Contacting With A -n=c=x-containing Reactant Which Has Been Previously Reacted With An Organic Compound Containing A Hydroxyl, Amine, Or -c(=o)-o- Group Patents (Class 525/127)
Solid polymer from ethylenic reactants only derived from halogen-containing reactant (Class 525/129)
-
Patent number: 11389402Abstract: Methods and devices suitable for delivering a pharmaceutical drug to patient. Such a device includes a multiple-network pseudo-interpenetrating polymer network (pseudo-IPN) hydrogel containing the drug. The hydrogel comprises loosely cross-linked polymeric networks that interpenetrate and are grafted to each other.Type: GrantFiled: June 15, 2018Date of Patent: July 19, 2022Assignee: Purdue Research FoundationInventors: Siamak Shams Es-haghi, Gustavo A. Guzman Cardozo, Mukerrem Cakmak
-
Patent number: 10800932Abstract: The present invention relates to a composition comprising a) an aqueous dispersion of polymer particles and b) a hydrophobically modified poly(oxyalkylene-urethane) rheology modifier having a 1) backbone; and 2) a hydrophobic portion represented by Fragment I: where R and R1 are defined herein. The composition is useful as an aqueous coating formulation that exhibits a highly shear thinning rheology profile suitable for spray applications to provide high sag resistance without adverse impact on gloss or corrosion resistance.Type: GrantFiled: January 23, 2019Date of Patent: October 13, 2020Assignees: Rohm and Haas Company, Dow Global Technologies LLCInventors: John J. Rabasco, Duane R. Romer, Joey W. Storer, Antony K. Van Dyk, Wenqin Wang, Mark Langille, Jessica Levin
-
Patent number: 10543661Abstract: A metal foil with resin is a metal foil with resin including a metal foil and a resin layer disposed on the metal foil, resin layer being obtained by half-curing a resin composition. The resin composition contains a first component that is a polymer, a second component that is a polyarylene ether copolymer, and a third component that is an epoxy resin. The first component has structures represented by formulae (1) and (2) below, with no unsaturated bond between carbon atoms. The third component has two or more epoxy groups per molecule. The second component is compatible with the first component, and the third component is incompatible with the first component. In the formulae (1) and (2), a ratio between x and y is x:y=0:1 to 0.35:0.65, R1 represents hydrogen atom or methyl group, and R2 represents hydrogen atom or an alkyl group.Type: GrantFiled: September 2, 2016Date of Patent: January 28, 2020Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Akihiro Yamauchi, Yoshiaki Esaki, Takayoshi Ozeki, Hiroaki Umehara, Hiroharu Inoue, Yoshihiko Nakamura
-
Patent number: 10480128Abstract: A composite pavement structure comprises a wearing course layer and a base course layer disposed below the wearing course layer. The base course layer comprises aggregate and an elastomeric composition. The elastomeric composition comprises the reaction product of an isocyanate component and an isocyanate-reactive component. The isocyanate component comprises a polymeric isocyanate, and optionally, an isocyanate-prepolymer. The isocyanate-reactive component comprises a hydrophobic polyol and a chain extender having at least two hydroxyl groups and a molecular weight of from about 62 to about 220. The chain extender is present in the isocyanate-reactive component in an amount of from about 1 to about 20 parts by weight based on 100 parts by weight of the isocyanate-reactive component. The wearing course layer comprises aggregate which is the same or different than the aggregate of the base course layer. Methods of forming the composite pavement structure are also disclosed.Type: GrantFiled: December 21, 2010Date of Patent: November 19, 2019Assignee: BASF SEInventors: David K. Bower, Steven Hicks, Melissa Terry, Calvin T. Peeler, Ronald A. Galecki, Erol Tutumluer
-
Patent number: 9957661Abstract: Polymers are described having repeat units of Formula (I): wherein R3 is H or alkyl group; x and t are positive integers; Q is C(O)O, C(O)NH, or direct bond; D is alkylene, arylene, or (CH2CH2O)n(CH(CH3)CH2O)m; E is O, S, NR5, or direct bond; R5 is H or alkyl; G is the residue of a polyisocyanate; V is a urethane, urea, or thiourea that bonds to other parts of the polymer compound or to a monovalent blocking group; s is 1 to 5; Y is O or a substituted or unsubstituted arylene group; A is an alkylene group; w, v, and y are 0 or 1; X is the residue of a cyclic or acyclic sugar alcohol which is substituted with —R1, —C(O)R1, —(CH2CH2O)n(CH(CH3)CH2O)mR2, —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1, or mixtures thereof; n and m are independently 0 to 20; R1 is independently an alkyl group; and R2 is independently —H or alkyl group.Type: GrantFiled: June 8, 2017Date of Patent: May 1, 2018Assignee: THE CHEMOURS COMPANY FC, LLCInventors: John Christopher Sworen, Gerald Oronde Brown, Tatsiana Haidzinskaya, Ewa Kohler
