With A -o-c(=o)-o-, -o-c(=o)-hal Or Hal-c(=o)-hal Group-containing Reactant Or Polymer Thereof Patents (Class 525/146)
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Patent number: 5218048Abstract: A resin composition comprising (A) a thermoplastic resin, (B) a functional compound having one or more bonds or one or more functional groups selected from the group consisting of organic groups having a non-aromatic carbon-carbon multiple bonds, oxirane groups and substituted carboxyl groups and (C) a diamino compound represented by the following general formula:R.sup.I NH--X--NHR.sup.IIwherein R.sup.I and R.sup.II each represents a hydrogen atom or an alkyl group optionally having one or more inactive substituents, and X represents an alkylene group having 7 to 30 carbon atoms and optionally having one or more inactive substituents.Type: GrantFiled: December 10, 1990Date of Patent: June 8, 1993Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroomi Abe, Kenji Nagaoka, Takashi Sanada
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Patent number: 5216079Abstract: Lubricant systems are provided in which a polyolefin or polyolefin/polytetrafluoroethylene blend functions as a lubricant in a polymer matrix material. The resulting polymer composites containing about 1 to 30 weight percent of the novel lubricant or lubricant blend have greatly improved friction and wear properties, including lower coefficients of friction and increased surface wear resistence. The polyolefin does not remain as discrete, identifiable particles after mixing with the polymer matrix, and has an average molecular weight of less than 500,000.Type: GrantFiled: February 23, 1990Date of Patent: June 1, 1993Assignee: Kawasaki LNP Inc.Inventors: Jane M. Crosby, John E. Theberge
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Patent number: 5189091Abstract: A polycarbonate blend of good impact strength, solvent resistance and weldline properties is prepared by admixing with polycarbonate an aromatic polyester, a grafted olefin/carbon monoxide copolymer and, optionally, an elastomeric toughening agent such as a rubber, and, optionally, a filler.Type: GrantFiled: November 26, 1990Date of Patent: February 23, 1993Assignee: The Dow Chemical CompanyInventor: Michael K. Laughner
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Patent number: 5189114Abstract: There are disclosed thermoplastic resin compositions with improved impact strength and other physical properties, specifically compatibilized compositions comprising polyphenylene ethers and thermoplastic polyesters, with the compatibilization being effected through the use of polystyrene-polycarbonate copolymer.Type: GrantFiled: December 31, 1990Date of Patent: February 23, 1993Assignee: General Electric CompanyInventors: Sterling B. Brown, Edward J. Fewkes, Jr.
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Patent number: 5187230Abstract: Polymer blends useful as thermoplastic molding resins comprise PC, PETG and sufficient rubber, e.g. nitrile rubber or ethylene-acrylate copolymer rubber, to enhance the moldability of the blend. Preferred blends comprise at least 30% PC, 30% PETG and 5% rubber.Type: GrantFiled: August 7, 1991Date of Patent: February 16, 1993Assignee: Monsanto CompanyInventor: Kishore Udipi
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Patent number: 5180781Abstract: The process for the production of an alloy of cross-linked or partially cross-linked rubbers and aromatic polyesters basically consists of reacting a mixture of a rubber latex and an aqueous solution of an alkali metal or alkaline earth metal diphenolate with a solution of a dicarboxylic acid halide and/or a carbonyl halide in a water-immiscible solvent. An aromatic polyester forms at the water/organic solvent phase boundary and goes over into the organic phase. At the same time, the rubber migrates from the aqueous into the organic phase. When the organic phase is separated and the organic solvent removed, the alloy of rubber and oirganic polyester remaining behind is suitable for the production of moulded articles of all kinds.Type: GrantFiled: May 31, 1991Date of Patent: January 19, 1993Assignee: Bayer AktiengesellschaftInventors: Holger Lutjens, Uwe Westeppe, Karl-Erwin Piejko, Christian Lindner
