Solid Polymer Derived From Fluorine-containing Ethylenic Reactant Patents (Class 525/199)
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Publication number: 20140377558Abstract: To provide a fluorinated elastomer composition which is excellent in flexibility and oil resistance to lubricant oil such as automatic transmission oil, is less susceptible to heat discoloration and is excellent also in moldability, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a tetrafluoroethylene/propylene copolymer (a), an ethylene/tetrafluoroethylene copolymer (b) and an ethylene copolymer (c) containing epoxy groups, wherein the mass ratio [(a)/(b)] of the tetrafluoroethylene/propylene copolymer (a) to the ethylene/tetrafluoroethylene copolymer (b) is from 70/30 to 40/60, and the mass ratio [(b)/(c)] of the ethylene/tetrafluoroethylene copolymer (b) to the ethylene copolymer (c) containing epoxy groups is from 100/0.1 to 100/10.Type: ApplicationFiled: September 10, 2014Publication date: December 25, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Go MIZUNO, Masahide YODOGAWA, Yuichi IWANO, Masao UMINO, Yasuhiko MATSUOKA
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Publication number: 20140378562Abstract: A process for devulcanizing fluoroelastomers having a fluorine content between 62% and 74% by weight vulcanized by ionic systems, preferably selected from bisphenol A and bisphenol AF, i.e. 2,2-bis(4-hydroxyphenyl)hexafluoropropane, the process including a step of heating the vulcanized fluoroelastomers in the presence of a hydrolysis composition having one or more chemical selected from water, water soluble alcohols, water soluble glycols and mixtures thereof, at a temperature from 350° C. to 430° C. Fluoroelastomers obtainable by this process and their use for the preparation of compounds and vulcanized compositions are also described.Type: ApplicationFiled: February 28, 2013Publication date: December 25, 2014Applicant: DOTT. VIOLA & PARTNERS CHEMICAL RESEARCH S.R.L.Inventors: Alessandro Cervellati, Gian Tommaso Viola
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Publication number: 20140377557Abstract: A fluorine-including elastomer composition includes a fluororesin component including a first fluorine-including copolymer including a tetrafluoroethylene and an ?-olefin having a carbon number of 2 to 4 and a second fluorine-including copolymer including an ethylene-tetrafluoroethylene copolymer, a polyethylene resin mixed in an amount of 10 to 50 parts by mass per 100 parts by mass of the fluororesin component, and a crosslinking aid. A mass ratio of the first fluorine-including copolymer to the second fluorine-including copolymer is 90:10 to 10:90.Type: ApplicationFiled: June 6, 2014Publication date: December 25, 2014Inventor: Masanobu NAKAHASHI
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Publication number: 20140370383Abstract: Disclosed is a composition comprising an ethylene copolymer and a halogenated polymer, wherein the ethylene copolymer comprises or is produced from repeat units derived from ethylene and a comonomer selected from the group consisting of an ?,?-unsaturated monocarboxylic acid or its derivative, an ?,?-unsaturated dicarboxylic acid or its derivative, an epoxide-containing monomer, a vinyl ester, or combinations of two or more thereof; and the composition can further comprise a curing agent to crosslink the ethylene copolymer. The composition is useful as a binder for a lithium ion battery.Type: ApplicationFiled: June 11, 2014Publication date: December 18, 2014Inventors: CHONGSOO LIM, Daniel P. Fore
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Patent number: 8912283Abstract: Provided is a fluorine-containing elastomer blend comprising 5 to 60 wt. % of a high-molecular-weight, fluorine-containing elastomer having a number average molecular weight of 3,000,000 or more, 20 to 80 wt. % of a medium-molecular-weight, fluorine-containing elastomer having a number average molecular weight of 100,000 to 1,000,000, and 10 to 50 wt. % of a low-molecular-weight, fluorine-containing elastomer having a number average molecular weight of 7,000 to 13,000; the number average molecular weight Mn of each fluorine-containing elastomer being measured by liquid chromatography using tetrahydrofuran as a developing solvent at a polymer concentration of 0.5 wt. % at a measurement temperature of 35° C. The fluorine-containing elastomer blend can achieve low hardness and low modulus while improving roll processability.Type: GrantFiled: October 19, 2011Date of Patent: December 16, 2014Assignee: Unimatec Co., Ltd.Inventors: Hideki Hayashi, Mitsuru Maeda, Akihiko Ikeda
