Solid Polymer Derived From Ethylenic Reactants Only Derived From At Least One Reactant Containing An Atom Other Than C, H, Or O Patents (Class 525/169)
  • Patent number: 4367315
    Abstract: An improved fire retardant polyester polymer system and composition comprising an interpolymer of a reaction product of hexachlorocyclopentadiene, a polyhydric alcohol, a carboxylic acid containing aliphatic carbon-to-carbon unsaturation, a styrene-type monomer, maleic acid or anhydride and a copolymerizable brominated neopentylacrylate comonomer.
    Type: Grant
    Filed: January 29, 1981
    Date of Patent: January 4, 1983
    Assignee: Occidental Chemical Corporation
    Inventors: Paul Zwaenepoel, Guido Strzelbicki, Daniel J. Scharf, George M. Wagner
  • Patent number: 4366290
    Abstract: An unsaturated polyester resin composition which is obtained by incorporating a thermoplastic random-copolymer having peroxycarbonate groups in the molecule thereof into an unsaturated polyester resin, which composition is excellent in low shrinkage characteristics and it is not weakened in mechanical strength.
    Type: Grant
    Filed: July 13, 1981
    Date of Patent: December 28, 1982
    Assignee: Nippon Oil and Fats Co., Ltd.
    Inventors: Norihisa Ujikawa, Masaharu Nakayama
  • Patent number: 4322334
    Abstract: Unsaturated polyester resin compositions that have a low shrinking property, and at the same time, an enough strength are provided. The compositions comprises (1) 30-70 parts by weight of an unsaturated polyester obtained by reacting terephthalic acid and/or isophthalic acid and one or more of unsaturated acids selected from the group consisting of maleic anhydride, maleic acid and fumaric acid, with a glycol, and having the unsaturation degree of 1.5-5.0 and the acid value of 18-40, (2) 70-30 parts by weight of .alpha.,.beta.-ethylenically unsaturated monomer, and (3) 5-30 parts by weight of a thermoplastic resin having the number average molecular weight of 5,000-500,000.
    Type: Grant
    Filed: December 4, 1979
    Date of Patent: March 30, 1982
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Kouji Arakawa, Kanemasa Nomaguchi, Etsuji Iwami
  • Patent number: 4320045
    Abstract: A resin molding composition comprising a thermoplastic polymer, a monomer and an unsaturated polyester which is the reaction product of at least one polyol having at least two, but not more than four hydroxyl groups, the polyols comprising not less than about 48% of the weight of the reactants forming the polyester.
    Type: Grant
    Filed: April 10, 1981
    Date of Patent: March 16, 1982
    Assignee: Owens-Corning Fiberglas Corporation
    Inventor: Gwilym Owen
  • Patent number: 4299934
    Abstract: Hot melt adhesive compositions having low melt viscosity and high adhesive strength are disclosed. The compositions include polyesters comprising 1,6-hexanediol and terephthalic acid, blended with a polymeric material comprising a vinyl aromatic polymer derived from a monomer of the formula ##STR1## wherein R is hydrogen or an alkyl group containing 1 to 4 carbon atoms and R.sub.1 is hydrogen, chlorine, alkyl from 1 to 4 carbon atoms or phenyl.
    Type: Grant
    Filed: October 2, 1980
    Date of Patent: November 10, 1981
    Assignee: Eastman Kodak Company
    Inventors: Frederick D. Petke, Richard L. McConnell
  • Patent number: 4298711
    Abstract: A low shrink unsaturated polyester based upon propylene glycol terephthalate reacted with a dibasic acid or anhydrides thereof and glycols.
    Type: Grant
    Filed: April 9, 1980
    Date of Patent: November 3, 1981
    Assignee: Cargill Incorporated
    Inventors: Thomas J. Moulson, John E. Greenzweig
  • Patent number: 4290927
    Abstract: An intimate polyblend of about 5-90% by weight of a thermoplastic copolyester or block copolyester elastomer and about 95-10% by weight of a vulcanizable synthetic or natural rubber. The preferred copolyester is a copolyester of polybutylene terephthalate and the prefered block copolyetherester is polybutylene terophthalate-poly (tetramethylene oxide) glycol block copolyester. These polyblends can be vulcanized to elastomeric molded articles which exhibit an excellent oil and oxygen/ozone resistance even at elevated temperatures, a high impact strength, an increased scuff resistance and an improved flexibility at low and high temperatures. The vulcanized molded articles also have an improved adhesive property with polyester fibers or fabrics.
    Type: Grant
    Filed: April 16, 1980
    Date of Patent: September 22, 1981
    Assignee: Toray Industries, Inc.
