Two Or More Solid Polymers Present Other Than Derived From A Polycarboxylic Acid Or Derivative And A Polyol Patents (Class 525/166)
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Patent number: 6818695Abstract: An extrudable composition comprising a major amount of a thermoplastic host polymer, a fluorocarbon polymer and a dendritic material wherein the extrudate demonstrates reduced levels of surface defects.Type: GrantFiled: May 20, 2002Date of Patent: November 16, 2004Assignee: 3M Innovative Properties CompanyInventors: Maria P. Dillon, John H. Horns, Claude Lavallée
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Patent number: 6815499Abstract: An object of the present invention is to substantially improve the compatibility between a radical copolymerizable unsaturated resin and an addition polymerized polymer (thermoplastic resin) which is added for the purpose of low profile and improvement of physical properties. The present invention provides a compatibilizing agent for compatibilizing a radical copolymerizable unsaturated resin with an addition polymerized polymer, characterized in that said compatibilizing agent is a graft copolymer (A) which contains a styrene monomer as a principal component, and has a principal chain (A1) consisting of a copolymer with a (meth)acrylate monomer and a side chain (A2) selected from a ring-opening polymerized polyether side chain consisting of a polyoxyalkylene ether, a polyester side chain, and a polycarbonate side chain, the side chain (A2) being bonded to the principal chain.Type: GrantFiled: February 14, 2002Date of Patent: November 9, 2004Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Takashi Yasumura, Akira Takano
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Patent number: 6809151Abstract: The present invention relates to the thermoplastic polyesters, which comprise, by weight (i) a thermoplastic polyester; (ii) an impact modifier comprising: (a) a core-shelf copolymer (A); (b) an ethylene copolymer (B) chosen from ethylene-unsaturated carboxylic acid anhydride copolymers (B1), ethylene-saturated epoxide copolymers (B2) and blends thereof; (iii) the (B)/(A) ratio being between 90/10 and 25/75 for proportions of impact modifier between 2 and 40% in 98 to 60% of polyester, respectively; (iv) the (B)/(A) ratio being between 25/75 and 10/90 for proportions of impact modifier between 18 and 40% in 82 to 60% of polyester, respectively. It is particularly useful for PET and PBT.Type: GrantFiled: November 24, 2000Date of Patent: October 26, 2004Assignee: AtofinaInventors: Christophe Lacroix, Alain Bouilloux
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Patent number: 6806314Abstract: A coating composition comprising at least one hydroxyl functional polymer, a crosslinker capable of crosslinking with said hydroxyl functional polymer (a) to form a film, and a reactive diluent comprising 1,3-cyclohexane dimethanol and 1,4-cyclohexane dimethanol.Type: GrantFiled: February 3, 2003Date of Patent: October 19, 2004Assignee: PPG Industries Ohio, Inc.Inventors: David R. Fenn, David N. Walters
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Patent number: 6790499Abstract: A mixture of a polyester, such as poly(ethylene terephthalate) PET, and an additive combination, when extrusion compounded exhibits a lower residual acetaldehyde content than does PET alone when similarly treated. The additive combination comprises compounds selected from at least two groups wherein the groups are (i.) poly(vinyl alcohol) or ethylene/vinyl alcohol copolymer, (ii.) polyhydric alcohols and (iii.) polyacrylamide, polymethacrylamide or copolymer of acrylamide or methacrylamide. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, beverages and most especially water.Type: GrantFiled: December 20, 2001Date of Patent: September 14, 2004Assignee: Ciba Speicalty Chemicals CorporationInventors: Stephen M Andrews, Paul A. Odorisio, Dirk Simon
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Patent number: 6780907Abstract: A means to improve thermoplastic formulations in terms of the physical properties they exhibit, such as impact strength and ductility, have been developed. The addition of a block chlorinated polyolefin (b-CPO) to polymer blends in which at least one component comprises a halogen-free hydrogen-bond acceptor polymer, achieves the desired enhancement. The synergetic effect of the b-CPO with the selected polymer blend is demonstrated. Blends of thermoplastic polyurethanes, polycarbonates, copolyesters and copolyamides with a blend partner such as thermoplastic polyolefins, styrenic copolymers such as styrene acrylonitrile copolymers, styrene ethylene butylene styrene copolymers, high rubber graft copolymers such as acrylonitrile butadiene styrene copolymers, methylmethacrylate butadiene styrene copolymers and the b-CPO have enhanced ductility and impact resistance. The addition of 0.5 wt.Type: GrantFiled: March 11, 2002Date of Patent: August 24, 2004Assignee: Noveon IP Holdings Corp.Inventors: A. Donald Meltzer, Dennis L. Lawson, Robert E. Detterman, Carole A. Lepilleur
