Agent Is An Organic Material Patents (Class 525/194)
  • Patent number: 6933344
    Abstract: Thermoplastic elastomeric compositions and processes for preparing the compositions comprising a blend of polypropylene, styrene-ethylene butylene-styrene copolymer, ethylene-propylene-diene monomer elastomer, linear low density polyethylene, peroxide crosslinking agent and a crosslinking coagent. The peroxide crosslinking agent and crosslinking coagent provide a crosslinking system. The compositions improve melt strength and increase resistance to flow and tear. The composition may further comprise mineral oil, antioxidant, colorant, a processing aid and stabilizer and mixtures thereof. The processes for preparing thermoplastic elastomeric compositions are particularly useful in microcellular injection molding to form articles with improved surface characteristics.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: August 23, 2005
    Assignee: Delphi Technologies, Inc.
    Inventors: Suresh Deepchand Shah, Michael William Jary, Ismat Ali Abu-Isa
  • Patent number: 6911497
    Abstract: A polypropylene resin composition having a melt flow rate of 70 to 120 g/10 min (at 230° C., 2.16 kgf-load), a flexural modulus of 1300 to 4000 MPa and an IZOD impact strength of 30 to 100 kJ/m2, wherein the composition is obtained by adding a small amount of an organic peroxide to a mixture comprising 60 to 80% by weight of a specific propylene-ethylene block copolymer made up of a propylene homopolymer portion and a propylene-ethylene random copolymer portion, a rubber which is a copolymer of ethylene and at least one ?-olefin having a melt flow rate of 2 to 10 g/10 min (at 190° C., 2.16 kgf-load), and inorganic filler (C), and kneading the combined ingredients at a temperature of 170 to 280° C.
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: June 28, 2005
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Jun Satoh, Hiroyuki Tanimura, Katsuyuki Imigi
  • Patent number: 6890992
    Abstract: The present invention is directed toward more durable golf ball cores and more durable golf balls. The golf balls of this invention comprise a cover and a core wherein the core may further comprise a center and one or more layers of a mantle disposed between the center and the cover. The core, the mantle or the layers of the mantle, comprise a mixture of one or more thermoset rubber materials and at least one compatible, modified, non-ionic polyolefin. The non-ionic polyolefin that is modified may be a homopolymer, copolymer, terpolymer, block copolymer or a mixture thereof that is present at about 0.5 to about 10 parts per hundred of the thermoset rubber material used in the core or core layer.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: May 10, 2005
    Assignee: Acushnet Company
    Inventor: Jeffrey L. Dalton
  • Patent number: 6890990
    Abstract: A thermoplastic elastomer with increased oil resistance and decreased compression set compared to conventionally cured thermoplastic elastomers may be made from a dynamically vulcanized blend of propylene resin and ethylene/alpha-olefin/non-conjugated diene elastomers via a curing system containing a free radical initiator, a first co-agent including diene-containing polymers with a 1,2-vinyl content greater than 50% by weight, and a second co-agent including multifunctional acrylates containing at least two acrylate groups, multifunctional maleimides containing at least two imide groups, or mixtures of both, where the elastomer gel content in the modified blend is at least 97%.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: May 10, 2005
    Assignee: Solvay Engineered Polymers, Inc.
    Inventors: Kevin Cai, Howard Colvin, Charles G. Reid, Hoan Tran
  • Patent number: 6887940
    Abstract: A compatible blend of an engineering thermoplastic such as a polyamide and an olefin polymer material is prepared by (1) making an oxidized olefin polymer material containing carboxylic acid groups or derivatives thereof, (2) extruding a mixture of (a) the oxidized olefin polymer material from step (1), (b) an engineering thermoplastic, (c) optionally, an inorganic base, and (d) optionally, a non-oxidized olefin polymer material, and (3) recovering a blend of the engineering thermoplastic, the oxidized olefin polymer material or an ionomer thereof, which acts as a compatibilizer, and, optionally, the non-oxidized olefin polymer material. The oxidized olefin polymer material can be made by treating the olefin polymer material with an organic peroxide initiator while adding a controlled amount of oxygen.
