Treating Polymer Or Polymer Mixture With A Chemical Treating Agent Other Than Solid Polymer Patents (Class 525/192)
  • Patent number: 7456241
    Abstract: Microfine powder adhesive blends are provided. The powders are comprised of a polyolefin base resin component and acid or acid derivative functionalized polyolefin component with one or more optional components. The microfine powders are produced from melt blended adhesive products using a dispersion process and have median particle sizes from 5 to 250 micrometers.
    Type: Grant
    Filed: August 23, 2005
    Date of Patent: November 25, 2008
    Assignee: Equistar Chemicals, LP
    Inventors: Douglas C. McFaddin, David O. Bostrom
  • Patent number: 7435786
    Abstract: The present invention relates to a partially-crystalline copolymer comprising tetrafluoroethylene, hexafluoropropylene in an amount corresponding to hexafluoropropylene index (HFPI) of from about 2.8 to 5.3, and preferably from about 0.2% to 3% by weight of perfluoro(alkyl vinyl ether), said copolymer being polymerized and isolated in the absence of added alkali metal salts, having a melt flow rate of within the range of about 30±3 g/10 min, and having no more than about 50 unstable endgroups/106 carbon atoms can be extruded at high speed onto conductor over a broad polymer melt temperature range to give insulated wire of high quality.
    Type: Grant
    Filed: August 16, 2006
    Date of Patent: October 14, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Thomas Robert Earnest, Jr., Daniel N. Favereau, Niall D. McKee, Patricia A. Tooley
  • Patent number: 7423079
    Abstract: Synthetic textile articles (e.g., filaments, fibers, yarns, fabrics and the like) and processes of making the same are provided which include flame-retardant SAP particles. The SAP particles are most preferably hydrated with an aqueous flame-retardant solution. In this regard, the flame-retardant solution may consist essentially of water alone or a water solution containing one or more water soluble inorganic flame retardants. When SAP particles are hydrated with an aqueous inorganic flame retardant solution, the SAP particles may thereafter be dried to remove substantially the water component. In such a manner, the inorganic flame retardant will remain as a dried residue physically entrained within the SAP particles. As such, the SAP particles serve as a physical matrix in which the inorganic flame retardant is homogenously dispersed. The SAP particles may then be chemically or physically affixed to the textile article in an amount sufficient to render the article flame-retardant.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: September 9, 2008
    Assignee: Luna Innovations Incorporated
    Inventors: Martin E. Rogers, Janice Paige Phillips, Bryan Koene
  • Patent number: 7423087
    Abstract: The present invention relates to the reduction of oligomer content of melt-processible fluoropolymer so that the fluoropolymer has at least 25 ppm less oligomer than the as-polymerized fluoropolymer.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: September 9, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Gregory Allen Chapman, David E. Bidstrup
  • Publication number: 20080200606
    Abstract: An objective of the present invention is to provide a block copolymer which is excellent in processability at the time of preparing a rubber composition and leads to a cross-linked rubber composition excellent in tensile property, wearing resistance, weatherability, ozone resistance and heat aging resistance when it is cross-linked, a rubber composition containing the block copolymer and a molded product. The block copolymer of the present invention comprises two polymer blocks each having an ethylenic unsaturated bond and other polymer block which is interposed between two polymer blocks, has a uniform weight average molecular weight in the range from 5,000 to 100,000. The weight average molecular weight of the polymer block having the ethylenic unsaturated bond is preferably in the range from 1,000 to 20,000.
    Type: Application
    Filed: April 11, 2008
    Publication date: August 21, 2008
    Applicant: JSR CORPORATION
    Inventors: Toshihiro Tadaki, Naokazu Kobayashi, Iwakazu Hattori
  • Patent number: 7411024
    Abstract: Interpolymer resin particles comprised of 20% to 60% by weight of uncross-linked polyolefin e.g. polyethylene, polypropylene, and from 40% to 80% by weight based on the weight of the particles of a vinyl aromatic monomer, e.g. styrene, that is polymerized in a suspension process to form an interpenetrating network of polyolefin with polymerized vinyl aromatic monomer particles and having a gel content of 0 to 1.5% by weight based on the weight of the particles for improved processability in end-use applications and improved ESCR properties. The interpolymer resin particles have a VICAT softening temperature from about 90° C. to about 115° C., and a melt index from 0.2 to 35.0 g/10 minutes (Condition G). The particles can be mixed with a blowing agent to form extruded foam articles, such as foam board, and can be used in extrusion, injection molding, rotomolding, and thermoforming processes to form a layer, e.g.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: August 12, 2008
    Assignee: NOVA Chemicals Inc.
    Inventor: Steven M. Krupinski
  • Patent number: 7399809
    Abstract: A method of modifying a polyethylene is disclosed. In the method ethylene or a mixture of ethylene and a C3-C10 ?-olefin is polymerized in an organic solvent with a Ziegler or single-site catalyst to form an initial polyethylene solution. The initial polyethylene solution is then reacted with a free radical initiator to produce a modified polyethylene. The modified polymer has an enhanced melt elasticity and increased long chain branching index, and is essentially free of gel.