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Publication number: 20140349185Abstract: A binder resin composition for secondary battery electrodes is described as containing a polymer (A) that has a structural unit represented by general formula (1) and a water-insoluble particulate polymer (B-1) and/or a water-soluble polymer (B-2) where (A), (B-1) and (B-2) are defined as described. A slurry for secondary battery electrodes contains the binder resin composition, an active material and a solvent. An electrode for secondary batteries is provided with a collector and an electrode layer that is arranged on the collector, where the electrode layer contains an active material and the binder resin composition. Alternatively, the electrode layer is obtained by applying the slurry for secondary battery electrodes to the collector, and drying the slurry thereon.Type: ApplicationFiled: January 11, 2013Publication date: November 27, 2014Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Fumino Momose, Haruki Okada, Ayako Shimonaka, Mitsufumi Nodono, Daisuke Fujikawa, Hikaru Momose, Akihiro Ishii
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Patent number: 8889779Abstract: A coating composition is provided comprising (a) an aqueous medium, (b) melt-fabricable perfluoropolymer dispersed in said aqueous medium and having a melting temperature of at least 290° C., (c) melt-fabricable perfluoropolymer dispersed in said aqueous medium and having a melting temperature of no greater than 270° C., and (d) water miscible organic liquid having a boiling temperature of at least 280° C. and optionally (e) filler, the combination of (c) and (d) providing sloughing resistance to said composition applied to a non-horizontal substrate and baked, component (d) being unnecessary when component (a) is not present in the coating composition, and when filler is present the amount of (c) being present in an effective amount to increase the cohesive strength of the baked layer of the coating composition.Type: GrantFiled: April 19, 2011Date of Patent: November 18, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Laurence Waino McKeen, Ying Wang
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Publication number: 20140335634Abstract: A mold release film, which is adapted to be disposed on the cavity surface of a mold to form a resin-encapsulated portion by encapsulating a semiconductor element of a semiconductor device with a curable encapsulation resin, has a tensile modulus of elasticity of from 10 to 24 MPa at 132° C. as measured in accordance with JIS K 7127, and a peak peel resistance of at most 0.8 N/25 mm.Type: ApplicationFiled: July 29, 2014Publication date: November 13, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Wataru KASAI, Yoshiaki HIGUCHI, Masakazu ATAKU, Daisuke TAGUCHI, Satoshi OTSUGU
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Patent number: 8883884Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a polymer blend comprising a copolymer and an additional polymer, the copolymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer immiscible with the backbone; the additional polymer consisting of a polymer miscible with the polymeric sidechains.Type: GrantFiled: November 27, 2012Date of Patent: November 11, 2014Assignee: The Goodyear Tire & Rubber CompanyInventors: Liqing Ma, Robert Fokko Roskamp, Ralf Mruk, Frank James Feher, Bruce Raymond Hahn
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Patent number: 8877823Abstract: The present invention relates generally to a method for manufacturing a foamed article, which comprises providing a composition comprising a melt-processable perfluoropolymer and talc, said perfluoropolymer comprising at least 50 percent by weight of said composition and said talc comprising about 2 percent to 3 percent by weight of said composition; wherein said melt-processable perfluoropolymer is selected from the group consisting of tetrafluoroethylent/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP), and perfluroralkoxy (PFA) and any blend thereof. The composition is heated to a processing temperature of at least 600° F. at which talc functions as a foaming agent, thereby causing the foaming of said composition at a foaming rate in a range from 20% to 50% so as to form a foamed article. The talc is the only foaming agent in said composition and the foaming is achieved without gas injection.Type: GrantFiled: October 1, 2012Date of Patent: November 4, 2014Assignee: Cable Components Group, LLCInventors: Charles A. Glew, Kenneth R. Boyle, Bradley Lane Kent, Jeffrey A. Hrivnak
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Patent number: 8865839Abstract: Provided is a material that can be easily biaxially oriented, homogeneously stretched even with a high draw ratio, and formed into a polytetrafluoroethylene porous membrane with low pressure loss. The present invention relates to a polytetrafluoroethylene mixture comprising: a modified polytetrafluoroethylene; and a fibrillable polytetrafluoroethylene homopolymer, the modified polytetrafluoroethylene having an extrusion pressure to a cylinder, at a reduction ratio of 1600, of 70 MPa or higher.Type: GrantFiled: December 21, 2011Date of Patent: October 21, 2014Assignee: Daikin Industries, Ltd.Inventors: Yasuhiko Sawada, Shunji Kasai, Taku Yamanaka, Makoto Ono, Yoshiyuki Shibuya, Kunihiko Inui, Shinichi Chaen