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Patent number: 6780481Abstract: A melt processable polymer composition that comprises a thermoplastic non-aliphatic host polymer and a minor but effective amount of a fluoropolymer processing aid, and a method of improving the melt processability of the host polymer are provided.Type: GrantFiled: May 12, 2000Date of Patent: August 24, 2004Assignee: 3M Innovative Properties CompanyInventors: Claude Lavallée, Maria P. Dillon, Thomas J. Blong, Susan S. Woods, Shannon S. Le Blanc
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Patent number: 6773819Abstract: This invention provides a paint composition for motorcars, which comprises a carboxyl-containing polyester resin which contains a unit or units derived from alicyclic polybasic acid (a) and/or alicyclic polyhydric alcohol (b), and a vinyl polymer having epoxy group(s) and hydroxyl group(s) within one molecule, and which is capable of forming cured coating having Universal Hardness (HU) not higher than 500 N/mm2.Type: GrantFiled: October 29, 2002Date of Patent: August 10, 2004Assignee: Kansai Paint Co., Ltd.Inventors: Kazuhiro Kato, Kazuaki Kitazono, Yoshizumi Matsuno
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Publication number: 20040152840Abstract: Acid dye stain-resistant fibers which are formed from a polyamide composition containing a mixture of a masterbatch concentrate, a fiber-forming polyamide and a polymer, the masterbatch concentrate including a carrier and a reagent having the formula: 1Type: ApplicationFiled: May 23, 2003Publication date: August 5, 2004Inventor: Matthew Benjamin Studholme
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Patent number: 6770378Abstract: Compounds which, for example, can be used as a compact substance and which are comprised of polyamide substance(s) and perfluoralkyl substance(s), and to mixtures of these compounds with additional polymer substance(s). Methods for producing such compounds are also provided in which aliphatic and/or partially aromatic homopolyamides and/or copolyamides and/or polyester amides and/or polyether amides and/or polyester ether amides and/or polyimide amides and/or polyamide amides and/or mixtures of these polyamide compound(s) with additional polymer(s) and modified perfluoralkyl substance(s) are compounded in a single step or multistep and are reactively converted during or afterwards. The homogenization of perfluoralkyl substance(s) in polyamide substance(s) melted masses is improved.Type: GrantFiled: January 5, 2001Date of Patent: August 3, 2004Assignee: Institut fur Polymerforschung E.V. DresdenInventor: Dieter Lehmann
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Patent number: 6765062Abstract: Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.Type: GrantFiled: July 10, 2002Date of Patent: July 20, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Hui Chin, James Botkin, Francesco Fuso, Wiebke Wunderlich
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Patent number: 6759480Abstract: The invention relates to thermoplastic compositions comprising: −40 to 97 parts of a thermoplastic polymer (M) forming a matrix, chosen from polyamides, polyamide block copolymers, fluoro polymers, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), copolymers containing polyester blocks and polyether blocks, polycarbonate-polyester alloys, polyketones, PVC and ethylene-vinyl alcohol copolymers (EVOH), −60 to 3 parts of (B) comprising: either an ethylene-alkyl (meth)acrylate copolymer (B1), the alkyl having at least 5 carbon atoms, which copolymer (B1) carries a functional group or a blend of an ethylene-alkyl (meth)acrylate copolymer (B2), the alkyl having at least 5 carbon atoms, which copolymer (B2) does not carry a functional group, and of an impact modifier which carries a functional group.Type: GrantFiled: September 26, 2000Date of Patent: July 6, 2004Assignee: AtofinaInventors: Alain Bouilloux, Christophe Lacroix, Jean-Marc Le Blevec, Thibaut Montanari
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Publication number: 20040116645Abstract: Coating compositions comprising:Type: ApplicationFiled: September 25, 2003Publication date: June 17, 2004Inventors: Jos Huybrechts, Ann Vaes, Lieve Bastin, Leen Tanghe
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Publication number: 20040116603Abstract: Polyester compositions which contain a copolymer of ethylene, an acrylate ester, and carbon monoxide and optionally a fibrous filler having a relatively small diameter are particularly suitable for parts whose surface appearance is important, such as appliance panels and automobile body panels.Type: ApplicationFiled: August 26, 2003Publication date: June 17, 2004Inventors: Toshikazu Kobayashi, Claire Brissot, Edmund Arthur Flexman