    Type: Grant
    Filed: January 11, 2007
    Date of Patent: July 15, 2008
    Assignee: Equistar Chemicals, LP
    Inventors: Andrew J. Scheie, Mark K. Reinking
  • Publication number: 20080167428
    Abstract: A polypropylene composition comprising (percent by weight) (a) 50-77 % of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar % and a polydispersity index ranging from 4 to 10; (b) 13-28 % of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 70 % and being partially soluble in xylene at ambient temperature, the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2 to 4 dl/g; and (c) 10-22 % of polyethylene having an intrinsic viscosity value ranging from 1 to 3 dl/g, in said composition component (b) plus component (c) being in amounts of at least 25 wt %. The polymer composition exhibits good impact resistant, whitening resistance and relatively low stiffness.
    Type: Application
    Filed: November 28, 2005
    Publication date: July 10, 2008
    Applicant: Basell Poliolefine Italia S.R.L.
    Inventors: Paola Massari, Marco Ciarafoni, Jean News
  • Patent number: 7396879
    Abstract: Residual monomer in a polymer matrix may be reduced by a method including admixing a polymer matrix comprising an amount of residual monomer and a conjugated diene. This method can be carried out under reaction conditions such that the amount of residual monomer is reduced. The monomer comprises at least one electron withdrawing substituent and the conjugated diene comprises at least one electron donating substituent. This method is particularly useful for reducing the amount of residual styrene monomer in polystyrene homopolymer and copolymer compositions.
    Type: Grant
    Filed: February 22, 2005
    Date of Patent: July 8, 2008
    Assignee: Fina Technology, Inc.
    Inventor: Jay Reimers
  • Patent number: 7396882
    Abstract: Styrene-free unsaturated polyester resin compositions are provided which have low volatile organic compounds and hazardous air pollutants emissions when these resin compositions are used in open molding applications. A process for the manufacture of these resin compositions is provided.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: July 8, 2008
    Assignee: AOC, LLC
    Inventors: John C. Hewitt, John E. McAlvin, Paul Taylor Hutson, Amber E. Craig, Marjorie Krantz, Derek K. Rivers
  • Patent number: 7393900
    Abstract: A chlorinated rubber composition which is resistant to various fluids such as transmission fluids comprises a blend of a chlorinated polyethylene elastomer, an ethylene acrylic elastomer and/or polyacrylic rubbers, and optionally a chlorosulfonated polyethylene. The rubber composition has many uses such as a tube and generally contains various additives such as fillers, plasticizers, vulcanizing agents, and the like. A heat resistant rubber composition comprises a blend of a chlorinated polyethylene elastomer, an ethylene-acrylic elastomer and/or polyacrylic rubbers, an ethylene-octene copolymer, and an ethylene-propylene-diene terpolymer, and the same can be used as a cover or jacket as on the above chlorinated rubber tube.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: July 1, 2008
    Assignee: Excel-Polymers, LLC
    Inventor: Matthew S. Snider
  • Patent number: 7390850
    Abstract: A thermoplastic elastomer composition comprises a blend of a thermoplastic component with a cured elastomer component characterised in that the elastomer component prior to curing comprises a major proportion of a main elastomer and a minor proportion of a high molecular weight reactive polymer which shows a higher crosslinking efficiency in free-radical induced vulcanisation than the main elastomer. Preferably, the high molecular weight reactive polymer comprises from (3) to (15), and more preferably (4) to (10), parts by weight per one hundred parts of the total elastomer component of the composition. The use of the high molecular weight reactive polymer in the composition improves the low temperature performance of the composition and gives improvements to the processing behaviour, the resistance to stiffening at low temperatures and recovery/relaxation properties. Preferably, the high molecular weight reactive polymer is miscible with the main elastomer in the elastomer component.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: June 24, 2008
    Assignee: Tun Abdul Razak Research Centre
    Inventors: Stuart Cook, Andrew Tinker, Jaymini Patel
  • Publication number: 20080146739
    Abstract: Process for removal of residual styrene monomers from polystyrene and from blends comprising water-insoluble, crosslinked polyvinylpyrrolidone, via treatment with water, which comprises carrying out the treatment on a particulate solid blend.
