Polycarboxylic Acid Or Derivative Contains Three Or More Carboxylic Acid Groups Or Derivatives Thereof; Or Wherein A Polyol Contains At Least Three Hydroxyl Groups Patents (Class 525/172)
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Patent number: 11286401Abstract: A powder coating composition comprising: a) a thermoset resin comprising an acid functional polyester material, b) a thermoplastic resin and c) a crosslinker material, wherein the coating composition is substantially free of bisphenol A (BPA), bisphenol F (BPF), bisphenol A diglycidyl ether (BADGE) and bisphenol F diglycidyl ether (BFDGE).Type: GrantFiled: November 2, 2020Date of Patent: March 29, 2022Assignee: PPG Industries Ohio, Inc.Inventors: William H. Retsch, Jr., Anthony M. Chasser, Edward R. Millero, Jr., John M. Dudik
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Publication number: 20130287682Abstract: The present invention is directed to a novel poly (diol citrates)-based coating for implantable devices. More specifically, the specification describes methods and compositions for making and using implantable devices coated with citric acid copolymers or citric acid copolymers impregnated with therapeutic compositions and/or cells.Type: ApplicationFiled: March 21, 2013Publication date: October 31, 2013Inventors: Guillermo Ameer, Jian Yang
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Patent number: 8097076Abstract: Low-VOC mixture of at least partially salified copolymers of at least one ethylenically unsaturated, phenyl-group-containing monomer and at least one ?,?-unsaturated monocarboxylic acid and/or at least one ?,?-unsaturated dicarboxylic acid, of at least one water-soluble polyether, esterification products of at least one water-soluble polyether and an aliphatic dicarboxylic acid, and of a star polymer obtainable by esterifying a carboxylic acid containing at least 3 carboxyl groups with at least one water-soluble polyether, and use thereof as a wetting and dispersing agent, preferably for producing low-VOC pigment pastes or low-VOC paint systems.Type: GrantFiled: July 28, 2010Date of Patent: January 17, 2012Assignee: BYK-Chemie GmbHInventors: Bernd Göbelt, Carsten Nagel, Jürgen Omeis, Marcus Meichsner, Diana Walter
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Publication number: 20110245393Abstract: The invention pertains to low profile additives (“LPA”) comprising branched polymers having a weight average molecular weight (Mw) of at least about 20,000 grams/mole and a number average molecular weight (Mn) of at least about 3,000 grams/mole and methods for making the LPAs. The invention further concerns compositions comprising LPAs synthesized from one or more Bifunctional monomers and one or more branching agents. Also, disclosed are thermosettable resinous compositions and molded articles comprising the LPAs.Type: ApplicationFiled: June 17, 2011Publication date: October 6, 2011Inventors: Husam A.A. Rasoul, Dejan D. Andjelkovic, Dennis H. Fisher
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Patent number: 7812097Abstract: An improved curable formaldehyde-free binding composition is provided. Such curable composition comprises the reaction product of a polyanhydride and a polyol crosslinker and a lower molecular weight anhydride. Initially, the polyanhydride is modified through reaction with a polyol (e.g., a glycol or an alkanolamine) and subsequently is grafted with the lower molecular weight anhydride (e.g., maleic anhydride) to form a water-soluble or water-dispersible curable reaction product. The composition is well suited for binding fibrous materials (e.g., a mat of glass fibers) or for bonding together non-fibrous materials. The binder composition displays an advantageous viscosity so as to facilitate a flowable application with ease combined with an adequately high molecular weight to satisfactorily undergo service as a binder following curing even when harsh environmental conditions (e.g., hot humid air) are encountered for a prolonged period of time.Type: GrantFiled: September 22, 2009Date of Patent: October 12, 2010Assignee: Johns ManvilleInventor: Kiarash Alavi Shooshtari
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Patent number: 7608670Abstract: An improved curable formaldehyde-free binding composition is provided. Such curable composition comprises the reaction product of a polyanhydride and a polyol crosslinker and a lower molecular weight anhydride. Initially, the polyanhydride is modified through reaction with a polyol (e.g., a glycol or an alkanolamine) and subsequently is grafted with the lower molecular weight anhydride (e.g., maleic anhydride) to form a water-soluble or water-dispersible curable reaction product. The composition is well suited for binding fibrous materials (e.g., a mat of glass fibers) or for bonding together non-fibrous materials. The binder composition displays an advantageous viscosity so as to facilitate a flowable application with ease combined with an adequately high molecular weight to satisfactorily undergo service as a binder following curing even when harsh environmental conditions (e.g.Type: GrantFiled: November 20, 2006Date of Patent: October 27, 2009Assignee: Johns ManvilleInventor: Kiarash Alavi Shooshtari
