Solid Polymer Derived From Ethylenic Reactant Containing A Heterocyclic Nitrogen Patents (Class 525/203)
  • Patent number: 4604422
    Abstract: A moldable composition which comprises a novel random N-(brominated or chlorinated phenyl) maleimide-containing copolymer, a thermoplastic resin, preferably, polycarbonate and a flame retardant synergist is disclosed. The molded composition exhibits at least a 94 V-1 classification when tested in accordance with Underwriters Laboratories Inc. Test Method UL94.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: August 5, 1986
    Assignee: Atlantic Richfield Company
    Inventor: Usama E. Younes
  • Patent number: 4568724
    Abstract: A moldable composition comprising a .gamma.-sultone derivative of an ethylene/propylene/substituted methylene norbornene terpolymer and a polymer which comprises recurring units of a vinyl aromatic monomer, a monomer having an active hydrogen with an acidity constant (pKa) within the range of from about 7.5 to about 10.5 and a vinyl pyridine monomer selected from the group consisting of 2-vinyl pyridine and 4-vinyl pyridine is disclosed. Optionally, the polymer comprises recurring units of an ethylenically unsaturated monomer.
    Type: Grant
    Filed: June 28, 1985
    Date of Patent: February 4, 1986
    Assignee: Atlantic Richfield Company
    Inventor: Barry D. Dean
  • Patent number: 4552927
    Abstract: A conducting organic polymer is disclosed consisting of a polypyrrole or an N-substituted analog of pyrrole and a non-nucleophilic polymeric anion. The polymer is formed by electropolymerizing pyrrole from an electrolyte containing a non-nucleophilic polymeric anion and pyrrole.
    Type: Grant
    Filed: September 9, 1983
    Date of Patent: November 12, 1985
    Assignee: Rockwell International Corporation
    Inventor: Leslie F. Warren
  • Patent number: 4539373
    Abstract: Novel thermoplastic polyelectrolyte complexes are disclosed which are the reaction products of (a) a polyanion and (b) a polycation wherein one of the polyanion and polycation contains repeating units derived from a soft monomer. By the selection of said soft monomers and of the cation group present in the polycation, moldable, extrudable polyelectrolyte complexes are obtained.
    Type: Grant
    Filed: July 12, 1982
    Date of Patent: September 3, 1985
    Assignee: The Dow Chemical Company
    Inventors: Inder Mani, Glen L. Gunderman
  • Patent number: 4537831
    Abstract: The binder composition for nonwoven products comprising a vinyl chloride-ethylene copolymer emulsion and up to 25 wt %, based on emulsion solids, of a polyamine containing 5 or 6 member N-heterocyclic moieties prepared by the polymerization of at least one diallylamine of the formula ##STR1## where R is hydrogen or a C.sub.1 -C.sub.4 alkyl group and R' is hydrogen or a methyl group.
    Type: Grant
    Filed: February 22, 1984
    Date of Patent: August 27, 1985
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Frank V. Di Stefano
  • Patent number: 4537601
    Abstract: This invention relates to compositions comprising (1) acrylic-type ester-acrylonitrile copolymers and (2) polymeric polyamines; and to such compositions in combination with organic liquids such as hydrocarbon fluids in which such compositions are effective as antistatic agents.
    Type: Grant
    Filed: October 29, 1984
    Date of Patent: August 27, 1985
    Assignee: Petrolite Corporation
    Inventor: Michael I. Naiman
  • Patent number: 4517333
    Abstract: The present invention relates to viscosification agents for aqueous solutions in which the viscosification agents are mixtures of water soluble polymer backbone containing an anionic comonomer and a copolymer of a water soluble polymer backbone containing a cationic comonomer.
    Type: Grant
    Filed: December 12, 1983
    Date of Patent: May 14, 1985
    Assignee: Exxon Research and Engineering Co.
