At Least Two Polymers Derived From Carboxylic Acid Ester Reactants Patents (Class 525/228)
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Publication number: 20100143629Abstract: The invention relates to a methacrylic composition comprising (100-x-y) parts of at least one methacrylic polymer that is a homopolymer or copolymer of MMA, dispersed in which are: x parts of particles of a thermoplastic polymer A comprising MMA as the main monomer that is either crosslinked or that has a weight-average molecular weight Mw>300 000 g/mol, advantageously >400 000 g/mol (relative to a PMMA standard), with a weight-average diameter (ASTM D1921)>100 ?m, advantageously >250 ?m and <500 ?m, advantageously <400 ?m; y parts of particles of a crosslinked thermoplastic polymer B comprising MMA as the main monomer, with a weight-average diameter (ASTM D1921) ranging from 15 to 70 ?m; such that x varies from 2 to 20 and y varies from 10 to 25. Preferably, x+y<33.Type: ApplicationFiled: November 8, 2007Publication date: June 10, 2010Applicant: Arkema FranceInventors: Patrick Delprat, Jerome Berge
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Patent number: 7723433Abstract: A clear, impact modified, heat resistant polyvinyl chloride composition is provided comprising (a) at least one polyvinyl halide; (b) at least one clear impact modifier possessing a refractive index which is not more than about 2% above or below the refractive index of the polyvinyl halide; and (c) at least one clear heat modifier comprising a terpolymer obtained by the copolymerization of a vinyl aromatic monomer, an acrylonitrile and an alkyl acrylate or alkyl methacrylate, wherein the terpolymer possesses a refractive index which is not more than about 2% above or below the refractive index of the polyvinyl halide and possesses a weight average molecular weight ranging from about 75,000 to about 400,000.Type: GrantFiled: November 22, 2004Date of Patent: May 25, 2010Assignee: Chemtura CorporationInventors: Larry B. Simmons, George P. McCarty
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Patent number: 7683131Abstract: The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.Type: GrantFiled: September 15, 2004Date of Patent: March 23, 2010Assignee: Röhm GmbH & Co. KGInventors: Thorsten Goldacker, Andreas Spiess, Reiner Mueller, Klaus Schultes, Uwe Numrich
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Publication number: 20100029855Abstract: A large sized thin-walled shaped article having a complicated shape can be realized by improving fluidity at the time of shaping without deterioration of the intrinsic characteristic properties of an aromatic polycarbonate resin, namely, transparency, resistance to exfoliation of surface layer, thermal resistance, impact resistance, and chemical resistance. Specifically disclosed is a fluidity-improving agent containing 0.5 to 99.5 parts by mass of a polymer (A) which is obtained by polymerizing a monomer mixture (a) containing 0.5 to 99% by mass of (a1) an aromatic vinyl monomer, 0.5 to 99% by mass of (a2) a phenyl(meth)acrylate or a phenyl(meth)acrylate having a substituent in a phenyl group, and 0.5 to 5% by mass of (a3) a vinyl monomer having a functional group (X), and 0.5 to 99.Type: ApplicationFiled: December 25, 2007Publication date: February 4, 2010Applicant: Mitsubishi Rayon co., LtdInventors: Shinji Matsuoka, Yasuhiko Nabeshima
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Patent number: 7651648Abstract: Methods of making articles are described comprising the steps of applying a capstock material over a layer of a substrate material and then calendaring said capstock material and said substrate material with calendaring rolls to form an article, wherein said capstock material contacts said calendar rolls for a shorter period of time than said substrate material. The capstock material comprises a melt-processable thermoplastic composition comprising a) 50-99.5 wt. % of a melt-processable thermoplastic polymer and b) 0.5-50 wt. % of a particulate polymer comprising the residues of a monomer mixture comprising 50-100 wt. % of MMA, at least 0-50 % of an ethylenically unsaturated comonomer comprising at least one alkyl acrylate or methacrylate and 0-10 wt. % of a copolymerisable cross-linking monomer said particles having a maximum dimension of 5 mm.Type: GrantFiled: December 9, 2008Date of Patent: January 26, 2010Assignee: Lucile International UK LimitedInventors: Paul Eustace, Nicholas John Maston, John Robert Oliver
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Publication number: 20090326155Abstract: A pressure-sensitive adhesive composition for PDP front filters includes 100 parts by weight of a high molecular weight acrylic polymer A having a COOH or OH group, a weight average molecular weight (Mw) of 400,000 to less than 800,000, a molecular weight distribution (Mw/Mn) of not more than 5 and a glass transition temperature (Tg-A) of ?40 to ?10° C., and 5 to 20 parts by weight of a low molecular weight acrylic polymer B having a weight average molecular weight (Mw) of 10,000 to 50,000, a molecular weight distribution (Mw/Mn) of not more than 5 and a glass transition temperature (Tg-B) of 40 to 120° C.; and is crosslinked to a gel fraction of 50 to 90% and has a 90° peel strength of 5 to 15 N/25 mm. The pressure-sensitive adhesive composition does not cause bonding failures such as lifting even when exposed to thermal cycles.Type: ApplicationFiled: June 14, 2007Publication date: December 31, 2009Applicant: SOKEN CHEMICAL & ENGINEERING CO., LTD.Inventor: Koji Tomita
