Solid Polymer Derived From Fluorine-containing Ethylenic Reactant Patents (Class 525/199)
  • Publication number: 20140377558
    Abstract: To provide a fluorinated elastomer composition which is excellent in flexibility and oil resistance to lubricant oil such as automatic transmission oil, is less susceptible to heat discoloration and is excellent also in moldability, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a tetrafluoroethylene/propylene copolymer (a), an ethylene/tetrafluoroethylene copolymer (b) and an ethylene copolymer (c) containing epoxy groups, wherein the mass ratio [(a)/(b)] of the tetrafluoroethylene/propylene copolymer (a) to the ethylene/tetrafluoroethylene copolymer (b) is from 70/30 to 40/60, and the mass ratio [(b)/(c)] of the ethylene/tetrafluoroethylene copolymer (b) to the ethylene copolymer (c) containing epoxy groups is from 100/0.1 to 100/10.
    Type: Application
    Filed: September 10, 2014
    Publication date: December 25, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Go MIZUNO, Masahide YODOGAWA, Yuichi IWANO, Masao UMINO, Yasuhiko MATSUOKA
  • Publication number: 20140378562
    Abstract: A process for devulcanizing fluoroelastomers having a fluorine content between 62% and 74% by weight vulcanized by ionic systems, preferably selected from bisphenol A and bisphenol AF, i.e. 2,2-bis(4-hydroxyphenyl)hexafluoropropane, the process including a step of heating the vulcanized fluoroelastomers in the presence of a hydrolysis composition having one or more chemical selected from water, water soluble alcohols, water soluble glycols and mixtures thereof, at a temperature from 350° C. to 430° C. Fluoroelastomers obtainable by this process and their use for the preparation of compounds and vulcanized compositions are also described.
    Type: Application
    Filed: February 28, 2013
    Publication date: December 25, 2014
    Applicant: DOTT. VIOLA & PARTNERS CHEMICAL RESEARCH S.R.L.
    Inventors: Alessandro Cervellati, Gian Tommaso Viola
  • Publication number: 20140377557
    Abstract: A fluorine-including elastomer composition includes a fluororesin component including a first fluorine-including copolymer including a tetrafluoroethylene and an ?-olefin having a carbon number of 2 to 4 and a second fluorine-including copolymer including an ethylene-tetrafluoroethylene copolymer, a polyethylene resin mixed in an amount of 10 to 50 parts by mass per 100 parts by mass of the fluororesin component, and a crosslinking aid. A mass ratio of the first fluorine-including copolymer to the second fluorine-including copolymer is 90:10 to 10:90.
    Type: Application
    Filed: June 6, 2014
    Publication date: December 25, 2014
    Inventor: Masanobu NAKAHASHI
  • Publication number: 20140370383
    Abstract: Disclosed is a composition comprising an ethylene copolymer and a halogenated polymer, wherein the ethylene copolymer comprises or is produced from repeat units derived from ethylene and a comonomer selected from the group consisting of an ?,?-unsaturated monocarboxylic acid or its derivative, an ?,?-unsaturated dicarboxylic acid or its derivative, an epoxide-containing monomer, a vinyl ester, or combinations of two or more thereof; and the composition can further comprise a curing agent to crosslink the ethylene copolymer. The composition is useful as a binder for a lithium ion battery.
    Type: Application
    Filed: June 11, 2014
    Publication date: December 18, 2014
    Inventors: CHONGSOO LIM, Daniel P. Fore
  • Patent number: 8912283
    Abstract: Provided is a fluorine-containing elastomer blend comprising 5 to 60 wt. % of a high-molecular-weight, fluorine-containing elastomer having a number average molecular weight of 3,000,000 or more, 20 to 80 wt. % of a medium-molecular-weight, fluorine-containing elastomer having a number average molecular weight of 100,000 to 1,000,000, and 10 to 50 wt. % of a low-molecular-weight, fluorine-containing elastomer having a number average molecular weight of 7,000 to 13,000; the number average molecular weight Mn of each fluorine-containing elastomer being measured by liquid chromatography using tetrahydrofuran as a developing solvent at a polymer concentration of 0.5 wt. % at a measurement temperature of 35° C. The fluorine-containing elastomer blend can achieve low hardness and low modulus while improving roll processability.
    Type: Grant
    Filed: October 19, 2011
    Date of Patent: December 16, 2014
    Assignee: Unimatec Co., Ltd.