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Patent number: 7557167Abstract: Crosslinked polymer compositions have backbones with first and second divalent saturated aliphatic moieties, a divalent saturated aliphatic secondary alcohol moiety, and a trivalent saturated aliphatic moiety. Hydrolytically labile ester bonds joined together these moieties. These polyesters may be polycondensation reaction products of a diol, a triol and a diacid. A molar ratio of the first divalent saturated aliphatic moiety, the divalent saturated aliphatic secondary alcohol moiety, and the trivalent saturated aliphatic moiety to the second divalent saturated aliphatic moiety is in the range of about 0.85 to about 1.5. Preferably, these polyesters are non-cytotoxic, biocompatible, bioabsorbable, or exhibit shape memory behavior with at least one transition temperature of greater than about 30° C. and less than about 100° C. and most preferably exhibit each of these qualities. The compositions may be adapted for a wide variety of uses, including medical applications.Type: GrantFiled: September 28, 2006Date of Patent: July 7, 2009Assignee: Gore Enterprise Holdings, Inc.Inventors: Brian J. Swetlin, Kenneth A. Mazich, Shaun Adkins Leone
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Patent number: 7514503Abstract: The present invention provides a molded article obtained from an aliphatic polyester resin composition comprising 60 to 99.9 parts by weight of at least one aliphatic polyester (A) and 0.1 to 40 parts by weight of at least one elastic polymer (B), provided that the total amount of the components (A) and (B) is 100 parts by weight, wherein the aliphatic polyester component in the molded article has an enthalpy of crystal fusion ?H determined using a differential scanning calorimeter of 5 J/g or more, the molded article has a continuous phase composed of the aliphatic polyester (A) and dispersed phases composed of the elastic polymer (B), and the distance T between the walls of the dispersed phases is less than 5.0 ?m.Type: GrantFiled: October 7, 2004Date of Patent: April 7, 2009Assignee: Asahi Kasei Chemicals CorporationInventors: Motonori Nakamichi, Tetsuo Ueno, Jun Yonezawa, Eiko Kobayashi, Kazuaki Saito, Takaaki Matsuda
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Patent number: 7498385Abstract: Crosslinked polymer compositions have backbones with first and second divalent saturated aliphatic moieties, a divalent saturated aliphatic secondary alcohol moiety, and a trivalent saturated aliphatic moiety. Hydrolytically labile ester bonds joined together these moieties. These polyesters may be polycondensation reaction products of a diol, a triol and a diacid. A molar ratio of the first divalent saturated aliphatic moiety, the divalent saturated aliphatic secondary alcohol moiety, and the trivalent saturated aliphatic moiety to the second divalent saturated aliphatic moiety is in the range of about 0.85 to about 1.5. Preferably, these polyesters are non-cytotoxic, biocompatible, bioabsorbable, or exhibit shape memory behavior with at least one transition temperature of greater than about 30° C. and less than about 100° C. and most preferably exhibit each of these qualities. The compositions may be adapted for a wide variety of uses, including medical applications.Type: GrantFiled: February 26, 2007Date of Patent: March 3, 2009Assignee: Gore Enterprise HoldingsInventors: Brian J. Swetlin, Kenneth A. Mazich
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Publication number: 20080317693Abstract: The present patent application relates to a composition containing a certain type of polyester and a branched hydrocarbon compound. Also described is a cosmetic treatment method employing the composition and the use of this composition for caring for or making up the skin or lips. Novel polyesters are also described.Type: ApplicationFiled: June 19, 2008Publication date: December 25, 2008Applicant: L'OREALInventor: Audrey RICARD
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Patent number: 7378470Abstract: This invention relates to thermoplastic molding compositions with improved flowability based on a thermoplastic polyester and on at least one copolymer composed of at least one olefin with at least one methacrylic ester or acrylic ester of an aliphatic alcohol, the MFI of the copolymer being not less than 50 g/10 min, to a process for preparation of these molding compositions, and also the use of these molding compositions for production of moldings for the electrical, electronics, telecommunications, motor vehicle or computer industry, in sports, in the household, in medicine or for the entertainment industry.Type: GrantFiled: November 30, 2005Date of Patent: May 27, 2008Assignee: LANXESS Deutschland GmbHInventors: Peter Persigehl, Detlev Joachimi, Kurt Jeschke, Marcus Schäfer, Ralph Ulrich, Robert Hubertus Van Mullekom, Jochen Endtner, Jens Peter Joschek, Matthias Bienmüller
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Patent number: 7192994Abstract: Disclosed is a method of producing a powdery coating material by using: a curable polyester resin (A) having a hydroxyl group and/or a carboxyl group at the terminals thereof, and further having a number average molecular weight of from 1,000 to 30,000, a glass transition temperature of from 30 to 100° C.; a curing agent (B) which is solid at normal temperature and is capable of being reacted with the hydroxyl group or the carboxyl group of the curable polyester resin (A); and a solvent (C) having a boiling point under normal pressure of from 50 to 130° C.; and comprising a step of kneading the curable polyester resin (A), the curing agent (B) and the solvent (C) under condition in which at 50 to 130° C., not less than 20% by weight of the curing agent (B) is dissolved in the solvent and, then, vapor-removing the solvent (C) under a reduced pressure.Type: GrantFiled: October 12, 2004Date of Patent: March 20, 2007Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Nobuyuki Koike, Shojiro Kuwahara
