Solid Polymer Derived From Ethylenic Reactants Only Is Derived From A Reactant Containing At Least One Halogen Atom Patents (Class 525/151)
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Patent number: 10113041Abstract: The present invention aims to provide a film having excellent mechanical strength and abrasion resistance. The film of the present invention contains an aromatic polyether ketone resin (I) and a fluororesin (II). The aromatic polyether ketone resin (I) has a crystallinity of 10% or higher.Type: GrantFiled: July 16, 2015Date of Patent: October 30, 2018Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Koji Nakanishi, Yuki Ueda, Haruhisa Masuda, Kazuki Sakami
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Patent number: 10012280Abstract: A friction material as a lining for a drum brake includes polytetrafluoroethylene and an acrylic rubber-modified phenol resin. In the friction material, the polytetrafluoroethylene is preferably included in an amount of 0.1% by mass to 5% by mass, and the acrylic rubber-modified phenol resin is preferably included in an amount of 1% by mass to 15% by mass.Type: GrantFiled: May 12, 2015Date of Patent: July 3, 2018Assignee: AKEBONO BRAKE INDUSTRY CO., LTD.Inventors: Yuki Sato, Mikiya Haruta
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Publication number: 20150079391Abstract: The present invention relates to a fiber which is produced by means of a melt spinning method, including a first component including a melt processable, fully fluorinated first polymer, and a second component including a thermoplastic second polymer.Type: ApplicationFiled: September 17, 2014Publication date: March 19, 2015Inventors: Claudia Stern, Michael Schlipf
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Publication number: 20150080502Abstract: The present disclosure relates to a polymer composition comprising a polymer blend of Polyaryl Ether Ketone (PAEK) and Poly(2,5-benzimidazole) characterized with enhanced mechanical and wear resistance properties as compared to commercial polymer blends of Polyaryl Ether Ketone and Polybenzimidazole. The present disclosure also relates to shaped articles derived from the polymer composition of the present disclosure.Type: ApplicationFiled: March 28, 2013Publication date: March 19, 2015Inventor: Keki Hormusji GHARDA
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Publication number: 20140357796Abstract: A thermoplastic composition comprises a polymer blend. The polymer blend comprises a first polyimide and a second polyimide. The first polyimide has repeating units derived from a first dianhydride and a first diamine. The second polyimide has repeating units derived from a second dianhydride and a second diamine. Either the first dianhydride and the second dianhydride are the same or the first diamine and the second diamine are the same.Type: ApplicationFiled: August 14, 2014Publication date: December 4, 2014Inventors: MICHAEL STEPHEN DONOVAN, ROBERT RUSSELL GALLUCCI, ROY RAY ODLE, KAPIL CHANDRAKANT SHETH
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Publication number: 20140342155Abstract: To provide a fluorinated copolymer composition which is excellent in physical properties such as abrasion resistance, etc. and which is suitable for use as e.g. an electric wire-coating material; a molded product; and an electric wire. The fluorinated copolymer composition comprises fluorinated copolymer (A) comprising constituent units (a) derived from tetrafluoroethylene, constituent units (b) derived from a fluorinated monomer (provided that tetrafluoroethylene is excluded), and constituent units (c) derived from a monomer having an acid anhydride residue and no fluorine atom, in a specific ratio, and thermoplastic resin (B) having a Rockwell hardness of at least M60 and an insulation performance as defined by ASTM D-257 of at least 1015 ?·cm in a volume ratio of (A)/(B)=from 99/1 to 55/45. The molded product and the electric wire are ones prepared by using such a fluorinated copolymer composition.Type: ApplicationFiled: July 31, 2014Publication date: November 20, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Masatoshi ABE, Ryuta YANAGAWA, Masao UMINO
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Publication number: 20140336333Abstract: A resin composition including an aromatic polyether ketone resin (I), and a fluororesin (II), the fluororesin (II) being a copolymer of tetrafluoroethylene and a perfluoroethylenic unsaturated compound represented by the following formula (1): CF2?CF—Rf1??(1) wherein Rf1 represents —CF3 or —ORf2, and Rf2 represents a C1 to C5 perfluoroalkyl group; the composition containing the aromatic polyether ketone resin (I) and the fluororesin (II) at a mass ratio (I):(II) of 95:5 to 50:50; the fluororesin (II) being dispersed as particles in the aromatic polyether ketone resin (I) and having an average dispersed particle size of 3.0 ?m or smaller.Type: ApplicationFiled: July 25, 2014Publication date: November 13, 2014Applicants: DAIKIN INDUSTRIES, LTD., TSINGHUA UNIVERSITYInventors: Xuming XIE, Haruhisa MASUDA
