Ester Derived From An Unsaturated Carboxylic Acid Patents (Class 525/227)
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Patent number: 6586530Abstract: A block copolymer including a block of residues of a low surface tension (meth)acrylate monomer; a block of residues of a monomer free of hydroxyl group and amine group residues; and, optionally, a third block of residues of a monomer free of hydroxyl groups and amine groups. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. A controlled radical polymerization method is disclosed to make the low surface tension block copolymers. The method includes the steps of sequentially adding a first monomer composition that is free of hydroxyl groups and amine groups and a second monomer composition that includes the low surface tension monomer to a suitable atom transfer radical polymerization initiator and polymerizing the monomer compositions to form a block copolymer.Type: GrantFiled: September 27, 2001Date of Patent: July 1, 2003Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan D. Goetz, Kurt A. Humbert, Karl F. Schimmel, Karen A. Barkac, Simion Coca, Joanne H. Smith
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Publication number: 20030114593Abstract: A block copolymer including a block of residues of a low surface tension (meth)acrylate monomer; a block of residues of a monomer free of hydroxyl group and amine group residues; and, optionally, a third block of residues of a monomer free of hydroxyl groups and amine groups. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. A controlled radical polymerization method is disclosed to make the low surface tension block copolymers. The method includes the steps of sequentially adding a first monomer composition that is free of hydroxyl groups and amine groups and a second monomer composition that includes the low surface tension monomer to a suitable atom transfer radical polymerization initiator and polymerizing the monomer compositions to form a block copolymer.Type: ApplicationFiled: September 27, 2001Publication date: June 19, 2003Inventors: Jonathan D. Goetz, Kurt A. Humbert, Karl F. Schimmel, Karen A. Barkac, Simion Coca, Joanne H. Smith
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Patent number: 6573330Abstract: A process for preparing a water-absorbent resin is provided which enables the water-absorbent resin to ensure the reduction in the release amount of liquid and the increase in the liquid diffusibility. In the preparation process, the water-absorbent resin is prepared by polymerization of a water-soluble ethylenic unsaturated monomer. The polymerization of the water-soluble ethylenic unsaturated monomer is allowed to take place in the presence of a water-absorbent resin having a water-absorbing rate different from that of a water-absorbent resin resulting from polymerization of the water-soluble ethylenic unsaturated monomer. In a preferred mode, the polymerization is performed by a reversed-phase suspension polymerization method.Type: GrantFiled: December 10, 1998Date of Patent: June 3, 2003Assignee: Sumitomo Seika Chemicals, Co., Ltd.Inventors: Masato Fujikake, Yasuhiro Nawata, Magoto Shirakawa, Masakazu Yamamori, Shioko Yoshinaka, Morio Nakamura
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Patent number: 6565616Abstract: The invention relates to blends of copolymers containing structural units of olefins, derivatives of dibasic carboxylic acids and, if required, polyolefins and, structural units of ethylene and vinyl esters of tertiary carboxylic acids, and their use as additives to fuel oils for improving their cold flow properties.Type: GrantFiled: March 14, 2001Date of Patent: May 20, 2003Assignee: Clariant GmbHInventors: Matthias Krull, Thomas Volkmer, Werner Reimann
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Patent number: 6559230Abstract: Safety glass interlayers are prepared from a composition comprising: A. A homogeneously linear or substantially linear ethylene/&agr;-olefin interpolymer, e.g., ethylene/1-octene; B. A coagent containing at least two vinyl groups, e.g., trimethyol propane tri(meth)acrylate; and C. A peroxide, e.g., Luperox™ 101. The interlayer films exhibit an excellent combination of tear strength and clarity.Type: GrantFiled: September 21, 2001Date of Patent: May 6, 2003Assignee: DuPont Dow Elastomers L.L.C.Inventors: Henry G. Heck, Douglas P. Waszeciak
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Patent number: 6552130Abstract: A resin composition comprising (A) a (meth)acrylic acid ester (B) and an acrylic polymer soluble in the component (A) and further (C) a compound having a mercapto group (—SH) and a carboxyl group (—COOH) in the molecule or an component (C) and (F) an organic amine or an component (F) and (G) a radical trapping agent. The composition is suitably used as a covering material for civil engineering and construction applications.Type: GrantFiled: July 18, 2001Date of Patent: April 22, 2003Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Takayuki Makino, Toshio Takemoto
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Patent number: 6548601Abstract: An ambient oxidative cure composition based on an acrylate functionalized alkyd resin is described. A method of preparing an ambient oxidative cure composition based on an acrylate functionalized alkyd resin is also described. Such ambient oxidative cure compositions may be used in, for example, fast drying, high solid paint or enamel compositions or formulations.Type: GrantFiled: June 16, 2000Date of Patent: April 15, 2003Assignee: Eastman Chemical CompanyInventors: Thauming Kuo, Mark D. Clark
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Patent number: 6528588Abstract: Blends of syndiotactic 1,2-polybutadiene and rubbery elastomers are prepared by a process that comprises polymerizing 1,3-butadiene monomer into syndiotactic 1,2-polybutadiene within a rubber cement of at least one rubbery elastomer by using a chromium-based or molybdenum-based catalyst composition.Type: GrantFiled: September 18, 2001Date of Patent: March 4, 2003Assignee: Bridgestone CorporationInventor: Steven Luo
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Patent number: 6528590Abstract: The present invention relates to an aqueous copolymer dispersion consisting essentially of A) an aqueous dispersion of a copolymer having a solids content of from 20 to 65% by weight, said copolymer being composed of various monomers and the weight fractions of the various monomers being chosen within the stated limits such that a synthetic resin composed of these monomers alone would have a glass transition temperature in the range from −50 to 35° C., B) from 0 to 10% by weight, based on the copolymer A, of benzophenone, acetophenone, one or more acetophenone derivatives or benzophenone derivatives without an ethylenically unsaturated group, or a mixture thereof, C) from 0.3 to 10% by weight, based on the copolymer A, of emulsifiers, and D) from 0 to 5% by weight, based on the copolymer A, of protective colloids; to a process for its preparation and to its use.Type: GrantFiled: October 5, 2001Date of Patent: March 4, 2003Assignee: Clariant GmbHInventors: Dierk Beyer, Volker Renisch, Rolf Kuropka, Susana Maria De Almeida Carvalho
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Patent number: 6512053Abstract: This invention discloses an emulsion styrene-butadiene rubber (SBR) that can be employed in manufacturing tire tread formulations that have rolling resistance and treadwear characteristics that are similar to those made with solution SBR but with improved traction characteristics. Thus, the emulsion SBR of this invention is superior in many respects for use in tire tread compounds to conventional solution SBR and conventional emulsion SBR. This invention more specifically discloses a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene, 1,3-butadiene, and a hydroxy alkyl acrylate monomer, wherein the styrene-butadiene rubber composition has a number average molecular weight as determined by field flow fractionation which is within the range of about 50,000 to 150,000, and wherein the styrene-butadiene rubber has a light scattering to refractive index ratio which is within the range of 1.8 to 3.9.Type: GrantFiled: June 20, 2002Date of Patent: January 28, 2003Assignee: The Goodyear Tire & Rubber CompanyInventors: Howard Allen Colvin, Michael Leslie Senyek, Jr.
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Patent number: 6506835Abstract: A novel composition is disclosed which comprises polyvinyl chloride, an ethylene-based copolymer as a compatibilizer, inorganic fillers and from about 5 to 95 percent by weight of either virgin or recycled/recovered polyvinyl butyral. A process for preparing this novel composition is also provided.Type: GrantFiled: June 12, 2000Date of Patent: January 14, 2003Assignee: E. I. du Pont de Nemours and CompanyInventor: George Henry Hofmann
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Patent number: 6506533Abstract: Infra-red absorbing polymers useful in imageable products and the lithographic printing field comprise infra-red absorbing groups carried as pendent groups on a polymer backbone. Certain infra-red absorbing groups may also act to insolublize the polymer in a developer, until it is imagewise exposed to infra-red radiation. The resulting heat renders the polymer soluble in the developer. Imagable products employing the infra-red absorbing polymers may include positive working lithographic printing plates.Type: GrantFiled: June 7, 2000Date of Patent: January 14, 2003Assignee: Kodak Polychrome Graphics LLCInventors: Eduard Kottmair, Hans-Horst Glatt, Stefan Hilgart, Paul West
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Patent number: 6506840Abstract: A process for producing a succinimide resin composition is provided which comprises reacting a maleic anhydride-olefin type copolymer constituted of 40-60 mol % of maleic anhydride units, 60-40 mol % of olefin units, and 0-20 mol % of a copolymerizable monomer units with one or more amine compounds for imide formation in the presence of a second polymer other than the succinimide resin. This process improves the productivity by lowering the torque in the extrusion reaction, giving a succinimide copolymer resin composition having low yellowness and high transparency with high production efficiency.Type: GrantFiled: April 16, 2001Date of Patent: January 14, 2003Assignee: Tosoh CorporationInventors: Takeshi Harunari, Yoshiki Uchida, Toru Doi
