Two Or More Solid Polymers Other Than Prepared From A Polycarboxylic Acid Or Derivative And A Polyamine, A Lactam, An Aminocarboxylic Acid Or Derivative, Or From A Polyamine Salt Of A Polycarboxylic Acid Patents (Class 525/179)
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Patent number: 6780481Abstract: A melt processable polymer composition that comprises a thermoplastic non-aliphatic host polymer and a minor but effective amount of a fluoropolymer processing aid, and a method of improving the melt processability of the host polymer are provided.Type: GrantFiled: May 12, 2000Date of Patent: August 24, 2004Assignee: 3M Innovative Properties CompanyInventors: Claude Lavallée, Maria P. Dillon, Thomas J. Blong, Susan S. Woods, Shannon S. Le Blanc
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Publication number: 20040157968Abstract: A composition comprising a polymer selected from a polyolefin, a polyamide or mixture thereof, in admixture with an acrylic polymer additive, wherein: the shear viscosity of the composition is less than the shear viscosity of the same composition not containing the acrylic polymer; or, the extensional viscosity of the composition is less than the extensional viscosity of the same composition not containing the acrylic polymer additive; or, both of the shear viscosity and extensional viscosity of the composition is less than the shear viscosity and extensional viscosity of the same composition not containing the acrylic polymer addictive,when measured at an identical applied specific shear rate in the range of 5000 s−1 to 500 s−1 under substantially the same conditions.Type: ApplicationFiled: March 11, 2004Publication date: August 12, 2004Inventors: John Nicholas Marston, Mark Davies, John Robert Oliver
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Patent number: 6770378Abstract: Compounds which, for example, can be used as a compact substance and which are comprised of polyamide substance(s) and perfluoralkyl substance(s), and to mixtures of these compounds with additional polymer substance(s). Methods for producing such compounds are also provided in which aliphatic and/or partially aromatic homopolyamides and/or copolyamides and/or polyester amides and/or polyether amides and/or polyester ether amides and/or polyimide amides and/or polyamide amides and/or mixtures of these polyamide compound(s) with additional polymer(s) and modified perfluoralkyl substance(s) are compounded in a single step or multistep and are reactively converted during or afterwards. The homogenization of perfluoralkyl substance(s) in polyamide substance(s) melted masses is improved.Type: GrantFiled: January 5, 2001Date of Patent: August 3, 2004Assignee: Institut fur Polymerforschung E.V. DresdenInventor: Dieter Lehmann
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Patent number: 6765062Abstract: Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.Type: GrantFiled: July 10, 2002Date of Patent: July 20, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Hui Chin, James Botkin, Francesco Fuso, Wiebke Wunderlich
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Patent number: 6756444Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.Type: GrantFiled: February 14, 2002Date of Patent: June 29, 2004Assignee: Honeywell International Inc.Inventors: Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft
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Patent number: 6750288Abstract: The present invention relates to an isotactic polypropylene obtained by metallocene catalysis, onto which is grafted a functional monomer. The invention also relates to a composition which may form part of the composition of a coextrusion binder. This composition according to the invention comprises isotactic polypropylene obtained by metallocene catalysis, grafted and then optionally diluted with at least one polyolefin (C1) and/or in at least one polymer of elastomeric nature (D). The invention also relates to a multilayer structure comprising a layer (L) comprising the above binder, and, directly attached thereto, a layer (E): which is polar, nitrogenous or oxygenated, such as a layer of polyamide resin, of ethylene/saponified vinyl acetate copolymer (EVOH) or of polyester; or of a mineral oxide deposited on a polymer such as polyethylene (PE), polyethylene terephthalate (PET) or EVOH; or which is metallic or metalloplastic.Type: GrantFiled: July 31, 2002Date of Patent: June 15, 2004Assignee: AtofinaInventor: Jean-Laurent Pradel
