Phenolic Reactant Contains A Phosphorus Or Sulfur Atom Or With Phosphorus- Or Sulfur-containing Reactant Patents (Class 525/150)
  • Patent number: 4544705
    Abstract: This invention is directed to novel aromatic polyformals comprising from about 5 weight percent to about 95 weight percent of repeating units (I) having the formula ##STR1## and from about 95 weight percent to about 5 weight percent of repeating units (II) having the formula ##STR2## in which the repeating units (I) and the repeating units (II) are connected by interbonding units (III) having the formula--CH.sub.2 -- (III)wherein Y is selected from alkyl groups of 1 to 4 carbon atoms, chlorine or bromine, each z, independently, has a value of from 0 to 4 inclusive, n has a value of 0 or 1, and R.sub.1 is a divalent saturated or unsaturated hydrocarbon radical, O, CO, SO.sub.2, S or a direct bond, with the proviso that when R.sub.1 is SO.sub.2 then repeating unit (II) is not the same as repeating unit (I). The invention is also directed to a process for preparing the novel aromatic polyformals. The aromatic polyformals have utility as molded plastic materials, adhesives, sealants and the like.
    Type: Grant
    Filed: December 21, 1983
    Date of Patent: October 1, 1985
    Assignee: Union Carbide Corporation
    Inventor: Louis M. Maresca
  • Patent number: 4536544
    Abstract: Described are blends of block copolymers of polyphenylene oxides and poly(aryl ether)s, a styrene based polymer or copolymer, and a poly(aryl) ether) and/or a polyphenylene oxide.
    Type: Grant
    Filed: December 22, 1983
    Date of Patent: August 20, 1985
    Assignee: Union Carbide Corporation
    Inventors: Markus Matzner, Donald M. Papuga
  • Patent number: 4536543
    Abstract: Described are novel copolymers of polyphenylene oxides and poly(aryl ether)s. These copolymers are readily compatible with styrene polymers and copolymers and give tough blends.
    Type: Grant
    Filed: September 30, 1983
    Date of Patent: August 20, 1985
    Assignee: Union Carbide Corporation
    Inventors: Markus Matzner, Donald M. Papuga
  • Patent number: 4532286
    Abstract: Compounds of formula I ##STR1## where R.sub.1 and R.sub.2 independently are alpha-branched alkyl of 3 to 8 carbon atoms, R.sub.3 is hydrogen, R.sub.4 is ethylene, 1,3-propylene or 1,4-butylene, and n is 2 or 4 are effective stabilizers for protecting elastomeric or acrylonitrile copolymer compositions or lubricating oil compositions against thermal oxidation and discoloration. 2-Mercaptoethyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate is particularly useful.
    Type: Grant
    Filed: November 3, 1983
    Date of Patent: July 30, 1985
    Assignee: Ciba-Geigy Corporation
    Inventor: Siegfried Rosenberger
  • Patent number: 4529778
    Abstract: A process for preparing aromatic-moiety-containing polymers having modified physical properties is disclosed. Briefly, the process comprises reacting in the presence of a Friedel-Crafts catalyst: (a) a suitable aromatic-moiety containing polymer resin and (b) a homopolymer of .omega.-halo-.alpha.-olefins, or co- or terpolymer of .omega.-halo-.alpha.-olefins with other .alpha.-olefins and/or ethylene.
    Type: Grant
    Filed: September 22, 1983
    Date of Patent: July 16, 1985
    Assignee: Conoco Inc.
    Inventor: Mark L. Shannon
  • Patent number: 4524177
    Abstract: 1,4-Dihydroxynaphthalene, iron compounds and optionally tertiary arylamines prove to be a highly active accelerator/stabilizer system for peroxide-catalyzed ethylenically unsaturated hardenable compounds.
    Type: Grant
    Filed: November 23, 1983
    Date of Patent: June 18, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Kloker, Klaus Kraft
  • Patent number: 4503168
    Abstract: Described herein is cookware made from a select polyarylethersulfone. The cookware can be used in essentially all cooking oven applications. Also described is a composition suitable for making cookware wherein the composition contains greater than 50 weight percent of the polyarylethersulfone.