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Patent number: 6498218Abstract: An interpenetrating polymer network (IPN) or semi-interpenetrating polymer network (semi-IPN) comprises a first phase which is continuous and comprises a flexible polymer and a second phase which is a fluorescent or nonfluorescent durable dispersed or continuous phase and comprises a dye and a polymer, wherein the polymer enhances durability of the dye. Such networks are particularly useful in fluorescent traffic signs or safety devices or in pavement marking tape or paint.Type: GrantFiled: March 11, 2002Date of Patent: December 24, 2002Inventors: Denise A. Barrera, Roberta E. Harelstad, William D. Joseph, Lee A. Pavelka
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Patent number: 6495626Abstract: Acrylic plastisol composition comprising a plasticiser component, a plasticiser compatible acrylic polymer powder component of primary particle size ≧0.4 &mgr;m and preferably not more than 30 &mgr;m, and Tg ≧65° C., and a plasticiser incompatible polymer powder component, where both polymers are preformed, are present in the weight ratio 95:5 to 40:60, and in combination are compatibly formulated with the plasticiser component.Type: GrantFiled: August 18, 1999Date of Patent: December 17, 2002Assignee: Zeneca LimitedInventors: Andrew Stuart Overend, David Henry Cooper, John Christopher Padget
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Patent number: 6492462Abstract: The rheological properties of a crosslinkable resin system are modified by the presence of a side chain crystalline (SCC) polymer (or a similar crystalline polymer which melts over a narrow temperature range). The polymer dissolves in the curable system at temperatures above the melting point of the crystalline polymer (Tp), but when the system is then cooled to a temperature below Tp, at least partially forms a separate phase in the curable system. Below Tp, this separate phase substantially increases the viscosity of the curable system (i.e. makes it thicker than the same system without the crystalline polymer). This is particularly valuable for sheet molding composites (SMCs) in which the increase in viscosity makes the composites less tacky, and for dry film resists (DFRs). Above Tp, the curable system containing the dissolved crystalline polymer has a viscosity which is substantially less than its viscosity below Tp.Type: GrantFiled: December 19, 2000Date of Patent: December 10, 2002Assignee: Landec CorporationInventors: Steven P. Bitler, David D. Taft, Ray F. Stewart
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Publication number: 20020182171Abstract: Water-soluble and/or water-dispersible comb polymers consisting of a polymer main chain and polyester side-arms which contain sulphone groups and are linked to said polymer main chain via ester groups.Type: ApplicationFiled: April 19, 2001Publication date: December 5, 2002Inventors: Marion Detert, Andreas Koller, Matthias Loffler, Bernhard Mees, Roman Morschhauser, Angelika Turowski
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Patent number: 6482892Abstract: An olefinic thermoplastic elastomer composition which does not exhibit problems due to a softening agent such as an oil is superior in molding processability. The thermoplastic elastomer composition is produced by a heat crosslinking process of a resin-rubber composition that contains an olefinic and/or diene rubber, an olefinic resin, and a vinyl copolymer. The vinyl copolymer is obtained by copolymerizing 20 wt % or more of a vinyl monomer represented by CH2═CHOCOR1 or CH2═CHOR2 wherein R1 and R2 are alkyl groups having 1-6 carbon atoms. The thermoplastic elastomer composition can include a vinyl copolymer that has not undergone a heat crosslinking process.Type: GrantFiled: June 27, 2000Date of Patent: November 19, 2002Assignee: JSR Elastomix Co., Ltd.Inventors: Seizo Katayama, Kazuo Kimura, Kazuhiro Ohashi, Minoru Horie
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Patent number: 6479592Abstract: A functionalized and polymerizable polymer is described which is obtainable by ring-opening metathesis polymerization and is suitable in particular as a dental material and especially as a constituent of dental adhesives owing to an adhesion-boosting effect.Type: GrantFiled: August 20, 1999Date of Patent: November 12, 2002Assignee: Ivoclar Vivadent AGInventors: Volker Rheinberger, Norbert Moszner, Franz Stelzer, Regina Schitter, Frank Zeuner
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Patent number: 6476148Abstract: The invention relates to a polymethacrylate matte-finish surface and comprised of: A thermoplastic polymer matrix A, in the amount of 99.9-30 wt. %, comprised of a hard phase (a1) and a tough phase (a2); and Latex particles of a thermoelastic polymer B, in t. of 0.1-70 wt. %, incorporated in the said matrix A, which particles give rise to the matte effect. Preferably the hard phase (a1) may contain low molecular weight and/or polymer-bound UV-absorbers. The difference between index of refraction of the thermoplastic polymer A and that of the thermoelastic polymer B is at most 0.02. Despite its matte finish, the film has high transparency, is weather resistant, has low incidence of white fracture when buckled or folded, and has impact strength which does not degrade upon cooling or heating. At the same time, the film is effective as a UV filter, to protect substrates which are sensitive to UV irradiation.Type: GrantFiled: December 30, 1993Date of Patent: November 5, 2002Assignee: Roehm GmbH & Co. KGInventor: Heinz Gross
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Patent number: 6476145Abstract: Polyester injection-moulded parts based on a polyester (A) and on a copolymer (B) of ethylene and of an unsaturated epoxy, such that weight % (B)×MFI (A+B)/MFI(A) is greater than 3 and in this expression: MFI (A+B) denotes the melt flow index of the modified polyester, that is to say the blend of (A) and (B) and of any fillers; MFI (A) denotes the melt flow index of the polyester (A) and of any fillers (without (B)); and weight % (B) denotes the percentage by weight of (B) in the blend of (A) and (B) and of any fillers.Type: GrantFiled: June 29, 2000Date of Patent: November 5, 2002Assignee: AtofinaInventors: Patrice Perret, Jacques Komornicki, Yoshiyuki Miyaki
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Publication number: 20020137850Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20° C.Type: ApplicationFiled: December 20, 2001Publication date: September 26, 2002Applicant: Westvaco Corporation, New York, NYInventor: Michael D. Matzinger
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Patent number: 6448339Abstract: An adhesive composition is prepared from a major proportion of (1) a corboxyl group-containing adhesive component having a weight average molecular weight of 800,000 or greater and a smaller amount of (2) an amino group-containing adhesion-improving component having a weight average molecular weight of 100,000 or less which is added to crosslink the component (1).Type: GrantFiled: December 11, 1997Date of Patent: September 10, 2002Assignees: Soken Chemical & Engineering Co., Ltd., Lintec CorporationInventor: Koji Tomita
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Patent number: 6448324Abstract: Provided are a flame-retardant polycarbonate resin composition having good blow moldability, and blow moldings of the composition having good flame retardancy and having good impact resistance, high mechanical strength and good thermal stability intrinsic to polycarbonate resins. The composition comprises 100 parts by weight of a resin or resin mixture of (A) from 30 to 100% by weight of a polycarbonate resin and (B) from 0 to 70% by weight of a styrenic resin, from 1 to 50 parts by weight of (C) a flame retardant, and from 1 to 20 parts by weight of (D) a methyl methacrylate polymer having a weight-average molecular weight of at least 1,000,000, and optionally contains (E) a fluoro-olefinic resin, (F) a rubber-like elastomer, and (G) an inorganic filler.Type: GrantFiled: August 2, 1999Date of Patent: September 10, 2002Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akio Nodera, Naoki Mitsuta, Kouichi Hara
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Publication number: 20020119308Abstract: The present invention is a puff heat transfer, a puff transfer composition, and a method of making a puff transfer composition. The puff transfer composition, i.e., ink, is actually loaded with the color. In particular, the transfer composition comprises effective amounts of a transfer base material, at least one pigment concentrate, and a puff base material. The transfer base material and the pigment concentrate may be mixed together and then loaded into the puff base material to form the transfer composition. The transfer composition may be deposited on a transfer sheet to make the heat transfer. The transfer sheet may be a substrate that is treated with quillon. By using a substrate sheet that is treated with quillon, the puff of the present invention has an improved, velvet-like feel when the transfer sheet is removed.Type: ApplicationFiled: September 21, 2001Publication date: August 29, 2002Applicant: Impulse Wear, Inc.Inventors: Christopher Roberts, Lawrence Levine
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Patent number: 6437046Abstract: This invention relates to a low-density polyethylene composition useful for coating polar substrates. This invention particularly relates to a low-density polyethylene composition useful for coating metal foils, wherein the composition comprises an ethylene/(meth)acrylic acid copolymer having a low acid content.Type: GrantFiled: October 4, 2000Date of Patent: August 20, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Barry Alan Morris
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Patent number: 6417277Abstract: The present invention provides a coating composition which is excellent in a curing property (particularly a low temperature curing property) of a coating film and which forms a coating film having excellent chipping resistance and adhesive property, and it comprises a hydroxyl group-containing resin (A), a cross-linking agent (B) and a phosphoric acid group-containing vinyl resin (C).Type: GrantFiled: September 27, 2000Date of Patent: July 9, 2002Assignee: Kansai Paint Co., Ltd.Inventors: Yasuhiro Tomizaki, Akira Kasari
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Patent number: 6408593Abstract: A polymeric roofing shingle composition is shown which includes (a) a rubber component present in the range from about 10-95% by weight, based on the total weight of the composition and (b) a polyolefin component present in the range from about 5-50% by weight, based on the total weight of the composition. A SBR/EVA closed cell rubber composition can be formulated which has a weight of less than 150 pounds per roofing square for ⅛ inch thickness and which is flame retardant at thicknesses of ⅛ inch and higher without the addition of separate flame retardant components.Type: GrantFiled: September 1, 1999Date of Patent: June 25, 2002Inventors: Pete Foster, Donald E. Dilks
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Patent number: 6407172Abstract: A composition suitable for thermoforming which demonstrates good grain retention at thin gauges, low gloss and whose cost is competitive for many applications, particularly in the automotive industry, is described. This composition contains (a) 10-35 wt. % of polypropylene or an ethylene/propylene copolymer, (b) 0-30 wt. % uncrosslinked ethylene propylene copolymer rubber having an ethylene content 60-80 wt. %, (c) 10-25 wt. % of an ionomeric copolymer of ethylene and an &agr;, &bgr;-unsaturated C3-C8 carboxylic acid, (d) 2-6 wt. % of a copolymer of ethylene and glycidyl acrylate or glycidyl methacrylate, (e) 5-20 wt. % polyethylene, and (f) 0-25 wt. % of an ethylene alpha-olefin copolymer elastomer.Type: GrantFiled: June 16, 2000Date of Patent: June 18, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Karlheinz Hausmann
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Patent number: 6403716Abstract: A thermoplastic rubber composition prepared by crosslinking 1-99 parts by weight of a crosslinkable rubbery polymer (A) and 1-99 parts by weight of a polypropylene resin (B) (total amount of (A) and (B) being 100 parts by weight), wherein said (B) comprises a polypropylene resin (B-1) characterized by generation of a torque higher than Mo after melting and a polypropylene resin (B-2) characterized by generation of a torque not higher than Mo after melting, in a melting test of said (B) in the presence of an organic peroxide (temperature condition being at 200° C.), and Mo being a torque right after complete melting.Type: GrantFiled: July 12, 2000Date of Patent: June 11, 2002Assignee: Asahi Kasei Kabushiki KaishaInventor: Hajime Nishihara
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Patent number: 6395828Abstract: A thermoplastic molding composition comprising a grafted acrylate rubber (ASA) and a gloss reducing agent and a process for making the same are disclosed. The gloss reducing agent is the reaction product of (i) a compound having two or more epoxy groups per molecule and (ii) a compound having two or more amine groups per molecule, with the proviso that the total of epoxy groups of (i) and amine groups of (ii) per molecule is greater than 4. The gloss reducing agent may be either incorporated in ASA as the reaction product of (i) and (ii) or, in the alternative, formed upon the reaction of (i) with (ii) in the course of the thermal processing of the a blend containing ASA, (i) and (ii).Type: GrantFiled: September 26, 2001Date of Patent: May 28, 2002Assignee: Bayer CorporationInventors: Moh-Ching Oliver Chang, Allen R. Padwa
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Patent number: 6395844Abstract: An interpenetrating polymer network (IPN) or semi-interpenetrating polymer network (semi-IPN) comprises a first phase which is continuous and comprises a flexible polymer and a second phase which is a fluorescent or nonfluorescent durable dispersed or continuous phase and comprises a dye and a polymer, wherein the polymer enhances durability of the dye. Such networks are particularly useful in fluorescent traffic signs or safety devices or in pavement marking tape or paint.Type: GrantFiled: September 1, 1999Date of Patent: May 28, 2002Assignee: 3M Innovative Properties CompanyInventors: Denise A. Barrera, Roberta E. Harelstad, William D. Joseph, Lee A. Pavelka
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Patent number: 6391972Abstract: It is an object of the present invention to provide a plastic article having moist touch, which differs from the smooth touch peculiar to the conventional plastic articles. A plastic article is characterized in that the surface of the article is at least partially constituted from a styrenic thermoplastic elastomer, an olefinic thermoplastic elastomer, a blend of a styrenic thermoplastic elastomer and a polyolefin, or a blend of an olefinic thermoplastic elastomer and a polyolefin.Type: GrantFiled: September 16, 1999Date of Patent: May 21, 2002Assignee: Heiwa Kagaku Kogyosho Co., Ltd.Inventor: Kazuyuki Hatakeyama
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Patent number: 6391973Abstract: The present invention provides a coating composition containing a two-stage polymer emulsion. The two-stage emulsion polymer contains composite polymeric particles of a first stage polymer prepared from about 0.25% to about 5% by weight monomer having at least two polymerizable ethylenically unsaturated groups, about 2.5% to about 10% by weight hydroxyl monomer, preferably at least about 50% by weight of non-functional monomer of hydrophobic monomer, and preferably without addition of any acid-functional monomer; and a second stage polymer having a theoretical glass transition temperature of at least about 50° C. prepared using, by weight, about 25% to about 50% by weight hydroxyl monomer, about 3% to about 9% carboxylic acid monomer, and preferably at least 25% by weight of non-functional monomer of hydrophobic monomer;. The composite polymeric particles have a theoretical glass transition temperature of not more than about 30° C., preferably not more than about 0° C., and include from about 0.Type: GrantFiled: July 24, 2000Date of Patent: May 21, 2002Assignee: BASF CorporationInventors: David Law, Walter H Ohrbom, S. Kendall Scott, Sergio E. Balatan, Thomas E. St. Henry, Robert Weise
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Patent number: 6388012Abstract: A thermosetting powder paint composition comprising (A) a resin composition component, (B) a hardener component and (C) a solid flow controlling component, wherein the component (A) contains a resin composition component having reactivity with the component (B), the component (B) contains a hardener having reactivity with the component (A), the component (C) contains a vinyl polymer which is solid at 20° C., and the relation between SPA of the component (A) and SPC of the component (C) satisfies the following numerical formula (1) and the following numerical formula (2) simultaneously. By this constitution, excellent blocking-resistance in storing as the powder paint composition and excellent appearance properties of a paint film formed by coating the powder paint composition can be simultaneously manifested. 8≦SPA≦13 (1) 7≦SPC≦SPA (2).Type: GrantFiled: April 4, 2000Date of Patent: May 14, 2002Assignee: Mitsui Chemicals, Inc.Inventors: Hiroyuki Sakayama, Yoshio Kikuta, Mitsuyuki Mizoguchi, Takahisa Miyawaki, Tsuyoshi Matsumoto
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Patent number: 6388014Abstract: A latex or fiber comprising a blend of polymeric materials consisting of one or more &agr;-olefin/ vinylidene monomer non-crosslinked substantially random interpolymers, wherein the distribution of the monomers of said interpolymers can be described by the Bernoulli statistical model or by a first or second order Markovian statistical model, and one or more homopolymers or copolymers of monomer components comprising aliphatic &agr;-olefins having from 2 to 20 carbon atoms, or aliphatic &agr;-olefins having from 2 to 20 carbon atoms and containing polar groups.Type: GrantFiled: April 27, 2001Date of Patent: May 14, 2002Assignee: The Dow Chemical CompanyInventors: Chung P. Park, Rene Broos, Johan Thoen, Martin J. Guest, Yunwa W. Cheung, John J. Gathers, Bharat I Chaudhary, Lawrence S. Hood
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Patent number: 6376611Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20° C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise: (a) from about 0.1% to about 30% of one or more colorants; and (b) from about 0.1 to about 99.9% of one or more hybrid polymers. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements.Type: GrantFiled: October 25, 1999Date of Patent: April 23, 2002Assignee: Westvaco CorporationInventor: Michael D. Matzinger
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Patent number: 6376058Abstract: A polypropylene based composition is described which comprises a mixture of (A) a propylene polymer or copolymer and (B) an alkylene-alkyl acrylate copolymer. These polypropylene based compositions are useful in the preparation of continuous films such as by extrusion, and the films can be oriented by stretching in the machine direction. The films prepared from the polypropylene compositions of this invention exhibit a variety of useful properties including the desired printability, stiffness, and die-cuttability to be useful as a facestock in preparing labels. Films prepared from the polypropylene based compositions of the invention also can be used as a base film, and the films can be overlaminated with a functional film. Machine-direction oriented monolayer and multilayer film facestocks for labels, and adhesive containing film labelstock for use in adhesive labels also are described.Type: GrantFiled: December 21, 1999Date of Patent: April 23, 2002Assignee: Avery Dennison CorporationInventors: Johannes Schut, Coen van Tol, Mitchell J. Rackovan, Paul C. McCaslin, Eng-Pi Chang
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Publication number: 20020037969Abstract: A polypropylene based composition is described which comprises a mixture of (A) a propylene polymer or copolymer and (B) an alkylene-alkyl acrylate copolymer. These polypropylene based compositions are useful in the preparation of continuous films such as by extrusion, and the films can be oriented by stretching in the machine direction. The films prepared from the polypropylene compositions of this invention exhibit a variety of useful properties including the desired printability, stiffness, and die-cuttability to be useful as a facestock in preparing labels. Films prepared from the polypropylene based compositions of the invention also can be used as a base film, and the films can be overlaminated with a functional film. Machine-direction oriented monolayer and multilayer film facestocks for labels, and adhesive containing film labelstock for use in adhesive labels also are described.Type: ApplicationFiled: December 21, 1999Publication date: March 28, 2002Inventors: JOHANNES SCHUT, COEN VAN TOL, MITCHELL J. RACKOVAN, PAUL C. MCCASLIN, ENG-PI CHANG
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Patent number: 6359074Abstract: A high strength, stretched, polyethylene plastic film is described. To obtain better stretchability, the film includes an effective amount of an acetate polymer. Typically, the polyethylene film contains up to 10% of acetate polymer. A suitable acetate polymer is polyvinyl acetate. A process for the production of a high strength polyethylene plastic film including an acetate polymer is also described.Type: GrantFiled: May 25, 2000Date of Patent: March 19, 2002Assignee: Windmöller & HölscherInventors: Christof Herschbach, Juergen Linkies, Markus Stumpf
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Publication number: 20020010267Abstract: Block copolymers are disclosed having at least one polymer segment characterized by a high degree of control over molecular weight, particle size, polydispersity and polymer composition and architecture. The block copolymers feature at least on polymer segment produced using a controlled free radical polymerization process in an emulsion. Additional polymer segments can be generated using the controlled free radical emulsion process or any other polymerization process. The block copolymers include polymers having unique structure, such as stars, grafts, telechelics and macromonomers. Block copolymers having hard/soft and amphiphilic characteristics are also disclosed. The block copolymers may also include adducts with nitroxide control agents capable of free radical re-initiation.Type: ApplicationFiled: July 2, 1999Publication date: January 24, 2002Applicant: Symyx Technologies, Inc., a Delaware corporationInventors: GERRIT KLAERNER, ADAM SAFIR, RALPH B. NIELSEN, BERND JANDELEIT, PETER HUEFNER
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Patent number: 6337374Abstract: There is a need for halogen-free polymeric compositions for utilization in gaskets and seals that offers high tensile strength and high tear strength as well as good resistance to compression set. Seals for automotive body applications, such as, windows, hoods, trunks, and doors, and building applications, such as window glazing gaskets and weather strips, should be dimensionally stable, provide low compression set, and offer outstanding sealing characteristics over a broad temperature range. They must be capable of sealing out noise, wind and water, while providing long-term ultraviolet light resistance.Type: GrantFiled: December 1, 1999Date of Patent: January 8, 2002Assignee: The Goodyear Tire & Rubber CompanyInventors: Hung Dang Ngoc, Agnés Marie Madeleine Louise DeLoor
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Patent number: 6329450Abstract: The present invention relates to a blend of polymeric materials comprising; (A) of from about 1 to about 80 percent by weight (based on the combined weights of Components A and B) of at least one substantially random interpolymer; wherein said interpolymer; (1) contains of from about 0.5 to about 50 mole percent of polymer units derived from; a) at least one vinyl or vinylidene aromatic monomer, or b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or c) a combination of at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer; (2) contains of from about 50 to about 99.5 mole percent of polymer units derived from at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; (3) has a melt index (I2) of from about 0.01 to about 100 g/10 min; and (4) has a molecular weight distribution (Mw/Mn) of from about 1.Type: GrantFiled: March 2, 1999Date of Patent: December 11, 2001Assignee: The Dow Chemical CompanyInventors: Samuel A. Ogoe, Charles F. Diehl, Leo A. Novak, Wendy D. Hoenig, Shaofu Wu, Donna C. Scott
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Patent number: 6329466Abstract: A foam comprising a blend of polymeric materials consisting of one or more &agr;-olefin/vinylidene monomer non-crosslinked substantially random interpolymers, wherein the distribution of the monomers of said interpolymers can be described by the Bernoulli statistical model or by a first or second order Markovian statistical model, and one or more homopolymers or copolymers of monomer components comprising aliphatic &agr;-olefins having from 2 to 20 carbon atoms, or aliphatic &agr;-olefins having from 2 to 20 carbon atoms and containing polar groups.Type: GrantFiled: October 12, 2000Date of Patent: December 11, 2001Assignee: The Dow Chemical CompanyInventors: Chung P Park, Rene Broos, Johan Thoen, Martin J. Guest, Yunwa W. Cheung, John J. Gathers, Bharat I Chaudhary, Lawrence S. Hood