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Patent number: 7638582Abstract: The present invention relates to a thermoformable sheet, for example, an acrylic sheet, comprising particles proximate to the top surface, wherein the textured sheet, when thermoformed, provides a low-gloss, textured surface that is less sensitive to marring, blemishes (including blemishes resulting from the mold), household wear and tear, and visibly reduces the appearance of oil deposits on its surface.Type: GrantFiled: October 29, 2003Date of Patent: December 29, 2009Assignee: Lucite International, Inc.Inventors: Fareeduddin Farooq, Andrew H. Janowicz, James R. Leach, Philip A. Janowicz
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Patent number: 7632892Abstract: Provided are an acrylic copolymer composition, a method for preparing an acrylic copolymer, and a vinyl chloride resin composition including the acrylic copolymer. The acrylic copolymer composition includes 5-15 wt % of a crosslinking agent and an alkyl acrylate monomer constituting an alkyl acrylate crosslinked polymer and 85-95 wt % of methyl methacrylate and at least one monomer selected from the group consisting of alkyl acrylate and alkyl methacrylate. Addition of the acrylic copolymer to the vinyl chloride resin composition enhances the foaming property of the vinyl chloride resin. Combination of the acrylic copolymer with an impact modifier further enhances the impact strength of the vinyl chloride resin.Type: GrantFiled: September 3, 2004Date of Patent: December 15, 2009Assignee: LG Chem, Ltd.Inventors: Yong-Hun Lee, Jung-sup Han, Hyung-Jun Son
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Publication number: 20090252885Abstract: Photopolymer resins ate disclosed which includes metal and/or ceramic surface chelating agents to provide strong bonding of the photopolymer resin to the inorganic surface of the first information layer of an optical disc. The resins also include a fast surface cure and glass transition temperature controlling monomers that provides easy stamper separation The disclosed photopolymer resins also include short wavelength (<405 nm) surface cure initiators. The resins may also optionally include shrinkage control oligomers and/or polymer fillers or a combination of both Use of the disclosed resins eliminates two steps from the manufacture of a multiple information layer optical disc as the formation of spacer layers and the curing of spacer layers is no longer necessary.Type: ApplicationFiled: April 7, 2008Publication date: October 8, 2009Applicant: Addison Clear Wave, LLCInventor: Chau Ha
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Publication number: 20090242118Abstract: A surfacing composition made of recycled paint, which requires no priming, has a non-reflective “flat” appearance, and is partially composed of dried paint. The composition provides a useful application for used or excess household paint, which would otherwise require special methods of disposal and potentially create future toxic cleanup problems. The composition is made of granular dried paint and a water-based sealer, which can be spread on a surface to repair imperfections. The surface can then be finished, and no priming is required. Due to the composition's flat appearance, the patch does not display any characteristic sheen where the repair has been made. The composition provides a simple means of recycling paint, and provides a simple and inexpensive means of repairing imperfections in walls and other surfaces while saving the step of priming the patch before painting or repainting.Type: ApplicationFiled: September 26, 2008Publication date: October 1, 2009Inventor: Larry Allen Holloway
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Publication number: 20090240002Abstract: Disclosed herein is an impact modifier formed by graft polymerizing about 45 to about 70% by weight of a rubber polymer with about 30 to about 55% by weight of a methacrylate-based monomer, wherein said rubber polymer is prepared by polymerizing about 0.1 to about 1 part by weight of an antioxidant with about 100 parts by weight of a monomer mixture comprising about 30 to about 45% by weight of a diene-based monomer and about 55 to about 70% by weight of alkyl acrylate. The methacrylate-based resin composition of the present invention using the aforementioned impact modifier may have improved transparency, impact resistance and a good appearance.Type: ApplicationFiled: June 2, 2009Publication date: September 24, 2009Applicant: CHEIL INDUSTRIES INC.Inventors: Ki Bo CHANG, Doo Han HA, Dong Wook JUNG, Jae Hun JUNG
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Publication number: 20090227739Abstract: The present invention is a composition useful as an impact modifier for polyamide compositions. In one embodiment, impact modifiers of the present invention are ethylene maleic anhydride copolymers having at least 3% maleic anhydride functionality. Compositions comprising copolymers of ethylene and maleic anhydride or its functional equivalents and ethylene copolymers with polar comonomers are disclosed. The compositions provide miscible blends and exhibit improved properties, such as increased temperature resistance and mechanical strength, compared to pure ethylene copolymers with polar comonomers.Type: ApplicationFiled: May 13, 2009Publication date: September 10, 2009Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: RICHARD T. CHOU