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: May 3, 2005
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Vu A. Dang, Dinshong Dong, Tam T. M. Phan, Cheng Q. Song
  • Patent number: 6884839
    Abstract: Aqueous primary dispersions and coating materials comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core shell particles having a diameter?500 nm preparable by controlled free-radical microemulsion or miniemulsion polymerization of A) at least one olefinically unsaturated monomer and B) at least one olefinically unsaturated monomer which is different than the olefinically unsaturated monomer (A) and has the general formula I: R1R2C?CR3R4 (I), in which the radicals R1, R2, R3 and R4 independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; and in the presence of (C) at least one hydrophobic cross-linking agent for the
    Type: Grant
    Filed: November 8, 2000
    Date of Patent: April 26, 2005
    Assignee: BASF Coatings AG
    Inventors: Maximilian Bendix, Reinhold Clauss, Ralf Nickolaus, Wolfgang Bremser
  • Patent number: 6881791
    Abstract: A curable, water-based coating composition comprising a reaction product of: a copolymer comprising a free-radical polymerization product of: a first block comprising a reaction product of: a plurality of ethylenically unsaturated monomers, and a vinyl aromatic hydrocarbon monomer, wherein at least one monomer of the plurality of ethylenically unsaturated monomers includes a functional group that can react with a water-dispersible cross-linking agent, and at least one monomer of the plurality of ethylenically unsaturated monomers is present in an amount such that it can render the copolymer water dispersible, and a second block comprising a reaction product of at least one ethylenically unsaturated monomer, wherein at least a portion of which are non-functional, and a water-dispersible cross-linking agent, wherein the water-based copolymer is free of salt structures.
    Type: Grant
    Filed: June 5, 2003
    Date of Patent: April 19, 2005
    Assignee: BASF Corporation
    Inventors: Swaminathan Ramesh, Paul Harris, Wolfgang Bremser, Walter H. Ohrbom
  • Patent number: 6875815
    Abstract: Disclosed is a thermosetting powder coating composition comprising (A) a glycidyl group-containing acrylic resin obtained by (co)polymerizing monomers containing an ethylenically unsaturated monomer having a glycidyl group and/or a ?-methylglycidyl group, (B) a polycarboxyl curative, and (C) an alcohol adduct of a styrene/maleic anhydride copolymer. Also disclosed are a cross-linked cured film of the composition and a process for preparing the composition. According to the invention, blending efficiency and dispersibility of the components of a powder coating, particularly those between the resin component and the curative component, are improved without changing a conventional production process of a powder coating, i.e., a process consisting of melt blending, cooling solidification, pulverization and sieving, and thereby a thermosetting powder coating composition, which is capable of forming a cross-linked cured film improved in appearance properties (high gloss, etc.
    Type: Grant
    Filed: May 28, 2003
    Date of Patent: April 5, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Mitsuyuki Mizoguchi, Yoshiharu Hirose
  • Patent number: 6864321
    Abstract: Compositions comprising (A) non-branched polybutadiene having terminal hydroxyl functionality less than 2 per molecule by average; and (B) branched polybutadiene having terminal hydroxyl functionality more than 2 per molecule by average; the weight ratio of (A) to (B) being about 99:1 to 1:99. These compositions are reacted with organic polyisocyanates to form prepolymers which are cured by reaction with a chain extender such as a diol to produce cured resins which exhibit unexpectedly improved tear strength properties and themoplasticity with high modulus, and improved tackiness and shelf life for hot melt adhesives. The prepolymers have lower viscosity and better storage stability as compared with those from conventional branched polybutadienes of the (B) type. Alternatively, the compositions can be cured directly in a one-shot reaction with diisocyanates to form a polyurethane with the described combination of properties.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: March 8, 2005
    Assignee: Sartomer Technology Co., Inc.
    Inventors: Herbert Chao, Nan Tian, Alain Drexler, John Schmidhauser
  • Patent number: 6861481
    Abstract: An ionomeric nanocomposite that includes a base component of a propylene-based polyolefin-metal salt component and a nanostructured material. Optionally, the blend further contains a polymeric component including an ethylene ionomer, a styrenic block ionomer, a hydrogenated styrene-butadiene random copolymer, or a combination thereof. Such ionomeric nanocomposites have increased scratch and mar resistance while still retaining clarity and thermal stability. Methods of preparing such blends, as well as resultant articles including such blends, are also part of the invention.
    Type: Grant
    Filed: June 11, 2003
    Date of Patent: March 1, 2005
    Assignee: Solvay Engineered Polymers, Inc.