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Patent number: 6740708Abstract: An impact-resistant polymer composition exhibiting improved impact resistance at no loss in creep is obtained by melt-mixing a solid matrix polymer A with a solid composition containing the rubber composition dispersed in a matrix polymer B. The dispersion of rubber composition in matrix polymer B is obtained by melt mixing the matrix polymer B with a rubber composition which includes a functionality rubber and a non-functionality rubber. The amounts of the components are such that the impact-resistant polymer composition contains 0.5 to 75 parts by weight of the rubber composition per 100 parts by weight of the matrix polymers A and B. The composition may be used in various applications, including plugs, heat bridges for aluminum windows, hammer heads and the like.Type: GrantFiled: December 14, 2001Date of Patent: May 25, 2004Assignee: DSM IP Assets B.V.Inventors: Wilhelmus G. M. Bruls, Johannes F. Repin, Jan De Kroon
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Patent number: 6720380Abstract: The invention relates to a modular system for the production of coating compositions for coating plastics comprising the following component modules: A) at least one base module containing at least one binder, extenders and/or pigments, optionally together with conventional coating additives, water and/or organic solvents, B) at least one adhesion module containing at least one adhesion-promoting component optionally together with binders, conventional coating additives, extenders, organic solvents and/or water, C) at least one elasticity module containing at least one elasticising component optionally together with conventional coating additives, extenders, organic solvents and/or water and D) at least one binder module containing at least one binder optionally together with additives, organic solvents and/or water.Type: GrantFiled: November 27, 2001Date of Patent: April 13, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Udo Hellmann, Maria Weigel
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Patent number: 6706851Abstract: The present invention relates to polyetheresteramides (B) containing polyamide blocks comprising dicarboxylic acid sulphonates either as polyamide-block chain limiters or combined with a diamine as one of the constituent monomers of the polyamide block, and containing polyether blocks consisting essentially of alkylene oxide units. The invention also relates to polyetheresteramides (B) containing polyamide blocks of the polyamide oligomer type of low molecular mass or of the copolyamide type which comprise dicarboxylic acid sulphonates and containing polyether blocks which are adducts of alkylene oxide with an aromatic diol. The invention also relates to antistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one of the above polyetheresteramides (B).Type: GrantFiled: August 17, 2001Date of Patent: March 16, 2004Assignee: AtofinaInventors: Reinhard Linemann, Thierry Briffaud, Hermann Hilgers, Christophe Lacroix
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Patent number: 6696165Abstract: The invention provides a weatherable low gloss styrene copolymer composition which requires the addition of from 0.1 to 20% by weight of the total composition, of a partially crystalline polymer such as a polyalkylterephthalate, especially polybutyleneterephthalate or polyethyleneterephthalate, or polyethylenenaphthalate to a styrene copolymer (A). The low gloss styrene copolymer composition of the invention has a graft copolymer resin which results from polymerizing one or more monomers (A1) selected from the group consisting of (i) aromatic vinyl compounds, (ii) ethylenically unsaturated compounds, and (iii) mixtures thereof, in the presence of an elastomeric rubber (A2) in particulate form.Type: GrantFiled: June 28, 2000Date of Patent: February 24, 2004Assignee: BASF CorporationInventors: James H. Bennett, Klaus Mühlbach, Gary Kogowski, Heiner Görrissen, Graham Edmund Mc Kee
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Patent number: 6673873Abstract: A substantially transparent, moldable, thermoplastic multipolymer composition comprising a methyl methacrylate copolymer containing a predominant amount of methyl methacrylate and a minor amount of one or more ethylenically unsaturated monomers; and an effective amount of a polyetheresteramide to enhance the electrostatic charge dissipation of the copolymer. The polyetheresteramide has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition, when subjected to injection molding, is such that the injection-molded composition exhibits a haze of not greater than about 25% and a light transmission of at least about 60%. Preferably, the composition includes an impact modifier which also has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition may also include a minor amount of a polyethylene glycol having a weight average molecular weight of about 2,000 to about 10,000.Type: GrantFiled: August 25, 1999Date of Patent: January 6, 2004Assignee: Cyro IndustriesInventor: Daniel Zimmerman