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Patent number: 5179161Abstract: An aromatic polycarbonate resin composition which contains(A) 3-97 parts by weight of an aromatic polycarbonate resin in which the ratio of the phenolic terminal group represented by the following formula I: ##STR1## with respect to the nonphenolic terminal group represented by the following formula II: ##STR2## (in which R.sub.1 and R.sub.2, which may be identical to or different from one another, are selected from a hydrogen atom and alkyl groups containing 20 or fewer carbon atoms which may or may not be substituted with halogen atoms)I/II is 1/19 or higher,(B) 97-3 parts by weight of a polyphenylene ether resin, A+B=100 parts by weight, and(C) 0.5 to 100 parts by weight, with respect to 100 parts by weight of the combined weights of (A) and (B), of a styrene copolymer which has an epxoy or oxazoline group.Type: GrantFiled: December 13, 1990Date of Patent: January 12, 1993Assignee: General Electric CompanyInventors: Akihiro Saito, Hideyuki Itoi, Yumiko Yoshida, Kazunari Inoue
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Patent number: 5177145Abstract: A thermoplastic molding composition comprising a polycarbonate resin and ABS is rendered improved levels of resistance to gasoline environment and thermal stability upon the incorporation therewith of a particular vinyl copolymer.Type: GrantFiled: February 11, 1991Date of Patent: January 5, 1993Assignee: Bayer AktiengesellschaftInventors: Ralf Dujardin, Jochen Schoeps, Martin Wandel
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Patent number: 5162434Abstract: The thermoplastic block copolymers according to the invention of optionally substituted vinyl or vinylidene polymer segments and segments of liquid crystalline polymers are suitable for use as compatibility improvers or dispersing agents in otherwise incompatible or poorly compatible thermoplastic polymer mixtures and may be used for the production of moulded articles, filaments, fibres and films.Type: GrantFiled: August 7, 1990Date of Patent: November 10, 1992Assignee: Bayer AktiengesellschaftInventors: Harald Pielartzik, Kurt P. Meurer, Rolf-Volker Meyer, Joseph W. Witte, deceased, by Klaus G. Witte, heir
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Patent number: 5159015Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether, one or more polyesters and a styrene polymer with side chains consisting entirely or partly of cyclic imino ether groups. The polymer mixtures have good properties, in particular a good impact strength in combination with good flow properties and a good chemical resistance.Type: GrantFiled: December 20, 1990Date of Patent: October 27, 1992Assignee: General Electric CompanyInventors: Wilhelmus J. L. A. Hamersma, Roger W. Avakian, Christian M. E. Bailly
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Patent number: 5137971Abstract: A process for producing a graft copolymer is disclosed. The graft copolymer, based on a rubber which contains phenolic OH groups and grafted with polycarbonate chains is produced under the conditions of the two-phase interfacial polycondensation. Also disclosed are gasoline resistant thermoplastic polycarbonate compositions containing the graft.Type: GrantFiled: January 31, 1991Date of Patent: August 11, 1992Assignee: Bayer AktiengesellschaftInventors: Ralf Dujardin, Richard Weider, Peter Horlacher, Werner Nouvertne
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Patent number: 5134194Abstract: Thermoplastic resin composition comprising the following components A and B is presented which improves the compatibility of component resins, to achieve a thermoplastic resin having excellent molding property and mechanical strength:A. 90 to 10 wt % of a polyolefin resin containing a substituted silyl group represented by general formula;--SiR.sub.n Y.sub.3-n(wherein, R is aliphatic hydrocarbon group; Y is hydrolyzable group or hydroxyl group; n represents 0, 1 or 2), andB. 10 to 90 wt % of saturated polyester resin or hydroxyalkylated polycarbonate resin or hydroxyalkylated polyphenylene ether resin.Type: GrantFiled: January 23, 1991Date of Patent: July 28, 1992Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Takayuki Inoue, Yusuke Arashiro, Shin-ichi Yamauchi, Michiharu Kihira, Haruo Ohmura, Fumiyoshi Yamada
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Patent number: 5116906Abstract: Disclosed is a thermoplastic resin composition which is improved in compatibility between polyphenylene ether and thermoplastic polyester and is excellent in processability, solvent resistance, and impact strength.This composition comprises:100 parts by weight of a composition comprising (A) 5-95% by weight of a polyphenylene ether and (B) 95-5% by weight of a thermoplastic polyester,(C) 0.5-100 parts by weight of an aromatic polycarbonate resin,(D) 0-50 parts by weight of a rubber-like polymer, and(E) 0.01-10 parts by weight of an amino resin obtained by modifying with an alcohol an addition reaction product of formaldehyde and at least one compound selected from the group consisting of melamine, guanamine and urea.Type: GrantFiled: February 8, 1990Date of Patent: May 26, 1992Assignee: Sumitomo Chemical Co., Ltd.Inventors: Yukio Mizuno, Takashi Maruyama