    Inventors: Hideki Hayashi, Mitsuru Maeda, Akihiko Ikeda
  • Publication number: 20140349185
    Abstract: A binder resin composition for secondary battery electrodes is described as containing a polymer (A) that has a structural unit represented by general formula (1) and a water-insoluble particulate polymer (B-1) and/or a water-soluble polymer (B-2) where (A), (B-1) and (B-2) are defined as described. A slurry for secondary battery electrodes contains the binder resin composition, an active material and a solvent. An electrode for secondary batteries is provided with a collector and an electrode layer that is arranged on the collector, where the electrode layer contains an active material and the binder resin composition. Alternatively, the electrode layer is obtained by applying the slurry for secondary battery electrodes to the collector, and drying the slurry thereon.
    Type: Application
    Filed: January 11, 2013
    Publication date: November 27, 2014
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Fumino Momose, Haruki Okada, Ayako Shimonaka, Mitsufumi Nodono, Daisuke Fujikawa, Hikaru Momose, Akihiro Ishii
  • Patent number: 8889779
    Abstract: A coating composition is provided comprising (a) an aqueous medium, (b) melt-fabricable perfluoropolymer dispersed in said aqueous medium and having a melting temperature of at least 290° C., (c) melt-fabricable perfluoropolymer dispersed in said aqueous medium and having a melting temperature of no greater than 270° C., and (d) water miscible organic liquid having a boiling temperature of at least 280° C. and optionally (e) filler, the combination of (c) and (d) providing sloughing resistance to said composition applied to a non-horizontal substrate and baked, component (d) being unnecessary when component (a) is not present in the coating composition, and when filler is present the amount of (c) being present in an effective amount to increase the cohesive strength of the baked layer of the coating composition.
    Type: Grant
    Filed: April 19, 2011
    Date of Patent: November 18, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Laurence Waino McKeen, Ying Wang
  • Publication number: 20140335634
    Abstract: A mold release film, which is adapted to be disposed on the cavity surface of a mold to form a resin-encapsulated portion by encapsulating a semiconductor element of a semiconductor device with a curable encapsulation resin, has a tensile modulus of elasticity of from 10 to 24 MPa at 132° C. as measured in accordance with JIS K 7127, and a peak peel resistance of at most 0.8 N/25 mm.
    Type: Application
    Filed: July 29, 2014
    Publication date: November 13, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Wataru KASAI, Yoshiaki HIGUCHI, Masakazu ATAKU, Daisuke TAGUCHI, Satoshi OTSUGU
  • Patent number: 8883884
    Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a polymer blend comprising a copolymer and an additional polymer, the copolymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer immiscible with the backbone; the additional polymer consisting of a polymer miscible with the polymeric sidechains.
    Type: Grant
    Filed: November 27, 2012
    Date of Patent: November 11, 2014
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Liqing Ma, Robert Fokko Roskamp, Ralf Mruk, Frank James Feher, Bruce Raymond Hahn
  • Patent number: 8877823
    Abstract: The present invention relates generally to a method for manufacturing a foamed article, which comprises providing a composition comprising a melt-processable perfluoropolymer and talc, said perfluoropolymer comprising at least 50 percent by weight of said composition and said talc comprising about 2 percent to 3 percent by weight of said composition; wherein said melt-processable perfluoropolymer is selected from the group consisting of tetrafluoroethylent/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP), and perfluroralkoxy (PFA) and any blend thereof. The composition is heated to a processing temperature of at least 600° F. at which talc functions as a foaming agent, thereby causing the foaming of said composition at a foaming rate in a range from 20% to 50% so as to form a foamed article. The talc is the only foaming agent in said composition and the foaming is achieved without gas injection.
    Type: Grant
    Filed: October 1, 2012
    Date of Patent: November 4, 2014
    Assignee: Cable Components Group, LLC
    Inventors: Charles A. Glew, Kenneth R. Boyle, Bradley Lane Kent, Jeffrey A. Hrivnak
  • Patent number: 8865839
    Abstract: Provided is a material that can be easily biaxially oriented, homogeneously stretched even with a high draw ratio, and formed into a polytetrafluoroethylene porous membrane with low pressure loss. The present invention relates to a polytetrafluoroethylene mixture comprising: a modified polytetrafluoroethylene; and a fibrillable polytetrafluoroethylene homopolymer, the modified polytetrafluoroethylene having an extrusion pressure to a cylinder, at a reduction ratio of 1600, of 70 MPa or higher.