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Patent number: 7157526Abstract: Aqueous primary dispersion, substantially or entirely free of volatile organic compounds, and comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core/shell particles with a particle diameter?500 nm, preparable by free-radical micro- or miniemulsion polymerization of at least one olefinically unsaturated monomer in the presence of at least one hydrophobic additive and of at least one oligomeric polyester with a number-average molecular weight of from 150 to 1 500 daltons, a hydroxyl number of from 100 to 1 000 mg KOH/g, and an acid number<20 mg KOH/g and also a process for preparing it and its use as a coating material, adhesive or sealing compound or to prepare a coating material, an adhesive or a sealing compound.Type: GrantFiled: February 13, 2002Date of Patent: January 2, 2007Assignee: BASF Coatings AGInventors: Ralf Nickolaus, Heinz-Peter Rink, Reinhold Clauss, Elisabeth Wessling, Wilma Löcken, Nicole Freitag, Dunja Mikolajetz
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Patent number: 6979716Abstract: This invention is related to a production method of a branched polymer which comprises polymerizing a macromonomer [I], said macromonomer [I] being a vinyl polymer obtainable by radical polymerization and terminally having one polymerizable carbon—carbon double bond-containing group per molecule. Furthermore, by producing the macromonomer by living radical polymerization, in particular atom transfer radical polymerization, it becomes possible to produce the above polymers or gels having well controlled side chain molecular weights.Type: GrantFiled: June 18, 1999Date of Patent: December 27, 2005Assignee: Kaneka CorporationInventors: Yoshiki Nakagawa, Shigeki Ono, Masayuki Fujita, Kenichi Kitano
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Patent number: 6822022Abstract: Disclosed is a method of producing a powdery coating material by using: a curable polyester resin (A) having a hydroxyl group and/or a carboxyl group at the terminals thereof, and further having a number average molecular weight of from 1,000 to 30,000, a glass transition temperature of from 30 to 100° C.; a curing agent (B) which is solid at normal temperature and is capable of being reacted with the hydroxyl group or the carboxyl group of the curable polyester resin (A); and a solvent (C) having a boiling point under normal pressure of from 50 to 130° C.; and comprising a step of kneading the curable polyester resin (A), the curing agent (B) and the solvent (C) under condition in which at 50 to 130° C., not less than 20% by weight of the curing agent (B) is dissolved in the solvent and, then, vapor-removing the solvent (C) under a reduced pressure.Type: GrantFiled: March 13, 2002Date of Patent: November 23, 2004Assignee: Mitsubishi Gas Chemical INCInventors: Nobuyuki Koike, Shojiro Kuwahara
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Patent number: 6780502Abstract: This invention relates to an insulating resin composition which exhibits high impact resistance and heat resistance and good adhesiveness to the plating metal, is selectively etchable by a permanganate salt commonly used in a plating operation and suited for an insulating layer in multilayer wiring boards. The insulating resin composition is a photo-polymerizable or thermally polymerizable resin composition comprising 3-10 parts by weight of a crosslinked elastic polymer per 100 parts by weight of a resin component (excluding the crosslinked elastic poly and including monomers) and said crosslinked elastic polymer has carboxyl groups and is dispersed with an average secondary particle diameter in the range of 0.5-2 &mgr;m.Type: GrantFiled: October 2, 2002Date of Patent: August 24, 2004Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Shinji Inaba, Koji Nakamura, Koichi Fujishiro, Kazuhiko Mizuuchi
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Patent number: 6656531Abstract: A method for forming a coated film comprises (1) applying a water or solvent based coating composition on an undercoated or intercoated substrate to form a base coating, (2) applying a clear coating composition thereon to form a clear coating without curing the base coating, and (3) heating and curing both the base coating and clear coating, wherein the clear coating composition comprises as a binder (a) from 10-70% by weight of an acrylic polycarboxylic acid having on average 2 or more carboxyl groups per molecule obtained by copolymerizing an acid anhydride group-containing ethylenically unsaturated monomer with an ethylenically unsaturated monomer having no acid anhydride group, then reacting the resulting copolymer with a monoalcohol; (b) from 5-70% by weight of a polyester polycarboxylic acid having an acid value of from 50-350 mg KOH/g (solid) obtained by reacting a polyester polyol having 3 or more hydroxyl groups with an acid anhydride group-containing compound; (c) from 10-80% by weight of a poType: GrantFiled: April 30, 2002Date of Patent: December 2, 2003Assignee: Nippon Paint Co., Ltd.Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
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Thermosetting powder coating composition, method of preparation thereof and coated article therewith
Patent number: 6649267Abstract: A thermosetting powder coating composition has an average particle diameter of entire particles is within a range from 5 to 50 &mgr;m, an average circularity of the particles is 0.90 or more, and a circularity of particles having a maximum number frequency in circularity distribution is within a range from 0.98 to 1.00, prepared by spray-drying an organic solvent solution containing, as a coating film forming component, an epoxy group-containing vinyl copolymer (A) having a glass transition temperature of 40° C. or higher, an epoxy group-containing vinyl copolymer (B) having a glass transition temperature of 0° C. or lower and a polycarboxylic acid (C) as an essential component.Type: GrantFiled: June 11, 2002Date of Patent: November 18, 2003Assignees: Dainippon Ink and Chemicals, Inc., Liquid Gas Co., Ltd.Inventors: Tetsuro Agawa, Katsuhiko Okada, Hiroo Tanaka, Masaya Hashimoto, Takaaki Asakura -