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Patent number: 5112913Abstract: The subject invention relates to the polyester compositions being composed of (a) an aromatic polyester having the relative viscosity of 1.2 to 2.0, (b) an aromatic polycarbonate having the number average molecular weight of 10,000 to 80,000, and (c) a glycidyl-group containing copolymer consisting essentially of .alpha.-olefine and glycidyl ester of .alpha.,.beta.-ethylenically unsaturated carboxylic acid and having the melt index of 0.1 to 100. They are useful for manufacturing electric, electronic and automotive parts, being superior in flow property and melt stability on molding, as well as in mechanical properties particularly in impact and hot-air aging resistance. The compositions can be molded to form various articles by conventional molding methods.Type: GrantFiled: July 26, 1990Date of Patent: May 12, 1992Assignee: Toray Industries, Inc.Inventors: Kenjiro Horiuchi, Kiichi Kometani, Toshihide Inoue
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Patent number: 5106907Abstract: A four-component blend of an aromatic carbonate polymer, a styrene-acrylonitrile copolymer, a methacrylate-diene-styrene shell-core copolymer and polybutylene terephthalate exhibits good shear thinning characteristics and weldline strength, as well as other favorable mechanical properties.Type: GrantFiled: July 10, 1990Date of Patent: April 21, 1992Assignee: General Electric CompanyInventor: Omar M. Boutni
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Patent number: 5104934Abstract: Polymer blends useful as thermoplastic molding resins comprise polycarbonate, PETG and ABS or ASA exhibit enhanced moldability, heat resistance and thick section impact resistance not available in binary blends of the components.Type: GrantFiled: August 12, 1991Date of Patent: April 14, 1992Assignee: Monsanto CompanyInventor: Kishore Udipi
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Patent number: 5104723Abstract: Mixtures containinga) thermoplastic polycarbonates based on diphenols corresponding to formula (I) ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl and c.sub.7 -C.sub.12 aralkyl,m is an integer of from 4 to 7,R.sup.3 and R.sup.4 may be individually selected for each X and independently of one another represent hydrogen or C.sub.1 -C.sub.6 alkyl andX represents carbon, with the proviso that, at at least one atom X, both R.sup.3 and R.sup.4 are alkyl, andb) elastomers or other thermoplastics than those of component a) and, optionally,c) standard additives,processes for their preparation, and the use thereof for the production of films.Type: GrantFiled: October 3, 1989Date of Patent: April 14, 1992Assignee: Bayer AktiengesellschaftInventors: Dieter Freitag, Uwe Westeppe, Kurt Weirauch, Gunther Weymans
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Patent number: 5100974Abstract: Blends of aromatic polycarbonate, alkylnaphthalene-formaldehyde condensation product and an impact modifier produce easy-flow, tough, stiff thermoplastics. The thermoplastics can be used to injection mold thin-walled housings for electronic circuits.Type: GrantFiled: December 4, 1990Date of Patent: March 31, 1992Assignee: General Electric CompanyInventor: Roger P. Kambour
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Patent number: 5100960Abstract: The invention relates to a thermoplastic molding composition comprising(A) from 10 to 98 parts by weight of a polydiorganosiloxane-polycarbonate block copolymer having a weight average molecular weight of from 10,000 to 200,000 and containing from 75 to 97.5 wt. % of aromatic carbonate structural units and from 25 to 2.5 wt. % of polydiorganosiloxane structural units;(B) from 2 to 90 parts by weight of a thermoplastic, aromatic polycarbonate having a weight average molecular weight of at least 10,000, andcontaining bifunctional carbonate structural units corresponding to ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.12 aralkyl;m represents an integer of from 4 to 7,R.sup.3 and R.sup.4, which may be selected individually for each X, independently represent hydrogen or C.sub.1 -C.sub.6 alkyl; andx represents carbon,with the proviso that, on at least one atom X, R.sup.3 and R.sup.Type: GrantFiled: March 12, 1990Date of Patent: March 31, 1992Assignee: Bayer AktiengesellschaftInventors: Ulrich Grigo, Peter Horlacher, Dieter Freitag, Karsten-Josef Idel, Uwe Westeppe, Wolfgang Beer, Werner Nouvertne
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Patent number: 5094806Abstract: A process of blow molding, and compositions useful in the process. The articles are blow molded from compositions formed from thermoplastic polymeric material, a fluorinated olefinic polymer or copolymer and, optionally, an elastomeric impact modifier.Type: GrantFiled: November 6, 1989Date of Patent: March 10, 1992Assignee: The Dow Chemical CompanyInventor: Michael K. Laughner
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Patent number: 5087524Abstract: A molding composition comprising a polycarbonate resin and plating modifier was found to be suitable for preparing metal coated articles where the metal coating is deposited by an electroless process. The plating modifier in accordance with the invention is at least one member selected from the group consisting of a polyanhydride, and a monovinyl aromatic-acrylonitrile copolymer. An advantageous embodiment of the invention includes incorporating in the molding composition a flame retarding amount of a conventional flame retarding agent for polycarbonate compositions.Type: GrantFiled: May 4, 1990Date of Patent: February 11, 1992Assignee: Mobay CorporationInventors: Sivaram Krishnan, Ronald L. Price, Peter H. C. Shu, Mark W. Witman
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Patent number: 5087665Abstract: It was surprisingly found that a thermoplastic molding composition which contains polycarbonate and polyalkylene terephthalate resins at a particular weight ratio therebetween is rendered improved impact strength and hydrolysis resistance upon the incorporation of an additive amount of high melt flow high density polyethylene therewith. The molding composition of the invention comprise about 20-90 percent of polycarbonate resin, 80-10 percent of polyalkylene terephthalate (preferably PET) and about 3 to 5 percent of a high density polyethylene resin having a specific gravity of 0.94-0.97 and melt flow of 1 to 80 gm/10 min. as determined in accordance with ASTM D 1238.Type: GrantFiled: December 20, 1989Date of Patent: February 11, 1992Assignee: Mobay CorporationInventors: James Y. J. Chung, John J. Charles, Nelson R. Lazear
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Patent number: 5082897Abstract: Polymer blends useful as thermoplastic molding resins comprise polycarbonate, PCTG and ABS or ASA and exhibit enhanced moldability, heat resistance and thick section toughness not available in binary blends of the components.Type: GrantFiled: December 15, 1989Date of Patent: January 21, 1992Assignee: Monsanto CompanyInventor: Kishore Udipi
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Patent number: 5081184Abstract: Impact- and solvent-resistant resin blends are prepared from a polyphenylene ether or blend thereof with a polystyrene, a linear polyester such as a poly(alkylene dicarboxylate), at least one polymer containing a substantial proportion of aromatic polycarbonate units as a compatibilizing agent, and, preferably, at least one elastomeric polyphenylene ether-compatible impact modifier. There may also be present a minor amount of at least one epoxide and/or masked isocyanate such as triglycidyl isocyanurate or a glycidyl methacrylate polymer. The polyphenylene ether preferably has a low proportion of unneutralized amino nitrogen, if any.Type: GrantFiled: May 22, 1989Date of Patent: January 14, 1992Assignee: General Electric CompanyInventors: Sterling B. Brown, Dennis J. McFay, John B. Yates, III, Gim F. Lee
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Patent number: 5077338Abstract: A method of preparing a fiber reinforced elastomer by forming fibers therein in-situ and an elastomer made thereby are provided. In the method, a fiber forming material, preferably a high performance polymer, is dissolved in a compatible solvent to form a solvent/polymer mixture, and the mixture is added to the elastomer during compounding or mixing. The polymer is quickly dispersed into the elastomer, and the solvent rapidly evaporates. The shear of the mixer causes elongation of the polymer into fibers. The fibers may also be oriented by the shear of the mixer.Type: GrantFiled: August 23, 1990Date of Patent: December 31, 1991Assignee: The Goodyear Tire & Rubber CompanyInventors: William C. T. Tung, Deborah A. Tung, Mellis M. Kelley, Douglas C. Callander, 1