-
Patent number: 9783623Abstract: The present invention relates to a polymerisable plasticiser formed by a hydrocarbon chain, one end of which bears more than one isocyanate function, said hydrocarbon chain comprising and/or being substituted by an aromatic ring and/or an aliphatic ring and/or said hydrocarbon chain is substituted by at least two hydrocarbon chains that can comprise an unsaturation, and the number of isocyanate functions being strictly greater than 1, preferably greater than 1.2, and, more preferably, grater than 1.5 but less than or equal to 2.2. The invention also relates to liquid polyurethane resin compositions and, in particular, stable, ready-to-use liquid polyurethane resin compositions comprising said plasticiser. The invention further relates to methods for replacing all or part of the exogenous plasticiser and/or solvent in a polyurethane resin by adding said polymerisable plasticiser.Type: GrantFiled: October 18, 2012Date of Patent: October 10, 2017Assignee: SopremaInventors: Louis Durot, Pierre-Etienne Bindschedler, Virginie Francois Barseghian, Remi Perrin
-
Patent number: 9585798Abstract: The present invention relates to improved water-absorbing storage layers for use in hygiene articles, the water-absorbing storage layers being essentially free of cellulose fibers.Type: GrantFiled: June 29, 2015Date of Patent: March 7, 2017Assignee: BASF SEInventor: Christophe Bauduin
-
Patent number: 9296957Abstract: A nondendrimeric hyperbranched polyester and/or polyesteramide which comprise alkenyl-substituted succinic acid units as demulsifiers for splitting oil-water emulsions, especially crude oil emulsions. In particular, the succinic acid is substituted with alkenyl groups containing 16 to 20 carbon atoms. Also, nondendrimeric hyperbranched polyesters or polyesteramides which comprise alkenyl-substituted succinic acid units, wherein the alkenyl group has from 16 to 20 carbon atoms. In addition to the alkenyl-substituted succinic acid units, the nondendrimeric hyperbranched polyester contains, as further units, at least trifunctional alcohols having been alkoxylated with an average of from 3 to 12 ethylene oxide units.Type: GrantFiled: October 2, 2008Date of Patent: March 29, 2016Assignee: BASF SEInventors: Bernd Bruchmann, Andreas Eichhorn, Marcus Guzmann, Wolfgang Gaschler
-
Publication number: 20150136319Abstract: A reactive hot melt adhesive comprising a blend of a (meth)acrylate polymer, a polyurethane polymer containing (meth)acrylate groups and a polyurethane prepolymer containing NCO-groups wherein the content of low molecular weight (meth)acrylate urethanes is less than 1 wt % of the adhesive. The adhesive provides a fast and improved green strength during application.Type: ApplicationFiled: January 26, 2015Publication date: May 21, 2015Inventors: Hans-Georg Kinzelmann, Yang Cao, Uwe Franken, Hongxia Zhao
-
Patent number: 9029475Abstract: The present disclosure is directed to a process for producing a low VOC (volatile organic content) coating composition. The present disclosure is particularly directed to a process for producing a low VOC (volatile organic content) coating composition by mixing a water based crosslinking component and an organic solvent based crosslinkable component. The present disclosure is further directed to a low VOC coating composition produced by the process.Type: GrantFiled: April 28, 2011Date of Patent: May 12, 2015Assignee: Axalta Coating Systems IP Co., LLCInventors: Ayumu Yokoyama, Jennifer Majlak, Ross Sydney Morgan
-
Patent number: 9006350Abstract: A selfbonding enamel containing resins which are capable of crosslinking with one another, comprising (A) 5 to 95 wt % of at least one resin with nucleophilic groups selected from the group consisting of OH, NHR, SH, C(O)NHR, carboxylate, CH-acidic groups and Carbanions, (B) 0 to 70 wt % of at least one amide group-containing resin and (C) 0 to 30 wt % of at least one polyurethane resin, (D) 0 to 30 wt % of at least one epoxy resin, (E) 5 to 95 wt % of at least one organic solvent, wherein the resins of either component (A) and/or, if component (B) is contained in the composition, component (B) contain ?-carboxy-?-oxocycloalkyl carboxylic acid amide groups the coatings of the selfbonding enamel have excellent adhesion to electrically conductive wires high sticking properties and high re-softening temperatures.Type: GrantFiled: December 13, 2007Date of Patent: April 14, 2015Assignee: Axalta Coating Systems IP Co., LLCInventors: Frank-Rainer Boehm, Michael Herm