    Type: Application
    Filed: March 14, 2006
    Publication date: June 19, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Klemens Mathauer, Marianna Pierobon, Tobias Petsch, Karl-Otto Heilmann, Michael Kerber, Robert Bayer
  • Patent number: 7385007
    Abstract: The present invention provides a pressure sensitive adhesive composition for optical members, which is excellent in durability, re-releasability and stress relaxation, as well as a pressure sensitive adhesive composition for optical members, which hardly increases adhesion after storage for a long time and does not leave a residual adhesive on glass upon disposal or repair. The pressure sensitive adhesive composition for optical members according to the present invention comprises 100 parts by weight of an acrylic polymer (A) having a weight-average molecular weight of 500,000 or more, containing at least 50 wt % alkyl (meth)acrylate having an alkyl group with 5 or more carbon atoms and 0.2 to 2 wt % unsaturated carboxylic acid as the monomer unit, 0.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: June 10, 2008
    Assignee: Nitto Denko Corporation
    Inventors: Yutaka Moroishi, Fumiko Nakano, Tetsuo Inoue, Yoshihide Kawaguchi, Kohei Yano
  • Patent number: 7371798
    Abstract: A thermoplastic water-curable composition which is excellent in mechanical properties, heat resistance, dimensional stability, and moldability and from which a mechanical part of a complicated shape can be produced: a molding formed from the thermoplastic water-curable composition; and a process for producing the molding. The thermoplastic water-curable composition comprises: a thermoplastic resin which upon contact with water undergoes a cross-linking reaction and thus comes to have a high molecular weight, desirably one having silane groups in inner parts thereof and a water-curable composition, the amount of water-curable composition being desirably 200 to 700 parts by weight per 100 parts by weight of the resin The molding is formed from the thermoplastic water-curable composition. The process comprises molding the thermoplastic water-curable composition into a given shape and then bringing the molding into contact with water to age and cure it.
    Type: Grant
    Filed: December 12, 2002
    Date of Patent: May 13, 2008
    Assignee: Sumitomo Osaka Cement Co., Ltd.
    Inventors: Satoshi Ozawa, Kouji Mikami, Shigefumi Hisatsune
  • Patent number: 7368506
    Abstract: A peroxide-crosslinked rubber composition having a superior anti-blooming property of a crosslinking agent and a high hardness containing (A) more than 60 parts by weight but not more than 95 parts by weight of rubber selected from NR, IR, SBR, BR, EPM, EPDM, silicone rubber and/or fluororubber and (B) 5 parts by weight but less than 40 parts by weight of a polar polymer having a solubility parameter (Sp value) of at least 17.6 (Pa1/2) and a weight average molecular weight of at least 100,000.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: May 6, 2008
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventor: Daisuke Kanenari
  • Patent number: 7365131
    Abstract: A thermoplastic vulcanizate composition comprised of (a) thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) at least one elastomer selected from the group consisting of butadiene-isoprene copolymer rubbers, copolymers of a conjugated diolefin monomer and an acrylate monomer, copolymers of a conjugated diolefin monomer and an methacrylate monomer, copolymers of a conjugated diolefin monomer and a vinyl aromatic monomer, copolymers of a conjugated diolefin monomer and an acrylonitrile monomer, blends of polyisoprene rubber with styrene-butadiene rubber, wherein the elastomer is at least partially crosslinked, wherein the repeat units in the elastomer are distributed throughout the elastomer in an essentially random manner, and (c) oil.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: April 29, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Manoj Ajbani, Christopher Kiehl, Thierry Florent Edme Materne
  • Publication number: 20080057313
    Abstract: Embodiments of the present invention include a heat-shrinkable article, comprising a thermoset cross-linked polymeric composition, wherein the cross-linked polymeric composition comprises at least one polypropylene polymer, and at least one polyethylene polymer, wherein the composition has a polypropylene content of less than about 50 percent by weight, and a polyethylene content of less than about 50 percent by weight, based on the total weight of the cross-linked polymeric composition. A method for making the heat-shrinkable article comprises melt mixing the at least one polypropylene polymer with the at least one polyethylene polymer and at least one additional ingredient, extruding the composition blend to form an extruded material, cross-linking the extruded material to produce a thermoset cross-linked material, stretching the cross-linked material at a temperature at or above a melting point of the material, and cooling the stretched material to maintain a form of the stretched material.
    Type: Application
    Filed: September 1, 2006
    Publication date: March 6, 2008
    Inventors: Sirarpi Bicakci-Jenkins, Abboud L. Mamish
  • Publication number: 20080051516
    Abstract: A thermoplastic vulcanizate comprising (i) a dynamically-cured rubber, and (ii) a thermoplastic polymer component, where the thermoplastic polymer component includes (a) a propylene-?-olefin thermoplastic copolymer characterized by including at least 5% by weight up to 35% by weight units deriving from ?-olefins, and having a heat of fusion, as determined by DSC, of less than 80 J/g, (b) and a functionalized thermoplastic polymer.