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Patent number: 5066717Abstract: This invention relates to thermostable thermoplastic moulding compounds consisting of a thermoplastic aromatic polycarbonate resin, a graft polymer and optionally a thermoplastic vinyl polymer wherein the graft or vinyl polymer is emulsion polymerized with an emulsifier which is the reaction product of 2 mols of certain carboxylic anhydrides and 1 mole of certain diols.Type: GrantFiled: April 20, 1990Date of Patent: November 19, 1991Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Dieter Wittmann, Adolf Schmidt, Karl-Heinz Ott
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Patent number: 5061754Abstract: A polycarbonate composition having present therein particles of rubber grafted with an ethylenically unsaturated aromatic monomer and either acrylonitrile or methacrylonitrile, characterized in that the particles have an average size of from 20 to 300 nm before being blended with the polycarbonate and agglomerate during blending to form aggregates of average size 500 to 10,000 nm, and in that the composition can be injection moulded to produce a moulding wherein the aggregates substantially retain their identity and the moulding has a surface of matt appearance.Type: GrantFiled: November 27, 1989Date of Patent: October 29, 1991Assignee: Monsanto Europe S.A.Inventors: Daniel L. Dufour, Jean Pierre
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Patent number: 5055523Abstract: An aromatic polycarbonate composition contains aromatic polycarbonate in which a ratio of the phenolic end group to the non-phenolic end group is at least 1/19, and a copolymer having epoxy or oxazolinyl group, aromatic vinyl-diene-vinyl cyanide copolymer or aromatic polyester, or glass filler. Compatability between the specific aromatic polycarbonate and the other resin, weld strength, melt stability or adhesion to glass filler are improved.Type: GrantFiled: March 15, 1990Date of Patent: October 8, 1991Assignee: CE Plastics Japan LimitedInventors: Kazushige Inoue, Akhiro Saito, Takorou Kitamura, Takashi Ohtomo, Hidenori Tazaki, Tetsuji Kodaira, Yumiko Yoshida, Hiromi Ishida, Takahiro Yokoshima, Hideyuki Itoi
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Patent number: 5049615Abstract: Novel thermoplastic compositions are provided comprising a blend of a polyindane resin and an engineering thermoplastic such as polyphenylene ethers, polysulfones, polycarbonates, polyether ether ketones, polyarylates, polyamides, polyimides and polyphenylene sulfides. Blends of thermoplastic block copolymers with polyindane resins are also provided. These blends provide improved processability with good physical properties including high impact strength and high heat distortion temperature.Type: GrantFiled: December 11, 1989Date of Patent: September 17, 1991Assignee: Hercules IncorporatedInventors: Sung G. Chu, Birendra K. Patnaik, Keith S. Shih
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Patent number: 5049619Abstract: Two-component polymeric compositions having two interconnected solid phases, and exhibiting spinodal decomposition morphology at the domain boundaries are shown, as are methods for forming the same. The compositions are prepared from two different polymers one of which possesses ductility in that it shows substantial yield behavior under tensile stressing, the other being brittle, exhibiting no such behavior; thermoplastic polymers, in conjunction with thermotropic liquid crystalline materials, exemplify such systems. The desired morphology is created by preparing the two component compositions in a single solid phase below the lower critical solution temperature of the compositions, and thereafter heating the compositions above such temperature to form a two-phase system.Type: GrantFiled: April 14, 1989Date of Patent: September 17, 1991Assignee: Edison Polymer Innovation CorporationInventor: Thein Kyu
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Patent number: 5043400Abstract: A method for producing articles of composite resin, wherein a liquid crystal polymer material in powder form is mixed with a second, melt-processable polymer material; the resulting mixture is kneaded at a temperature at which the second polymer material will melt but at which no deformation of the liquid crystal polymer will be caused so as to prepare a blend comprising the liquid crystal polymer powder uniformly dispersed in the matrix of the second polymer; and the blend is then subjected to a molding or shaping process at a temperature within the range at which the liquid crystal polymer is capable of forming liquid crystals.Type: GrantFiled: January 23, 1991Date of Patent: August 27, 1991Assignee: Tosoh CorporationInventors: Akeharu Tsuruta, Hisato Kawaguchi, Tomohiro Ishikawa, Yozo Kondo
