With A -o-c(=o)-o-, -o-c(=o)-hal Or Hal-c(=o)-hal Group-containing Reactant Or Polymer Thereof Patents (Class 525/146)
  • Patent number: 5189091
    Abstract: A polycarbonate blend of good impact strength, solvent resistance and weldline properties is prepared by admixing with polycarbonate an aromatic polyester, a grafted olefin/carbon monoxide copolymer and, optionally, an elastomeric toughening agent such as a rubber, and, optionally, a filler.
    Type: Grant
    Filed: November 26, 1990
    Date of Patent: February 23, 1993
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5187230
    Abstract: Polymer blends useful as thermoplastic molding resins comprise PC, PETG and sufficient rubber, e.g. nitrile rubber or ethylene-acrylate copolymer rubber, to enhance the moldability of the blend. Preferred blends comprise at least 30% PC, 30% PETG and 5% rubber.
    Type: Grant
    Filed: August 7, 1991
    Date of Patent: February 16, 1993
    Assignee: Monsanto Company
    Inventor: Kishore Udipi
  • Patent number: 5180781
    Abstract: The process for the production of an alloy of cross-linked or partially cross-linked rubbers and aromatic polyesters basically consists of reacting a mixture of a rubber latex and an aqueous solution of an alkali metal or alkaline earth metal diphenolate with a solution of a dicarboxylic acid halide and/or a carbonyl halide in a water-immiscible solvent. An aromatic polyester forms at the water/organic solvent phase boundary and goes over into the organic phase. At the same time, the rubber migrates from the aqueous into the organic phase. When the organic phase is separated and the organic solvent removed, the alloy of rubber and oirganic polyester remaining behind is suitable for the production of moulded articles of all kinds.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: January 19, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Holger Lutjens, Uwe Westeppe, Karl-Erwin Piejko, Christian Lindner
  • Patent number: 5179161
    Abstract: An aromatic polycarbonate resin composition which contains(A) 3-97 parts by weight of an aromatic polycarbonate resin in which the ratio of the phenolic terminal group represented by the following formula I: ##STR1## with respect to the nonphenolic terminal group represented by the following formula II: ##STR2## (in which R.sub.1 and R.sub.2, which may be identical to or different from one another, are selected from a hydrogen atom and alkyl groups containing 20 or fewer carbon atoms which may or may not be substituted with halogen atoms)I/II is 1/19 or higher,(B) 97-3 parts by weight of a polyphenylene ether resin, A+B=100 parts by weight, and(C) 0.5 to 100 parts by weight, with respect to 100 parts by weight of the combined weights of (A) and (B), of a styrene copolymer which has an epxoy or oxazoline group.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: January 12, 1993
    Assignee: General Electric Company
    Inventors: Akihiro Saito, Hideyuki Itoi, Yumiko Yoshida, Kazunari Inoue
  • Patent number: 5177145
    Abstract: A thermoplastic molding composition comprising a polycarbonate resin and ABS is rendered improved levels of resistance to gasoline environment and thermal stability upon the incorporation therewith of a particular vinyl copolymer.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: January 5, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ralf Dujardin, Jochen Schoeps, Martin Wandel
  • Patent number: 5162434
    Abstract: The thermoplastic block copolymers according to the invention of optionally substituted vinyl or vinylidene polymer segments and segments of liquid crystalline polymers are suitable for use as compatibility improvers or dispersing agents in otherwise incompatible or poorly compatible thermoplastic polymer mixtures and may be used for the production of moulded articles, filaments, fibres and films.