    Inventors: Robert D. Lundberg, Robert R. Phillips, Dennis G. Peiffer
  • Patent number: 4508883
    Abstract: A flame retarding additive comprising an alternating copolymer of a brominated styrene and N-brominated phenylmaleimide, is blended with a matrix resin to produce molding compositions which when molded exhibit improved flame retarding characteristics. The flame retarding additives of this invention also exhibit non-blooming characteristics.
    Type: Grant
    Filed: April 28, 1983
    Date of Patent: April 2, 1985
    Assignee: Atlantic Richfield Company
    Inventor: Usama E. Younes
  • Patent number: 4499220
    Abstract: Copolymer light stabilizers are provided having at least one 2,2,6,6-tetraalkyl piperidyl group in the molecule and a molecular weight within the range from about 1000 to about 20,000, that are copolymers of a maleic or fumaric acid ester containing a 2,2,6,6-tetraalkyl piperidyl group in the alcohol group of the formula: ##STR1## wherein ##STR2## R.sub.2 is alkyl or R.sub.1 ; X is ##STR3## R.sub.6 is lower alkyl; R.sub.3 is hydrogen or alkyl;R.sub.4 is hydrogen or methyl;R.sub.5 is alkylene;Y is ##STR4## R.sub.7 is alkylene; and at least one monomer selected from the group consisting of aliphatic carboxylic acid vinyl ester having from two to eight carbon atoms; alkyl vinyl ethers having from one to eighteen carbon atoms; triallyl isocyanurate; pinene; and tricyclo-(5.2.1.0.sup.2.6)-decene-3; and synthetic resin compositions having improved light stability comprising per 100 parts by weight of resin from 0.001 to 5 parts by weight of the polymeric light stabilizer.
    Type: Grant
    Filed: May 20, 1982
    Date of Patent: February 12, 1985
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Motonobu Minagawa, Naohiro Kubota, Toshihiro Shibata
  • Patent number: 4497923
    Abstract: The present invention relates to a process for the viscosification of an organic liquid which comprises the steps of forming a first solution of an anionic polymer dissolved in the organic liquid; forming a second solution of a cationic polymer dissolved in the organic liquid; and mixing the first and the second solutions together to form an interpolymer complex of the anionic and cationic polymer in the organic liquid, wherein the organic liquid containing the interpolymer complex has improved viscosification properties. This solution possesses higher viscosity than the mean of the separate viscosities of the starting solutions at relatively low solids content. Moreover, these interpolymer complexes, in hydrocarbon solutions, can be formulated to exhibit shear thickening at increased shear rates. This property is useful in such technological applications as antimisting of the solvent.
    Type: Grant
    Filed: November 2, 1983
    Date of Patent: February 5, 1985
    Assignee: Exxon Research & Engineering Co.
    Inventors: Robert D. Lundberg, Dennis G. Peiffer, Ilan Duvdevani, Robert R. Phillips
  • Patent number: 4491651
    Abstract: This invention relates to compositions comprising (1) acrylic-type ester-acrylonitrile copolymers and (2) polymeric polyamines; and to such compositions in combination with organic liquids such as hydrocarbon fluids in which such compositions are effective as antistatic agents.
    Type: Grant
    Filed: May 17, 1982
    Date of Patent: January 1, 1985
    Assignee: Petrolite Corporation
    Inventor: Michael I. Naiman
  • Patent number: 4490494
    Abstract: Improved dyeability of alpha-monoolefin polymers is obtained by incorporating in the olefin polymer a polymeric dye receptor and a small amount of a carboxylic acid metal salt.
    Type: Grant
    Filed: December 15, 1983
    Date of Patent: December 25, 1984
    Assignee: Phillips Petroleum Company
    Inventor: Robin D. Shropshire
  • Patent number: 4489180
    Abstract: The present invention discloses a class of water soluble complex polymers of relatively low molecular weight, which have been found to be improved drag reducing agents. These complex polymers are a mixture of a cationic copolymer having a water soluble polymer backbone and an anionic copolymer having a water soluble polymer backbone. The solutions of these complex polymers are improved drag reducing agents for aqueous systems at low concentrations (i.e., 10 to 500 ppm) relative to individual solutions of the copolymers which make upon the polymer complex.