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Patent number: 5043200Abstract: A resin composition comprising (A) from 10 to 90% by weight of a styrene resin; (B) from 10 to 90% by weight of a thermoplastic polyester resin; (C) from 1 to 80% by weight of an aromatic polycarbonate resin; and (D) from 1 to 80% by weight of an ethylene-ethyl acrylate copolymer resin.Type: GrantFiled: December 8, 1989Date of Patent: August 27, 1991Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Kazuhiro Kobayashi, Hifumi Kouguthi, Toshio Hara
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Patent number: 5041493Abstract: A moldable polyblend of an aromatic polycarbonate, a polyester of an aromatic dicarboxylic acid, an elastomeric rubber, and a polylactone, which polylactone is present within the range of from about 1.0 to about 10 weight % of the polyblend.Type: GrantFiled: November 16, 1989Date of Patent: August 20, 1991Assignee: Enichem Americas, Inc.Inventors: Kavilipalayam M. Natarajan, Robert Mininni
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Patent number: 5034458Abstract: Aromatic polycarbonates having weight average molecular weight M.sub.w of at least 10,000 which contain bifunctional carbonate structural units corresponding to general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently represent hydrogen, C.sub.1 -C.sub.12 hdyrocarbon or halogen radicals; andR.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 independently represent hydrogen or C.sub.1 -C.sub.12 hydrocarbon radicals, one or R.sup.5 and R.sup.9 representing hydrogen and the other C.sub.1 -C.sub.12 hydrocarbon radical;in amounts of from 100 to 1 mole % based on the total amount of difunctional carbonate structural units in the polycarbonate were found to be useful for thermoplast processing of compositions which are characterized by their improved toughness and high heat deflection temperature.Type: GrantFiled: August 9, 1990Date of Patent: July 23, 1991Assignee: Bayer AktiengesellschaftInventors: Volker Serini, Dieter Freitag, Karsten-Josef Idel, Ulrich Grigo
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Patent number: 5034457Abstract: Thermoplastic blends ofA) 1 to 99% by weight of at least one thermoplastic aromatic polycarbonate which contains difunctional carbonate structural units of the formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are hydrogen, a C.sub.1 -C.sub.12 -hydrocarbon radical or halogen and R.sup.5, R.sup.6 and R.sup.7 independently of one another are H or a hydrocarbon radical, with the proviso that at least one of the radicals R.sup.5, R.sup.6 and R.sup.7 is a hydrocarbon radical, that when only one of the radicals R.sup.5, R.sup.6 or R.sup.7 is present as a hydrocarbon radical this is a C.sub.3 -C.sub.12 -hydrocarbon radical with the exception of C.sub.3 -C.sub.12 -n-alkyl, and that when two or three radicals R.sup.5, R.sup.6 and R.sup.7 are present as hydrocarbon radicals these are any C.sub.1 -C.sub.Type: GrantFiled: March 6, 1990Date of Patent: July 23, 1991Assignee: Bayer AktiengesellschaftInventors: Volker Serini, Dieter Freitag, Karsten Idel, Ulrich Grigo
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Patent number: 5030675Abstract: Flame-resistant molding compounds of polycarbonate, polyalkylene terephthalate, graft polymer, fluorinated polyolefine and phosphorus compound can be worked up into moulded products which have a particularly advantageous combination of joint line strength, dimensional stability under heat and toughness.Type: GrantFiled: December 13, 1989Date of Patent: July 9, 1991Assignee: Bayer AktiengesellschaftInventors: Dieter Wittmann, Hans-Jurgen Kress, Horst Peters, Josef Buekers, Christian Lindner
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Patent number: 5030693Abstract: Triazine compounds are prepared by the reaction of a bisphenol or a hydroxy-terminated polycarbonate with a chlorocyanurate containing epoxy and/or aromatic substituents. The compounds derived from bisphenols or protected bisphenols may be converted to polycarbonates, which form copolymers with other polymers containing acid or amine groups or derivatives thereof.Type: GrantFiled: March 19, 1990Date of Patent: July 9, 1991Assignee: General Electric CompanyInventors: Sterling B. Brown, Ronald J. Gambale, Linda L. McCracken