    Type: Grant
    Filed: August 7, 1990
    Date of Patent: November 10, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Pielartzik, Kurt P. Meurer, Rolf-Volker Meyer, Joseph W. Witte, deceased, by Klaus G. Witte, heir
  • Patent number: 5159015
    Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether, one or more polyesters and a styrene polymer with side chains consisting entirely or partly of cyclic imino ether groups. The polymer mixtures have good properties, in particular a good impact strength in combination with good flow properties and a good chemical resistance.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: October 27, 1992
    Assignee: General Electric Company
    Inventors: Wilhelmus J. L. A. Hamersma, Roger W. Avakian, Christian M. E. Bailly
  • Patent number: 5137971
    Abstract: A process for producing a graft copolymer is disclosed. The graft copolymer, based on a rubber which contains phenolic OH groups and grafted with polycarbonate chains is produced under the conditions of the two-phase interfacial polycondensation. Also disclosed are gasoline resistant thermoplastic polycarbonate compositions containing the graft.
    Type: Grant
    Filed: January 31, 1991
    Date of Patent: August 11, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ralf Dujardin, Richard Weider, Peter Horlacher, Werner Nouvertne
  • Patent number: 5134194
    Abstract: Thermoplastic resin composition comprising the following components A and B is presented which improves the compatibility of component resins, to achieve a thermoplastic resin having excellent molding property and mechanical strength:A. 90 to 10 wt % of a polyolefin resin containing a substituted silyl group represented by general formula;--SiR.sub.n Y.sub.3-n(wherein, R is aliphatic hydrocarbon group; Y is hydrolyzable group or hydroxyl group; n represents 0, 1 or 2), andB. 10 to 90 wt % of saturated polyester resin or hydroxyalkylated polycarbonate resin or hydroxyalkylated polyphenylene ether resin.
    Type: Grant
    Filed: January 23, 1991
    Date of Patent: July 28, 1992
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Takayuki Inoue, Yusuke Arashiro, Shin-ichi Yamauchi, Michiharu Kihira, Haruo Ohmura, Fumiyoshi Yamada
  • Patent number: 5116906
    Abstract: Disclosed is a thermoplastic resin composition which is improved in compatibility between polyphenylene ether and thermoplastic polyester and is excellent in processability, solvent resistance, and impact strength.This composition comprises:100 parts by weight of a composition comprising (A) 5-95% by weight of a polyphenylene ether and (B) 95-5% by weight of a thermoplastic polyester,(C) 0.5-100 parts by weight of an aromatic polycarbonate resin,(D) 0-50 parts by weight of a rubber-like polymer, and(E) 0.01-10 parts by weight of an amino resin obtained by modifying with an alcohol an addition reaction product of formaldehyde and at least one compound selected from the group consisting of melamine, guanamine and urea.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: May 26, 1992
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Yukio Mizuno, Takashi Maruyama
  • Patent number: 5112913
    Abstract: The subject invention relates to the polyester compositions being composed of (a) an aromatic polyester having the relative viscosity of 1.2 to 2.0, (b) an aromatic polycarbonate having the number average molecular weight of 10,000 to 80,000, and (c) a glycidyl-group containing copolymer consisting essentially of .alpha.-olefine and glycidyl ester of .alpha.,.beta.-ethylenically unsaturated carboxylic acid and having the melt index of 0.1 to 100. They are useful for manufacturing electric, electronic and automotive parts, being superior in flow property and melt stability on molding, as well as in mechanical properties particularly in impact and hot-air aging resistance. The compositions can be molded to form various articles by conventional molding methods.
    Type: Grant
    Filed: July 26, 1990
    Date of Patent: May 12, 1992
    Assignee: Toray Industries, Inc.
    Inventors: Kenjiro Horiuchi, Kiichi Kometani, Toshihide Inoue
  • Patent number: 5106907
    Abstract: A four-component blend of an aromatic carbonate polymer, a styrene-acrylonitrile copolymer, a methacrylate-diene-styrene shell-core copolymer and polybutylene terephthalate exhibits good shear thinning characteristics and weldline strength, as well as other favorable mechanical properties.
