the need for acrylated oligomers.
    Type: Grant
    Filed: April 22, 2003
    Date of Patent: June 14, 2005
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Daniel B. Pourreau, Shanti P. Patel, L. Joseph Junker, Wei Wang, Stephen H. Harris, Shao-Hua Guo
  • Patent number: 6897258
    Abstract: An object of the present invention is to provide a practical compatibilizing agent which makes it possible to convert the resin mixture into a homogeneous resin mixture free from separation and to eliminate defects caused by separation on molding by prevention of the separation between the radical polymerizable unsaturated resin and low profile additive, which could have not been attained by the prior art.
    Type: Grant
    Filed: January 10, 2003
    Date of Patent: May 24, 2005
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Akira Takano, Takashi Yasumura