Polycarboxylic Acid Or Derivative Contains Three Or More Carboxylic Acid Groups Or Derivatives Thereof; Or Wherein A Polyol Contains At Least Three Hydroxyl Groups Patents (Class 525/172)
  • Patent number: 11286401
    Abstract: A powder coating composition comprising: a) a thermoset resin comprising an acid functional polyester material, b) a thermoplastic resin and c) a crosslinker material, wherein the coating composition is substantially free of bisphenol A (BPA), bisphenol F (BPF), bisphenol A diglycidyl ether (BADGE) and bisphenol F diglycidyl ether (BFDGE).
    Type: Grant
    Filed: November 2, 2020
    Date of Patent: March 29, 2022
    Assignee: PPG Industries Ohio, Inc.
    Inventors: William H. Retsch, Jr., Anthony M. Chasser, Edward R. Millero, Jr., John M. Dudik
  • Publication number: 20130287682
    Abstract: The present invention is directed to a novel poly (diol citrates)-based coating for implantable devices. More specifically, the specification describes methods and compositions for making and using implantable devices coated with citric acid copolymers or citric acid copolymers impregnated with therapeutic compositions and/or cells.
    Type: Application
    Filed: March 21, 2013
    Publication date: October 31, 2013
    Inventors: Guillermo Ameer, Jian Yang
  • Patent number: 8097076
    Abstract: Low-VOC mixture of at least partially salified copolymers of at least one ethylenically unsaturated, phenyl-group-containing monomer and at least one ?,?-unsaturated monocarboxylic acid and/or at least one ?,?-unsaturated dicarboxylic acid, of at least one water-soluble polyether, esterification products of at least one water-soluble polyether and an aliphatic dicarboxylic acid, and of a star polymer obtainable by esterifying a carboxylic acid containing at least 3 carboxyl groups with at least one water-soluble polyether, and use thereof as a wetting and dispersing agent, preferably for producing low-VOC pigment pastes or low-VOC paint systems.
    Type: Grant
    Filed: July 28, 2010
    Date of Patent: January 17, 2012
    Assignee: BYK-Chemie GmbH
    Inventors: Bernd Göbelt, Carsten Nagel, Jürgen Omeis, Marcus Meichsner, Diana Walter
  • Publication number: 20110245393
    Abstract: The invention pertains to low profile additives (“LPA”) comprising branched polymers having a weight average molecular weight (Mw) of at least about 20,000 grams/mole and a number average molecular weight (Mn) of at least about 3,000 grams/mole and methods for making the LPAs. The invention further concerns compositions comprising LPAs synthesized from one or more Bifunctional monomers and one or more branching agents. Also, disclosed are thermosettable resinous compositions and molded articles comprising the LPAs.
    Type: Application
    Filed: June 17, 2011
    Publication date: October 6, 2011
    Inventors: Husam A.A. Rasoul, Dejan D. Andjelkovic, Dennis H. Fisher
  • Patent number: 7812097
    Abstract: An improved curable formaldehyde-free binding composition is provided. Such curable composition comprises the reaction product of a polyanhydride and a polyol crosslinker and a lower molecular weight anhydride. Initially, the polyanhydride is modified through reaction with a polyol (e.g., a glycol or an alkanolamine) and subsequently is grafted with the lower molecular weight anhydride (e.g., maleic anhydride) to form a water-soluble or water-dispersible curable reaction product. The composition is well suited for binding fibrous materials (e.g., a mat of glass fibers) or for bonding together non-fibrous materials. The binder composition displays an advantageous viscosity so as to facilitate a flowable application with ease combined with an adequately high molecular weight to satisfactorily undergo service as a binder following curing even when harsh environmental conditions (e.g., hot humid air) are encountered for a prolonged period of time.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: October 12, 2010
    Assignee: Johns Manville
    Inventor: Kiarash Alavi Shooshtari
  • Patent number: 7608670
    Abstract: An improved curable formaldehyde-free binding composition is provided. Such curable composition comprises the reaction product of a polyanhydride and a polyol crosslinker and a lower molecular weight anhydride. Initially, the polyanhydride is modified through reaction with a polyol (e.g., a glycol or an alkanolamine) and subsequently is grafted with the lower molecular weight anhydride (e.g., maleic anhydride) to form a water-soluble or water-dispersible curable reaction product. The composition is well suited for binding fibrous materials (e.g., a mat of glass fibers) or for bonding together non-fibrous materials. The binder composition displays an advantageous viscosity so as to facilitate a flowable application with ease combined with an adequately high molecular weight to satisfactorily undergo service as a binder following curing even when harsh environmental conditions (e.g.