Patent number: 6599993Abstract: A powder coating composition that includes at least about 9% by weight, based on total vehicle weight, of a branched carboxylic acid-functional polyester having a number average molecular weight of from about 425 to about 1050 and at least one vehicle component reactive with carboxylic acid groups comprising an epoxy-functional material, produces a matte, textured coating.Type: GrantFiled: October 11, 2000Date of Patent: July 29, 2003Assignee: BASF CorporationInventors: William C. Norris, Josef Rademacher
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Patent number: 6472471Abstract: Various modified carbon products are disclosed which can form a part of a polymeric product containing the modified carbon product and a polymer. One type of modified carbon product disclosed is a carbon product having attached at least one organic group, monomeric group, or polymeric group. Another type of modified carbon product disclosed is a carbon product having attached a group having the formula: —Ar—CO2—R or —CnH2nCO2—R where R is an organic group, monomeric group, or a polymeric group.Type: GrantFiled: December 14, 1998Date of Patent: October 29, 2002Assignee: Cabot CorporationInventors: Joel M. Cooke, Collin P. Galloway, Mark A. Bissell, Curtis E. Adams, Michael C. Yu, James A. Belmont, Robert M. Amici
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Patent number: 6410647Abstract: A high-solid curable resin composition which forms a coated film having excellent acid rain resistance, mar resistance and appearance comprises: (a) 10 to 70% by weight of an acrylic polycarboxylic acid having 2 or more carboxyl groups per molecule on an average, an acid value of 5 to 300 mg KOH/g (solid) and a number-average molecular weight of 500 to 8000; (b) 5 to 70% by weight of a polyester polycarboxylic acid having an acid value of 50 to 350 mg KOH/g (solid), a number-average molecular weight of 400 to 3500 and a ratio of weight-average molecular weight to number-average molecular weight of 1.Type: GrantFiled: November 30, 1999Date of Patent: June 25, 2002Assignee: Nippon Paint Co., Ltd.Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
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Patent number: 6406753Abstract: Coating composition especially for preparing automotive surfacers, comprising an anionically stabilized resin, preferably a condensation product A of a carboxyl group-containing resin A1 and a hydroxyl group-containing resin A2, and a curing agent C, which becomes active even at room temperature or slightly elevated temperature of up to not more than 120° C., and comprises a mixture of an unblocked isocyanate C1 and a hydrophilic partially etherified amino resin C2.Type: GrantFiled: November 30, 2000Date of Patent: June 18, 2002Assignee: Solutia Austria AGInventors: Gert Dworak, Ulrike Kuttler
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Patent number: 6391970Abstract: A resinous binder useful in clear coat compositions comprises a) a polyepoxide such as a copolymer of an ethylenically unsaturated epoxide with other (meth)acrylate(s) or styrene, b) a polyacid such as a carboxyl-terminated polyester, and c) a polyisocyanate.Type: GrantFiled: December 2, 1998Date of Patent: May 21, 2002Assignee: BASF CorporationInventors: Swaminathan Ramesh, Manoj K. Gupta
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Patent number: 6171654Abstract: Water-soluble or water-dispersible and curable polyester resins are suitable as binders in various applications, The resins are reaction products of polyterephthalate, polyols, polyacids, end acids and crosslinking agents. The waste terephthalates can be utilized when making the binders of the present invention. The preferred polyol is pentaerythritol. The resins can be used as binder for glass fiber insulation products.Type: GrantFiled: August 24, 1999Date of Patent: January 9, 2001Assignee: Seydel Research, Inc.Inventors: Robert Keith Salsman, Timothy Shouting Wang
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Patent number: 6121382Abstract: Disclosed is a surface treatment agent for aqueous ink receiving media such as ink jet recording paper, printing sheets, coating materials and so on. The surface treatment agent according to the invention comprises a water-based resin and a carboxylic acid-containing hydrophilic sulfopolyester which provides superior adhesion and water resistance. With the superior adhesion properties, the surface treatment agent can be directly coated on substrates without the inconvenience of primer coating. The surface treatment agent of the invention is suitable for aqueous ink jet printing, coating, or recording media, particularly those of ink jet printers and ink jet plotters.Type: GrantFiled: April 16, 1998Date of Patent: September 19, 2000Assignee: Industrial Technology Research InstituteInventors: Shinn-Jen Chang, Yih-Her Chang, Rong-Shuh Chang, Wan-Jung Teng, Yuan-Tung Hung