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Publication number: 20140287200Abstract: To provide a curable composition which has favorable insulating property and liquid repellency, and from which a cured film having liquid repellency capable of being sufficiently converted to be liquid-philic even by irradiation with ultraviolet light having a wavelength of at least 300 nm, can be formed; an article having a cured film obtained by curing the curable composition and its production process. A cured film is formed by using a curable composition comprising a polymer having units (u1) based on a compound represented by the following formula (m1): wherein R1=a hydrogen atom, a methyl group or the like; R2=a bivalent organic group or the like; Cf=a C1-20 fluoroalkyl group or the like, X?O, S, N or NH; m=1 to 2; n=0 to 4; k=0 to 1; and Z=a (meth)acryloyl group or the like.Type: ApplicationFiled: June 5, 2014Publication date: September 25, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: MASAHIRO ITO, KAORI TSURUOKA, YASUHIRO KUWANA, YUSUKE NAGAI, MIYAKO SASAKI
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Publication number: 20140187721Abstract: [Problem] To provide a resin composition having excellent sliding properties and mechanical properties and a sliding member that uses the same. [SOLUTION] According to a resin composition of a fluorine-based resin dispersed in a hard resin, the maximum particle size of the fluorine-based resin is adjusted to be no greater than 950 nm and the mean particle size is adjusted to 100 nm to 450 nm. The hard resin is preferably at least one type selected from among polyether ether ketone, polyphenylene sulfide, polybutylene terephthalate, polyamides, polyamideimides, vinylidene fluoride and liquid crystal polymers. Polytetrafluoroethylene is preferred as the fluorine-based resin.Type: ApplicationFiled: September 26, 2012Publication date: July 3, 2014Applicant: Kabushiki Kaisha RikenInventors: Hiroshi Ito, Akihiro Oowada, Mika Saito
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Publication number: 20130172487Abstract: An anti-wear material of modified polytetrafluoroethylene resin is provided, which is prepared by mixing sufficiently a polyphenyl p-hydroxybenzoate polymer used as modifier with polytetrafluoroethylene resin in a certain weight ratio, and then carrying out cold-press sintering or hot-press sintering. The anti-wear material made from the modified polytetrafluoroethylene resin has very low average wear coefficient.Type: ApplicationFiled: December 30, 2010Publication date: July 4, 2013Inventors: Ping Xiao, Jianxin Zhang, Yunfeng Zhou
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Publication number: 20130109809Abstract: The application relates to polymeric antistatic agents for use in polymer moulding compositions, as well as moulding compositions containing these antistatic agents, the antistatic agents having good compounding properties and being inexpensive to produce, wherein the antistatic agent is an antistatic agent of the general formula (I) having a polymeric cationic polyelectrolyte constituent produced from diallyldialkylammonium compounds and an anionic counterion A?, in which R1 is uniformly or mutually independently C1-C18 alkyl, A? is an acid anion, and n is a whole number from 10 to 1000.Type: ApplicationFiled: April 20, 2011Publication date: May 2, 2013Applicant: Bayer Intellectual Property GmbHInventors: Helmut Werner Heuer, Rolf Wehrmann
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Patent number: 8349965Abstract: A fluororubber composition according to the present invention contains 0.1 to 3 parts by weight of a polyol compound, 0.1 to 4 parts by weight of a peroxide crosslinking agent, and 1 to 9 parts by weight of a co-crosslinking agent per 100 parts by weight of a peroxide-crosslinkable fluoropolymer. A crack-resistant seal according to the present invention contains a crosslinked fluoropolymer and a polyol compound. The crack-resistant seal according to the present invention can be formed by crosslinking the fluororubber composition, and the resultant crack-resistant seal has particularly high crack resistance. With the fluororubber composition according to the present invention, a durable crack-resistant seal having high plasma resistance, crack resistance, and compression set and that produces few particles can be formed at low cost.Type: GrantFiled: March 12, 2009Date of Patent: January 8, 2013Assignee: Nippon Valqua Industries, Ltd.Inventors: Masanori Okazaki, Naoki Ohsumi
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OPTICAL AND THERMAL ENERGY CROSS-LINKABLE INSULATING LAYER MATERIAL FOR ORGANIC THIN FILM TRANSISTOR