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Patent number: 6656531Abstract: A method for forming a coated film comprises (1) applying a water or solvent based coating composition on an undercoated or intercoated substrate to form a base coating, (2) applying a clear coating composition thereon to form a clear coating without curing the base coating, and (3) heating and curing both the base coating and clear coating, wherein the clear coating composition comprises as a binder (a) from 10-70% by weight of an acrylic polycarboxylic acid having on average 2 or more carboxyl groups per molecule obtained by copolymerizing an acid anhydride group-containing ethylenically unsaturated monomer with an ethylenically unsaturated monomer having no acid anhydride group, then reacting the resulting copolymer with a monoalcohol; (b) from 5-70% by weight of a polyester polycarboxylic acid having an acid value of from 50-350 mg KOH/g (solid) obtained by reacting a polyester polyol having 3 or more hydroxyl groups with an acid anhydride group-containing compound; (c) from 10-80% by weight of a poType: GrantFiled: April 30, 2002Date of Patent: December 2, 2003Assignee: Nippon Paint Co., Ltd.Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
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Patent number: 6649700Abstract: A thermosetting powder coating composition prepared by a wet process, which contains a mixture comprising (a) an epoxy-containing acrylic resin, (b) a polycarboxylic acid compound curing agent, (c) fine crosslinked resin particles and, optionally, (d) a resin that exists in the liquid form at room temperature.Type: GrantFiled: September 21, 2001Date of Patent: November 18, 2003Assignee: Nippon Paint Co., Ltd.Inventors: Masami Yabuta, Yutaka Harada, Atsushi Yamada, Yasuhiko Nakae, Kazuhiko Nishimura, Haruhiko Sato
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Patent number: 6642310Abstract: Extrusion processability of non-fluorinated melt-processable polymers is improved by introducing a fluoropolymer process aid by means whereby the weight average particle size of the fluoropolymer is greater than 2 microns as it reaches the extruder die entrance.Type: GrantFiled: September 17, 2001Date of Patent: November 4, 2003Assignee: DuPont Dow Elastomers L.L.C.Inventors: George Richard Chapman, Jr., Steven Richard Oriani
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Patent number: 6624250Abstract: A substantially transparent, moldable, thermoplastic multipolymer composition comprising a methyl methacrylate copolymer containing a predominant amount of methyl methacrylate and a minor amount of one or more ethylenically unsaturated monomers; and an effective amount of from about 1% to 35% by weight of the composition, of a polyetheresteramide to enhance the electrostatic charge dissipation of the copolymer. The polyetheresteramide has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition, when subjected to injection molding, is such that the injection-molded composition exhibits a haze of not greater than about 25% and a light transmission of at least about 60%. The composition may include an impact modifier which also has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition may also include a minor amount of a polyethylene glycol having a weight average molecular weight of about 2,000 to about 10,000.Type: GrantFiled: December 5, 2001Date of Patent: September 23, 2003Assignee: Cyro IndustriesInventor: Daniel Zimmerman
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Publication number: 20030153684Abstract: Polyester compositions useful to improve the impact and heat distortion properties of polyethylene terephthalate, providing the polyethylene terephthalate with both high notched Izod properties and high heat distortion properties. The composition is the reaction of a terpolymer of ethylene, an acrylate or a methacrylate, and glycidyl methacrylate with polyethylene terephthalate in the presence of at least one elastomer such as a copolymer of ethylene and 1-octene, and polypropylene, an ethylene propylene copolymer, polybutyleneterephthalate, polycyclohexanedimethanolterephthalate, or mixtures thereof, having a melt flow of about 6 to about 15 g/10 min. The product has a notched Izod value of at least about 4 ft. lbs/in and a heat distortion temperature of about 150° C. to about 190° C.Type: ApplicationFiled: January 31, 2003Publication date: August 14, 2003Applicant: HITECH POLYMERS INC.Inventor: Gerald W. Miller
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Publication number: 20030134978Abstract: A powder coating composition includes an acid-functional polyester resin and a matting agent selected from styrene-maleic anhydride copolymers and acid-functional acrylic resins. The compositions provide low gloss finishes at low curing temperatures, as well as consistent gloss over a wide range of curing temperatures.Type: ApplicationFiled: October 9, 2002Publication date: July 17, 2003Inventors: Tina L. Tullos, Brian T. Myers, Charles P. Tarnoski