    Type: Grant
    Filed: May 25, 1983
    Date of Patent: March 5, 1985
    Assignee: Union Carbide Corporation
    Inventor: Tyler F. Hartsing, Jr.
  • Patent number: 4495333
    Abstract: Linear, branched and/or cross-linked block copolymers of poylphenylene oxide and polystyrene obtained using phosphoryl coupling agents is disclosed.
    Type: Grant
    Filed: November 28, 1983
    Date of Patent: January 22, 1985
    Assignee: General Electric Company
    Inventor: Dwain M. White
  • Patent number: 4493917
    Abstract: The present invention relates to a plastic blend of polymers, capable of being injected and extruded, the process for producing it and its applications.This blend is produced by extrusion of a matrix of heat-stable material consisting of a polysulfone resin or polyphenylene sulfide and of a filler of a fluorocarbon polymer resin, the extrusion producing a network of interconnected and inter-penetrated fibers of filler within the matrix.This blend can be employed in an aggressive environment and at a high temperature, particularly for the manufacture of components of electrochemical reactors such as electrolysis cells.
    Type: Grant
    Filed: November 3, 1983
    Date of Patent: January 15, 1985
    Assignee: Electricite de France
    Inventors: Christian Bailleux, Michel Bernard, Bernard Dupont, Guy Lozach, Jean-Pierre Mata
  • Patent number: 4477630
    Abstract: A resin composition excellent in sliding characteristics, composed of 95 to 30% by weight of an aromatic polysulfone, 2.5 to 60% by weight of a fluorocarbon polymer and 2.5 to 60% by weight of an oxybenzoyl polyester.
    Type: Grant
    Filed: March 9, 1983
    Date of Patent: October 16, 1984
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Teruo Saito, Kuniaki Asai, Isamu Nakagawa, Tadayasu Kobayashi
  • Patent number: 4473684
    Abstract: Poly(aryl ether)s which contain at least 20% by weight of bis-(3,5-dimethyl-4-oxyphenyl)sulfone structural units exhibit improved glass transition temperatures, improved flame resistance, improved gas permeability and improved alloying compatibility.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: September 25, 1984
    Assignee: Union Carbide Corporation
    Inventors: Louis M. Maresca, Herbert S. Chao
  • Patent number: 4463112
    Abstract: Organic polyphosphites are disclosed having in the molecule at least two phosphite ester groups, at least one of which is linked through oxygen to a phenylethylidene-substituted phenyl group and to a residue of a polyhydroxy compound which is a pentaerythritol residue or a residue of a phenol or alcohol having two to three hydroxyl groups separated from one another by at least three carbon atoms.Polymer stabilizer compositions comprising an organic polyphosphite as disclosed and a known polymer stabilizer, as well as synthetic resin stabilized with such stabilizer compositions, are also disclosed.
    Type: Grant
    Filed: February 13, 1980
    Date of Patent: July 31, 1984
    Inventors: William E. Leistner, Motonobu Minagawa, Yutaka Nakahara, Kazumi Kitsukawa
  • Patent number: 4447581
    Abstract: Sulfur-containing polymers, such as polyphenylene sulfide, are stabilized from releasing sulfur-containing exhaust gases by adding an additive polymer having at least one reactive radical selected from the group consisting of amino radicals, amido radicals, imido radicals, and keto radicals therein, and which is of approximate the same thermal stability as the sulfur-containing polymer, to such sulfur-containing polymer. In other embodiments of the invention, sulfur-stabilization is also achieved by incorporating suitable fundamental building blocks of the additive polymer into the sulfur-containing polymer chain in the form of reactive monomers. Further, in other embodiments, additive polymers or oligomers (so-called telecheles) having reactive radicals at their ends can be introduced into the sulfur-containing polymer chain as copolymers.
