Solid Polymer Derived From Oxygen-containing Reactant Patents (Class 525/231)
  • Patent number: 6429264
    Abstract: A thermoplastic elastomer composition comprising 100 parts by weight of a polyolefin resin, 5 to 250 parts by weight of a rubbery polymer and 0 to 500 parts by weight of an ethylene-&agr;-olefin copolymer rubber, wherein a complex dynamic viscosity &eegr;*(1) at 250° C. is 1.5×105 poise or less and a Newtonian viscosity index n is 0.67 or less, and furthermore, wherein said thermoplastic elastomer composition has a specific tan &dgr; peak, the peak temperature of which is different from that of the polyolefin resin and that of the rubbery polymer, at a temperature within the range from −70 to 30° C. in a temperature dependence curve of tan &dgr; determined by solid dynamic viscoelasticity measurement, powder or pellet thereof, and a molded article thereof.
    Type: Grant
    Filed: April 26, 2001
    Date of Patent: August 6, 2002
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyuki Sugimoto, Yoshihiro Nakatsuji, Susumu Ejiri
  • Patent number: 6410655
    Abstract: A resin composition for an aqueous paint containing different phase structure emulsion particles obtained by multi-stage emulsion polymerization as a binder, wherein the different phase structure emulsion particles have an outermost phase formed by an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from −50° C. to 10° C., and satisfy the following conditions (1) to (3): (1) the emulsion polymer forming the outermost phase contains from 1 to 20 mass % of an ethylenic unsaturated monomer having at least one of a polyethylene glycol chain and a polypropylene glycol chain, (2) at least one phase of inner phases from the outermost phase of the different phase structure emulsion particles comprises an emulsion polymer of an ethylenic unsaturated monomer having a glass transition temperature of from 30° C. to 110° C., and (3) the binder has a minimum film-forming temperature of at most 10° C.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: June 25, 2002
    Assignee: Dai Nippon Toryo Co., Ltd.
    Inventors: Masayoshi Okubo, Shinya Sakaguchi, Atsushi Takamatsu, Hiroharu Sasaki, Kazuyoshi Tsuneta
  • Publication number: 20020061953
    Abstract: In a fluorosilicone rubber composition comprising (A) an organopolysiloxane having trifluoropropyl and (B) a silica filler, there are included (C) an organic peroxide of percarbonate type as a crosslinking agent and (D) a compound having a molecular weight of up to 10,000 and bearing in a molecule at least two substituents selected from among allyl, acryloyl, methacryloyl, epoxy and alkoxy groups as a co-crosslinking agent, whereby the vulcanization molding time is substantially reduced without detracting from physical properties.
    Type: Application
    Filed: August 31, 2001
    Publication date: May 23, 2002
    Inventors: Kenichi Takita, Kunihiko Mita
  • Patent number: 6388012
    Abstract: A thermosetting powder paint composition comprising (A) a resin composition component, (B) a hardener component and (C) a solid flow controlling component, wherein the component (A) contains a resin composition component having reactivity with the component (B), the component (B) contains a hardener having reactivity with the component (A), the component (C) contains a vinyl polymer which is solid at 20° C., and the relation between SPA of the component (A) and SPC of the component (C) satisfies the following numerical formula (1) and the following numerical formula (2) simultaneously. By this constitution, excellent blocking-resistance in storing as the powder paint composition and excellent appearance properties of a paint film formed by coating the powder paint composition can be simultaneously manifested. 8≦SPA≦13  (1) 7≦SPC≦SPA  (2).
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: May 14, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroyuki Sakayama, Yoshio Kikuta, Mitsuyuki Mizoguchi, Takahisa Miyawaki, Tsuyoshi Matsumoto
  • Patent number: 6380313
    Abstract: A polymer processing aid composition, a melt processable polymer composition that uses the polymer processing aid, and a method of improving the melt processability of a thermoplastic polymer are provided. The polymer processing aid composition comprises a fluoropolymer that comprises interpolymerized units derived from a perfluorovinyl ether, preferably one having the formula CF2═CF—(OCF2CF(CF3))AORf where a has a value of 0 to 3 and Rf is a perfluoroaliphatic (preferably perfluoroalkyl or perfluoroalkoxy) having from 1 to 8 (preferably 1 to 3) carbon atoms.