    Type: Grant
    Filed: November 20, 2006
    Date of Patent: October 27, 2009
    Assignee: Johns Manville
    Inventor: Kiarash Alavi Shooshtari
  • Patent number: 7557167
    Abstract: Crosslinked polymer compositions have backbones with first and second divalent saturated aliphatic moieties, a divalent saturated aliphatic secondary alcohol moiety, and a trivalent saturated aliphatic moiety. Hydrolytically labile ester bonds joined together these moieties. These polyesters may be polycondensation reaction products of a diol, a triol and a diacid. A molar ratio of the first divalent saturated aliphatic moiety, the divalent saturated aliphatic secondary alcohol moiety, and the trivalent saturated aliphatic moiety to the second divalent saturated aliphatic moiety is in the range of about 0.85 to about 1.5. Preferably, these polyesters are non-cytotoxic, biocompatible, bioabsorbable, or exhibit shape memory behavior with at least one transition temperature of greater than about 30° C. and less than about 100° C. and most preferably exhibit each of these qualities. The compositions may be adapted for a wide variety of uses, including medical applications.
    Type: Grant
    Filed: September 28, 2006
    Date of Patent: July 7, 2009
    Assignee: Gore Enterprise Holdings, Inc.
    Inventors: Brian J. Swetlin, Kenneth A. Mazich, Shaun Adkins Leone
  • Patent number: 7514503
    Abstract: The present invention provides a molded article obtained from an aliphatic polyester resin composition comprising 60 to 99.9 parts by weight of at least one aliphatic polyester (A) and 0.1 to 40 parts by weight of at least one elastic polymer (B), provided that the total amount of the components (A) and (B) is 100 parts by weight, wherein the aliphatic polyester component in the molded article has an enthalpy of crystal fusion ?H determined using a differential scanning calorimeter of 5 J/g or more, the molded article has a continuous phase composed of the aliphatic polyester (A) and dispersed phases composed of the elastic polymer (B), and the distance T between the walls of the dispersed phases is less than 5.0 ?m.
    Type: Grant
    Filed: October 7, 2004
    Date of Patent: April 7, 2009
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Motonori Nakamichi, Tetsuo Ueno, Jun Yonezawa, Eiko Kobayashi, Kazuaki Saito, Takaaki Matsuda
  • Patent number: 7498385
    Abstract: Crosslinked polymer compositions have backbones with first and second divalent saturated aliphatic moieties, a divalent saturated aliphatic secondary alcohol moiety, and a trivalent saturated aliphatic moiety. Hydrolytically labile ester bonds joined together these moieties. These polyesters may be polycondensation reaction products of a diol, a triol and a diacid. A molar ratio of the first divalent saturated aliphatic moiety, the divalent saturated aliphatic secondary alcohol moiety, and the trivalent saturated aliphatic moiety to the second divalent saturated aliphatic moiety is in the range of about 0.85 to about 1.5. Preferably, these polyesters are non-cytotoxic, biocompatible, bioabsorbable, or exhibit shape memory behavior with at least one transition temperature of greater than about 30° C. and less than about 100° C. and most preferably exhibit each of these qualities. The compositions may be adapted for a wide variety of uses, including medical applications.
    Type: Grant
    Filed: February 26, 2007
    Date of Patent: March 3, 2009
    Assignee: Gore Enterprise Holdings
    Inventors: Brian J. Swetlin, Kenneth A. Mazich
  • Publication number: 20080317693
    Abstract: The present patent application relates to a composition containing a certain type of polyester and a branched hydrocarbon compound. Also described is a cosmetic treatment method employing the composition and the use of this composition for caring for or making up the skin or lips. Novel polyesters are also described.
    Type: Application
    Filed: June 19, 2008
    Publication date: December 25, 2008
    Applicant: L'OREAL
    Inventor: Audrey RICARD
  • Patent number: 7378470
    Abstract: This invention relates to thermoplastic molding compositions with improved flowability based on a thermoplastic polyester and on at least one copolymer composed of at least one olefin with at least one methacrylic ester or acrylic ester of an aliphatic alcohol, the MFI of the copolymer being not less than 50 g/10 min, to a process for preparation of these molding compositions, and also the use of these molding compositions for production of moldings for the electrical, electronics, telecommunications, motor vehicle or computer industry, in sports, in the household, in medicine or for the entertainment industry.
    Type: Grant
    Filed: November 30, 2005
    Date of Patent: May 27, 2008
    Assignee: LANXESS Deutschland GmbH
    Inventors: Peter Persigehl, Detlev Joachimi, Kurt Jeschke, Marcus Schäfer, Ralph Ulrich, Robert Hubertus Van Mullekom, Jochen Endtner, Jens Peter Joschek, Matthias Bienmüller
  • Patent number: 7192994
    Abstract: Disclosed is a method of producing a powdery coating material by using: a curable polyester resin (A) having a hydroxyl group and/or a carboxyl group at the terminals thereof, and further having a number average molecular weight of from 1,000 to 30,000, a glass transition temperature of from 30 to 100° C.; a curing agent (B) which is solid at normal temperature and is capable of being reacted with the hydroxyl group or the carboxyl group of the curable polyester resin (A); and a solvent (C) having a boiling point under normal pressure of from 50 to 130° C.; and comprising a step of kneading the curable polyester resin (A), the curing agent (B) and the solvent (C) under condition in which at 50 to 130° C., not less than 20% by weight of the curing agent (B) is dissolved in the solvent and, then, vapor-removing the solvent (C) under a reduced pressure.