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: April 21, 1992
    Assignee: General Electric Company
    Inventor: Omar M. Boutni
  • Patent number: 5104723
    Abstract: Mixtures containinga) thermoplastic polycarbonates based on diphenols corresponding to formula (I) ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl and c.sub.7 -C.sub.12 aralkyl,m is an integer of from 4 to 7,R.sup.3 and R.sup.4 may be individually selected for each X and independently of one another represent hydrogen or C.sub.1 -C.sub.6 alkyl andX represents carbon, with the proviso that, at at least one atom X, both R.sup.3 and R.sup.4 are alkyl, andb) elastomers or other thermoplastics than those of component a) and, optionally,c) standard additives,processes for their preparation, and the use thereof for the production of films.
    Type: Grant
    Filed: October 3, 1989
    Date of Patent: April 14, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Freitag, Uwe Westeppe, Kurt Weirauch, Gunther Weymans
  • Patent number: 5104934
    Abstract: Polymer blends useful as thermoplastic molding resins comprise polycarbonate, PETG and ABS or ASA exhibit enhanced moldability, heat resistance and thick section impact resistance not available in binary blends of the components.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: April 14, 1992
    Assignee: Monsanto Company
    Inventor: Kishore Udipi
  • Patent number: 5100960
    Abstract: The invention relates to a thermoplastic molding composition comprising(A) from 10 to 98 parts by weight of a polydiorganosiloxane-polycarbonate block copolymer having a weight average molecular weight of from 10,000 to 200,000 and containing from 75 to 97.5 wt. % of aromatic carbonate structural units and from 25 to 2.5 wt. % of polydiorganosiloxane structural units;(B) from 2 to 90 parts by weight of a thermoplastic, aromatic polycarbonate having a weight average molecular weight of at least 10,000, andcontaining bifunctional carbonate structural units corresponding to ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.12 aralkyl;m represents an integer of from 4 to 7,R.sup.3 and R.sup.4, which may be selected individually for each X, independently represent hydrogen or C.sub.1 -C.sub.6 alkyl; andx represents carbon,with the proviso that, on at least one atom X, R.sup.3 and R.sup.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: March 31, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Grigo, Peter Horlacher, Dieter Freitag, Karsten-Josef Idel, Uwe Westeppe, Wolfgang Beer, Werner Nouvertne
  • Patent number: 5100974
    Abstract: Blends of aromatic polycarbonate, alkylnaphthalene-formaldehyde condensation product and an impact modifier produce easy-flow, tough, stiff thermoplastics. The thermoplastics can be used to injection mold thin-walled housings for electronic circuits.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: March 31, 1992
    Assignee: General Electric Company
    Inventor: Roger P. Kambour
  • Patent number: 5094806
    Abstract: A process of blow molding, and compositions useful in the process. The articles are blow molded from compositions formed from thermoplastic polymeric material, a fluorinated olefinic polymer or copolymer and, optionally, an elastomeric impact modifier.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: March 10, 1992
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5087524
    Abstract: A molding composition comprising a polycarbonate resin and plating modifier was found to be suitable for preparing metal coated articles where the metal coating is deposited by an electroless process. The plating modifier in accordance with the invention is at least one member selected from the group consisting of a polyanhydride, and a monovinyl aromatic-acrylonitrile copolymer. An advantageous embodiment of the invention includes incorporating in the molding composition a flame retarding amount of a conventional flame retarding agent for polycarbonate compositions.
    Type: Grant
    Filed: May 4, 1990
    Date of Patent: February 11, 1992
    Assignee: Mobay Corporation
    Inventors: Sivaram Krishnan, Ronald L. Price, Peter H. C. Shu, Mark W. Witman
  • Patent number: 5087665
    Abstract: It was surprisingly found that a thermoplastic molding composition which contains polycarbonate and polyalkylene terephthalate resins at a particular weight ratio therebetween is rendered improved impact strength and hydrolysis resistance upon the incorporation of an additive amount of high melt flow high density polyethylene therewith. The molding composition of the invention comprise about 20-90 percent of polycarbonate resin, 80-10 percent of polyalkylene terephthalate (preferably PET) and about 3 to 5 percent of a high density polyethylene resin having a specific gravity of 0.94-0.97 and melt flow of 1 to 80 gm/10 min. as determined in accordance with ASTM D 1238.