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Patent number: 6020431Abstract: Dynamic vulcanizates of an engineering thermoplastic ("plastic"), e.g. a polyamide or polyester, with acrylate rubbers having dissimilar functional groups are prepared with a metal fatty acid salt in the absence of a conventional curative, provided the rubbers are molecularly intermixed. An acrylate rubber with halogen functionality ("AcrRubHal") is thus crosslinked in a single mixing stage with an acrylate rubber having carboxyl, hydroxyl or epoxy functionality ("AcrRubX") in a "plastic". Quaternary ammonium salts and tertiary amines do not function as curatives, as one might expect. But a metal fatty acid salt, preferably a metal stearate or oleate and concentrates thereof effectively crosslink the rubbers. TPVs produced without conventional curing agents are relatively "soft", but have highly desirable low temperature physical properties and oil resistance.Type: GrantFiled: July 2, 1998Date of Patent: February 1, 2000Assignee: Advanced Elastomer Systems, L.P.Inventors: Krishna Venkataswamy, Tonson Abraham
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Patent number: 5948866Abstract: A powder paint composition and application method therefor are provided which can form a paint coating which has superior mar resistance and for which the external appearance, such as its smoothness and sharpness, is excellent.This paint powder composition comprises a multi-functional vinyl-type copolymer (A) which has a glass transition temperature of 40.degree. C. and which contains functional groups which are reactable with carboxylic acid; a polycarboxylic acid (B); and a multi-functional vinyl-type copolymer (C) which has a glass transition temperature of 0.degree. C. and which contains functional groups which are reactable with carboxylic acid.Type: GrantFiled: August 19, 1997Date of Patent: September 7, 1999Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Hirofumi Takeda, Ikuo Nakaya, Michiya Sugiyama, Akio Shoji
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Patent number: 5587429Abstract: A processing aid system composition containing fluoropolymer processing aid, polar-side-group-containing extrusion adjuvant, and poly(oxyalkylene) polymer enhances extrusion of polyolefins.Type: GrantFiled: April 4, 1995Date of Patent: December 24, 1996Assignee: E. I. DuPont de Nemours and CompanyInventor: Donnan E. Priester
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Patent number: 5580926Abstract: Curable compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhydride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; and(iv) a hydroxy-functional compound having an average of at least two hydroxyl groups per molecule;wherein at least one of the compounds (i), (ii), (iii) or (iv) comprises a film forming polymer.Type: GrantFiled: August 26, 1991Date of Patent: December 3, 1996Assignee: The Sherwin-Williams CompanyInventors: Mohamad D. Shalati, James A. Marquart, Sandra H. Angelo, Rodney M. Harris
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Patent number: 5516846Abstract: Coating compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhydride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; wherein at least one of the compounds (i), (ii), or (iii) comprises a film forming polymer.Type: GrantFiled: August 25, 1995Date of Patent: May 14, 1996Assignee: The Sherwin-Williams CompanyInventors: Mohamad D. Shalati, James A. Marquart, John L. Petty, Rodney M. Harris
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Patent number: 5409764Abstract: A curable adhesive composition comprising an unsaturated polyester oligomer (A) of any of the following formulae (I) to (IV), obtained by reacting a compound (a) having a hydroxyl group and/or an amino group, a cyclic acid anhydride (b) and an epoxide (c) having an ethylenically unsaturated group, and an adhesive polymer (B), ##STR1## wherein: R.sub.1 is a divalent organic moiety having 1 to 40 carbon atoms,R.sub.2 is a divalent organic moiety having 1 to 10 carbon atoms,R.sub.3 is hydrogen or methyl,R.sub.4 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.5 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.6 is hydrogen or a monovalent organic moiety having 1 to 10 carbon atoms, andn is an integer of 2 or greater.Type: GrantFiled: September 23, 1994Date of Patent: April 25, 1995Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Tsukasa Otsuki, Masato Yanagi, Toshikazu Onikubo, Kouichi Iibuchi
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Patent number: 5405657Abstract: A process for the production of flexible impregnated protective, auxiliary and insulating materials on a fibre basis for electrical purposes by the application of an impregnating agent to the material to be impregnated, followed by curing, characterised in that a solvent-free impregnating mass containing one or more olefinically unsaturated, radically polymerisable polyesters, which contain one or more radically polymerisable monomers as reactive diluents, one or more plasticizing agents and optionally one or more peroxide-free radical initiators is applied to the material to be impregnated and curing is then carried out with high energy radiation and optionally by further heating.Type: GrantFiled: November 2, 1993Date of Patent: April 11, 1995Assignee: Herberts G.m.b.H.Inventors: Udo Bastian, Rainer Krause, Gerhard Kiessling
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Patent number: 5202382Abstract: A thermosetting powder coating composition which has good stability, pigment dispersion and impact characteristics is disclosed. The composition comprises a co-reactable particle mixture of an acid group-containing acrylic polymer having a Tg in the range of -20.degree. C. to 30.degree. C., an acid group-containing acrylic polymer having a Tg in the range of 40.degree. C. to 100.degree. C. and a curing agent, therefor.Type: GrantFiled: January 9, 1992Date of Patent: April 13, 1993Assignee: PPG Industries, Inc.Inventor: Paul H. Pettit, Jr.