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Publication number: 20090226748Abstract: The invention provides a process for preparing organic nanoparticles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin, an initiator and a hydrophobic monomer; (b) emulsifying the solution obtained in step (a) in an aqueous phase; and thereafter (c) curing the emulsified solution. The invention further provides organic nanoparticles obtainable by the process according to the invention; various uses of said nanoparticles; and paper, dye compositions and toner compositions comprising said nanoparticles.Type: ApplicationFiled: July 12, 2007Publication date: September 10, 2009Inventors: Matthias Jozef Gertruda Brouns, Joseph Petronella Friederichs, Johan Franz Gradus Antonius Jansen, Marco Marcus Matheus Driessen
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Publication number: 20090198327Abstract: Disclosed are soft, high refractive index device materials having improved strength. The materials contain a polystyrene macromer.Type: ApplicationFiled: April 2, 2009Publication date: August 6, 2009Inventor: Douglas C. Schlueter
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Patent number: 7544757Abstract: Disclosed are copolymers derived from ethylene and an alkyl acrylate comonomer wherein the copolymer has a number average molecular weight (Mn) above 40,000. This invention also provides compounded compositions and cured compositions (i.e., vulcanizates) comprising these copolymers. The copolymers provide improved dynamic fatigue resistance of the vulcanizates. Also disclosed are articles comprising the copolymers, such as tubing, hoses, dampers, seals and gaskets.Type: GrantFiled: June 30, 2006Date of Patent: June 9, 2009Assignee: E. I. du Pont de Nemours and CompanyInventors: Yun-Tai Wu, Mark Aaron Stewart, Yi Ye
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Patent number: 7497979Abstract: A melt-processable thermoplastic composition is described, which comprises a) 50-99.5 wt. % of a melt-processable thermoplastic polymer and b) 0.5-50 wt. % of a particulate polymer comprising the residues of a monomer mixture comprising 50-100 wt. % of MMA, at least 0-50% of an ethylenically unsaturated comonomer comprising at least one alkyl acrylate or methacrylate and 0-10 wt. % of a copolymerisable cross-linking monomer said particles having a maximum dimension of 5 mm. The compositions have reduced surface gloss and may be useful for forming building components or in any other application in which a low gloss surface is required. A method of making the composition and its uses, for example its use as a capstock material, are also described.Type: GrantFiled: February 1, 2005Date of Patent: March 3, 2009Assignee: Lucite International UK LimitedInventors: Paul Eustace, Nicholas John Marston, John Robert Oliver
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Publication number: 20090041842Abstract: The invention relates to a partly neutralised anionic (meth)acrylate copolymer consisting of radically polymerised units containing 25-95% by weight (meth)acrylic acid C1 to C4 alkylesters and 5-75% by weight (meth)acrylate monomer with an anionic group, wherein 0.1 to 25% contained anionic groups are neutralised by a base. Said invention is characterised in that said base is embodied in the form of an cationic organic base whose molecular weight is greater than 150. A medical form containing said partly neutralised anionic (meth)acrylate copolymer and the use of said partly neutralised anionic (meth)acrylate copolymer for producing a medical form rapidly releasing an active substance having a determined pH value are also disclosed.Type: ApplicationFiled: December 15, 2005Publication date: February 12, 2009Applicant: Roehm GmbHInventors: Rosario Lizio, Hans-Ulrich Petereit, Erna Roth, Michael Damm, Ruediger Alexowsky
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Publication number: 20090043047Abstract: A resin composition having good scratch resistance includes about 5 to about 50 parts by weight of core-shell graft resin (A) and about 95 to about 50 parts by weight of resin (B) which includes about 40 to about 100% by weight of (meth)acrylic acid alkyl ester. The outer shell of the core-shell graft resin (A) comprises (meth)acrylic acid alkyl ester.Type: ApplicationFiled: October 17, 2008Publication date: February 12, 2009Applicant: Cheil Industries Inc.Inventors: Doo Han HA, Bong Jae JEONG
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Publication number: 20090025866Abstract: A transfer-type adhesive material A is obtained by applying a adhesive 1 composed of a adhesive composition 10 (not shown) containing an acrylic polymer or a styrene-based polymer onto a release substrate in an intermittent pattern. The present invention includes pressing a nut N and a washer W as hard articles against the above-mentioned transfer-type adhesive material A, transferring a plurality of dots 1d of the adhesive 1 onto pressed surfaces Na and Wa of the nut N and the washer W, and applying onto a target surface C1b the plurality of dots 1d of the adhesive 1 transferred onto the pressed surfaces Na and Wa.Type: ApplicationFiled: February 6, 2007Publication date: January 29, 2009Inventors: Hiroyuki Kasahara, Kazushige Kawashita, Akiko Ide, Yoshihiro Morishita, Toyoaki Kurihara
