Phenolic Reactant Prior To Contact With Aldehyde Or Aldehyde-type Reactant Contains At Least Two Aryl Rings Each Of Which Contains Phenolic Substituents Patents (Class 525/137)
  • Patent number: 10844239
    Abstract: The present disclosure is directed to a two-component epoxy resin paint, comprising a) an epoxy resin component; and b) an amine component for curing the epoxy resin component, the amine component comprising: i) at least one polyamide curing agent; and ii) at least one Mannich base curing agent, wherein at least one of the polyamide curing agent and the Mannich base curing agent is derived from one or more multifunctional amines comprising at least one cycloaliphatic multifunctional amine, and wherein the cycloaliphatic multifunctional amine is present in an amount of 30 wt % or more relative to the total amount of the multifunctional amines, wherein the ratio by weight of the epoxy resin component a) to the amine component b) is in the range of 100:8 to 100:20.
    Type: Grant
    Filed: April 17, 2017
    Date of Patent: November 24, 2020
    Assignee: Valspar Sourcing, Inc.
    Inventors: Wanjun Xu, Fan Yang, Daqian Pei
  • Patent number: 8981006
    Abstract: The present invention is a method for manufacturing a rubber composition containing a rubber component, a resin, a reinforcing filler and a crosslinking agent, and the method contains: a first step of adding the resin to the rubber component to produce a master batch; a second step of kneading the master batch with the reinforcing filler to produce a filled master batch; and a third step of kneading the filled master batch with the crosslinking agent, thereby providing a rubber composition having higher elasticity and large breaking elongation.
    Type: Grant
    Filed: August 19, 2011
    Date of Patent: March 17, 2015
    Assignee: Bridgestone Corporation
    Inventors: Reiko Yagi, Kumi Fujiki
  • Patent number: 8486604
    Abstract: The present invention provides a positive-type radiation-sensitive composition containing (A) a siloxane polymer, and (B) a quinone diazide compound, in which the content of aryl groups relative to Si atoms in the siloxane polymer (A) is greater than 60% by mole and no greater than 95% by mole.
    Type: Grant
    Filed: June 29, 2010
    Date of Patent: July 16, 2013
    Assignee: JSR Corporation
    Inventors: Masaaki Hanamura, Daigo Ichinohe, Hideaki Takase
  • Patent number: 8470930
    Abstract: The present invention relates to novolak resins prepared with, inter alia, one or more alkylphenols. The invention further relates to compositions comprising the novolak resins, such as vulcanizable rubber compositions, and to products obtained therewith.
    Type: Grant
    Filed: September 10, 2008
    Date of Patent: June 25, 2013
    Assignee: SI Group, Inc.
    Inventors: L. Scott Howard, Todd M. Aube, Timothy Edward Banach, James J. Lamb
  • Patent number: 8268929
    Abstract: A resin composition comprises (a) 100 parts by weight of at least one compound selected from the group consisting of phenol resins and brominated phenol resins, (b) 20 to 500 parts by weight of a crystalline olefin resin, provides that copolymers of ethylene with unsaturated carboxylic acid ester or vinyl acetate are precluded, and (c) 0 to 300 parts by weight of a non-aromatic softening agent for rubber. The resin composition is easy to handle in dynamic cross-linking of rubber or a thermoplastic elastomer to give uniform cross-linking. A cross-linked rubber composition or thermoplastic elastomer composition has improved compression set and moldability.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: September 18, 2012
    Assignee: Riken Technos Corporation
    Inventor: Naoyuki Ono
  • Patent number: 8017695
    Abstract: This invention relates to a method for producing functionalized cis-1,4-polydienes having a combination of a high cis-1,4-linkage content and a high functionality, the resulting polymers and the vulcanized products containing the polymers. The functionalized cis-1,4-polydienes of the present invention are produced by a method comprising the steps of: (1) preparing a reactive polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst in the presence of less than 20% by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst is the combination of or reaction product of (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a halogen-containing compound; and (2) contacting the reactive polymer with a functionalizing agent.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: September 13, 2011
    Inventors: Steven Luo, Junko Kurazumi, Yoichi Ozawa, Timothy L. Tartamella, Mark Smale, Kevin McCauley
  • Patent number: 7772323
    Abstract: The present invention relates to conjugated copolymers comprising blocks which are linked by random or partly random sections. The materials of the invention display an improved efficiency, a reduced operating voltage and a longer life.
    Type: Grant
    Filed: August 12, 2004
    Date of Patent: August 10, 2010
    Assignee: Merck Patent GmbH
    Inventors: Heinrich Becker, Esther Breuning, Aurélie Falcou, Amir Parham
  • Publication number: 20080275185
    Abstract: Poly(arylene ether)-poly(alkylene ether) block copolymers and methods for their preparation are provided. The block copolymers include structural units derived from a poly(arylene ether), a poly(alkylene ether), and an activated aromatic carbonate.
    Type: Application
    Filed: June 15, 2006
    Publication date: November 6, 2008
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Rene deKok, Erik R. Delsman, Amy R. Freshour, Farah Jean-Jacques Toublan, Patrick J. McCloskey, Edward N. Peters, Gary W. Yeager
  • Patent number: 7425602
    Abstract: The present invention relates to novolak resins prepared with, inter alia, one or more alkylphenols. The invention further relates to compositions comprising the novolak resins, such as vulcanizable rubber compositions, and to products obtained therewith.
    Type: Grant
    Filed: November 19, 2004
    Date of Patent: September 16, 2008
    Assignee: SI Group, Inc.
    Inventors: L. Scott Howard, Todd M. Aube, Timothy Edward Banach, James J. Lamb
  • Patent number: 7393899
    Abstract: As a rubber composition having an elasticity further increased as compared with the conventional rubber composition while preventing the lowering of the fracture resistance, there is provided a rubber composition comprising a rubber component of at least one of natural rubber and synthetic diene rubbers and a phenolic resin compounded therein and represented by the following formula (I): (wherein R0 is a hydrogen atom, an alkyl group, a phenyl group or a methylol group, and each of R1 and R2 is an arylene group, an alkylene group having a carbon number of 2-10, an aralkylene group, a cycloalkenylene group or a cycloalkadienylene group, and n is 0-10).
    Type: Grant
    Filed: October 7, 2003
    Date of Patent: July 1, 2008
    Assignee: Bridgestone Corporation
    Inventor: Ritsuko Yamada
  • Patent number: 7125930
    Abstract: A block copolymer comprising two or more blocks and having fluorescence in the solid state, wherein blocks thereof may be the same or different, and in each of the blocks, one or more kinds of repeating units are bonded through conjugated bonds, and bonding between the blocks is made by junction unit having conjugated bond, and the polystyrene reduced number average molecular weight of at least one block is 1×103 to 1×108.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: October 24, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takanobu Noguchi, Yoshiaki Tsubata, Shuji Doi
  • Patent number: 7074861
    Abstract: A modified resorcinol resin is prepared by reacting a phenolic compound (e.g., resorcinol) with an olefinically unsaturated compound (e.g., styrene) and two types of aldehyde: a formaldehyde and an alkyl aldehyde (e.g., butyraldehyde). The reaction is typically carried out in the presence of an acid catalyst. The resulting resin has a lower softening point and can be used as a methylene acceptor compound in a vulcanizable rubber composition.
    Type: Grant
    Filed: February 18, 2003
    Date of Patent: July 11, 2006
    Assignee: INDSPEC Chemical Corporation
    Inventors: Raj Durairaj, Mark A. Lawrence
  • Patent number: 6737478
    Abstract: The invention relates to rubber compounds comprising at least one double bond-containing rubber, additions of rubber gels, phenolic resin adducts or phenol/formaldehyde condensation products, such as resols or novolaks, and optionally, further fillers and rubber auxiliary substances, and the vulcanizates and molded rubber articles produced from them. The rubber compounds according to the present invention are characterized in the uncrosslinked state by good processability (compound viscosity ML 1+4/100° C.<60 ME) and in the vulcanized state by Shore-A hardness values/23° C.>60, high impact resilience values E/23° C.>60% and a low specific density. The vulcanizates are suitable for the production of industrial rubber articles and for various tire components, such as roll coverings, conveyor belt coverings, belts, spinning cops, seals, golf ball cores, shoe soles and bead compounds, tire carcasses, subtread compounds and tire sidewalls.
    Type: Grant
    Filed: October 16, 2001
    Date of Patent: May 18, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Obrecht, Anthony Sumner
  • Publication number: 20040034165
    Abstract: An electron-beam curable polyurethane resin for magnetic recording media is produced by modifying a polyurethane resin having active hydrogen in the molecule thereof with a compound having at least two acrylic double bonds, wherein the modification is performed on the active hydrogen so that the polyurethane resin becomes electron-beam curable. By subjecting a known thermosetting polyurethane resin to electron-beam sensitive modification, the resulting resin is highly crosslinked and is thus capable of being suitably used for magnetic recording media. Also, an electron-beam curable polyurethane resin having excellent crosslinking characteristics can easily be produced from the known thermosetting polyurethane resin. Furthermore, by using the electron-beam curable polyurethane resin, a high-performance magnetic recording medium can be provided.
    Type: Application
    Filed: March 27, 2003
    Publication date: February 19, 2004
    Applicant: TDK CORPORATION
    Inventors: Hideki Sasaki, Hiroyuki Yamada, Kenichi Kitamura, Kazushi Tanaka
  • Patent number: 6624244
    Abstract: An improved material comprising the reaction product of an A-side having an isocyanate and a B-side having a cross-linker comprising a multifunctional alcohol, a vegetable oil, preferably a blown/oxidized vegetable oil, most preferably a blown/oxidized soybean oil, and a catalyst and the method of producing the same.
    Type: Grant
    Filed: September 24, 2002
    Date of Patent: September 23, 2003
    Assignee: Urethane Soy Systems Company
    Inventor: Thomas M. Kurth
  • Patent number: 5916933
    Abstract: Proppants comprising a particle coated with a composition comprising bisphenol-aldehyde novolak resin, a bisphenol homopolymer or mixtures including such polymers are disclosed. Foundry sands comprising a particle coated with a composition comprising bisphenol-aldehyde novolak resin, a bisphenol homopolymer or mixtures including such polymers are disclosed. Methods of making and using these proppant particles in subterranean formations or making and using these foundry sands in foundries are also disclosed.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: June 29, 1999
    Assignee: Borden Chemical, Inc.
    Inventors: Calvin K. Johnson, Kwok-tuen Tse
  • Patent number: 5552509
    Abstract: A phenolic resin composition herein disclosed comprises, as essential components, (i) at least one phenol resin A selected from the group consisting of residues formed through purification of bisphenol A, residues obtained by cleaving the bisphenol A-purification residue, condensates of the bisphenol A-purification residue obtained by reacting the bisphenol A-purification residue with formaldehyde and condensates of the cleavage residue obtained by reacting the cleavage residue with formaldehyde, and (ii) at least one phenolic resin B selected from the group consisting of high-boiling fraction obtained through production of bisphenol F and condensates of the high-boiling fraction obtained by reacting the high-boiling fraction with formaldehyde.
    Type: Grant
    Filed: August 31, 1993
    Date of Patent: September 3, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tomoko Takashima, Shigeru Iimuro, Takashi Kitamura
  • Patent number: 5021522
    Abstract: An improved vulcanizable rubber composition of the type comprising (I) a rubber component selected from natural rubber, synthetic rubber or combinations thereof, and (II) a methylene donor compound which generates formaldehyde upon heating, and (III) a phenolic novolak resin type methylene acceptor compound is disclosed. The improvement comprises having at least ten mole percent of the phenolic groups of the phenolic novolak resin aralkylated with one or more compounds selected from the group consisting of styrene, alpha methyl styrene, beta methyl styrene, p-methyl styrene, alpha chloro styrene and vinyl naphthalenes.
    Type: Grant
    Filed: February 21, 1990
    Date of Patent: June 4, 1991
    Assignee: Indspec Chemical Corporation
    Inventors: Bojayan Durairaj, Alex Peterson, Jr., Robert M. Lamars, Richard T. Hood
  • Patent number: 4605696
    Abstract: There is disclosed a method for adhering rubber to reinforcing materials which comprises embedding a textile fiber or metal reinforcing material in a vulcanizable rubber composition comprising rubber, a vulcanizing agent, reinforcement, a methylene donor, and a phenolic ester as a methylene acceptor.
    Type: Grant
    Filed: September 27, 1985
    Date of Patent: August 12, 1986
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: David A. Benko, Syed K. Mowdood, Paul H. Sandstrom, Walter H. Waddell, III, Lawson G. Wideman
  • Patent number: 4465807
    Abstract: A process for the preparation of reinforced vulcanizates which process comprises vulcanizing a mixture comprising rubber, a novolak and at least one reactive melamine resin obtained by reaction of one mol of melamine with 0.5 to 6 mols of aldehyde, said melamine resin being present in an amount of from 0.5 to 120% by weight, based on the weight of the novolak resin, and the phenolic component of said novolak resin being selected from the group consisting of phenol, polynuclear polyphenols, alkylphenols, a combination of alkylphenols with phenol, and a combination of at least one of said phenols with a further phenol selected from the group consisting of resorcinol, phenylphenol and polyalkylphenols. The invention also includes rubber articles prepared from a product of such a process.
    Type: Grant
    Filed: August 30, 1983
    Date of Patent: August 14, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Arnold Giller, Joachim Weil
  • Patent number: 4369290
    Abstract: Resinous coating compositions can be expediently heat cured by phenol compounds containing at least two methylene amine groups which are conjugated with the aromatic alcohol group or phenol group. The hydroxyl group substantially increase the reactivity of the aminomethyl functionality whereby active hydrogen containing resins can be effectively cross-linked.
    Type: Grant
    Filed: March 12, 1979
    Date of Patent: January 18, 1983
    Assignee: SCM Corporation
    Inventors: James M. Evans, James T. K. Woo
  • Patent number: 4350800
    Abstract: A process for the preparation of synthetic resins based on resorcinol compounds which comprises reacting a resorcinol pitch which is obtained in the manufacture of resorcinol from benzenedisulfonic acid in at least one step with an oxo-compound selected from aldehydes, ketones and compounds based on or splitting off at least one of these substances, and the use of the products as binders for abrasive articles.
    Type: Grant
    Filed: September 14, 1981
    Date of Patent: September 21, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Hesse, Franz Landauer, Klaus Schmiedel
  • Patent number: 4260704
    Abstract: Resins having a softening point of from 50.degree. to 130.degree. C., an OH-number of from 250 to 400 and an iodine number of from 90 to 160, obtainable by reacting an alkyl phenol-formaldehyde novolak or an alkyl phenol mixture-formaldehyde novolak under acid-catalysed conditions with a polunuclear phenol or polynuclear phenol mixture and formaldehyde and/or an aliphatic aldehyde or aliphatic aldehyde mixture, the ratio by weight of the alkyl phenol or alkyl phenol mixture to the polynuclear phenol or polynyclear phenol mixture being from 2.2:1 to 1:10.
    Type: Grant
    Filed: October 10, 1978
    Date of Patent: April 7, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Manfred Schmidt, Theo Kemperman, Dieter Freitag, Hermann Fries, Erich Esch
  • Patent number: 4246368
    Abstract: A powder coating composition for forming multi layer coatings comprising:(1) at least one of finely divided thermosetting addition copolymers having a glass transition temperature of 35.degree. to 75.degree. C. and comprising as comonomers a wt. % of a hardness imparting monomer and b wt. % of a softness imparting monomer based on the copolymer wherein a+b.ltoreq.60, b.ltoreq.a and b.ltoreq.20, and(2) at least one of finely divided thermosetting resinous materials having incompatibility or low compatibility with the copolymer and a substantially greater surface tension than the copolymer when melted at the same temperature and substantially differing from the copolymer in composite parameter.
    Type: Grant
    Filed: May 5, 1978
    Date of Patent: January 20, 1981
    Assignee: Kansai Paint Company, Limited
    Inventor: Heihachi Murase