    Inventors: Rui-dong Ding, Clint Newell
  • Patent number: 6855769
    Abstract: The present invention relates to a thermoplastic styrenic resin composition comprises a styrenic copolymer comprising 15-100 parts by weight of a unit derived from a styrenic monomer (i-1), 0-45 parts by weight of a unit derived from a vinyl cyanide monomer (i-2), 0-40 parts by weight of a unit derived from a copolymerizable vinyl monomer (i-3) other than the above monomers, and 0.0005-1.0 parts by weight of a unit derived from a polyfunctional maleimide monomer, all based on 100 parts by weight of the total amount of (i-1) to (i-3). The thermoplastic styrenic resin composition manufactured in the present invention is excellent in processability. The rubber modified thermoplastic styrenic resin composition of the present invention gives a good heat stability, impact strength, fluidity and other mechanical properties. In addition, it also gives a uniform wall thickness, and the gloss on the surface of injected products after painting process is excellent.
    Type: Grant
    Filed: November 7, 2003
    Date of Patent: February 15, 2005
    Assignee: Chi Mei Corporation
    Inventor: Wen-Yi Su
  • Patent number: 6838520
    Abstract: Adhesives useful for adhering fluoropolymers are provided. The adhesives are a blend of linear low density polyethylene, ethylene polymer plastomer, polyolefin elastomer and modified polyolefin having acid or acid derivative functionality. Composite fluoropolymer/adhesive structures are also provided.
    Type: Grant
    Filed: May 29, 2003
    Date of Patent: January 4, 2005
    Assignee: Equistar Chemicals, LP
    Inventor: Bradley P. Etherton
  • Patent number: 6835269
    Abstract: A laminated film exhibiting excellent interlayer adhesiveness obtained by extrusion-laminating a resin directly on a polyester film without effecting anchor-coating or without treating the molten film of the extrusion-laminated resin with ozone. The laminated film is obtained by extrusion-laminating, onto the polyester film, an ethylene copolymer containing an unsaturated carboxylic acid and a (meth)acrylic acid ester, which may be further blended with a small amount of an ethylene/&agr;-olefin copolymer having a density of 840 to 900 kg/m3, the amount of the unsaturated carboxylic acid component being from 1 to 12% by weight and the amount of the (meth)acrylic acid ester component being from 2 to 25% by weight.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: December 28, 2004
    Assignee: DuPont-Mitsui Polychemicals Co., Ltd.
    Inventors: Kenji Miharu, Naozumi Suzuki
  • Publication number: 20040236030
    Abstract: An ionomer modified by an amine-functionalized chemical for use in sporting equipment. The ionomer modified by an amine-functionalized chemical facilitates high COR, compression, durability, and ease of processing.
    Type: Application
    Filed: May 12, 2004
    Publication date: November 25, 2004
    Applicant: Taylor Made Golf Company, Inc.
    Inventors: Hyun Jin Kim, Hong Guk Jeon
  • Patent number: 6803437
    Abstract: A process for producing a tetrafluoroethylene polymer, which comprises polymerizing tetrafluoroethylene in an aqueous medium in the presence of a water-soluble initiator, wherein the water used for the polymerization is regulated to have a TOC of 100 ppb or lower and/or an electrical conductivity of 1.0 &mgr;S/cm or lower. When this process for producing a tetrafluoroethylene polymer is employed, a decrease or fluctuation in the polymerization rate during the polymerization of tetrafluoroethylene will be minimal, and a deterioration in the physical properties of the obtained tetrafluoroethylene polymer will be minimal.
    Type: Grant
    Filed: December 10, 2002
    Date of Patent: October 12, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Shigeki Kobayashi, Jun Hoshikawa, Kazuo Kato, Hiroki Kamiya, Hiroyuki Hirai
  • Publication number: 20040198910
    Abstract: A sealant rubber composition which forms a spongy tacky sealant layer having moderate viscosity properties; and a pneumatic tire having in the tire main body a tacky sealant layer obtained by heating the rubber composition. The rubber composition comprises 0.2 to 20 parts by weight of a peroxide per 100 parts by weight of polymers comprising 95 to 50 parts by weight of a polymer decomposable with the peroxide and 5 to 50 parts by weight of a polymer crosslinkable with the peroxide.
    Type: Application
    Filed: February 11, 2004
    Publication date: October 7, 2004
    Inventors: Takashi Fukutomi, Takumi Sekiguchi, Issei Nakakita, Mitsuru Naito, Yuichi Kobayashi, Tetsuo Ikegami, Satoshi Makino, Takayuki Toyoshima, Tetsuya Mizone, Naoya Miyawaki
  • Patent number: 6797780
    Abstract: The invention relates to rubber compounds based on rubber particles and phosphoryl polysulfides, as well as to vulcanizates or shaped articles prepared therefrom. The addition of phosphoryl polysulfides improves the strengthening effect of the rubber particles and the level of the mechanical properties, without lowering the resilience of the vulcanizates prepared therefrom.