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Patent number: 5026792Abstract: The present invention provides a resin composition which is a composition of 30 to 99.5 wt. % of an aromatic polycarbonate and 70 to 0.5 wt. % of a vinylidene fluoride-hexafluoroacetone copolymeric elastomer.This resin composition is excellent in moldability and processability, heat resistance and impact resistance, and useful as an engineering plastic.Type: GrantFiled: March 7, 1990Date of Patent: June 25, 1991Assignee: Teijin Chemicals, Ltd.Inventors: Saburo Akiyama, Naoyuki Murakami, Kazuo Kitamura
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Patent number: 5026777Abstract: Thermoplastic molding compositions having an inherent matte or low gloss surface finish comprise a polymer blend of a polycarbonate and an emulsion grafted ABS polymer, and a low gloss enhancing amount of a poly(epoxide).Type: GrantFiled: November 17, 1989Date of Patent: June 25, 1991Assignee: General Electric CompanyInventors: Ronald L. Jalbert, David O. Phillips
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Patent number: 5023299Abstract: The present invention relates to poly-(C.sub.2 -C.sub.10 -.alpha.-olefine)-carboxylic acids of Mw (weight average) 2000 to 350,000, to their preparation by oxidative degradation of polyolefines or by reaction of "Living" polyolefines with CO.sub.2, to their conversion into poly-(C.sub.2 -C.sub.10 -.alpha.-olefine)-carbonyl halides and to their use for preparing polyolefine/polycarbonate block copolymers and the block copolymers obtainable by the process according to the invention.Type: GrantFiled: February 1, 1990Date of Patent: June 11, 1991Assignee: Bayer AktiengesellschaftInventors: Kurt P. Meuer, Helmut Waniczek, Gerd Sylvester, Josef Witte
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Patent number: 5021504Abstract: A thermoplastic resin composition having well-balanced properties which comprises 95-5 weight % of polycarbonate, 5-95 weight % of polyolefin and a particular combination of additional components selected from a styrene-ethylene.propylene copolymer, a styrene-ethylene. butyrene-styrene block copolymer, an AES resin, a styrene-olefin block copolymer, an unsaturated carboxylic acid-modified polyolefin, polybutylene terephthalate, a styrene-maleic anhydride copolymer, an oxazoline ring-containing styrene copolymer a saponified olefin-vinyl ester copolymer and an epoxy group-containing styrene copolymer.Type: GrantFiled: September 19, 1988Date of Patent: June 4, 1991Assignees: Tonen Sekiyukagaku Kabushiki Kaisha, Toyota Jidosha Kabushiki KaishaInventors: Yuuji Fujita, Tadashi Sezume, Kitsusho Kitano, Kiyotada Narukawa, Takashi Mikami, Tetsuya Kawamura, Shigeru Sato, Takeyoshi Nishio, Toshio Yokoi, Takao Nomura
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Patent number: 5011891Abstract: The present invention relates to compositions comprising at least one elastomer and at least one plastic. The composition can be produced by preparing the elastomer and then blending it with the plastic. The composition can be subjected to an additional step of curing.Type: GrantFiled: August 21, 1990Date of Patent: April 30, 1991Assignee: Exxon Research & Engineering CompanyInventors: Lawrence Spenadel, Joel H. Grosser, Stephen M. Dwyer
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Patent number: 5011889Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether, one or more polyesters and a styrene polymer with side chains consisting entirely or partly of cyclic imino ether groups. The polymer mixtures have good properties, in particular a good impact strength in combination with good flow properties and a good chemical resistance.Type: GrantFiled: November 19, 1987Date of Patent: April 30, 1991Assignee: General Electric Co.Inventors: Wilhelmus Hamersma, Roger W. Avakian, Christian Bailly
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Patent number: 5008333Abstract: Thermoplastic blends having excellent chemical resistance and improved impact strength are prepared from a polyphenylene ether, a linear polyester such as poly(alkylene dicarboxylate), a polymer containing a substantial proportion or aromatic polycarbonate units, and property improving amounts of an alkylene acrylate copolymer.Type: GrantFiled: June 13, 1988Date of Patent: April 16, 1991Assignee: General Electric Co.Inventors: John B. Yates, III, Gim F. Lee, Jr.