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Publication number: 20140296438Abstract: The invention relates to a polyvinylidene fluoride polymer having an ultra-high molecular weight, and unexpected physical properties. The ultra-high molecular weight polymer is clear, has a lower melting point, reduced crystallinity, excellent impact resistance, and a high elongation at the yield point. The ultra-high molecular weight polyvinylidene fluoride can be alone, or blended with other polymers, in final applications and articles.Type: ApplicationFiled: June 11, 2014Publication date: October 2, 2014Inventor: Ramin Amin-Sanayei
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Patent number: 8846812Abstract: Disclosed herein is a process for the manufacture of a fluoroelastomer composition containing fluoropolymer fibrils. The process comprises applying shear to a fluoroelastomer gum in a mixer while adding a liquid dispersion of fibrillatable fluoropolymer.Type: GrantFiled: November 14, 2012Date of Patent: September 30, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Christopher J Bish, Kostantinos Kourtakis
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Patent number: 8835551Abstract: Iodine containing amorphous fluoropolymers having at least one fluoropolymer with a cure site, where the fluoropolymer has a Mooney viscosity of 2 or less (ML 1+10) at 100° C. according to ASTM D1646, and a peel strength to a roll mill of 10 dN/cm or less and methods for making such iodine containing amorphous fluoropolymers are described. Articles derived from the cured product of such iodine containing amorphous fluoropolymers are also described. Solutions, dispersions and coatings derived from such iodine containing amorphous fluoropolymers are also described.Type: GrantFiled: September 11, 2008Date of Patent: September 16, 2014Assignee: 3M Innovative Properties CompanyInventors: Tatsuo Fukushi, Peter J. Scott, Cynthia N. Ferguson, Werner M. A. Grootaert, Denis Duchesne, Yeng Moua, Larry A. Last, Terri A. Shefelbine, Luke M. B. Rodgers
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Patent number: 8822602Abstract: Heterophasic propylene copolymer (HECO) comprising: (a) a polypropylene matrix comprising: (a1) a first propylene homopolymer fraction (PPH1) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >200 to 500 g/10 min, (a2-1) a second propylene homopolymer fraction (PPH2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >30 to ?200 g/10 min or, (a2-2) a second propylene homopolymer fraction (PPH2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >5 to ?30 g/10 min and, (a3-1) a third propylene homopolymer fraction (PPH3) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 0.03 to ?5 g/10 min, if the second propylene homopolymer fraction is fraction (a2-1) or, (a3-2) a third propylene homopolymer fraction (PPH3) with a melt flow rate MFR2 (230° C.Type: GrantFiled: November 8, 2011Date of Patent: September 2, 2014Assignee: Borealis AGInventors: Pauli Leskinen, Petar Doshev, Cornelia Kock
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Publication number: 20140235783Abstract: The present invention aims to provide a composition that forms a film excellent in freeze-thaw resistance, as well as in transparency, weather resistance, adhesion to a base material, and blocking resistance. The present invention relates to a composition comprising polymer particles (A) and a crosslinking agent (B), the polymer particles (A) obtainable by seed polymerization of at least one monomer selected from the group consisting of acrylic acid esters and methacrylic acid esters, an unsaturated carboxylic acid, and a hydrolyzable silyl group-containing monomer in the presence of fluoropolymer particles as seed particles, and the crosslinking agent (B) having at least one group selected from the group consisting of aziridine, carbodiimide, and oxazoline groups.Type: ApplicationFiled: October 1, 2012Publication date: August 21, 2014Inventors: Mayumi Iida, Katsuhiko Imoto, Yoshinari Fukuhara, Shumi Yoshida
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Patent number: 8796384Abstract: Provided is a cross-linkable fluororubber composition capable of giving a fluororubber cross-linked molded article that has excellent mechanical strength and low friction properties. The cross-linkable fluororubber composition includes a coagulum obtained by co-coagulating a fluororubber (A) and a fluororesin (B).Type: GrantFiled: July 2, 2010Date of Patent: August 5, 2014Assignee: Daikin Industries, Ltd.Inventors: Kouhei Takemura, Tomihiko Yanagiguchi
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Publication number: 20140213730Abstract: The invention pertains to a process for cryogenic milling mixtures of (per)fluoroelastomers and semicrystalline thermoplastic VDF polymers, and to free-flowing micronized pellets obtainable therefrom, said micronized pellets advantageously yielding, after extrusion and compounding, excellent mechanical properties, even improved over those of base fluoroelastomer matrix.Type: ApplicationFiled: August 9, 2012Publication date: July 31, 2014Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Liubov Chernysheva, Giovanni Comino, Giulio Brinati
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Publication number: 20140205757Abstract: Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (?m), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processible fluoropolymer (MPF), such as perfluoromethylvinvyl ether (MFA), fluorinated ethylene propylene (FEP), or perfluoropropylvinvyl ether (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (?m).Type: ApplicationFiled: March 24, 2014Publication date: July 24, 2014Applicant: WHITFORD CORPORATIONInventors: Leonard W. Harvey, Michael Coates, Julie K. Wright
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Patent number: 8785560Abstract: Process for reducing thermally induced discoloration of fluoropolymer resin produced by polymerizing fluoromonomer in an aqueous dispersion medium to form aqueous fluoropolymer dispersion and isolating said fluoropolymer from the aqueous medium by separating fluoropolymer resin in wet form from the aqueous medium and drying to produce fluoropolymer resin in dry form. The process comprises: pretreating the aqueous fluoropolymer dispersion and/or the fluoropolymer resin in wet or dry form; and exposing the fluoropolymer resin in dry form to fluorine.Type: GrantFiled: May 2, 2013Date of Patent: July 22, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Paul Douglas Brothers, Gregory Allen Chapman, Subhash Vishnu Gangal
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Publication number: 20140178686Abstract: A fiber is disclosed having a central axis or spline and a major outer surface, the fiber made of a base material and poly(vinylidene fluoride), the proportion of base material to poly(vinylidene fluoride) being greater towards the central axis or spline of the fiber than at the major outer surface of the fiber. The base material may be selected from the group consisting of polyethylene, polypropylene and nylon. The fiber has a surface roughness.Type: ApplicationFiled: December 11, 2013Publication date: June 26, 2014Applicant: POLYSTEEL ATLANTIC LIMITEDInventors: Dean Paul Forgeron, Shannon Marie O'Connell
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Patent number: 8754176Abstract: The present invention provides a low-molecular weight polytetrafluoroethylene powder that, when used as an additive in a coating material, etc., can form a coating with excellent texture and gliding properties, while also improving dispersibility and viscosity; and a production process therefor. The present invention is a process for producing a low-molecular weight polytetrafluoroethylene powder, the process comprising: an emulsion polymerization step of polymerizing at least tetrafluoroethylene in the presence of a polymerization initiator and an aqueous medium to produce emulsified particles thereof; an agglomeration step of agglomerating the emulsified particles to form an agglomerated powder thereof; and a suspension polymerization step of polymerizing at least tetrafluoroethylene in the presence of the agglomerated powder, a polymerization initiator, and an aqueous medium.Type: GrantFiled: March 31, 2010Date of Patent: June 17, 2014Assignee: Daikin Industries, Ltd.Inventors: Taku Yamanaka, Masayuki Tsuji, Shunji Kasai, Yasuhiko Sawada
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Patent number: 8742015Abstract: The objective of the present invention is to provide a thermoplastic resin composition having an excellent balance of chemical resistance, heat resistance and impact resistance and a molded article comprising this thermoplastic resin composition. The present thermoplastic resin composition comprises a rubber-reinforced resin, an ethylene•(meth)acrylic acid ester•carbon monoxide copolymer, and polytetrafluoroethylene, and contents of ethylene•(meth)acrylic acid ester•carbon monoxide copolymer and polytetrafluoroethylene are respectively from 0.5 to 20 parts by weight and from 0.01 to 5 parts by weight, with respect to 100 parts by weight of the rubber-reinforced resin. A modified polyolefin resin may be contained.Type: GrantFiled: July 11, 2007Date of Patent: June 3, 2014Assignee: Techno Polymer Co., Ltd.Inventors: Keigo Higaki, Yasuhiko Itou
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Patent number: 8710149Abstract: This invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic hydrogen-containing fluoropolymer [polymer (A)]; and from 0.1 to 10% by weight of (A) of at least one per(halo)fluoropolymer chosen among tetrafluoroethylene (TFE) copolymers having a dynamic viscosity at a shear rate of 1 rad sec?1 of less than 10 Pa sec at a temperature of 280° C. [polymer (B)]. The addition of a TFE copolymer [polymer (B)] of low melt viscosity advantageously enables improvement of rheological behavior of thermoplastic hydrogen-containing fluoropolymer (A), making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the invention are a process for manufacturing said thermoplastic fluoropolymer composition and the articles, such as shaped articles, films, cable sheathing, pipes, flexible pipes, hollow bodies comprising said thermoplastic fluoropolymer composition.Type: GrantFiled: April 23, 2007Date of Patent: April 29, 2014Assignee: Solvay Solexis S.p.A.Inventors: Julio Abusleme, Alessio Marrani
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Patent number: 8691344Abstract: Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (?m), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processible fluoropolymer (MPF), such as methylfluoroalkoxy (MFA), fluorinated ethylene propylene (FEP), or perfluoroalkoxy (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (?m).Type: GrantFiled: May 19, 2009Date of Patent: April 8, 2014Assignee: Whitford CorporationInventors: Leonard W. Harvey, Michael Coates, Julie K. Wright
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Patent number: 8669336Abstract: The invention relates to a coating composition comprising short chain fluorinated acrylates and to the use of short chain fluorinated acrylates as levelling agents for pigmented and unpigmented coating compositions. The coating composition comprises a) a film forming binder resin, and b) a copolymer made by controlled polymerization or by conventional radical polymerization comprising a monomer (M1x) selected from unsaturated monomers out of the group of (meth)acrylates, styrenic monomers or (meth)acrylamides whereby the copolymer contains at least >30 wt % (meth)acrylates; and a monomer (M2y) selected from C1-C4-fluoralkyl(meth)acrylates; x denotes the total number of monomers M1 within the structural element (M1x): x>5, preferred, 10-1000, most preferred, 10-500; y denotes the total number of monomers M2 within the structural element (M2y): y>1, preferred, 2-20, most preferred 2-10; c) optional other conventional coating components and/or additives.Type: GrantFiled: February 3, 2009Date of Patent: March 11, 2014Assignee: BASF SEInventors: Andreas Möck, Ralf Knischka, Clemens Auschra
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Publication number: 20140066573Abstract: Provided is a polymer preparing method. By additionally inputting a catalytic reducing agent that reduces an inactivated metal complex compound catalyst to an activated metal complex compound catalyst, a polymer polymerized at a high conversion ratio of a monomer can be provided.Type: ApplicationFiled: November 6, 2013Publication date: March 6, 2014Applicant: LG CHEM, LTD.Inventors: Su Jeong KIM, Jeong Ae YOON
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Patent number: 8653213Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Compositions that include perfluorohexyl(meth)acrylate and a branched or high Tg monomer are provided as are articles coated with the polymerization product of the composition. Methods are also provided for forming hydrophobic coatings on articles.Type: GrantFiled: August 16, 2011Date of Patent: February 18, 2014Assignee: Cytonix, LLCInventor: James F Brown
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Patent number: 8648147Abstract: Heat aging of the composition comprising melt-fabricable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, the alkyl containing 1 to 5 carbon atoms and melt flowable polytetrafluoroethylene is effective to cause thermal transformation of the composition in the solid state, which is epitaxial co-crystallization of the polymer components of the composition, and other valuable changes, such as increased continuous use temperature.Type: GrantFiled: July 29, 2011Date of Patent: February 11, 2014Assignee: E I du Pont de Nemours and CompanyInventor: Jacob Lahijani
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Publication number: 20140034109Abstract: A resin composition, a multi-layered film, a backsheet for photovoltaic modules, a method thereof, and a photovoltaic module are provided. The multi-layered film including a coating layer including a fluorine-based polymer has an excellent durability and weather resistance, and also exhibits high interfacial adhesive strength to a substrate since the multi-layered film is formed by coating a cured product of the resin composition including the fluorine-based polymer, an acrylic polymer including a thermosetting functional group, and a heat-curing agent on the substrate. In addition, drying can be performed at a low temperature during the manufacture of the multi-layered film so that the manufacturing costs can be decreased, productivity can be increased, and the deterioration of the product due to heat modification, heat shock, and the like, can be prevented. The multi-layered film can be effectively used as a backsheet for various photovoltaic modules.Type: ApplicationFiled: October 11, 2013Publication date: February 6, 2014Applicant: LG CHEM, LTDInventors: Hyun Cheol KIM, Hyun Seong KO