Publication number: 20120292626Abstract: The problem of the present invention is to provide an organic thin film transistor insulating layer material capable of producing an organic thin film transistor having a small absolute value of threshold voltage and small hysteresis. The means for solving the problem is an organic thin film transistor insulating layer material comprising a macromolecular compound (A) containing repeating units having a fluorine atom-containing group, repeating units having a photodimerizable group and repeating units having a first functional group that generates a second functional group which reacts with active hydrogen by the action of electromagnetic waves or heat, and an active hydrogen compound (B).Type: ApplicationFiled: November 10, 2010Publication date: November 22, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Isao Yahagi -
Patent number: 8211979Abstract: A multicomponent system is provided, composed of a thermoplastic component and of a rubber component, which comprises at least two different peroxidic crosslinking agents with specific decomposition temperatures, as also is a process for production of rubber-thermoplastic composite mouldings using the multicomponent system, and also the resultant rubber-thermoplastic composite mouldings.Type: GrantFiled: December 15, 2006Date of Patent: July 3, 2012Assignee: LANXESS Deutschland GmbHInventors: Dirk Achten, Stefanie Nickel, Maik Schulte, Michael Münker, Detlev Joachimi
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Publication number: 20120061119Abstract: In order to provide polymer compounds which are improved with respect to their properties in comparison with conventional PTFE, on the one hand, and compounds thereof with additional high performance polymers, on the other hand, it is suggested that a polymer compound comprise a proportion of a fully fluorinated, thermoplastic polymer material as well as a proportion of at least one additional high performance polymer different thereto and selected from the group consisting of polyether ketone, polyether ether ketone and polyether aryl ketone as well as copolymers and derivatives of these polymers and copolymers, wherein the compound displays a homogeneous distribution of the proportions of the polymers and the polymer material.Type: ApplicationFiled: September 7, 2011Publication date: March 15, 2012Inventors: Michael Schlipf, Claudia Stern, Martin Maier
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Publication number: 20110206840Abstract: A powder adhesive comprising a primary rubber bonding polymer and a thermosetting component, and a method for bonding elastomers to metals employing the same. By adding a thermosetting component to a powdered adhesive, the adhesive may be applied to a substrate, sintered and thermoset to provide a sweep resistant adhesive film on the substrate, which may subsequently be bonded to an elastomer. Without a thermosetting component, the adhesive is at risk to re-melt or otherwise soften during a heated elastomer molding operation which in turn could cause the adhesive material to sweep off the substrate.Type: ApplicationFiled: November 9, 2009Publication date: August 25, 2011Inventors: James R. Halladay, Kei-Yi Wei, Kirk J. Abbey
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Patent number: 7947775Abstract: Aqueous dispersions on non-melt flowable PTFE and melt-fabricable perfluoropolymer are mixed together, followed by recovery of the resultant mixture of the dispersed particles of each of these polymers, and melt mixing of the resultant mixture of particles to obtain a blend in which the PTFE particles form the disperse phase and the perfluoropolymer forms the continuous phase, the melt mixing producing advantageous melt viscosities and the blend exhibiting advantageous physical properties even at high PTFE contents of about 30 wt %.Type: GrantFiled: September 29, 2009Date of Patent: May 24, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Sundar Kilnagar Venkataraman, Ralph Munson Aten, Heidi Elizabeth Burch
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Patent number: 7585914Abstract: The present invention provides a thermoplastic composition which may be unvulcanized or vulcanized. The thermoplastic composition can be a blend of a thermoplastic engineering resin, a halogenated terpolymer of a C4 to C7 isomonoolefin, a para-alkylstyrene, and a multiolefin. The engineering resin can be a polyamide, such as nylon 6/66 copolymers for example. The isomonoolefin can be an isobutylene for example. The multiolefin can be a C4 to C14 diene, such as isoprene for example.Type: GrantFiled: November 9, 2005Date of Patent: September 8, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Andy Haishung Tsou, David Yen-Lung Chung