-
Patent number: 8987374Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilizing side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.Type: GrantFiled: May 3, 2010Date of Patent: March 24, 2015Assignee: The Lubrizol CorporationInventors: Stuart Nicholas Richards, Andrew James Shooter
-
Patent number: 8981005Abstract: Disclosed are coating compositions comprising polycarbodiimides having onium salt groups, as well as relating methods and coated substrates.Type: GrantFiled: February 12, 2009Date of Patent: March 17, 2015Assignee: PPG Industries Ohio, Inc.Inventors: Anthony M. Chasser, Lawrence J. Fitzgerald, Venkateshwarlu Kalsani
-
Publication number: 20150059604Abstract: A resin composition for laser engraving that comprises (Component A) a resin that is a plastomer at 20° C., (Component B) a polymerizable compound, and (Component C) a polymerization initiator, wherein Component A has a constitutional repeating unit having an acid group, and the content of the constitutional repeating unit having an acid group is 0.01 to 15 mass % relative to a total mass of Component A. A flexographic printing plate precursor that has a relief-forming layer formed of the resin composition for laser engraving on a support, and a flexographic printing plate precursor that has a crosslinked relief-forming layer obtained by crosslinking a relief-forming layer formed of the resin composition for laser engraving by heat and/or light.Type: ApplicationFiled: August 13, 2014Publication date: March 5, 2015Applicant: FUJIFILM CORPORATIONInventor: Kazuhiro HAMADA
-
Patent number: 8962771Abstract: Elastomer composites are prepared by wetting particles of a natural or synthetic rubber with a liquid one-component moisture-curable resin composition and then exposing the wetted particles to moisture to cure the resin composition. The moisture-curable resin composition comprises (a) an isocyanate-terminated polyurethane prepolymer having an isocyanate content of from 0.5 to 12% by weight and (b) from 1 to 30%, based on the combined weight of components (a) and (b), of an epoxide or lactone compound having a molecular weight of from about 70 to about 1000 and which is miscible in the prepolymer at the relative proportions thereof that are present. In addition, the composition contains no more than 0.1% by weight of compounds having a primary or secondary amino group.Type: GrantFiled: May 26, 2011Date of Patent: February 24, 2015Assignee: Dow Global Technologies LLCInventors: Blndu Radhakrishnan, William Aaron Koonce
-
Patent number: 8957156Abstract: An optical adhesive film prepared from an optical adhesive composition, an optical adhesive composition, and a display panel, the optical adhesive film having an elongation of about 200 to about 800% and a tensile strength of about 10 gf/mm2 or less, and the optical adhesive composition including a urethane (meth)acrylate copolymer, a reactive monomer, and an initiator.Type: GrantFiled: December 27, 2011Date of Patent: February 17, 2015Assignee: Cheil Industries, Inc.Inventors: Lee June Kim, Ji Hye Kwon, Kyoung Jin Ha, Kil sung Lee
-
Patent number: 8946313Abstract: This invention relates to hybrid polymer polyols. These hybrid polymer polyols comprise the free-radical polymerization product of (A) a base polyol comprising (1) a polymer modified polyol selected from (a) dispersions of polyureas and/or polyhydrazodicarbonamides in a hydroxyl group containing compound and (b) polyisocyanate polyaddition polyols, and (2) optionally, a polyol having a functionality of 2 to 6 and an OH number of from 20 to 500; (B) optionally, a preformed stabilizer; and (C) one or more ethylenically unsaturated monomers, in the presence of (D) a free-radical polymerization initiator, and (E) optionally, a polymer control agent. The present invention also relates to a process for the preparation of these hybrid polymer polyols, foams prepared from these hybrid polymer polyols and to a process for the preparation of these foams.Type: GrantFiled: December 16, 2011Date of Patent: February 3, 2015Assignee: Bayer MaterialScience LLCInventors: Rick L. Adkins, Brian L. Neal
-
Patent number: 8927653Abstract: Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.Type: GrantFiled: December 12, 2008Date of Patent: January 6, 2015Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Shawn Ricci, Michael J. Sullivan, Kevin M. Harris, Pamela V. Arnold
-