    Type: Grant
    Filed: June 14, 1982
    Date of Patent: May 8, 1984
    Assignee: Siemens Aktiengesellschaft
    Inventors: Ferdinand Quella, Hans-Friedrich Schmidt
  • Patent number: 4390682
    Abstract: An aromatic polyester copolymer consisting of 10 to 90 mol % of a recurring unit of the formula: ##STR1## and 90 to 10 mol % of a recurring unit of the formula: ##STR2## and having a logarithmic viscosity number of at least 0.3 as measured in a mixture of phenol and tetrachloroethane (6:4 in weight ratio) at a concentration of 1 g/100 cc at 25.degree. C. and having a terminal carboxyl content of about 80 mol eq./ton or less. This aromatic polyester copolymer has high durability under dry and moist heat as well as high resistance to water crazing and hence can be fabricated into useful articles by various molding techniques.
    Type: Grant
    Filed: October 5, 1981
    Date of Patent: June 28, 1983
    Assignee: Unitika Ltd.
    Inventors: Kayomon Kyo, Yasuhiko Asai, Isamu Hirose, Nobuo Suyama
  • Patent number: 4350793
    Abstract: A flame-retardant composition comprising a polyphenylene ether and a polystyrene resin in a weight ratio of between 4:1 to 1:4 in admixture with an aromatic thermoplastic polyphonate having a number average molecular weight of 4,000 to 80,000, said thermoplastic polyphosphonate being present in an amount of 1 to 20 parts by weight per 100 parts by weight of the total mixture.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: September 21, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Manfred Schmidt, Klaus Reinking
  • Patent number: 4344993
    Abstract: Coatings having very low critical surface tensions comprise (1) a hydrophilic polymer such as polyacrylamide, (2) an ionic perfluorocarbon compound such as 3-[((heptadecafluorooctyl)sulfonyl)amino]-N,N,N-trimethyl-1-propanaminium iodide and (3) a cyclic sulfonium zwitterion cross-linking agent such as 2,2-bis(3-tetrahydrothiophenium-4-oxidophenyl)-propylidene. Such coatings are most advantageously employed as release coatings on internal surfaces of chemical reaction vessels in order to minimize the deposition (build-up) of undesirable materials on such internal surfaces.
    Type: Grant
    Filed: September 2, 1980
    Date of Patent: August 17, 1982
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Schmidt, Malcolm E. Pruitt, Keith I. Dismuke
  • Patent number: 4308180
    Abstract: A rubber composition comprising vulcanizable natural or synthetic rubber and a sulfide resin produced by (1) reacting a component (A) with a componet (B), followed by reacting with a component (D), or (2) reacting a component (A) with a component (B), followed by reacting with a component (C) and a component (D) simultaneously or sequentially, and if desired reacting the resulting phenol resin with an acylating agent, the component (A) being a phenol compound of the following formula, and/or an acylated compound thereof, ##STR1## wherein R.sub.1 and R.sub.2 are each a hydrogen atom, a hydroxyl, carboxyl, amino, C.sub.1 -C.sub.18 alkyl, C.sub.3 -C.sub.10 cycloalkyl, C.sub.3 -C.sub.10 cycloalkenyl or C.sub.7 -C.sub.12 aralkyl group or a phenyl group unsubstituted or substituted with at least one C.sub.1 -C.sub.
    Type: Grant
    Filed: March 19, 1980
    Date of Patent: December 29, 1981
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Haruki Okamura, Tetsuo Yamaguchi, Tamaki Ishii
  • Patent number: 4263201
    Abstract: A flame retardant polycarbonate composition comprising in admixture an aromatic carbonate polymer and a minor amount of a mixture of a metal salt of an organic sulfonate or organic carboxylate, and an organic halogenated compound.This invention relates generally to flame retardant polycarbonate compositions and more particularly to flame retardant compositions containing an aromatic carbonate polymer and a minor amount of a mixture of a metal salt of an organic sulfonate or organic carboxylate, and an organic halogenated compound.
    Type: Grant
    Filed: December 7, 1978
    Date of Patent: April 21, 1981
    Assignee: General Electric Company
    Inventors: Victor Mark, Jimmy L. Webb, Joseph B. Williams
  • Patent number: 4259222
    Abstract: The present invention provides new linear phosphorus- and halogen-containing flame retardant polyester additives for normally flammable polymers and coatings for normally flammable natural and synthetic films and fibers, for instance, polyester and cellulose ester films and fibers. The phosphorus- and halogen-containing polymers of the invention are water dispersible or can be rendered water-soluble. They can be prepared by reacting a phosphorus acid reactant such as phosphoric acid with at least one halogenated difunctional monomer. The water-soluble polyesters can be cross-linked to render them insoluble in water by heating together with a methylol compound.Said halogenated monomer is preferably an oxyalkylated diacid or diol and said halogen is attached either on one or more aromatic rings or on a cycloaliphatic ring.
    Type: Grant
    Filed: August 16, 1978
    Date of Patent: March 31, 1981
    Assignee: BASF Wyandotte Corporation
    Inventors: Robert B. Login, David D. Newkirk
  • Patent number: 4200579
    Abstract: Novel, rubbery copolymers of ethylene with at least one other .alpha.-alkene such as propylene, and a polyene such as 5-ethylidene norbornene-2, characterized by a differential scanning calorimetry thermogram maximum peak at a temperature between -7 and +11.degree. C., are disclosed. These specific rubbery copolymers when one or more tackifiers are included therein, exhibit an unprecedentedly high tack and consequently provide for the first time EDPM-type compositions that have sufficient building tack for the manufacture of multi-ply articles such as tires.
    Type: Grant
    Filed: November 19, 1976
    Date of Patent: April 29, 1980
    Assignee: Stamicarbon, B.V.
    Inventors: Albertus J. Pennings, Arnold Vossebeld
  • Patent number: 4174359
    Abstract: The present invention pertains to a halogen-containing, copolycarbonate blend having improved critical thickness and flammability properties comprising an aromatic copolycarbonate comprising the reaction product of an aromatic diphenol, an aromatic thiodiphenol and a carbonic acid derivative, such as phosgene or carbonyl bromide, blended with an effective amount of a halogen-containing compound. In a preferred embodiment, the copolycarbonate blend also contains small amounts of a perfluoro sulfonic or carboxylic acid salt.
    Type: Grant
    Filed: March 29, 1978
    Date of Patent: November 13, 1979
    Assignee: Mobay Chemical Corporation
    Inventors: Parameswar Sivaramakrishnan, Arthur L. Baron
  • Patent number: 4169117
    Abstract: The novel coating composition contains a uniformly dispersed perfluorocarbon polymer in an organic solvent solution of an aromatic polysulfone resin; finishes of the novel composition have excellent grease and stain resistance, good thermal stability, toughness and durability and good release properties and are useful as coatings for vessels, appliances, industrial equipment and in particular as release finishes for bakeware and cookware.
    Type: Grant
    Filed: November 26, 1975
    Date of Patent: September 25, 1979
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Joseph A. Vasta
  • Patent number: 4160757
    Abstract: An adhesive composition which shows improved stickiness and adhesive property at room temperature and exhibits an excellent adhering ability in a short time is prepared by compounding(a) an acrylonitrile-containing copolymer having carbon-to-carbon double bond(b) a phenol-polysulfide resin(c) a metal oxide, and(d) a polyfunctional electrophilic reactive compound containing at least two electrophilic reactive groups.
    Type: Grant
    Filed: February 28, 1977
    Date of Patent: July 10, 1979
    Assignee: Bridgestone Tire Co., Ltd.
    Inventors: Toshio Honda, Yukio Fukuura, Shoji Tanaka, Itsuo Tanuma, Yoshikatsu Suzuki, Hikaru Ishikawa
  • Patent number: RE31448
    Abstract: A coating composition is provided which comprises (a) 10% to 90% by weight of at least one thermoplastic aromatic .[.polysulphones.]. .Iadd.polysulphone .Iaddend.preferably having a reduced viscosity of at least 0.3 (measured at 25.degree. C. on a solution in dimethyl formamide containing 1 g of polymer in 100 cm.sup.3 of solution) and (b) 90% to 10% by weight of at least one fluorocarbon polymer.
    Type: Grant
    Filed: January 29, 1982
    Date of Patent: November 22, 1983
    Assignee: Imperial Chemical Industries, Ltd.
    Inventors: Terence E. Attwood, Barry W. Farrant