    Inventors: Chiaki Tanaka, Masanobu Morikawa, Yoshio Kohno
  • Patent number: 4288571
    Abstract: The disclosure of this application is directed to unsaturated polyester compositions, containing as a low-profile additive a carboxyl containing thermoplastic polymer of a vinyl ester of an aliphatic, saturated monocarboxylic acid, which have particular utility in molding applications to form aesthetically attractive thermoset articles characterized by excellent physical properties, as for example, impact strength and by excellent surface properties such as excellent smoothness and gloss, excellent receptiveness to paints and excellent reproduction of the surface contours of the mold in which they are formed into shaped, thermoset articles.
    Type: Grant
    Filed: February 26, 1973
    Date of Patent: September 8, 1981
    Assignee: Union Carbide Corporation
    Inventors: Lowell R. Comstock, Percy L. Smith
  • Patent number: 4284736
    Abstract: The disclosure of this application is directed to unsaturated polyester compositions, containing a thermoplastic terpolymer of a vinyl halide monomer, a vinyl ester of a saturated, monocarboxylic acid and as the third component, an unsaturated, dicarboxylic acid or anhydride thereof; or as the third component, a glycidyl ester of an unsaturated, monocarboxylic acid, which can be pigmented with organic and/or inorganic pigments and molded into shaped, thermoset articles such as housings for telephones, automobile heater ducts and the like which are characterized by excellent surface characteristics and color properties.
    Type: Grant
    Filed: February 26, 1973
    Date of Patent: August 18, 1981
    Assignee: Union Carbide Corporation
    Inventors: Lowell R. Comstock, Percy L. Smith
  • Patent number: 4273890
    Abstract: Block copolyesters and block copolyesterurethanes are presented which are useful as plastifiers for PVC. The plastifiers, depending on process variations, contain ordered or random blocks of amorphous and semi-crystalline structure and are characterized as being highly compatible and substantially non-fugitive when blended with PVC.
    Type: Grant
    Filed: March 21, 1980
    Date of Patent: June 16, 1981
    Assignee: Monsanto Company
    Inventor: John W. Hirzy
  • Patent number: 4263417
    Abstract: A vinyl monomer is copolymerized with a multifunctional monomer having one vinyl group and one or more allyl groups whereby the resulting copolymer has active pendant allyl groups. This copolymer is then crosslinked with a polyester. The resulting product has improved thermal dimensional stability and physical properties over those containing simple non reactive thermoplastic additives.
    Type: Grant
    Filed: August 3, 1979
    Date of Patent: April 21, 1981
    Assignee: Pennwalt Corporation
    Inventor: Christopher J. Dyball
  • Patent number: 4263199
    Abstract: Glass-reinforced polyester molding compositions when mixed with lactone polymers and vinyl chloride polymers as additives afford molding compounds with greater shrinkage control and molded parts with smoother surfaces.
    Type: Grant
    Filed: November 13, 1979
    Date of Patent: April 21, 1981
    Assignee: Union Carbide Corporation
    Inventor: Kenneth E. Atkins
  • Patent number: 4237244
    Abstract: Molding compositions comprising terminally unsaturated polyesters, vinyl or vinylidene compounds copolymerizable therewith and elastomeric polymers have an excellent impact strength and a good heat distortion temperature, strength and rigidity.
    Type: Grant
    Filed: January 3, 1979
    Date of Patent: December 2, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hannes von Harpe, Ludwig Bottenbruch, Bernd Peltzer, Hansjochen Schulz-Walz
  • Patent number: 4233436
    Abstract: Block polymers containing an hydroxyalkyl phthalate ester as one of the constituent blocks and a copolymer of tetrahydrofuran and one or more alkylene oxides as one or more of the other constituent blocks are useful in preparing polyurethanes and polyesters.
    Type: Grant
    Filed: February 12, 1979
    Date of Patent: November 11, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Ivan M. Robinson
  • Patent number: 4225684
    Abstract: Compositions comprising vinyl chloride polymers and from 10 to 25 wt % of a cross-linked, aliphatic polyester elastomer, said polyester elastomer being produced by preparing a cross-linked latex of the polyester.
    Type: Grant
    Filed: May 29, 1979
    Date of Patent: September 30, 1980
    Assignee: Borg-Warner Corporation
    Inventor: John C. Falk
  • Patent number: 4222926
    Abstract: A flame-retarding thermoplastic polyester resin composition comprising (1) a polyester obtained from a terephthalic acid or an alkyl ester thereof and a glycol having 2 to 4 carbon atoms, (2) an organohalogen compound, (3) an inorganic flame-retarding supplementary agent, and (4) at least one polymer selected from a saponified polyvinyl acetate having a saponification degree of greater than 50%, an ethylene/vinyl acetate copolymer and a saponified ethylene/vinyl acetate copolymer, and optionally (5) a reinforcing agent; and a process for production thereof.