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Publication number: 20090087799Abstract: A composition comprising (A) a polymer having an alcohol structure with plural fluorine atoms substituted at ?- and ??-positions and having k=0.01-0.4 and (B) an aromatic ring-containing polymer having k=0.3-1.2 is used to form an antireflective coating. The ARC-forming composition can be deposited by the same process as prior art ARCs. The resulting ARC is effective in preventing reflection of exposure light in photolithography and has an acceptable dry etching rate.Type: ApplicationFiled: September 26, 2008Publication date: April 2, 2009Inventors: Seiichiro Tachibana, Kazumi Noda, Jun Hatakeyama, Takeshi Kinsho
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Patent number: 7087679Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150° C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.Type: GrantFiled: December 31, 2002Date of Patent: August 8, 2006Assignee: Daikin Industries, Ltd.Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
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Patent number: 6998438Abstract: The present invention provides plastics with high toughness and the preparation thereof. The plastics with high toughness, which have the balance of stiffness and toughness, stable properties and good processability, are obtained by blending the rubber particles having an average particle size of 20 to 200 nm with the pseudoductile plastics, wherein the weight ratio of the rubber particles to the plastics is from 0.5:99.5 to 70:30. The present invention also provides plastics with both high stiffness and high toughness and the preparation thereof. The plastics with both high stiffness and high toughness, which have also an improved heat resistance and good processability, are prepared by blending the rubber particles having an average particle size of 20 to 500 nm and the crystalline plastics, wherein the amount of the rubber particles added in the plastics matrix is from 0.3 to 5 weight parts.Type: GrantFiled: April 18, 2002Date of Patent: February 14, 2006Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical IndustryInventors: Jinliang Qiao, Shijun Zhang, Xiaohong Zhang, Yiqun Liu, Jianming Gao, Wei Zhang, Genshuan Wei, Jingbo Shao, Hua Yin, Renli Zhai, Zhihai Song, Fan Huang, Jiuqiang Li
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Patent number: 6907911Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene) polymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol polymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 29, 2004Date of Patent: June 21, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
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Patent number: 6875807Abstract: A silane-modified phenolic resin is prepared by reacting a phenolic compound (e.g., resorcinol) with an aldehyde to produce a phenolic novolak resin. The phenolic novolak resin is further reacted with at least one silane compound to produce the silane-modified phenolic resin. The reaction is typically carried out in the presence of an acid or base catalyst. The resulting resin has a lower softening point and can be used as a methylene acceptor compound in a vulcanizable rubber composition.Type: GrantFiled: May 28, 2003Date of Patent: April 5, 2005Assignee: Indspec Chemical CorporationInventors: Raj B. Durairaj, C. Michael Walkup, Mark A. Lawrence
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Patent number: 6843292Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene) polymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol polymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 8, 2001Date of Patent: January 18, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
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Patent number: 6784260Abstract: A powder coating composition comprises at least one thermosetting resin such as epoxy resins, carboxy- or hydroxy-functional polyesters; hydroxy-, carboxyl- or glycidyl-functional acrylic resins; and/or hydroxy- or carboxyl-functional fluoropolymers, fluorochloropolymers or fluoroacrylic polymers blended with a at least one poly(phenylene ether) and at least one curing agent for the thermosetting resin.Type: GrantFiled: January 31, 2003Date of Patent: August 31, 2004Assignee: General Electric CompanyInventors: Gary William Yeager, Michael Teruki Takemori
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Patent number: 6759470Abstract: There is provided a resin powder for molding which comprises 35 to 98% by weight of a polytetrafluoroethylene powder having an average particle size of not more than 120 &mgr;m, 35 to 2% by weight of a heat resistant aromatic polyoxybenzoyl ester resin powder subjected to water repelling treatment and 30 to 0% by weight of an inorganic filler, has an apparent density of not less than 0.6 g/cm3 and an average particle size of not more than 800 &mgr;m, and provides a molded article having an elongation at break of not less than 20%. The resin powder for molding is free from separation of a filler, has excellent flowability and apparent density which are important characteristics in handling the powder, and can provide a PTFE molded article having a high elongation which has not been obtained.Type: GrantFiled: April 19, 2002Date of Patent: July 6, 2004Assignee: Daikin Industries, Ltd.Inventors: Masamichi Sukegawa, Michio Asano
