Solid Polymer Derived From Ethylenic Reactants Only Is Derived From A Nitrogen-containing Reactant Patents (Class 525/142)
  • Patent number: 11028207
    Abstract: A method of preparing a flame retardant grafted polyolefin resin is provided. The method includes a step of reacting in an extrusion barrel a reactive polyolefin and a monomeric flame retardant agent to form the flame retardant grafted polyolefin resin. The reactive polyolefin has a functional group including a moiety selected from the group consisting of anhydrides, epoxies, carboxylic acids, ketones, and isocyanates. The monomeric flame retardant agent has an amine functional group. The method also includes a step of extruding the flame retardant grafted polyolefin resin. Also provided is a flame retardant grafted polyolefin resin that can be made according to the method. Further provided is a flame retardant cable that incorporates can incorporate the flame retardant grafted polyolefin resin.
    Type: Grant
    Filed: April 25, 2019
    Date of Patent: June 8, 2021
    Assignee: CORNING INCORPORATED
    Inventors: Xiaole Cheng, Dayue Jiang
  • Patent number: 9540510
    Abstract: A stabilized, dynamically vulcanized thermoplastic elastomer composition comprising dispersed dynamically vulcanized particles of at least one first elastomer or rubber comprising halogenated isobutylene-containing elastomer and dispersed particles of at least one second elastomer or rubber comprising at least one functional group capable of reacting with and grafting to a polyamide, the particles of the at least one first and at least one second elastomers dispersed in a continuous thermoplastic polyamide or nylon resin matrix comprising at least one nylon homopolymer, nylon copolymer or mixture thereof, the composition or the at least one first elastomer further comprising at least one stabilizer against degradation induced by exposure to actinic, particularly ultraviolet, radiation.
    Type: Grant
    Filed: December 17, 2008
    Date of Patent: January 10, 2017
    Assignees: The Yokohama Rubber Co., Ltd, ExxonMobil Chemical Patents Inc.
    Inventors: Edward John Blok, Bruce Alan Harrington, Yuichi Hara, Shusaku Tomoi
  • Patent number: 9289631
    Abstract: Personal care compositions comprising a polymer-bound UV absorber are described that provide enhanced properties, including customizable UV spectrum protection, broad-spectrum UV spectrum protection, water resistance, and labile UV stabilization. The polymer comprises anhydride functionality, such as maleic anhydride or a derivative thereof, and the UV absorber contains at least one hydroxyl, primary amine, or secondary amine group. The personal care compositions may be used to treat and/or protect against burns, cancers, erythema, lentigo (“liver spots”), keratotic lesions, wrinkles, and cellular changes of the skin; and/or color changes, embrittlement, lack of luster, tangles, split ends, and/or unmanageability of the hair.
    Type: Grant
    Filed: June 1, 2015
    Date of Patent: March 22, 2016
    Assignee: ISP INVESTMENTS INC.
    Inventors: Osama M. Musa, Jenn S. Shih
  • Patent number: 9044623
    Abstract: Personal care compositions comprising a polymer-bound UV absorber are described that provide enhanced properties, including customizable UV spectrum protection, broad-spectrum UV spectrum protection, water resistance, and labile UV stabilization. The polymer comprises anhydride functionality, such as maleic anhydride or a derivative thereof, and the UV absorber contains at least one hydroxyl, primary amine, or secondary amine group. The personal care compositions may be used to treat and/or protect against burns, cancers, erythema, lentigo (“liver spots”), keratotic lesions, wrinkles, and cellular changes of the skin; and/or color changes, embrittlement, lack of luster, tangles, split ends, and/or unmanageability of the hair.
    Type: Grant
    Filed: January 27, 2010
    Date of Patent: June 2, 2015
    Assignee: ISP Investments Inc.
    Inventors: Osama M. Musa, Jenn S. Shih
  • Patent number: 9023931
    Abstract: Oxidation-sensitive, low-peroxide polymer contained in a sealed, protective-gas-filled packaging form, comprising, per kilogram of polymer solid, at least one inorganic phosphorus compound in amounts such that the total phosphorus content is 2*10?5 to 0.02 mol, and methods for stabilizing oxidation-sensitive polymer against peroxide formation, wherein, during or after the polymerization, at least one inorganic phosphorus compound is added in one or more portions in amounts such that the total phosphorus content per kilogram of polymer solid content of the finished polymer is 2*10?5 to 0.02 mol, and the polymer treated in such a way is placed into a protective-gas filled, sealed packaging form, and also use of these polymers.