    Type: Grant
    Filed: December 21, 2011
    Date of Patent: October 21, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Yasuhiko Sawada, Shunji Kasai, Taku Yamanaka, Makoto Ono, Yoshiyuki Shibuya, Kunihiko Inui, Shinichi Chaen
  • Publication number: 20140296438
    Abstract: The invention relates to a polyvinylidene fluoride polymer having an ultra-high molecular weight, and unexpected physical properties. The ultra-high molecular weight polymer is clear, has a lower melting point, reduced crystallinity, excellent impact resistance, and a high elongation at the yield point. The ultra-high molecular weight polyvinylidene fluoride can be alone, or blended with other polymers, in final applications and articles.
    Type: Application
    Filed: June 11, 2014
    Publication date: October 2, 2014
    Inventor: Ramin Amin-Sanayei
  • Patent number: 8846812
    Abstract: Disclosed herein is a process for the manufacture of a fluoroelastomer composition containing fluoropolymer fibrils. The process comprises applying shear to a fluoroelastomer gum in a mixer while adding a liquid dispersion of fibrillatable fluoropolymer.
    Type: Grant
    Filed: November 14, 2012
    Date of Patent: September 30, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Christopher J Bish, Kostantinos Kourtakis
  • Patent number: 8835551
    Abstract: Iodine containing amorphous fluoropolymers having at least one fluoropolymer with a cure site, where the fluoropolymer has a Mooney viscosity of 2 or less (ML 1+10) at 100° C. according to ASTM D1646, and a peel strength to a roll mill of 10 dN/cm or less and methods for making such iodine containing amorphous fluoropolymers are described. Articles derived from the cured product of such iodine containing amorphous fluoropolymers are also described. Solutions, dispersions and coatings derived from such iodine containing amorphous fluoropolymers are also described.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: September 16, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Tatsuo Fukushi, Peter J. Scott, Cynthia N. Ferguson, Werner M. A. Grootaert, Denis Duchesne, Yeng Moua, Larry A. Last, Terri A. Shefelbine, Luke M. B. Rodgers
  • Patent number: 8822602
    Abstract: Heterophasic propylene copolymer (HECO) comprising: (a) a polypropylene matrix comprising: (a1) a first propylene homopolymer fraction (PPH1) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >200 to 500 g/10 min, (a2-1) a second propylene homopolymer fraction (PPH2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >30 to ?200 g/10 min or, (a2-2) a second propylene homopolymer fraction (PPH2) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of >5 to ?30 g/10 min and, (a3-1) a third propylene homopolymer fraction (PPH3) with a melt flow rate MFR2 (230° C.) measured according to ISO 1133 in the range of 0.03 to ?5 g/10 min, if the second propylene homopolymer fraction is fraction (a2-1) or, (a3-2) a third propylene homopolymer fraction (PPH3) with a melt flow rate MFR2 (230° C.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: September 2, 2014
    Assignee: Borealis AG
    Inventors: Pauli Leskinen, Petar Doshev, Cornelia Kock
  • Publication number: 20140235783
    Abstract: The present invention aims to provide a composition that forms a film excellent in freeze-thaw resistance, as well as in transparency, weather resistance, adhesion to a base material, and blocking resistance. The present invention relates to a composition comprising polymer particles (A) and a crosslinking agent (B), the polymer particles (A) obtainable by seed polymerization of at least one monomer selected from the group consisting of acrylic acid esters and methacrylic acid esters, an unsaturated carboxylic acid, and a hydrolyzable silyl group-containing monomer in the presence of fluoropolymer particles as seed particles, and the crosslinking agent (B) having at least one group selected from the group consisting of aziridine, carbodiimide, and oxazoline groups.
    Type: Application
    Filed: October 1, 2012
    Publication date: August 21, 2014
    Inventors: Mayumi Iida, Katsuhiko Imoto, Yoshinari Fukuhara, Shumi Yoshida
  • Patent number: 8796384
    Abstract: Provided is a cross-linkable fluororubber composition capable of giving a fluororubber cross-linked molded article that has excellent mechanical strength and low friction properties. The cross-linkable fluororubber composition includes a coagulum obtained by co-coagulating a fluororubber (A) and a fluororesin (B).