    Type: Grant
    Filed: October 12, 2004
    Date of Patent: March 20, 2007
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Nobuyuki Koike, Shojiro Kuwahara
  • Patent number: 7157526
    Abstract: Aqueous primary dispersion, substantially or entirely free of volatile organic compounds, and comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core/shell particles with a particle diameter?500 nm, preparable by free-radical micro- or miniemulsion polymerization of at least one olefinically unsaturated monomer in the presence of at least one hydrophobic additive and of at least one oligomeric polyester with a number-average molecular weight of from 150 to 1 500 daltons, a hydroxyl number of from 100 to 1 000 mg KOH/g, and an acid number<20 mg KOH/g and also a process for preparing it and its use as a coating material, adhesive or sealing compound or to prepare a coating material, an adhesive or a sealing compound.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: January 2, 2007
    Assignee: BASF Coatings AG
    Inventors: Ralf Nickolaus, Heinz-Peter Rink, Reinhold Clauss, Elisabeth Wessling, Wilma Löcken, Nicole Freitag, Dunja Mikolajetz
  • Patent number: 6979716
    Abstract: This invention is related to a production method of a branched polymer which comprises polymerizing a macromonomer [I], said macromonomer [I] being a vinyl polymer obtainable by radical polymerization and terminally having one polymerizable carbon—carbon double bond-containing group per molecule. Furthermore, by producing the macromonomer by living radical polymerization, in particular atom transfer radical polymerization, it becomes possible to produce the above polymers or gels having well controlled side chain molecular weights.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: December 27, 2005
    Assignee: Kaneka Corporation
    Inventors: Yoshiki Nakagawa, Shigeki Ono, Masayuki Fujita, Kenichi Kitano
  • Patent number: 6822022
    Abstract: Disclosed is a method of producing a powdery coating material by using: a curable polyester resin (A) having a hydroxyl group and/or a carboxyl group at the terminals thereof, and further having a number average molecular weight of from 1,000 to 30,000, a glass transition temperature of from 30 to 100° C.; a curing agent (B) which is solid at normal temperature and is capable of being reacted with the hydroxyl group or the carboxyl group of the curable polyester resin (A); and a solvent (C) having a boiling point under normal pressure of from 50 to 130° C.; and comprising a step of kneading the curable polyester resin (A), the curing agent (B) and the solvent (C) under condition in which at 50 to 130° C., not less than 20% by weight of the curing agent (B) is dissolved in the solvent and, then, vapor-removing the solvent (C) under a reduced pressure.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: November 23, 2004
    Assignee: Mitsubishi Gas Chemical INC
    Inventors: Nobuyuki Koike, Shojiro Kuwahara
  • Patent number: 6780502
    Abstract: This invention relates to an insulating resin composition which exhibits high impact resistance and heat resistance and good adhesiveness to the plating metal, is selectively etchable by a permanganate salt commonly used in a plating operation and suited for an insulating layer in multilayer wiring boards. The insulating resin composition is a photo-polymerizable or thermally polymerizable resin composition comprising 3-10 parts by weight of a crosslinked elastic polymer per 100 parts by weight of a resin component (excluding the crosslinked elastic poly and including monomers) and said crosslinked elastic polymer has carboxyl groups and is dispersed with an average secondary particle diameter in the range of 0.5-2 &mgr;m.
    Type: Grant
    Filed: October 2, 2002
    Date of Patent: August 24, 2004
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Shinji Inaba, Koji Nakamura, Koichi Fujishiro, Kazuhiko Mizuuchi
  • Patent number: 6656531
    Abstract: A method for forming a coated film comprises (1) applying a water or solvent based coating composition on an undercoated or intercoated substrate to form a base coating, (2) applying a clear coating composition thereon to form a clear coating without curing the base coating, and (3) heating and curing both the base coating and clear coating, wherein the clear coating composition comprises as a binder (a) from 10-70% by weight of an acrylic polycarboxylic acid having on average 2 or more carboxyl groups per molecule obtained by copolymerizing an acid anhydride group-containing ethylenically unsaturated monomer with an ethylenically unsaturated monomer having no acid anhydride group, then reacting the resulting copolymer with a monoalcohol; (b) from 5-70% by weight of a polyester polycarboxylic acid having an acid value of from 50-350 mg KOH/g (solid) obtained by reacting a polyester polyol having 3 or more hydroxyl groups with an acid anhydride group-containing compound; (c) from 10-80% by weight of a po
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: December 2, 2003
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
  • Patent number: 6649267
    Abstract: A thermosetting powder coating composition has an average particle diameter of entire particles is within a range from 5 to 50 &mgr;m, an average circularity of the particles is 0.90 or more, and a circularity of particles having a maximum number frequency in circularity distribution is within a range from 0.98 to 1.00, prepared by spray-drying an organic solvent solution containing, as a coating film forming component, an epoxy group-containing vinyl copolymer (A) having a glass transition temperature of 40° C. or higher, an epoxy group-containing vinyl copolymer (B) having a glass transition temperature of 0° C. or lower and a polycarboxylic acid (C) as an essential component.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: November 18, 2003
    Assignees: Dainippon Ink and Chemicals, Inc., Liquid Gas Co., Ltd.