Patent number: 8927001Abstract: Absorbable, essentially non-absorbable, and non-absorbable crystalline, amphiphilic, block/graft copolymeric compositions exhibit an inherent viscosity of at least 0.5 dL/g, a heat of fusion of at least 10 J/g and undergo swelling in the biological environment due to a water up-take of at least 10 percent of original dry mass. These compositions are designed for use in swellable surgical sutures, coatings of medical devices, and carriers for the delivery of bioactive agents.Type: GrantFiled: June 14, 2006Date of Patent: January 6, 2015Assignee: Poly-Med, Inc.Inventors: Shalaby W. Shalaby, James M. Lindsey
-
Publication number: 20140371362Abstract: Disclosed herein are self-healing materials, which are smart materials that are capable of repairing themselves without any external intervention when they are damaged. The self-healing materials may be microencapsulated, for example in a one-capsule system or a two-capsule system, and damage to a matrix containing the microcapsules may rupture the microcapsules and cause the healing materials to be released into the site of damage, where it may polymerize and restore the functional capabilities of the matrix. The self-healing materials may be based on unsaturated multi-functional resins capable of oxygen-initiated cross-linking, and may include alkyd resins, such as alkyd resins that include one or more telechelic end groups.Type: ApplicationFiled: June 12, 2014Publication date: December 18, 2014Inventor: Gerald O. Wilson
-
Patent number: 8895674Abstract: A method disclosed for making a side-chain dendrimer vesicle. The method includes the steps of: At first, there is provided a random copolymer with a narrow distribution of molecular weights by active polymerization and chemical modification. Then, chemical modification is executed to graft various generations of dendrimers to the random copolymer to provide a side-chain dendritic random copolymer with various generations. Two steps of emulsification are taken to induce macromolecular self-assembling of the side-chain dendritic random copolymer solution to form the macromolecular vesicle. The side-chain dendrimer includes C10˜C18 hydrophobic alkyl chains.Type: GrantFiled: January 23, 2014Date of Patent: November 25, 2014Assignee: Chung-Shan Institute of Science and Technology, Armaments, Bureau, Ministry of National DefenseInventors: Wen-Chiung Su, Wei-Ho Ting, Mao-Syong Lin, Chia-Cheng Chang, Hsin-Cheng Chiu, Sheng-hong Dai, Ru-Jong Jeng
-
Publication number: 20140338550Abstract: To provide a resin composition for a laser-engravable flexographic printing plate that has excellent removability for engraving residue generated when laser-engraving a printing plate precursor and that can give a flexographic printing plate that is excellent in terms of non-tackiness, hardness, printing durability, and halftone shape. A resin composition for a laser-engravable flexographic printing plate, the resin composition that comprises (Component A) a polyurethane resin having a group represented by Formula (1), (Component B) an ethylenically unsaturated compound, and (Component C) a polymerization initiator wherein in the Formula, R and R? independently denote a hydrogen atom or an alkyl group, R? denotes an alkyl group, R and R? may be linked to form a ring, and the wavy line portion denotes the position of bonding.Type: ApplicationFiled: July 30, 2014Publication date: November 20, 2014Applicant: FUJIFILM CorporationInventor: Hiroshi SATO
-
Patent number: 8883871Abstract: This invention relates to chemical polymer compositions, methods of synthesis, and fabrication methods for devices regarding polymers capable of displaying shape memory behavior (SMPs) and which can first be polymerized to a linear or branched polymeric structure, having thermoplastic properties, subsequently processed into a device through processes typical of polymer melts, solutions, and dispersions and then crossed linked to a shape memory thermoset polymer retaining the processed shape.Type: GrantFiled: May 2, 2011Date of Patent: November 11, 2014Assignee: Lawrence Livermore National Security, LLC.Inventors: Thomas S. Wilson, Michael Keith Hearon, Jane P. Bearinger
-
Publication number: 20140329097Abstract: An adhesive composition that includes: one or more polyester polyether copolymers of formula I: wherein Nu is a predominately cyclic nucleus and R1 is randomly selected from either a C2-6 alkylene or an amorphous, long-chain polyether subunit including a polyoxyalkylene group; one or more polyisocyanate prepolymers that includes the reaction product of: one or more polyols; and a polyfunctional isocyanate having a functionality of more than about 2; polymeric MDI; and a first aromatic or aromatic-aliphatic polymer tackifying resin having a softening point of equal to or greater than about 100° C.Type: ApplicationFiled: July 21, 2014Publication date: November 6, 2014Inventors: Marietta B. Helmeke, Jeffery G. Schmierer, Theresa Unze-Schmierer