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Patent number: 6586527Abstract: Polyester molding compositions, which have improved crystallization and processing, a cycloaliphatic polyester component, and a nucleating agent comprising a fluoropolymer containing a thermoplastic resin.Type: GrantFiled: March 20, 2001Date of Patent: July 1, 2003Assignee: General Electric CompanyInventors: Peter Hendrikus Theodurus Vollenberg, Gerardus Bernardus Wilhelmus Hieltjes, Franciscus Petrus Maria Mercx, Aagje Petronella den Breejen
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Patent number: 6579943Abstract: A method of producing modified polyester moulded articles which is characterized in that, when producing moulded articles from a modified polyester composition comprising a polyester composed of an acid component chiefly consisting of aromatic dicarboxylic acid and glycol component chiefly consisting of aliphatic diol, and a modified polyolefin, there is incorporated an ethylene-acrylate copolymer; together with the moulded articles produced thereby.Type: GrantFiled: June 26, 2000Date of Patent: June 17, 2003Assignee: Elf Atochem S.A.Inventors: K Ishino, Takatoshi Ku-Ratsuji
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Patent number: 6576309Abstract: Thermoplastic compositions comprising a bulk polymer, an additive, and a compatibilizer/emulsifier/surfactant (CES) are described. The bulk polymer comprises an alkylene terephthalate or naphthalate polyester such as polyethylene terephthalate. The additive comprises an amorphous or substantially amorphous co-polymer of ethylene and a co-monomer that forms polar portions, such as methacrylate, butylacrylate, ethyl acrylate, or ethylhexyl methacrylate. The CES comprises a co-polymer or ter-polymer of ethylene and a glycidyl acrylate or maleic anhydride, and optionally an acrylate such as methacrylate, ethylacrylate, propylacrylate, butylacrylate, ethylhexylacrylate, or mixtures thereof. The thermoplastic compositions of the present invention exhibit improved molding properties, high dimensional stability, high temperature resistance, and are particularly useful in food-grade applications such as dual-ovenable containers.Type: GrantFiled: December 2, 1999Date of Patent: June 10, 2003Assignee: Associated Packaging EnterprisesInventors: Edward J. Dalgewicz, III, John Bond
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Publication number: 20030105231Abstract: Polyester compositions useful to improve the impact and heat distortion properties of polyethylene terephthalate, providing the polyethylene terephthalate with both high notched Izod properties and high heat distortion properties. The composition is the reaction of a terpolymer of ethylene, an acrylate or a methacrylate, and glycidyl methacrylate with polyethylene terephthalate in the presence of at least one elastomer such as a copolymer of ethylene and 1-octene.Type: ApplicationFiled: November 28, 2001Publication date: June 5, 2003Applicant: HITECH POLYMERS INC.Inventor: Gerald W. Miller
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Publication number: 20030100678Abstract: The present invention provides a low temperature curing coating powder composition comprising a mixture of a high gloss film-forming system and a low gloss film-forming system. Preferably, the high gloss film-forming system comprises a GMA (glycidyl methacrylate) resin, a curing agent, and a catalyst and forms a coating having a gloss greater than 80% measured at 60°. Preferably the low gloss film-forming system comprises a carboxyl terminated polyester, acrylic resin and a catalyst and forms a coating having a gloss less than 50% measured at 60°. The composition of the present invention provides coatings having a control gloss, which can range from a low to a high gloss and is useful for coating heat-sensitive substrates.Type: ApplicationFiled: November 13, 2002Publication date: May 29, 2003Inventors: Edward G. Nicholl, Andrew T. Daly, Carryll A. Seeling
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Patent number: 6509417Abstract: A multi-component coating composition having a hard, glossy, and tack-free finish is described. The coating composition comprises a fatty acid modified glycidyl-containing component and a hydroxy-functional polymer. The coating composition can be used to originally finish or to refinish such articles as farm, industrial, and construction equipment, automobiles, and trucks, and to paint structures such as bridges, buildings, appliances, metal furniture, and the like.Type: GrantFiled: October 31, 2000Date of Patent: January 21, 2003Assignee: Lilly Industries, Inc.Inventors: Wylie H. Wetzel, William G. O'Dell