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Patent number: 6747096Abstract: This invention relates to high molecular weight block copolymers of one or more lactones and/or one or more lactams prepared by sequential bulk polymerization using a mixture of at least one anionic polymerization initiator and optionally at least one co-initiator. A preferred continuous sequential bulk reactive extrusion process comprises feeding a mixture of at least one lactam, at least one anionic polymerization initiator, and at least one co-initiator into the first (i.e., upstream) hopper of an extruder, and thereafter feeding at least one lactone into a second (i.e., downstream) hopper of the extruder. The preferred continuous sequential bulk reactive extrusion is solvent free, rapid (typical mean and maximum residence times in the extruder being no more than about 20 minutes and 30 minutes respectively), and produces a high conversion of monomers to block copolymer.Type: GrantFiled: March 27, 2002Date of Patent: June 8, 2004Assignee: University of AkronInventors: James L. White, Charles E. Wilkes, Byong-Jun Kim
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Patent number: 6740708Abstract: An impact-resistant polymer composition exhibiting improved impact resistance at no loss in creep is obtained by melt-mixing a solid matrix polymer A with a solid composition containing the rubber composition dispersed in a matrix polymer B. The dispersion of rubber composition in matrix polymer B is obtained by melt mixing the matrix polymer B with a rubber composition which includes a functionality rubber and a non-functionality rubber. The amounts of the components are such that the impact-resistant polymer composition contains 0.5 to 75 parts by weight of the rubber composition per 100 parts by weight of the matrix polymers A and B. The composition may be used in various applications, including plugs, heat bridges for aluminum windows, hammer heads and the like.Type: GrantFiled: December 14, 2001Date of Patent: May 25, 2004Assignee: DSM IP Assets B.V.Inventors: Wilhelmus G. M. Bruls, Johannes F. Repin, Jan De Kroon
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Patent number: 6733854Abstract: Disclosed are a polyamide resin composition and a synthetic resin product prepared therefrom. The polyamide resin composition comprises 30-95 parts by weight of polyamide resin, 1-45 parts by weight of impact resistant component, 0.1-20 parts by weight of nylon plasticizer, 0.01-5 parts by weight of nylon thickener having at least two functional groups at the ends of its polymer chain and 0.5-10 parts by weight of core-shell rubber. Such composition is advantageous in light of much lower preparation cost, while retaining higher flexibility, moldability and excellent external appearance, compared to conventional nylon elastomer reinforced polyamide resin composition. Thereby, the composition can be effectively applied to internal or external decorative articles for motor vehicles and electrical or electronic components.Type: GrantFiled: December 19, 2001Date of Patent: May 11, 2004Assignees: Hyundai Motor Company, Honeyell Korea Ltd.Inventors: Sang-Rok Lee, Jin-Myung Choi
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Patent number: 6723443Abstract: This invention relates to blends of nylon homopolymers and copolymers with poly(hydroxyamino ether) polymers. More particularly, there are provided blends of nylon 6 and its copolymers with poly(hydroxyamino ether) which form films having high miscibility, high clarity and good processability.Type: GrantFiled: November 21, 2001Date of Patent: April 20, 2004Assignee: Honeywell International Inc.Inventors: Mingliang L. Tsai, Murali K. Akkapeddi, Clark V. Brown, Darnell C. Worley, II
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Publication number: 20040059056Abstract: The invention relates to a polyamide-based thermoplastic composition comprising, by weight:Type: ApplicationFiled: June 10, 2003Publication date: March 25, 2004Inventors: Thibaut Montanari, Philippe Bussi, Alain Bouilloux
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Patent number: 6696165Abstract: The invention provides a weatherable low gloss styrene copolymer composition which requires the addition of from 0.1 to 20% by weight of the total composition, of a partially crystalline polymer such as a polyalkylterephthalate, especially polybutyleneterephthalate or polyethyleneterephthalate, or polyethylenenaphthalate to a styrene copolymer (A). The low gloss styrene copolymer composition of the invention has a graft copolymer resin which results from polymerizing one or more monomers (A1) selected from the group consisting of (i) aromatic vinyl compounds, (ii) ethylenically unsaturated compounds, and (iii) mixtures thereof, in the presence of an elastomeric rubber (A2) in particulate form.Type: GrantFiled: June 28, 2000Date of Patent: February 24, 2004Assignee: BASF CorporationInventors: James H. Bennett, Klaus Mühlbach, Gary Kogowski, Heiner Görrissen, Graham Edmund Mc Kee
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Patent number: 6673867Abstract: A heat-resistant engineering-plastic composition that satisfies a soldering-heat resistance of 260° C. for 10 to 60 secs., that is less costly, that is free of problems in injection molding process, and that is excellent in heat-aging resistance. A heat-resistant molded product made with the heat-resistant engineering-plastic composition, such as a connector mounted on printed circuit board. The heat-resistant molded product is produced by (a) melt-kneading (a1) an engineering plastic either having or introduced an active site for reacting with a specific functional group and (a2) either an organic compound that has both the said specific functional group and a polymerizing functional group in the same molecule or polyolefin that has the said specific functional group described in (a1) to obtain a resin composition, (b) melt-molding the resin composition comprising of (a), and (c) irradiating the melt-molded resin composition with ionizing radiation.Type: GrantFiled: November 13, 2001Date of Patent: January 6, 2004Assignee: Sumitomo Electric Fine Polymer, Inc.Inventors: Hiroshi Hayami, Shinya Nishikawa
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Patent number: 6642310Abstract: Extrusion processability of non-fluorinated melt-processable polymers is improved by introducing a fluoropolymer process aid by means whereby the weight average particle size of the fluoropolymer is greater than 2 microns as it reaches the extruder die entrance.Type: GrantFiled: September 17, 2001Date of Patent: November 4, 2003Assignee: DuPont Dow Elastomers L.L.C.Inventors: George Richard Chapman, Jr., Steven Richard Oriani
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Patent number: 6624250Abstract: A substantially transparent, moldable, thermoplastic multipolymer composition comprising a methyl methacrylate copolymer containing a predominant amount of methyl methacrylate and a minor amount of one or more ethylenically unsaturated monomers; and an effective amount of from about 1% to 35% by weight of the composition, of a polyetheresteramide to enhance the electrostatic charge dissipation of the copolymer. The polyetheresteramide has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition, when subjected to injection molding, is such that the injection-molded composition exhibits a haze of not greater than about 25% and a light transmission of at least about 60%. The composition may include an impact modifier which also has a refractive index within about 0.005 units of the refractive index of the copolymer. The composition may also include a minor amount of a polyethylene glycol having a weight average molecular weight of about 2,000 to about 10,000.Type: GrantFiled: December 5, 2001Date of Patent: September 23, 2003Assignee: Cyro IndustriesInventor: Daniel Zimmerman
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Publication number: 20030158339Abstract: A golf ball providing resistance to abrasion and resistance to wear generally in an excellent balance is formed of a core and a cover arranged to cover the core, the cover being formed of a compound containing relative to 100 parts by mass of a polymer component thereof composed mainly of polybutadiene rubber 1-40 parts by mass of a reinforcement material formed of organic short fiber and 10-40 parts by mass of a metallic salt of &agr;,&bgr;-ethylene unsaturated carboxylic acid. It is characterized in that the organic short fiber is suitably a ternary composite formed of a rubber component, a polyolefin component and a nylon component and the metallic salt of &agr;,&bgr;-ethylene unsaturated carboxylic acid is suitably zinc acrylate, zinc methacrylate, magnesium acrylate or magnesium methacrylate.Type: ApplicationFiled: January 16, 2003Publication date: August 21, 2003Inventor: Satoshi Iwami
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Patent number: 6605656Abstract: A thermoplastic olefin resin composition having improved resistance to surface impacts, such as scratching, marring and gouging, is provided. The thermoplastic olefin resin comprises a blend of polyolefin alloy and polyamide components. The components have relative melt flow rates such that the polyamide component is selectively segregated toward the front of a melt flow. A compatibilizing agent is added to overcome the natural incompatibility of the polyolefin alloy and polyamide components of the resin. The thermoplastic olefin resin may further include a filler material when increased stiffness or modulus is desired.Type: GrantFiled: November 29, 2000Date of Patent: August 12, 2003Assignee: Visteon Global Technologies, Inc.Inventors: Rose A. Ryntz, Beth M. Wichterman
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Patent number: 6579938Abstract: Disclosed herein is a golf ball with a cover or mantle, or both, formed from a composition comprising a polyamide-ionomer graft copolymer and a method of making the same. Polyamide-ionomer graft copolymers include a polyamide component and an ionomeric component. In a preferred form, polyamide-ionomer graft copolymers have a polyamide component backbone and ionomeric components grafted thereto. Golf balls according to the invention may also be formed from a composition or material that includes a blend of a polyamide-ionomer graft copolymer and an ionomer. Such blends are preferably employed as a mantle or a cover of a golf ball. The cover composition has excellent durability and resistance to cracking, even at cold temperatures. Materials comprising polyamide-ionomer graft copolymer are a useful substitute for an ionomer golf ball cover, particularly when a low spin golf ball is desired.Type: GrantFiled: December 11, 2000Date of Patent: June 17, 2003Assignee: Spalding Sports Worldwide, Inc.Inventors: Michelle A. Bellinger, Michael J. Sullivan
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Patent number: 6579581Abstract: A molding which comprises the following components: (I) from 60 to 96.5 parts by weight of polyamide; (II) from 3 to 39.5 parts by weight of an impact-modifying component which contains anhydride groups, (III) from 0.5 to 20 parts by weight of a copolymer which contains units of the monomers: (a) &agr;-olefin, (b) acrylic compound, and also (c) olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline or oxazinone, where the total of the parts by weight of components I, II, and III is 100, and where moreover the polyamide has an excess of amino end groups, has improved low-temperature impact strength, even if the molding composition also comprises a plasticizer.Type: GrantFiled: June 22, 2001Date of Patent: June 17, 2003Assignee: Degussa AGInventors: Wilfried Bartz, Franz-Erich Baumann, Guido Schmitz, Georg Oenbrink, Harald Haeger
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Patent number: 6548181Abstract: The invention relates to a flexible polyamide composition containing at least 50 parts by weight of non-cross-linked rubber per 50 parts by weight of polyamide and the production thereof. The polyamide has a molecular weight such that the melt viscosity at the processing temperature is at most 300 pa.s, preferably at most 200 pa.s. The rubber's Mooney viscosity is at least 40, most preferable is a rubber with a Mooney viscosity of at least 60. The rubber has been functionalized. Preferably a combination of a functionalized and a non-functionalized rubber is used. The rubber particles in the polyamide matrix have a particle size of at most 5 &mgr;m, preferably at most 3 &mgr;m.Type: GrantFiled: September 26, 2001Date of Patent: April 15, 2003Assignee: DSM N.V.Inventor: Guido P. C. Beusen
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Patent number: 6541085Abstract: Disclosed is a member of nylon 12 having a relative viscosity of from 1.9 to 3.5 when measured in 98% sulfuric acid at a concentration of 10 g/dm3 and at 25° C. and a melt flow rate of 0.1 g/10 min. or more when measured at 235° C. under a load of 2,160 g, wherein said relative viscosity and said melt flow rate have a relationship of the following formula (I): 2.87×103 exp (−3.48 &eegr;r)≦MFR≦3.25×104 exp (−3.48 &eegr;r) (I) wherein &eegr;r is relative viscosity and MFR is melt flow rate. The nylon 12 has excellent extrusion moldability and creep characteristics, fatigue characteristics and the like mechanical properties and is suited for tubular molds. A nylon 12 composition comprising the nylon 12 having the above-described specific relationship between &eegr;r and MFR and a plasticizer is also disclosed.Type: GrantFiled: August 7, 2001Date of Patent: April 1, 2003Assignee: Ube Industries, Ltd.Inventors: Noriyuki Isobe, Tetsuji Hirano, Kouichiro Kurachi, Nobuhiro Ogawa
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Patent number: 6538099Abstract: Disclosed is a member of nylon 12 having a relative viscosity of from 1.9 to 3.5 when measured in 98% sulfuric acid at a concentration of 10 g/dm3 and at 25° C. and a melt flow rate of 0.1 g/10 min. or more when measured at 235° C. under a load of 2,160 g, wherein said relative viscosity and said melt flow rate have a relationship of the following formula (I): 2.87×103 exp(−3.48 &eegr;r)≦MFR≦3.25×104 exp(−3.48 &eegr;r) (I) wherein &eegr;r is relative viscosity and MFR is melt flow rate. The nylon 12 has excellent extrusion moldability and creep characteristics, fatigue characteristics and the like mechanical properties and is suited for tubular molds. A nylon 12 composition comprising the nylon 12 having the above-described specific relationship between &eegr;r and MFR and a plasticizer is also disclosed.Type: GrantFiled: August 7, 2001Date of Patent: March 25, 2003Assignee: Ube Industries, Ltd.Inventors: Noriyuki Isobe, Tetsuji Hirano, Kouichiro Kurachi, Nobuhiro Ogawa
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Patent number: 6531529Abstract: This invention is a flame-retardant, anti-dripping polyamide composition comprising a high temperature polyphthalamide, a halogen-containing organic compound, and an anti-drip effective amount of an anti-drip component comprising a polymer formed from at least one ethylenically unsaturated monomer and at least one carboxylic acid containing monomer.Type: GrantFiled: December 18, 2000Date of Patent: March 11, 2003Assignee: Solvay Advanced Polymers, L.L.C.Inventors: Bruce H. Bersted, Mark G. Reichmann
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Patent number: 6525137Abstract: The invention relates to an improvement to conveyors comprising moving elements which slide over fixed elements such that at least one moving element made of a polyamide-based blend (A) slides over a fixed element made of polyacetal and/or such that at least one moving element made of polyacetal slides over a fixed element made of a polyamide-based blend (A).Type: GrantFiled: December 1, 2000Date of Patent: February 25, 2003Assignee: AtofinaInventors: Patrick Alex, Christian Capion Knudsen, Niels Peter Rosenkrands
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Patent number: 6518334Abstract: This invention relates to polymer blends comprising a polycarboxypolyamide resin with an alkali dispersible resin. This invention also relates to the use of the polymer blends to prepare aqueous dispersions. The aqueous dispersions were obtained by heating polycarboxypolyamide resins with alkali dispersible resins in an aqueous medium. The invention further relates to coating compositions containing the aqueous dispersions. Such coating compositions include inks, floor finishes, overprint varnishes, sizing, paints and adhesives.Type: GrantFiled: March 22, 2000Date of Patent: February 11, 2003Assignee: JohnsonDiversey, Inc.Inventors: Glenn C. Calhoun, Michael T. Sarkis
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Patent number: 6486250Abstract: The present invention is directed to a golf ball and a to a process for forming a golf ball having least one layer, where the layer is formed of a saponified polymer/polyamide blend, having from about 1 to about 99 parts of at least one saponified polymer and from about 99 to 1 parts of at least one polyamide polymer, based on 100 parts by weight of the saponified polymer/polyamide blend. The layer may be foamed or unfoamed, and may form at least a portion of any of the cover, the core, or an intermediate layer situated between the cover and the core.Type: GrantFiled: June 30, 2000Date of Patent: November 26, 2002Assignee: Acushnet CompanyInventor: Murali Rajagopalan
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Patent number: 6476125Abstract: A fluorine-containing polymer alloy comprising a grafted fluorine-containing polymer (a) and a polymer (c) containing no fluorine atom, said grafted fluorine-containing polymer (a) comprising a fluorine-containing polymer (d) having hydrogen atoms bonded to carbon atoms of its main chain and a grafting compound having a linking group capable of grafting to the fluorine-containing polymer (d) and a functional group capable of providing an adhesive property, grafted to the fluorine-containing polymer (d).Type: GrantFiled: August 21, 1996Date of Patent: November 5, 2002Assignee: Asahi Glass Company Ltd.Inventors: Jun-ichi Iura, Eiichi Nishi, Masataka Yokota
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Publication number: 20020161122Abstract: A sulfur-containing water insoluble hydrogel polymer for selectively removing trace amounts of dissolved metal species is produced from a reaction product of nitrilotriacetic acid (NTA) and polyethylenimine (PEI) which is then treated in a water-swollen state with carbon disulfide. The polymer has a physical configuration that facilitates formation of a porous stationary bed through which water can pass for treatment.Type: ApplicationFiled: March 15, 2001Publication date: October 31, 2002Inventor: Norman B. Rainer
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Publication number: 20020147280Abstract: The present invention relates to a golf ball comprising at least one core layer, a cover layer, and at lest one intermediate layer disposed between the core and the cover, wherein the at least one layer is formed of a polymer composition comprising at least one ionomer and at least one polyamide polymer.Type: ApplicationFiled: February 6, 2002Publication date: October 10, 2002Inventor: Murali Rajagopalan
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Patent number: 6451912Abstract: Flexible, halogen-free, high frequency-sealable films fabricated from a blend of a copolyamide and a polyolefin having a carboxylic acid or carboxylic acid anhydride functionality have sufficient copolyamide to yield a DLF of at least 0.05 at a frequency of 27 megahertz and serve as effective substitutes for flexible polyvinyl chloride films. The films may be mono-layer films or multi-layer films, especially where the high frequency-sealable films serve as outer or skin layers in multi-layer films. Products made from such monolayer and multi-layer films find utility in a number of applications, especially for medical device applications.Type: GrantFiled: March 12, 2001Date of Patent: September 17, 2002Assignee: Dow Global Technologies Inc.Inventor: Robert H. Kelch
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Patent number: 6451911Abstract: The invention relates to a composition based on an ethylene-vinyl alcohol copolymer comprising: 50 to 98% by weight of an EVOH copolymer 1 to 50% by weight of a polyethylene (A) 1 to 15% by weight of a polymer (B) resulting from the reaction (i) of a copolymer (B1) of ethylene and of an unsaturated monomer X grafted or copolymerized with (ii) a polyamide (B2). It also relates to a multilayer structure comprising a layer consisting of this composition. This structure is useful for making packaging. The composition of the invention also adheres well to PET, this property being useful in coinjection to make bioriented preforms.Type: GrantFiled: January 19, 2000Date of Patent: September 17, 2002Assignee: AtofinaInventors: Denis Bertin, Denis Germain, Patrice Robert
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Publication number: 20020128385Abstract: The invention relates to a flexible polyamide composition containing at least 50 parts by weight of non-cross-linked rubber per 50 parts by weight of polyamide and the production thereof. The polyamide has a molecular weight such that the melt viscosity at the processing temperature is at most 300 pa.s, preferably at most 200 pa.s. The rubber's Mooney viscosity is at least 40, most preferable is a rubber with a Mooney viscosity of at least 60. The rubber has been functionalized. Preferably a combination of a functionalized and a non-functionalized rubber is used. The rubber particles in the polyamide matrix have a particle size of at most 5 &mgr;m, preferably at most 3 &mgr;m.Type: ApplicationFiled: September 26, 2001Publication date: September 12, 2002Applicant: DSM N.V.Inventor: Guido P.C. Beusen
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Patent number: 6444754Abstract: Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.Type: GrantFiled: August 8, 2000Date of Patent: September 3, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Hui Chin, James Botkin, Francesco Fuso, Wiebke Wunderlich
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Patent number: 6432548Abstract: The invention relates to compositions containing a polyamide matrix (A) and a polyolefin dispersed phase (B), in which compositions the polyamide has a melting point below that of PA-6 and the dispersed phase consists of at least one polyolefin (B) chosen from functionalized polyolefins (B1) and non-functionalized polyolefins (B2). Advantageously, (A) is PA-6/12 or PA-6/6,6. These compositions are useful for making monolayer or multilayer films by extrusion with EVA or PE.Type: GrantFiled: June 2, 2000Date of Patent: August 13, 2002Assignee: AtofinaInventors: Patrick Alex, Jean-Jacques Flat, Philippe Blondel, Gérard Reignier
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Patent number: 6423776Abstract: Oxygen barrier polyamide compositions exhibiting high oxygen scavenging capability suitable for extended shelf-life, packaging applications. Thus a polyamide composition comprises a polyamide homopolymer, copolymer, or blends thereof, and at least one polyamide reactive, oxidizable polydiene or oxidizable polyether. The polyamide products are particularly suited to making barrier packaging articles such as monolayer or multi-layer films, sheets, thermoformed containers and coinjection/coextrusion blow molded bottles comprising PET, polyolefin or polycarbonate as structural layers. Such articles are useful in a variety of oxygen-sensitive food, beverage, pharmaceutical and health care product packaging applications.Type: GrantFiled: May 2, 2000Date of Patent: July 23, 2002Assignee: Honeywell International Inc.Inventors: Murali K. Akkapeddi, Timothy J. Kraft, Edward P. Socci
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Patent number: 6420481Abstract: A multiphase polymer composition having increased impact resistance at low temperatures, includes a blend of an ionomer dispersed in nylon 6, a polyamide other than nylon 6, and a composition that includes EP or EPDM grafted with 0.05 to 3 weight percent of a carboxylic acid or any anhydride thereof. The ionomer is formed from a partially neutralized acid copolymer precursor, the acid copolymer precursor having polymerized in-chain units derived from the monomers comprising: (a) ethylene, (b) 2 to 25 weight percent of (meth)acrylic acid, (c) 0.1 to 15 weight percent of a dicarboxylic acid monomer, (d) 0-40 weight percent of a C1-C8-alkyl alkyl acrylate, the ionomer being formed by neutralization of from about 5 to 90 percent of the total number of carboxylic acid units in the copolymer with metal ions.Type: GrantFiled: February 15, 2001Date of Patent: July 16, 2002Assignee: E. I. du Pont de Nemours and ComapnyInventors: Silvia Di-Benedetto, Edmund A. Flexman
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Patent number: 6417284Abstract: A release coating layer comprising a continuous phase of an organic polymer binder; a discontinuous phase of a fluorinated resin having a molecular weight between 2500 and 10,000,000, wherein the ratio of organic polymer binder to fluorinated resin is between 60:39.9 to 80:18 by weight; and a priming agent composition comprising a perfluoroalkylsubstituted fluororesin-reactive compound having the formula: where R5 is H or F, Q is OH, SiR6R7R8, R6, R7, and R8 being independently selected from the group consisting of Cl, OH, an alkyl group containing 1 to about 4 carbon atoms, an alkoxy group containing 1 to about 4 carbon atoms, an acyloxy group containing 2 to about 4 carbon atoms, and an amino group containing 0 to about 4 carbon atoms; and n is an integer from 1 to about 15; with the proviso that, at least one of R6, R7, and R8 is Cl, OH, or an alkoxy, acyloxy, or amino group.Type: GrantFiled: September 30, 1999Date of Patent: July 9, 2002Assignee: NexPress Solutions LLCInventors: Jiann-Hsing Chen, Biao Tan, Joseph A. Pavlisko, Robert A. Lancaster, Craig M. Cody
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Patent number: 6414081Abstract: The invention relates to compatibilized blends comprising a non-polar thermoplastic elastomer, a polar thermoplastic polymer selected from thermoplastic polyurethane (TPU), chloro containing polymers, fluoro containing polymers, polyesters, acrylonitrile-butadiene-styrene copolymers, styrene-acrylonitrile copolymers, styrene-maleic anhydride copolymer, polyacetal, polycarbonate, polyphenylene oxide, and a suitable compatibilizer.Type: GrantFiled: May 23, 2000Date of Patent: July 2, 2002Assignee: Advanced Elastomer Systems, LP.Inventor: Trazollah Ouhadi
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Publication number: 20020082352Abstract: Good adhesion between layers is achieved in a multilayer composite having the following layers:Type: ApplicationFiled: December 26, 2001Publication date: June 27, 2002Applicant: Degussa AGInventors: Guido Schmitz, Harald Haeger
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Patent number: 6407158Abstract: The present invention relates to a water-soluble or water-dispersible polymeric salt, to a cosmetic or pharmacuetical composition which comprises at least one such polymeric salt, and to the use of the polymeric salts.Type: GrantFiled: March 20, 2000Date of Patent: June 18, 2002Assignee: BASF AktiengesellschaftInventors: Son Nguyen Kim, Axel Sanner, Peter Hössel
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Patent number: 6407164Abstract: The present invention relates to a multiphase thermoplastic composition consisting of a mixture (I) including at least one ethylene polymer (A) which has units derived from unsaturated epoxy and at least one thermoplastic resin (B) partly encapsulated by the said ethylene polymer (A), the said mixture (I) being dispersed in a matrix of thermoplastic resin (C).Type: GrantFiled: May 20, 1996Date of Patent: June 18, 2002Assignee: Atofina SAInventors: Marius Hert, Patrice Perret
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Patent number: 6391971Abstract: A short fiber-reinforced rubber composition comprises a master batch (A) comprised of (a) a first diene-based elastomer, (b) a polyolefin having a melting point of 100-150° C. and (c) short fibers of a thermoplastic polymer having amide group in its main chain, and a second diene-based elastomer (B) kneaded with the master batch (A), in which an amount of the component (c) is 5-30 parts by weight based on 100 parts by weight in total of the first diene-based elastomer and the second diene-based elastomer. Further, a rubber sheet made of the short fiber-reinforced rubber composition is inserted in a given zone of the sidewall portion, whereby the stiffness of the sidewall portion is enhanced to simultaneously establish the steering stability and the ride comfort and reduce the rolling resistance.Type: GrantFiled: November 12, 1999Date of Patent: May 21, 2002Assignee: Bridgestone CorporationInventor: Hiroyuki Teratani
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Patent number: 6384140Abstract: Disclosed herein is a golf ball with a cover formed from a polyamide composition and a method of making the same. More specifically, the golf ball has a cover which contains a combination of a polyamide component including polyphthalamide and an ionomeric component or a non-ionomeric terpolymer component. The cover composition has excellent durability and resistance to cracking, even at cold temperatures. The nylon-ionomer blend is a useful substitute for an ionomer golf ball cover, particularly when a low spin golf ball is desired.Type: GrantFiled: March 10, 2000Date of Patent: May 7, 2002Assignee: Spalding Sports Worldwide, Inc.Inventors: David M. Melanson, Michelle A. Bellinger
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Patent number: 6380310Abstract: Disclosed herein is a golf ball with a cover formed from a polyamide composition and a method of making the same. More specifically, the golf ball has a cover which contains a combination of a polyamide component and an ionomeric component or a non-ionomeric terpolymer component. The cover composition has excellent durability and resistance to cracking, even at cold temperatures. The nylon-ionomer blend is a useful substitute for an ionomer golf ball cover, particularly when a low spin golf ball is desired.Type: GrantFiled: February 1, 1999Date of Patent: April 30, 2002Inventors: Michelle A. Bellinger, Michael J. Sullivan
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Patent number: 6359055Abstract: Polyamide-based compositions whose processability is improved by the addition of a processing agent chosen from fluoropolymers. These compositions are useful for molding shaped articles by extrusion, extrusion blowing, extrusion thermoforming or injection molding.Type: GrantFiled: April 26, 1994Date of Patent: March 19, 2002Assignee: Solvay( Societe Anonyme)Inventors: Vincent Delannoy, Jacques D'Heur
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Patent number: 6353058Abstract: A golf ball including at least one core layer, a cover layer, and at least one intermediate layer disposed between the core and the cover, wherein the at least one intermediate layer is formed of a polymer composition having a flexural modulus of about 52,000 psi or less and the golf ball has a coefficient of restitution of greater than about 0.7, wherein the polymer composition includes at least one ionomer and at least one polyamide polymer, or wherein the polymer composition includes a thermoset or thermoplastic polymer.Type: GrantFiled: June 16, 1999Date of Patent: March 5, 2002Assignee: Acushnet CompanyInventor: Murali Rajagopalan
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Patent number: 6346571Abstract: A thermoplastic composition which may be unvulcanized or vulcanized is provided which comprises a polymer blend of an elastomeric thermoplastic engineering resin and a halogen-containing copolymer of a C4 to C7 isomonoolefin and a para-alkylstyrene. A process for preparing a dynamically vulcanized composition is also provided.Type: GrantFiled: November 2, 1999Date of Patent: February 12, 2002Assignee: ExxonMobil Chemical Patents Inc.Inventors: Narayanaswami Raja Dharmarajan, Robert Chester Puydak, Hsien Chang Wang, Kenneth William Powers, Thomas Chen-Chi Yu, Donald Ross Hazelton
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Patent number: 6344269Abstract: A heat-transfer label that is well-suited for use on untreated polyethylene, particularly untreated high-density polyethylene and untreated low-density polyethylene. In one embodiment, the label includes a support portion, the support portion comprising a paper carrier web. The label also includes a wax release layer overcoating the paper carrier web. The label further comprises a transfer portion printed on top of the wax release layer, the transfer portion including a protective lacquer layer, an ink layer and an adhesive layer. The protective lacquer layer is printed onto the wax release layer and comprises a polyester resin, castor oil and a chlorinated polypropylene capable of immobilizing the ink layer relative to the protective lacquer. The ink layer, which comprises an acrylic ink, is printed onto the protective lacquer layer. The adhesive layer is printed over the ink layer and comprises a polyamide resin, an ethylene vinyl acetate resin, erucamide and a chlorinated polyethylene resin.Type: GrantFiled: August 27, 1997Date of Patent: February 5, 2002Assignee: Avery Dennison CorporationInventors: Onsy Y. Makar, Samuel H. Stein
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Publication number: 20020013413Abstract: A technique for preparing polyamide-ionomer graft copolymers is disclosed which involves first preparing a copolymer from a polyamide and an ionomer precursor, and then neutralizing the ionomer precursor. Also disclosed is a technique for preparing a polyamide and ionomer blend by first blending a polyamide and an ionomer precursor together, and then neutralizing the ionomer precursor. Golf balls utilizing these compositions and related methods of forming are also described herein.Type: ApplicationFiled: March 14, 2001Publication date: January 31, 2002Inventors: Michelle A. Bellinger, David M. Melanson
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Publication number: 20020004555Abstract: A multiphase polymer composition having increased impact resistance at low temperatures, includes a blend of an ionomer dispersed in nylon 6, a polyamide other than nylon 6, and a composition that includes EP or EPDM grafted with 0.05 to 3 weight percent of a carboxylic acid or any anhydride thereof. The ionomer is formed from a partially neutralized acid copolymer precursor, the acid copolymer precursor having polymerized in-chain units derived from the monomers comprising: (a) ethylene, (b) 2 to 25 weight percent of (meth)acrylic acid, (c) 0.1 to 15 weight percent of a dicarboxylic acid monomer, (d) 0-40 weight percent of a C1-C8-alkyl alkyl acrylate, the ionomer being formed by neutralization of from about 5 to 90 percent of the total number of carboxylic acid units in the copolymer with metal ions.Type: ApplicationFiled: January 19, 2001Publication date: January 10, 2002Inventors: Silvia Di-Benedetto, Edmund A. Flexman