-
Patent number: 8877875Abstract: The object of the present invention is to provide a golf ball that satisfies both of the flight distance at the shot with a driver, a long iron, and a middle iron and the controllability at the approach shot with a short iron and is also excellent in the abrasion resistance of the cover.Type: GrantFiled: November 7, 2008Date of Patent: November 4, 2014Assignee: SRI Sports LimitedInventors: Kazuya Kamino, Keiji Ohama, Toshiyuki Tarao
-
Patent number: 8853295Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.Type: GrantFiled: February 12, 2010Date of Patent: October 7, 2014Assignee: ALLNEX IP S.a.r.L.Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
-
Publication number: 20140272425Abstract: A moisture-curable hot melt adhesive which is excellent in light resistance and durability against high temperature and high humidity. The moisture-curable hot melt adhesive includes a urethane prepolymer having an isocyanate group at the end and an acrylic based polymer, wherein the urethane prepolymer contains chemical structures derived from a polycarbonate polyol and a non-crystalline polyesterpolyol. The moisture-curable hot melt adhesive can be used to produce an automobile interior material since no deterioration occurs even under sunlight, or under severe high temperature and high humidity conditions in the summer season.Type: ApplicationFiled: June 2, 2014Publication date: September 18, 2014Inventor: Tsuyoshi Tamogami
-
Patent number: 8834670Abstract: An optical adhesive composition includes a urethane (meth)acrylate resin having at least one hydroxyl group and at least one vinyl group, the urethane (meth)acrylate resin having a curing contraction ratio expressed by Equation 1 of about 0 to about 3%; and an adhesion of about 30 to about 80 kgf: Curing contraction ratio (%)=(A?B)/A×100,??[Equation 1] where A is a specific gravity of the optical adhesive composition before curing, and B is a specific gravity of the solid optical adhesive composition after curing.Type: GrantFiled: October 14, 2011Date of Patent: September 16, 2014Assignee: Cheil Industries, Inc.Inventors: Kyoung Jin Ha, Ji Hye Kwon, Kil Sung Lee, Irina Nam, Lee June Kim
-
Publication number: 20140256855Abstract: The present invention provides: a carbon fiber sizing agent that can obtain a carbon fiber bundle having a superior effect of improving mechanical properties when composited using a resin; an aqueous dispersion thereof; a carbon fiber bundle; a sheet-shaped article having a carbon fiber bundle; and a composite material. The carbon fiber sizing agent contains: a compound (A) that is an ester of an unsaturated monobasic acid and an epoxy compound having a plurality of epoxy groups in the molecule, and that has at least one epoxy group in the molecule; a urethane acrylate oligomer (B) that is bifunctional and that has a tensile elongation rate of the cured product of at least 40%; and a polyurethane resin (C) having a tensile elongation rate of a dried coating film of 350-900% inclusive. The amounts of A-C contained satisfy the conditions described in the description. The aqueous dispersion disperses the sizing agent. The carbon fiber bundle contains 0.6-3.0 mass % inclusive of the sizing agent.Type: ApplicationFiled: August 21, 2012Publication date: September 11, 2014Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Kouki Wakabayashi, Naoki Sugiura, Masahiro Hata, Shigekazu Takeda, Keigo Yoshida, Shuuichi Nakamura
-
Publication number: 20140255560Abstract: A two-part, solvent-free laminating adhesive including a Part A that is a liquid mixture of a first polyol and a hydroxyl functional acrylic polymer having a molecular weight of no greater than 15,000 g/mole, and a Part B that is an isocyanate-terminated polyurethane prepolyiner. The adhesive is especially suited for making flexible laminates for use in food packaging. When adhered two polymeric film materials and in cured form, the adhesive provides substantially no contribution to the oxygen barrier properties of the laminate.Type: ApplicationFiled: March 6, 2013Publication date: September 11, 2014Applicant: H.B. FULLER COMPANYInventors: WAYNE G. EKLUND, Stephen G. Rippe
-
Patent number: 8735495Abstract: A two-component urethane system. The first component is a hydroxy-terminated polyester polyol containing polymerized residues of phthalic acid and an aliphatic diol having Mn from 60 to 150, and having no more than 15 wt % polymerized residues of aliphatic acids. The second component is an isocyanate-terminated prepolymer containing polymerized residues of diphenyl methane diisocyanate and/or toluene diisocyanate and a glycol or polyol having Mn from 90 to 1000.Type: GrantFiled: July 12, 2012Date of Patent: May 27, 2014Assignee: Rohm and Haas CompanyInventors: Larry F. Brinkman, David E. Vietti, Joseph James Zupancic