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Publication number: 20090029160Abstract: The present application is directed to a film having high solvent resistance, in addition to high tensile strength and elongation characteristics. A (meth)acrylic film formed of: (A-1) an acidic group-containing (meth)acrylic polymer having a glass transition temperature (Tg) of 0° C. or higher obtained by copolymerizing a composition containing a monoethylenically unsaturated monomer as a main component and an unsaturated monomer having an acidic group; (B-1) a basic group-containing (meth)acrylic polymer having a glass transition temperature (Tg) of 0° C. or lower obtained by copolymerizing a composition containing a monoethylenically unsaturated monomer as a main component and an unsaturated monomer having a basic group; and (C) a compound containing a radical generating group.Type: ApplicationFiled: March 2, 2006Publication date: January 29, 2009Inventors: Yorinobu Takamatsu, Hiroshi Sakaguchi, Hidetoshi Abe
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Patent number: 7482405Abstract: The present invention concerns a cement additive containing copolymers comprising one or more constitutional units represented by formula A: (A) R1 is hydrogen, an alkyl group having 1 to 4 carbon atoms, an alkenyl group having 1 to 4 carbon atoms or an aryl group having 6 to 9 carbon atoms; R2 is hydrogen or an alkyl group having 1 to 9 carbon atoms, an alkenyl group having 1 to 9 carbon atoms or an aryl group having 6 to 9 carbon atoms; T is alkylene (including straight-chain and branched alkylene) having 1 to 4 carbon atoms or arylene having 6 to 9 carbon atoms; n is 0 or 1; S1 and S2 are, independently of one another, —OCkH2k— or —OCH2CHR3—, with the proviso that k is 2 or 3, R3 is an alkyl group having 1 to 9 carbon atoms, an aryl group having 6 to 9 carbon atoms; and 6<_m1+m2<_25.Type: GrantFiled: March 5, 2004Date of Patent: January 27, 2009Assignee: Construction Research & Technology GmbHInventors: Toshimi Matsumoto, Sven Asmus, Gerhard Albrecht, Klaus Lorenz, Petra Wagner, Christian Scholz
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Publication number: 20090023864Abstract: An object of the present invention is to provide a (meth)acrylic polymer in which the occurrence of air marks and flow marks during forming, in particular, calendering is suppressed and a vinyl chloride-based resin composition containing the same. The present invention provides a (meth)acrylic polymer containing 15 to 65 parts by weight of a polymer (A) having a specific viscosity of 0.90 to 2.00 and containing 70 to 100 weight percent of methyl methacrylate, 0 to 30 weight percent of a (meth)acrylic ester other than methyl methacrylate, and 0 to 10 weight percent of another monomer copolymerizable with these; 20 to 75 parts by weight of a polymer (B) having a specific viscosity of 0.40 or more and less than 0.90 and containing 70 to 100 weight percent of methyl methacrylate, 0 to 30 weight percent of a (meth)acrylic ester other than methyl methacrylate, and 0 to 10 weight percent of another monomer copolymerizable with these; and 1 to 30 parts by weight of a polymer (C) having a specific viscosity of 0.Type: ApplicationFiled: March 8, 2006Publication date: January 22, 2009Inventors: Mitsutaka Sato, Yasushi Nakanishi
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Publication number: 20090017287Abstract: A melt processed film comprising a polymer having several acrylic components.Type: ApplicationFiled: June 27, 2008Publication date: January 15, 2009Inventors: Hailan Guo, Jiun-Chen Wu
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Patent number: 7446149Abstract: A refinish clearcoat composition includes an hydroxyl-functional acrylic polymer. The acrylic polymer has a number average molecular weight of at least about 5000 and is polymerized using at least about 45% by weight cycloaliphatic monomer, based on total monomer weight polymerized. The clearcoat composition is fast drying. Optionally, the clearcoat is cured by low temperature baking. The cured clearcoat surface may be taped without leaving tape marks as soon as the substrate is cooled. The cured clearcoat may undergo wet sanding after baking as soon as the part is cooled, and can then be buffed back to a high gloss finish after sanding and washing.Type: GrantFiled: September 27, 2001Date of Patent: November 4, 2008Assignee: BASF CorporationInventors: Ali Rihan, Emerson Keith Colyer
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Publication number: 20080262160Abstract: This invention relates to monodisperse or nearly monodisperse (co)polymers containing acrylic or (?-substituted)acrylic acid moieties, polymeric precursors thereof as well as methods for making them by at least partial hydrolysis of said polymeric precursors. The invention also relates to compositions comprising such (co)polymers optionally in combination with polymer processing additives for use in various fields of technology including imaging applications.Type: ApplicationFiled: June 30, 2005Publication date: October 23, 2008Applicant: UNIVERSITEIT GENTInventors: Filip Du Prez, Wim Van Camp, Stefan A. F. Bon
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Patent number: 7393900Abstract: A chlorinated rubber composition which is resistant to various fluids such as transmission fluids comprises a blend of a chlorinated polyethylene elastomer, an ethylene acrylic elastomer and/or polyacrylic rubbers, and optionally a chlorosulfonated polyethylene. The rubber composition has many uses such as a tube and generally contains various additives such as fillers, plasticizers, vulcanizing agents, and the like. A heat resistant rubber composition comprises a blend of a chlorinated polyethylene elastomer, an ethylene-acrylic elastomer and/or polyacrylic rubbers, an ethylene-octene copolymer, and an ethylene-propylene-diene terpolymer, and the same can be used as a cover or jacket as on the above chlorinated rubber tube.Type: GrantFiled: December 2, 2004Date of Patent: July 1, 2008Assignee: Excel-Polymers, LLCInventor: Matthew S. Snider
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Patent number: 7385007Abstract: The present invention provides a pressure sensitive adhesive composition for optical members, which is excellent in durability, re-releasability and stress relaxation, as well as a pressure sensitive adhesive composition for optical members, which hardly increases adhesion after storage for a long time and does not leave a residual adhesive on glass upon disposal or repair. The pressure sensitive adhesive composition for optical members according to the present invention comprises 100 parts by weight of an acrylic polymer (A) having a weight-average molecular weight of 500,000 or more, containing at least 50 wt % alkyl (meth)acrylate having an alkyl group with 5 or more carbon atoms and 0.2 to 2 wt % unsaturated carboxylic acid as the monomer unit, 0.Type: GrantFiled: August 6, 2004Date of Patent: June 10, 2008Assignee: Nitto Denko CorporationInventors: Yutaka Moroishi, Fumiko Nakano, Tetsuo Inoue, Yoshihide Kawaguchi, Kohei Yano
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Publication number: 20080132603Abstract: A polymerizable dental material formed of a liquid component containing A) at least one liquid methyl methacrylate monomer component, B) at least one acrylated or methacrylated butadiene oligomer or acrylated or methacrylated butadiene polymer and/or an acrylated or methacrylated acrylonitrile-butadiene oligomer or acrylated or methacrylated acrylonitrile-butadiene polymer, and optionally a powder component containing a polymer powder or a bead polymer based on methacrylate.Type: ApplicationFiled: November 19, 2007Publication date: June 5, 2008Applicant: HERAEUS KULZER GMBHInventors: KARL-HEINZ RENZ, NOVICA SAVIC, KEVIN KERSCHER
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Patent number: 7332544Abstract: A chlorinated vinyl chloride-based resin composition in which from 2 to 9 parts by weight of an MBS resin and from 0.5 to 3 parts by weight of chlorinated polyethylene are blended to 100 parts by weight of a chlorinated vinyl chloride-based resin with a chlorine content of from 62 to 70% by weight obtained by post-chlorinating a vinyl chloride-based resin, which can provide an injection molding product such as a joint of excellent heat resistance, impact strength, moldability and surface property.Type: GrantFiled: April 19, 2004Date of Patent: February 19, 2008Assignee: Kaneka CorporationInventor: Takeyuki Suzuki
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Patent number: 7250472Abstract: Acrylic compositions which can be processed into thermoformable acrylic sheet material with variegated non-homogeneous granite appearance are disclosed. The acrylic compositions comprise a matrix of polymethyl methacrylate having dispersed within it particles of a thermoplastic such as polymethyl methacrylate and one or more comonomers wherein the thermoplastic is in the shape of thin wafers 0.05 to 9.53 mm thick, 0.18 to 12.8 wide and 0.18 to 7.62 mm long.Type: GrantFiled: October 25, 1999Date of Patent: July 31, 2007Assignee: Lucite International, Inc.Inventors: Fareeduddin Farooq, James Leach, Michael R. Turbeville, Andrew H. Janowicz, Richard D. Redfearn
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Patent number: 7211622Abstract: An object of the present invention is to provide an aqueous resin composition and its uses, wherein the aqueous resin composition combines the blocking resistance and the frost damage resistance and thereby can secure the durability over a long period of time even under circumstances where a severe temperature cycle is present. As a means of achieving this object, the aqueous resin composition according to the present invention is an aqueous resin composition comprising an acrylic resin emulsion and a crosslinking agent as essential components, with the aqueous resin composition being characterized in that, when a coating film is formed from the aqueous resin composition, the formed coating film exhibits an elongation ratio (E (%)) that satisfies a specific relational expression along with the glass transition temperature (TgT (° C.)) of the acrylic resin in the emulsion.Type: GrantFiled: May 7, 2004Date of Patent: May 1, 2007Assignee: Nippon Shokubai Co., Ltd.Inventors: Masaya Uchida, Kanji Nakao, Yoshiyuki Yokota
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Patent number: 7186772Abstract: Self-coating or self-layering lacquer systems from at least two different resins, oligomers, or polymers, which are emulsifiable or dispersible in water, have different surface tensions, and form self-layering phases. After the application, the phases separate into the components of the formulation.Type: GrantFiled: September 26, 2003Date of Patent: March 6, 2007Assignee: DaimlerChrysler AGInventors: Reinhold Berkau, Michael Gailberger, Thomas Gruber, Karl Holdik, Georg Meichsner, Fritz Mezger
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Patent number: 7166675Abstract: A thermosetting protective and/or decorative coating composition that includes a co-reactable solid, particulate mixture of a film-forming material that includes a copolymer containing functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the copolymer. The film-forming material makes up from 20 to 95 wt. % and the crosslinking agent makes up from 5 to 80 wt. % of the composition. The composition is applied as a coating and cured, forming a bicontinuous morphology where the film-forming material and the crosslinking agent form separate phases resulting in a low gloss coating as indicated by a specular gloss measurement of not more than 10 gloss units measured at 60° with an appropriate instrument. A method of coating a substrate using the composition, substrates coated using the method, and a multi-component composite coating composition that includes the composition are disclosed.Type: GrantFiled: January 30, 2004Date of Patent: January 23, 2007Assignee: PPG Industries Ohio, Inc.Inventors: Kristin M. Bartlett, Simion Coca, Anthony M. Chasser
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Patent number: 7105601Abstract: An adhesive resin composition comprising, based on the total weight of the composition, a first resin component having one or more glass transition temperatures of about ?15 to about 50° C.; optionally, up to about 49 weight percent of a second resin component having one or more glass transition temperatures greater than about 100° C.; and up to about 50 weight percent of a particulate inorganic filler; wherein a tan ? value of the adhesive resin composition is greater than about 0.2 over a temperature range of about ?15 to about 50° C. when measured at a frequency of 1 Hz. The adhesive resin compostions are of particular utility in suspension assemblies.Type: GrantFiled: December 19, 2002Date of Patent: September 12, 2006Assignee: World Properties, Inc.Inventors: Hong-Fei David Guo, Robert Henry Walker, III
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Patent number: 7074858Abstract: The present invention provides novel compositions prepared from a first oligomer containing reactive functional groups capable of reaction at effective rates (at normal processing temperatures) with a co-reactive second component oligomer possessing functionality that is complementary to that of the first oligomer. The compositions may be used as coatings, including hard surface coatings, clear coatings, powder coatings and pattern coatings; as adhesives, including pressure sensitive adhesives and hot melt adhesives; as sealants; as optical coatings; as blown microfibers (BMF); as high refractive index optical materials; as barrier films; in microreplication; as low adhesion backsizes, (LABs) and as release coatings.Type: GrantFiled: June 4, 2003Date of Patent: July 11, 2006Inventors: Steven M. Heilmann, Babu N. Gaddam, Ahmed S. Abuelyaman, Duane D. Fansler, Todd D. Jones, Maureen A. Kavanagh, Kevin M. Lewandowski, Michael S. Wendland
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Patent number: 7041738Abstract: The present invention provides an additive for improving the cold flow properties of vegetable or animal fuel oil. The additive comprises A) a copolymer of ethylene and 8–21 mol % of at least one acrylic or vinyl ester having a C1–C18-alkyl radical and B) a comb polymer of at least one C8–C16-alkyl ester of an ethylenically unsaturated dicarboxylic acid and at least one C10–C20-olefin, wherein the sum Q Q = ? i ? w 1 ? i · n 1 ? i + ? j ? w 2 ? j · n 2 ? j ?of the molar averages of the carbon chain distributions in the alkyl side chains of the olefins (monomer 1) and the fatty alcohols (monomer 2) is from 23 to 27. In Q, w1 and w2 are the molar proportions of the individual chain lengths in the comb polymer from the different monomers 1 and 2, and n1 and n2 are the side chain carbon atom lengths, excluding comb polymer bonded carbon atoms of monomer 1, and the running variables i and j are the individual side chain lengths in the particular monomer groups.Type: GrantFiled: June 11, 2003Date of Patent: May 9, 2006Assignee: Clariant GmbHInventors: Matthias Krull, Bettina Siggelkow, Martina Hess, Ulrike Neuhaus
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Patent number: 7015286Abstract: The present invention provides melt-processible adhesive compositions prepared from a first oligomer containing reactive functional groups capable of reaction at effective rates (at normal processing temperatures) with a co-reactive second component oligomer possessing functionality that is complementary to that of the first oligomer. The compositions may be used as coatings, including hard surface coatings, clear coatings, powder coatings and pattern coatings; as adhesives, including pressure sensitive adhesives and hot melt adhesives; as sealants; as optical coatings; as blown microfibers (BMF); as high refractive index optical materials; as barrier films; in microreplication; as low adhesion backsizes, (LABs) and as release coatings.Type: GrantFiled: June 4, 2003Date of Patent: March 21, 2006Assignee: 3M Innovative Properties CompanyInventors: Steven M. Heilmann, Babu N. Gaddam, Ahmed S. Abuelyaman, Duane D. Fansler, Todd D. Jones, Maureen A. Kavanagh, Kevin M. Lewandowski, Michael S. Wendland
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Patent number: 6951899Abstract: To provide a method for producing a blend composition of an acrylic type polymer having an excellent mechanical characteristic as well as a low temperature characteristic, and to provide a blend composition of an acrylic type polymer, and also to provide a blend composition of an acrylic type polymer for sealing materials having an excellent abrasion resistance which is important for sealing materials. To prepare a blend composition of an acrylic type polymer by co-precipitation after mixing (A) an aqueous latex of a copolymer—showing about ?10° C. to ?65° C. of a glass transition temperature Tg—obtained by emulsion polymerization or suspension polymerization of at least one of an acrylic ester and methacrylic ester with a vinyl monomer containing crosslinking group with (B) an aqueous latex of copolymer—showing about 0° C.Type: GrantFiled: March 10, 2003Date of Patent: October 4, 2005Assignee: NOK CorporationInventor: Seiji Nakagome
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Medical contact adhesive comprising a two phase adhesive matrix of polyacrylates and polyamine salts
Patent number: 6936661Abstract: A medical pressure sensitive adhesive based on polyacrylates and neutral polyamine salts is characterized in that it has a pressure-sensitive adhesive matrix of two polymer components A and B, with polymer component A being a polyacrylate pressure-sensitive adhesive containing carboxyl groups, the carboxyl groups of which are neutralized; the polymer component B being a neutral polyamine salt obtained by reacting a polyacrylate copolymer containing amino groups with an acid, with the polymer component B being dispersed in the polymer component A, and the two components forming a two-phase system.Type: GrantFiled: July 11, 2001Date of Patent: August 30, 2005Assignee: LTS Lohmann Therapie-Systeme AGInventors: Andreas Koch, Stefan Bracht, Christoph Schmitz -
Patent number: 6858673Abstract: A composition for hydrogels which comprises (A1) a copolymer which comprises 25 to 97 mol % of unit (a) derived from a compound represented by formula (1) and 3 to 75 mol % of unit (b) derived from a monomer represented by formula (2) and is soluble in aqueous media and (B) a polymer which has hydrophilic groups such as hydroxyl or carboxyl groups and is soluble in aqueous media; and a hydrogel comprising the composition. (X represents a divalent organic residue; Y represents alkyleneoxy, etc.; Z, R1, R2, R3, R4, and L2 each represents hydrogen, etc.; and L1 represents —C6H4—, etc.Type: GrantFiled: May 9, 2000Date of Patent: February 22, 2005Assignee: NOF CorporationInventors: Nobuyuki Sakamoto, Kenshiro Shuto, Shujiro Sakaki, Ken Suzuki, Shinji Tanaka
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Patent number: 6833409Abstract: An impact strength modifier comprises an acrylic rubber graft copolymer (I) obtained by graft-polymerizing a polyalkyl (meth)acrylate composite rubber (A) with a vinyl monomer (B), and a compound (II) which has a sulfonic acid group or a sulfuric acid group and also has two or more benzene ring skeletons, or a salt thereof. The polyalkyl (meth)acrylate composite rubber (A) contains two or more acrylic rubber components each having a different glass transition temperature, and the respective acrylic rubber components have 20% by weight or less of a monomer having two or more unsaturated bonds in a molecule. The compound (II) preferably has two or more benzene ring skeletons, and a particle size distribution of the polyalkyl (meth)acrylate composite rubber (A) is preferably a polydisperse distribution in which two or more peaks exist within a specific range.Type: GrantFiled: October 21, 2002Date of Patent: December 21, 2004Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Keiji Nakamura, Masakazu Ito
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Patent number: 6812302Abstract: A process for preparing a liquid rubber composition comprises: (a) Forming a reaction mixture of (i) from 1.0 to 99.999 weight percent of the reaction mixture of at least one C1-C20 alkyl acrylate monomer; and (ii) from 0.001 to 20 weight percent of the reaction mixture of at least one aromatic-containing initiator; (b) charging the reaction mixture into a reactor maintained at a reaction temperature of up to 400° C.; and (c) polymerizing said monomer with said aromatic-containing initiator to form a liquid rubber with polymer chains having at least one non-functional aromatic end-group.Type: GrantFiled: June 18, 2002Date of Patent: November 2, 2004Assignee: Rohm and Haas CompanyInventor: Edward Ewart La Fleur
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Patent number: 6812313Abstract: A polymer comprises polymer chains having a glass transition temperature of less than 25° C. and a weight average molecular weight of less than 20,000 wherein the polymer chains contain at least one non-functional aromatic end-group. The polymer is miscible in the uncured state of said thermoset resins and immiscible in the cured state of the thermoset resins.Type: GrantFiled: June 18, 2002Date of Patent: November 2, 2004Assignee: Rohm and Haas CompanyInventor: Edward Ewart La Fleur