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Patent number: 8642699Abstract: A fluidity improver for a PC resin that improves the melt fluidity during molding without impairing the excellent properties of the PC resin, and also yields a molded product in which external appearance defects are unlikely. The fluidity improver for an aromatic polycarbonate resin according to the present invention is including a first polymer obtained by polymerizing 0.5 to 99.5 parts by mass of a monomer first mixture including 0.5 to 99.5% by mass of styrene and 0.5 to 99.5% by mass of phenyl (meth)acrylates, in the presence of a second polymer obtained by polymerizing 0.5 to 99.5 parts by mass of a second monomer mixture containing 0.5 to 50% by mass of ?-methylstyrene, 0.5 to 99% by mass of styrene and 0.5 to 99% by mass of phenyl (meth)acrylates, wherein the combined total of both monomer mixtures is 100 parts by mass.Type: GrantFiled: March 11, 2009Date of Patent: February 4, 2014Assignees: Mitsubishi Rayon Co., Ltd., Koito Manufacturing Co., Ltd.Inventors: Shinji Matsuoka, Hidetaka Anma, Kazuyuki Miyake
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Patent number: 8642702Abstract: The invention pertains to a thermoplastic VDF polymer composition comprising: at least one thermoplastic vinylidene fluoride (VDF) polymer comprising at least 85% by moles of recurring units derived from VDF; and at least one ethylene/chlorotrifluoroethylene (ECTFE) polymer, wherein said ECTFE polymer possesses a melting point of less than 210° C. and it is comprised in an amount of from 0.1 to 20% wt with respect to the total weight of VDF polymer and ECTFE polymer. The invention also pertains to a process for making the VDF polymer and to the uses thereof for manufacturing films, in particular transparent films.Type: GrantFiled: April 26, 2011Date of Patent: February 4, 2014Assignee: Solvay Specialty Polymers Italy S.p.A.Inventors: Julio A. Abusleme, Stefano Mortara
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Patent number: 8642159Abstract: Provided is a film having high crystallinity, transparency, and surface smoothness, a lamination of the film, a sheet of the film, and a laminated body. A film contains vinylidene fluoride-based resin (A) and acrylic-based resin (B). The film has at least one surface with arithmetic mean roughness of 0.1 to 20 nm. The at least one surface has crystal fusion heat of 18 to 40 J/g and a haze value of 3.5 or less, the crystal fusion heat being measured using a differential scanning calorimeter.Type: GrantFiled: May 13, 2011Date of Patent: February 4, 2014Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Yuhei Konokawa, Yoshinori Abe
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Publication number: 20140031475Abstract: Provided is a seal ring manufactured from a mixture containing a soft resin including at least one of a thermoplastic elastomer and a dynamic crosslinked resin, and a hard resin including a thermoplastic resin. With this seal ring, the adhesion to the inner peripheral surface of a housing can be maintained in a no-load state where a hydraulic pressure is not generated even after use as a one-piece type for an extended period of time and oil leakage can be effectively prevented. The mixture constituting the seal ring preferably has a compression permanent deformation of 95% or lower after immersion in an automatic transmission fluid at 150° C. for 100 hours.Type: ApplicationFiled: January 13, 2012Publication date: January 30, 2014Applicant: KABUSHIKI KAISHA RIKENInventors: Hiroshi Ito, Akihiro Oowada
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Patent number: 8637608Abstract: Fluoropolymers containing one or more azide group wherein the azide group is not a sulfonyl-azide group and processes of preparing them.Type: GrantFiled: August 17, 2009Date of Patent: January 28, 2014Assignee: 3M Innovative Properties CompanyInventors: Klaus Hintzer, Michael Juergens, Harald Kaspar, Kai H. Lochhaas, Oleg Shyshkov, Andre Streiter, Tilman C. Zipplies, Sabine H. G. Beuermann, Muhammad Imran ul-haq
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Patent number: 8632856Abstract: Highly water repellent coated articles may be made by applying to a substrate a coating having dispersed therein or sprinkled thereon partially or fully fluorinated polymer microparticles. The coating includes a partially fluorinated hexafluoropropylene copolymer binder in a nonfluorinated solvent that dissolves the binder and does not dissolve the microparticles. The coating is heated sufficiently to bond the microparticles to the binder but not so much as to cause the receding water contact angle for the coating to fall below 80°.Type: GrantFiled: December 20, 2006Date of Patent: January 21, 2014Assignee: 3M Innovative Properties CompanyInventors: Naiyong Jing, Lisa P. Chen
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Patent number: 8623963Abstract: High purity perfluoroelastomer composites and processes for producing the same are provided. High purity composites may be formed from compositions comprising a crosslinkable fluoroelastomer terpolymer of TFE, PAVE, and CNVE, and functionalized PTFE, which may be crosslinked to form crosslinked composites having low metal content and low compression set. Emulsion mixtures for forming the high purity composites are also provided.Type: GrantFiled: January 14, 2009Date of Patent: January 7, 2014Assignee: W. L. Gore & Associates, Inc.Inventors: Ping Xu, Jack Hegenbarth
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Publication number: 20140005335Abstract: A process for the preparation of a fluoroolefin polymer from an azeotropic mixture of monomers having a constant composition, the process including the step of: contacting in a reaction zone: (i) an initiator; and (ii) an azeotropic mixture of monomers including at least one fluoroolefin and, optionally, at least one ethylenically unsaturated comonomer capable of copolymerizing therewith; wherein the contacting is carried out at a temperature, pressure and length of time sufficient to produce the fluoroolefin polymer.Type: ApplicationFiled: September 5, 2013Publication date: January 2, 2014Applicant: Honeywell International Inc.Inventors: George J. Samuels, Gregory J. Shafer, Hang T. Pham
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Publication number: 20140005334Abstract: It is provided a polymer blend that contains a polymer formed of fluorinated monomers and hydrocarbon monomers and another biocompatible polymer.Type: ApplicationFiled: August 9, 2013Publication date: January 2, 2014Applicant: Abbott Cardiovascular Systems Inc.Inventor: Stephen D. Pacetti
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Patent number: 8609756Abstract: Polymeric composition based on a PVDF homopolymer and a thermoplastic fluorocopolymer Polymeric composition based on a PVDF homopolymer and a thermoplastic fluoropolymer offering an improved toughness/processability compromise, possessing an apparent melt viscosity not exceeding 60 000 Pa·s at a shear rate of 1 s?1, a ductile-brittle transition temperature below +5° C. and a weight loss in air at 150° C. of 5% or less. Pipes and fashioned articles prepared from this composition.Type: GrantFiled: October 20, 2005Date of Patent: December 17, 2013Assignee: Solvay (Societe Anonyme)Inventors: Thierry Baert, Bernard Goffaux, Vincent Bodart, Stephane Heuschling
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Publication number: 20130330392Abstract: It is provided an implantable device including a polymer blend that contains a polymer formed of fluorinated monomers and hydrocarbon monomers and another biocompatible polymer.Type: ApplicationFiled: August 14, 2013Publication date: December 12, 2013Applicant: Abbott Cardiovascular Systems Inc.Inventor: Stephen D. Pacetti
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Patent number: 8603411Abstract: A seal is formed of a material including a crosslinked fluoropolymer. The seal substantially prevents leaks in a high pressure pump.Type: GrantFiled: December 10, 2012Date of Patent: December 10, 2013Assignee: Saint-Gobain Performance Plastics CorporationInventors: Robert Thomas Racicot, Jon M. Lenhert, Karthik Vaideeswaran, Christopher M. Comeaux
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Patent number: 8586673Abstract: Polymer composition (C) containing (i) a poly(aryl ether sulfone) material (M12) composed of a poly(biphenyl ether sulfone) (P1) and, optionally in addition, a poly(aryl ether sulfone) (P2) containing recurring units with arylene groups linked to each other via a secondary, ternary or quaternary carbon atom, and (ii) a per(halo)fluoropolymer material (M34), composed of a per(halo)fluoropolymer (P3) of which at least 2.0 wt. % of the recurring units are derived from a per(halo)fluoromonomer other than tetrafluoroethylene, and a polytetrafluoroethylene (P4). Shaped article, especially aircraft interior component, comprising the polymer composition (C).Type: GrantFiled: May 7, 2009Date of Patent: November 19, 2013Assignee: Solvay Advanced Polymers, L.L.C.Inventor: Shari A. Weinberg