    Inventors: Tetsuro Agawa, Katsuhiko Okada, Hiroo Tanaka, Masaya Hashimoto, Takaaki Asakura
  • Patent number: 6599993
    Abstract: A powder coating composition that includes at least about 9% by weight, based on total vehicle weight, of a branched carboxylic acid-functional polyester having a number average molecular weight of from about 425 to about 1050 and at least one vehicle component reactive with carboxylic acid groups comprising an epoxy-functional material, produces a matte, textured coating.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: July 29, 2003
    Assignee: BASF Corporation
    Inventors: William C. Norris, Josef Rademacher
  • Patent number: 6472471
    Abstract: Various modified carbon products are disclosed which can form a part of a polymeric product containing the modified carbon product and a polymer. One type of modified carbon product disclosed is a carbon product having attached at least one organic group, monomeric group, or polymeric group. Another type of modified carbon product disclosed is a carbon product having attached a group having the formula: —Ar—CO2—R or —CnH2nCO2—R where R is an organic group, monomeric group, or a polymeric group.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: October 29, 2002
    Assignee: Cabot Corporation
    Inventors: Joel M. Cooke, Collin P. Galloway, Mark A. Bissell, Curtis E. Adams, Michael C. Yu, James A. Belmont, Robert M. Amici
  • Patent number: 6410647
    Abstract: A high-solid curable resin composition which forms a coated film having excellent acid rain resistance, mar resistance and appearance comprises: (a) 10 to 70% by weight of an acrylic polycarboxylic acid having 2 or more carboxyl groups per molecule on an average, an acid value of 5 to 300 mg KOH/g (solid) and a number-average molecular weight of 500 to 8000; (b) 5 to 70% by weight of a polyester polycarboxylic acid having an acid value of 50 to 350 mg KOH/g (solid), a number-average molecular weight of 400 to 3500 and a ratio of weight-average molecular weight to number-average molecular weight of 1.
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: June 25, 2002
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Manabu Yoshioka, Akira Fushimi, Seigo Miyazoe, Masanobu Inoue, Yoshio Eguchi
  • Patent number: 6406753
    Abstract: Coating composition especially for preparing automotive surfacers, comprising an anionically stabilized resin, preferably a condensation product A of a carboxyl group-containing resin A1 and a hydroxyl group-containing resin A2, and a curing agent C, which becomes active even at room temperature or slightly elevated temperature of up to not more than 120° C., and comprises a mixture of an unblocked isocyanate C1 and a hydrophilic partially etherified amino resin C2.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: June 18, 2002
    Assignee: Solutia Austria AG
    Inventors: Gert Dworak, Ulrike Kuttler
  • Patent number: 6391970
    Abstract: A resinous binder useful in clear coat compositions comprises a) a polyepoxide such as a copolymer of an ethylenically unsaturated epoxide with other (meth)acrylate(s) or styrene, b) a polyacid such as a carboxyl-terminated polyester, and c) a polyisocyanate.
    Type: Grant
    Filed: December 2, 1998
    Date of Patent: May 21, 2002
    Assignee: BASF Corporation
    Inventors: Swaminathan Ramesh, Manoj K. Gupta
  • Patent number: 6171654
    Abstract: Water-soluble or water-dispersible and curable polyester resins are suitable as binders in various applications, The resins are reaction products of polyterephthalate, polyols, polyacids, end acids and crosslinking agents. The waste terephthalates can be utilized when making the binders of the present invention. The preferred polyol is pentaerythritol. The resins can be used as binder for glass fiber insulation products.
    Type: Grant
    Filed: August 24, 1999
    Date of Patent: January 9, 2001
    Assignee: Seydel Research, Inc.
    Inventors: Robert Keith Salsman, Timothy Shouting Wang
  • Patent number: 6121382
    Abstract: Disclosed is a surface treatment agent for aqueous ink receiving media such as ink jet recording paper, printing sheets, coating materials and so on. The surface treatment agent according to the invention comprises a water-based resin and a carboxylic acid-containing hydrophilic sulfopolyester which provides superior adhesion and water resistance. With the superior adhesion properties, the surface treatment agent can be directly coated on substrates without the inconvenience of primer coating. The surface treatment agent of the invention is suitable for aqueous ink jet printing, coating, or recording media, particularly those of ink jet printers and ink jet plotters.