    Type: Grant
    Filed: June 27, 2000
    Date of Patent: April 30, 2002
    Assignee: Dyneon LLC
    Inventors: Maria P. Dillon, Harald Kaspar, Bernhard Hirsch, Klaus Hintzer, Karl-Dieter Weilandt
  • Publication number: 20020007014
    Abstract: A pressure-sensitive adhesive comprising a blend of at least two components, wherein the first component is at least one pressure-sensitive adhesive and the second component is at least one thermoplastic material, wherein the components form a blended composition having more than one domain and, wherein one domain is substantially continuous (generally, the pressure-sensitive adhesive) and the other domain is substantially fibrinous to schistose (generally, the thermoplastic material). The second component can be (a) at least one thermoplastic elastomer, (b) at least one elastomer with a tackifying resin or (c) at least one elastomer.
    Type: Application
    Filed: June 13, 2001
    Publication date: January 17, 2002
    Applicant: Minnesota Mining and Manufacturing Company
    Inventors: Patrick D. Hyde, Dennis L. Krueger, Felix P. Lau, Eumi Pyun, Robert W. Shipman, Pamela S. Tucker, Roy Wong, David J. Yarusso
  • Patent number: 6331582
    Abstract: A liquid surface coating composition which exhibits low gloss after curing or drying comprises binder resin other than polyvinyl acetal, pigment colorant and a gloss-reducing amount of matting agent consisting essentially of polyvinyl acetal containing acetal groups derived from one or more aliphatic or aromatic aldehydes having 1 to 10 carbon atoms, preferably polyvinyl butyral of weight average molecular weight between 10,000 to 500,000 Daltons.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: December 18, 2001
    Assignee: Solutia Inc.
    Inventors: Augustin T. Chen, Paul E. Kestyn, Hong Zhao
  • Patent number: 6316090
    Abstract: A thermoplastic elastomer composition comprising 100 parts by weight of a polyolefin resin, 5 to 250 parts by weight of a rubbery polymer and 0 to 500 parts by weight of an ethylene-&agr;-olefin copolymer rubber, wherein a complex dynamic viscosity &eegr;*(1) at 250° C. is 1.5×105 poise or less and a Newtonian viscosity index n is 0.67 or less, and furthermore, wherein said thermoplastic elastomer composition has a specific tan &dgr; peak, the peak temperature of which is different from that of the polyolefin resin and that of the rubbery polymer, at a temperature within the range from −70 to 30° C. in a temperature dependence curve of tan &dgr; determined by solid dynamic viscoelasticity measurement, powder or pellet thereof, and a molded article thereof.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: November 13, 2001
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyuki Sugimoto, Yoshihiro Nakatsuji, Susumu Ejiri
  • Publication number: 20010034410
    Abstract: The invention relates to additives for improving the cold flow properties of middle distillates, containing from 10 to 95% by weight of copolymers A), from 5 to 90% by weight of copolymers B) and, if required, from 0 to 70% by weight of copolymers C), which correspond to the following formulae:
    Type: Application
    Filed: March 14, 2001
    Publication date: October 25, 2001
    Applicant: Clariant GmbH
    Inventors: Matthias Krull, Thomas Volkmer, Werner Reimann
  • Patent number: 6306520
    Abstract: There are provided; a laminated film or sheet formed by adhesively integrating a resin layer (1) of an acrylic resin with a resin composition layer (2) of a polyolefin resin composition, the polyolefin resin composition comprising an ethylene based copolymer (a) prepared by polymerizing ethylene with at least one compound selected from the group consisting of unsaturated carboxylic acids, unsaturated carboxylic esters, unsaturated carboxylic anhydrides and vinyl acetate, a polyethylene resin (b) excluding the copolymer (a), and a polypropylene resin (c), which is characterized in that the layers (1) and (2) are adhesively integrated with each other to the satisfaction, even if no layer of an adhesive agent is interposed between them; and a laminated structure formed by adhesively integrating the laminated film or sheet with a substrate of a polyolefin resin, which is particularly suitable for uses such as interior or exterior car parts, electric appliances, parts of miscellaneous goods and signboards.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: October 23, 2001
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Makoto Nagata, Hiroaki Takahata
  • Publication number: 20010025084
    Abstract: A substrate for solid phase synthesis comprising a solid phase-linker combination of the formula I is disclosed. Also disclosed are processes for preparing the substrate and chemical intermediates useful therein. Among the novel intermediates are compounds of the formula II wherein R1 is —NO2 or —CHO; R2 is —OCH3, —CHO or —H; R3 is chosen from the group consisting of hydroxyl, the residue of a solid support having a plurality of amino groups, and the residue of an ester, and n=1 or 3-12.