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Publication number: 20030008976Abstract: The invention relates to thermoplastic compositions comprising a thermoplastic polymer, in which polymer is incorporated a crosslinked phase originating from the reaction:Type: ApplicationFiled: August 27, 1999Publication date: January 9, 2003Inventors: ALAIN BOUILLOUX, LAURENT TEZE
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Publication number: 20020188073Abstract: A polyester type resin composition comprising (A) 30 to 95 parts by weight of a polybutylene terephthalate type resin containing a polybutylene terephthalate-isophthalate copolymer in which the content of an isophthalic acid ingredient to the entire dicarboxylic acid ingredient is 3 to 30 mol %, (B) 1 to 30 parts by weight of a polycarbonate resin, (C) 1 to 30 parts by weight of an elastomer and (D) 3 to 60 parts by weight of a fibrous reinforcing material, wherein the total amount for (A)-(D) is 100 parts by weight, the composition being used for insert molding.Type: ApplicationFiled: March 21, 2002Publication date: December 12, 2002Inventors: Tomoyuki Uno, Takashi Sugata, Akira Hirai, Tetsuya Hirose, Hiroyuki Yamazaki, Kazuo Kato
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Publication number: 20020188074Abstract: A method of producing extruded synthetic lumber for use in construction matting comprising the steps of first, providing a blend of ground synthetic particles, the blend selected from the group comprising primarily ground high density polyethylene particles and ground polyethylene terephthalate particles in an amount not more than 99.0 percent by weight and a composition of ground styrene-butadiene rubber comprised primarily of tire buffings in an amount from 1.0 percent to about 3.5 percent by weight. The blend is mixed, heated and extruded into dimensional lumber and then cooled. The resulting lumber has a low retained memory and reduced electrosstatic potential.Type: ApplicationFiled: April 29, 2002Publication date: December 12, 2002Inventors: Robert S. Parker, Ernest E. Holden, Mark L. Phillips
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Publication number: 20020177662Abstract: Polyester molding compositions, which have improved crystallization and processing, a cycloaliphatic polyester component, and a nucleating agent comprising a fluoropolymer containing a thermoplastic resin.Type: ApplicationFiled: March 20, 2001Publication date: November 28, 2002Inventors: Peter Hendrikus Theodurus Vollenberg, Gerardus Bernardus Wilhelmus Hieltjes, Franciscus Petrus Maria Mercx, Aagje Petronella den Breejen
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Patent number: 6476145Abstract: Polyester injection-moulded parts based on a polyester (A) and on a copolymer (B) of ethylene and of an unsaturated epoxy, such that weight % (B)×MFI (A+B)/MFI(A) is greater than 3 and in this expression: MFI (A+B) denotes the melt flow index of the modified polyester, that is to say the blend of (A) and (B) and of any fillers; MFI (A) denotes the melt flow index of the polyester (A) and of any fillers (without (B)); and weight % (B) denotes the percentage by weight of (B) in the blend of (A) and (B) and of any fillers.Type: GrantFiled: June 29, 2000Date of Patent: November 5, 2002Assignee: AtofinaInventors: Patrice Perret, Jacques Komornicki, Yoshiyuki Miyaki
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Patent number: 6476125Abstract: A fluorine-containing polymer alloy comprising a grafted fluorine-containing polymer (a) and a polymer (c) containing no fluorine atom, said grafted fluorine-containing polymer (a) comprising a fluorine-containing polymer (d) having hydrogen atoms bonded to carbon atoms of its main chain and a grafting compound having a linking group capable of grafting to the fluorine-containing polymer (d) and a functional group capable of providing an adhesive property, grafted to the fluorine-containing polymer (d).Type: GrantFiled: August 21, 1996Date of Patent: November 5, 2002Assignee: Asahi Glass Company Ltd.Inventors: Jun-ichi Iura, Eiichi Nishi, Masataka Yokota
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Publication number: 20020161121Abstract: Disclosed is a high-solid curable resin composition which forms a coated film having excellent acid rain resistance, mar resistance and appearance comprising:Type: ApplicationFiled: April 30, 2002Publication date: October 31, 2002Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
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Patent number: 6444754Abstract: Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.Type: GrantFiled: August 8, 2000Date of Patent: September 3, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Hui Chin, James Botkin, Francesco Fuso, Wiebke Wunderlich