    Type: Grant
    Filed: December 20, 1989
    Date of Patent: February 11, 1992
    Assignee: Mobay Corporation
    Inventors: James Y. J. Chung, John J. Charles, Nelson R. Lazear
  • Patent number: 5082897
    Abstract: Polymer blends useful as thermoplastic molding resins comprise polycarbonate, PCTG and ABS or ASA and exhibit enhanced moldability, heat resistance and thick section toughness not available in binary blends of the components.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: January 21, 1992
    Assignee: Monsanto Company
    Inventor: Kishore Udipi
  • Patent number: 5081184
    Abstract: Impact- and solvent-resistant resin blends are prepared from a polyphenylene ether or blend thereof with a polystyrene, a linear polyester such as a poly(alkylene dicarboxylate), at least one polymer containing a substantial proportion of aromatic polycarbonate units as a compatibilizing agent, and, preferably, at least one elastomeric polyphenylene ether-compatible impact modifier. There may also be present a minor amount of at least one epoxide and/or masked isocyanate such as triglycidyl isocyanurate or a glycidyl methacrylate polymer. The polyphenylene ether preferably has a low proportion of unneutralized amino nitrogen, if any.
    Type: Grant
    Filed: May 22, 1989
    Date of Patent: January 14, 1992
    Assignee: General Electric Company
    Inventors: Sterling B. Brown, Dennis J. McFay, John B. Yates, III, Gim F. Lee
  • Patent number: 5077338
    Abstract: A method of preparing a fiber reinforced elastomer by forming fibers therein in-situ and an elastomer made thereby are provided. In the method, a fiber forming material, preferably a high performance polymer, is dissolved in a compatible solvent to form a solvent/polymer mixture, and the mixture is added to the elastomer during compounding or mixing. The polymer is quickly dispersed into the elastomer, and the solvent rapidly evaporates. The shear of the mixer causes elongation of the polymer into fibers. The fibers may also be oriented by the shear of the mixer.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: December 31, 1991
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: William C. T. Tung, Deborah A. Tung, Mellis M. Kelley, Douglas C. Callander, 1
  • Patent number: 5066717
    Abstract: This invention relates to thermostable thermoplastic moulding compounds consisting of a thermoplastic aromatic polycarbonate resin, a graft polymer and optionally a thermoplastic vinyl polymer wherein the graft or vinyl polymer is emulsion polymerized with an emulsifier which is the reaction product of 2 mols of certain carboxylic anhydrides and 1 mole of certain diols.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: November 19, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Dieter Wittmann, Adolf Schmidt, Karl-Heinz Ott
  • Patent number: 5061754
    Abstract: A polycarbonate composition having present therein particles of rubber grafted with an ethylenically unsaturated aromatic monomer and either acrylonitrile or methacrylonitrile, characterized in that the particles have an average size of from 20 to 300 nm before being blended with the polycarbonate and agglomerate during blending to form aggregates of average size 500 to 10,000 nm, and in that the composition can be injection moulded to produce a moulding wherein the aggregates substantially retain their identity and the moulding has a surface of matt appearance.
    Type: Grant
    Filed: November 27, 1989
    Date of Patent: October 29, 1991
    Assignee: Monsanto Europe S.A.
    Inventors: Daniel L. Dufour, Jean Pierre
  • Patent number: 5055523
    Abstract: An aromatic polycarbonate composition contains aromatic polycarbonate in which a ratio of the phenolic end group to the non-phenolic end group is at least 1/19, and a copolymer having epoxy or oxazolinyl group, aromatic vinyl-diene-vinyl cyanide copolymer or aromatic polyester, or glass filler. Compatability between the specific aromatic polycarbonate and the other resin, weld strength, melt stability or adhesion to glass filler are improved.