    Type: Grant
    Filed: April 4, 1978
    Date of Patent: September 16, 1980
    Assignee: Dainippon Ink & Chemicals, Inc.
    Inventors: Shioji Mizuno, Norio Enokimoto
  • Patent number: 4220737
    Abstract: An air drying paint composition comprising a chlorinated polymer selected from the group consisting of chlorinated polydiolefin rubbers and chlorinated polyolefins as at least one ingredient of a binder, said composition further comprising 5 to 100 parts by weight, per 100 parts by weight of the chlorinated polymer, of a cyclopentadiene resin having a softening point of 50.degree. to 160.degree. C. prepared by heat polymerization of 50 to 100% by weight of a cyclopentadiene monomer and 50 to 0% by weight of a comonomer copolymerizable with it.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: September 2, 1980
    Assignee: Nippon Zeon Co. Ltd.
    Inventor: Ryuji Kita
  • Patent number: 4210730
    Abstract: Block copolyesters and block copolyesterurethanes are presented which are useful as plastifiers for PVC. The plastifiers, depending on process variations, contain ordered or random blocks of amorphous and semi-crystalline structure and are characterized as being highly compatible and substantially non-fugitive when blended with PVC.
    Type: Grant
    Filed: December 27, 1977
    Date of Patent: July 1, 1980
    Assignee: Monsanto Company
    Inventor: J. William Hirzy
  • Patent number: 4208488
    Abstract: A thermosetting coating or adhesive composition based on (A) at least one component selected from the group consisting of oligomeric and polymeric compounds containing at least one of the functional groups hydroxyl and epoxy groups, and (B) a polycarboxylic acid mixture comprising trimellitic acid and a major amount of at least one compound of one of the formulae ##STR1## wherein R, R' and R'", being the same or different, each represents a di- to hexavalent hydrocarbon radical having a total of from 1 to 12 carbon atoms, said radical containing from zero to 2 olefinic double bonds, said radical without double bonds being interrupted by up to 3 ether bridges:x and y which may be the same or different, each represents an integer of from 2 to 6;t an integer of from 1 to 5; andz and u, which may be the same or different, each represents zero or an integer of from 1 to 5 and a process for coating a substrate with said composition.
    Type: Grant
    Filed: February 15, 1978
    Date of Patent: June 17, 1980
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Kurt Kraft, Gerd Walz, Thaddaus Wirth
  • Patent number: 4206291
    Abstract: Polyvinyl halide or polyvinyl graft copolymers intimately mixed with a polyester derived mainly from an halogenated bicycloheptene carboxylic acid or anhydride such as chlorendic acid or anhydride and an alkylene glycol or alkylene oxide such as ethylene oxide are provided. The graft copolymers of the invention are obtained by polymerizing a vinyl halide in bulk in contact with an olefin polymer. The graft copolymer compositions of the invention have good clarity and provide improved processing characteristics and increased impact strength without reduction in heat distortion resulting from the addition of the polyester. The improved impact strength polyvinyl halide compositions of the invention can include blends of the polyester of the invention with modifying compounds, such as alkyl methacrylate-butadiene/styrene graft polymer impact modifiers and halogenated polyvinyl chloride. Blends of vinyl halide polymers with the polyesters of the invention provide compositions having improved processability.
    Type: Grant
    Filed: March 12, 1979
    Date of Patent: June 3, 1980
    Assignee: Hooker Chemicals & Plastics Corp.
    Inventors: Akio Takahashi, Geoffrey H. Smith, George C. Hopkins
  • Patent number: 4178327
    Abstract: Ar-halo-ar(t-alkyl)styrenes, e.g., 2-chloro-4-(t-butyl)styrene, polymerize to form materials having unusually high temperature resistance. Additionally, compositions of such monomers, unsaturated polyesters and free-radical generating catalysts cure at lower temperatures and in less time than similar compositions containing conventional styrene monomers.
    Type: Grant
    Filed: August 5, 1977
    Date of Patent: December 11, 1979
    Assignee: The Dow Chemical Company
    Inventors: Richard H. Hall, Daniel H. Haigh, Junior J. Lamson, Larry D. Yats
  • Patent number: 4161471
    Abstract: Filled unsaturated ester bulk molding, sheet molding, premix or mat molding compositions are modified with elastomer to give finished products with both improved impact strength and improved surface characteristics. The elastomeric modifier is selected from the group consisting of chloroprene polymers and hydrocarbon polymers such as ethylene/propylene di-, ter-, or tetrapolymers.
    Type: Grant
    Filed: April 13, 1978
    Date of Patent: July 17, 1979
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert J. Kassal