From Two Or More Polyols Patents (Class 525/173)
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Patent number: 12097094Abstract: A reduced pressure dressing for applying reduced pressure treatment to a tissue site includes an interface layer adapted to be positioned at the tissue site. An absorbent layer is in fluid communication with the interface layer to absorb liquid from at least one of the interface layer and the tissue site. A pump is in fluid communication with the absorbent layer to deliver a reduced pressure to the tissue site. A cover is positioned over the pump, the absorbent layer, and the interface layer to maintain the reduced pressure at the tissue site, and a liquid-air separator is positioned between the absorbent layer and the pump to inhibit liquid from entering the pump.Type: GrantFiled: April 28, 2021Date of Patent: September 24, 2024Assignee: Solventum Intellectual Properties CompanyInventors: Jonathan Paul Jaeb, Richard Daniel John Coulthard, Timothy Mark Robinson, Christopher Brian Locke, Aidan Marcus Tout
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Patent number: 11965078Abstract: A chloroprene-unsaturated nitrile copolymer composition containing 100 parts by mass of a chloroprene-unsaturated nitrile copolymer having 3 to 20% by mass of a structural unit derived from an unsaturated nitrile monomer, and 0.05 to 2.0 parts by mass of a xanthogen compound.Type: GrantFiled: November 6, 2019Date of Patent: April 23, 2024Assignee: Denka Company LimitedInventors: Suguru Onuki, Wataru Nishino, Atsunori Kondo, Yuhei Ishigaki, Naoki Kobayashi
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Patent number: 11926117Abstract: The present invention relates to an MDO thermoresistant heat-shrinkable multilayer film of a copolymer polyester having excellent thermal resistance. In particular, the present invention provides an MDO thermoresistant heat-shrinkable multilayer film that includes multiple skin layers capable of improving thermal resistance formed on a substrate layer capable of providing high shrinkage, and simultaneously has excellent thermal resistance and high shrinkage properties through MD orientation instead of the conventional TD orientation method.Type: GrantFiled: November 24, 2017Date of Patent: March 12, 2024Assignee: SK Chemicals Co., Ltd.Inventors: Seol-Hee Lim, Sung-Gi Kim, So-Yeon Kim
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Patent number: 10988612Abstract: The invention relates to a polymer composition based on thermoplastic copolyester elastomer comprising: —from 90% to 70% by weight of the thermoplastic copolyester elastomer containing ester and ether bonds; —from 5% to 25% by weight of one or more saturated esters with a molecular weight between about 200 and 1,000, and preferably between 300 and 380; —from 2 to 10% by weight of expanding additives. This invention also covers a manufactured article obtained by injection moulding a predefined amount of the polymer composition according to this invention, as well as a production process of such polymer composition.Type: GrantFiled: September 8, 2016Date of Patent: April 27, 2021Assignee: CELANESE INTERNATIONAL CORPORATIONInventors: Denis Grechi, Stefano Zocca
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Patent number: 10988587Abstract: This invention relates to a polymer composition which is particularly suitable for use in the manufacture of films having a great ability to disintegrate, preferably at low temperatures, which can be used in the mulch film sector.Type: GrantFiled: February 27, 2018Date of Patent: April 27, 2021Assignee: NOVAMONT S.P.A.Inventors: Sebastia Gesti Garcia, Giovanni Tettoni
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Patent number: 10468568Abstract: A polyester resin composition includes: (A) a polyester resin which includes a polymer of a dicarboxylic acid component including an aromatic dicarboxylic acid, for example but not limited to terephthalic acid, and a diol component including an alicyclic diol, for example but not limited to cyclohexanedimethanol, having a trans/cis isomer ratio of about 2.3 or more; (B) a white pigment; and (C) inorganic fillers. A molded article formed from the polyester resin composition can exhibit improved mechanical properties and moldability, and thus can be suitable for light emitting diode (LED) reflectors.Type: GrantFiled: March 31, 2015Date of Patent: November 5, 2019Assignee: Lotte Advanced Materials Co., Ltd.Inventors: Tae Gon Kang, Chan Moo Park, Yoo Jin Jung, Jong Cheol Lim, Sang Hyun Hong, Tae Soo Kim, Young Ho Park
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Patent number: 10385204Abstract: A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of a cyclic ester compound having a structure shown as formula (I), which is 100 ppm-950 ppm is provided. The cyclic ester compound is added into the composition and controlling the content of the cyclic ester compound in a range of 100 ppm-950 ppm to realize an anti-thermal oxidative aging property of the biodegradable polyester composition. In addition, a film is prepared by blow molding or a part prepared by injection molding after being digested with 95% ethanol at 40° C. for 240 hours.Type: GrantFiled: February 24, 2017Date of Patent: August 20, 2019Inventor: Hongmei Yang
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Patent number: 10364320Abstract: A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of cyclopentanone which is 0.5 ppm-85 ppm is provided. The cyclopentanone is added into the composition and controlling the content of cyclopentanone in the composition within a range of 0.5 ppm-85 ppm to realize a lubrication degree of a film of biodegradable polyester during a blow molding process. When a velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2 ?m and a relative deviation of the film thickness is less than 1%.Type: GrantFiled: December 15, 2016Date of Patent: July 30, 2019Inventor: Hongmei Yang
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Patent number: 10131785Abstract: A polyester resin composition and a molded article produced using the same. The polyester resin composition includes: (A) two polyester resins including an aliphatic ring structure and having different trans/cis isomer ratios in the aliphatic ring; (B) a white pigment; and (C) an inorganic filler, wherein the polyester resin composition has a crystallization temperature (Tc) of about 230° C. to about 250° C., as measured by differential scanning calorimetry (DSC) while cooling the resin composition at a cooling rate of ?100° C./min. Exemplary compositions include a first poly(1,4-cyclohexylene dimethylene terephthalate) and a second poly(1,4-cyclohexylene dimethylene terephthalate) having different trans/cis isomer ratios in the cyclohexylene rings thereof, titanium oxide, glass fiber, and wollastonite.Type: GrantFiled: June 28, 2016Date of Patent: November 20, 2018Assignee: Lotte Advanced Materials Co., Ltd.Inventors: Young Ho Park, Tae Gon Kang, Yang Il Kim, Chan Moo Park, Sang Hyun Hong
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Patent number: 10093823Abstract: The present invention relates to a flame retardant resin composition including (A) 100 parts by weight of a blend resin composition including a styrene copolymer and a polyester elastomer, (B) 1 to 30 parts by weight of an epoxy resin, and (C) 1 to 30 parts by weight of a phosphor-based flame retardant agent. The flame retardant resin composition has improved flame retardant properties and flexibility and is used for coating a wire and a cable.Type: GrantFiled: October 14, 2014Date of Patent: October 9, 2018Assignee: LG CHEM, LTD.Inventors: Jae Young Sim, Ki Young Nam, Yong Yeon Hwang, Je Sun Yoo, Seon Hyeong Bae, Jae Yeon Bae
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Patent number: 9636950Abstract: A tire having a crown reinforcement formed of at least two working crown layers having unequal axial widths, a layer C of rubber mixture being positioned between at least the ends of the said at least two working crown layers, and the crown reinforcement having at least one layer of circumferential reinforcing elements positioned radially between two working crown layers. The distance d between the end of the axially narrowest working layer and the working layer separated from the axially narrowest working layer by the layer C of rubber mixture is such that 1.1ø<d<2.2ø, ø being the diameter of the reinforcing elements of the said at least one layer of circumferential reinforcing elements, and, in a meridian plane, the thickness of the layer C of rubber mixture is substantially uniform.Type: GrantFiled: October 12, 2012Date of Patent: May 2, 2017Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: Alain Domingo, Jacques Besson, Francois Barbarin, Gilles Sallaz, Robert Ciprian Radulescu
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Patent number: 9056972Abstract: Barrier films made from a composition comprising vinylidene chloride (VDC) interpolymer and poly(butylene succinate) (PBS) exhibit improved tear resistance in both the machine and cross directions without a significant deterioration in oxygen transmission rate as compared to barrier films made under like conditions and from a composition alike in all respects except that the PBS is replaced with additional VDC interpolymer.Type: GrantFiled: September 12, 2012Date of Patent: June 16, 2015Assignee: Dow Global Technologies LLCInventors: Hyun K. Jeon, Douglas E. Beyer
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Patent number: 9034988Abstract: A resin composition includes a copolymerized polyester resin, which exhibits excellent flexibility at room temperature, improvement in problems of brittleness, and excellent adhesiveness and moist-heat durability. The invention relates to a resin composition containing a copolymerized polyester resin which contains, as an acid component, an aromatic dicarboxylic acid and a dimer acid and, as a glycol component 1,4-butane diol and polybutadiene glycols, with the content of the dimer acid being 10 to 50 mol % in the acid component, the content of the 1,4-butane diol being 50 mol % or greater in the glycol component, and the content of the polybutadiene glycols being 0.5 to 20 mol % in the glycol component.Type: GrantFiled: August 3, 2011Date of Patent: May 19, 2015Assignees: UNITIKA LTD., NIPPON ESTER CO., LTD.Inventors: Motoki Tomizawa, Takao Okochi, Tomoki Tanaka, Naomi Kida, Yuji Oida
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Patent number: 8993676Abstract: A blend of polylactic acid resin and copolyester resin, which has excellent impact resistance and heat resistance, and a molded article manufactured using the same are disclosed. The blend of polylactic acid resin and copolyester resin, comprises 5 to 94 wt % of a polylactic acid resin; 3 to 92 wt % of a copolyester resin comprising a dicarboxylic acid component, which contains a terephthalic acid residue, and a diol component which contains 3 to 99 mol % of a cyclohexanedimethanol residue and 1 to 60 mol % of an isosorbide residue; and 3-30 wt % of a compatibilizer containing at least one reactive functional group selected from the group consisting of glycidyl, maleic anhydride, epoxy, isocyanate, amino, carboxylic acid and oxazoline groups, and mixtures thereof.Type: GrantFiled: November 13, 2012Date of Patent: March 31, 2015Assignee: SK Chemicals Co., Ltd.Inventors: Kyu-Tae Park, Jong-Ryang Kim, Jong-Wook Shin, Min-Goo Kang
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Patent number: 8901250Abstract: The present invention relates to a powder coating composition for low temperature cure which comprises a mixture of a carboxylic acid group containing first polyester; at least one of a second polyester having a glass transition temperature ?45° C. and/or a crystalline polycarboxylic acid; a glycidyl group containing acrylic copolymer; a further compound and/or resin having functional groups readable with the carboxylic acid groups; and a thermosetting curing catalyst. These thermosetting powder coatings are designed for coating heat-sensitive substrates such as wood, fiber board and other materials which can not withstand the excessive heat/time conditions necessary to cure traditional coatings. The powder coatings of the invention, when cured at temperatures below 150° C., produce a finish which exhibits a high gloss, smooth surface along with an outstanding hardness and weatherability.Type: GrantFiled: June 28, 2010Date of Patent: December 2, 2014Assignee: Allnex Belgium S.A.Inventor: Luc Moens
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Publication number: 20140288241Abstract: A blend of polylactic acid resin and copolyester resin, which has excellent impact resistance and heat resistance, and a molded article manufactured using the same are disclosed. The blend of polylactic acid resin and copolyester resin, comprises 5 to 94 wt % of a polylactic acid resin; 3 to 92 wt % of a copolyester resin comprising a dicarboxylic acid component, which contains a terephthalic acid residue, and a diol component which contains 3 to 99 mol % of a cyclohexanedimethanol residue and 1 to 60 mol % of an isosorbide residue; and 3-30 wt % of a compatibilizer containing at least one reactive functional group selected from the group consisting of glycidyl, maleic anhydride, epoxy, isocyanate, amino, carboxylic acid and oxazoline groups, and mixtures thereof.Type: ApplicationFiled: November 13, 2012Publication date: September 25, 2014Inventors: Kyu-Tae Park, Jong-Ryang Kim, Jong-Wook Shin, Min-Goo Kang
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Patent number: 8754171Abstract: Compositions comprising: (a) 30 to 65 weight percent of a polyester; (b) 7 to 25 weight percent of an ethylene copolymer toughener; (c) 5 to 25 weight percent of a copolyether ester elastomer having a shore D hardness of 20 to 50; optionally (d) 15 to 35 weight percent of a halogenated epoxy flame retardant; and (e) when (d) is present in the composition, optionally, 2 to 10 weight percent of a flame retardant synergist; wherein: the ratio of the combined weight of (b)+(c) relative to the weight of (a) ranges from 0.40 to 0.85; the ratio of the weight of (b) relative to that of (c) ranges from 0.3 to 2.5; and the Gardner impact of the composition, when molded, is at least 4.2 J, measured at ?40° C. according to ASTM D5420. Methods of making articles by molding these melt-mixed compositions.Type: GrantFiled: March 4, 2013Date of Patent: June 17, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Masahiro Kurouchi, Hiroyuki Sumi
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Patent number: 8697245Abstract: A biodegradable injection mouldable polymer composition including on a dry weight basis from 45-85% w/w by weight of a starch and/or a modified high amylose starch, from 2-15% w/w by weight of a water soluble polymer preferably selected from polyvinyl alcohol, polyvinyl acetate and copolymers of ethylene and vinyl alcohol which have a melting point compatible with the molten state of the starch components, and from 5-45% w/w by weight of one or more polyol plasticizers having a molecular weight in the range of 50-6000, more preferably 50-2500, and still more preferably 100-400 and preferably selected from the group consisting of sorbitol, glycerol, maltitol, xylitol, mannitol, erythritol, polyglycerol, glycerol trioleate, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate, polyethylene oxide, ethylene glycol, diethylene glycol or polyethylene glycol; more preferably glycerol, maltitol, sorbitol, erythritol and xylitol.Type: GrantFiled: August 6, 2007Date of Patent: April 15, 2014Assignee: Plantic Technologies Ltd.Inventors: Kishan Khemani, Nicholas John McCaffrey, Rulande Henderson
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Publication number: 20140023817Abstract: An elastomeric polymer composition is disclosed that is wear resistant at a broad range of temperatures. The composition contains a thermoplastic elastomer, such as a thermoplastic polyester elastomer, that forms a polymer matrix in products made from the polymer composition. The polymer composition may also contain a fluoropolymer and/or unmodified or functionalized ultra-high molecular weight polyolefin particles, such as ultra-high molecular weight polyethylene particles.Type: ApplicationFiled: July 18, 2013Publication date: January 23, 2014Applicant: Ticona LLCInventors: Mukul Kaushik, Dirk Zierer, Deiwes Jose Rigoletti Orloski, Suzanne Renee Redding, Simone Pereira Orosco, Guert Ruecker
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Publication number: 20130303692Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising 80 to 100 mole % terephthalic acid residues; optionally, 0 to 20 mole % aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 20 to 30 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 70 to 80 mole % 1,4-cyclohexanedimethanol residues. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: ApplicationFiled: July 12, 2013Publication date: November 14, 2013Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell, Ted Calvin Germroth, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Publication number: 20130274418Abstract: A resin composition includes a copolymerized polyester resin, which exhibits excellent flexibility at room temperature, improvement in problems of brittleness, and excellent adhesiveness and moist-heat durability. The invention relates to a resin composition containing a copolymerized polyester resin which contains, as an acid component, an aromatic dicarboxylic acid and a dimer acid and, as a glycol component 1,4-butane diol and polybutadiene glycols, with the content of the dimer acid being 10 to 50 mol % in the acid component, the content of the 1,4-butane diol being 50 mol % or greater in the glycol component, and the content of the polybutadiene glycols being 0.5 to 20 mol % in the glycol component.Type: ApplicationFiled: August 3, 2011Publication date: October 17, 2013Inventors: Motoki Tomizawa, Takao Okochi, Tomoki Tanaka, Naomi Kida, Yuji Oida
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Patent number: 8524834Abstract: Disclosed are solvent borne thermosetting coating compositions that contain a curable polyester resin blended with an acrylic copolymer, a crosslinker, and a solvent. The polyester resin contains 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibits good dry time, compatibility with acrylic resins, sag resistance and hardness development in a coating composition. The coating compositions can be used to prepare clear coat or pigmented coatings for automotive OEM, auto refinish, and other applications.Type: GrantFiled: March 30, 2012Date of Patent: September 3, 2013Assignee: Eastman Chemical CompanyInventors: Stacey James Marsh, Angela Hartley Honeycutt, Deepanjan Bhattacharya
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Patent number: 8519055Abstract: Disclosed are polyester resins and solvent borne thermosetting coating compositions that include these resins in combination with at least one crosslinker. The polyester resins contain 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibit a combination of good solubility in organic solvents and high hardness with good flexibility in a coating composition.Type: GrantFiled: March 13, 2012Date of Patent: August 27, 2013Assignee: Eastman Chemical CompanyInventors: Stacey James Marsh, Angela Hartley Honeycutt
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Patent number: 8519053Abstract: A flooring product is provided which has at least one layer including a polymeric binder comprising homo-polymer PVC resin and thermoplastic, high molecular weight polyester resin or highly viscous polyester resin. The polyester resin comprises renewable components, and can be amorphous or crystalline in nature. A flooring product is described that comprises a renewable or recycle content that classifies the product for points under the LEED system for commercial products.Type: GrantFiled: October 2, 2006Date of Patent: August 27, 2013Assignee: Armstrong World Industries, Inc.Inventors: Dong Tian, Gary A. Sigel, Fang Qiao, Rebecca L. Winey, Jeffrey S. Ross
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Publication number: 20130217830Abstract: The present invention relates to a clear, semicrystalline article comprising a polyester comprising terephthalic acid residues as the dicarboxylic acid component, and 1 to 15 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 85 to 99 mole % of 1,4-cyclohexanedimethanol residues as the glycol component. The article may be in the form of a film or sheet, a bottle, or a fiber. The article, when produced by a process involving strain-induced crystallization, is characterized with high crystallinity.Type: ApplicationFiled: February 16, 2012Publication date: August 22, 2013Applicant: EASTMAN CHEMICAL COMPANYInventors: Emmett Dudley Crawford, Michael Eugene Donelson
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Publication number: 20130210986Abstract: The present invention relates to a crosslinkable composition comprising at least one crosslinkable component and a latent base crosslinking catalyst, which crosslinkable composition has a solids content of typically at least 55 wt (dry weight after crosslinking relative to the total weight of the crosslinking composition) wherein the latent base catalyst is a substituted carbonate salt according to formula (I) wherein X+ represents a non acidic cation, preferably a quaternary ammonium or phosphonium, and wherein R is hydrogen, alkyl, aryl or aralkyl group. The invention relates in particular to a composition crosslinkable by Real Michael Addition (RMA) reaction wherein a component with at least 2 activated unsaturated groups and a malonate component with at least 2 acidic protons C—H in activated methylene or methine groups react and crosslink to each other in the presence of the base catalyst.Type: ApplicationFiled: April 7, 2011Publication date: August 15, 2013Applicant: NUPLEX RESINS B.V.Inventors: Richard Hendrikus Gerrit Brinkhuis, Jan Andre Jozef Schutyser, Paulus Jozef Dolphijn, Antonius Johannes Wilhelmus Buser, Petrus Johannes Maria David Elfrink, Michael Anthony Gessner, Mohamad Deeb Shalati
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Patent number: 8507638Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and cyclohexanedimethanol residues. The polyesters have a desirable combination of inherent viscosity and glass transition temperature (“Tg”). The polyesters can have an inherent viscosity from 0.35 to 1.2 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C. and a Tg of 85 to 115° C. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: GrantFiled: August 23, 2011Date of Patent: August 13, 2013Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, David Scott Porter, Gary Wayne Connell, Ted Calvin Germroth, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 8501287Abstract: The invention is generally directed to baby bottles and other articles produced by blow molding from polymeric materials having glass transition temperatures ranging from 100° C. to 130° C., as well as to processes for producing them. These articles can be exposed to boiling water and can be produced by using a suitable combination of a stretch ratio of less than 3 and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material.Type: GrantFiled: September 23, 2010Date of Patent: August 6, 2013Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Spencer Allen Gilliam, Alan Keith Phillips, Robert Ellis McCrary
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Patent number: 8415450Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues, 2,2,4,4-tetramethyl-l,3-cyclobutanediol, and 1,4-cyclohexanedimethanol, wherein the inherent viscosity of said polyester is from 0.55 to 0.68 dL/g as determined in 60/40(wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a Tg from 110 to 160° C.; wherein the polyester composition comprises no polycarbonate; wherein the melt viscosity of the polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.; and wherein the polyester has a notched Izod impact strength, of at least 7.5 ft-lb/in.ch at 23° C. according to ASTM D256 with a 10-mil notch in a ? inch thick bar. The polyesters may be manufactured into articles of manufacture as fibers, films, bottles or sheets.Type: GrantFiled: January 12, 2012Date of Patent: April 9, 2013Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8383719Abstract: Water-borne polyurethane coating compositions are provided. One exemplary water-borne coating composition includes a substantially water-free base component and an activator component. The substantially water-free base component includes at least a hydrophilic polyol, and the activator component includes at least a hydrophobic isocyanate.Type: GrantFiled: October 23, 2007Date of Patent: February 26, 2013Assignee: PRC De Soto International, Inc.Inventors: Siamanto Abrami, Guangliang Tang
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Patent number: 8354491Abstract: Described are container(s) comprising polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 15 to 50 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 50 to 85 mole % 1,4-cyclohexanedimethanol residues; wherein the total mole % of said dicarboxylic acid component is 100 mole %, and the total mole % of said glycol component is 100 mole %; wherein the inherent viscosity of the polyester is from 0.50 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a 1/8-inch thick bar; and wherein the melt viscosity of said polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.Type: GrantFiled: January 28, 2011Date of Patent: January 15, 2013Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
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Publication number: 20120328806Abstract: A compostion comprising: at least one copolymer (A) of vinylidene chloride and of at least one comonomer copolymerizable therewith selected from butyl acrylates; and from 1 to 20% by weight, relative to the total weight of the composition, of at least one polymeric plasticizer (B) selected from polyesters derived from a polycondensation reaction of at least one aliphatic polycarboxylic acid and at least one polyhydroxylated aliphatic alcohol. The composition is suitable for the preparation of mono- or multi-layer films for the packaging of food products.Type: ApplicationFiled: March 8, 2011Publication date: December 27, 2012Applicant: SOLVAY SAInventors: Pascal Dewael, Agnes Chapotot, Yves Vanderveken
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Patent number: 8299204Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbons atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.Type: GrantFiled: October 27, 2006Date of Patent: October 30, 2012Assignee: Eastman Chemical CompanyInventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 8287970Abstract: The invention is generally directed to baby bottles and other articles produced by blow molding from polymeric materials having glass transition temperatures ranging from 100° C. to 130° C., as well as to processes for producing them. These articles can be exposed to boiling water and can be produced by using a suitable combination of a stretch ratio of less than 3 and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material.Type: GrantFiled: November 20, 2008Date of Patent: October 16, 2012Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Spencer Allen Gilliam, Alan Keith Phillips
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Patent number: 8193302Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3 -cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.Type: GrantFiled: October 27, 2006Date of Patent: June 5, 2012Assignee: Eastman Chemical CompanyInventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 8168721Abstract: Disclosed are solvent borne thermosetting coating compositions that contain a curable polyester resin blended with an acrylic copolymer, a crosslinker, and a solvent. The polyester resin contains 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibits good dry time, compatibility with acrylic resins, sag resistance and hardness development in a coating composition. The coating compositions can be used to prepare clear coat or pigmented coatings for automotive OEM, auto refinish, and other applications.Type: GrantFiled: February 6, 2009Date of Patent: May 1, 2012Assignee: Eastman Chemical CompanyInventors: Stacey James Marsh, Angela Hartley Honeycutt, Deepanjan Bhattacharya
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Patent number: 8163850Abstract: Disclosed are polyester resins and solvent borne thermosetting coating compositions that include these resins in combination with at least one crosslinker. The polyester resins contain 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibit a combination of good solubility in organic solvents and high hardness with good flexibility in a coating composition.Type: GrantFiled: February 6, 2009Date of Patent: April 24, 2012Assignee: Eastman Chemical CompanyInventors: Stacey James Marsh, Angela Hartley Honeycutt
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Patent number: 8133967Abstract: Described are restaurant smallware, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.Type: GrantFiled: October 7, 2010Date of Patent: March 13, 2012Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 8119761Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues in the amount from 80 to 100 mole %, 2,2,4,4-tetramethyl-1,3- cyclobutanediol in the preferable amount from 30 to 40 mole % and 1,4-cyclohexanedimethanol in the preferable amount from 60 to 70 mole % , wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mote %; and the inherent viscosity of polyester is from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachtoroethane at a concentration of 0.5 g/100 ml at 25° C., polyester has a Tg from 110 to 160° C. and polyester composition comprises no polycarbonate. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: GrantFiled: March 28, 2006Date of Patent: February 21, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8119762Abstract: Described are film or sheet, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.Type: GrantFiled: November 10, 2010Date of Patent: February 21, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20120021158Abstract: Described are polyester compositions comprising (a) a dicarboxylicacidcomponent comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, wherein said 2,2,4,4-tetramethyl-1,3-cyclobutanediol contains certain cis to trans ratios; and 1,4-cyclohexanedimethanol residues.Type: ApplicationFiled: June 17, 2011Publication date: January 26, 2012Applicant: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 8101705Abstract: Described are articles, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.60 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 100° C. to 130° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate. Composition can be manufactured into articles as fibers, films, bottles or sheets.Type: GrantFiled: May 20, 2010Date of Patent: January 24, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8097076Abstract: Low-VOC mixture of at least partially salified copolymers of at least one ethylenically unsaturated, phenyl-group-containing monomer and at least one ?,?-unsaturated monocarboxylic acid and/or at least one ?,?-unsaturated dicarboxylic acid, of at least one water-soluble polyether, esterification products of at least one water-soluble polyether and an aliphatic dicarboxylic acid, and of a star polymer obtainable by esterifying a carboxylic acid containing at least 3 carboxyl groups with at least one water-soluble polyether, and use thereof as a wetting and dispersing agent, preferably for producing low-VOC pigment pastes or low-VOC paint systems.Type: GrantFiled: July 28, 2010Date of Patent: January 17, 2012Assignee: BYK-Chemie GmbHInventors: Bernd Göbelt, Carsten Nagel, Jürgen Omeis, Marcus Meichsner, Diana Walter
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Publication number: 20110306730Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and cyclohexanedimethanol residues. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: ApplicationFiled: August 23, 2011Publication date: December 15, 2011Applicant: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20110294955Abstract: Disclosed is a composition including a melt mixed blend including (a) 58 to 96.8 weight percent one or more copolyester thermoplastic elastomers; (b) 3 to 40 weight percent polyphenylene ether; (c) 0.1 to 6 weight % ionomer and (d) 0.1 to 8 weight percent of polymeric toughener selected from the group consisting ethylene copolymers of the formula E/X/Y wherein: E is the radical formed from ethylene; X is selected from the group consisting of radicals formed from CH2?CH(R1)—C(O)—OR2 wherein R1 is H, CH3 or C2H5, and R2 is an alkyl group having 1-8 carbon atoms; vinyl acetate; and mixtures thereof; wherein X comprises 0 to 50 weight % of E/X/Y copolymer; and Y is a radical formed from glycidyl (meth)acrylate; and wherein the composition has one or more low temperature glass transition(s) between minus 100 and plus 150° C. Also disclosed are molded articles including the compositions, including CVJ boots and air ducts for automotive applications.Type: ApplicationFiled: May 23, 2011Publication date: December 1, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: KAZUKI AKIBA
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Patent number: 8067525Abstract: Described are film(s) and/or sheet(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: November 29, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8063173Abstract: Described as one aspect of the invention are polyesters containing (a) a dicarboxylic acid component having from 70 to 100 mole % of terephthalic acid residues and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component having from 11 to 25 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 75 to 89 mole % of 1,4-cyclohexanedimethanol residues; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %. The polyesters may be manufactured into articles.Type: GrantFiled: March 28, 2006Date of Patent: November 22, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8063172Abstract: Described are film(s) and/or sheet(s) made using polyester compositions comprising polyesters comprising (a) a dicarboxylic acid component comprising 70 to 100 mole % of terephthalic acid residues, and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: November 22, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20110269873Abstract: The invention relates to biodegradable polyester mixture, comprising i) from 5 to 80% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic and aromatic dicarboxylic acids and on aliphatic dihydroxy compounds, and ii) from 20 to 95% by weight, based on the total weight of components i to ii, of at least one biodegradable homo- or copolyester selected from the group consisting of polylactide, polycaprolactone, polyhydroxyalkanoates, and polyesters composed of aliphatic dicarboxylic acids and of aliphatic diols, and iii) from 0.Type: ApplicationFiled: July 13, 2011Publication date: November 3, 2011Applicant: BASF SEInventors: Ursula Seeliger, Gabriel Skupin, Dirk Stärke
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Publication number: 20110237750Abstract: The present invention relates to a process for producing films which are resistant to tear propagation, by using biodegradable polyesters obtainable via polycondensation of: i) from 65 to 80 mol %, based on components i to ii, of one or more dicarboxylic acid derivatives or dicarboxylic acids selected from the group consisting of: succinic acid, adipic acid, sebacic acid, azelaic acid, and brassylic acid; ii) from 35 to 20 mol %, based on components i to ii, of a terephthalic acid derivative; iii) from 98 to 102 mol %, based on components i to ii, of a C2-C8-alkylenediol or C2-C6-oxyalkylenediol; iv) from 0.05 to 2% by weight, based on the polymer obtainable from components i to iii, of an at least trifunctional crosslinking agent or of an at least difunctional chain extender. The invention further relates to polymer mixtures which are suitable for producing films which are resistant to tear propagation.Type: ApplicationFiled: March 24, 2011Publication date: September 29, 2011Applicant: BASF SEInventors: Liqun Ren, Robert Loos