    Type: Grant
    Filed: March 15, 1990
    Date of Patent: October 8, 1991
    Assignee: CE Plastics Japan Limited
    Inventors: Kazushige Inoue, Akhiro Saito, Takorou Kitamura, Takashi Ohtomo, Hidenori Tazaki, Tetsuji Kodaira, Yumiko Yoshida, Hiromi Ishida, Takahiro Yokoshima, Hideyuki Itoi
  • Patent number: 5049615
    Abstract: Novel thermoplastic compositions are provided comprising a blend of a polyindane resin and an engineering thermoplastic such as polyphenylene ethers, polysulfones, polycarbonates, polyether ether ketones, polyarylates, polyamides, polyimides and polyphenylene sulfides. Blends of thermoplastic block copolymers with polyindane resins are also provided. These blends provide improved processability with good physical properties including high impact strength and high heat distortion temperature.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: September 17, 1991
    Assignee: Hercules Incorporated
    Inventors: Sung G. Chu, Birendra K. Patnaik, Keith S. Shih
  • Patent number: 5049619
    Abstract: Two-component polymeric compositions having two interconnected solid phases, and exhibiting spinodal decomposition morphology at the domain boundaries are shown, as are methods for forming the same. The compositions are prepared from two different polymers one of which possesses ductility in that it shows substantial yield behavior under tensile stressing, the other being brittle, exhibiting no such behavior; thermoplastic polymers, in conjunction with thermotropic liquid crystalline materials, exemplify such systems. The desired morphology is created by preparing the two component compositions in a single solid phase below the lower critical solution temperature of the compositions, and thereafter heating the compositions above such temperature to form a two-phase system.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: September 17, 1991
    Assignee: Edison Polymer Innovation Corporation
    Inventor: Thein Kyu
  • Patent number: 5043400
    Abstract: A method for producing articles of composite resin, wherein a liquid crystal polymer material in powder form is mixed with a second, melt-processable polymer material; the resulting mixture is kneaded at a temperature at which the second polymer material will melt but at which no deformation of the liquid crystal polymer will be caused so as to prepare a blend comprising the liquid crystal polymer powder uniformly dispersed in the matrix of the second polymer; and the blend is then subjected to a molding or shaping process at a temperature within the range at which the liquid crystal polymer is capable of forming liquid crystals.
    Type: Grant
    Filed: January 23, 1991
    Date of Patent: August 27, 1991
    Assignee: Tosoh Corporation
    Inventors: Akeharu Tsuruta, Hisato Kawaguchi, Tomohiro Ishikawa, Yozo Kondo
  • Patent number: 5043200
    Abstract: A resin composition comprising (A) from 10 to 90% by weight of a styrene resin; (B) from 10 to 90% by weight of a thermoplastic polyester resin; (C) from 1 to 80% by weight of an aromatic polycarbonate resin; and (D) from 1 to 80% by weight of an ethylene-ethyl acrylate copolymer resin.
    Type: Grant
    Filed: December 8, 1989
    Date of Patent: August 27, 1991
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuhiro Kobayashi, Hifumi Kouguthi, Toshio Hara
  • Patent number: 5041493
    Abstract: A moldable polyblend of an aromatic polycarbonate, a polyester of an aromatic dicarboxylic acid, an elastomeric rubber, and a polylactone, which polylactone is present within the range of from about 1.0 to about 10 weight % of the polyblend.
    Type: Grant
    Filed: November 16, 1989
    Date of Patent: August 20, 1991
    Assignee: Enichem Americas, Inc.
    Inventors: Kavilipalayam M. Natarajan, Robert Mininni
  • Patent number: 5034458
    Abstract: Aromatic polycarbonates having weight average molecular weight M.sub.w of at least 10,000 which contain bifunctional carbonate structural units corresponding to general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently represent hydrogen, C.sub.1 -C.sub.12 hdyrocarbon or halogen radicals; andR.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 independently represent hydrogen or C.sub.1 -C.sub.12 hydrocarbon radicals, one or R.sup.5 and R.sup.9 representing hydrogen and the other C.sub.1 -C.sub.12 hydrocarbon radical;in amounts of from 100 to 1 mole % based on the total amount of difunctional carbonate structural units in the polycarbonate were found to be useful for thermoplast processing of compositions which are characterized by their improved toughness and high heat deflection temperature.