    Type: Grant
    Filed: July 2, 2010
    Date of Patent: August 5, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Kouhei Takemura, Tomihiko Yanagiguchi
  • Publication number: 20140213730
    Abstract: The invention pertains to a process for cryogenic milling mixtures of (per)fluoroelastomers and semicrystalline thermoplastic VDF polymers, and to free-flowing micronized pellets obtainable therefrom, said micronized pellets advantageously yielding, after extrusion and compounding, excellent mechanical properties, even improved over those of base fluoroelastomer matrix.
    Type: Application
    Filed: August 9, 2012
    Publication date: July 31, 2014
    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Liubov Chernysheva, Giovanni Comino, Giulio Brinati
  • Publication number: 20140205757
    Abstract: Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (?m), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processible fluoropolymer (MPF), such as perfluoromethylvinvyl ether (MFA), fluorinated ethylene propylene (FEP), or perfluoropropylvinvyl ether (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (?m).
    Type: Application
    Filed: March 24, 2014
    Publication date: July 24, 2014
    Applicant: WHITFORD CORPORATION
    Inventors: Leonard W. Harvey, Michael Coates, Julie K. Wright
  • Patent number: 8785560
    Abstract: Process for reducing thermally induced discoloration of fluoropolymer resin produced by polymerizing fluoromonomer in an aqueous dispersion medium to form aqueous fluoropolymer dispersion and isolating said fluoropolymer from the aqueous medium by separating fluoropolymer resin in wet form from the aqueous medium and drying to produce fluoropolymer resin in dry form. The process comprises: pretreating the aqueous fluoropolymer dispersion and/or the fluoropolymer resin in wet or dry form; and exposing the fluoropolymer resin in dry form to fluorine.
    Type: Grant
    Filed: May 2, 2013
    Date of Patent: July 22, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Paul Douglas Brothers, Gregory Allen Chapman, Subhash Vishnu Gangal
  • Publication number: 20140178686
    Abstract: A fiber is disclosed having a central axis or spline and a major outer surface, the fiber made of a base material and poly(vinylidene fluoride), the proportion of base material to poly(vinylidene fluoride) being greater towards the central axis or spline of the fiber than at the major outer surface of the fiber. The base material may be selected from the group consisting of polyethylene, polypropylene and nylon. The fiber has a surface roughness.
    Type: Application
    Filed: December 11, 2013
    Publication date: June 26, 2014
    Applicant: POLYSTEEL ATLANTIC LIMITED
    Inventors: Dean Paul Forgeron, Shannon Marie O'Connell
  • Patent number: 8754176
    Abstract: The present invention provides a low-molecular weight polytetrafluoroethylene powder that, when used as an additive in a coating material, etc., can form a coating with excellent texture and gliding properties, while also improving dispersibility and viscosity; and a production process therefor. The present invention is a process for producing a low-molecular weight polytetrafluoroethylene powder, the process comprising: an emulsion polymerization step of polymerizing at least tetrafluoroethylene in the presence of a polymerization initiator and an aqueous medium to produce emulsified particles thereof; an agglomeration step of agglomerating the emulsified particles to form an agglomerated powder thereof; and a suspension polymerization step of polymerizing at least tetrafluoroethylene in the presence of the agglomerated powder, a polymerization initiator, and an aqueous medium.
    Type: Grant
    Filed: March 31, 2010
    Date of Patent: June 17, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Taku Yamanaka, Masayuki Tsuji, Shunji Kasai, Yasuhiko Sawada
  • Patent number: 8742015
    Abstract: The objective of the present invention is to provide a thermoplastic resin composition having an excellent balance of chemical resistance, heat resistance and impact resistance and a molded article comprising this thermoplastic resin composition. The present thermoplastic resin composition comprises a rubber-reinforced resin, an ethylene•(meth)acrylic acid ester•carbon monoxide copolymer, and polytetrafluoroethylene, and contents of ethylene•(meth)acrylic acid ester•carbon monoxide copolymer and polytetrafluoroethylene are respectively from 0.5 to 20 parts by weight and from 0.01 to 5 parts by weight, with respect to 100 parts by weight of the rubber-reinforced resin. A modified polyolefin resin may be contained.
    Type: Grant
    Filed: July 11, 2007
    Date of Patent: June 3, 2014
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Keigo Higaki, Yasuhiko Itou
  • Patent number: 8710149
    Abstract: This invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic hydrogen-containing fluoropolymer [polymer (A)]; and from 0.1 to 10% by weight of (A) of at least one per(halo)fluoropolymer chosen among tetrafluoroethylene (TFE) copolymers having a dynamic viscosity at a shear rate of 1 rad sec?1 of less than 10 Pa sec at a temperature of 280° C. [polymer (B)]. The addition of a TFE copolymer [polymer (B)] of low melt viscosity advantageously enables improvement of rheological behavior of thermoplastic hydrogen-containing fluoropolymer (A), making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the invention are a process for manufacturing said thermoplastic fluoropolymer composition and the articles, such as shaped articles, films, cable sheathing, pipes, flexible pipes, hollow bodies comprising said thermoplastic fluoropolymer composition.
    Type: Grant
    Filed: April 23, 2007
    Date of Patent: April 29, 2014
    Assignee: Solvay Solexis S.p.A.
    Inventors: Julio Abusleme, Alessio Marrani
  • Patent number: 8691344
    Abstract: Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (?m), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processible fluoropolymer (MPF), such as methylfluoroalkoxy (MFA), fluorinated ethylene propylene (FEP), or perfluoroalkoxy (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (?m).
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: April 8, 2014
    Assignee: Whitford Corporation
    Inventors: Leonard W. Harvey, Michael Coates, Julie K. Wright
  • Patent number: 8669336
    Abstract: The invention relates to a coating composition comprising short chain fluorinated acrylates and to the use of short chain fluorinated acrylates as levelling agents for pigmented and unpigmented coating compositions. The coating composition comprises a) a film forming binder resin, and b) a copolymer made by controlled polymerization or by conventional radical polymerization comprising a monomer (M1x) selected from unsaturated monomers out of the group of (meth)acrylates, styrenic monomers or (meth)acrylamides whereby the copolymer contains at least >30 wt % (meth)acrylates; and a monomer (M2y) selected from C1-C4-fluoralkyl(meth)acrylates; x denotes the total number of monomers M1 within the structural element (M1x): x>5, preferred, 10-1000, most preferred, 10-500; y denotes the total number of monomers M2 within the structural element (M2y): y>1, preferred, 2-20, most preferred 2-10; c) optional other conventional coating components and/or additives.
    Type: Grant
    Filed: February 3, 2009
    Date of Patent: March 11, 2014
    Assignee: BASF SE
    Inventors: Andreas Möck, Ralf Knischka, Clemens Auschra
  • Publication number: 20140066573
    Abstract: Provided is a polymer preparing method. By additionally inputting a catalytic reducing agent that reduces an inactivated metal complex compound catalyst to an activated metal complex compound catalyst, a polymer polymerized at a high conversion ratio of a monomer can be provided.
    Type: Application
    Filed: November 6, 2013
    Publication date: March 6, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Su Jeong KIM, Jeong Ae YOON
  • Patent number: 8653213
    Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Compositions that include perfluorohexyl(meth)acrylate and a branched or high Tg monomer are provided as are articles coated with the polymerization product of the composition. Methods are also provided for forming hydrophobic coatings on articles.
    Type: Grant
    Filed: August 16, 2011
    Date of Patent: February 18, 2014
    Assignee: Cytonix, LLC
    Inventor: James F Brown
  • Patent number: 8648147
    Abstract: Heat aging of the composition comprising melt-fabricable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, the alkyl containing 1 to 5 carbon atoms and melt flowable polytetrafluoroethylene is effective to cause thermal transformation of the composition in the solid state, which is epitaxial co-crystallization of the polymer components of the composition, and other valuable changes, such as increased continuous use temperature.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: February 11, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Jacob Lahijani
  • Publication number: 20140034109
    Abstract: A resin composition, a multi-layered film, a backsheet for photovoltaic modules, a method thereof, and a photovoltaic module are provided. The multi-layered film including a coating layer including a fluorine-based polymer has an excellent durability and weather resistance, and also exhibits high interfacial adhesive strength to a substrate since the multi-layered film is formed by coating a cured product of the resin composition including the fluorine-based polymer, an acrylic polymer including a thermosetting functional group, and a heat-curing agent on the substrate. In addition, drying can be performed at a low temperature during the manufacture of the multi-layered film so that the manufacturing costs can be decreased, productivity can be increased, and the deterioration of the product due to heat modification, heat shock, and the like, can be prevented. The multi-layered film can be effectively used as a backsheet for various photovoltaic modules.
    Type: Application
    Filed: October 11, 2013
    Publication date: February 6, 2014
    Applicant: LG CHEM, LTD
    Inventors: Hyun Cheol KIM, Hyun Seong KO
  • Patent number: 8642699
    Abstract: A fluidity improver for a PC resin that improves the melt fluidity during molding without impairing the excellent properties of the PC resin, and also yields a molded product in which external appearance defects are unlikely. The fluidity improver for an aromatic polycarbonate resin according to the present invention is including a first polymer obtained by polymerizing 0.5 to 99.5 parts by mass of a monomer first mixture including 0.5 to 99.5% by mass of styrene and 0.5 to 99.5% by mass of phenyl (meth)acrylates, in the presence of a second polymer obtained by polymerizing 0.5 to 99.5 parts by mass of a second monomer mixture containing 0.5 to 50% by mass of ?-methylstyrene, 0.5 to 99% by mass of styrene and 0.5 to 99% by mass of phenyl (meth)acrylates, wherein the combined total of both monomer mixtures is 100 parts by mass.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: February 4, 2014
    Assignees: Mitsubishi Rayon Co., Ltd., Koito Manufacturing Co., Ltd.
    Inventors: Shinji Matsuoka, Hidetaka Anma, Kazuyuki Miyake
  • Patent number: 8642702
    Abstract: The invention pertains to a thermoplastic VDF polymer composition comprising: at least one thermoplastic vinylidene fluoride (VDF) polymer comprising at least 85% by moles of recurring units derived from VDF; and at least one ethylene/chlorotrifluoroethylene (ECTFE) polymer, wherein said ECTFE polymer possesses a melting point of less than 210° C. and it is comprised in an amount of from 0.1 to 20% wt with respect to the total weight of VDF polymer and ECTFE polymer. The invention also pertains to a process for making the VDF polymer and to the uses thereof for manufacturing films, in particular transparent films.
    Type: Grant
    Filed: April 26, 2011
    Date of Patent: February 4, 2014
    Assignee: Solvay Specialty Polymers Italy S.p.A.
    Inventors: Julio A. Abusleme, Stefano Mortara
  • Patent number: 8642159
    Abstract: Provided is a film having high crystallinity, transparency, and surface smoothness, a lamination of the film, a sheet of the film, and a laminated body. A film contains vinylidene fluoride-based resin (A) and acrylic-based resin (B). The film has at least one surface with arithmetic mean roughness of 0.1 to 20 nm. The at least one surface has crystal fusion heat of 18 to 40 J/g and a haze value of 3.5 or less, the crystal fusion heat being measured using a differential scanning calorimeter.
    Type: Grant
    Filed: May 13, 2011
    Date of Patent: February 4, 2014
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yuhei Konokawa, Yoshinori Abe
  • Publication number: 20140031475
    Abstract: Provided is a seal ring manufactured from a mixture containing a soft resin including at least one of a thermoplastic elastomer and a dynamic crosslinked resin, and a hard resin including a thermoplastic resin. With this seal ring, the adhesion to the inner peripheral surface of a housing can be maintained in a no-load state where a hydraulic pressure is not generated even after use as a one-piece type for an extended period of time and oil leakage can be effectively prevented. The mixture constituting the seal ring preferably has a compression permanent deformation of 95% or lower after immersion in an automatic transmission fluid at 150° C. for 100 hours.
    Type: Application
    Filed: January 13, 2012
    Publication date: January 30, 2014
    Applicant: KABUSHIKI KAISHA RIKEN
    Inventors: Hiroshi Ito, Akihiro Oowada
  • Patent number: 8637608
    Abstract: Fluoropolymers containing one or more azide group wherein the azide group is not a sulfonyl-azide group and processes of preparing them.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: January 28, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Klaus Hintzer, Michael Juergens, Harald Kaspar, Kai H. Lochhaas, Oleg Shyshkov, Andre Streiter, Tilman C. Zipplies, Sabine H. G. Beuermann, Muhammad Imran ul-haq
  • Patent number: 8632856
    Abstract: Highly water repellent coated articles may be made by applying to a substrate a coating having dispersed therein or sprinkled thereon partially or fully fluorinated polymer microparticles. The coating includes a partially fluorinated hexafluoropropylene copolymer binder in a nonfluorinated solvent that dissolves the binder and does not dissolve the microparticles. The coating is heated sufficiently to bond the microparticles to the binder but not so much as to cause the receding water contact angle for the coating to fall below 80°.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: January 21, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Naiyong Jing, Lisa P. Chen
  • Patent number: 8623963
    Abstract: High purity perfluoroelastomer composites and processes for producing the same are provided. High purity composites may be formed from compositions comprising a crosslinkable fluoroelastomer terpolymer of TFE, PAVE, and CNVE, and functionalized PTFE, which may be crosslinked to form crosslinked composites having low metal content and low compression set. Emulsion mixtures for forming the high purity composites are also provided.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: January 7, 2014
    Assignee: W. L. Gore & Associates, Inc.