    Type: Application
    Filed: January 22, 2001
    Publication date: September 27, 2001
    Inventors: Vinh D. Tran, Vu Van Ma, Ruiyan Liu
  • Publication number: 20010018495
    Abstract: The invention relates to rubber blends containing said at least one solution-polymerized rubber containing hydroxyl groups, synthesized from diolefins and vinylaromatic monomers, wherein said at least one solution-polymerized rubber containing hydroxyl groups contain in the region of 0.1 to 5 wt. % of bonded hydroxyl groups, to a process for their preparation and to their use for the production of all kinds of moldings.
    Type: Application
    Filed: April 11, 2001
    Publication date: August 30, 2001
    Inventors: Thomas Scholl, Ulrich Eisele, Jurgen Trimbach, Stefan Kelbch
  • Patent number: 6277487
    Abstract: The present invention provides a fluoropolymer coating composition which is capable of coating thick and forming a coating film being excellent in abrasion resistance, corrosion resistance and non-sticking property, and provides a coated article obtained by coating the above-mentioned composition as a top coat. The fluoropolymer coating composition comprises fine particles of a fluoropolymer, 0.
    Type: Grant
    Filed: October 22, 1998
    Date of Patent: August 21, 2001
    Assignee: Daikin Industries, Ltd.
    Inventors: Yoshihiro Soda, Nobuyuki Tomihashi
  • Publication number: 20010007892
    Abstract: A rubber composition obtained by
    Type: Application
    Filed: February 5, 2001
    Publication date: July 12, 2001
    Applicant: Sumitomo Rubber Industries, Ltd.
    Inventors: Yasuhisa Minagawa, Hiroki Sarashi, Minoru Ueda
  • Patent number: 6254956
    Abstract: A floor, wall or ceiling covering which comprises one or more substantially random interpolymers prepared by polymerizing one or more &agr;-olefin monomers with one or more vinylidene aromatic monomers and/or one or more hindered aliphatic or cycloaliphatic vinylidene monomers, and optionally with other polymerizable ethylenically unsaturated monomer(s). The floor, wall or ceiling covering has a good balance of properties, such as sufficient flexibility and conformability to uneven or contoured surfaces for efficient application to floors, walls, or ceilings, sufficient scratch resistance, sufficient indentation resistance, indentation recovery and/or sufficient abrasion resistance.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: July 3, 2001
    Assignee: The Dow Chemical Company
    Inventors: Jerker B. I. Kjellqvist, Stephen R. Betso, Ronald Wevers, Johan A. Thoen, John O. Bieser
  • Publication number: 20010003769
    Abstract: A rubber-modified styrene type polymer excellent in transparency and excellent in impact strength and moldability, is presented.
    Type: Application
    Filed: December 20, 2000
    Publication date: June 14, 2001
    Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHA
    Inventors: Takeshi Yamada, Tetsuya Shinmura
  • Publication number: 20010003770
    Abstract: A resin composition for an aqueous paint containing different phase structure emulsion particles obtained by multi-stage emulsion polymerization as a binder, wherein the different phase structure emulsion particles have an outermost phase formed by an emulsion polymer of an ethylenic unsaturated monomer, having a glass transition temperature of from −50° C. to 10° C.
    Type: Application
    Filed: December 8, 2000
    Publication date: June 14, 2001
    Applicant: Dai Nippon Toryo Co., Ltd.
    Inventors: Masayoshi Okubo, Shinya Sakaguchi, Atsushi Takamatsu, Hiroharu Sasaki, Kazuyoshi Tsuneta
  • Patent number: 6166168
    Abstract: A novel polyalkyl ether/polyaryl ether sulfone or ketone copolymer and a specific polyether ester copolymer are useful for producing a medical material to be used to contact the blood; and methods for producing the medical material comprising said polyalkyl ether/polyaryl ether sulfone or ketone copolymer or a specific polyether ester copolymer.
    Type: Grant
    Filed: March 17, 1999
    Date of Patent: December 26, 2000
    Assignee: Teijin Limited
    Inventors: Hiroaki Kuwahara, Takeyuki Kawaguchi, Satoru Ohmori, Shunichi Matsumura
  • Patent number: 6153701
    Abstract: A wettable polypropylene composition comprising polypropylene and a hydrophilic, polar compound which includes functional sites selected from the group consisting of carboxyl, hydroxy, ether or ester moieties, wherein the polypropylene composition is wettable, having a contact angle less than or equal to 75.degree.. The hydrophilic polar compounds are selected from the group consisting of maleic anhydride-modified polypropylene (MAPP), acrylic acid modified polypropylene, ethylene acrylate modified polypropylene, polypropylene grafted with a sodium salt of an acrylic acid, polyethylene glycol (PEG), modified polyethylene glycol, polyvinyl alcohol (PVOH), polyvinyl formal (PVF); and monomer and dimer fatty acids having a carbon chain length in the range of 6 to 50, preferably 18 to 36. The compositions can further include the presence of an amorphous compound and surfactants.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: November 28, 2000
    Assignee: International Paper Company
    Inventors: Prasad S. Potnis, Ashok M. Adur, Wayne Chu
  • Patent number: 6127482
    Abstract: A composition comprising:(a) polyethylene;(b) a cure booster selected from the group consisting of 3,9-divinyl-2,4,8,10-tetra-oxaspiro[5.5]undecane (DVS); a copolymer of ethylene and DVS; and an ethylene homopolymer or copolymer having DVS grafted thereto; and(c) an organic peroxide.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: October 3, 2000
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Michael John Keogh
  • Patent number: 6127325
    Abstract: A viscosity index improver for addition to lubricating oil or the like, which comprises a graft copolymer having structural units of an oil-soluble polymer (a) comprising an olefin polymer and structural units of a copolymer (b) of a monomer having a peroxide bond with a (meth)acrylate or the like or a copolymer (c) of a monomer having a peroxide bond with 2-hydroxyethyl(meth)acrylate or the like. The improver is excellent in the effect of improving the viscosity index, the thickening effect, the fluidity at low temperatures and the shear stability, and has no fear of causing phase separation in lubricating oil.
    Type: Grant
    Filed: October 5, 1998
    Date of Patent: October 3, 2000
    Assignee: NOF Corporation
    Inventors: Shuji Suyama, Yoshiki Higuchi, Hidefumi Tochigi, Hiroshi Ohmura
  • Patent number: 6110849
    Abstract: A thermoplastic composition that comprises a mixture of a polyethylene oxide polymer, a polyolefin polymer, a polyester polymer, and, optionally, a compatibilizer for the polymers. One embodiment of such a thermoplastic composition is a mixture of polyethylene oxide polymer, poly(lactic acid) polymer, and polyethylene polymer. The thermoplastic composition is capable of being extruded into fibers that may be formed into nonwoven structures that may be used in a disposable absorbent product intended for the absorption of fluids such as body fluids.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: August 29, 2000
    Assignee: Kimberly-Clark Worlwide, Inc.