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Patent number: 6750274Abstract: A curable coating composition is disclosed comprising a resinous binder comprising (a) a reaction product of an epoxy-containing polymer with a compound containing phosphorus acid groups, the reaction product having reactive functional groups, and (b) a curing agent having functional groups reactive with the functional groups of (a). An electroconductive pigment is dispersed in (a) such that the weight ratio of the electroconductive pigment to (a) plus (b) is within the range of 0.5 to 9.0:1. When the curable coating composition is deposited and cured on a metal substrate, the cured coating is weldable.Type: GrantFiled: May 16, 2001Date of Patent: June 15, 2004Assignee: PPG Industries Ohio. Inc.Inventors: Ralph C. Gray, Ellor James Van Buskirk, Michael J. Pawlik, Richard M. Nugent, Jr., Dennis W. Jones, Kathleen M. Coldren, Steven D. Perrine, James E. Jones
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Publication number: 20040048983Abstract: A fluoroelastomer composition contains a peroxide-curable solid fluoroelastomer and a peroxide curative agent combined therewith, and, a bisphenol-curable liquid fluoroelastomer and a bisphenol curative agent combined therewith. The solid fluoroelastomer/peroxide curative when combined with the liquid fluoroelastomer/bisphenol curative results in a composition exhibiting improved polymeric properties including improved flowability at room temperature and improved fluid resistance and sealability at a wide range of temperatures.Type: ApplicationFiled: September 10, 2002Publication date: March 11, 2004Inventors: Paul J. Hochgesang, James W. Jacks
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Patent number: 6649697Abstract: A hyperbranched polyetherketone and a heat-resistant blend of polyvinylchloride with the same. The polyethereketone is synthesized by self-polycondensation of 3,5-bis[4-[(2,3,4,5,6-pentafluorophenyl)carbonyl]phenoxy]-4-hydroxbenzophenone or 3,5-difluoro-4-hydroxybenzophenone, and then substituting 50 to 80 mole % of fluorine atoms present in the side chains and ends of the PEK molecule by polar groups. In addition, a blend of polyvinylchloride can be manufactured using the hyperbranched polyetherketone by a melt blending technique applicable for industrial purpose at a temperature of 180 to 120° C., and thus the blend of polyvinylchloride with the polyetherekentone can be applied to high temperature end-use products such as hot water pipes.Type: GrantFiled: January 9, 2002Date of Patent: November 18, 2003Assignee: Polyplus Co., Ltd.Inventors: Seung-yeop Kwak, Dae-up Ahn
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Patent number: 6624244Abstract: An improved material comprising the reaction product of an A-side having an isocyanate and a B-side having a cross-linker comprising a multifunctional alcohol, a vegetable oil, preferably a blown/oxidized vegetable oil, most preferably a blown/oxidized soybean oil, and a catalyst and the method of producing the same.Type: GrantFiled: September 24, 2002Date of Patent: September 23, 2003Assignee: Urethane Soy Systems CompanyInventor: Thomas M. Kurth
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Patent number: 6579942Abstract: Melt fabricable compositions of at least 50 wt % polytetrafluoroethylene are provided, wherein the composition contains polyaryletherketone and optionally part of the polytetrafluoroethylene is PTFE micropowder.Type: GrantFiled: March 12, 2001Date of Patent: June 17, 2003Assignee: E. I. du Pont de Nemours and CompanyInventor: Jacob Lahijani
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Patent number: 6576718Abstract: Powder coating compositions comprising at least one thermosetting resin and at least one poly(phenylene ether) are disclosed.Type: GrantFiled: October 4, 2000Date of Patent: June 10, 2003Assignee: General Electric CompanyInventors: Gary William Yeager, Michael Teruki Takemori
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Patent number: 6552127Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150° C.Type: GrantFiled: March 31, 2000Date of Patent: April 22, 2003Assignee: Daikin Industries, Ltd.Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