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Patent number: 6803416Abstract: The present invention provides a moulding composition, which includes: a plurality of bead polymers dispersed in at least one matrix polymer; wherein the bead polymers: have an average particle size of 5 to 40 &mgr;m, and have a refractive index nD at 20° C. which is different from a refractive index nD at 20° C. of said matrix polymer; and wherein the bead polymers are prepared by a process, which includes: contacting: at least one polymerizable mix which includes at least 50% by weight of at least one (meth)acrylate monomer, at least one aluminum compound, and an aqueous phase, to prepare a mixture; dispersing the mixture at a shear rate ≧103 s−1 to form a dispersion, wherein the dispersion is stabilized by the aluminum compound; and polymerizing to produce the bead polymers having an average particle size of 5 to 40 &mgr;m.Type: GrantFiled: December 28, 2001Date of Patent: October 12, 2004Assignee: Roehm GmbH & Co. KGInventors: Klaus Schultes, Thomas Suefke, Markus Parusel, Werner Hoess
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Publication number: 20040192849Abstract: A multipurpose masterbatch carrier which includes a chlorinated polyolefin, an acrylic processing aid; and an acrylic impact modifier, and also a method of making such a carrier.Type: ApplicationFiled: February 27, 2004Publication date: September 30, 2004Inventor: Anthony Richard Gaukroger
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Patent number: 6783850Abstract: An acrylic pressure sensitive adhesive composition comprising 5 to 75 parts by weight of an adherent polymer (a) comprising (meth)acrylic ester component units as principal structural units and having a weight average molecular weight of 50,000 or more; 5 to 40 parts by weight of a tackifier resin (b) comprising (meth)acrylic ester component units as principal structural units and having a weight average molecular weight of 20,000 or less; and 20 to 90 parts by weight of monomers (c) whose principal component is a (meth)acrylic ester, wherein substantially no solvent is contained is provided. Further, a pressure sensitive adhesive tape having a pressure sensitive adhesive layer superimposed on a support surface is provided by coating the support surface with the above acrylic pressure sensitive adhesive composition, which contain a partial polymerizate, and carrying out a polymerization reaction on the support surface.Type: GrantFiled: June 21, 2002Date of Patent: August 31, 2004Assignee: Soken Chemical & Engineering Co., Ltd.Inventors: Youichi Takizawa, Mitsuhiko Nakazawa
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Patent number: 6773863Abstract: Disclosed is a novel positive-working chemical-amplification photoresist composition capable of giving an extremely finely patterned resist layer in the manufacturing process of semiconductor devices. The photoresist composition comprises: (A) 100 parts by weight of a copolymeric resin consisting of from 50 to 85% by moles of (a) hydroxyl group-containing styrene units, from 15 to 35% by moles of (b) styrene units and from 2 to 20% by moles of (c) acrylate or methacrylate ester units each having a solubility-reducing group capable of being eliminated in the presence of an acid; and (B) from 1 to 20 parts by weight of a radiation-sensitive acid-generating agent which is an onium salt containing a fluoroalkyl sulfonate ion having 3 to 10 carbon atoms as the anion such as bis(4-tert-butylphenyl) iodonium nonafluorobutane sulfonate.Type: GrantFiled: February 21, 2003Date of Patent: August 10, 2004Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Katsumi Oomori, Hiroto Yukawa, Ryusuke Uchida, Kazufumi Sato
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Patent number: 6743520Abstract: A primer useful in the preparation of an anti-fouling surface contains (I) a copolymer formed from acrylates, free carboxyl group containing monomer and an aromatic sulfonic acid or salt, an acrylic polymeric resin and a cross-linking agent.Type: GrantFiled: December 17, 2002Date of Patent: June 1, 2004Assignee: DuPont Teijin Films US Ltd. PartnershipInventors: Andrew Street, Allan Lovatt, Jane Constance Campbell, Hikaru Takeuchi, Sumio Wakabayashi, Yasuo Fujieda
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Patent number: 6730741Abstract: The present invention provides a processing aid that reduces ungelled products and flow marks generated on a sheet, and improves releasability of the sheet from the metallic surface of a roll, with the processing aid comprising: a copolymer (A) obtained by copolymerizing a monomer mixture comprising 70 to 90% by weight of methyl methacrylate, 10 to 30% by weight of acrylate or methacrylate other than methyl methacryrate and a different type of monomer capable of being copolymerized with those monomers; and a copolymer (B) obtained by copolymerizing a monomer mixture comprising at least 30% by weight of methyl methacrylate and a monomer having as constitutional units at least one type selected from methacrylates other than methyl methacrylate, acrylates, aromatic alkenyl compounds and other monomers.Type: GrantFiled: February 1, 2002Date of Patent: May 4, 2004Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Souichiro Honda, Akira Nakata, Ken Tsuchibe
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Patent number: 6699934Abstract: There is provided a resin composition comprising; (A) from 1 to 99% by weight of a copolymer, which comprises an ethylene unit and an &agr;-olefin unit of 3 to 12 carbon atoms, and satisfies the specific requirements (A-1) to (A-4), and (B) from 99 to 1% by weight of a copolymer, which comprises an ethylene unit and a unit of a compound having a carbon-carbon double bond and an oxygen atom, and satisfies the specific requirements (B-1) and (B-2).Type: GrantFiled: August 10, 2001Date of Patent: March 2, 2004Assignee: Sumitomo Chemical Company, LimitedInventors: Kenzo Chikanari, Satoru Koyama, Daigo Nakanishi