    Type: Grant
    Filed: April 11, 2012
    Date of Patent: May 5, 2015
    Assignee: BASF SE
    Inventor: Bernhard Fussnegger
  • Patent number: 8338547
    Abstract: To provide a structure material having excellent mechanical characteristics and a functional material having excellent regularity, provided are a polymer alloy which is composed of at least two components of thermoplastic resins and of which the structure can be controlled finely and evenly dispersed and a production method of the polymer alloy. With respect to a polymer alloy composed of at least two or more components of thermoplastic resins, a precursor (A) of at least one thermoplastic resin among the thermoplastic resin components composing the polymer alloy is chemically reacted in the co-presence of the remaining thermoplastic resin component (B1) and/or a precursor (B2) of the thermoplastic resin component to induce spinodal decomposition, so that it is made possible to obtain a polymer alloy having excellent regularity and of which the structure is finely controllable and the structure is evenly dispersed.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: December 25, 2012
    Assignee: Toray Industries, Inc.
    Inventors: Hiroshi Takahashi, Sadayuki Kobayashi
  • Patent number: 8318824
    Abstract: Disclosed is a hydrophilic polyolefin sintered material which is a water-absorbing sintered material of a polyolefin resin ice having a graft chain composed of at least one molecular chain selected from hydrophilic ethylenically unsaturated group-containing monomers and their polymers. This hydrophilic polyolefin sintered material has an average porosity of 20-80% by volume and an open cell having an average pore diameter of 1-150 ?m.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: November 27, 2012
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Naoki Matsuoka, Minoru Yamamoto, Shigeru Nakajima, Takahiro Deguchi
  • Patent number: 7927691
    Abstract: A prepreg composite material that includes a fiber layer and a resin comprising a thermoset resin component, a curing agent and a fibrous micropulp. The micropulp component is an aramid fiber having a volume average length of from 0.01 to 100 micrometers. The prepreg is useful in composite panel construction for minimizing fluid permeation into the cured structure. This prepreg is particularly suitable for making honeycomb sandwich panels. Film adhesives, liquid and paste resins containing aramid fiber micropulp are also disclosed.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: April 19, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Subhotosh Khan, Halvar Young Loken
  • Patent number: 7247388
    Abstract: A vulcanizable adhesive composition, which comprises 100 parts by weight of phenolxylylene resin or phenolbiphenyl resin, 10 to 1,000 parts by weight of resol-type phenol resin, 0 to 1,000 parts by weight of novolak-type phenol resin, 10 to 1,000 parts by weight of unvulcanized nitrile rubber and 10 to 500 parts by weight of chlorinated polyethylene, is effectively applied to (hydrogenated) nitrile rubber with a nitrile content of 18 to 48%, and has a suppression effect on a decrease in the adhesiveness even if exposed to dip in various cryogenic liquids such as flon gas, polyalkylene glycol, water, etc. for a long time.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: July 24, 2007
    Assignee: NOK Corporation
    Inventors: Kiyofumi Fukasawa, Tomohiro Kaise
  • Patent number: 7097759
    Abstract: A method for dispersing asphaltenes in a petroleum product by adding to the petroleum product 0.001% to 20% of at least one compound having formula (V) wherein R14 is C15–C21 alkyl. In addition to dispersing asphaltenes, the method of the present invention typically also increases demulsibility, reduces viscosity, reduces sediment formation, reduces surface fouling and reduces corrosion.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: August 29, 2006
    Assignee: Rohm and Haas Company
    Inventor: Ravindranath Mukkamala
  • Patent number: 6875807
    Abstract: A silane-modified phenolic resin is prepared by reacting a phenolic compound (e.g., resorcinol) with an aldehyde to produce a phenolic novolak resin. The phenolic novolak resin is further reacted with at least one silane compound to produce the silane-modified phenolic resin. The reaction is typically carried out in the presence of an acid or base catalyst. The resulting resin has a lower softening point and can be used as a methylene acceptor compound in a vulcanizable rubber composition.
    Type: Grant
    Filed: May 28, 2003
    Date of Patent: April 5, 2005
    Assignee: Indspec Chemical Corporation
    Inventors: Raj B. Durairaj, C. Michael Walkup, Mark A. Lawrence
  • Patent number: 6841221
    Abstract: A process for making a textured coating on a substrate and compositions for such coatings are disclosed wherein coating mixtures comprising un-expanded micro-capsules and a plastisol or other suitable resins are applied to the substrate and subsequently heat treated to expand the micro-capsules within the coating. The expanded micro-capsules create an aesthetically pleasing surface texture in the coating while retaining the desired wear-resistant properties of the coating.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: January 11, 2005
    Assignee: Congoleum Corporation
    Inventor: Richard C. MacQueen
  • Patent number: 6686418
    Abstract: A process for reducing the heat evolution on dynamic stressing of vulcanised rubber products, using for this purpose, in vulcanizable rubber mixtures, mixtures made from non-selfcuring novolaks A and from unetherified or partially etherified triazine resins B, as a combination of reinforcing resin and curing agent.