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Patent number: 4994526Abstract: Block copolymers which include polyisobutylene chain moieties of the formula: ##STR1## wherein n is an integer such that the moiety has a molecular weight contribution of from 5,000 to 30,000 Daltons as determined by gel permeation chromatography are obtained by block copolymerization of appropriate compounds of the formula: ##STR2## wherein n is as defined above and X represents hydroxyl, halogen or alkoxy, with polycarbonates, polyesters, polyamides, poly(ester-amides), polyarylates, polyetherimides or monomer precursors thereof. The block copolymers are useful thermoplastic molding compositions.Type: GrantFiled: March 24, 1989Date of Patent: February 19, 1991Assignee: General Electric CompanyInventor: Edward N. Peters
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Patent number: 4988748Abstract: The invention relates to thermoplastic polycarbonate molding compounds containing polycarbonates, copolymers, phosphorus compounds, tetrafluoroethylene polymers and, optionally, graft polymers and also further additives and other thermoplastics and also stabilizers, pigments, flow aids, mold release agents, antistatic agents and/or other flameproffing agents, characterized in that they contain as phosphorus compounds those corresponding to formula (I) ##STR1## and to a process for the production of the polycarbonate molding compounds.Type: GrantFiled: July 10, 1989Date of Patent: January 29, 1991Assignee: Bayer AktiengesellschaftInventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott, Hans-Dieter Block, Bernd Urbanneck, Werner Ballas
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Patent number: 4985494Abstract: A thermoplastic molding composition comprising 70 to 98 parts of an aromatic polycarbonate having a viscosity number of from 40 to 100 cm.sup.3 /g and 2 to 30 parts of a polyoctenylene or a modified polyoctenylene.Type: GrantFiled: February 21, 1990Date of Patent: January 15, 1991Assignee: Huels AktiengesellschaftInventors: Ralf Schueler, Joachim Muegge, Michael Droescher, Wilfried Bartz, Roland Feinauer
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Patent number: 4983658Abstract: The present invention relates to thermoplastic moulding compositions which are provided with a flame-repellent finish by adding phosph(on)ate esters, tetrafluoroethylene polymers and, if appropriate, halogen compounds.Type: GrantFiled: March 27, 1989Date of Patent: January 8, 1991Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Heremann Kauth, Horst Peters, Christian Lindner, Friedemann Muller
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Patent number: 4973626Abstract: Polybend interdispersions of two or more different polymers formed at least partially in the presence of an interdispersing aid which can be polytetrafluoroethylene or ultra high molecular weight polyethylene; said blend can be chemically cross-linked with peroxides.Type: GrantFiled: March 20, 1990Date of Patent: November 27, 1990Inventors: Edward V. Wilkus, Alexander F. Wu
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Patent number: 4959411Abstract: Carboxy-functionalized polycarbonates are prepared by incorporating a carboxylic acid-substituted phenol, preferably t-butyl p-hydroxybenzoate, as a chainstopper in a polycarbonate-forming reaction. The products are capable of forming copolymers with other polymers such as polyamides and functionalized olefin polymers, by generation of a carboxy group which reacts therewith.Type: GrantFiled: December 27, 1988Date of Patent: September 25, 1990Assignee: General Electric CompanyInventors: Ronald J. Gambale, Susan J. Hathaway, Kathryn L. Longley, Timothy J. Ullman