    Type: Grant
    Filed: August 9, 1990
    Date of Patent: July 23, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Serini, Dieter Freitag, Karsten-Josef Idel, Ulrich Grigo
  • Patent number: 5034457
    Abstract: Thermoplastic blends ofA) 1 to 99% by weight of at least one thermoplastic aromatic polycarbonate which contains difunctional carbonate structural units of the formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are hydrogen, a C.sub.1 -C.sub.12 -hydrocarbon radical or halogen and R.sup.5, R.sup.6 and R.sup.7 independently of one another are H or a hydrocarbon radical, with the proviso that at least one of the radicals R.sup.5, R.sup.6 and R.sup.7 is a hydrocarbon radical, that when only one of the radicals R.sup.5, R.sup.6 or R.sup.7 is present as a hydrocarbon radical this is a C.sub.3 -C.sub.12 -hydrocarbon radical with the exception of C.sub.3 -C.sub.12 -n-alkyl, and that when two or three radicals R.sup.5, R.sup.6 and R.sup.7 are present as hydrocarbon radicals these are any C.sub.1 -C.sub.
    Type: Grant
    Filed: March 6, 1990
    Date of Patent: July 23, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Serini, Dieter Freitag, Karsten Idel, Ulrich Grigo
  • Patent number: 5030693
    Abstract: Triazine compounds are prepared by the reaction of a bisphenol or a hydroxy-terminated polycarbonate with a chlorocyanurate containing epoxy and/or aromatic substituents. The compounds derived from bisphenols or protected bisphenols may be converted to polycarbonates, which form copolymers with other polymers containing acid or amine groups or derivatives thereof.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: July 9, 1991
    Assignee: General Electric Company
    Inventors: Sterling B. Brown, Ronald J. Gambale, Linda L. McCracken
  • Patent number: 5030675
    Abstract: Flame-resistant molding compounds of polycarbonate, polyalkylene terephthalate, graft polymer, fluorinated polyolefine and phosphorus compound can be worked up into moulded products which have a particularly advantageous combination of joint line strength, dimensional stability under heat and toughness.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: July 9, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Wittmann, Hans-Jurgen Kress, Horst Peters, Josef Buekers, Christian Lindner
  • Patent number: 5026777
    Abstract: Thermoplastic molding compositions having an inherent matte or low gloss surface finish comprise a polymer blend of a polycarbonate and an emulsion grafted ABS polymer, and a low gloss enhancing amount of a poly(epoxide).
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: June 25, 1991
    Assignee: General Electric Company
    Inventors: Ronald L. Jalbert, David O. Phillips
  • Patent number: 5026792
    Abstract: The present invention provides a resin composition which is a composition of 30 to 99.5 wt. % of an aromatic polycarbonate and 70 to 0.5 wt. % of a vinylidene fluoride-hexafluoroacetone copolymeric elastomer.This resin composition is excellent in moldability and processability, heat resistance and impact resistance, and useful as an engineering plastic.
    Type: Grant
    Filed: March 7, 1990
    Date of Patent: June 25, 1991
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Saburo Akiyama, Naoyuki Murakami, Kazuo Kitamura
  • Patent number: 5023299
    Abstract: The present invention relates to poly-(C.sub.2 -C.sub.10 -.alpha.-olefine)-carboxylic acids of Mw (weight average) 2000 to 350,000, to their preparation by oxidative degradation of polyolefines or by reaction of "Living" polyolefines with CO.sub.2, to their conversion into poly-(C.sub.2 -C.sub.10 -.alpha.-olefine)-carbonyl halides and to their use for preparing polyolefine/polycarbonate block copolymers and the block copolymers obtainable by the process according to the invention.