    Type: Grant
    Filed: December 12, 1983
    Date of Patent: December 18, 1984
    Assignee: Exxon Research and Engineering Co.
    Inventors: Robert D. Lundberg, Dennis G. Peiffer, Ilan Duvdevani, Ralph M. Kowalik
  • Patent number: 4487900
    Abstract: Polymers of diallyl 4-(2,2,6,6-tetramethyl piperidyl) amines are provided, having a molecular weight within the range from about 800 to about 20,000, and derived from the monomer ##STR1## wherein: R is selected from the group consisting of hydrogen, oxyl, alkyl and hydroxyalkyl having from one to about eighteen carbon atoms; alkylaryl having from seven to about eighteen carbon atoms; epoxy alkyl having from three to about eighteen carbon atoms and acyl having from two to about eighteen carbon atoms, as well as stabilized synthetic resin compositions having an improved resistance to deterioration by light and containing such a polymer.
    Type: Grant
    Filed: September 9, 1983
    Date of Patent: December 11, 1984
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Yutaka Nakahara, Ryoji Kimura
  • Patent number: 4487887
    Abstract: Polymers of diallyl amino-4-(2,2,6,6-tetramethyl piperidyl) carboxylic acid esters and amides are provided, having a molecular weight within the range from about 800 to about 20,000, and derived from a monomer having the formula: ##STR1## wherein: R is alkylene or alkyleneoxy having from one to about six carbon atoms and m is 0 or 1;R.sub.1 is selected from the group consisting of hydrogen; oxyl; alkyl and hydroxyalkyl having from one to about eighteen carbon atoms; alkylaryl having from seven to about eighteen carbon atoms; epoxy alkyl having from three to about eighteen carbon atoms; and acyl having from two to about eighteen carbon atoms; andY is selected from the group consisting of ##STR2## where R.sub.2 and R.sub.3 are hydrogen or alkyl having from one to about eight carbon atoms and n is 0 or 1;Z is selected from the group consisting of ##STR3## in which R.sub.4, R.sub.5 and R.sub.
    Type: Grant
    Filed: September 9, 1983
    Date of Patent: December 11, 1984
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Yutaka Nakahara, Ryoji Kimura
  • Patent number: 4480063
    Abstract: This invention relates to thermoplastic and/or elastomer blend compositions having a viscosity at 200.degree. C., at 0.73 sec.sup.-1 of about 5000 to about 5.times.10.sup.6 poises, wherein the compositions used for elastomeric articles which include a polymer complex of a neutralized sulfonated polymer and a polymer containing basic nitrogen atoms can also include about 25 to about 150 parts by weight of a nonpolar process oil per 100 parts of the polymer complex and about 50 to 300 parts by weight of a filler per 100 parts of the polymer complex. These blend compositions can be processed on conventional plastic fabrication equipment into polymeric articles having excellent physical properties.
    Type: Grant
    Filed: November 2, 1983
    Date of Patent: October 30, 1984
    Assignee: Exxon Research & Engineering Co.
    Inventors: Robert D. Lundberg, Dennis G. Peiffer, Robert R. Phillips
  • Patent number: 4472463
    Abstract: Non-adhesive activated ("non-AA") polyester cord, or aramid cord, and fabrics made therefrom, may be coated in a two-step process, the first step of which is conventional. In the novel second step, after the cord is conventionally pre-coated in the first step, it is dipped in a R/F-free latex of a diene polymer in which an acrylic resin having a mol wt. in the range from about 100,000 to about 1,000,000 is dispersed. The acrylic resin resin is a copolymer selected from the group consisting of two or more monomers, one of which is (meth)acrylic acid and another is a lower alkyl(meth)acrylic acid ester, the monomers having the configuration ##STR1## wherein, R represents H, methyl, ethyl, Cl or CN, and, X represents hydroxyl (OH), hydroxymethylamino (NHCH.sub.2 OH), or alkoxy (O-alkyl) having from 1 to 4 carbon atoms; and, optionally, in addition the copolymer may include a vinyl aromatic monomer having from 8 to about 18 carbon atoms.
    Type: Grant
    Filed: December 6, 1982
    Date of Patent: September 18, 1984
    Assignee: The B. F. Goodrich Company
    Inventor: Thomas S. Solomon
  • Patent number: 4451617
    Abstract: A miscible polyblend comprising an .alpha., .beta.-ethylencially unsaturated dicarboxylic acid or its anhydride copolymerized with at least one monovinyl-substituted aryl hydrocarbon monomer and an imide derivative of maleic anhydride copolymerized with at least one monovinyl-substituted-aryl hydrocarbon monomer is disclosed.
    Type: Grant
    Filed: August 16, 1982
    Date of Patent: May 29, 1984
    Assignee: Atlantic Richfield Company
    Inventor: Bi L. Khac
  • Patent number: 4413096
    Abstract: .alpha.-Olefin copolymers having recurring structural units of the formula ##STR1## where preferably T is hydrogen, L.sub.1 is hydrogen, L.sub.2 is COOL.sub.3, L.sub.3 is lower alkyl, E is --COO--, G is a hindered amine moiety, a/a+b+c=0.50 to 0.99, b/a+b+c=0 to 0.49 and c/a+b+c=0.01 to 0.50, are useful as light stabilizers for polymeric substrates, particularly polyolefins.
    Type: Grant
    Filed: January 26, 1982
    Date of Patent: November 1, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Frank T. Fu, Roland A. E. Winter
  • Patent number: 4404301
    Abstract: Polymeric light stabilizers are provided having at least one 2,2,6,6-tetraalkyl piperidyl group in the molecule and a molecular weight within the range from about 1000 to about 20,000, that are polymers of an unsaturated carboxylic acid ester selected from the group consisting of unsaturated cycloaliphatic mono-, di, and tri-carboxylic acid esters having from seven to about thirty carbon atoms; unsaturated branched-chain aliphatic di- and tri-carboxylic acid esters having from four to about thirty carbon atoms; sorbic acid ester, 3,8-nonadienyl acid ester, oleic acid ester, linolenic acid ester and ricinoleic acid ester; or copolymers of at least one thereof with another copolymerizable unsaturated monomer; and synthetic resin compositions having improved light stability comprising per 100 parts by weight of resin from 0.001 to 10 parts by weight of the polymeric light stabilizer.
    Type: Grant
    Filed: April 22, 1982
    Date of Patent: September 13, 1983
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Naohiro Kubota, Toshihiro Shibata, Ryozo Arata
  • Patent number: 4400486
    Abstract: An acrylic adhesive composition comprising an acrylic polymer as a base resin and a modified cyclopentadiene resin having a softening point of at least 60.degree. C. obtained by copolymerizing (a) 85 to 50% by weight of a cyclopentadiene monomer and (b) 15 to 50% by weight of a polar vinyl monomer or a hydrogenation product of said cyclopentadiene resin as a tackifier.
    Type: Grant
    Filed: August 18, 1982
    Date of Patent: August 23, 1983
    Assignee: Nippon Zeon Co. Ltd.
    Inventors: Riso Iwata, Akira Wada
  • Patent number: 4373008
    Abstract: The present invention is concerned with, as a hydrocurable composition, a mixture of an oxazolidine-functional polymer and a compound of a monomeric or polymeric character having a plurality of acryloxy groups. The first-mentioned polymer contains a plurality of pendant groups containing 2,2,-dialkyl oxazolidine groups. The mixture of these two components can be stored under anhydrous conditions in a closed container without co-reaction so that a one-pot or one-package composition can be made up with many conventional ingredients of coating compositions other than aqueous components and stored without gelling until the time for application when the composition may be applied at ambient temperature and humidity whereupon reaction between the main two components mentioned above occurs in the film deposited and the film set up.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: February 8, 1983
    Assignee: Rohm and Haas Company
    Inventors: William D. Emmons, Wayne E. Feely
  • Patent number: 4356287
    Abstract: Polymers of the following monomer ##STR1## wherein R and/or R.sup.1 contains a polymerizable double bond are disclosed as light stabilizers for polymers.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: October 26, 1982
    Assignee: American Cyanamid Company
    Inventors: Frank F. Loffelman, Thomas E. Brady
  • Patent number: 4347339
    Abstract: Water soluble cationic block copolymer comprising at least one first polymer block selected from a first class consisting of polymeric species having amino groups in the polymeric structure thereof wherein a majority of said amino groups are quaternary, and at least one second polymer block selected from a second class consisting of polymer species having amino groups in the polymeric structure thereof wherein a majority of said amino groups are other than quaternary amino acids. Also included are the methods of making these copolymers.
    Type: Grant
    Filed: May 8, 1981
    Date of Patent: August 31, 1982
    Assignee: Nalco Chemical Company
    Inventors: Jan E. Boevink, Arthur P. Derrick, John A. Moodie
  • Patent number: 4311820
    Abstract: Homopolymers and copolymers of vinyl ethers of the formula I ##STR1## in which R is hydrogen or methyl and R.sup.1 is hydrogen, C.sub.1 -C.sub.8 -alkyl, benzyl, allyl or C.sub.1 -C.sub.2 -acyl, are effective stabilizers for plastics, especially to protect them against photochemical degradation. The monomeric vinyl ethers of the formula I are novel compounds, which can be prepared from the corresponding piperidinols by vinylation by means of acetylene or by transvinylation by means of vinyl ethers or vinyl esters.
    Type: Grant
    Filed: February 4, 1980
    Date of Patent: January 19, 1982
    Assignee: Ciba-Geigy Corporation
    Inventor: Erwin Nikles
  • Patent number: 4308362
    Abstract: The invention relates to copolymers of polyalkyl piperidines which are substituted by a polymerizable group and which have the formula ##STR1## with olefinic comonomers such as ethylene, styrene, vinyl acetate, acrylates or methacrylates. The copolymers which have a molecular weight of from 1,000 to 10,000 are used as light stabilizers for synthetic polymers which do not migrate to the surface of the polymers.
    Type: Grant
    Filed: May 19, 1980
    Date of Patent: December 29, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hartmut Wiezer, Gerhard Pfahler, Norbert Mayer
  • Patent number: 4299867
    Abstract: The present invention is concerned with, as a hydrocurable composition, a mixture of an oxazolidine-functional polymer and a compound of a monomeric or polymeric character having a plurality of acryloxy groups. The first-mentioned polymer contains a plurality of pendant groups containing 2,2-dialkyl oxazolidine groups. The mixture of these two components can be stored under anhydrous conditions in a closed container without co-reaction so that a one-pot or one-package composition can be made up with many conventional ingredients of coating compositions other than aqueous components and stored without gelling until the time for application when the composition may be applied at ambient temperature and humidity whereupon reaction between the main two components mentioned above occurs in the film deposited and the film set up.
    Type: Grant
    Filed: January 30, 1980
    Date of Patent: November 10, 1981
    Assignee: Rohm and Haas Company
    Inventors: William D. Emmons, Wayne E. Feely
  • Patent number: 4292237
    Abstract: An ultraviolet light sensitive polymer composition wherein resistance to photodegradation is enhanced by the inclusion therein of a stabilizer polymer having structural units corresponding to the following formula ##STR1## wherein R.sub.a, R.sub.b, and R.sub.
    Type: Grant
    Filed: November 14, 1977
    Date of Patent: September 29, 1981
    Assignee: The B. F. Goodrich Company
    Inventors: Robert W. Layer, Pyong N. Son
  • Patent number: 4229498
    Abstract: A light-polarizing film comprising a polymer mixture containing a polymer having polyene chains formed by partial dehydrohalogenation of a halogenated vinyl polymer or a halogenated vinylidene polymer and one or more of the polymers selected from the group consisting of acrylate polymers and methacrylate polymers. Said light-polarizing film has excellent heat stability as well as humidity resistance and is useful in various fields including liquid crystal device, optical device, etc.
    Type: Grant
    Filed: March 29, 1979
    Date of Patent: October 21, 1980
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hajime Suzuki, Hiroyuki Hamada, Rinjiro Ichikawa
  • Patent number: 4226953
    Abstract: Thermoplastic compositions are described comprising blends of styrene-acrylonitrile resin and nitrile rubber of high gel content.
    Type: Grant
    Filed: February 22, 1979
    Date of Patent: October 7, 1980
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Raman P. Patel
  • Patent number: 4211691
    Abstract: A thermoplastic powder coating composition is provided, comprising particles of polymeric material comprising a mixture of polymer (A) and polymer (B),polymer (A) and polymer (B) being selected from the group consisting of polymer of ethylenically unsaturated monomer, alkyd, polyester, and polyester urethane,one of either polymer (A) or polymer (B) containing an average of about 0.9-1.1 reactive groups per molecule and the other of polymer (A) or polymer (B) containing an average of 1-10 reactive groups per molecule,the reactive groups on polymer (A) being coreactive in a condensation reaction with the reactive groups on polymer (B), andpolymer (A) and polymer (B) are compatible.
    Type: Grant
    Filed: November 6, 1978
    Date of Patent: July 8, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Emerson B. FitzGerald, Walter C. Meyer
  • Patent number: 4199491
    Abstract: Since their surfaces are inactive, polyolefin resins are difficult to plate. A plating method utilizing sensitizing-activation of the surface has been used for plating polyolefin resins. Many attempts have been made to improve the plating properties of the surfaces of polyolefin resins, for example, a mechanical method, a method employing a solvent, a method of coating other types of resins on the surface, etc. As methods modifying the plastics themselves, there are several; a method of introducing polar radicals by graft polymerization, etc., a method of introducing atactic polypropylene or block copolymer of polypropylene and polyethylene, a method of mixing rubber or a copolymer of ethylene and vinyl acetate, a method of mixing in an inorganic filler, etc.
    Type: Grant
    Filed: December 4, 1978
    Date of Patent: April 22, 1980
    Assignee: Idemitsu Kosan Company Limited
    Inventors: Akio Inayoshi, Hitomi Tomari, Kikuo Nagatoshi, Yasuo Hata
  • Patent number: 4194999
    Abstract: A powdery rubber is produced by mixing an anionic or nonionic rubber latex with an aqueous solution of an anionic water soluble macro-molecular compound which is dissociated in water to give negative charge; adjusting the pH to an acidic condition; adding to the aqueous solution either a cationic polymer which is water soluble in an acidic condition or a cationic surfactant which causes a coacervation with the anionic water soluble macromolecular compound in an acidic condition to separate the rubber particles from the rubber latex under coacervation and adding an emulsion of a synthetic resin having a glass transition temperature higher than 30.degree. C. to the rubber particles at a ratio of 1 to 50 wt.% (as a solid content) to the solid content of the rubber latex and dehydrating and drying the resulting powdery rubber.
    Type: Grant
    Filed: November 7, 1977
    Date of Patent: March 25, 1980
    Assignee: Toyo Soda Manufacturing Company, Ltd.
    Inventors: Takao Hayashi, Yasuhiro Sakanaka, Akihiko Shimizu
  • Patent number: 4188351
    Abstract: This invention relates to heterogeneous elastomeric blends having improved rheological properties of a major portion of a neutralized sulfonated elastomeric polymer with a minor portion of a polystyrene thermoplastic resin or a neutralized sulfonated polystyrene resin and mixtures thereof. Both the sulfonated elastomeric polymer and the sulfonated thermoplastic resin have about 0.2 to about 10.0 mole percent of SO.sub.3 H groups, at least 90% of which are neutralized with an organic amine.
    Type: Grant
    Filed: October 11, 1978
    Date of Patent: February 12, 1980
    Assignee: Exxon Research & Engineering Co.
    Inventor: Chan I. Chung