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Patent number: 5124176Abstract: A powder coating composition comprises a component (A) containing carboxylic acid or anhydride functionality and a component (B) containing hydroxy functionality. The components (A) and (B) are both solids at temperatures up to 50.degree. C. and at least one of them is a synthetic resin having a glass transition temperature in the range 0.degree. to 120.degree. C. The carboxylic acid or anhydride-functional component (A) is a compound or polymer containing at least two cyclic carboxylic anhydride groups per molecule or is a compound containing a moiety of the formula: ##STR1## where X is a hydrogen atom or an alkyl group, or a cyclic anhydride thereof. The hydroxy-functional component (B) contains at least two hydroxy groups per molecule and contains at least one amine group in its molecule to catalyze the reaction of the carboxylic acid or anhydride groups of component (A) with the hydroxy groups of component (B).Type: GrantFiled: May 3, 1989Date of Patent: June 23, 1992Assignee: International Paint public limited companyInventor: Alastair R. Marrion
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Patent number: 5098955Abstract: A thermosetting powder coating composition which has good stability, pigment dispersion and impact characteristics is disclosed. The composition comprises a co-reactable particle mixture of an acid group-containing acrylic polymer having a Tg in the range of -20.degree. C. to 30.degree. C., an acid group-containing acrylic polymer having a Tg in the range of 40.degree. C. to 100.degree. C. and a curing agent, therefor.Type: GrantFiled: October 1, 1990Date of Patent: March 24, 1992Assignee: PPG Industries, Inc.Inventor: Paul H. Pettit, Jr.
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Patent number: 5055524Abstract: There is disclosed herein an improved thermosetting powder coating composition comprising an epoxy resin and a curing agent, the improvement comprising the curing agent which is a polyol-modified polymeric polyanhydride containing anhydride linkages in the polymeric backbone.Type: GrantFiled: July 16, 1987Date of Patent: October 8, 1991Assignee: PPG Industries, Inc.Inventors: Paul H. Pettit, Jr., Debra L. Singer, William S. Ewing
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Patent number: 4988767Abstract: A thermosetting powder coating composition which has good stability, pigment dispersion and impact characteristics is disclosed. The composition comprises a co-reactable particle mixture of an acid group-containing acrylic polymer having a Tg in the range of -20.degree. C. to 30.degree. C., an acid group-containing acrylic polymer having a Tg in the range of 40.degree. C. to 100.degree. C. and a curing agent, therefor.Type: GrantFiled: September 18, 1989Date of Patent: January 29, 1991Assignee: PPG Industries, Inc.Inventor: Paul H. Pettit, Jr.