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Patent number: 6437056Abstract: Coating composition suitable for multilayer lacquering, containing, in addition to organic solvent, anti-sagging agents, optionally pigments, extenders and additives, a binder/crosslinkin agent system containing A) from 20 to 80 wt. % of carboxyl-functional (meth)acrylic copolymers and/or carboxyl-functional polyesters having an acid number of from 20 to 300, B) from 20 to 80 wt. % of epoxy-functional crosslinking agents, the percentages by weight of A) and B) adding up to 100 wt. %. C) from 0 to 30 wt. % of polymer polyol C), based on the sum of the weights of A) and B), E) from 0 to 20 wt. % of further crosslinking agents, based on the sum of the weights of A, B, and C), F) from 0 to 10 wt. % of monoepoxides, based on the sum of the weights of A) and B), and D) as anti-sagging agents, from 0.1 to 3 wt.Type: GrantFiled: December 11, 2000Date of Patent: August 20, 2002Assignee: E. I. du Pont de Nmeours and CompanyInventors: Ralf Dahm, Carmen Flosbach, Hermann Kerber, Walter Schubert, Astrid Tückmantel
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Patent number: 6428900Abstract: A water-sensitive hot melt adhesive composition based on sulfonated branched copolyester polymers for use with articles such as paper products, disposable nonwoven products, tapes, labels and packaging materials. The adhesive composition includes about 10% to about 90%, by weight, of a sulfonated polyester copolymer or a blend of one or more sulfonated polyester polymers; about 0% to about 80%, by weight, of a tackifying resin; about 0% to about 40%, by weight, of a compatible plasticizer; about 5% to about 50% by weight of a polyethylene glycol having a molecular weight greater than 2000 and a melting point greater than 50° C; and about 0% to about 3% by weight of one or more antioxidant. The adhesive maintains the article in an assembled condition by providing adequate adhesive bond strength during normal use, but dissolves in the presence of water thereby permitting the article to be recycled or otherwise disposed of in an environmentally friendly manner.Type: GrantFiled: March 9, 2000Date of Patent: August 6, 2002Assignee: Ato Findley, Inc.Inventor: Baoyu Wang
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Patent number: 6417284Abstract: A release coating layer comprising a continuous phase of an organic polymer binder; a discontinuous phase of a fluorinated resin having a molecular weight between 2500 and 10,000,000, wherein the ratio of organic polymer binder to fluorinated resin is between 60:39.9 to 80:18 by weight; and a priming agent composition comprising a perfluoroalkylsubstituted fluororesin-reactive compound having the formula: where R5 is H or F, Q is OH, SiR6R7R8, R6, R7, and R8 being independently selected from the group consisting of Cl, OH, an alkyl group containing 1 to about 4 carbon atoms, an alkoxy group containing 1 to about 4 carbon atoms, an acyloxy group containing 2 to about 4 carbon atoms, and an amino group containing 0 to about 4 carbon atoms; and n is an integer from 1 to about 15; with the proviso that, at least one of R6, R7, and R8 is Cl, OH, or an alkoxy, acyloxy, or amino group.Type: GrantFiled: September 30, 1999Date of Patent: July 9, 2002Assignee: NexPress Solutions LLCInventors: Jiann-Hsing Chen, Biao Tan, Joseph A. Pavlisko, Robert A. Lancaster, Craig M. Cody
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Patent number: 6414081Abstract: The invention relates to compatibilized blends comprising a non-polar thermoplastic elastomer, a polar thermoplastic polymer selected from thermoplastic polyurethane (TPU), chloro containing polymers, fluoro containing polymers, polyesters, acrylonitrile-butadiene-styrene copolymers, styrene-acrylonitrile copolymers, styrene-maleic anhydride copolymer, polyacetal, polycarbonate, polyphenylene oxide, and a suitable compatibilizer.Type: GrantFiled: May 23, 2000Date of Patent: July 2, 2002Assignee: Advanced Elastomer Systems, LP.Inventor: Trazollah Ouhadi
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Patent number: 6410647Abstract: A high-solid curable resin composition which forms a coated film having excellent acid rain resistance, mar resistance and appearance comprises: (a) 10 to 70% by weight of an acrylic polycarboxylic acid having 2 or more carboxyl groups per molecule on an average, an acid value of 5 to 300 mg KOH/g (solid) and a number-average molecular weight of 500 to 8000; (b) 5 to 70% by weight of a polyester polycarboxylic acid having an acid value of 50 to 350 mg KOH/g (solid), a number-average molecular weight of 400 to 3500 and a ratio of weight-average molecular weight to number-average molecular weight of 1.Type: GrantFiled: November 30, 1999Date of Patent: June 25, 2002Assignee: Nippon Paint Co., Ltd.Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
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Patent number: 6407164Abstract: The present invention relates to a multiphase thermoplastic composition consisting of a mixture (I) including at least one ethylene polymer (A) which has units derived from unsaturated epoxy and at least one thermoplastic resin (B) partly encapsulated by the said ethylene polymer (A), the said mixture (I) being dispersed in a matrix of thermoplastic resin (C).Type: GrantFiled: May 20, 1996Date of Patent: June 18, 2002Assignee: Atofina SAInventors: Marius Hert, Patrice Perret