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Patent number: 8586677Abstract: Blended fluoropolymer compositions that, in one exemplary application, may be applied as a coating to a substrate and, optionally, may be applied to a substrate that has been previously coated with a primer or basecoat and/or a midcoat. In one embodiment, the composition is a blend of at least one high molecular weight trace modified polytetrafluoroethyelene (TMHPTFE) and at least one melt-processible fluoropolymer (MPF). After being applied to the substrate, optionally over a primer or basecoat and/or midcoat, and then cured, the present compositions form coatings that demonstrate improved abrasion resistance and/or improved release characteristics and/or increased translucency/transparency and/or improved impermeability. The present compositions may also be used to produce films having a high degree of clarity and impermeability. The present compositions in powder form may be melt or paste extruded to form articles with improved impermeability.Type: GrantFiled: April 11, 2011Date of Patent: November 19, 2013Assignee: Whitford CorporationInventors: Leonard W. Harvey, Helen L. Brain, Susan J. Roberts-Bleming, Lawrence D. Leech, Thomas J. Bate
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Patent number: 8580892Abstract: A rubber composition has sufficient resistance to degradation and swelling caused by a liquid such as a water-soluble coolant and also is capable of having sufficient resistance to ozone. The rubber composition contains a fluororubber not having a vinylidene fluoride structure, a nitrile rubber, a fluorine-based oil and a peroxide vulcanizing agent.Type: GrantFiled: November 16, 2010Date of Patent: November 12, 2013Assignee: OMRON CorporationInventors: Kazuyuki Tsukimori, Junryo Nariai, Tsutomu Inuyama, Shinji Mizuno
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Patent number: 8575273Abstract: Certain embodiments described herein are directed to silane coupling agents that may be used, for example, to covalently couple a polymer to a filler. In some examples, devices that include the polymer-silane coupling agent-filler compositions are also described.Type: GrantFiled: November 26, 2008Date of Patent: November 5, 2013Assignee: Schlumberger Technology CorporationInventors: Huilin Tu, Agathe Robisson, Julien Ramier
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Patent number: 8569413Abstract: An aqueous coating composition having excellent coating adhesion, workability, heat resistance and chemical resistance, and has an object to provide an aqueous coating composition for sealing, which is suitable for members to be screwed in. An aqueous coating composition including: as main components, component (A) an ethylene-vinyl acetate copolymer resin emulsion and component (B) two or more PTFE resin powders having different particle diameters, in which 35 to 80 parts by mass of water is contained on the basis of 100 parts by mass of the total of (A) and (B).Type: GrantFiled: October 29, 2009Date of Patent: October 29, 2013Assignee: Three Bond Co., Ltd.Inventors: Hidenori Kanazawa, Naoki Satou
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Patent number: 8563660Abstract: [Object] To provide a fluororubber-based sealing material which is excellent in sealing properties under high/low temperature load and is capable of sealing at a temperature of not higher than ?40° C. even when gas oil (diesel fuel) is used. [Means for Solving] A fluororubber-based sealing material obtained by crosslinking a composition for a fluororubber-based sealing material, said composition comprising 100 parts by weight of a fluorine-containing copolymer which contains 64 to 69% by weight of fluorine, has a crosslinking site derived from a bromine-containing compound and/or an iodine-containing compound and is capable of being crosslinked by a peroxide, 0.Type: GrantFiled: April 7, 2009Date of Patent: October 22, 2013Assignee: Nok CorporationInventor: Hiroyuki Sano
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Publication number: 20130267621Abstract: Provided is a material that can be easily biaxially oriented, homogeneously stretched even with a high draw ratio, and formed into a PTFE porous membrane with low pressure loss. The present invention relates to a polytetrafluoroethylene mixture comprising: a fibrillable modified polytetrafluoroethylene; and a fibrillable polytetrafluoroethylene homopolymer, the polytetrafluoroethylene homopolymer having strength at break of 25 N or higher.Type: ApplicationFiled: December 21, 2011Publication date: October 10, 2013Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Yasuhiko Sawada, Shunji Kasai, Taku Yamanaka, Yoshiyuki Shibuya, Kunihiko Inui, Shinichi Chaen
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Publication number: 20130264522Abstract: The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF), and from 0.01% to 5% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (F) comprising end groups having formula —CF2H and/or —CF2CH3 in an amount of at least 30 mmoles per Kg of vinylidene fluoride (VDF) recurring units. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as binders for the manufacture of electrodes or for the manufacture of membranes.Type: ApplicationFiled: December 13, 2011Publication date: October 10, 2013Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Milena Stanga, Bradley Lane Kent, Alessio Marrani, Giulio Brinati