    Type: Grant
    Filed: February 1, 1990
    Date of Patent: June 11, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Kurt P. Meuer, Helmut Waniczek, Gerd Sylvester, Josef Witte
  • Patent number: 5021504
    Abstract: A thermoplastic resin composition having well-balanced properties which comprises 95-5 weight % of polycarbonate, 5-95 weight % of polyolefin and a particular combination of additional components selected from a styrene-ethylene.propylene copolymer, a styrene-ethylene. butyrene-styrene block copolymer, an AES resin, a styrene-olefin block copolymer, an unsaturated carboxylic acid-modified polyolefin, polybutylene terephthalate, a styrene-maleic anhydride copolymer, an oxazoline ring-containing styrene copolymer a saponified olefin-vinyl ester copolymer and an epoxy group-containing styrene copolymer.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: June 4, 1991
    Assignees: Tonen Sekiyukagaku Kabushiki Kaisha, Toyota Jidosha Kabushiki Kaisha
    Inventors: Yuuji Fujita, Tadashi Sezume, Kitsusho Kitano, Kiyotada Narukawa, Takashi Mikami, Tetsuya Kawamura, Shigeru Sato, Takeyoshi Nishio, Toshio Yokoi, Takao Nomura
  • Patent number: 5011889
    Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether, one or more polyesters and a styrene polymer with side chains consisting entirely or partly of cyclic imino ether groups. The polymer mixtures have good properties, in particular a good impact strength in combination with good flow properties and a good chemical resistance.
    Type: Grant
    Filed: November 19, 1987
    Date of Patent: April 30, 1991
    Assignee: General Electric Co.
    Inventors: Wilhelmus Hamersma, Roger W. Avakian, Christian Bailly
  • Patent number: 5011891
    Abstract: The present invention relates to compositions comprising at least one elastomer and at least one plastic. The composition can be produced by preparing the elastomer and then blending it with the plastic. The composition can be subjected to an additional step of curing.
    Type: Grant
    Filed: August 21, 1990
    Date of Patent: April 30, 1991
    Assignee: Exxon Research & Engineering Company
    Inventors: Lawrence Spenadel, Joel H. Grosser, Stephen M. Dwyer
  • Patent number: 5008333
    Abstract: Thermoplastic blends having excellent chemical resistance and improved impact strength are prepared from a polyphenylene ether, a linear polyester such as poly(alkylene dicarboxylate), a polymer containing a substantial proportion or aromatic polycarbonate units, and property improving amounts of an alkylene acrylate copolymer.
    Type: Grant
    Filed: June 13, 1988
    Date of Patent: April 16, 1991
    Assignee: General Electric Co.
    Inventors: John B. Yates, III, Gim F. Lee, Jr.
  • Patent number: 4994526
    Abstract: Block copolymers which include polyisobutylene chain moieties of the formula: ##STR1## wherein n is an integer such that the moiety has a molecular weight contribution of from 5,000 to 30,000 Daltons as determined by gel permeation chromatography are obtained by block copolymerization of appropriate compounds of the formula: ##STR2## wherein n is as defined above and X represents hydroxyl, halogen or alkoxy, with polycarbonates, polyesters, polyamides, poly(ester-amides), polyarylates, polyetherimides or monomer precursors thereof. The block copolymers are useful thermoplastic molding compositions.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: February 19, 1991
    Assignee: General Electric Company
    Inventor: Edward N. Peters
  • Patent number: 4988748
    Abstract: The invention relates to thermoplastic polycarbonate molding compounds containing polycarbonates, copolymers, phosphorus compounds, tetrafluoroethylene polymers and, optionally, graft polymers and also further additives and other thermoplastics and also stabilizers, pigments, flow aids, mold release agents, antistatic agents and/or other flameproffing agents, characterized in that they contain as phosphorus compounds those corresponding to formula (I) ##STR1## and to a process for the production of the polycarbonate molding compounds.