    Type: Grant
    Filed: April 16, 1998
    Date of Patent: September 19, 2000
    Assignee: Industrial Technology Research Institute
    Inventors: Shinn-Jen Chang, Yih-Her Chang, Rong-Shuh Chang, Wan-Jung Teng, Yuan-Tung Hung
  • Patent number: 6020431
    Abstract: Dynamic vulcanizates of an engineering thermoplastic ("plastic"), e.g. a polyamide or polyester, with acrylate rubbers having dissimilar functional groups are prepared with a metal fatty acid salt in the absence of a conventional curative, provided the rubbers are molecularly intermixed. An acrylate rubber with halogen functionality ("AcrRubHal") is thus crosslinked in a single mixing stage with an acrylate rubber having carboxyl, hydroxyl or epoxy functionality ("AcrRubX") in a "plastic". Quaternary ammonium salts and tertiary amines do not function as curatives, as one might expect. But a metal fatty acid salt, preferably a metal stearate or oleate and concentrates thereof effectively crosslink the rubbers. TPVs produced without conventional curing agents are relatively "soft", but have highly desirable low temperature physical properties and oil resistance.
    Type: Grant
    Filed: July 2, 1998
    Date of Patent: February 1, 2000
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Krishna Venkataswamy, Tonson Abraham
  • Patent number: 5948866
    Abstract: A powder paint composition and application method therefor are provided which can form a paint coating which has superior mar resistance and for which the external appearance, such as its smoothness and sharpness, is excellent.This paint powder composition comprises a multi-functional vinyl-type copolymer (A) which has a glass transition temperature of 40.degree. C. and which contains functional groups which are reactable with carboxylic acid; a polycarboxylic acid (B); and a multi-functional vinyl-type copolymer (C) which has a glass transition temperature of 0.degree. C. and which contains functional groups which are reactable with carboxylic acid.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: September 7, 1999
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Hirofumi Takeda, Ikuo Nakaya, Michiya Sugiyama, Akio Shoji
  • Patent number: 5587429
    Abstract: A processing aid system composition containing fluoropolymer processing aid, polar-side-group-containing extrusion adjuvant, and poly(oxyalkylene) polymer enhances extrusion of polyolefins.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: December 24, 1996
    Assignee: E. I. DuPont de Nemours and Company
    Inventor: Donnan E. Priester
  • Patent number: 5580926
    Abstract: Curable compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhydride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; and(iv) a hydroxy-functional compound having an average of at least two hydroxyl groups per molecule;wherein at least one of the compounds (i), (ii), (iii) or (iv) comprises a film forming polymer.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: December 3, 1996
    Assignee: The Sherwin-Williams Company
    Inventors: Mohamad D. Shalati, James A. Marquart, Sandra H. Angelo, Rodney M. Harris
  • Patent number: 5516846
    Abstract: Coating compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhydride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; wherein at least one of the compounds (i), (ii), or (iii) comprises a film forming polymer.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: May 14, 1996
    Assignee: The Sherwin-Williams Company
    Inventors: Mohamad D. Shalati, James A. Marquart, John L. Petty, Rodney M. Harris
  • Patent number: 5409764
    Abstract: A curable adhesive composition comprising an unsaturated polyester oligomer (A) of any of the following formulae (I) to (IV), obtained by reacting a compound (a) having a hydroxyl group and/or an amino group, a cyclic acid anhydride (b) and an epoxide (c) having an ethylenically unsaturated group, and an adhesive polymer (B), ##STR1## wherein: R.sub.1 is a divalent organic moiety having 1 to 40 carbon atoms,R.sub.2 is a divalent organic moiety having 1 to 10 carbon atoms,R.sub.3 is hydrogen or methyl,R.sub.4 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.5 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.6 is hydrogen or a monovalent organic moiety having 1 to 10 carbon atoms, andn is an integer of 2 or greater.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: April 25, 1995
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Tsukasa Otsuki, Masato Yanagi, Toshikazu Onikubo, Kouichi Iibuchi
  • Patent number: 5405657
    Abstract: A process for the production of flexible impregnated protective, auxiliary and insulating materials on a fibre basis for electrical purposes by the application of an impregnating agent to the material to be impregnated, followed by curing, characterised in that a solvent-free impregnating mass containing one or more olefinically unsaturated, radically polymerisable polyesters, which contain one or more radically polymerisable monomers as reactive diluents, one or more plasticizing agents and optionally one or more peroxide-free radical initiators is applied to the material to be impregnated and curing is then carried out with high energy radiation and optionally by further heating.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: April 11, 1995
    Assignee: Herberts G.m.b.H.