    Type: Grant
    Filed: May 22, 2001
    Date of Patent: February 3, 2004
    Assignee: Solutia Germany GmbH & Co. KG
    Inventors: Siegfried Wallenwein, Frank Scholl, Helmut Eckes
  • Patent number: 6662840
    Abstract: The present invention relates to a rubber stock for bead wire compounds comprising (A) based on 100 parts by weight of rubber (1) from about 5 to about 40 weight percent of a carboxylated acrylonitrile-diene rubber having an acrylonitrile content ranging from about 15 to 45 percent by weight; and (2) from about 60 to about 95 weight percent of a non-carboxylated rubber selected from the group consisting of natural rubber, polyisoprene, polybutadiene, styrene-butadiene rubber, styrene-isoprene-butadiene rubber, styrene-isoprene rubber, isoprene-butadiene rubber and mixtures thereof; (B) from about 0.1 to about 10 phr of a methylene acceptor; and (C) from about 0.1 to about 10 phr of a methylene donor.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: December 16, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Georges Marcel Victor Thielen, Filomeno Gennaro Corvasce
  • Patent number: 6512048
    Abstract: The invention provides a polymer (a) having a polymer backbone having appended thereto at least one carbamate functional group, the polymer represented by randomly repeating units according to the formula: R1 represents H or CH3, R2 represents H, alkyl, or cycloalkyl, L represents a divalent linking group, A represents repeat units comprising at least one repeat unit having a pendant cationic salting group, x represents 10 to 90 weight %, and y represents 90 to 10 weight %. The invention further provides a cathodic electrocoat coating composition comprising an aqueous dispersion of a polymer (a) and (b) a compound having a plurality of functional groups that are reactive with said carbamate groups, wherein the repeat units A of polymer (a) having a pendant cationic salting group are salted with an acid.
    Type: Grant
    Filed: October 26, 2000
    Date of Patent: January 28, 2003
    Assignee: BASF Corporation
    Inventors: Timothy S. December, Walter H Ohrbom, Gregory G. Menovcik
  • Patent number: 6492462
    Abstract: The rheological properties of a crosslinkable resin system are modified by the presence of a side chain crystalline (SCC) polymer (or a similar crystalline polymer which melts over a narrow temperature range). The polymer dissolves in the curable system at temperatures above the melting point of the crystalline polymer (Tp), but when the system is then cooled to a temperature below Tp, at least partially forms a separate phase in the curable system. Below Tp, this separate phase substantially increases the viscosity of the curable system (i.e. makes it thicker than the same system without the crystalline polymer). This is particularly valuable for sheet molding composites (SMCs) in which the increase in viscosity makes the composites less tacky, and for dry film resists (DFRs). Above Tp, the curable system containing the dissolved crystalline polymer has a viscosity which is substantially less than its viscosity below Tp.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: December 10, 2002
    Assignee: Landec Corporation
    Inventors: Steven P. Bitler, David D. Taft, Ray F. Stewart
  • Patent number: 6423817
    Abstract: A process for preparing inherently light- and heat-stabilized polyamides comprises polymerizing in the presence of at least one triacetonediamine compound of the formula where R is hydrogen or hydrocarbyl having from 1 to 20 carbon atoms, preferably alkyl having from 1 to 18 carbon atoms, or benzyl.
    Type: Grant
    Filed: December 31, 1996
    Date of Patent: July 23, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Weinerth, Karlheinz Mell, Paul Matthies, Ludwig Beer
  • Patent number: 6391390
    Abstract: The present invention provides a curable coating composition that includes a film-forming polymer, a polymeric additive having at least one bound surface protecting group, and a crosslinker that is reactive with the film-forming polymer. The polymeric additive is substantially free of groups reactive with the crosslinker and has comonomer units with aryl groups, alkyl groups having, on average, four or more carbon atoms, or combinations of the aryl and alkyl groups. When the coating composition is cured to form a cured coating layer, the concentration of the polymeric additive in the upper about 50% of the cured coating layer thickness is at least about 10% higher than the concentration of the polymeric additive in the rest of the cured coating layer.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: May 21, 2002
    Assignee: BASF Corporation
    Inventors: John E. Boisseau, Donald L. St. Aubin, Walter H Ohrbom
  • Patent number: 6303690
    Abstract: The invention provides a cathodic electrocoat coating composition having (A) a polymer comprising at least one primary carbamate group and at least one cationic salting site, (B) a curing agent having groups that are reactive with said functional groups on (A), and (C) a reactive additive comprising at least one compound having a molecular weight of from 131 to 2000 and comprising at least one primary carbamate group and at least one alkyl group selected from the group consisting of branched alkyl groups of from 5 to 30 carbons, straight chain alkyl groups of more than 10 carbons, and mixtures thereof, wherein one or both of (A) and (B) comprise groups that are reactive with the primary carbamate group of (C).
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: October 16, 2001
    Assignee: BASF Corporation
    Inventors: Timothy S. December, Walter H Ohrbom
  • Patent number: 6297319
    Abstract: The present invention provides: a process for producing a water-absorbing agent by using a crosslinking agent of high safety, wherein the water-absorbing agent is excellent in the absorption capacities under no load and under a load and further in the blocking ratio under a load, and can display excellent absorption properties even if the weight percentage of the water-absorbent resin (resin concentration) is high when the water-absorbent resin is used for materials such as sanitary materials; and such a water-absorbing agent. The water-absorbent resin is mixed and treated with an oxazoline compound, wherein the oxazoline compound has at least three structural units of general formula (1) below: wherein R1˜R4 separately denote a hydrogen atom, an alkyl group, an aromatic group, a halogen group, a substituted alkyl group, or a substituted aromatic group.
    Type: Grant
    Filed: November 2, 1999
    Date of Patent: October 2, 2001
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kinya Nagasuna, Shinichi Fujino, Masatoshi Nakamura, Kunihiko Ishizaki
  • Patent number: 6232399
    Abstract: The specification discloses a method for the manufacture of a fluorescent polyphenolic product with high UV absorbance, its subsequent epoxidation as well as polyphenolic products and epoxidized derivatives and compositions thereof. The polyphenolic products are prepared by heating glyoxal at a temperature of about 80° C. to about 100° C. with a molar excess of a phenol in the presence of an acidic catalyst which is eliminated from the reaction mixture at a temperature below about 170° C. The total mole ratio of glyoxal to phenol charged to the reaction mixture is about 0.15 to 0.22 moles of glyoxal for each mole of phenol. The glyoxal is added continuously or by stepwise additions to the phenol so as to keep the aldehyde units in the reaction mixture to less than about 70% of the aldehyde units in the total quantity of glyoxal to be charged for making the polyphenol. Water is distilled stepwise or continuously from the reaction mixture.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: May 15, 2001
    Assignee: Borden Chemical, Inc.
    Inventor: Arthur H. Gerber
  • Patent number: 6232398
    Abstract: A resin matrix with resistances to alkali and acid such as a fluorene-containing epoxy acrylate and/or a benzocyclobutene resin includes at least any one of insulative organic particles and insulative composite particles having an organic component and an inorganic component with the total amount of these particles being in the range of 5-50% by volume, wherein the insulative organic particles and the organic component of the insulative composite particles are allowed to be corroded by either alkali or acid, and wherein not less than 90% by volume of the insulative organic particles and insulative composite particles have a particle diameter in the range of 1-20 micrometers.
    Type: Grant
    Filed: December 5, 1997
    Date of Patent: May 15, 2001
    Assignee: NEC Corporation
    Inventors: Yoshitsugu Funada, Koji Matsui
  • Patent number: 6201094
    Abstract: The specification discloses epoxidized products and compositions of a polyphenol of a phenol and glyoxal wherein the polyphenol prior to epoxidation has an ultraviolet (UV) absorbance of at lest 0.260 at 365 nanometers (nm) and/or at least 0.400 at 350 nm.
    Type: Grant
    Filed: October 20, 1999
    Date of Patent: March 13, 2001
    Assignee: Borden Chemical, Inc.
    Inventor: Arthur H. Gerber
  • Patent number: 6150496
    Abstract: An inherently light- and heat-stabilized polyamide has at least one piperidine compound bonded to the backbone polymer chain and at least one 4-amino-2,2,6,6-tetramethylpiperidine compound bonded to the backbone polymer chain. The inherently light- and heat-stabilized polyamide may be used to form articles such as, for example, fibers, carpets, yarns, and textile fabrics.