-
Patent number: 8716402Abstract: A barrier coating comprising a polyurethane dispersion and an elastomeric material is disclosed. The polyurethane comprises at least 30 weight percent of meta-substituted aromatic material. Methods for improving barrier using the coatings are also disclosed.Type: GrantFiled: March 22, 2010Date of Patent: May 6, 2014Inventors: Rodger G. Temple, Brian E. Woodworth, Diep Nguyen, Michelle S. Miles, Walter F. Kasper, Dennis L. Faler
-
Patent number: 8680205Abstract: A method for improving flow of a two-component urethane system by adding a hydroxy-functional acrylic polymer.Type: GrantFiled: July 12, 2012Date of Patent: March 25, 2014Assignee: Rohm and Haas CompanyInventors: Larry F. Brinkman, Mai Chen, David E. Vietti, Melinda L. Einsla, Joseph James Zupancic
-
Patent number: 8680204Abstract: The present invention relates to golf balls comprising a crosslinked ionomer composition formed by the reaction of either one or more ionomers, or an ionomer precursor composition, with one or more crosslinking agents including polyisocyanates, blocked polyisocyanates, polyurethane prepolymers, blocked polyurethane prepolymers, polyurea prepolymers, blocked polyurea prepolymers, polyamines, blocked polyamines and dicyanodiamides. The resulting modified ionomer compositions exhibit increased tensile strength and a decrease in tensile elongation as compared to the uncrosslinked ionomer analogs while maintaining Shore D hardness.Type: GrantFiled: December 21, 2010Date of Patent: March 25, 2014Inventors: Hyun J. Kim, Hong G. Jeon
-
Publication number: 20140039417Abstract: A composite material includes nitrile group-containing copolymer rubber; polyester-based thermoplastic polyurethane; and polyalkylene oxide containing metal salt, in which the metal salt is alkali metal salt or alkaline earth metal salt, and an amount of the metal salt in the polyalkylene oxide containing metal salt is 0.5 parts by mass to 3.0 parts by mass with respect to 100 parts by mass of the total amount of the nitrile group-containing copolymer rubber and the polyester-based thermoplastic polyurethane.Type: ApplicationFiled: October 10, 2013Publication date: February 6, 2014Applicant: Olympus CorporationInventors: Naoyuki Osako, Takeshi Kida, Kohei Oguni
-
Patent number: 8609768Abstract: A hot melt adhesive composition employing a thermoplastic polyurethane, which has a high adhesive strength even under bonding conditions of low temperature and short time or even to nylon cloth, and which has a favorable adhesive strength in a wide temperature range of from room temperature to low temperature. A hot melt adhesive composition comprising a thermoplastic polyurethane (A) having a flow initiation temperature of from 80 to 150° C. and a phenolic hydroxy group-containing compound (B) having phenolic hydroxy groups and having a molecular weight of at least 1,000.Type: GrantFiled: January 24, 2012Date of Patent: December 17, 2013Assignee: Asahi Glass Company, LimitedInventors: Makito Nakamura, Genichirou Enna
-
Publication number: 20130330550Abstract: A coating liquid for forming an anchor layer interposed between an optical film and a pressure-sensitive adhesive layer, comprising a polythiophene based polymer, a polyoxyalkylene-group-containing polymer, and a mixed solvent comprising 65 to 100% by weight of water and 0 to 35% by weight of an alcohol.Type: ApplicationFiled: June 5, 2013Publication date: December 12, 2013Inventors: Yuusuke Toyama, Tomoyuki Kimura, Masakuni Fujita
-
Patent number: 8575280Abstract: Disclosed is a thermosetting resin composition including; (A) a carboxyl group-containing polyurethane prepared by using (a) a polyisocyanate compound (b) polyol compounds (c) a carboxyl group-containing dihydroxy compound as raw materials, (B) a curing agent, wherein the polyol compounds (b) are one or more kinds of polyol compound(s) selected from Group (I) and one or more kinds of polyol compound(s) selected from Group (II); Group I: polycarbonate polyol, polyether polyol, polyester polyol, and polylactone polyol, Group II: polybutadiene polyol, polysilicone having terminal hydroxyl groups, and such a polyol that has 18 to 72 carbon atoms and oxygen atoms present only in hydroxyl groups. The thermosetting resin composition can give a protection film for flexible printed circuits that has excellent long-term reliability of electric insulation, flexibility, and low warpage from curing shrinkage, and particularly low tackiness.Type: GrantFiled: December 7, 2006Date of Patent: November 5, 2013Assignee: Showa Denko K.K.Inventors: Hiroshi Uchida, Ritsuko Azuma