    Type: Grant
    Filed: July 10, 1989
    Date of Patent: January 29, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Fuhr, Friedemann Muller, Karl-Heinz Ott, Hans-Dieter Block, Bernd Urbanneck, Werner Ballas
  • Patent number: 4985494
    Abstract: A thermoplastic molding composition comprising 70 to 98 parts of an aromatic polycarbonate having a viscosity number of from 40 to 100 cm.sup.3 /g and 2 to 30 parts of a polyoctenylene or a modified polyoctenylene.
    Type: Grant
    Filed: February 21, 1990
    Date of Patent: January 15, 1991
    Assignee: Huels Aktiengesellschaft
    Inventors: Ralf Schueler, Joachim Muegge, Michael Droescher, Wilfried Bartz, Roland Feinauer
  • Patent number: 4983658
    Abstract: The present invention relates to thermoplastic moulding compositions which are provided with a flame-repellent finish by adding phosph(on)ate esters, tetrafluoroethylene polymers and, if appropriate, halogen compounds.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: January 8, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Jurgen Kress, Heremann Kauth, Horst Peters, Christian Lindner, Friedemann Muller
  • Patent number: 4973626
    Abstract: Polybend interdispersions of two or more different polymers formed at least partially in the presence of an interdispersing aid which can be polytetrafluoroethylene or ultra high molecular weight polyethylene; said blend can be chemically cross-linked with peroxides.
    Type: Grant
    Filed: March 20, 1990
    Date of Patent: November 27, 1990
    Inventors: Edward V. Wilkus, Alexander F. Wu
  • Patent number: 4959411
    Abstract: Carboxy-functionalized polycarbonates are prepared by incorporating a carboxylic acid-substituted phenol, preferably t-butyl p-hydroxybenzoate, as a chainstopper in a polycarbonate-forming reaction. The products are capable of forming copolymers with other polymers such as polyamides and functionalized olefin polymers, by generation of a carboxy group which reacts therewith.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: September 25, 1990
    Assignee: General Electric Company
    Inventors: Ronald J. Gambale, Susan J. Hathaway, Kathryn L. Longley, Timothy J. Ullman
  • Patent number: 4954569
    Abstract: The invention relates to the use of thermoplastic homopolycarbonates of 3,3'-dihydroxydiphenyl ether in quantities of 3% by weight to 30% by weight for modifying filsm of other thermoplastics than the thermoplastic homopolycarbonates of 3,3'-dihydroxydiphenyl ether, to a process for modifying films of these other thermoplastics, to the films obtainable by this process and to mixtures containing the homopolycarbonates mentioned and the other thermoplastics.
    Type: Grant
    Filed: June 26, 1989
    Date of Patent: September 4, 1990
    Inventors: Gunther Weymans, Klaus Berg, Ulrich Grigo, Karsten-Josef Idel, Ludwig Bottenbruch
  • Patent number: 4948839
    Abstract: A composition comprising a modified polyester, said modification being in the additional presence in the backbone of the polyester unsaturated aliphatic diester repeating units, the said modified polyester being covalently bonded to a polyolefin.
    Type: Grant
    Filed: September 12, 1988
    Date of Patent: August 14, 1990
    Assignee: General Electric Company
    Inventors: Christopher M. Hawkins, Robert R. Gallucci
  • Patent number: 4945126
    Abstract: Lubricant systems are provided in which a polyolefin or polyolefin/polytetrafluoroethylene blend functions as a lubricant in a polymer matrix material. The resulting polymer composites containing about 1 to 30 weight percent of the novel lubricant or lubricant blend have greatly improved friction and wear properties, including lower coefficients of friction and increased surface wear resistence. The polyolefin does not remain as discrete, identifiable particles after mixing with the polymer matrix, and has an average molecular weight of less than 500,000.
    Type: Grant
    Filed: February 2, 1987
    Date of Patent: July 31, 1990
    Assignee: ICI Americas Inc.
    Inventors: Jane M. Crosby, John E. Theberge