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Publication number: 20020099237Abstract: In one aspect, the invention provides curable fluoropolymer compositions comprising fluoropolymer, onium, and alkyl or aryl oxalate-blocked compound and carbonate-blocked compound as crosslinking agents. In other aspects, the invention provides methods of making curable fluoropolymer compositions and provides alkyl or aryl oxalate-blocked and carbonate-blocked compounds.Type: ApplicationFiled: December 28, 2001Publication date: July 25, 2002Applicant: 3M Innovative Properties CompanyInventors: Naiyong Jing, Brant U. Kolb, Robert E. Kolb
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Publication number: 20020099139Abstract: A hyperbranched polyetherketone and a heat-resistant blend of polyvinylchloride with the same. The polyethereketone is synthesized by self-polycondensation of 3,5-bis[4-[(2,3,4,5,6-pentafluorophenyl)carbonyl]phenoxy]-4-hydroxbenzophenone or 3,5-difluoro-4-hydroxybenzophenone, and then substituting 50 to 80 mole % of fluorine atoms present in the side chains and ends of the PEK molecule by polar groups. In addition, a blend of polyvinylchloride can be manufactured using the hyperbranched polyetherketone by a melt blending technique applicable for industrial purpose at a temperature of 180 to 120° C., and thus the blend of polyvinylchloride with the polyetherekentone can be applied to high temperature end-use products such as hot water pipes.Type: ApplicationFiled: January 9, 2002Publication date: July 25, 2002Applicant: Young Chang Chemical Co., Ltd.Inventors: Seung-Yeop Kwak, Dae-Up Ahn
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Publication number: 20020091282Abstract: In one aspect, the invention provides curable fluoropolymer compositions comprising fluoropolymer, onium, and alkyl or aryl oxalate-blocked compound as a crosslinking agent. In other aspects, the invention provides methods of making curable fluoropolymer compositions and provides alkyl or aryl oxalate-blocked compounds.Type: ApplicationFiled: December 28, 2001Publication date: July 11, 2002Applicant: 3M Innovative Properties CompanyInventors: Naiyong Jing, Brant U. Kolb, Robert E. Kolb
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Patent number: 6388011Abstract: A hyperbranched polyetherketone and a heat-resistant blend of polyvinylchloride with the same. The polyetherketone is synthesized by self-polycondensation of 3,5-bis[4-[(2,3,4,5,6-pentafluorophenyl)carbonyl]phenoxy]-4-hydroxybenzophenone or 3,5-difluoro-4-hydroxybenzophenone, and then substituting 50 to 80 mole % of fluorine atoms present in the side chains and ends of the PEK molecule by polar groups. In addition, a blend of polyvinylchloride can be manufactured using the hyperbranched polyetherketone by a melt blending technique applicable for industrial purpose at a temperature of 180 to 120° C., and thus the blend of polyvinylchloride with the polyetherketone can be applied to high temperature end-use products such as hot water pipes.Type: GrantFiled: March 17, 2000Date of Patent: May 14, 2002Assignee: Young Chow Chemical Co., Ltd.Inventors: Seung-yeop Kwak, Dae-up Ahn
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Patent number: 6376598Abstract: The invention generally relates to thermoplastic blends having improved properties. Optionally, these blends may be dynamically vulcanized. More specifically, this invention is directed to a composition comprising a blend of chloromethylated(styrene-isobutylene)copolymer and a thermoplastic resin selected from the group consisting of polyamides, polyesters, polycarbonates, polysulfones, polyacetals, polyacetones, acrylonitrile-butadiene styrene resins, polyphenylene oxide, polyphenylene sulfide, styrene-acrylonitrile resins, styrene-maleic anhydride resins, polyamides, aromatic polyketones, ethylene vinyl alcohol copolymer and mixtures thereof. Tires and tire components such as air permeation prevention films comprising these compositions are also provided.Type: GrantFiled: June 15, 2000Date of Patent: April 23, 2002Assignee: Exxon Mobil Chemical Patents Inc.Inventor: Hsien-Chang Wang
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Patent number: 6365665Abstract: A composition and method for promoting improved adhesion between a thermoplastic resinous substrate and polyurethane foam is provided. In one aspect of this invention, the composition comprises a thermoplastic mixture of at least one polyphenylene ether and at least one poly(alkenylaromatic) compound; and at least one primary amine-containing material or secondary amine-containing material.Type: GrantFiled: September 13, 2000Date of Patent: April 2, 2002Assignee: General Electric CompanyInventors: Herbert Shin-I Chao, Geoffrey Henry Riding, David John Swanson
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Patent number: 6346571Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C4 to C7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.Type: GrantFiled: November 2, 1999Date of Patent: February 12, 2002Assignee: ExxonMobil Chemical Patents Inc.Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton
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Publication number: 20010016625Abstract: Melt fabricable compositions of at least 50 wt % polytetrafluoroethylene are provided, wherein the composition contains polyaryletherketone and optionally part of the polytetrafluoroethylene is PTFE micropowder.Type: ApplicationFiled: March 12, 2001Publication date: August 23, 2001Inventor: Jacob Lahijani
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Patent number: 6265492Abstract: Melt fabricable compositions of at least 50 wt % polytetrafluoroethylene are provided, wherein the composition contains polyaryletherketone and optionally part of the polytetrafluoroethylene is PTFE micropowder.Type: GrantFiled: June 15, 1998Date of Patent: July 24, 2001Assignee: E. I. du Pont de Nemours and CompanyInventor: Jacob Lahijani
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Patent number: 6248500Abstract: A composition for anti-reflective coating material is disclosed, comprising a polymer compound having repeating units having specific structure, and optionally a melamine, guanamine, urea, phenol, naphthol or hydroxyanthracene compound substituted by at least one group selected from the group consisting of a methylol group and an alkoxymethyl group at two or more positions. The composition for anti-reflective coating material of the present invention is effective for the reduction of adverse effects of reflection by the substrate in a lithographic process using various radiations. A resist pattern formation process which comprises the use of the composition for anti-reflective coating material is also disclosed.Type: GrantFiled: February 7, 2000Date of Patent: June 19, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuyoshi Mizutani, Hiroshi Yoshimoto
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Patent number: 6153303Abstract: Fluoropolymer compositions containing melt-flowable tetrafluoroethylene copolymers with reactive end groups and isotropic polyesters have excellent adhesion to metal substrates, especially steel, and excellent water resistance.Type: GrantFiled: August 19, 1998Date of Patent: November 28, 2000Assignee: Dupont Mitsui FluorochemicalsInventors: Sinichi Namura, Takahiko Iwasaki
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Patent number: 6087435Abstract: A polystyrene-based resin composition, comprising (A) a styrene-based resin with a mainly syndiotactic configuration, (B) a polyolefin, and (C) rubber polymer particles as main components, exhibits excellent heat resistance and impact resistance.Type: GrantFiled: June 5, 1995Date of Patent: July 11, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 6054537Abstract: A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.Type: GrantFiled: November 5, 1998Date of Patent: April 25, 2000Assignee: Daikin Industries, Ltd.Inventors: Tetsuo Shimizu, Yoshihisa Yamamoto, Seitaro Yamaguchi, Nobuhiko Tsuda, Noriyasu Yamane, Takafumi Yamato, Masahiro Kumegawa, Takayuki Araki
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Patent number: 6051655Abstract: A composition amenable to injection molding and extrusion comprises a syndiotactic styrene resin, a thermoplastic resin such as a polyolefin and an inorganic filler optionally contains a rubber.Type: GrantFiled: June 5, 1995Date of Patent: April 18, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 6043315Abstract: A functionalized copolymer of the formulaA--B--Z--XwhereA is a block of vinylaromatic monomers of 8 to 20, preferably 8 to 12, carbon atoms,B is a block of alkadiene monomers of 4 to 12, preferably 4 to 8, carbon atoms,Z is a fundamental building block of a compound having sterically hindering groups andX is a functionalized fundamental building block,a process for its preparation, thermoplastic molding materials containing said copolymer, processes for their preparation, the use for the production of moldings and moldings comprising said molding materials.Type: GrantFiled: November 20, 1997Date of Patent: March 28, 2000Assignee: BASF AktiengesellschaftInventors: Axel Gottschalk, Ralf Engelhardt, Jurgen Koch, Robert Weiss
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Patent number: 6013719Abstract: Low melt viscosity polytetrafluorethylene (PTFE), i.e. having a melt viscosity of 50 to 1.times.10.sup.5 Pa.multidot.s at 372.degree. C., is combined with non-fluorinated thermally stable polymer such as polyarleneetherketone to provide melt-fabricability application for the low MV PTFE and provide improved properties for the thermally stable polymer.Type: GrantFiled: June 15, 1998Date of Patent: January 11, 2000Assignee: E. I. du Pont de Nemours and CompanyInventor: Jacob Lahijani
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Patent number: 6013727Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.Type: GrantFiled: January 31, 1991Date of Patent: January 11, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton