Solid Polymer Derived From Reactant Containing A Phenolic Group Patents (Class 525/219)
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Patent number: 11417909Abstract: A solid electrolyte composition for a lithium secondary battery including a fluorine-based polymer having grafted thereon a unit comprising alkylene oxide group and a crosslinkable functional group. The polymer may be formed by a process including grafting a monomer on a fluorine-based polymer, where the monomer includes alkylene oxide group and a crosslinkable functional group. Also disclosed is a solid electrolyte for a secondary battery formed by thermally curing the composition. By graft copolymerizing a monomer including alkylene oxide group and a crosslinkable functional group on a fluorine-based polymer having high lithium ion conductivity, the solid electrolyte is capable of providing a solid electrolyte for a secondary battery having significantly enhanced solid electrolyte ion conductivity and electrochemical stability.Type: GrantFiled: July 20, 2018Date of Patent: August 16, 2022Assignee: LG ENERGY SOLUTION, LTD.Inventors: Sujee Kwon, Jeongae Yoon, Sung Soo Yoon, Kyung Oh Kim, Jonghyun Chae, Yeonju Lee, Daeil Kim, Lucia Kim, Jongheon Kwak
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Publication number: 20140341524Abstract: A coating composition including a reinforcing agent. The coating composition may include one or more radiation-curable monofunctional monomers, one or more radiation-curable multifunctional monomers or oligomers, a photoinitiator, and a reinforcing agent. The monofunctional monomers, multifunctional monomers, and multifunctional oligomers may include acrylate groups. The reinforcing agent may be an acrylic co-polymer that includes two or more repeat units. At least one of the repeat units includes chemical groups that enable self-association of the acrylic co-polymer. Self-association of the acrylic co-polymer may improve the tensile strength of coatings formed from the coating compositions.Type: ApplicationFiled: April 9, 2014Publication date: November 20, 2014Applicant: Corning IncorporatedInventors: Dana Craig Bookbinder, Michelle Dawn Fabian, Kevin Robert McCarthy, Weijun Niu, David Neal Schissel, Michael James Winningham
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Publication number: 20140161993Abstract: Disclosed therein are an acrylate compound having a photoreactive group, a photoreactive acrylate polymer, and a photo-alignment layer comprising the same that not only have excellences in alignment properties and alignment rate and readiness for change in the alignment direction based on the polarization direction of radiation but also exhibit a high solubility to organic solvents and good workability.Type: ApplicationFiled: November 29, 2013Publication date: June 12, 2014Applicant: LG CHEM, LTD.Inventors: Dong-Woo Yoo, Sung-Ho Chun, Dai-Seung Choi
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Patent number: 8729187Abstract: It is an object of the present invention to provide (1) a copolymer for a cured product that is satisfactory in properties, such as adhesion properties, as a chip stacking adhesive or the like. The present invention is a copolymer comprising repeating units represented by formula (I), formula (II), and formula (III), (wherein R1, R2, and R3 each independently represent a hydrogen atom or a methyl group, R4 represents an alkyl group or a cycloalkyl group, R5 represents a hydrogen atom or a C1 to C6 alkyl group, m, n, and k represent a molar ratio of the respective repeating units, m represents a positive number of 0 or more and less than 1, n and k each independently represent a positive number, and satisfy a relation of m+n+k=1), and having a weight-average molecular weight in the range of 50,000 to 200,000.Type: GrantFiled: August 4, 2010Date of Patent: May 20, 2014Assignee: Nippon Soda Co., Ltd.Inventors: Eiji Takahashi, Shinji Marumo, Gou Mishima
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Patent number: 8609772Abstract: A film comprising one or more propylene-based polymers, one or more hydrocarbon resins, and one or more polyolefin additives provides enhanced mechanical and elastic properties compared to the neat propylene-based polymer. The propylene-based polymer may have (i) 60 wt % or more units derived from propylene; and (ii) crystallinity of from 0.25% to 40%, resulting from isotactically arranged propylene-derived sequences. The hydrocarbon resin may have a glass transition temperature greater than 20° C. The polyolefin additive may have a crystallinity greater than the crystallinity of the propylene-based polymer. Methods for making and using the films are also described.Type: GrantFiled: March 31, 2011Date of Patent: December 17, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventor: Michael Glenn Williams
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Publication number: 20130324635Abstract: A dental curable composition includes: a radically polymerizable monomer; a polymerization initiator; and a hyperbranched polymer, in which the hyperbranched polymer includes a unit structure represented by the general formula (I) and unit structures represented by the general formula (IIA) and/or the general formula (IIB) (in the general formula (I), A represents a single bond for bonding C and R1, >C?O, —O—, or —COO—, R1 represents a divalent saturated aliphatic hydrocarbon group or a divalent aromatic hydrocarbon group, and R2 represents a hydrogen atom or a methyl group; and in the general formula (IIA) and the general formula (IIB), R3, R4, and R5 each represent a hydrogen atom, an alkyl group, an alkoxycarbonyl group, an aryl group, or a cyano group, and R6 represents an alkylene group).Type: ApplicationFiled: February 10, 2012Publication date: December 5, 2013Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Tomonao Shimizu, Tatsuya Yamazaki, Hideki Kazama, Hironobu Akizumi
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Patent number: 8568891Abstract: Provided is a thermosetting resin composition which can be used for the production of printed circuit boards, having good dielectric properties in high frequency bands so that transmission loss can be significantly lowered, having excellent heat resistance after moisture absorption and thermal expansion properties, and satisfying peeling strength between the resin composition and metal foil. The present invention relates to a thermosetting resin composition of a semi-IPN composite, comprising (A) a polyphenylene ether, and a prepolymer formed from (B) a chemically unmodified butadiene polymer containing 40% or more of a 1,2-butadiene unit having a 1,2-vinyl group in a side chain of a molecule and (C) a crosslinking agent, in a compatibilized and uncured state; and a resin varnish, a prepreg and a metal clad laminated board using the same.Type: GrantFiled: May 3, 2012Date of Patent: October 29, 2013Assignee: Hitachi Chemical Company, Ltd.Inventors: Yasuyuki Mizuno, Daisuke Fujimoto, Kazutoshi Danjobara, Hikari Murai
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Publication number: 20130215362Abstract: Methods of evaluating birefringence of an adhesive agent, and of designing and producing an adhesive agent using the evaluation method, as well as adhesive agents produced using these methods. A polarizing plate and a liquid crystal display device using the obtained adhesive agent are proposed, as well as methods for producing the same.Type: ApplicationFiled: November 9, 2012Publication date: August 22, 2013Inventors: Yasuhiro Koike, Akihiro Tagaya, Sumihisa Oda, Takeshi Nagakura
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Patent number: 8501870Abstract: Provided is a thermosetting resin composition which can be used for the production of printed circuit boards, having good dielectric properties in high frequency bands so that transmission loss can be significantly lowered, having excellent heat resistance after moisture absorption and thermal expansion properties, and satisfying peeling strength between the resin composition and metal foil. The present invention relates to a thermosetting resin composition of a semi-IPN composite, comprising (A) a polyphenylene ether, and a prepolymer formed from (B) a chemically unmodified butadiene polymer containing 40% or more of a 1,2-butadiene unit having a 1 2,-vinyl group in a side chain of a molecule and (C) a crosslinking agent, in a compatibilized and uncured state; and a resin varnish, a prepreg and a metal clad laminated board using the same.Type: GrantFiled: September 13, 2012Date of Patent: August 6, 2013Assignee: Hitachi Chemical Co., Ltd.Inventors: Yasuyuki Mizuno, Daisuke Fujimoto, Kazutoshi Danjobara, Hikari Murai
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Patent number: 8492485Abstract: Provided is a polycarbonate-based resin composition for sliding use including 0.01 to 1 part by mass of an antioxidant with respect to 100 parts by mass of a polycarbonate-polyorganosiloxane copolymer which has structural units represented by a general formula (A) and structural units represented by a general formula (B), which contains a polyorganosiloxane block moiety containing the structural units represented by the general formula (B) at a content of 1 to 30 mass %, and which has an average repetition number of the structural units represented by the general formula (B) of 110 to 1000. The polycarbonate-based resin composition for sliding use has a specific structure having improved wear resistance, in particular, improved sliding property. Also provided is a molded article using the resin composition, and excellent in wear resistance and sliding property.Type: GrantFiled: July 6, 2009Date of Patent: July 23, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Yasuhiro Ishikawa, Eiji Tamura
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Publication number: 20130005851Abstract: The present invention relates to a unique polymer dispersant mixture to be incorporated into a carbon black ink formulation. More particularly, the a polymeric dispersant mixture consists of a first polymer dispersant having moieties of methacrylic acid; poly(propylene glycol)-4-nonylphenyl ether acrylate; and poly(ethylene glycol)2,4,6-tris-(1-phenylethyl)phenyl ether methacrylate in combination with a second polymer dispersant selected from the group consisting of a copolymer of methacrylic acid and benzyl methacrylate and a terpolymer of styrene, alpha-methyl styrene and acrylic acid. Carbon black inkjet inks having this particular polymer dispersant mixture exhibit improved text quality when compared to carbon black inks not having this polymer dispersant mixture.Type: ApplicationFiled: June 30, 2011Publication date: January 3, 2013Inventors: Xiaorong Cai, Elaine Money
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Patent number: 8288761Abstract: A composition for photosensitive dielectric material is provided. The composition includes 4 to 10 percent by weight of a polymer material, 1.5 to 10 percent by weight of a crosslinking agent, 0.32 to 2 percent by weight of a photoacid generator (PAG) and 78 to 94.18 percent by weight of solvent, based on a total weight of the composition.Type: GrantFiled: April 20, 2009Date of Patent: October 16, 2012Assignee: Industrial Technology Research InstituteInventors: Mei-Ru Lin, Jing-Yi Yan, Liang-Hsiang Chen, Chin-Lung Liao
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Patent number: 8277948Abstract: Provided is a thermosetting resin composition which can be used for the production of printed circuit boards, having good dielectric properties in high frequency bands so that transmission loss can be significantly lowered, having excellent heat resistance after moisture absorption and thermal expansion properties, and satisfying peeling strength between the resin composition and metal foil. The present invention relates to a thermosetting resin composition of a semi-IPN composite, comprising (A) a polyphenylene ether, and a prepolymer formed from (B) a chemically unmodified butadiene polymer containing 40% or more of a 1,2-butadiene unit having a 1 2,-vinyl group in a side chain of a molecule and (C) a crosslinking agent, in a compatibilized and uncured state; and a resin varnish, a prepreg and a metal clad laminated board using the same.Type: GrantFiled: February 14, 2007Date of Patent: October 2, 2012Assignee: Hitachi Chemical Co., Ltd.Inventors: Yasuyuki Mizuno, Daisuke Fujimoto, Kazutoshi Danjobara, Hikari Murai
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Publication number: 20120180802Abstract: The invention is directed to shape memory polymer compositions, articles of manufacture thereof, and methods of preparation and use thereof. The invention is further directed to methods of controlling the nature of the interaction of a shape memory device with the environment in which it is operating.Type: ApplicationFiled: June 17, 2011Publication date: July 19, 2012Applicant: The Board of Regents of the University of Texas SystemInventors: Taylor Ware, Walter Voit
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Patent number: 8143366Abstract: The present invention provides a compound having a formula: where R1 is selected from the group consisting of alkyl, CH2(OC2H4)OCH3, and —(OC2H4)OCH3; n is 0-4; Olig is an oligomer having a formula: -L-O-PAGR.R2]q where L is a optional linker moiety selected from the group consisting of —CH2O—, —CH2OX—, —OX—, —C(O)—, —C(O)X, —NH—, —NHC(O)—, —XNHC(O)—, —NHC(O)X—, —C(O)NH—, —C(O)NHX—, and where X is alkyl1-6 or is not present, Y is N or O or is not present, and R3 is alkyl1-6; PAG is a linear or branched polyalkylene glycol moiety; R2 is an alkyl1-22 capping moiety if X is present or alkyl2-22 if X is not present; and q is a number from 1 to the maximum number of branches on PAG; and m is 1-5.Type: GrantFiled: November 20, 2009Date of Patent: March 27, 2012Assignee: Biocon LimitedInventors: Nnochiri N. Ekwuribe, Amy L. Odenbaugh
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Patent number: 8142929Abstract: A positive electrode for non-aqueous electrolyte battery includes a positive electrode active material layer containing at least a positive electrode active material and a binder and a coating layer containing a polymer provided on the positive electrode active material layer, wherein the polymer has a block chain A composed of a random copolymer containing a repeating unit (I) represented by formula (I) and a repeating unit (II) represented by formula (II) and a block chain B containing a repeating unit (III) represented by formula (III) wherein R1-R3, R4a, R4b, R5-R13 are as defined herein.Type: GrantFiled: May 16, 2011Date of Patent: March 27, 2012Assignees: Sanyo Electric Co., Ltd., Nippon Soda Co., Ltd.Inventors: Nobuhiro Sakitani, Naoki Imachi, Atsushi Kaizuka, Takeshi Niitani, Masato Amaike
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Publication number: 20120071606Abstract: Methods of forming polycarbonate graft copolymers are provided. In particular, a polycarbonate polymer or copolymer containing allyl groups provides the backbone for the graft copolymer, and pendant chains are attached to the copolymer through the allyl groups. The graft copolymers exhibit a combination of high transparency, good graft levels, good scratch resistance, and/or good anti-fog properties.Type: ApplicationFiled: September 17, 2010Publication date: March 22, 2012Inventors: Rubin Huang, Andre van Zyl, Jan Pleun Lens, Theodorus Lambertus Hoeks, Hans-Peter Brack, Jan Henk Kamps
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Patent number: 7968229Abstract: A positive electrode for a non-aqueous electrolyte battery includes a positive electrode active material layer containing at least a positive electrode active material and a binder and a coating layer containing a polymer provided on the positive electrode active material layer, wherein the polymer has a block chain A composed of a random copolymer containing a repeating unit (I) represented by formula (I), a repeating unit (II) represented by formula (II), and a block chain B containing a repeating unit (III) represented by formula (III) wherein R1-R3, R4a, R4b, R5-R13 are as defined herein.Type: GrantFiled: September 26, 2008Date of Patent: June 28, 2011Assignees: Sanyo Electric Co., Ltd., Nippon Soda Co., Ltd.Inventors: Nobuhiro Sakitani, Naoki Imachi, Atsushi Kaizuka, Takeshi Niitani, Masato Amaike
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Publication number: 20110086973Abstract: To provide a curable composition which is quickly cured, with which objects to be bonded can be sufficiently bonded even if gaps are formed between the objects, if the size of the gaps is at a level of at most 100 ?m. A curable composition which comprises at least one organic peroxide, an accelerator which reacts with the organic peroxide to accelerate polymerization of monomers, a monofunctional (meth)acrylate and a multifunctional (meth)acrylate, wherein the organic peroxide is encapsulated in microcapsules. Preferably the above curable composition, wherein the monofunctional (meth)acrylate contains a (meth)acrylate having a carboxylic group and a (meth)acrylate having an alicyclic hydrocarbon.Type: ApplicationFiled: June 11, 2008Publication date: April 14, 2011Applicant: Denki Kagaku Kogyo Kabushiki KaishaInventors: Keita Kobayashi, Kimihiko Yoda, Jun Watanabe
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Patent number: 7875661Abstract: An intraocular lens with an ordered polymer system contained within a lens capsule or a membrane in the lens capsule. The ordered polymer system includes at least one negatively charged copolymer comprising hydrophilic groups, anionic groups and hydrophobic groups, and at least one positively charged copolymer comprising hydrophilic groups, cationic groups and hydrophobic groups. The at least one negatively charged copolymer and the at least one positively charged copolymer are associatively arranged through non-covalent interactions in the lens capsule or the membrane.Type: GrantFiled: December 11, 2007Date of Patent: January 25, 2011Assignee: Bausch & Lomb IncorporatedInventor: Joseph C. Salamone
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Patent number: 7666575Abstract: The present invention relates to an antireflective coating composition comprising, (i) a thermal acid generator; (ii) a crosslinkable polymer comprising at least one aromatic group; and, (iii) a polymeric crosslinker comprising at least one unit of structure (6), where R11 to R13 is independently selected from H, (C1-C6) alkyl and aromatic group, R14 and R15 are independently (C1-C10) alkyl. The invention also relates to a process for imaging the antireflective coating composition of the present invention.Type: GrantFiled: October 18, 2006Date of Patent: February 23, 2010Assignee: AZ Electronic Materials USA CorpInventors: Woo-Kyu Kim, Hengpeng Wu, David Abdallah, Mark Neisser, PingHung Lu, Ruzhi Zhang, M. Dalil Rahman
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Patent number: 7645830Abstract: A polymer including a block chain A which is formed from a random copolymer containing a repeating unit (I) represented by the formula (I) wherein R1 to R3 each independently represents hydrogen or C1-10 hydrocarbon and R1 and R3 may bond to form a ring; R4a and R4b each independently represents hydrogen or methyl; R5 represents hydrogen, hydrocarbon, acyl, or silyl; and m represents any integer of 1 to 100 and when m is 2 or more and each R4a may be the same or different from one another and each R4b may be the same or different from one another; and a repeating unit (II) represented by the formula (II) wherein R6 and R8 each independently represents hydrogen or C1-10 hydrocarbon and R6 and R8 may bond to form a ring; R7 represents hydrogen, C1-10 hydrocarbon, hydroxyl, hydrocarbonoxy, carboxyl, acid anhydride, amino, ester, or an organic group having at least one functional group selected from the group consisting of hydroxyl, carboxyl, epoxy, acid anhydride, and amino; and R9 represents anType: GrantFiled: January 18, 2006Date of Patent: January 12, 2010Assignee: Nippon Soda Co., Ltd.Inventors: Takeshi Niitani, Masato Amaike, Mikiya Shimada, Kiyoshi Kawamura
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Publication number: 20090093592Abstract: Disclosed are soft, high refractive index, acrylic device materials. The materials comprise di-block or tri-block macromers containing hydrophilic side-chains. The materials have improved glistening resistance.Type: ApplicationFiled: October 3, 2008Publication date: April 9, 2009Applicant: Alcon, Inc.Inventor: Douglas C. Schlueter
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Publication number: 20090076181Abstract: The present invention describes the synthesis of solvent soluble copolymers containing multiple unsaturations. These copolymers contain reactive vinyl groups, which can be further reacted in a second stage polymerization. The process involves copolymerization of a vinyl monomer with an inclusion complex of a monomer having multiple unsaturations and a cyclic macromolecular compound to yield soluble polymers. These polymers may be cast into films, membranes or may be converted in micro or nanoparticles and then crosslinked in a second step polymerization.Type: ApplicationFiled: October 24, 2008Publication date: March 19, 2009Applicant: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESInventors: Mohan G. KULKARNI, Rohini N. Karmalkar, Sunita S. Satav
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Publication number: 20080166636Abstract: A polymer including a block chain A which is formed from a random copolymer containing a repeating unit (I) represented by the formula (I) wherein R1 to R3 each independently represents hydrogen or C1-10 hydrocarbon and R1 and R3 may bond to form a ring; R4a and R4b each independently represents hydrogen or methyl; R5 represents hydrogen, hydrocarbon, acyl, or silyl; and m represents any integer of 1 to 100 and when m is 2 or more and each R4a may be the same or different from one another and each R4b may be the same or different from one another; and a repeating unit (II) represented by the formula (II) wherein R6 and R8 each independently represents hydrogen or C1-10 hydrocarbon and R6 and R8 may bond to form a ring; R7 represents hydrogen, C1-10 hydrocarbon, hydroxyl, hydrocarbonoxy, carboxyl, acid anhydride, amino, ester, or an organic group having at least one functional group selected from the group consisting of hydroxyl, carboxyl, epoxy, acid anhydride, and amino; and R9 represents anType: ApplicationFiled: January 18, 2006Publication date: July 10, 2008Inventors: Takeshi Niitani, Masato Amaike, Mikiya Shimada, Kiyoshi Kawamura
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Publication number: 20080107913Abstract: A composition for cord coating of the present invention comprises a latex of a first rubber, a phenol resin, and a water-soluble condensation product of resorcinol-formaldehyde so that a ratio of the first rubber to a solid content of the composition, a ratio of the phenol resin thereto, and a ratio of the water- soluble condensation product thereto are 30 to 95 wt.%, 0.01 to 30 wt.%, and 2 to 15 wt.%, respectively, wherein the first rubber is a nitrile group-containing highly saturated polymer rubber having an iodine value of 120 or less, and the above-described water-soluble condensation product is a novolac-type condensation product.Type: ApplicationFiled: March 25, 2005Publication date: May 8, 2008Applicant: Nippon Sheet Glass Company, LimitedInventors: Keisuke Kajihara, Naoya Mizukoshi
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Patent number: 7268193Abstract: Branched polyarylene polymers are provided comprising monovalent endcappers, divalent linear units, and polyvalent branching units. The composition of the polymers is controlled by adjusting the ratio of the three types of monomers.Type: GrantFiled: March 4, 2005Date of Patent: September 11, 2007Assignee: Mississippi Polymer Technologies, Inc.Inventors: Matthew L. Marrocco, III, Mark S. Trimmer, Ying Wang
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Patent number: 7208551Abstract: Polyaryleneetherketone triphenylphosphine oxide compositions incorporating cycloaliphatic units are provided which may be used as a polymeric binders in thermal control coatings for use in space environments. A method is also provided for synthesizing the polyaryleneetherketone triphenylphosphine oxide compositions. A method is also provided for synthesizing the monomeric compositions used to make the polyaryleneetherketone triphenylphosphine oxide compositions.Type: GrantFiled: August 18, 2004Date of Patent: April 24, 2007Assignee: University of DaytonInventors: Thuy D. Dang, Matthew J. Dalton, Narayanan Venkatasubramanian, Joel A. Johnson, William A. Feld
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Patent number: 7105269Abstract: 1. A copolymer having recurring units of the following formulas (1), (2), and (3), wherein R1, R4, R5, and R6 are a hydrogen atom or a methyl group, R2, R3, and R7 represent a monovalent organic group, k is 1 or 2, 1 is 0–4, n is 1–3, m is 0–3, R8 is a substituted methyl group, 1-substituted ethyl group, 1-branched alkyl group, triorganosilyl group, triorganogermyl group, alkoxycarbonyl group, acyl group, or cyclic acid-dissociable group, with two or more R8 groups being the same or different, q is 1–3, and p is 0–3, the copolymer having a GPC average molecular weight of 3,000–100,000. The composition is useful as a polymer component for a radiation-sensitive resin composition suitable as a chemically-amplified resist.Type: GrantFiled: December 18, 2002Date of Patent: September 12, 2006Assignee: JSR CorporationInventors: Tomoki Nagai, Daisuke Shimizu, Tsutomu Shimokawa, Fumihisa Miyajima, Masaaki Miyaji
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Patent number: 6867255Abstract: A nanocomposite made with an inorganic layered material and a star-shaped polystyrene that can be blended with normal linear polystyrene is disclosed. The inorganic layered material can have an exfoliated structure, substantially exfoliated, or intercalated structure. The exfoliated structure can result in significantly improved physical properties, even with only a very low content of clay. The invention is also directed to a process that can be used to make the compositions of the present invention. In one embodiment, a physical mixture of clay and star polymer is prepared and then the mixture is heated for several hours, preferably under high-shear mixing, to increase the rate of exfoliation, after which mostly inexpensive commodity linear polystyrene polymer completes the composition.Type: GrantFiled: October 3, 2003Date of Patent: March 15, 2005Assignee: Eastman Kodak CompanyInventors: Douglas R. Robello, Nori Yamaguchi, Thomas N. Blanton, Craig L. Barnes
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Patent number: 6812302Abstract: A process for preparing a liquid rubber composition comprises: (a) Forming a reaction mixture of (i) from 1.0 to 99.999 weight percent of the reaction mixture of at least one C1-C20 alkyl acrylate monomer; and (ii) from 0.001 to 20 weight percent of the reaction mixture of at least one aromatic-containing initiator; (b) charging the reaction mixture into a reactor maintained at a reaction temperature of up to 400° C.; and (c) polymerizing said monomer with said aromatic-containing initiator to form a liquid rubber with polymer chains having at least one non-functional aromatic end-group.Type: GrantFiled: June 18, 2002Date of Patent: November 2, 2004Assignee: Rohm and Haas CompanyInventor: Edward Ewart La Fleur
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Patent number: 6812313Abstract: A polymer comprises polymer chains having a glass transition temperature of less than 25° C. and a weight average molecular weight of less than 20,000 wherein the polymer chains contain at least one non-functional aromatic end-group. The polymer is miscible in the uncured state of said thermoset resins and immiscible in the cured state of the thermoset resins.Type: GrantFiled: June 18, 2002Date of Patent: November 2, 2004Assignee: Rohm and Haas CompanyInventor: Edward Ewart La Fleur
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Patent number: 6806029Abstract: A pattern formation material of this invention contains a base polymer including a first unit represented by Chemical Formula 1 and a second unit represented by Chemical Formula 2, and an acid generator: wherein R1 and R2 are the same or different and selected from the group consisting of a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group and an alkyl group including a fluorine atom; R3 is a protecting group released by an acid; m is an integer of 0 through 5; and a and b satisfy 0<a<1,0<b<1 and 0<a+b≦1.Type: GrantFiled: September 6, 2002Date of Patent: October 19, 2004Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Shinji Kishimura, Masayuki Endo, Masaru Sasago, Mitsuru Ueda, Tsuyohiko Fujigaya
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Patent number: 6773863Abstract: Disclosed is a novel positive-working chemical-amplification photoresist composition capable of giving an extremely finely patterned resist layer in the manufacturing process of semiconductor devices. The photoresist composition comprises: (A) 100 parts by weight of a copolymeric resin consisting of from 50 to 85% by moles of (a) hydroxyl group-containing styrene units, from 15 to 35% by moles of (b) styrene units and from 2 to 20% by moles of (c) acrylate or methacrylate ester units each having a solubility-reducing group capable of being eliminated in the presence of an acid; and (B) from 1 to 20 parts by weight of a radiation-sensitive acid-generating agent which is an onium salt containing a fluoroalkyl sulfonate ion having 3 to 10 carbon atoms as the anion such as bis(4-tert-butylphenyl) iodonium nonafluorobutane sulfonate.Type: GrantFiled: February 21, 2003Date of Patent: August 10, 2004Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Katsumi Oomori, Hiroto Yukawa, Ryusuke Uchida, Kazufumi Sato
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Patent number: 6737214Abstract: A chemical amplification positive resist composition comprising a polymeric mixture of a polyhydroxystyrene derivative having a Mw of 1000-500,000 and a copolymer of hydroxystyrene and (meth)acrylate having a Mw of 1000-500,000, as a base resin, has improved dry etching resistance, high sensitivity, high resolution, and process adaptability, and is suppressed in the slimming of pattern films after development with aqueous base.Type: GrantFiled: March 8, 2001Date of Patent: May 18, 2004Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takanobu Takeda, Osamu Watanabe, Kazuhiro Hirahara, Katsuya Takemura, Wataru Kusaki, Akihiro Seki
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Patent number: 6646045Abstract: Thermoplastic molding compositions containing graft polymers produced with different initiator systems are disclosed. The compositions are distinguished by a combination of good toughness and reduced opacity. As a result, appreciably smaller quantities of pigment are needed to color the molding composition.Type: GrantFiled: November 30, 2001Date of Patent: November 11, 2003Assignee: Bayer AktiengesellschaftInventor: Herbert Eichenauer
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Patent number: 6646052Abstract: Solid blends of rubbery polymers and amorphous or crystalline polymers, said blends being free-flowing at temperatures lower than the glass transition temperature or crystalline melting temperature of the amorphous or crystalline polymer, are prepared by intimate mixing procedures. In general, said mixing conditions include high shear conditions sufficient to convert polymer A to dispersed particles coated with polymer B and produce a free-flowing powder blend.Type: GrantFiled: May 7, 2002Date of Patent: November 11, 2003Assignee: General Electric CompanyInventors: Navjot Singh, Joseph Michael Anostario
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Patent number: 6632887Abstract: Hydrophilic coatings for implantable ophthalmic lenses are disclosed. The coatings, which are applied to the edge surface of the ophthalmic lens, comprise a hydrophobic (meth)acrylic polymer and a hydrophilic polymer. When hydrated, the coatings reduce or eliminate edge glare.Type: GrantFiled: March 29, 2002Date of Patent: October 14, 2003Assignee: Alcon Universal Ltd.Inventors: Albert R. LeBoeuf, John W. Sheets, Jr.
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Patent number: 6613844Abstract: A chemically amplified positive resist composition comprising a styrene polymer represented by formula (1), terminated with P, and having a weight average molecular wherein R is OH or OR3, R1 is H or CH3, R2 is alkyl, R3 is acid labile group, x≧0, y>0, k≧0, m≧0, n>0, 0<q≦0.8, p+q=1, P is H, alkyl, alkenyl, aromatic, carboxyl, OH, —R4(COR5)r, —R4O(OH)r or —R4 (OR5)r. A chemically amplified positive resist composition comprising the polymer as a base resin has high sensitivity and resolution and forms resist patterns having plasma etching resistance, heat resistance, and reproducibility.Type: GrantFiled: March 19, 2002Date of Patent: September 2, 2003Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Osamu Watanabe, Shimada Junji, Nagura Shigehiro, Takeda Takanobu
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Patent number: 6586491Abstract: A method of reducing the flow viscosity of a polyacrylate composition, which comprises adding a) to a polyacrylate, a polyacrylate copolymer, a polyacrylate mixture or a mixture of polyacrylates and polyacrylate copolymers having an average molecular weight of more than 500000 g/mol b) a polyacrylate, a polyacrylate copolymer, a polyacrylate mixture or a mixture of polyacrylates and polyacrylate copolymers having an average molecular weight of less than 500000 g/mol, component (b) possessing functional groups crosslinkable by UV irradiation.Type: GrantFiled: January 25, 2001Date of Patent: July 1, 2003Assignee: tesa AGInventors: Marc Husemann, Stephan Zöllner
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Patent number: 6534595Abstract: A coating solution for forming porous organic film comprising the following A) to C), wherein A) and B) have respective heat decomposition initiation temperatures Ta and Tb satisfying a relation: Ta>Tb: A) a thermosetting resin having an aromatic ring in the main chain, B) a heat decomposable resin obtained by polymerization of monomers which include at least one compound represented by the following formula (1) or (2), and C) an organic solvent, wherein, X and each of R1 to R3 are defined in the specification.Type: GrantFiled: December 22, 2000Date of Patent: March 18, 2003Assignee: Sumitomo Chemical Company, LimitedInventors: Yuji Yoshida, Hyuncheol Choi, Atsushi Sukumoda
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Publication number: 20030013832Abstract: A styrene polymer represented by formula (1), terminated with P, and having a weight average molecular 1Type: ApplicationFiled: March 19, 2002Publication date: January 16, 2003Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Osamu Watanabe, Shimada Junji, Nagura Shigehiro, Takeda Takanobu
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Patent number: 6465581Abstract: This invention relates to use of stabilized unsymmetrical coupling agents for use in conjugated diene-based rubber compositions reinforced with silica-based reinforcement, namely use of stabilized 2-benzothiazyl-3-(triethoxysilylpropyl) disulfide and 3-(triethoxysilyl)propyl-N-maleamic acid. Said stabilized unsymmetrical coupling agent materials may be provided for mixing with said diene-based rubber(s), for example, as individual materials, as at least one of said materials being pre-reacted with aggregates of precipitated silica, said precipitated silica having hydroxyl groups (e.g. silanol groups) on its surface. The invention includes an article of manufacture, including a tire, having at least one component comprised of such rubber composition.Type: GrantFiled: January 24, 2001Date of Patent: October 15, 2002Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, Paul Harry Sandstrom, Theodore Lamson Folk
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Publication number: 20020128390Abstract: A thermoplastic elastomer formed by a process comprising the steps of dynamically vulcanizing a rubber within a mixture that includes the rubber, from about 10 to about 80 percent by weight of a thermoplastic resin based upon the total weight of the rubber and the thermoplastic combined, and from about 1 to about 25 percent by weight of a polymeric processing additive based upon the total weight of the rubber and the thermoplastic combined, where the polymeric processing additive is a linear polyolefin resin that has an melt flow rate that is greater than about 1,000 dg/min, a diene-modified polyolefin polymer that has an melt flow rate that is greater than about 1,000 dg/min, from about 0.005 to about 2.00 mole percent polymeric units deriving from dienes, and a viscosity average branching index that is from about 0.4 to about 0.Type: ApplicationFiled: December 29, 2000Publication date: September 12, 2002Inventors: Maria D. Ellul, Paul E. McDaniel, Thomas L. Peltier, Jianya Cheng, Patrick Brant, Armenag H. Dekmezian
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Patent number: 6433090Abstract: A thermoplastic vulcanizate prepared by a process comprising the steps of dynamically vulcanizing a vulcanizable rubber within a mixture that includes from about 15 to about 90 percent by weight of the rubber and from about 10 to about 85 percent by weight of a long-chain branched thermoplastic resin, where the long-chain branched thermoplastic resin is (i) an &agr;-olefin polymer, (ii) a copolymer of an &agr;-olefin and an &agr;-&ohgr;-olefin diene, or (iii) a mixture thereof, where the long-chain branched thermoplastic resin is characterized by a weight average molecular weight from about 100,000 to about 600,000, a number average molecular weight from about 40,000 to about 200,000, a z-average molecular weight from about 400,000 to about 2,000,000, a <g′>vis from about 0.2 to about 0.95, and a melt flow rate from about 0.3 to about 30 dg/min.Type: GrantFiled: January 26, 2001Date of Patent: August 13, 2002Assignee: Advanced Elastomer Systems, L.P.Inventors: Maria D. Ellul, Abdelhadi Sahnoune
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Patent number: 6403720Abstract: A rubber composition containing 50 to 90 parts by weight of a diene rubber and 50 to 10 parts by weight of a gelled rubber having a toluene swelling index of 16 to 150, based upon the total amount of 100 parts by weight of the diene rubber and the gelled rubber.Type: GrantFiled: August 22, 2000Date of Patent: June 11, 2002Assignee: The Yokohama Rubber Co., Ltd.Inventors: Keisuke Chino, Hidekazu Onoi, Satoshi Mihara
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Patent number: 6384169Abstract: A styrene polymer represented by formula (1), terminated with P, and having a weight average molecular wherein R is OH or OR3 R1 is H or CH3, R2 is alkyl, R3 is acid labile group, x≧0, y>0, k≧0, m≧0, n>0, 0<q≦0.8, p+q=1, P is H, alkyl, alkenyl, aromatic, carboxyl, OH, —R4 (COR5)r, —R4O (OH)r or —R4 (OR5)r. A chemically amplified positive resist composition comprising the polymer as a base resin has high sensitivity and resolution and forms resist patterns having plasma etching resistance, heat resistance, and reproducibility.Type: GrantFiled: October 7, 1998Date of Patent: May 7, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Osamu Watanabe, Shimada Junji, Nagura Shigehiro, Takeda Takanobu
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Publication number: 20020013416Abstract: The present invention provides a mineral filled thermoplastic olefin (MFTPO) composition comprising a polymer mixture, a mineral and a flexural modulus modifying agent and/or a heat deflection temperature modifying agent, and a method for producing the same. The flexural modulus modifying agent and/or a heat deflection temperature modifying agent significantly increases the flexural modulus and/or a heat deflection temperature of the MFTPO without substantially affecting the falling weight impact resistance of the MFTPO relative to a similar MFTPO composition which lacks the flexural modulus modifying agent and/or a heat deflection temperature modifying agent.Type: ApplicationFiled: June 14, 2001Publication date: January 31, 2002Inventor: Oscar French Noel
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Patent number: 6312869Abstract: A chemically amplified positive resist composition contains (A) an organic solvent, (B) a base resin in the form of a polymer having at least one acid labile group and crosslinked within a molecule and/or between molecules with a crosslinking group having a C—O—C linkage, the polymer having a weight average molecular weight of 1,000-500,000, (C) a photoacid generator, (D) a basic compound, and (E) an aromatic compound having a group ≡C—COOH in a molecule. The composition has a high alkali dissolution contrast, high sensitivity and high resolution.Type: GrantFiled: June 12, 2000Date of Patent: November 6, 2001Assignee: Shin-Etsu Chemical, Co., Ltd.Inventors: Satoshi Watanabe, Osamu Watanabe, Tomoyoshi Furihata, Yoshihumi Takeda, Shigehiro Nagura, Toshinobu Ishihara, Tsuguo Yamaoka
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Patent number: 6268436Abstract: The present invention is directed to a high-performance irradiation sensitive positive-tone resist and to a method of formulating the same. In one aspect, the polymer resin composition of the present invention comprises a blend of at least two miscible aqueous base soluble polymer resins, wherein one of said aqueous base soluble polymer resins of said blend is partially protected with a high activation energy protecting group and the other aqueous base soluble polymer resin of said blend is partially protected with a low activation energy protecting group. A chemically amplified resist system comprising said polymer resin composition; at least one acid generator; and a solvent is also provided herein.Type: GrantFiled: December 27, 1999Date of Patent: July 31, 2001Assignee: International Business Machines CorporationInventors: Kuang-Jung Chen, Ronald A. DellaGuardia, Wu-Song Huang, Ahmad D. Katnani, Mahmoud M. Khojasteh, Quighuang Lin