-
Publication number: 20130288034Abstract: The present invention relates to resorbable membranes for medical uses. The membranes according to the present invention are produced or producible from a composition comprising at least one polyol component, at least one polyisocyanate component and an additive selected from polyvinylpyrrolidone, polyvinylpolypyrrolidone, a copolymer of polyvinylpyrrolidone with vinylacetate, vinylimidazole or vinylcaprolactam or mixtures thereof. The present invention further relates to a kit comprising a multitude of membranes with different absorption rates.Type: ApplicationFiled: November 7, 2011Publication date: October 31, 2013Applicant: NOLAX AGInventors: Jessica Blume, Stephan Buser, Andreas Dobmann, Erika Zimmermann
-
Patent number: 8563654Abstract: An object of the present invention is to provide a golf ball comprising a core and a cover, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a urethane prepolymer (b-1) having at least two isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75, and the cover has a thickness of 2.5 mm or less.Type: GrantFiled: November 7, 2008Date of Patent: October 22, 2013Assignee: SRI Sports LimitedInventors: Tsutomu Hirau, Toshiyuki Tarao
-
Patent number: 8563636Abstract: The present invention provides an aqueous two-package type clear coating composition comprising: (A) an aqueous dispersion of a hydroxyl group- and acid group-containing acrylic resin having a hydroxyl value of 30 to 200 mg KOH/g, an acid value of 5 to 50 mg KOH/g, a weight average molecular weight of 3,000 to 30,000, and a glass transition temperature of ?30 to +40° C. obtained by radical polymerization of 10 to 50 mass % of a secondary hydroxyl group-containing monomer (a) and 50 to 90 mass % of at least one other unsaturated monomer (b); and (B) a polyisocyanate curing agent obtained by mixing (c) a polyisocyanate compound and (d) a compound containing an anionic functional group, a polyoxyethylene group, and a hydrocarbon group, and a process for forming a multilayer topcoat film using the same.Type: GrantFiled: October 23, 2007Date of Patent: October 22, 2013Assignee: Kansai Paint Co., Ltd.Inventors: Seiji Wada, Yuta Baba, Koki Chiga, Takashi Noguchi, Takato Adachi, Hiroyuki Onoyama, Hideo Sugai
-
Patent number: 8563639Abstract: An object of the present invention is to provide a golf ball which is excellent in the gloss and the evenness of the paint film and a golf ball aqueous paint therefor. The golf ball of the present invention has a paint film which is formed from a curing type polyurethane aqueous golf ball paint, comprising (A) an aqueous polyol composition and (B) an aqueous polyisocyanate, wherein (A) the aqueous polyol composition contains (a-1) an aqueous acrylic polyol, (a-2) an aqueous urethane polyol and (a-3) an aqueous polyurethane resin; a molar ratio (NCO/OH) of an isocyanate group of (B) the aqueous polyisocyanate to a hydroxyl group of (A) the aqueous polyol composition ranges from 1.25 to 2.50; and a content of a high boiling point solvent having a boiling point of 150° C. or more in the aqueous golf ball paint is more than 0 mass % and 10 mass % or less.Type: GrantFiled: October 22, 2010Date of Patent: October 22, 2013Assignees: SRI Sports Limited, Shinto Paint Co., Ltd.Inventors: Toshiyuki Tarao, Kuniyasu Horiuchi, Hirokazu Okamoto, Masahiko Shiraishi
-
Patent number: 8512834Abstract: A polyurethane that is a reaction product of reaction components, the reaction components comprising (a) a polyol; (b) a polyisocyanate selected from an aromatic, alicyclic or aliphatic polyisocyanate or combinations thereof; (c) a mixture of chain extenders that includes (i) a chain extender having a sulfur bridge in an amount of between 1 and 30 weight percent of the total mixture of claim extenders and (ii) a main chain extender, wherein the chain extender having a sulfur bridge. The chain extender having a sulfur bridge may be characterized as R1-A-Sx—B—R2 wherein R1 and R2 are selected from an OH, an NH2 or combinations thereof, A and B are selected from a divalent aliphatic, alicyclic or aromatic organic group or combinations thereof, A and B may be the same or different and x is an integer of between 2 and 10.Type: GrantFiled: December 20, 2007Date of Patent: August 20, 2013Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S. A.Inventor: Michael E. Dotson
-
Patent number: 8487051Abstract: Polymeric urethane dispersants with solubilizing polymer chains and with reactive carbon to carbon double bonds are described. The reactive double bonds facilitate molecular weight build-up of the dispersant on dispersed particles (enhancing colloidal stability) or enhance the ability of the dispersants to be crosslinked into a matrix material.Type: GrantFiled: December 15, 2009Date of Patent: July 16, 2013Assignee: Lubrizol Advanced Materials, Inc.Inventors: Stuart N. Richards, Andrew J. Shooter