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Patent number: 6316548Abstract: A (meth)acrylic premix comprising a (meth)acrylic resin composition (A) containing a (meth)acrylic monomer (a) and a (meth)acrylic polymer (b), an inorganic filler (B), and a curing agent (C), wherein, the component (a) is a (meth)acrylate having a bicyclo ring, fluorine atom, cyclic ether, cyclohexane ring or tricyclo ring, and the component (C) is a radical polymerization initiator having a 10 hours half-life temperature of 75° C. or more; an acrylic SMC or BMC comprising this (meth)acrylic premix and a thickening agent; and a method for producing (meth)acrylic artificial marble, wherein this (meth)acrylic SMC or BMC is cured with being pressurized and heated at a temperature in the range from 105 to 150° C., are provided. These are useful for producing (meth)acrylic artificial marble having various excellent physical properties such as appearance, dimension stability, hot water resistance, weatherability.Type: GrantFiled: October 14, 1999Date of Patent: November 13, 2001Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Seiya Koyanagi, Katsumi Yonekura, Shinji Saiki, Kentaro Hayashi, Yuichiro Kishimoto
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Patent number: 6310137Abstract: A multilayered acrylic polymer comprising an innermost layer polymer (A) formed from a C1-4 alkyl methacrylate, a C1-8 alkyl acrylate, etc., an intermediate layer polymer (B) formed from a C1-8 alkyl acrylate, an aromatic vinyl monomer, etc., and an outermost layer polymer (C) formed from a C1-4 alkyl methacrylate, a C1-8 alkyl acrylate, etc., and wherein the average value of the coating ratio, i.e. [(minimum thickness of the intermediate layer)÷(maximum thickness of the intermediate layer)]×100, is not less than 30%; and a methacrylic resin composition containing the same. This multilayered acrylic polymer can improve the falling-ball or falling-weight impact strength, resistance to impact whitening, transparency and other properties of the methacrylic resin composition.Type: GrantFiled: December 6, 1999Date of Patent: October 30, 2001Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Hirofumi Uno, Jun Nakauchi
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Patent number: 6306520Abstract: There are provided; a laminated film or sheet formed by adhesively integrating a resin layer (1) of an acrylic resin with a resin composition layer (2) of a polyolefin resin composition, the polyolefin resin composition comprising an ethylene based copolymer (a) prepared by polymerizing ethylene with at least one compound selected from the group consisting of unsaturated carboxylic acids, unsaturated carboxylic esters, unsaturated carboxylic anhydrides and vinyl acetate, a polyethylene resin (b) excluding the copolymer (a), and a polypropylene resin (c), which is characterized in that the layers (1) and (2) are adhesively integrated with each other to the satisfaction, even if no layer of an adhesive agent is interposed between them; and a laminated structure formed by adhesively integrating the laminated film or sheet with a substrate of a polyolefin resin, which is particularly suitable for uses such as interior or exterior car parts, electric appliances, parts of miscellaneous goods and signboards.Type: GrantFiled: December 22, 1998Date of Patent: October 23, 2001Assignee: Sumitomo Chemical Company, LimitedInventors: Makoto Nagata, Hiroaki Takahata
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Patent number: 6303692Abstract: Blends of syndiotactic 1,2-polybutadiene and rubbery elastomers are prepared by a process that comprises polymerizing 1,3-butadiene monomer into syndiotactic 1,2-polybutadiene within a rubber cement of at least one rubbery elastomer by using a catalyst composition that is formed by combining (a) a molybdenum-containing compound, (b) a hydrogen phosphite, and (c) an organoaluminum compound.Type: GrantFiled: April 13, 2000Date of Patent: October 16, 2001Assignee: Bridgestone CorporationInventor: Steven Luo
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Patent number: 6300419Abstract: Disclosed are propylene polymer compositions comprising a high crystalline propylene polymer, a substantially linear ethylene polymer, linear ethylene polymer or combinations thereof, an optional filler and an optional additional polymer. Said propylene polymer compositions have improved processability with a good balance of stillness and toughness which demonstrates improved scratch resistance in injection molded articles.Type: GrantFiled: December 8, 1999Date of Patent: October 9, 2001Assignee: The Dow Chemical CompanyInventors: Kalyan Sehanobish, Harry Craig Silvis, Marie L. Hare, Wendy D. Hoenig, John Newton
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Patent number: 6300407Abstract: An elastomer composition, including: at least one elastomer; a plasticizer which includes at least one polymeric material having a weighted average molecular weight of (Mw) of 500 to 1,000,000, formed from at least one ethylenically unsaturated monomer, and a curing agent, wherein the at least one polymeric material is substantially permanent within the elastomer. The subject elastomer compositions have enhanced plasticity and processability without attendant migration, heat or solvent extraction and compatibility problems.Type: GrantFiled: February 4, 1999Date of Patent: October 9, 2001Assignee: Rohm and Haas CompanyInventors: Warren Harvey Machleder, Robert Howard Gore, David Sterett Moorman, Michael Damian Bowe