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Patent number: 4950717Abstract: A compatible polymer blend, comprising(i) about 10 to 90 weight percent of an ethylene-acrylic acid copolymer comprising from about 10 to 50 mole percent acrylic acid monomer units; and(ii) about 90 to 10 weight percent of a polyester-ether derived from 1,4-cyclohexane dicarboxylic acid, 1,4-cyclohexane dimethanol and poly(oxytetramethylene) glycol.Type: GrantFiled: June 2, 1989Date of Patent: August 21, 1990Assignee: Eastman Kodak CompanyInventors: Robert W. Seymour, Thomas E. Flora
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Patent number: 4902771Abstract: An imido-modified unsaturated polyester resin composition comprising an imido-modified unsaturated polyester obtainable by reacting an animal or vegetable fat and oil or a fatty acid thereof, an imido alcohol obtainable from a primary amino-alcohol and a polybasic acid anhydride, a polyhydroxy alcohol, and a polybasic acid in such a manner that the imido alcohol is used in an amount of 10 to 60% equivalent amount based on the alcoholic components; and a polymeric monomer.In one of the preferred embodiments, the composition according to the present invention further contains an inorganic filler.According to the present invention, there can be provided resin composition in which the compatibility under heat deterioration when used in enamelled wires has been improved, while maintaining excellent electrical and mechanical properties.Type: GrantFiled: August 23, 1988Date of Patent: February 20, 1990Assignee: Hitachi Chemical Company, Ltd.Inventors: Yasuo Sugawara, Yuuji Aimono, Hatuo Sugitani
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Patent number: 4895901Abstract: The present invention relates to novel compounds corresponding to the formula: ##STR1## wherein R.sub.1 and R.sub.4 may be the same or different, and each is a lower alkyl radical; R.sub.2 and R.sub.3 may be the same or different, and each is a substituted piperidine radical; M is equal to the total number of monomer units in the polymer chain, and is of a magnitude sufficient to provide a polymer having a molecular weight of at least 500; W is equal to at least 0.5, X is equal to at least 0.1 but not greater than 0.2, Y is equal to at least 0.1, Z is equal to at least 0.05 but not greater than 0.2, and W plus X plus Y plus Z is equal to 1.These novel compounds are useful as stabilizers for a wide variety of organic materials and are prepared by transesterification of a suitable acrylate-methacrylate copolymer.Type: GrantFiled: November 23, 1988Date of Patent: January 23, 1990Assignee: Ferro CorporationInventors: Chester E. Ramey, Ronald E. Thompson, Charles J. Rostek, Jr.
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Patent number: 4871806Abstract: Curable compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhdyride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; and(iv) a hydroxy-functional compound having an average of at least two hydroxyl groups per molecule;wherein at least one of the compounds (i), (ii), (iii) or (iv) comprises a film forming polymer.Type: GrantFiled: November 16, 1987Date of Patent: October 3, 1989Assignee: The Sherwin-Williams CompanyInventors: Mohamad D. Shalati, James A. Marquart
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Patent number: 4849475Abstract: Water-dilutable paint binders based on acrylates for cathodically depositable paints particularly suited for the formulation of decorative single coats or pale primers are described. The binders are partial condensation products of from 60% to 90% by weight of a hydroxy and amino group containing acrylic copolymer, the basic groups of which were obtained through reaction of glycidyl groups with secondary amines, with 10% to 40% by weight of an oliogomeric or polymeric compound carrying CH-active ester groups, preferably malonic acid ester groups, capable of transesterification or transamidation. The paint films afford particularly good yellowing resistance, detergent resistance, and abrasion resistance.Type: GrantFiled: November 16, 1987Date of Patent: July 18, 1989Assignee: Vianova Kunstharz, A.G.Inventors: Herbert Zima, Josef Forstner
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Patent number: 4789706Abstract: A polyester composition having an average molecular weight of greater than 450 comprising a most prevalent compound having a main polyester chain containing at least 17 and fewer than 52 carbon atoms and at least 6 and fewer than 18 oxygen atoms, at least 40 weight percent of the molecules of said composition having a molecular weight within 50% of the average molecular weight of the composition. Often less than 36 weight percent of the molecules of the composition having a molecular weight greater than 150 percent of the average molecular weight and less than 12 weight percent of the molecules of the composition having a molecular weight less than 50 percent of the average molecular weight of the composition. The polyester composition desirably contains at least 1.6 equivalents of unreacted hydroxy groups or at least 1.6 equivalents of unreacted carboxy groups per mole. The composition contains at least four equivalents of ester links in the main chains of the molecules per mole.Type: GrantFiled: March 23, 1988Date of Patent: December 6, 1988Assignee: NL Chemicals, Inc.Inventor: Roy C. Williams
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Patent number: 4743655Abstract: A polyester composition having an average molecular weight of greater than 450 comprising a most prevalent compound having a main polyester chain containing at least 17 and fewer than 52 carbon atoms and at least 6 and fewer than 18 oxygen atoms, at least 40 weight percent of the molecules of said composition having a molecular weight within 50% of the average molecular weight of the composition. The polyester composition desirably contains at least 1.6 equivalents of unreacted hydroxy groups or at least 1.6 equivalents of unreacted carboxy groups per mole. The composition contains at least four equivalents of ester links in the main chains of the molecules per mole.The composition of the present invention is obtained by the method of the invention wherein alternating series of reactions are each driven essentially to completion where the final molecule of each reaction provides the only available reaction site for the next alternate monomer reaction.Type: GrantFiled: April 20, 1987Date of Patent: May 10, 1988Assignee: NL Chemicals, Inc.Inventor: Roy C. Williams