    Type: Application
    Filed: August 28, 2006
    Publication date: February 28, 2008
    Inventors: Weiguo Hu, Jim Lee Johnson
  • Patent number: 7332544
    Abstract: A chlorinated vinyl chloride-based resin composition in which from 2 to 9 parts by weight of an MBS resin and from 0.5 to 3 parts by weight of chlorinated polyethylene are blended to 100 parts by weight of a chlorinated vinyl chloride-based resin with a chlorine content of from 62 to 70% by weight obtained by post-chlorinating a vinyl chloride-based resin, which can provide an injection molding product such as a joint of excellent heat resistance, impact strength, moldability and surface property.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: February 19, 2008
    Assignee: Kaneka Corporation
    Inventor: Takeyuki Suzuki
  • Publication number: 20080039576
    Abstract: In one embodiment herein there is provided a hot melt vulcanizate composition made by the process comprising: a) producing a reaction product (i) from (1) at least one first resin selected from the group consisting of thermoplastic polymer and elastomeric polymer, (2) at least one unsaturated carboxylic acid anhydride, (3) at least one alkylamine possessing two or more amine functionalities, and optionally (4) at least one free-radical generating catalyst, and wherein said reaction product (i) optionally further comprises, at least one first additive; and, optionally, b) blending said reaction product (i) with at least one second resin selected from the group consisting of thermoplastic polymer and elastomeric polymer, provided that at least one of second resin is different from at least one of first resin and, optionally, at least one second additive; c) curing said reaction product (i), wherein reaction product (i) has been blended as in (b) above, or not, to produce a hot melt vulcanizate composition; a
    Type: Application
    Filed: August 14, 2006
    Publication date: February 14, 2008
    Applicant: General Electric Company
    Inventors: Roy M. Griswold, Francis J. McKeon, Timothy J. Fahrenkopf, Philbert E. Ramdatt
  • Patent number: 7326752
    Abstract: Styrene-free unsaturated polyester resin compositions are provided which contain low amounts of hazardous air pollutants, good mechanical and physical properties and good weathering characteristics. A process for the manufacture of these resin compositions is also provided.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: February 5, 2008
    Assignee: AOC, LLC
    Inventors: John E. McAlvin, Daniel A. Oakley, Paul Taylor Hutson, David J. Zwissler, Thomas J. Folda
  • Publication number: 20080015313
    Abstract: Thermoplastic vulcanizates having improved physical properties, including extrusion surface roughness can be achieved by a method that includes a first processing step to form a fully cured TPV base, a cooling step wherein the fully cured TPV base is solidified and a second processing step which imparts improved physical properties including improved extrusion surface roughness to the resultant TPV. The method may be adapted for use in conjunction with a peroxide curing agents to protect a portion of the thermoplastic, which may be polypropylene, from degradation by the peroxide curing agent. The adaptation to the methods may include the addition of a portion of the thermoplastic to the TPV after the peroxide curing agent has been added. The adaptation may also include one or more devolatalization steps with or without the addition of a stripping agent.
    Type: Application
    Filed: July 11, 2006
    Publication date: January 17, 2008
    Inventor: Oansuk Chung
  • Publication number: 20080009588
    Abstract: It is an object of the present invention to provide a method for producing an olefin thermoplastic elastomer composition which, through dynamic crosslinking of an olefin resin and an ethylene-?-olefin copolymer rubber as polymer components, has excellent appearance of the extrusion molding while also having excellent physical properties such as compression set, oil resistance and tensile strength. The present invention is directed to a method for producing a thermoplastic elastomer composition having the steps of: dynamically heat treating the following components (A) to (D); adding a component (E) to a resulting composition; and kneading a resulting mixture, (A): an ethylene-?-olefin-based copolymer rubber; (B): a polyolefin resin; (C): a halogenated alkylphenolic resin-based crosslinking agent; (D): zinc oxide; and (E): a halogen capturing agent.
    Type: Application
    Filed: July 2, 2007
    Publication date: January 10, 2008
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kohichi Iketani, Hironobu Shigematsu, Nobuhiro Natsuyama
  • Patent number: 7309738
    Abstract: The invention provides polymer blends containing polyhydroxyamide and one or more flammable polymers. The polymer blends are flame retardant and have improved durability and heat stability compared to the flammable polymer portion of the blends. Articles containing the polymer blends are also provided.
    Type: Grant
    Filed: October 6, 2004
    Date of Patent: December 18, 2007
    Assignee: United States of America as Represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Martha K. Williams, Trent M. Smith
  • Patent number: 7297743
    Abstract: The object of the present invention is to significantly improve weather resistance over a long period of time of the cured product of the invention, while maintaining physical properties, such as tensile properties and rubber-like elasticity, at levels required of sealing compositions for use in general buildings. The curable composition of the invention is a curable composition which comprises a vinyl polymer having a reactive silicon containing group (a), such as a (meth) acrylic polymer having a reactive silicon containing group, a polyoxyalkylene polymer having a reactive silicon containing group (b), such as a polyoxypropylene having a reactive silicon containing group, and a plasticizer having an acrylic component (c), such as an acrylic polymer, and is reacted and crosslinked in the presence of moisture to provide a rubbery cured product.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: November 20, 2007
    Assignee: Kaneka Corporation
    Inventors: Yuka Kanamori, Junji Takase
  • Publication number: 20070249787
    Abstract: The invention relates to an elastomeric product which contains a radical cross-linked rubber mixture, especially drive belts. For the production of elastomeric products, especially drive belts, having a long service life and producible in an environmentally friendly way, the rubber mixture contains (a) 0.1 to 50 phr of at least one carboxylic acid, which is at least ?,? unsaturated and ?,? unsaturated and preferably has at least one allylic hydrogen atom; and, (b) 0.1 to 50 phr of at least one salt-former as co-activator.
    Type: Application
    Filed: July 14, 2006
    Publication date: October 25, 2007
    Inventors: Karl-Friedrich Grussel, Reinhard Teves, Michael Well
  • Patent number: 7268193
    Abstract: Branched polyarylene polymers are provided comprising monovalent endcappers, divalent linear units, and polyvalent branching units. The composition of the polymers is controlled by adjusting the ratio of the three types of monomers.
    Type: Grant
    Filed: March 4, 2005
    Date of Patent: September 11, 2007
    Assignee: Mississippi Polymer Technologies, Inc.
    Inventors: Matthew L. Marrocco, III, Mark S. Trimmer, Ying Wang
  • Publication number: 20070197731
    Abstract: A process for producing a thermoplastic resin composition comprising the steps of (1) reacting with one another, at least, 0.1 to 100% by weight of an amorphous olefin copolymer resin (a1), 0 to 99.9% by weight of a crystalline polyolefin resin (a2), 0.01 to 20 parts by weight of a compound (b) containing at least one kind of an unsaturated group (b1) and at least one kind of a polar group (b2), and 0.001 to 20 parts by weight of an organic peroxide (c), thereby producing a modified polyolefin resin (A), and (2) blending 1 to 99% by weight of said modified polyolefin resin (A) with 1 to 99% by weight of a crystalline thermoplastic resin (B).
    Type: Application
    Filed: February 16, 2007
    Publication date: August 23, 2007
    Inventor: Shinichi Kondo
  • Publication number: 20070185268
    Abstract: Terminally-functional low molecular weight alkoxylated polybutadiene (meth)acrylates are used to improve the physical properties of elastomeric compositions cured in the presence of at least one free-radical generating compound selected from peroxides, percarbonates or azo compounds. The elastomers are natural or synthetic, or mixtures thereof. Reinforcing fillers may also be present. Preferred alkoxylated polybutadiene (meth)acrylates are of Formula I wherein R is H, Me, Et or C6H5; R? is H or Me; R? is H or Me; n=1 to 100; and Z=1 to 3.
    Type: Application
    Filed: February 9, 2007
    Publication date: August 9, 2007
    Applicant: SARTOMER TECHNOLOGY COMPANY, INC.
    Inventors: Steven K. Henning, Jeffrey Klang, Richard Costin
  • Publication number: 20070161750
    Abstract: The present invention provides a golf ball with excellent abrasion-resistance, durability and resilience having an ionomer resin cover therein. The ionomer composition for the golf ball of the invention comprises a reaction product obtained by reacting a telechelic copolymer having functional groups introduced in both terminals of a binary copolymer formed by copolymerizing an olefin monomer having 2 to 8 carbon atoms and an unsaturated carboxylic acid having 2 to 18 carbon atoms, and/or a ternary copolymer formed by copolymerizing an olefin monomer having 2 to 8 carbon atoms, an unsaturated carboxylic acid having 2 to 18 carbon atoms and an unsaturated carboxylic acid ester with a hydroxyl group-containing compound or an isocyanate group-containing compound, wherein at least 10 mole % of a carboxylic group in said reaction product is neutralized with an inorganic metal.
    Type: Application
    Filed: January 9, 2007
    Publication date: July 12, 2007
    Inventors: Satoko Okabe, Takashi Sasaki, Toshiyuki Tarao
  • Patent number: 7235609
    Abstract: A thermoplastic olefin (TPO) composition comprises (1) a major amount by weight of (a) a substantially linear homopolymer or copolymer of a C2–C10 ?-olefin in major proportion to (b) a long chain branched a linear homopolymer or copolymer of a C2–C10 ?-olefin, (2) a minor amount by weight of a cross linkable elastomer, and (3) at least one thermally decomposing free radical generating agent present in an amount sufficient to promote an increase in melt strength of the composition over that of the melt strength of the linear homopolymer or copolymer of a C2–C10 ?-olefin alone and insufficient to substantially degrade the ?-olefinic polymers. The TPO composition is prepared by melt blending the components at a temperature sufficient to melt said homopolymers or copolymers of a C2–C10 ?-olefin and thermally decompose said agent. Articles are thermoformed from the thermoplastic olefin.
    Type: Grant
    Filed: January 14, 2004
    Date of Patent: June 26, 2007
    Inventors: Amitkumar Dharia, Jerry Wayne Rodrigue
  • Patent number: 7235606
    Abstract: Disclosed is a glass-filled coupled impact propylene copolymer composition having an improved combination of strength, stiffness, impact properties and melt strength; articles made therefrom; and a process to prepare said articles.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: June 26, 2007
    Assignee: Dow Global Technologies Inc.
    Inventors: Lana S. Spencer, Michael Plaver, Sam Crabtree
  • Patent number: 7217765
    Abstract: A composite composition is disclosed that comprises the reaction product of a mixture of a styrenic polymer, as defined herein, a polar component having nucleophilic functional groups, and from 0.5 to 10 wt % of a compatibilizer having the formula: Ry(I)-(styrene)n-[(styrene)m(X)]p—I(Ry) wherein: R is the residue of a nitroxide used to regulate the polymerization of the compatibilizer; I is the residue of a radical initiator used to initiate polymerization of the compatibilizer; n is an integer from 50 to 750; m is an integer from 0 to 10; p is an integer from 1 to 50; and y is an integer from 0 to 1; and X is any polymerized monomeric moiety having at least one functional group capable of reacting with the nucleophilic functional groups present in the polar component of the composite at the temperature at which the composite components are mixed.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: May 15, 2007
    Assignee: Crompton Corporation
    Inventors: Sung Chul Hong, Qinggao Ma, Paul Edwin Stott, John M. Wefer, Leigh Cameron Allen
  • Patent number: 7217768
    Abstract: A paintable impact copolymer composition is produced by in-reactor blending of a xylene insoluble polypropylene fraction and a xylene soluble ethylene-propylene rubber (EPR) fraction. The composition comprises from about 5 wt. % to about 50 wt. % a xylene-soluble portion and from about 50 wt. % to about 95 wt. % a xylene-insoluble portion. The ratio of the weight average molecular weight of said xylene-soluble portion to that of said xylene-insoluble portion is from about 0.5 to about 1.8. The intrinsic viscosity of said xylene-soluble portion is from about 0.5 to about 7.0 dL/g. The xylene-soluble portion comprises from about 30 to about 70 mole percent ethylene units.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: May 15, 2007
    Assignee: Sunoco, Inc. (R&M)
    Inventors: Jeff S. Salek, Kimberly M. McLoughlin, Dan Rosenthal, Andrew Schnitgen
  • Patent number: 7211629
    Abstract: The present invention relates to the reduction of oligomer content of melt-processible fluoropolymer so that the fluoropolymer has at least 25 ppm less oligomer than the as-polymerized fluoropolymer, the reduction being obtained by melting the fluoropolymer forming a surface of molten fluoropolymer and regenerating this surface, contacting the regenerating surface with inert gas, and devolatilizing the resultant molten fluoropolymer.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: May 1, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Gregory Allen Chapman, David E. Bidstrup
  • Patent number: 7201969
    Abstract: A surface protecting adhesive film for a semiconductor wafer in which an adhesive layer is formed on one surface of a base film, wherein the adhesive layer comprises 100 weight parts of a polymer (A) having a functional group capable of reacting with a cross-linking agent and a temperature in a range of from ?50° C. to 5° C. at which tan ? of a dynamic viscoelasticity is maximized, from 10 weight parts to 100 weight parts of a polymer (B) having a functional group capable of reacting with a cross-linking agent and a temperature in a range of from more than 5° C. to 50° C. at which tan ? of a dynamic viscoelasticity is maximized, and from 0.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: April 10, 2007
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masafumi Miyakawa, Makoto Kataoka, Jun Nakashima, Yoshihisa Saimoto, Shinichi Hayakawa, Yasuhisa Fujii
  • Patent number: 7193018
    Abstract: A polymeric laminate comprising (A) a substrate, and (B) a slip layer covering at least a portion of said substrate, where the slip layer consists essentially of (i) a polyethylene blend, where said blend includes (a) from about 3 to about 97 percent by weight, based upon the total weight of said blend, of a first polyethylene resin having a weight average molecular weight from 110,000 to about 140,000 and a polydispersity of less than about 12, (b) from about 3 to about 97 percent by weight, based upon the total weight of said blend, of a second polyethylene resin having a weight average molecular weight from 50,000 up to 109,999 and a polydispersity of less than about 12, and (c) from about 0 to about 40 percent by weight, based upon the total weight of said blend, of a third polyethylene resin having a weight average molecular weight from about 20,000 up to 49,999 and polydispersity of less than about 12, with the proviso that said blend includes at least 60 percent, based upon the total weight of said ble
    Type: Grant
    Filed: September 15, 2004
    Date of Patent: March 20, 2007
    Assignee: Advanced Elastomer Systems, Lp.
    Inventors: Sunny Jacob, Marvin C. Hill
  • Patent number: 7169849
    Abstract: A process for production of a thermoplastic elastomer composition by melt-kneading a mixture in one step to thereby conduct dynamic crosslinking, wherein the mixture comprises a hydrogenated block copolymer (a1) which is prepared by hydrogenating a block copolymer comprising a vinyl aromatic polymer block (A1) and a conjugated diene polymer block (B1) and has number-average molecular weight of 200000 or above and, if necessary, a non-hydrogenated block copolymer (a2) comprising a vinyl aromatic polymer block (A2) and a conjugated diene polymer block (B2), and contains a non-aromatic rubber softening agent (b), a peroxide-crosslinkable olefin resin (c) having a density of 0.94 g/cm3 or above, a peroxide-decomposable olefin resin (d), an organic peroxide (e), and a crosslinking aid (f), the amount of (b) being 50 to 250 parts by mass per 100 parts by mass of the sum of (a1) +(a2), the amount of (c) being 2.5 to 50 parts by mass per 100 parts by mass of (a); and the amount of (d) being 0.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: January 30, 2007
    Assignee: Kuraray Co., Ltd.
    Inventors: Masaki Ikuji, Koichi Wada, Masanari Uno
  • Patent number: 7153908
    Abstract: A process involves adding a peroxide masterbatch to a molten blend of a fluorocarbon elastomer and a thermoplastic material. The peroxide masterbatch contains greater than or equal to 5% weight percent organic peroxide, further contains a fluorocarbon elastomer, and typically also contains a crosslinker containing at least two sites of olefinic unsaturation. The fluorocarbon elastomer in the molten blend and in the peroxide masterbatch may be the same or different. After the peroxide masterbatch is added to the molten blend, the combination is mixed at a temperature and for a time sufficient to effect cure of the fluorocarbon elastomers. By using a masterbatch, a faster and more uniform dispersion of peroxide curative is possible due to pre-dispersion of peroxide in the elastomer phase, which leads to shaped articles having improved mechanical properties.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: December 26, 2006
    Assignee: Freudenberg-NOK General Partnership
    Inventor: Edward Hosung Park
  • Patent number: 7148279
    Abstract: A golf ball a core and a cover, wherein at least one of the core or the cover includes a blend of a highly neutralized ionomer formed from a reaction between an ionomer having acid groups, a suitable cation source, and a salt of an organic acid, the cation source being present in an amount sufficient to neutralized the acid by 80% or greater; and a crosslinked or vulcanized diene rubber.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: December 12, 2006
    Assignee: Acushnet Company
    Inventors: Peter R. Voorheis, Michael J. Sullivan, Derek A. Ladd, Murali Rajagopalan
  • Patent number: 7126056
    Abstract: The present invention relates to a partially-crystalline copolymer comprising tetrafluoroethylene, hexafluoropropylene in an amount corresponding to HFPI of from about 2.8 to 5.3, and preferably from about 0.2% to 3% by weight of perfluoro(alkyl vinyl ether), said copolymer being polymerized and isolated in the absence of added alkali metal salts, having a melt flow rate of within the range of about 30±3 g/10 min, and having no more than about 50 unstable endgroups/106 carbon atoms can be extruded at high speed onto conductor over a broad polymer melt temperature range to give insulated wire of high quality.
    Type: Grant
    Filed: September 10, 2004
    Date of Patent: October 24, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Thomas Robert Earnest, Jr., Daniel A. Favereau, Niall D. McKee, Patricia A. Tooley
  • Patent number: 7122609
    Abstract: The present invention relates to a partially-crystalline copolymer comprising tetrafluoroethylene, hexafluoropropylene in an amount corresponding to a hexafluoropropylene index (HFPI) of from about 2.8 to 5.3, and preferably from about 0.2% to 3% by weight of perfluoro(alkyl vinyl ether), said copolymer being polymerized and isolated in the absence of added alkali metal salts, having a melt flow rate of within the range of about 30±3 g/10 min, and having no more than about 50 unstable endgroups/106 carbon atoms can be extruded at high speed onto conductor over a broad polymer melt temperature range to give insulated wire of high quality.
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: October 17, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Thomas Robert Earnest, Jr., Daniel A. Favereau, Niall D. McKee, Patricia A. Tooley
  • Patent number: 7105600
    Abstract: A polymer composition obtainable by subjecting a particular crosslinkable polymer composition to dynamic crosslinking. The crosslinkable polymer composition contains. (a) a block copolymer comprising two or more polymer blocks of a vinyl aromatic compound and one or more (hydrogenated) polymer blocks of a conjugated diene; (b) an olefin copolymer having a density of 0.88 to 0.92 g/cm2 and obtained through copolymerization of ethylene and an ?-olefin having 4 to 12 carbon atoms; (c) a softening agent; and (d) an organic peroxide in respective amounts that satisfy the following relational expressions {circle around (1)} to {circle around (3)}: 0.66?Wb/Wa?4{circle around (1)} 0?Wc/(Wa+Wb+Wc)?0.25{circle around (2)} 0.001?Wd/(Wa+Wb+Wc)?0.01{circle around (3)} wherein Wa, Wb, Wc and Wd represent the respective amounts (by mass) of the components (a), (b), (c) and (d), that are present in the polymer composition prior to the dynamic crosslinking.
    Type: Grant
    Filed: August 7, 2001
    Date of Patent: September 12, 2006
    Assignee: Kuraray Co., Ltd.
    Inventors: Hajime Kitano, Koichi Wada, Masanari Uno
  • Patent number: 7098270
    Abstract: A fluoroelastomer composition contains a peroxide-curable solid fluoroelastomer and a peroxide curative agent combined therewith, and, a bisphenol-curable liquid fluoroelastomer and a bisphenol curative agent combined therewith. The solid fluoroelastomer/peroxide curative when combined with the liquid fluoroelastomer/bisphenol curative results in a composition exhibiting improved polymeric properties including improved flowability at room temperature and improved fluid resistance and sealability at a wide range of temperatures.
    Type: Grant
    Filed: September 10, 2002
    Date of Patent: August 29, 2006
    Assignee: Freudenberg-NOK General Partnership
    Inventors: Paul J. Hochgesang, James W. Jacks
  • Patent number: 7094836
    Abstract: A compatibilizer including a first portion compatible with a fluoropolymer and a second portion compatible with a polyolefin. Compatibilized compositions comprising a polyolefin, a fluoropolymer, and a compatibilizer are also disclosed. Methods for forming both the compatibilizer and the blends contained in the compatibilizer are described. The compatibilized compositions of the present invention exhibit desired mechanical properties such as tensile strength and elongation. The flame retarded compatibilized blends exhibit desirable dielectric properties, are flame resistant and exhibit low smoke emission.
    Type: Grant
    Filed: March 4, 2004
    Date of Patent: August 22, 2006
    Assignee: Teknor Apex Company
    Inventors: Raman Patel, Biing-Lin Lee, John C. Andries, Maryellen Cox
  • Patent number: 7064171
    Abstract: The present invention reveals a tire having a tread that is comprised of (1) 30 phr to 80 phr of a non-random styrene-butadiene rubber comprised of polymer chains that are derived from styrene and 1,3-butadiene, wherein from about 10 weight percent to about 50 weight percent of the repeat units in the styrene-butadiene rubber are derived from styrene, wherein from about 60 weight percent to about 90 weight percent of the repeat units in the styrene-butadiene rubber are derived from 1,3-butadiene, wherein from about 30 weight percent to about 50 weight percent of the styrene repeat units are in sequences containing 5 to 20 styrene repeat units, wherein the bound styrene content found in the first half of the polymer chains differs from the bound styrene content found in the second half of the polymer chains by at least 5 weight percent, wherein the styrene-butadiene rubber has a 1,2-vinyl content which is within the range of about 8 percent to about 20 percent, wherein the styrene-butadiene rubber has a number
    Type: Grant
    Filed: September 22, 2005
    Date of Patent: June 20, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Wen-Liang Hsu, David Michael Smith, Sr., Warren James Busch, John Joseph Andre Verthe, Scott Edwards Johnson
  • Patent number: 7053155
    Abstract: A vibration damping rubber composition capable of exhibiting an excellent vibration damping property comprising: (A) a diene rubber; (B) a bismaleimide compound represented by the following general formula (1); wherein n denotes an integer of 4 to 12; and (C) a vulcanization accelerator; wherein said rubber composition does not contain elemental sulfur as a raw material for a vulcanizing agent.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: May 30, 2006
    Assignee: Tokai Rubber Industries, Ltd.
    Inventors: Norihito Kimura, Fumihiko Jinno, Takehiko Taguchi
  • Patent number: 7041740
    Abstract: Heat-settable epoxy resin mixtures are provided that can be used alone or in combination with fibers to form large composite material structures without the need for high consolidation pressures. The heat-settable resin mixture is composed of a resin component, curing agent component and a particulate component. The particulate component includes rigid-rod polymer particles that dissolve when the heat-settable resin is heated to temperatures within a predetermined processing window. After heating to the processing temperature, the resulting heat-set resin is cooled to form a curable solid resin. The curable solid resin may be stored indefinitely or re-heated to curing temperatures to form a cured product.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: May 9, 2006
    Assignee: Hexcel Corporation
    Inventor: Cary J. Martin
  • Patent number: 7034077
    Abstract: The invention relates to a foil or molded body based on a transparent and high frequency weldable polymer mixture containing a) (I) a copolymer of ethylene with about 8 to 60% by weight of comonomers, selected from vinyl esters of saturated C2–C8 carboxylic acids saturated C1–C12 alkylacrylates and methacrylates, optionally with carbon monoxide as termonomer, and/or (II) ethylene homopolymer, ethylene copolymer, propylene homopolymer and/or propylene copolymer with about 8 to 60% by weight of grafted units of unsaturated carboxylic acids, dicarboxylic acids, their esters and/or anhydrides or (III) a mixture of two or more of the above mentioned compounds, independently of their allocation to groups, whereby the polymers or their mixture have a melt index MFI (190° C.; 2.16 kg) of about 0.2 to 15.0 g/10 min and b) a copolymer of ethylene with about 10 to 30% by weight of C3–C12–?-olefin with a melt index MFI (190° C., 2.16 kg) of about 0.2 to 15.
    Type: Grant
    Filed: September 2, 2003
    Date of Patent: April 25, 2006
    Assignee: Benecke-Kaliko AG
    Inventor: Jürgen Bühring