    Type: Grant
    Filed: October 29, 2001
    Date of Patent: September 28, 2004
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Werner Obrecht, Winfried Jeske, Thomas Früh, Ludger Heiliger
  • Patent number: 6797222
    Abstract: A slush molding process in which the moldable thermoplastic composition powder dosed to the mold is prepared by blending ethylene carboxylic acid copolymers or ionomers with ethylene/glycidyl acrylate or methacrylate copolymer and cross-linking promoter at a temperature and for a time that does not cause significant cross-linking prior to dosing to mold, which is held for sufficient time and temperature to cause cross-linking in-situ, and optionally, other additives including release agents.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: September 28, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Karlheinz Hausmann, George K. Kodokian, George W. Prejean
  • Patent number: 6797778
    Abstract: Use of modified olefin polymers for production of polyolefin products with improved toughness, strength and heat resistance. Polyolefin products with high requirements for toughness, strength and heat resistance, produced from modified olefin polymers based on modified propylene polymers which have been modified by reaction with bifunctional monomers in the presence of free-radical generators in the solid phase. The polyolefin products are particularly suitable for shock-absorbing components of motor vehicles, such as bumpers, spoilers and side edge protection elements.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: September 28, 2004
    Assignee: Borealis GmbH
    Inventors: Norbert Reichelt, Manfred Raetzsch, Gerald Rohaczek
  • Publication number: 20040176524
    Abstract: A process for production of a thermoplastic elastomer composition by melt-kneading a mixture in one step to thereby conduct dynamic crosslinking, wherein the mixture comprises a hydrogenated block copolymer (a1) which is prepared by hydrogenating a block copolymer comprising a vinyl aromatic polymer block (A1) and a conjugated diene polymer block (B1) and has number-average molecular weight of 200000 or above and, if necessary, a non-hydrogenated block copolymer (a2) comprising a vinyl aromatic polymer block (A2) and a conjugated diene polymer block (B2), and contains a non-aromatic rubber softening agent (b), a peroxide-crosslinkable olefin resin (c) having a density of 0.94 g/cm3 or above, a peroxide-decomposable olefin resin (d), an organic peroxide (e), and a crosslinking aid (f), the amount of (b) being 50 to 250 parts by mass per 100 parts by mass of the sum of (a1) +(a2), the amount of (c) being 2.5 to 50 parts by mass per 100 parts by mass of (a); and the amount of (d) being 0.
    Type: Application
    Filed: December 17, 2003
    Publication date: September 9, 2004
    Inventors: Masaki Ikuji, Koichi Wada, Masanari Uno
  • Publication number: 20040167278
    Abstract: Disclosed are a precursor composition, a rubber component and a shear ply prepared from the precursor composition, and methods for making and using the same. The precursor composition includes a first hydrogenated nitrile conjugated-diene copolymer modified by a metal salt unsaturated carboxylic acid ester, wherein the first hydrogenated nitrile conjugated-diene copolymer is derived from a first ethylenically unsaturated nitrile and a first conjugated diene a second hydrogenated nitrile conjugated-diene copolymer derived from a second ethylenically unsaturated nitrile and a second conjugated diene; and a curing agent.
    Type: Application
    Filed: February 19, 2004
    Publication date: August 26, 2004
    Inventors: Albert R. Harvey, John W. Ellertson
  • Patent number: 6777502
    Abstract: Coupled polymers are prepared by a process comprising heating an admixture containing (1) at least one polyolefin comprising ethylene and optionally at least one comonomer and (2) a coupling amount at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer; particularly where the polyolefin is the product of polymerization of ethylene and optionally at least one other alpha-olefin in the presence of a single site catalyst.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: August 17, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Thoi H. Ho, Wendy D. Hoenig, Che-l Kao, Michael E. Rowland, Clark H. Cummins, Michael J. Mullins, H. Craig Silvis
  • Patent number: 6774162
    Abstract: The invention relates to a thermoplastic vulcanizate comprising four components (A, B. C, D), notably: a thermoplastic (A); a substantially non-cross-linked polyethylene (B); an at least partially vulcanized rubber (C); a softener (D); as well as standard blend ingredients (E). The above mixture contains between 5 and 20% by weight thermoplastic (A), in relation to the sum of the four components (A, B, C, D). The invention also relates to advantageous material parameters and process steps.
    Type: Grant
    Filed: August 15, 2001
    Date of Patent: August 10, 2004
    Assignee: PolyOne Corporation
    Inventors: Jörg Vortkort, Friedrich Wilhelm Gräbner, Andre Bontemps, Stefan Volkmann
  • Patent number: 6774186
    Abstract: Rheology-modified thermoplastic elastomer compositions comprising a melt blend of an ethylene/&agr;-olefin polymer and a high melting polymer such as polypropylene or a propylene/&agr;-olefin copolymer wherein the rheology modification is induced by a combination of a peroxide and a free radical coagent. The resulting compositions have an elastomeric phase, a non-elastomeric phase and certain physical properties that exceed those of a like composition that is rheology-modified by peroxide alone. The compositions can be used to make a variety of articles of manufacture, such as automotive instrument panel skins, via calendaring and thermoforming procedures.
    Type: Grant
    Filed: February 10, 2003
    Date of Patent: August 10, 2004
    Assignee: DuPont Dow Elastomers LLC
    Inventor: Kim Louis Walton
  • Publication number: 20040147677
    Abstract: Thermoplastic vulcanizates, comprising blends of olefin rubber having a high Mooney Viscosity and thermoplastic olefin resin in which the rubber is completely cured by a phenolic curative, exhibit superior physical properties over other products.
    Type: Application
    Filed: December 5, 2003
    Publication date: July 29, 2004
    Inventors: Jonas Angus, Paul Brunelle
  • Patent number: 6762246
    Abstract: The present invention relates to compositions and preparative process of partially or fully neutralized mixtures of carboxylate functionalized ethylene high copolymers or terpolymers (Mw between 80,000 and 500,000) with carboxylate functionalized ethylene low copolymers (Mw between 2,000 and 30,000) and organic acid salts and injection or compression molded applications such as golf ball components thereof.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: July 13, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: John C. Chen
  • Patent number: 6750288
    Abstract: The present invention relates to an isotactic polypropylene obtained by metallocene catalysis, onto which is grafted a functional monomer. The invention also relates to a composition which may form part of the composition of a coextrusion binder. This composition according to the invention comprises isotactic polypropylene obtained by metallocene catalysis, grafted and then optionally diluted with at least one polyolefin (C1) and/or in at least one polymer of elastomeric nature (D). The invention also relates to a multilayer structure comprising a layer (L) comprising the above binder, and, directly attached thereto, a layer (E): which is polar, nitrogenous or oxygenated, such as a layer of polyamide resin, of ethylene/saponified vinyl acetate copolymer (EVOH) or of polyester; or of a mineral oxide deposited on a polymer such as polyethylene (PE), polyethylene terephthalate (PET) or EVOH; or which is metallic or metalloplastic.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: June 15, 2004
    Assignee: Atofina
    Inventor: Jean-Laurent Pradel
  • Publication number: 20040097654
    Abstract: The present invention is a composition and a method of forming a composition, the composition comprising at least a halogenated elastomer and an amine or phosphine. An additional rubber component may be present in the composition of the invention. In one embodiment, the halogenated elastomer is a isoolefin copolymer comprising a halomethylstyrene derived unit. The amine or phosphine compound is represented by the formula (R1R2R3)Q, wherein Q is a Group 15 element, and wherein R1 is either hydrogen or a C4 to C30 hydrocarbyl group, R2 is either hydrogen or a C1 to C30 hydrocarbyl group; and R3 is either hydrogen or a C1 to C30 hydrocarbyl group provided that at least one of R1, R2 and R3 is not hydrogen.
    Type: Application
    Filed: April 3, 2003
    Publication date: May 20, 2004
    Inventors: Hsien-Chang Wang, Ilan Duvdevani, Connie R Qian, Pawan K. Agarwal
  • Patent number: 6737479
    Abstract: A millable, vulcanizable elastomeric composition comprising two fluoroelastomer phases, phase 1 and phase 2, wherein fluoroelastomer phase 1 is present as crosslinked fluoroelastomer particles, and where fluoroelastomer phase 2 remains flowable until a final stage vulcanization occurs, and where fluoroelastomer phase 1 is present at between 5-85% by weight of the final composition.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: May 18, 2004
    Assignee: Immix Technologies, LLC
    Inventor: Roger Faulkner
  • Patent number: 6730722
    Abstract: The invention provides cross-linkable polymer powder compositions containing a) at least one water-soluble polyhydroxy compound; b) at least one boric acid complex compound which is of limited solubility in water that is, it has a water solubility of less than 10 g per liter at normal conditions; and optionally c) a water-soluble film-forming polymer consisting of one or more free-radical polymerizable, ethylenically unsaturated monomers. The compositions are useful as a constituent in adhesives, plaster, jointing mortars, paints and binders for coating compositions, textiles, paper and the like.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: May 4, 2004
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Eck, Hans Donislreiter
  • Patent number: 6723794
    Abstract: An olefin thermoplastic elastomer composition comprises a crystalline polyolefin resin (A) and an ethylene/&agr;-olefin/nonconjugated polyene copolymer rubber (B), and optionally a softener (C) and/or an inorganic filler (D), in a specific ratio. The copolymer rubber (B) is prepared by the use of a metallocene catalyst and comprises ethylene, an &agr;-olefin of 3 to 20 carbon atoms and a nonconjugated polyene. This composition ca provide molded products of more excellent tensile strength, elongation at break, elastomeric properties (elongation set, permanent compression set, etc.), heat resistance and low-temperature properties than the conventional non-crosslinked olefin thermoplastic elastomers, even if the composition is in the non-crosslinked form. The composition in the partially or completely crosslinked form can provided molded products of more excellent low-temperature properties, tensile strength, elongation at break and elastomeric properties than the conventional vulcanized rubbers.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: April 20, 2004
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masaaki Kawasaki, Keiji Okada, Tetsuo Tojo, Kyoko Kobayashi, Yuichi Itoh, Akira Uchiyama, Toshiyuki Tsutsui, Toshihiro Sagane
  • Patent number: 6713520
    Abstract: A foam profile prepared by a process comprising the steps of foaming a thermoplastic vulcanizate, where the thermoplastic vulcanizate is prepared by a process comprising the step of dynamically vulcanizing a rubber within a mixture that includes from about 15 to about 95 percent by weight of the rubber and from about 5 to about 85 percent by weight of a thermoplastic component based upon the total weight the rubber and thermoplastic component combined, where the thermoplastic component includes from about 65 to about 90 percent by weight of a conventional thermoplastic resin and from about 10 to about 35 percent by weight of a random propylene copolymer based upon the total weight of the thermoplastic component.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: March 30, 2004
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Abdelhadi Sahnoune, Terry M. Finerman
  • Patent number: 6706816
    Abstract: The present invention is directed to methods of making natural or synthetic latex articles without the use of accelerators, thiurams or carbamates. The method includes making an elastomeric material by mixing a base polymer containing carboxylate groups with a carboxylic acid or derivative thereof, a divalent or trivalent metal, an amine or amino compound, and a neutralizing agent. The elastomeric material is formed into a latex article. The present invention is also directed to a latex article made according to this method. The latex article does not contain any accelerators, thiurams or carbamates.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: March 16, 2004
    Assignee: Best Manufacturing Company
    Inventors: William Andrus Williams, Joyce Lee Cleveland
  • Patent number: 6706818
    Abstract: This invention provides a curable resin composition for one-pack type water-based paint which is readily cured regardless of coating environment, said resin composition comprising copolymer (I) which is produced by the copolymerization of unsaturated group-containing urethane prepolymer (A) which is obtained from a reaction of diisocyanate compound (a), glycol compound (b), carboxyl group-containing glycol compound (c) and hydroxyl group-containing ethylenically unsaturated monomer (d), with maleimide group-containing ethylenically unsaturated monomer (e), carbonyl group-containing ethylenically unsaturated monomer (f) and another ethylenically unsaturated monomer (g), and compound (II) which has, per molecule, two or more same or different functional groups selected from hydrazide group, semicarbazide group and hydrazone group
    Type: Grant
    Filed: May 30, 2002
    Date of Patent: March 16, 2004
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Yushichi Ishihara, Masami Sugishima, Nobushige Numa, Mitsutaka Hasegawa, Hiroshi Inukai
  • Patent number: 6699943
    Abstract: The present invention is directed to a curable, water-based coating composition utilized in waterborne coating systems. The coating composition is the reaction product of a water-based copolymer prepared by free-radical polymerization, and a cross-linking agent. The copolymer is the reaction product of a first block and a second block. The first block is the reaction product of a first ethylenically unsaturated monomer, acrylic acid, and a second ethylenically unsaturated monomer, methyl methacrylate, as well as the reaction product of a vinylaromatic hydrocarbon monomer, diphenylethylene. The second block is the reaction product of a plurality of ethylenically unsaturated monomers, styrene, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, and carbonate-modified glycidyl methacrylate including a carbonate functional group that is subsequently converted into a carbamate functional group by ammonium hydroxide.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: March 2, 2004
    Assignee: BASF Corporation
    Inventors: Swaminathan Ramesh, Paul Lessek, Wolfgang Bremser
  • Patent number: 6673446
    Abstract: A fiber composition which comprises a blend of modified polypropylene and modified poly(ethylene oxide). This fiber composition can be melt-processed to make fibers useful in flushable personal care products. A process for making this fiber composition is also provided.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: January 6, 2004
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James H. Wang, David M. Schertz
  • Patent number: 6657014
    Abstract: A crosslinkable rubber composition comprising (a) 100 weight parts of a nitrile group-containing highly saturated copolymer rubber containing units of an ethlenically unsaturated dicarboxylic acid monoalkyl ester monomer, (b) 0.5 to 10 parts by weight of a polyamine crosslinking agent, and (c) 0.5 to 10 parts by weight of a basic crosslinking accelerator. This rubber composition gives a crosslinked nitrile group-containing highly saturated copolymer rubber article having excellent heat resistance, flex fatigue resistance and elongation, and reduced permanent set.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: December 2, 2003
    Assignee: Zeon Corporation
    Inventors: Osamu Mori, Takafumi Kawanaka, Yoshiaki Aimura, Hiroyuki Kotsuji, Haruhiko Fujita
  • Publication number: 20030220431
    Abstract: New anti-reflective or fill compositions having improved flow properties are provided. The compositions comprise a styrene-allyl alcohol polymer and preferably at least one other polymer (e.g., cellulosic polymers) in addition to the styrene-allyl alcohol polymer. The inventive compositions can be used to protect contact or via holes from degradation during subsequent etching in the dual damascene process. The inventive compositions can also be applied to substrates (e.g., silicon wafers) to form anti-reflective coating layers having high etch rates which minimize or prevent reflection during subsequent photoresist exposure and developing.
    Type: Application
    Filed: May 23, 2002
    Publication date: November 27, 2003
    Inventors: Gu Xu, Jimmy D. Meador, Mandar R. Bhave, Shreeram V. Deshpande, Kelley A. Nowak
  • Patent number: 6652796
    Abstract: In manufacturing glass fiber-reinforced resin moldings a peroxide is mixed into a molding material prepared by mixing glass fibers with a thermoplastic resin, and such a molding material is molded. The peroxide is fed together with the molding material in an injection molding machine, the molding material is heated and kneaded in the molding machine, and the glass fiber mixed molten resin is injected into a mold to obtain a molded body.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: November 25, 2003
    Assignee: Kishimoto Sangyu Co Ltd
    Inventors: Takeshi Moriwaki, Toshiharu Sakaguchi
  • Patent number: 6649267
    Abstract: A thermosetting powder coating composition has an average particle diameter of entire particles is within a range from 5 to 50 &mgr;m, an average circularity of the particles is 0.90 or more, and a circularity of particles having a maximum number frequency in circularity distribution is within a range from 0.98 to 1.00, prepared by spray-drying an organic solvent solution containing, as a coating film forming component, an epoxy group-containing vinyl copolymer (A) having a glass transition temperature of 40° C. or higher, an epoxy group-containing vinyl copolymer (B) having a glass transition temperature of 0° C. or lower and a polycarboxylic acid (C) as an essential component.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: November 18, 2003
    Assignees: Dainippon Ink and Chemicals, Inc., Liquid Gas Co., Ltd.
    Inventors: Tetsuro Agawa, Katsuhiko Okada, Hiroo Tanaka, Masaya Hashimoto, Takaaki Asakura
  • Patent number: 6639022
    Abstract: A process for the preparation of superabsorbent polymers by alkaline hydrolysis of polyacrylonitrile emulsions is disclosed. In an embodiment of the invention the process comprise preparing a PAN emulsion, subjecting the emulsion to alkaline hydrolysis, neutralizing the hydrolysate followed by drying, granulation and modifying the surface of the granular polymer by crosslinking. The process is characterized in that the isolation of the superabsorbent polymer entails neither alcohols nor organic solvents.
    Type: Grant
    Filed: April 16, 2001
    Date of Patent: October 28, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gisbert Michels, Thomas Gross
  • Publication number: 20030195298
    Abstract: A process for polymerizing polycycloolefins containing pendant anhydride moieties is disclosed. The process utilizes a single component nickel containing catalyst of the formula EnNi(C6F5)2 wherein n is 1 or 2 and E represents a neutral electron donor ligand.
    Type: Application
    Filed: February 27, 2003
    Publication date: October 16, 2003
    Applicant: Sumitomo Bakelite Co., Ltd.
    Inventors: Saikumar Jayaraman, Brian L. Goodall, Richard Vicari, John-Henry Lipian
  • Patent number: 6632888
    Abstract: The invention relates to rubber mixtures which contain microgels and isocyanatosilanes and vulcanisates produced therefrom. By adding isocyanatosilanes the mechanical properties of the vulcanisates, in particular the elongation properties and the abrasion resistance, are improved without the difference in rebound resilience at 70° C. and 23° C. being reduced.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: October 14, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Obrecht, Martin Mezger, Anthony Sumner
  • Patent number: 6630538
    Abstract: Thermoplastic elastomer compositions having improved processabillity while maintaining good physical properties are prepared from a mixture of olefinic rubber and a polypropylene composition having a melt flow rate in the range of from about 0.5 to about 5 dg/min. and a molecular weight distribution Mw/Mn of greater than 5.5 up to about 20. The rubber component of the mixture may be at least partially cured by dynamic vulcanization.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: October 7, 2003
    Inventors: Maria D. Ellul, Prasadarao Meka, Kang-Bo Wang, Yu-Feng Wang
  • Publication number: 20030181595
    Abstract: The present invention relates to compositions and preparative process of partially or fully neutralized mixtures of carboxylate functionalized ethylene high copolymers or terpolymers (Mw between 80,000 and 500,000) with carboxylate functionalized ethylene low copolymers (Mw between 2,000 and 30,000) and organic acid salts and injection or compression molded applications such as golf ball components thereof.
    Type: Application
    Filed: February 28, 2003
    Publication date: September 25, 2003
    Inventor: John C. Chen
  • Patent number: 6610785
    Abstract: Disclosed are thermoplastic elastomeric compositions include: A) from 10 to 80% by weight of one or more crystalline polymer of propylene containing from 0.05 to 15% in moles of ethylenic unsaturation, or a mixture of the above polymer with a saturated thermoplastic olefin polymer in quantities lower than or equal to 80% by weight; B) from 20 to 90% by weight of an unsaturated elastomeric olefin polymer; the compositions having been dynamically cross-linked with a cross-linking agent which includes a free radical generator.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: August 26, 2003
    Assignee: Montell North America Inc.
    Inventors: Giuliano Cecchin, Enea Garagnani
  • Patent number: 6610786
    Abstract: A thermoplastic elastomer exhibiting scarce tendency of depositing gummy crust around the extrusion die upon extrusion molding articles therefrom and a superior oil-resistance, which comprises (A) a crystalline polyolefin resin and (B) a cross-linked rubber component produced by a specific melt-kneading technique and which has a certain high level of gel content, a high oil-resistance and a certain reduced rate of deposition of gummy crust on the extrusion die.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: August 26, 2003
    Assignee: Mitsui Chemicals Inc
    Inventors: Yuichi Itoh, Akira Uchiyama
  • Patent number: 6605671
    Abstract: The invention discloses an improved process for the production of cross-linked rubber particles. The cross-linking agents are added to the aqueous rubber dispersions and converted at relatively high temperatures without inertization of the reaction mix and without pressurizing of an inert gas. The cross-linked rubber particles are suitable, for example, for the production of technical rubber products and for various tire components.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: August 12, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventor: Werner Obrecht
  • Patent number: 6602958
    Abstract: Adhesive composition, including a mixture of about 1 percent to about 35 percent by weight of chlorinated polymer, about 1 percent to about 35 percent by weight of a nitrile elastomer, a rubber-modified acrylonitrile copolymer, or mixtures thereof, and about 25 percent to about 90 percent by weight of an alkyl acrylate or methacrylate monomer.
    Type: Grant
    Filed: July 10, 2001
    Date of Patent: August 5, 2003
    Assignee: IPS Corporation
    Inventors: Paul C. Briggs, Masaki Minato, Samuel B. Osae
  • Patent number: 6602956
    Abstract: The melt strength is increased and the gloss level is reduced in olefinic TPE compositions through the addition of sufficient amounts of free radical generators (A) and co-curative agents (B). The free radical generators (A) include peroxides, organic peroxides, the persulfates, and the diazo compounds, and mixtures thereof. The co-curative agents (B) includes metal salts of alpha, beta-unsaturated carboxylic acids and alpha, beta-unsaturated carboxylic acids where the pending acid group has been neutralized, or mixtures thereof, and the metals for forming the metal salts of co-curative agent (B) include zinc, lithium, calcium, magnesium, sodium or aluminum, or mixtures thereof.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: August 5, 2003
    Assignee: Solvay Engineered Polymers
    Inventors: Xia Zhao, Hoan Tran, Charles G. Reid, Ruidong Ding