    Inventors: Ping Xu, Jack Hegenbarth
  • Publication number: 20140005335
    Abstract: A process for the preparation of a fluoroolefin polymer from an azeotropic mixture of monomers having a constant composition, the process including the step of: contacting in a reaction zone: (i) an initiator; and (ii) an azeotropic mixture of monomers including at least one fluoroolefin and, optionally, at least one ethylenically unsaturated comonomer capable of copolymerizing therewith; wherein the contacting is carried out at a temperature, pressure and length of time sufficient to produce the fluoroolefin polymer.
    Type: Application
    Filed: September 5, 2013
    Publication date: January 2, 2014
    Applicant: Honeywell International Inc.
    Inventors: George J. Samuels, Gregory J. Shafer, Hang T. Pham
  • Publication number: 20140005334
    Abstract: It is provided a polymer blend that contains a polymer formed of fluorinated monomers and hydrocarbon monomers and another biocompatible polymer.
    Type: Application
    Filed: August 9, 2013
    Publication date: January 2, 2014
    Applicant: Abbott Cardiovascular Systems Inc.
    Inventor: Stephen D. Pacetti
  • Patent number: 8609756
    Abstract: Polymeric composition based on a PVDF homopolymer and a thermoplastic fluorocopolymer Polymeric composition based on a PVDF homopolymer and a thermoplastic fluoropolymer offering an improved toughness/processability compromise, possessing an apparent melt viscosity not exceeding 60 000 Pa·s at a shear rate of 1 s?1, a ductile-brittle transition temperature below +5° C. and a weight loss in air at 150° C. of 5% or less. Pipes and fashioned articles prepared from this composition.
    Type: Grant
    Filed: October 20, 2005
    Date of Patent: December 17, 2013
    Assignee: Solvay (Societe Anonyme)
    Inventors: Thierry Baert, Bernard Goffaux, Vincent Bodart, Stephane Heuschling
  • Publication number: 20130330392
    Abstract: It is provided an implantable device including a polymer blend that contains a polymer formed of fluorinated monomers and hydrocarbon monomers and another biocompatible polymer.
    Type: Application
    Filed: August 14, 2013
    Publication date: December 12, 2013
    Applicant: Abbott Cardiovascular Systems Inc.
    Inventor: Stephen D. Pacetti
  • Patent number: 8603411
    Abstract: A seal is formed of a material including a crosslinked fluoropolymer. The seal substantially prevents leaks in a high pressure pump.
    Type: Grant
    Filed: December 10, 2012
    Date of Patent: December 10, 2013
    Assignee: Saint-Gobain Performance Plastics Corporation
    Inventors: Robert Thomas Racicot, Jon M. Lenhert, Karthik Vaideeswaran, Christopher M. Comeaux
  • Patent number: 8586673
    Abstract: Polymer composition (C) containing (i) a poly(aryl ether sulfone) material (M12) composed of a poly(biphenyl ether sulfone) (P1) and, optionally in addition, a poly(aryl ether sulfone) (P2) containing recurring units with arylene groups linked to each other via a secondary, ternary or quaternary carbon atom, and (ii) a per(halo)fluoropolymer material (M34), composed of a per(halo)fluoropolymer (P3) of which at least 2.0 wt. % of the recurring units are derived from a per(halo)fluoromonomer other than tetrafluoroethylene, and a polytetrafluoroethylene (P4). Shaped article, especially aircraft interior component, comprising the polymer composition (C).
    Type: Grant
    Filed: May 7, 2009
    Date of Patent: November 19, 2013
    Assignee: Solvay Advanced Polymers, L.L.C.