    Inventors: Udo Bastian, Rainer Krause, Gerhard Kiessling
  • Patent number: 5202382
    Abstract: A thermosetting powder coating composition which has good stability, pigment dispersion and impact characteristics is disclosed. The composition comprises a co-reactable particle mixture of an acid group-containing acrylic polymer having a Tg in the range of -20.degree. C. to 30.degree. C., an acid group-containing acrylic polymer having a Tg in the range of 40.degree. C. to 100.degree. C. and a curing agent, therefor.
    Type: Grant
    Filed: January 9, 1992
    Date of Patent: April 13, 1993
    Assignee: PPG Industries, Inc.
    Inventor: Paul H. Pettit, Jr.
  • Patent number: 5124176
    Abstract: A powder coating composition comprises a component (A) containing carboxylic acid or anhydride functionality and a component (B) containing hydroxy functionality. The components (A) and (B) are both solids at temperatures up to 50.degree. C. and at least one of them is a synthetic resin having a glass transition temperature in the range 0.degree. to 120.degree. C. The carboxylic acid or anhydride-functional component (A) is a compound or polymer containing at least two cyclic carboxylic anhydride groups per molecule or is a compound containing a moiety of the formula: ##STR1## where X is a hydrogen atom or an alkyl group, or a cyclic anhydride thereof. The hydroxy-functional component (B) contains at least two hydroxy groups per molecule and contains at least one amine group in its molecule to catalyze the reaction of the carboxylic acid or anhydride groups of component (A) with the hydroxy groups of component (B).
    Type: Grant
    Filed: May 3, 1989
    Date of Patent: June 23, 1992
    Assignee: International Paint public limited company
    Inventor: Alastair R. Marrion
  • Patent number: 5098955
    Abstract: A thermosetting powder coating composition which has good stability, pigment dispersion and impact characteristics is disclosed. The composition comprises a co-reactable particle mixture of an acid group-containing acrylic polymer having a Tg in the range of -20.degree. C. to 30.degree. C., an acid group-containing acrylic polymer having a Tg in the range of 40.degree. C. to 100.degree. C. and a curing agent, therefor.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: March 24, 1992
    Assignee: PPG Industries, Inc.
    Inventor: Paul H. Pettit, Jr.
  • Patent number: 5055524
    Abstract: There is disclosed herein an improved thermosetting powder coating composition comprising an epoxy resin and a curing agent, the improvement comprising the curing agent which is a polyol-modified polymeric polyanhydride containing anhydride linkages in the polymeric backbone.
    Type: Grant
    Filed: July 16, 1987
    Date of Patent: October 8, 1991
    Assignee: PPG Industries, Inc.
    Inventors: Paul H. Pettit, Jr., Debra L. Singer, William S. Ewing
  • Patent number: 4988767
    Abstract: A thermosetting powder coating composition which has good stability, pigment dispersion and impact characteristics is disclosed. The composition comprises a co-reactable particle mixture of an acid group-containing acrylic polymer having a Tg in the range of -20.degree. C. to 30.degree. C., an acid group-containing acrylic polymer having a Tg in the range of 40.degree. C. to 100.degree. C. and a curing agent, therefor.
    Type: Grant
    Filed: September 18, 1989
    Date of Patent: January 29, 1991
    Assignee: PPG Industries, Inc.
    Inventor: Paul H. Pettit, Jr.
  • Patent number: 4950717
    Abstract: A compatible polymer blend, comprising(i) about 10 to 90 weight percent of an ethylene-acrylic acid copolymer comprising from about 10 to 50 mole percent acrylic acid monomer units; and(ii) about 90 to 10 weight percent of a polyester-ether derived from 1,4-cyclohexane dicarboxylic acid, 1,4-cyclohexane dimethanol and poly(oxytetramethylene) glycol.
    Type: Grant
    Filed: June 2, 1989
    Date of Patent: August 21, 1990
    Assignee: Eastman Kodak Company
    Inventors: Robert W. Seymour, Thomas E. Flora
  • Patent number: 4902771
    Abstract: An imido-modified unsaturated polyester resin composition comprising an imido-modified unsaturated polyester obtainable by reacting an animal or vegetable fat and oil or a fatty acid thereof, an imido alcohol obtainable from a primary amino-alcohol and a polybasic acid anhydride, a polyhydroxy alcohol, and a polybasic acid in such a manner that the imido alcohol is used in an amount of 10 to 60% equivalent amount based on the alcoholic components; and a polymeric monomer.In one of the preferred embodiments, the composition according to the present invention further contains an inorganic filler.According to the present invention, there can be provided resin composition in which the compatibility under heat deterioration when used in enamelled wires has been improved, while maintaining excellent electrical and mechanical properties.