-
Patent number: 8450397Abstract: The present invention provides a golf ball comprising a core and a cover covering the core, wherein the cover is formed from a cover composition containing a non-petroleum based polyester resin as a resin component (A) and a needle-like and/or fibrous filler (B). The present invention further provide a golf ball comprising a core and a cover covering the core, wherein the cover is formed from a cover composition containing, a non-petroleum based polyester resin (A-1), at least one petroleum based thermoplastic resin (A-2), and a compatibilizer (C) containing at least a (meth)acrylic resin (C-1) having a polar functional group and an olefin resin (C-2) having a polar functional group. According to the present invention, durability, abrasion resistance and repulsion of a golf ball can be improved.Type: GrantFiled: September 24, 2008Date of Patent: May 28, 2013Assignee: Dunlop Sports Co. Ltd.Inventor: Satoko Okabe
-
Patent number: 8450419Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.Type: GrantFiled: August 24, 2010Date of Patent: May 28, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
-
Patent number: 8436125Abstract: The present invention relates to materials comprising (A) at least one rubber, (B) at least one polyimide selected from branched condensation products of (a) at least one polyisocyanate having on average more than two isocyanate groups per molecule, and (b) at least one polycarboxylic acid having at least 3 COOH groups per molecule or anhydride thereof.Type: GrantFiled: May 24, 2011Date of Patent: May 7, 2013Assignee: BASF SEInventors: Anna Cristadoro, Bernd Bruchmann, Anna Thome, Juergen Widler
-
Patent number: 8415421Abstract: An object of the present invention is to provide a two-component curing type urethane-based aqueous golf ball paint, which is excellent in gloss of a paint film and evenness of the film thickness. Another object of the present invention is to provide a two-component curing type urethane-based aqueous golf ball paint, which is excellent in adhesion to the surface of a golf ball body. The present invention provides a two-component curing type urethane-based aqueous golf ball paint containing (A) an aqueous polyol composition and (B) an aqueous polyisocyanate, wherein the aqueous paint has a contact angle of 45° or less to a resin component constituting an outermost layer of a golf ball body and a paint film has reflectivity of 70% or more at an incident angle of 20°.Type: GrantFiled: December 17, 2009Date of Patent: April 9, 2013Assignees: SRI Sports Limited, Shinto Paint Co., Ltd.Inventors: Toshiyuki Tarao, Kuniyasu Horiuchi, Hirokazu Okamoto, Masahiko Shiraishi
-
Patent number: 8399569Abstract: An object of the present invention is to provide a reactive urethane compound having superior curability, adhesion to substrates, transparency, molecular flexibility, and mechanical properties, a curable composition containing the compound, and a cured material formed from the composition. An ethylenically-unsaturated-group containing reactive urethane compound of the present invention is represented by formula (I): wherein R1 and R2 are each independently a hydrogen atom or an alkylene group; R3 is a hydrogen atom, a alkyl group, or an aryl group; R4 is a single bond or an alkylene group; R5 is a hydrogen atom or a methyl group; R6 is an oxygen atom, a sulfur atom, or an imino group; n is 2 to 12; m is 1 to 300; and X is an aliphatic, aromatic or heterocyclic compound residue.Type: GrantFiled: May 21, 2008Date of Patent: March 19, 2013Assignee: Showa Denko K.K.Inventors: Katsumi Murofushi, Nobuaki Ishii, Miyuki Tomita, Yotaro Hattori, Yoshifumi Urakawa
-
Patent number: 8367781Abstract: The invention provides a golf ball having a core and one or more cover layer encasing the core, wherein at least one cover layer is formed by injection-molding a single resin composition of primarily (A) a thermoplastic polyurethane and (B) a polyisocyanate compound, and at least some polyisocyanate compound in which all the isocyanate groups on the molecule remain in an unreacted state is present in the resin composition. The golf ball has a high rebound, an excellent spin performance and an excellent scuff resistance, and the cover layer-forming resin composition has excellent flow properties and an excellent cover layer manufacturability.Type: GrantFiled: July 27, 2011Date of Patent: February 5, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Hiroyuki Nagasawa, Hiroshi Higuchi, Motoki Aoyagi, Daisuke Arai