    Inventor: Shari A. Weinberg
  • Patent number: 8586677
    Abstract: Blended fluoropolymer compositions that, in one exemplary application, may be applied as a coating to a substrate and, optionally, may be applied to a substrate that has been previously coated with a primer or basecoat and/or a midcoat. In one embodiment, the composition is a blend of at least one high molecular weight trace modified polytetrafluoroethyelene (TMHPTFE) and at least one melt-processible fluoropolymer (MPF). After being applied to the substrate, optionally over a primer or basecoat and/or midcoat, and then cured, the present compositions form coatings that demonstrate improved abrasion resistance and/or improved release characteristics and/or increased translucency/transparency and/or improved impermeability. The present compositions may also be used to produce films having a high degree of clarity and impermeability. The present compositions in powder form may be melt or paste extruded to form articles with improved impermeability.
    Type: Grant
    Filed: April 11, 2011
    Date of Patent: November 19, 2013
    Assignee: Whitford Corporation
    Inventors: Leonard W. Harvey, Helen L. Brain, Susan J. Roberts-Bleming, Lawrence D. Leech, Thomas J. Bate
  • Patent number: 8580892
    Abstract: A rubber composition has sufficient resistance to degradation and swelling caused by a liquid such as a water-soluble coolant and also is capable of having sufficient resistance to ozone. The rubber composition contains a fluororubber not having a vinylidene fluoride structure, a nitrile rubber, a fluorine-based oil and a peroxide vulcanizing agent.
    Type: Grant
    Filed: November 16, 2010
    Date of Patent: November 12, 2013
    Assignee: OMRON Corporation
    Inventors: Kazuyuki Tsukimori, Junryo Nariai, Tsutomu Inuyama, Shinji Mizuno
  • Patent number: 8575273
    Abstract: Certain embodiments described herein are directed to silane coupling agents that may be used, for example, to covalently couple a polymer to a filler. In some examples, devices that include the polymer-silane coupling agent-filler compositions are also described.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: November 5, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Huilin Tu, Agathe Robisson, Julien Ramier
  • Patent number: 8569413
    Abstract: An aqueous coating composition having excellent coating adhesion, workability, heat resistance and chemical resistance, and has an object to provide an aqueous coating composition for sealing, which is suitable for members to be screwed in. An aqueous coating composition including: as main components, component (A) an ethylene-vinyl acetate copolymer resin emulsion and component (B) two or more PTFE resin powders having different particle diameters, in which 35 to 80 parts by mass of water is contained on the basis of 100 parts by mass of the total of (A) and (B).
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: October 29, 2013
    Assignee: Three Bond Co., Ltd.
    Inventors: Hidenori Kanazawa, Naoki Satou
  • Patent number: 8563660
    Abstract: [Object] To provide a fluororubber-based sealing material which is excellent in sealing properties under high/low temperature load and is capable of sealing at a temperature of not higher than ?40° C. even when gas oil (diesel fuel) is used. [Means for Solving] A fluororubber-based sealing material obtained by crosslinking a composition for a fluororubber-based sealing material, said composition comprising 100 parts by weight of a fluorine-containing copolymer which contains 64 to 69% by weight of fluorine, has a crosslinking site derived from a bromine-containing compound and/or an iodine-containing compound and is capable of being crosslinked by a peroxide, 0.
    Type: Grant
    Filed: April 7, 2009
    Date of Patent: October 22, 2013
    Assignee: Nok Corporation
    Inventor: Hiroyuki Sano
  • Publication number: 20130267621
    Abstract: Provided is a material that can be easily biaxially oriented, homogeneously stretched even with a high draw ratio, and formed into a PTFE porous membrane with low pressure loss. The present invention relates to a polytetrafluoroethylene mixture comprising: a fibrillable modified polytetrafluoroethylene; and a fibrillable polytetrafluoroethylene homopolymer, the polytetrafluoroethylene homopolymer having strength at break of 25 N or higher.
    Type: Application
    Filed: December 21, 2011
    Publication date: October 10, 2013
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Yasuhiko Sawada, Shunji Kasai, Taku Yamanaka, Yoshiyuki Shibuya, Kunihiko Inui, Shinichi Chaen
  • Publication number: 20130264522
    Abstract: The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF), and from 0.01% to 5% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (F) comprising end groups having formula —CF2H and/or —CF2CH3 in an amount of at least 30 mmoles per Kg of vinylidene fluoride (VDF) recurring units. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as binders for the manufacture of electrodes or for the manufacture of membranes.
    Type: Application
    Filed: December 13, 2011
    Publication date: October 10, 2013
    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Milena Stanga, Bradley Lane Kent, Alessio Marrani, Giulio Brinati