    Type: Grant
    Filed: August 23, 1988
    Date of Patent: February 20, 1990
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yasuo Sugawara, Yuuji Aimono, Hatuo Sugitani
  • Patent number: 4895901
    Abstract: The present invention relates to novel compounds corresponding to the formula: ##STR1## wherein R.sub.1 and R.sub.4 may be the same or different, and each is a lower alkyl radical; R.sub.2 and R.sub.3 may be the same or different, and each is a substituted piperidine radical; M is equal to the total number of monomer units in the polymer chain, and is of a magnitude sufficient to provide a polymer having a molecular weight of at least 500; W is equal to at least 0.5, X is equal to at least 0.1 but not greater than 0.2, Y is equal to at least 0.1, Z is equal to at least 0.05 but not greater than 0.2, and W plus X plus Y plus Z is equal to 1.These novel compounds are useful as stabilizers for a wide variety of organic materials and are prepared by transesterification of a suitable acrylate-methacrylate copolymer.
    Type: Grant
    Filed: November 23, 1988
    Date of Patent: January 23, 1990
    Assignee: Ferro Corporation
    Inventors: Chester E. Ramey, Ronald E. Thompson, Charles J. Rostek, Jr.
  • Patent number: 4871806
    Abstract: Curable compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhdyride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; and(iv) a hydroxy-functional compound having an average of at least two hydroxyl groups per molecule;wherein at least one of the compounds (i), (ii), (iii) or (iv) comprises a film forming polymer.
    Type: Grant
    Filed: November 16, 1987
    Date of Patent: October 3, 1989
    Assignee: The Sherwin-Williams Company
    Inventors: Mohamad D. Shalati, James A. Marquart
  • Patent number: 4849475
    Abstract: Water-dilutable paint binders based on acrylates for cathodically depositable paints particularly suited for the formulation of decorative single coats or pale primers are described. The binders are partial condensation products of from 60% to 90% by weight of a hydroxy and amino group containing acrylic copolymer, the basic groups of which were obtained through reaction of glycidyl groups with secondary amines, with 10% to 40% by weight of an oliogomeric or polymeric compound carrying CH-active ester groups, preferably malonic acid ester groups, capable of transesterification or transamidation. The paint films afford particularly good yellowing resistance, detergent resistance, and abrasion resistance.
    Type: Grant
    Filed: November 16, 1987
    Date of Patent: July 18, 1989
    Assignee: Vianova Kunstharz, A.G.
    Inventors: Herbert Zima, Josef Forstner
  • Patent number: 4789706
    Abstract: A polyester composition having an average molecular weight of greater than 450 comprising a most prevalent compound having a main polyester chain containing at least 17 and fewer than 52 carbon atoms and at least 6 and fewer than 18 oxygen atoms, at least 40 weight percent of the molecules of said composition having a molecular weight within 50% of the average molecular weight of the composition. Often less than 36 weight percent of the molecules of the composition having a molecular weight greater than 150 percent of the average molecular weight and less than 12 weight percent of the molecules of the composition having a molecular weight less than 50 percent of the average molecular weight of the composition. The polyester composition desirably contains at least 1.6 equivalents of unreacted hydroxy groups or at least 1.6 equivalents of unreacted carboxy groups per mole. The composition contains at least four equivalents of ester links in the main chains of the molecules per mole.
    Type: Grant
    Filed: March 23, 1988
    Date of Patent: December 6, 1988
    Assignee: NL Chemicals, Inc.
    Inventor: Roy C. Williams
  • Patent number: 4743655
    Abstract: A polyester composition having an average molecular weight of greater than 450 comprising a most prevalent compound having a main polyester chain containing at least 17 and fewer than 52 carbon atoms and at least 6 and fewer than 18 oxygen atoms, at least 40 weight percent of the molecules of said composition having a molecular weight within 50% of the average molecular weight of the composition. The polyester composition desirably contains at least 1.6 equivalents of unreacted hydroxy groups or at least 1.6 equivalents of unreacted carboxy groups per mole. The composition contains at least four equivalents of ester links in the main chains of the molecules per mole.The composition of the present invention is obtained by the method of the invention wherein alternating series of reactions are each driven essentially to completion where the final molecule of each reaction provides the only available reaction site for the next alternate monomer reaction.
    Type: Grant
    Filed: April 20, 1987
    Date of Patent: May 10, 1988
    Assignee: NL Chemicals, Inc.
    Inventor: Roy C. Williams
  • Patent number: 4436869
    Abstract: A process for the preparation of moldings, in particular resilient elements, which by virtue of a densified surface zone with substantially closed cells, have only a low water absorption, wherein a mixture comprising:(a) 100 parts by weight of an NCO-containing prepolymer, having an NCO content of from 3 to 6% by weight and based on organic diisocyanates and substantially linear polyester-polyols or polytetramethylene ether glycol,(b) from 0.5 to 1.6 parts by weight of water,(c) one or more catalysts, preferably a tertiary amine, in an amount of from 0.01 to 2.0 parts by weight and(d) assistants, with or without additives, is reacted in a closed mold, while undergoing densification, the surface temperature of the inner wall of the mold being from 50.degree. to 70.degree. C.
    Type: Grant
    Filed: March 30, 1982
    Date of Patent: March 13, 1984
    Assignee: Elastogran GmbH
    Inventors: Otmar Zipp, Heinz Bollmann, Herbert Stutz, Wolfgang Scholz
  • Patent number: 4405662
    Abstract: A thermosetting resinous binder composition, heat-curable in combination with a transesterification-promoting metal compound as a catalyst to provide an insoluble infusible coating, comprising a mixture of:(1) a non-acidic resinous compound essentially free of ethylenical unsaturation, having a molecular weight of at least 900 and a hydroxyl content of at least 0.
    Type: Grant
    Filed: September 24, 1982
    Date of Patent: September 20, 1983
    Assignee: Shell Oil Company
    Inventors: Werner T. Raudenbusch, Adrianus J. M. Barnhoorn, Petrus G. Kooijmans, Willem L. Sederel, Adrianus M. C. Van Steenis, Theresia F. M. Schets
  • Patent number: 4397990
    Abstract: A thermosetting binder composition for coating, comprising:(1) A non-acidic resinous saturated compound having a molecular weight of at least 900, and an alcoholic hydroxyl content of at least 0.2 eq./100 g;(2) A non-acidic polyester of a polycarboxylic acid cross-linking agent having more than one .beta.-hydroxyl ester group per molecule, and at least one of components (1) and (2) having an alcoholic hydroxyl functionality of more than 2, and(II) A transesterification-promoting metal salt or complex curing catalyst which is soluble in liquid hydrocarbons.For aqueous compositions, component (I) (1) is preferably a neutralized epoxy resin/amine adduct and component (II) should be insoluble in water; they can be used for cathodic electrodeposition.
    Type: Grant
    Filed: February 16, 1982
    Date of Patent: August 9, 1983
    Assignee: Shell Oil Company
    Inventors: Petrus G. Kooymans, Johannes J. M. H. Wintraecken, Werner T. Raudenbusch, Josepha M. E. Seelen-Kruijssen, Gerardus C. M. Schreurs
  • Patent number: 4373059
    Abstract: The invention concerns a pre-condensed, thermosetting aqueous lacquer coating material containing a pre-condensation product that becomes water-dilutable after protonization with acids and has a mean molecular weight [M.sub.n ] of 800 to 15,000, obtainable by heating of 55 to 95% by weight, based on the total quantity of the binding agent, of an organic synthetic-resin binder containing primary and/or secondary amino groups which has an amine number of 30 to 150 and 5 to 45% by weight of a crosslinking agent possessing esterified terminal carboxyl groups.The invention moreover concerns the application of this lacquer coating material for cathodic deposition upon electrically conducting surfaces.
    Type: Grant
    Filed: September 2, 1980
    Date of Patent: February 8, 1983
    Assignee: Herberts Gesellschaft mit Beschrankter Haftung
    Inventors: Hans-Peter Patzschke, Armin Gobel
  • Patent number: 4362847
    Abstract: The present invention is directed to thermosetting binder compositions for coating, comprising:(I) (1) A non-acidic resinous compound, saturated, molecular weight at least 900, alcoholic hydroxyl content at least 0.2 eq/100 g;(2) a cross-linking agent comprising a non-acidic polyester of a polycarboxylic acid, having more than one beta-hydroxyl ester group per molecule, at least one of components (1) and (2) having an alcoholic hydroxyl functionality of more than 2, and(II) a curing catalyst comprising a transesterification-promoting metal compound which is insoluble in liquid hydrocarbons.These compositions can be used in solvent-based lacquers and paints, in coating powders, aqueous powder suspensions, in aqueous coating compositions for cathodic electrodeposition; for aqueous compositions component (I) (1) is preferably an epoxy resin/amine adduct.
    Type: Grant
    Filed: April 20, 1981
    Date of Patent: December 7, 1982
    Assignee: Shell Oil Company
    Inventors: Petrus G. Kooijmans, Werner T. Raudenbusch, Adrianus M. C. Van Steenis, Wolfgang Kunze, Josepha M. E. Seelen-Kruijssen
  • Patent number: 4320045
    Abstract: A resin molding composition comprising a thermoplastic polymer, a monomer and an unsaturated polyester which is the reaction product of at least one polyol having at least two, but not more than four hydroxyl groups, the polyols comprising not less than about 48% of the weight of the reactants forming the polyester.
    Type: Grant
    Filed: April 10, 1981
    Date of Patent: March 16, 1982
    Assignee: Owens-Corning Fiberglas Corporation
    Inventor: Gwilym Owen