    Type: Grant
    Filed: February 5, 1999
    Date of Patent: November 21, 2000
    Assignee: BASF Corporation
    Inventors: Otto M. Ilg, Ulrike Breiner, Manfred Juluis
  • Patent number: 6140421
    Abstract: The specification discloses a method for the manufacture of a fluorescent polyphenolic product with high UV absorbance, its subsequent epoxidation as well as polyphenolic products and epoxidized derivatives and compositions thereof. The polyphenolic products are prepared by heating glyoxal at a temperature of about 80.degree. C. to about 100.degree. C. with a molar excess of a phenol in the presence of an acidic catalyst which is eliminated from the reaction mixture at a temperature below about 170.degree. C. The total mole ratio of glyoxal to phenol charged to the reaction mixture is about 0.15 to 0.22 moles of glyoxal for each mole of phenol. The glyoxal is added continuously or by stepwise additions to the phenol so as to keep the aldehyde units in the reaction mixture to less than about 70% of the aldehyde units in the total quantity of glyoxal to be charged for making the polyphenol. Water is distilled stepwise or continuously from the reaction mixture.
    Type: Grant
    Filed: September 23, 1999
    Date of Patent: October 31, 2000
    Assignee: Borden Chemical, Inc.
    Inventor: Arthur Harry Gerber
  • Patent number: 6040062
    Abstract: Environmental etch resistant coatings are described. The coatings are derived from aqueous, curable coating compositions comprising:(a) a carbamate-functional grafted acrylic polymer that comprises the reaction product of a first acrylic polymer and a second acrylic polymer, with at least one of the first and second acrylic polymers having groups that impart water dispersibility to the grafted acrylic polymer, and at least one of the first and second acrylic polymers having carbamate functionality; and(b) a second component comprising a compound having a plurality of functional groups that are reactive with the carbamate functionality.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: March 21, 2000
    Assignee: BASF Corporation
    Inventors: John D. McGee, Donald H. Campbell, John W. Rehfuss
  • Patent number: 5936038
    Abstract: A vulcanizable elastomer having at least one pendant reactive amino group. The elastomer is vulcanized by using a phenolic-resin curative essentially in the absence of an activation catalyst, to form a vulcanizate. Also provided is a thermoplastic elastomeric vulcanizable composition of matter, employing the elastomer having the pendent reactive amino group, which may be dynamically vulcanized without the use of an activation catalyst. Further provided is a method for vulcanizing an elastomer having at least one pendent reactive amino group by utilizing a phenolic vulcanizing agent without the use of a catalyst.
    Type: Grant
    Filed: August 9, 1996
    Date of Patent: August 10, 1999
    Assignee: The University of Akron
    Inventors: Aubert Y. Coran, Oansuk Chung
  • Patent number: 5919837
    Abstract: Wet processed friction materials are disclosed wherein the components thereof include blends of a) fibrillated, organic, synthetic polymer, b) organic, synthetic polymer staple and c) organic, synthetic soluble polymer particles.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: July 6, 1999
    Assignee: Sterling Chemicals International, Inc.
    Inventors: Stanley Sigmund Kaminski, Robert Ellsworth Evans
  • Patent number: 5889080
    Abstract: A method for making a dry blend for use in the preparation of a friction material, a dry blend per se and dry friction materials is disclosed wherein the components thereof include a) fibrillated, organic, synthetic polymer, b) organic, synthetic polymer staple and c) organic, synthetic soluble polymer particles.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: March 30, 1999
    Assignee: Sterling Chemicals International, Inc.
    Inventors: Stanley Sigmund Kaminski, Robert Ellsworth Evans
  • Patent number: 5889082
    Abstract: A method for producing wet processed friction materials are disclosed wherein the components thereof include blends of a) fibrillated, organic, synthetic polymer, b) organic, synthetic polymer staple and c) organic, synthetic soluble polymer particles.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: March 30, 1999
    Assignee: Sterling Chemicals International, Inc.
    Inventors: Stanley Sigmund Kaminski, Robert Ellsworth Evans
  • Patent number: 5837752
    Abstract: Compositions for bone repair have been developed based on linear hydrophobic degradable polymers and monomers or macromers, at least one of which includes an anhydride linkage. The monomers and/or macromers crosslink each other but not to the linear polymer to form semi-interpenetrating networks. The compositions can include various excipients, therapeutic and/or diagnostic agents. The compositions can be polymerized in the presence of dissolvable particles such as inorganic salts and proteinaceous materials to provide a porous polymer network. The compositions can be injected into a patient and polymerized in situ or can be polymerized ex vivo and implanted. When polymerized ex vivo, the composition can be shaped into various articles, such as pins, screws, and hollow tubes, which can be used to repair broken bones.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: November 17, 1998
    Assignee: Massachusetts Institute of Technology
    Inventors: Venkatram R. Shastri, Robert S. Langer, Peter J. Tarcha
  • Patent number: 5733979
    Abstract: Catalytic solids based on titanium trichloride complex, usable for the stereospecific polymerisation of alpha-olefins, obtained by heat treatment, in the presence of a halogenated activating agent, of the liquid material resulting from bringing TiCl.sub.4, pretreated with an electron-donor compound, into contact with a composition (C) corresponding to the general formulaAlR.sub.p (Y).sub.q X.sub.3-(p+q)in whichR represents a hydrocarbon radical or a hydrogen atom;Y represents a group chosen from --OR', --SR' and --NR'R", in which R' and R" each represent a hydrocarbon radical or a hydrogen atom;X represents a halogen;p is an arbitrary number such that 0<p<3; andq is an arbitrary number such that 0<q<3;the sum (p+q) being such that 0<(p+q).ltoreq.3.These catalytic solids of controllable porosity permit the production of a wide range of propylene polymers, in particular the propylene and ethylene copolymers known as "block" copolymers.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: March 31, 1998
    Assignee: Solvay (Societe Anonyme)
    Inventors: Jean-Louis Costa, Sabine Pamart
  • Patent number: 5726244
    Abstract: Environmental etch resistant coatings are described. The coatings are derived from aqueous, curable coating compositions comprising:(a) a carbamate-functional grafted acrylic polymer that comprises the reaction product of a first acrylic polymer and a second acrylic polymer, with at least one of the first and second acrylic polymers having groups that impart water dispersibility to the grafted acrylic polymer, and at least one of the first and second acrylic polymers having carbamate functionality; and(b) a second component comprising a compound having a plurality of functional groups that are reactive with the carbamate functionality.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: March 10, 1998
    Assignee: BASF Corporation
    Inventors: John D. McGee, Donald H. Campbell, John W. Rehfuss
  • Patent number: 5639828
    Abstract: A curable coating composition is described comprising two components that are reactive with one another upon curing to form urethane linkages. The urethane-forming components are an active hydrogen groups-containing component and a polyisocyanate, or a carbamate groups-containing component and a carbamate group-reactive component. The composition further comprises a third component that includes one or more epoxide groups. Coatings prepared with this coating composition can be cured and coated with additional coating(s), providing good intercoat adhesion to the subsequent coating.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: June 17, 1997
    Assignee: BASF Corporation
    Inventors: Rodney L. Briggs, John W. Rehfuss, Walter H Ohrbom, Gregory G. Menovcik
  • Patent number: 5618909
    Abstract: A dyed or undyed polyamide substrate, preferably film, fiber, or an article manufactured therefrom, with excellent breaking strength retention and ultimate elongation retention, is prepared by reacting a sufficient number of amine and/or amide-forming functional groups of a hindered amine with the end groups of the polyamide precursor(s) at a temperature sufficient for polymerization to occur, to thereby bind the hindered amine to the polyamide and inhibit migration, leaching, and volatilization of the hindered amine. The hindered amine is represented by the formula: ##STR1## in which R.sub.1 comprises the amine or amide-forming functional group;R.sub.2 is alkyl; andR.sub.3 is selected from the group consisting of hydrogen; alkyl of 1 to 3 carbons; and --OR.sub.4 in which R.sub.4 is selected from the group consisting of hydrogen, methyl, and alkyl of 1 to 7 carbons.The light stabilized polyamide substrate has particular utility in flags, decorative banners, and personal flotation device covers.
    Type: Grant
    Filed: July 27, 1995
    Date of Patent: April 8, 1997
    Assignee: AlliedSignal Inc.