    Inventors: Fu-Jya Tsai, Brian T. Etzel
  • Patent number: 5998546
    Abstract: An anti-static resinous composition with permanent anti-static property is provided. The anti-static resinous composition comprises from 5 to 50 percent by weight of hydrophilic copolymer and from 50 to 95 percent by weight of thermoplastic. The hydrophilic copolymer is formed by self-emulsion polymerization. The monomer mixture used in the reaction comprises from 10 to 70 percent by weight of vinyl or propenyl macromonomer containing a polyethylene oxide chain and from 30 to 90 percent by weight of ordinary vinyl monomer. The thermoplastic is compatible with the hydrophilic copolymer. The resultant resinous composition has permanent anti-static properties.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: December 7, 1999
    Assignee: Industrial Technology Research Institute
    Inventors: Kuo-Chen Li, Jui-Ming Ni, Tsai-Wie Tseng, Jen-Lien Lin
  • Patent number: 5919845
    Abstract: The present invention relates to a powder coating having improved surface properties which contains from 0.05 to 5% by weight, preferably 0.5 to 1.5% by weight, of aliphatic polyvinyl ethers.
    Type: Grant
    Filed: April 23, 1998
    Date of Patent: July 6, 1999
    Assignee: BASF Coatings AG
    Inventors: Richard Foukes, Klaus Cibura, Rolf Boysen, Josef Rademacher
  • Patent number: 5900462
    Abstract: A curable resin composition comprises a compound containing a primary hydroxyl group and a compound containing a ketone group, in which the compound containing the ketone group is a compound in which at least one of the carbon atoms adjacent to the carbonyl carbon bonds to a hydrogen atom, and the curable resin composition can give a cured product having a high crosslink density by means of a dehydrating reaction between the primary hydroxyl group and the ketone group and the subsequent crosslinking of a vinyl bond formed by the dehydrating reaction.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: May 4, 1999
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventor: Hozumi Tanaka
  • Patent number: 5891956
    Abstract: Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: April 6, 1999
    Assignee: The Regents of the University of California, Office of Technology Transfer
    Inventors: Barbara F. Smith, Thomas W. Robison, Joel W. Gohdes
  • Patent number: 5840806
    Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: November 24, 1998
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka
  • Patent number: 5804652
    Abstract: A method and composition for coating a metal for use in connection with improving corrosion resistance and paint adhesion. The composition is a non-corrosive ester cross-linked polymer system having a plurality of carboxylic functional groups and a plurality of hydroxyl groups. The polymer system may be a bifunctional copolymer or the reaction product of a first polymer having a plurality of carboxylic functional groups (e.g. polyacrylic acid or polymethylvinylmaleic anhydride), and a second polymer having a plurality of hydroxyl groups (e.g. polyvinyl alcohol). The resulting reaction product of these two polymers is a cross-linked polymeric blend. A compound of a Group IV-B element may be added to this polymer blend to increase the degree of cross-linking and improve paint adhesion and corrosion resistance. Such a Group IV-B compound may be an acid such as fluozirconic acid, fluotitanic acid or fluohafnic acid, or a salt such as ammonium zirconium carbonate.
    Type: Grant
    Filed: May 30, 1996
    Date of Patent: September 8, 1998
    Assignee: Bulk Chemicals, Inc.
    Inventors: Lawrence E. Jones, Michael D. Wert, JoseB. Rivera
  • Patent number: 5736229
    Abstract: In order to improve the printing capability with high-performance laser printers and the subsequent processing of a single-layered paper article, in particular, a single-sheet mailer having an adhesive coating adapted to be activated for adhering a single layer with itself or with further layers, it is suggested that a component is added to the adhesive coating which can absorb the separating agents used during laser printing and can remove them from the paper surface. According to the invention, additives of oleophilic bentonite and/or polyvinyl alkylether and/or polyethylene glycol are suggested.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: April 7, 1998
    Assignee: Drescher Geschaeftsdrucke GmbH
    Inventor: Reinhold Uhlemayr
  • Patent number: 5733538
    Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 31, 1998
    Assignee: Thoratec Laboratories, Inc.
    Inventor: Judy S. Riffle
  • Patent number: 5684089
    Abstract: A pregellable adhesive containing several polymers, of which at least one is olefinically unsaturated and the other capable of curing by esterification, prepared in such a way that it cures by two different chemical reaction mechanisms which can be activated successively and catalyzed at least substantially independently of one another.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: November 4, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thierry Lanoye, Anne-Marie Garnault
  • Patent number: 5665822
    Abstract: Thermoplastic elastomers (TPEs) containing side chain crystalline (SCC) blocks. The SCC blocks my be hard (A) blocks or the soft (B) blocks (or both) in the TPE. Some of these TPEs are novel, e.g. those in which A blocks are SCC blocks, and the B blocks are polyethers, polyacrylates, polyamides, polyurethanes or polysiloxanes. The SCC-containing TPEs are particularly useful as matrix materials for other components which are dispersed therein, e.g. energetic solids and other thermally responsive materials.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: September 9, 1997
    Assignee: Landec Corporation
    Inventors: Steven P. Bitler, Ray F. Stewart, David A. Kamp, Robert G. Freelin, Valentine Y. Yoon
  • Patent number: 5650205
    Abstract: A flame-retardant resin composition comprising 100 parts by weight of a thermoplastic resin, from 10 to 80 parts by weight of a bis(halogenophenyl)terephthalamide, and from 5 to 40 parts by weight of antimony trioxide; an electric wire comprising a conductor having thereon an insulating layer comprising the resin composition; and a tube or a heat-shrinkable tube comprising the resin composition.
    Type: Grant
    Filed: April 13, 1993
    Date of Patent: July 22, 1997
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventor: Satoshi Shukushima
  • Patent number: 5622783
    Abstract: A pressure-sensitive adhesive composition comprising an ethylene-vinyl chloride polymer containing at least 40% by weight of the polymer of vinyl-acetate to serve as a permanent pressure-sensitive adhesive for bonding front materials to plasticizer vinyl and other substrates.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: April 22, 1997
    Assignee: Avery Dennison Corporation
    Inventors: L. Huizer, H. van der Bent, P. J. Heederik
  • Patent number: 5569710
    Abstract: Polymer blends of at least one polar polymer are prepared by admixture with a poly(vinyl alcohol) and a (meth)acrylate copolymer also containing vinyl amide and/or unsaturated acid units. The ternary compositions have attractive processing and performance properties.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: October 29, 1996
    Assignee: Rohm and Haas Company
    Inventors: Edward E. LaFleur, William J. Work, Robert M. Amici, Newman M. Bortnick, Norman L. Holy
  • Patent number: 5559192
    Abstract: An air curing polymer composition is disclosed which contains acetoacetate functional polymer and an autoxidizable material. The composition cures on exposure to oxygen. One pack stable ambient curing compositions and a method of stabilizing acetoacetate functional groups to prevent hydrolysis are also disclosed.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 24, 1996
    Assignee: Rohm and Haas Company
    Inventors: Daniel A. Bors, Alvin C. Lavoie, William D. Emmons
  • Patent number: 5548029
    Abstract: Graft copolymers which are isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: August 20, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Kenneth W. Powers, Hsien-Chang Wang, T-C. Chung, Anthony J. Dias, Joseph A. Olkusz
  • Patent number: 5514752
    Abstract: Moldings which have been produced by thermoplastic forming from a polypropylene molding composition which comprises polypropylene or ethylene/propylene copolymers and polyvinyl butyral of the formula ##STR1## have considerable advantages over moldings of a polypropylene molding composition without PVB, since they have a higher surface tension and can therefore be coated, printed on, written on and laminated without problems without further pretreatment of the surface.
    Type: Grant
    Filed: September 20, 1994
    Date of Patent: May 7, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Matthias Gutweiler, Hans-Jurgen Zimmermann
  • Patent number: 5510421
    Abstract: Azlactone-functional membranes prepared by solvent phase inversion techniques are disclosed. Adduct membranes prepared by the reaction of azlactone-functional membranes with nucleophilic reagents are also disclosed. Both azlactone-functional copolymers and blends of azlactone-functional homopolymers or copolymers with blending polymers can be used. These azlactone-functional membranes have azlactone functionality throughout all surfaces formed ab initio into any desired shape. Membrane properties can be modified by sacrifice of some azlactone functionality via crosslinking between azlactone moieties or coupling of hydrophilic ligands.
    Type: Grant
    Filed: May 26, 1994
    Date of Patent: April 23, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kathleen A. Dennison, Monserrat R. La Londe, James S. Stefely
  • Patent number: 5498670
    Abstract: Disclosed herein are crosslinked spherical fine particles having good toughness, elastic properties, and chemical properties, and a process for producing the same, said fine particles being obtained by radical polymerization in the suspended state of a component [M] capable of radical polymerization containing a vinyl group-containing compound (V) capable of radical polymerization which is obtained by reaction of (a) a selected polyol, (b) an isocyanate group-containing compound, and (c) an active hydrogen-containing vinyl monomer capable of radical polymerization. Also disclosed herein are the secondary products of the crosslinked spherical fine particles, which include a coating composition and its derivatives (such as filmlike article, sheetlike article, adhesive filmlike article, and adhesive sheetlike article) and a peelable pressure-sensitive adhesive and peelable pressure-sensitive adhesive article.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: March 12, 1996
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Takahiro Aoyama, Mitsuo Nakazaki, Akikazu Banba, Masatoshi Yoshida, Toshiaki Matsunaga, Tsuneo Tsubakimoto
  • Patent number: 5492787
    Abstract: A resin composition for toners with excellent characteristics is provided. The composition comprises, as principal components, a resin (A) containing carboxyl groups and a resin (B) containing glycidyl or .beta.-methylglycidyl groups, wherein the resin (A) is obtained by a reaction between a multivalent metal compound (m) and copolymer .alpha., said copolymer .alpha. being obtained from a styrene type monomer (a), a (meth)acrylic ester monomer (b), and a vinyl type monomer (c) containing carboxyl groups, and the resin (B) is copolymer .beta. obtained from a vinyl type monomer (d) containing glycidyl or .beta.-methylglycidyl groups and another vinyl type monomer (e).
    Type: Grant
    Filed: February 6, 1995
    Date of Patent: February 20, 1996
    Assignee: Sekisui Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takayoshi Matsunaga, Susumu Tanaka, Yoshiyuki Kosaka, Tatsuo Suzuki, Masazumi Okudo
  • Patent number: 5476902
    Abstract: A processing agent for polyvinyl chloride and other thermoplastic polymers. The processing agent is a copolymer which contains a monomer whose homopolymer has a T.sub.g .gtoreq.65 C. and contains 3 to less than 75% by weight of a comonomer which has a C.sub.8 -C.sub.22 alkyl component. The alkyl component should be apportioned in such a fashion that the transmission of the copolymer in ethyl acetate is at least 90% in the case of a 10% solution.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: December 19, 1995
    Assignee: Degussa Aktiengesellschaft
    Inventors: Volker H. Schull, Detlef Arnoldi
  • Patent number: 5470895
    Abstract: A process that is provided for agglomerating rubber particles of a rubbery latex. The process involves producing an agglomerating agent which is in the form of latex having particles which comprise high molecular weight polyoxyethylene bound therein. The agglomerating agent is affixed with an elastomeric latex to form agglomerated elastomeric particles. The process results in the formation of uniform size agglomerating particles, and utilizes a non-surfactant form of polyoxyethylene, which can be utilized in small amounts to yield the desired agglomerated elastomeric latex. The agglomerated particles may then be utilized as the substrate for graft copolymers, such as acrylonitrile-butadiene-styrene graft copolymers.
    Type: Grant
    Filed: June 13, 1994
    Date of Patent: November 28, 1995
    Assignee: General Electric Company
    Inventors: Kevin R. Kidder, Vijaya K. Kuruganti, Donald M. Kulich, John F. Graf
  • Patent number: 5430104
    Abstract: Polymer mixtures made from two different polymer components and exhibiting LCST behavior are provided for use in applications which require temperature-dependent light permeability. The polymer mixtures P are made from:P1: from 98 to 2% by weight of poly-.alpha.-methylstyrene (PAMs); andP2: from 2 to 98% by weight of polyvinyl methyl ether (PVMe).
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: July 4, 1995
    Assignee: Roehm GmbH Chemische Fabrik
    Inventors: Werner Siol, Ulrich Terbrack
  • Patent number: 5399642
    Abstract: This invention relates to latent thiol mercaptan chain transfer agents and their use in the synthesis of polymers. In addition, this invention relates to novel polymers and block copolymers formed using these latent thiol mercaptan chain transfer agents.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: March 21, 1995
    Assignee: Rohm & Haas Company
    Inventors: William D. Emmons, Andrew W. Gross
  • Patent number: 5367003
    Abstract: Environmentally friendly, disposable, degradable and/or recyclable plastic articles are made from water soluble, miscible, high molecular weight, thermoplastic, polymeric resin blends that are comprised by weight of about 65% to 95% high molecular weight water soluble thermoplastic resin having an inverse solubility characteristic and about 35% to 5% of at least one of certain high molecular weight thermoplastic polymers that are functionally compatible (miscible) with the inversely soluble resin. The articles are insoluble when used for their intended purposes, but become soluble when exposed to tepid or cool water and degradable when buried in a land fill or compost. The inversely soluble resin comprises high molecular weight poly(ethylene oxide). The compatible polymer is selected from the group consisting of Nylon 11, Nylon 12, polycaprolactone, polycaprolactone, polyethylene-co-acrylic acid, polyethylene-co-methacrylic acid, polyethylene-co-vinylacetate and polyethylene-co-vinylalcohol.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: November 22, 1994
    Inventor: Robert J. Petcavich
  • Patent number: 5359006
    Abstract: Hot-melt adhesives based upon a mixture composed of poly(vinylmethylether), greater than about 10 weight percent of a thermoplastic resin and, optionally a tackifier resin and/or extender, are found to be superior for the binding of polyolefins such as polyethylene, polypropylene, and ethylene-propylene copolymers to themselves and to other substrates. In particular, the hot-melt adhesives are useful for bonding polyethylene-backed and latex-backed carpet to polyethylene, polypropylene, or ethylene-propylene copolymer.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: October 25, 1994
    Assignee: Amoco Corporation
    Inventors: Matthew A. Kulzick, Wayne R. Pretzer, Tsuei-Yun Lynch, Paul A. Koning
  • Patent number: 5330832
    Abstract: A water soluble pressure sensitive adhesive composition is disclosed wherein polyvinyl methyl ether is the major component and a styrenic block copolymer is the second component, the polyvinyl methyl ether and styrenic block copolymer present in a weight ratio of from about 95:5 to about 88:12, said styrenic block copolymer in said composition comprising less than about 14 percent by weight of the weight of the polyvinyl methyl ether. The pressure sensitive adhesive is useful for bonding polyethylene, polypropylene, ethylene-propylene copolymers, and paper.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: July 19, 1994
    Assignee: Amoco Corporation
    Inventor: Wen-Feng Liu
  • Patent number: 5322901
    Abstract: The disclosure describes a resin and rubber composition with good heat-shrinkability characteristics. Also described is a resin and/or rubber composition having dispersed therein a metal compound used for heating the composition.
    Type: Grant
    Filed: October 25, 1991
    Date of Patent: June 21, 1994
    Assignee: Toyoda Gosei Co., Ltd.
    Inventor: Mitsuru Kato
  • Patent number: 5321080
    Abstract: A resin composition comprising an olefin resin (A), a copolymer of olefin with non-conjugated diene (B) and at least one polymer (C) selected from the group consisting of the following polymers;C1: diene polymer containing a hydroxyl group or the hydrogenation product thereof,C2: polymer containing a hydroxyl group,C3: polymer containing a carboxyl group (including an acid anhydride group),C4: polymer containing an amino group and/or imino group, andC5: polymer containing an epoxy group; and optionally an elastomer (D), filler (E) and at least one compound (F) selected from the group consisting of the following compounds;F1: organotin compound,F2: tertiary amine compound, andF3: phosphorus oxy compound.The moldings prepared from this resin composition have remarkable adhesive properties for paints, adhesives and printing inks. Thus, paints, etc. may be applied directly to the moldings, without surface treatment or washing thereof.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: June 14, 1994
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Yuta Kumano, Sadao Kitagawa, Mitsushige Baba, Shiroh Gotoh