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Patent number: 4436869Abstract: A process for the preparation of moldings, in particular resilient elements, which by virtue of a densified surface zone with substantially closed cells, have only a low water absorption, wherein a mixture comprising:(a) 100 parts by weight of an NCO-containing prepolymer, having an NCO content of from 3 to 6% by weight and based on organic diisocyanates and substantially linear polyester-polyols or polytetramethylene ether glycol,(b) from 0.5 to 1.6 parts by weight of water,(c) one or more catalysts, preferably a tertiary amine, in an amount of from 0.01 to 2.0 parts by weight and(d) assistants, with or without additives, is reacted in a closed mold, while undergoing densification, the surface temperature of the inner wall of the mold being from 50.degree. to 70.degree. C.Type: GrantFiled: March 30, 1982Date of Patent: March 13, 1984Assignee: Elastogran GmbHInventors: Otmar Zipp, Heinz Bollmann, Herbert Stutz, Wolfgang Scholz
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Patent number: 4405662Abstract: A thermosetting resinous binder composition, heat-curable in combination with a transesterification-promoting metal compound as a catalyst to provide an insoluble infusible coating, comprising a mixture of:(1) a non-acidic resinous compound essentially free of ethylenical unsaturation, having a molecular weight of at least 900 and a hydroxyl content of at least 0.Type: GrantFiled: September 24, 1982Date of Patent: September 20, 1983Assignee: Shell Oil CompanyInventors: Werner T. Raudenbusch, Adrianus J. M. Barnhoorn, Petrus G. Kooijmans, Willem L. Sederel, Adrianus M. C. Van Steenis, Theresia F. M. Schets
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Patent number: 4397990Abstract: A thermosetting binder composition for coating, comprising:(1) A non-acidic resinous saturated compound having a molecular weight of at least 900, and an alcoholic hydroxyl content of at least 0.2 eq./100 g;(2) A non-acidic polyester of a polycarboxylic acid cross-linking agent having more than one .beta.-hydroxyl ester group per molecule, and at least one of components (1) and (2) having an alcoholic hydroxyl functionality of more than 2, and(II) A transesterification-promoting metal salt or complex curing catalyst which is soluble in liquid hydrocarbons.For aqueous compositions, component (I) (1) is preferably a neutralized epoxy resin/amine adduct and component (II) should be insoluble in water; they can be used for cathodic electrodeposition.Type: GrantFiled: February 16, 1982Date of Patent: August 9, 1983Assignee: Shell Oil CompanyInventors: Petrus G. Kooymans, Johannes J. M. H. Wintraecken, Werner T. Raudenbusch, Josepha M. E. Seelen-Kruijssen, Gerardus C. M. Schreurs
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Patent number: 4373059Abstract: The invention concerns a pre-condensed, thermosetting aqueous lacquer coating material containing a pre-condensation product that becomes water-dilutable after protonization with acids and has a mean molecular weight [M.sub.n ] of 800 to 15,000, obtainable by heating of 55 to 95% by weight, based on the total quantity of the binding agent, of an organic synthetic-resin binder containing primary and/or secondary amino groups which has an amine number of 30 to 150 and 5 to 45% by weight of a crosslinking agent possessing esterified terminal carboxyl groups.The invention moreover concerns the application of this lacquer coating material for cathodic deposition upon electrically conducting surfaces.Type: GrantFiled: September 2, 1980Date of Patent: February 8, 1983Assignee: Herberts Gesellschaft mit Beschrankter HaftungInventors: Hans-Peter Patzschke, Armin Gobel
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Patent number: 4362847Abstract: The present invention is directed to thermosetting binder compositions for coating, comprising:(I) (1) A non-acidic resinous compound, saturated, molecular weight at least 900, alcoholic hydroxyl content at least 0.2 eq/100 g;(2) a cross-linking agent comprising a non-acidic polyester of a polycarboxylic acid, having more than one beta-hydroxyl ester group per molecule, at least one of components (1) and (2) having an alcoholic hydroxyl functionality of more than 2, and(II) a curing catalyst comprising a transesterification-promoting metal compound which is insoluble in liquid hydrocarbons.These compositions can be used in solvent-based lacquers and paints, in coating powders, aqueous powder suspensions, in aqueous coating compositions for cathodic electrodeposition; for aqueous compositions component (I) (1) is preferably an epoxy resin/amine adduct.Type: GrantFiled: April 20, 1981Date of Patent: December 7, 1982Assignee: Shell Oil CompanyInventors: Petrus G. Kooijmans, Werner T. Raudenbusch, Adrianus M. C. Van Steenis, Wolfgang Kunze, Josepha M. E. Seelen-Kruijssen
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Patent number: 4320045Abstract: A resin molding composition comprising a thermoplastic polymer, a monomer and an unsaturated polyester which is the reaction product of at least one polyol having at least two, but not more than four hydroxyl groups, the polyols comprising not less than about 48% of the weight of the reactants forming the polyester.Type: GrantFiled: April 10, 1981Date of Patent: March 16, 1982Assignee: Owens-Corning Fiberglas CorporationInventor: Gwilym Owen