    Inventors: Robert A. Lofquist, Yousef Mohajer
  • Patent number: 5605962
    Abstract: A flame retarding resin composition comprising 100 parts by weight of a specific rubber-reinforced resin, 1-200 parts by weight of a phenol resin, 1-200 parts by weight of an organic phosphorus compound, 1-50 parts by weight of a nitrogen-containing compound, 0-40 parts by weight of an oligomer-type polymer containing a functional group, 0-30 parts by weight of a metal compound, a silicon compound, and/or polytetrafluoroethylene, and 0-300 parts by weight of a styrene-type resin. The composition has high impact resistance, excellent heat resistance, and a superior self-fire-extinguishing characteristic.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: February 25, 1997
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Masanori Suzuki, Hiroyuki Itoh, Koichi Sumi, Yoichi Kamoshida, Shigeru Abe, Seiichi Atomori, Tateki Furuyama
  • Patent number: 5336723
    Abstract: Disclosed is a phenolic resin molding material which is mainly composed of (1) 25-55 parts by weight of a phenolic resin containing 60% by weight or more of a resol-type phenolic resin, (2) 2-10 parts by weight of a partially crosslinked NBR, and (3) 35-70 parts by weight of an inorganic filler, on the basis of 100 parts by weight in total of these components.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: August 9, 1994
    Assignee: Sumitomo Bakelite Company Limited
    Inventors: Shinji Ikeda, Keiji Ooi, Ken Katoh
  • Patent number: 5314955
    Abstract: A coating composition containing a hydrogenated acrylonitrile-butadiene copolymer, a phenolic resin, a curing component, and a solvent. The coating composition is useful for protecting elastomeric materials from corrosive materials such as oil or fuel. The coating composition is resistant to fatigue and provides for excellent adhesion to both rigid and flexible substrates.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: May 24, 1994
    Assignee: Lord Corporation
    Inventor: James R. Halladay
  • Patent number: 5232972
    Abstract: An adhesive composition comprising a mixture of(1) a latex having a double construction of vinylpyridine-styrene-butadiene terpolymer prepared by(A) polymerizing a monomer mixture comprising 30-60 wt % of styrene, 0.5-15 wt % of vinylpyridine and less than 60 wt % of butadiene and then(B) polymerizing a monomer mixture comprising 10-40 wt % of styrene, 5-20 wt % of vinylpyridine and 45-75 wt % of butadiene, and with the styrene content by percentage in (B) being less than that in (A) and(2) 10-30 parts on a solids basis of a thermosetting resin based on 100 parts on a solids basis of said latex (1).
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: August 3, 1993
    Assignee: Bridgestone Corporation
    Inventors: Kozo Sasaki, Toshihiro Yotsumoto
  • Patent number: 5166237
    Abstract: A novel thermoplastic composition having improved paint adhesion strength comprising,A) from about 5 to 95 weight % of a6t least one polyphenylene ether.B) from about 95 to 5 weight % of at least one polyamide,C) paint adhesion improving amount of at least one paint adhesion improver selected from the class consisting of(1) homopolymers or copolymers of unsaturated nitrile compounds and(2) homopolymers or copolymers of alkyl (meth)acrylate, excluding an ethylene alkylacrylate copolymer having about 50 weight % or higher of ethylene,D) from about 0.01 to 30 parts by weight of at least one compatibilizer, based on 100 by weight of the total of the polyphenylene either and polyamide.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: November 24, 1992
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Hiroomi Abe, Taichi Nishio, Takashi Sanada, Noriyasu Kagawa
  • Patent number: 5160764
    Abstract: Holt melt adhesive compositions having longer pot lives and comprising adhesive thermoplastic compositions having high cohesion and low flowability based on copolymers A) composed of ethylenically unsaturated monomers containing chelating metal compounds B) and, if desired, other conventional additives C), these hot melt adhesive compositions additionally containing an alkylphenolic resin or an arylphenolic resin in amounts of up to 20% by weight, relative to copolymer A), as crosslinking regulator in order to extend the pot life and to improve their processibility like a thermoplastic, and processes for preparing hot melt adhesive compositions by mixing the starting components.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: November 3, 1992
    Assignee: Hoechst AG
    Inventors: Heinz Schmelzer, Manfred Kuechler
  • Patent number: 5143594
    Abstract: An asphalt or asphaltene refinery anti-foulant technique comprising the use in crude oil, or crude oil fraction, streams of alkyl-substituted phenol formaldehyde liquid resins in combination with hydrophilic-lipophilic vinylic polymers. The polymeric anti-foulant is added to asphalt or asphaltene containing crude oil streams to prevent fouling of metallic, or other, i.e. ceramic, surfaces, especially heat transfer surfaces.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: September 1, 1992
    Assignee: Nalco Chemical Company
    Inventors: William K. Stephenson, Bradley D. Mercer, David G. Comer
  • Patent number: 5120789
    Abstract: Hot melt adhesive compositions having longer pot lives and comprising adhesive thermoplastic compositions having high cohesion and low flowability based on copolymers A) composed of ethylenically unsaturated monomers containing chelating metal compounds B) and, if desired, other conventional additives C), these hot melt adhesive compositions additionally containing an alkylphenolic resin or an arylphenolic resin in amounts of up to 20% by weight, relative to copolymer A), as crosslinking regulator in order to extend the pot life and to improve their processibility like a thermoplastic, and processes for preparing hot melt adhesive compositions by mixing the starting components.
    Type: Grant
    Filed: January 15, 1991
    Date of Patent: June 9, 1992
    Assignee: Hoechst AG
    Inventors: Heinz Schmelzer, Manfred Kuechler
  • Patent number: 5100531
    Abstract: An asphalt or asphaltene refinery anti-foulant technique comprising the use in crude oil, or crude oil fraction, streams of alkyl-substituted phenol formaldehyde liquid resins in combination with hydrophilic-lipophilic vinylic polymers. The polymeric anti-foulant is added to asphalt or asphaltene containing crude oil streams to prevent fouling of metallic, or other, i.e. ceramic, surfaces, especially heat transfer surfaces.
    Type: Grant
    Filed: April 18, 1991
    Date of Patent: March 31, 1992
    Assignee: Nalco Chemical Company
    Inventors: William K. Stephenson, Bradley D. Mercer, David G. Comer
  • Patent number: 5096968
    Abstract: A thermoplastic methacrylimide-containing polymer comprising 2 to 100% by weight of structural units represented by the following formula (I): ##STR1## wherein R is hydrogen or a hydrocarbon group having 1 to 20 carbon atoms, and 0 to 98% by weight of structural units derived from an ethylenically unsaturated monomer, wherein the content of iron in the polymer is not larger than 20 ppm and the difference between the maximum value and minimum value of the degree of imidization is preferably not larger than 5% by weight. This methacrylimide-containing polymer is used alone or as a blend thereof with another thermoplastic polymer.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: March 17, 1992
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Isao Sasaki, Kozi Nishida, Hisao Anzai, Masaharu Fujimoto
  • Patent number: 5073248
    Abstract: A method of dispersing asphalt/asphaltene comprising an admixture of polymer A and polymer B ranging from 90 to 10 weight percent A to from 10 to 90 weight percent B. Wherein polymer A is an alkyl substituted phenolformaldehyde liquid resin having a weight average molecular weight ranging from about 1000 to about 20,000 and an alkyl substituent containing from 4 to 24 carbon atoms, with alkyl substituent may be linear or branched alkyl group. Polymer B is a hydrophilic-lipophilic vinylic polymer.
    Type: Grant
    Filed: February 14, 1991
    Date of Patent: December 17, 1991
    Assignee: Nalco Chemical Company
    Inventors: William K. Stephenson, Morris Kaplan
  • Patent number: 5049618
    Abstract: The present invention relates to vulcanizable rubber compositions containing a methylene donor and a hydroxy-aryl substituted monomaleimide. The substituted monomaleimides may be used as a replacement for resorcinol and function as a methylene acceptor. The vulcanizable rubber compositions exhibit improved rubber/reinforcement interaction for increased adhesion and tear in rubber. These vulcanizable rubber compositions also contain a vulcanizing agent.
    Type: Grant
    Filed: September 5, 1989
    Date of Patent: September 17, 1991
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson G. Wideman, Paul H. Sandstrom
  • Patent number: 5021498
    Abstract: An asphalt/asphaltene dispersant comprising an admixture of polymer A and polymer B ranging from 100 to 10 weight percent A to from 10 to 100 weight percent B. Wherein polymer A is an alkyl substituted phenol-formaldehyde liquid resin having a weight average molecular weight ranging from about 1000 to about 20,000 and an alkyl substituent containing from 4 to 24 carbon atoms, with alkyl substituent may be linear or branched alkyl group. Polymer B is a hydrophilic-lipophilic vinylic polymer.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: June 4, 1991
    Assignee: Nalco Chemical Company
    Inventors: William K. Stephenson, Morris Kaplan
  • Patent number: RE34141
    Abstract: The weather and UV-light resistance of polyacetal resin compositions is improved by incorporating into polyacetal resin a stabilizing package comprised of at least one stabilizing agent selected from benzotriazoles, benzophenones, aromatic benzoates, cyanoacrylates, oxalanilides, and hindered amines, and an acylate resin selected from homopolymers or copolymers of acrylic or methacrylic acid, and ester derivatives thereof.
    Type: Grant
    Filed: August 1, 1991
    Date of Patent: December 8, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventor: Sadatsugu Okuda
  • Patent number: RE34791
    Abstract: Polymer bound hindered amine light stabilizers are prepared by reacting hindered amine light stabilizers containing reactive hydrazide functionalities with anhydride containing polymers or copolymers. The reactions may be carried out in an inert solvent or in a melt blending step. The polymer bound hindered amine light stabilizers are useful alone or may also be used to stabilize other polymers, copolymers or polymers blends against the deleterious effects of heat and/or light.
    Type: Grant
    Filed: July 16, 1991
    Date of Patent: November 15, 1994
    Assignee: Atochem North America, Inc.
    Inventors: Robert T. Kazmierzak, Ronald E. MacLeay