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Patent number: 6399700Abstract: Synthetic comb copolymers which elicit controlled cellular response, methods of applying these polymers to various surfaces, and methods of using the polymers for modifying biomaterial surfaces, in tissue engineering applications and as drug delivery devices are provided. The comb copolymers are comprised of hydrophobic polymer backbones and hydrophilic, non-cell binding side chains which can be end-capped with cell-signaling ligands that guide cellular response. By mixing non-cell binding combs with ligand-bearing combs, the surface concentration and spatial distribution of one or more types of ligands, including adhesion peptides and growth factors, can be tuned on a surface to achieve desired cellular response. In one embodiment, the combs are used as stabilizing agents for dispersion polymerization of latexes. The comb-stabilized latexes can be applied to substrates by standard coating operations to create a bioregulating surface, or used as drug delivery agents.Type: GrantFiled: March 26, 2001Date of Patent: June 4, 2002Assignee: Massachusetts Institute of TechnologyInventors: Anne M. Mayes, Linda G. Griffith, Darrell J. Irvine, Pallab Banerjee, Terry D. Johnson
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Patent number: 6380309Abstract: A method of producing a synthetic structural material for use in constructing mats for temporary roads and access areas. The matting is formed from extruded synthetic structural members formed from a blend comprising HDPE; SBR in an amount less than 4.0 percent by weight of the blend; and PET. Extruded structural members so produced have low electrostatic properties with a desired structural flexibility and resistance to retained memory after loading.Type: GrantFiled: July 31, 2000Date of Patent: April 30, 2002Inventors: R. S. Parker, E. E. Holden, Jr., Mark L. Phillips
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Patent number: 6357802Abstract: An air-pressure joint 1 comprising a pipe main body 2 made of a rigid thermoplastic resin and a release ring 3 made of a rigid thermoplastic resin inserted from one opening of the pipe main body, wherein the release ring includes a slip-off preventing protrusion 13 on an outer circumferential surface of its insertion site; and the pipe main body 2 includes a ring-shaped sealing portion 9 made of an elastic resin and integrally formed on an inner circumferential surface thereof, an insertion mouth pipe portion 7 made of a rigid rigid resin, coaxially disposed to abut one opening side portion of the pipe main body 2 and forming a recess groove 10 on an inner circumferential surface of an abutting portion thereof for stopping the slip-off preventing protrusion 13 of the release ring 3, and a ring-shaped connecting portion 8 made of a rigid synthetic resin and integrally molded to an outer circumferential surface of the abutting portion of this mouth pipe for connecting the insertion mouth pipe portion 7 to the pType: GrantFiled: February 24, 2000Date of Patent: March 19, 2002Assignees: Mikuni Plastics Co., Ltd., Daicel-Hüls, Ltd., Daicel Chemical Industries, Ltd.Inventors: Nobuhiro Nozato, Atsushi Inagaki, Shinichi Matsumoto, Hajime Komada, Mitsuteru Mutsuda, Masanori Hiraishi
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Patent number: 6355319Abstract: The present invention provides a polyester resin composition comprising (A) a polyethylene terephthalate composed mainly of repeating units derived from a dicarboxylic acid containing terephthalate acid and/or an esterified derivative thereof and a diol containing ethylene glycol and/or esterified derivative thereof, and (B) an ethylene/(meth) acrylic acid copolymer and, optionally, (C) polyethylene. The polyethylene terephthalate contains diethylene glycol units in a ratio of 0.5 to 2.0% by weight and a cyclic trimer in an amount not greater than 0.5% by weight based on polyethylene terephthalate. The ethylene/ (meth) arcylic acid coploymer is in an amount of 0.1 to 10,000 ppb based on the composition. Also provided are a perform formed from the composition and a blow molded container produced therefrom.Type: GrantFiled: May 24, 2000Date of Patent: March 12, 2002Assignee: Mitsui Chemicals INCInventors: Koji Nakamachi, Hiroji Niimi, Mitsuaki Masumoto
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Patent number: 6346571Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C4 to C7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.Type: GrantFiled: November 2, 1999Date of Patent: February 12, 2002Assignee: ExxonMobil Chemical Patents Inc.Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton