Solid Polymer Derived From Reactant Containing At Least Two Ethylenic Groups And Is Devoid Of Aryl Ring Patents (Class 525/232)
  • Publication number: 20080269385
    Abstract: A non-halogenated rubber compound is provided for use in conveyor belts, particularly those used in underground mining. The non-halogenated rubber compound is fire-resistant in accordance with MSHA standards and produces acceptable levels of toxicity and smoke upon burning. Such non-halogenated rubber compound includes a blend of rubbery polymers in combination with aluminum trihydrate, which is a fire retardant, and optionally a phosphate plasticizer, which can provide the rubber compound with a more desirable workability. The blend of rubbery polymers is composed of natural rubber and butadiene rubber, and optionally styrene-butadiene rubber, such blend being present in a total amount of 100 phr. In one embodiment, the aluminum trihydrate is present in an amount of about 30 phr to about 150 phr. In another embodiment, the phosphate plasticizer is present in an amount of about 10 phr to about 60 phr.
    Type: Application
    Filed: April 25, 2007
    Publication date: October 30, 2008
    Inventors: Kenneth Michael Alexander, David Joseph Maguire
  • Publication number: 20080245477
    Abstract: A resealable adhesive formulation comprises a paraffinic hydrocarbon, an aliphatic ester, an aliphatic alcohol, an acrylate adhesive, a surfactant free of perfluoroalkylsulfonyl groups and optionally a tackifying resin. The adhesive is capable of multiple open/close cycles and is particularly useful for resealable cassettes and cartridges for medical imaging films.
    Type: Application
    Filed: September 12, 2007
    Publication date: October 9, 2008
    Inventors: Roland John Koestner, Scott L. Salcido
  • Publication number: 20080249232
    Abstract: The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Application
    Filed: April 3, 2008
    Publication date: October 9, 2008
    Inventors: Sudhin Datta, Charles L. Sims, Peijun Jiang, Abdelhadi Sahnoune, Derek W. Thurman
  • Publication number: 20080249231
    Abstract: The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Application
    Filed: April 3, 2008
    Publication date: October 9, 2008
    Inventors: Sudhin Datta, Charles L. Sims, Peijun Jiang, Abdelhadi Sahnoune, Derek W. Thurman
  • Publication number: 20080233399
    Abstract: A vinyl.cis-polybutadiene rubber is provided containing 1,2-polybutadiene and a polymer substance of a melting point lower than that of the 1,2-polybutadiene and with at least one unsaturated double bond per repeating unit, where the 1,2-polybutadiene and the polymer substance are dispersed at physically and/or chemically adsorbed states in the cis-polybutadiene rubber as the matrix component of the vinyl.cis-polybutadiene rubber, and a method for producing the same, to provide a vulcanized product exerting a small die swell ratio and excellent extrusion processability and operability, as well as very great characteristics demanded for the side tread of tire and the like.
    Type: Application
    Filed: December 2, 2004
    Publication date: September 25, 2008
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Yoshio Asakura, Yasuyoshi Okabe
  • Patent number: 7423089
    Abstract: This invention relates to preparation of rubber compositions comprised of EPDM and conjugated diene-based elastomer, particularly including cis 1,4-polyisoprene rubber, and particularly natural cis 1,4-polyisoprene rubber, blends and pneumatic rubber tire with an outer, visible sidewall layer of a rubber composition comprised of such rubber composition. For such preparation, a combination of at least two diverse EPDM elastomers is used together with a phase mixing process comprised of sequential phase mixing or parallel phase mixing in the sense of reinforcement filler and sulfur curatives.
    Type: Grant
    Filed: October 13, 2005
    Date of Patent: September 9, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Junling Zhao, Aaron Scott Puhala, Bina Patel Botts, Brad Stephen Gulas
  • Patent number: 7423086
    Abstract: Disclosed herein is an ethylene-propylene-diene EPDM rubber composition with improved adhesion properties. The ethylene-propylene-diene rubber composition comprises an EPDM rubber, a crystalline polyolefin, and a polyolefin containing at least one carbonyl group (—C?O) within the structure as an adhesion improver. The ethylene-propylene-diene rubber composition improves adhesion to a polar polymeric material. Specifically, the EPDM rubber composition comprises 100 phr of an EPDM rubber, 5˜40 phr of a polyolefin containing at least one carbonyl group and 10˜30 phr of a crystalline polyolefin resin.
    Type: Grant
    Filed: January 6, 2005
    Date of Patent: September 9, 2008
    Assignee: Kumho Polychem Co., Ltd.
    Inventors: Sang Bae Kim, Gyu Yeop Lee
  • Publication number: 20080188592
    Abstract: The invention includes select blends of elastomeric compositions of at least one halogenated elastomer and at least one other elastomer to impart certain properties to articles made from those select blends. For example, the at least one halogenated elastomer may be at least one halogenated butyl rubber, at least one halogenated star-branched butyl rubber, or at least one halogenated random copolymer of a C4 to C7 isomonoolefin derived unit, such as an isobutylene derived unit, and at least one other polymerizable unit, such as methylstyrene. The invention also includes methods to improve the brittleness point of articles made from those select blends.
    Type: Application
    Filed: September 30, 2005
    Publication date: August 7, 2008
    Inventors: Walter Harvey Waddell, Donald Sheley Tracey, Glenn Edward Jones
  • Publication number: 20080188621
    Abstract: Provided is a rubber composition which can give a tire excellent in braking performance and fuel consumption and which is excellent in mechanical strength and fatigue resistance, and a use thereof. The rubber composition of the present invention contains a (A) 60 to 0.1 parts by weight of a nonconjugated polyene copolymer, which is a random copolymer containing 96 to 70 mol % of the structural units derived from ?-olefin (A1) and 4 to 30 mol % of the structural units derived from a nonconjugated polyene (A2), and has a glass transition temperature (Tg) of ?25 to 20° C., (B) 40 to 99.9 parts by weight of a diene rubber and (C) at least one selected from the group consisting of specific polymers.
    Type: Application
    Filed: April 28, 2005
    Publication date: August 7, 2008
    Inventors: Kotaro Ichino, Masao Kunizane, Yuji Ishit, Kunihide Hiraoka, Masaaki Kawasaki, Hidetatsu Murakami, Keiji Okada
  • Patent number: 7393897
    Abstract: The method for manufacturing a thermoplastic elastomer composition of the present invention comprises continuously feeding a mixture comprising pelletized olefinic resin (A), a pulverized product (B) obtained by pulverizing bulk olefinic rubber, and a crosslinking agent (C) into a continuous kneading machine, and performing a dynamic heat treatment to yield the thermoplastic elastomer composition. An olefinic thermoplastic elastomer composition having excellent tensile characteristics and molded appearance can be manufactured with high productivity by the method of the present invention.
    Type: Grant
    Filed: February 26, 2003
    Date of Patent: July 1, 2008
    Assignee: Mitsui Chemicals, Inc.
    Inventor: Yuichi Ito
  • Patent number: 7390850
    Abstract: A thermoplastic elastomer composition comprises a blend of a thermoplastic component with a cured elastomer component characterised in that the elastomer component prior to curing comprises a major proportion of a main elastomer and a minor proportion of a high molecular weight reactive polymer which shows a higher crosslinking efficiency in free-radical induced vulcanisation than the main elastomer. Preferably, the high molecular weight reactive polymer comprises from (3) to (15), and more preferably (4) to (10), parts by weight per one hundred parts of the total elastomer component of the composition. The use of the high molecular weight reactive polymer in the composition improves the low temperature performance of the composition and gives improvements to the processing behaviour, the resistance to stiffening at low temperatures and recovery/relaxation properties. Preferably, the high molecular weight reactive polymer is miscible with the main elastomer in the elastomer component.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: June 24, 2008
    Assignee: Tun Abdul Razak Research Centre
    Inventors: Stuart Cook, Andrew Tinker, Jaymini Patel
  • Patent number: 7384684
    Abstract: The invention relates to an aqueous coating composition which comprises a mixture of polyvinylpyrrolidone, a surfactant and optionally an adhesion-promoting polymer. This mixture is suitable for inline coating of biaxially oriented polyester films. The thus obtained films feature a characteristic hydrophilic surface which prevents the fogging of the films with water droplets.
    Type: Grant
    Filed: October 4, 2005
    Date of Patent: June 10, 2008
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Matthias Konrad, Dagmar Klein, Herbert Peiffer, Gottfried Hilkert
  • Publication number: 20080132595
    Abstract: A composition comprising: (a) a high melt strength material, comprising a first polymer selected from the group consisting of an elastomeric ethylene/?-olefin polymer and a polypropylene polymer, and (b) a high flow material, comprising a second polymer selected from the group consisting of an elastomeric ethylene/?-olefin polymer and a polypropylene polymer. The high melt strength material has a dynamic complex viscosity greater than, or equal to, 175,000 Poise (17,500 Pa-s), measured using parallel plate rheometry at 1 radians per second and 190 degrees Centigrade, and the high flow material has a ratio, ?*/td, less than 2500, where ?* is the dynamic complex viscosity and td is the tan delta, both measured at 1 radian per second at 190 degrees Centigrade. The composition exhibits minimal necking when extruded at high speeds and is particularly useful for making sheets via high speed extrusion.
    Type: Application
    Filed: November 16, 2005
    Publication date: June 5, 2008
    Inventor: Henry G. Heck
  • Patent number: 7365131
    Abstract: A thermoplastic vulcanizate composition comprised of (a) thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) at least one elastomer selected from the group consisting of butadiene-isoprene copolymer rubbers, copolymers of a conjugated diolefin monomer and an acrylate monomer, copolymers of a conjugated diolefin monomer and an methacrylate monomer, copolymers of a conjugated diolefin monomer and a vinyl aromatic monomer, copolymers of a conjugated diolefin monomer and an acrylonitrile monomer, blends of polyisoprene rubber with styrene-butadiene rubber, wherein the elastomer is at least partially crosslinked, wherein the repeat units in the elastomer are distributed throughout the elastomer in an essentially random manner, and (c) oil.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: April 29, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Manoj Ajbani, Christopher Kiehl, Thierry Florent Edme Materne
  • Patent number: 7365130
    Abstract: Cycloolefinic polymer compositions exhibiting an advantageous balance of dimensional stability, improved impact resistance and superior optical properties are provided. The cycloolefinic polymer compositions of the invention generally include at least one cycloolefinic polymer and an effective amount of an elastomeric copolymer having an aromatic vinyl content of from 14 to 39 weight percent. The cycloolefinic polymer compositions may be incorporated into a variety of products, including multilayer films.
    Type: Grant
    Filed: January 28, 2004
    Date of Patent: April 29, 2008
    Assignee: Cryovac, Inc.
    Inventors: Janet W. Rivett, Nathanael Rustia Miranda, Kelly Ray Ahlgren
  • Patent number: 7351769
    Abstract: Processable rubber compositions comprising a vulcanized elastomer dispersed in a matrix of a thermoplastic polymeric material. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a curative, an uncured fluorocarbon elastomer, and a reactive oligomer, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material and polymerization of the oligomer, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles such as seals, gaskets, O-rings, and hoses may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.
    Type: Grant
    Filed: January 26, 2004
    Date of Patent: April 1, 2008
    Assignee: Freudenberg-NOK General Partnership
    Inventor: Edward Hosung Park
  • Publication number: 20080050568
    Abstract: The invention provides a tape film backing including a mixing layer comprising 40-60 parts by weight of PE and 60-40 parts by weight of EPDM rubber and a PE layer. The invention also provides a tape with an adhesive layer coated on the mixing layer or the PE layer of the tape film backing. The tape and the film backing is a halogen-free eco-material possessing superior physical properties as well as fine electrical insulating properties.
    Type: Application
    Filed: August 24, 2007
    Publication date: February 28, 2008
    Inventors: Lucky Lee, Tai Hsun Lee, Ching-Chih Lai, Yan-sheng Yang
  • Patent number: 7326748
    Abstract: The subject invention discloses a thermoplastic composition which is comprised of a blend of a thermoplastic resin and an elastomer, wherein said thermoplastic resin is selected from the group consisting of polyphenylene ether and polystyrene, wherein said elastomer is comprised of a conjugated diene selected from 1,3-butadiene and isoprene, wherein said elastomer is highly branched, wherein said elastomer is characterized by having a G? and G? frequency crossover of no more than 4 radians/s at 100° C., wherein the thermoplastic resin is present in an amount which is within the range of about 5 parts by weight to about 95 parts by weight, and wherein the elastomer is present in an amount which is within the range of about 5 parts by weight to about 95 parts by weight, based upon the total weight of the thermoplastic composition.
    Type: Grant
    Filed: June 14, 2004
    Date of Patent: February 5, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Manoj Ajbani, Christopher Kiehl, Thierry Florent Edme Materne
  • Patent number: 7323516
    Abstract: The present invention is directed to a peroxide curable rubber compound containing a butyl rubber polymer and an olefin polymer of ethylene and at least one ?-olefin. The present invention is also directed to a peroxide curable rubber compound containing a butyl polymer and an EP(D)M rubber polymer.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: January 29, 2008
    Assignee: Lanxess Inc.
    Inventors: Akhtar Osman, Adam Gronowski
  • Patent number: 7309739
    Abstract: A polymer blend and a method of making the same are provided. The polymer blend includes an ethylene-propylene (C2-C3) random copolymer and a modifier selected from the group consisting of a metallocene-catalyzed polyethylene-based copolymer, a metallocene-catalyzed polyethylene-based terpolymer, and a syndiotactic polypropylene homopolymer. The polymer blend may also include an organic peroxide for visbreaking the polymer blend. An end use article is made from the foregoing polymer blend. The end use article may be, for example, a film, an injection molded article, a compression molded article, a thermoformed article, and a fiber. The end use article is desirably a film having an Elmendorf tear strength of at least about 300 g/ply in the machine and transverse directions.
    Type: Grant
    Filed: November 2, 2005
    Date of Patent: December 18, 2007
    Assignee: Fina Technology, Inc.
    Inventors: Michael Musgrave, Likuo Sun, Mark Miller
  • Patent number: 7294675
    Abstract: Disclosed herein are low Shore A Hardness thermoplastic vulcanizate compositions having high Rebound values. In at least one exemplary embodiment, the compositions include a dispersed at least partially vulcanized rubber component; a thermoplastic component; and process oil; wherein the weight ratio of the thermoplastic component to the rubber component ranges from 80:20 to 15:85; and the thermoplastic component comprises more than 80 wt % of a polypropylene (preferably a random propylene copolymer) having a melting point less than about 105° C. The compositions can be used in molded products, consumer goods and the like.
    Type: Grant
    Filed: December 15, 2004
    Date of Patent: November 13, 2007
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Danny Van Hoyweghen, Tonson Abraham, Bahar Azimipour
  • Patent number: 7294676
    Abstract: Styrenic resin composition comprising a rubber modified styrene maleic anhydride copolymer and polybutene. The resin is prepared by several methods including adding polybutene into the reactor, or adding polybutene to the syrup exiting the reactor and prior to entering the devolatilizer, or compounding polybutene into the polymer in an extruder after the polymer exits the devolatilizer. The polybutene ranges from 0.1 to 8% by weight and has a number average molecular weight from 900 to 2500. The rubber ranges from 4% to 20% by weight and has a particle size from 0.1 micron to 11 microns. The resin can be extruded into sheet and thermoformed into an article or can be coextruded to produce a laminated article, which may be a container for packaged foods that can be heated in microwave ovens and which container has improved toughness, elongation, and heat distortion resistance properties.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: November 13, 2007
    Assignee: NOVA Chemicals Inc.
    Inventors: John Chi Hee Kwok, Richard Albert Cooper, Steven Michael Krupinski
  • Patent number: 7294674
    Abstract: A polyolefin composition suitable for preparing films and sheets, comprising: (A) from 15 to 40% by weight of a crystalline copolymer of propylene with at least one alpha-olefin of formula H2C?CHR1, where R1 is H or a C2-8 linear or branched alkyl, containing at least 90% by weight of propylene, having solubility in xylene at room temperature lower than 15% by weight; (B) from 60 to 85% by weight of an elastomeric fraction comprising: (1) a copolymer of propylene with ethylene, optionally containing 0.5 to 5% by weight of a diene, containing from 20 to 35% by weight ethylene, and having solubility in xylene at room temperature greater than 45% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 1.0 to 3.0 dl/g; and (2) a copolymer of ethylene with at least one alpha-olefin of formula H2C?CHR2, where R2 is a C2-8 linear or branched alkyl, optionally containing 0.
    Type: Grant
    Filed: March 5, 2003
    Date of Patent: November 13, 2007
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Anteo Pelliconi, Antonella Angelini
  • Patent number: 7291677
    Abstract: A thermoplastic elastomer that is adherent to polar materials may be made from a dynamically vulcanized blend of propylene resin, ethylene/alpha-olefin/non-conjugated diene elastomers, and a bonding agent via a curing system containing a free radical initiator, at least one co-agent including multifunctional acrylates containing at least two acrylate groups, multifunctional maleimides containing at least two imide groups, or mixtures of both, where the elastomer gel content in the modified blend is at least about 97 percent. Reaction mixtures, articles made therefrom, and methods of dynamically vulcanizing are also disclosed.
    Type: Grant
    Filed: June 29, 2004
    Date of Patent: November 6, 2007
    Assignee: Solvay Engineered Polymers, Inc.
    Inventors: Kevin Cai, Anthony Nguyen, Charles G. Reid
  • Patent number: 7279526
    Abstract: The invention provides a heterophasic propylene polymer composition comprising the following components: i) 60 to 90% wt, relative to the total weight of components i), ii) and iii), of a propylene polymer matrix comprising a propylene homopolymer and, optionally a propylene copolymer, said propylene polymer matrix having an ethylene content of no more than 5% wt; ii) wt 5 to 30% wt, relative to the total weight of components i), ii) and iii), of an elastomer; and iii) 5 to 25% wt, relative to the total weight of components i), ii) and iii), of an ethylene copolymer plastomer having a density of not more than 910 kg/m3 and a melt flow rate MFR2.16 (190° C.) of at least 0.5 g/10 minutes at 190° C. under a weight of 2.16 kg.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: October 9, 2007
    Assignee: Borealis Technology Oy
    Inventors: Bo Malm, Pirjo Jååskelåainen, Päivi Pitkånen, Reijo Perålå, Jari Lehtinen
  • Patent number: 7276559
    Abstract: This invention relates to a soft thermoplastic vulcanizate composition comprising: a) from about 2-10 wt %, based upon total polymer content weight a)+b)+c), of a thermoplastic polyethylene or polypropylene homopolymer, or ethylene-propylene copolymer, or copolymer that includes ethylene or propylene together with one or more C4 to C20 ?-olefins, said thermoplastic having at least 25% crystallinity by DSC; b) from about 15 to about 36 wt. %, based upon total polymer content weight a)+b)+c), of an ethylene-?-olefin random or block copolymer thermoplastic having less than 5% crystallinity by DSC; c) from about 60 to about 80 wt. %, based upon total polymer content weight a)+b)+c), of a cross-linked elastomer; and d) from about 50 to about 65 wt %, based upon total composition weight a)+b)+c)+d), of a process oil; wherein said thermoplastic vulcanizate composition has a Shore A Hardness of less than 35. The invention compositions may also comprise from about 0 to about 40 wt.
    Type: Grant
    Filed: December 15, 2004
    Date of Patent: October 2, 2007
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Tonson Abraham, Kuo-Shein Shen, Norman G. Barber
  • Patent number: 7268185
    Abstract: Disclosed is a thermoplastic resin composition that contains specific amounts of polypropylene resin (A), elastomer (B), inorganic filler (C) and resin (D) which is composed of 60 to 80% by weight of a first segment which is a propylene homopolymer or a propylene-ethylene random copolymer and has an intrinsic viscosity, measured in tetralin at 135° C., of 5 dl/g or more and 20 to 40% by weight of a second segment which is a propylene homopolymer or a propylene-ethylene random copolymer and has an intrinsic viscosity, measured in tetralin at 135° C., of 0.8 to 1.2 dl/g.
    Type: Grant
    Filed: September 17, 2004
    Date of Patent: September 11, 2007
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Moriyasu Shimojo, Ryoji Matunaga, Tsuyoshi Watanabe
  • Patent number: 7262254
    Abstract: The invention relates to a tire having a tread of a rubber composition with compositional limitations containing minimal, if any, of in situ formed volatile alcohol byproduct. The tread component rubber composition contains a combination or pre-hydrophobated silica reinforcement and siloxane functionalized styrene/butadiene copolymer elastomer. The pre-hydrophobated silica is prepared, prior to mixing with the elastomer(s), by reacting hydroxyl groups (e.g. silanol groups) contained on the surface of a precipitated silica with an alkoxyorganomercaptosilane or with a bis-3(triethoxysilylpropyl)polysulfide which contains an average of from 2 to 4 connecting sulfur atoms in its polysulfidic bridge to form a composite thereof which may optionally include an alkyl silane. The volatile alcohol byproduct (e.g. ethanol) therefrom is thereby removed from the pre-hydrophobated silica composite prior to its introduction into the rubber composition(s).
    Type: Grant
    Filed: August 26, 2005
    Date of Patent: August 28, 2007
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: David John Zanzig
  • Patent number: 7262251
    Abstract: A hot melt adhesive composition is based on an isotactic polypropylene random copolymer (RCP). The composition contains about 4%-50% by weight of the RCP copolymer, about 20%-65% by weight of a compatible tackifier, about 0%-40% by weight of a plasticizer, about 0%-3% by weight of a stabilizer, about 0%-40% by weight of a wax, about 0%-60% by weight of an atactic poly-?-olefin (APAO), and about 0%-40% by weight of a secondary polymer. The adhesive composition may be used in a number of applications such as, for example, in disposable nonwoven hygienic articles, paper converting, flexible packaging, wood working, carton and case sealing, labeling and other assembly applications.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: August 28, 2007
    Assignee: Bostik Findley, Inc.
    Inventors: Monina Dadap Kanderski, Lacretia A. Svenningsen, Diane M. Strelow, Chongyao Zhang, Mark A. Gibes, Baoyu Wang
  • Patent number: 7262249
    Abstract: A thermoplastic resin composition comprising: a graft copolymer obtained by polymerizing 10 to 70 parts by weight of a monomer containing 60 to 100% by weight of at least one vinyl monomer selected from the group consisting of a (meth)acrylate ester compound, an aromatic vinyl compound and a vinyl cyanide compound and 0 to 40% by weight of a monomer which is copolymerizable therewith, in the presence of 30 to 90 parts by weight of hollow rubber particles which are rubber obtained by polymerizing a polymerization component comprising a butadiene without using a crosslinking agent and have a porosity of 3 to 90% in the form of a latex, wherein the total amount of the monomer and the rubber particles is 100 parts by weight; and a thermoplastic resin.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: August 28, 2007
    Assignee: Kaneka Corporation
    Inventors: Akira Takaki, Toshio Mizuta, Akio Sato
  • Patent number: 7259209
    Abstract: A mixture of at least two thermoplastic particles having reactive grups which when melted and mixed react to form a high molecular weight polymer. The blend of particles when molten is particularly useful in forming double insulating glass or plastic panels.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: August 21, 2007
    Assignee: H.B.Fuller Licensing & Financing, Inc.
    Inventors: Stefan Grimm, Manfred Proebster, Matthias Kohl, Andreas Ferencz
  • Patent number: 7259210
    Abstract: A bone cement formulation stored as a solid component pack having 0.3 to 20 solid component pack weight percent of an elastomer and a polymer bead core having a polyacrylate terminated surface. The second component pack is a liquid component pack including an acrylate monomer. An alternate solid component pack includes 3 to 25 solid component pack weight percent of a polyacrylate and a rubber toughened polymethyl methacrylate. A cement mixing and delivering system according to the present invention includes a tube having an exit nozzle and an aperture. An end plate is adapted to seal against the interior of the tube aperture and the end plate has a plurality of needles protruding therefrom into the tube. A rotatable and slidable divider is received within the tube intermediate between the end plate and the exit nozzle. The divider includes at least two plates.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: August 21, 2007
    Assignee: The UAB Research Foundation
    Inventors: Aaron D. Puckett, Jr., Jack Lemons, Lujia Bu, Jimmy W. Mays
  • Patent number: 7250470
    Abstract: A method of nucleating a propylene homo- or copolymer, the method comprising contacting the propylene polymer with a semi-crystalline branched or coupled polymeric nucleating agent under nucleation conditions. In one embodiment, the propylene homopolymer is characterized as having 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity. In another embodiment, the copolymer is characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene, and as having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about ?1.
    Type: Grant
    Filed: February 22, 2006
    Date of Patent: July 31, 2007
    Assignee: Dow Global Technologies Inc.
    Inventors: James C. Stevens, Daniel D. Vanderlende, Patricia Ansems
  • Patent number: 7241839
    Abstract: A reaction product is prepared by reacting a first polymer having pendant or terminal carboxyl or anhydride groups with a second polymer (e.g. elastomer) having an amine containing terminal group. The second polymer is anionically polymerized. The second polymer is functionalized by reacting the growing anionic chain end with an imine. Then a protic terminating agent terminates the growing chain end. The first and second polymers are reacted by mixing (desirably above their softening temperatures) and forming a blend with improved physical properties over a blend of similar polymers lacking a reactive amine group.
    Type: Grant
    Filed: August 17, 2005
    Date of Patent: July 10, 2007
    Assignee: Bridgestone Corporation
    Inventors: James A. Krom, Xiaorong Wang
  • Patent number: 7238747
    Abstract: The invention is directed to a plasticized polypropylene thermoplastic composition comprising a blend of A) from 50 to 99.9 wt % of a thermoplastic polymer derived from polypropylene, optionally with one or more copolymerizable monomer selected from C2-C10 ?-olefin or diolefin, said polymer having a melt flow rate (MFR) (ASTM D1238) of from 0.5 to 1000 and a crystallinity by differential scanning calorimetry of from 0 to 70%; B) from 0.1 to 50 wt % of at least one ethylene copolymer having a weight-average molecular weight (Mw) (GPC) of from 500 to 10,000, a molecular weight distribution (MWD) (GPC) of from greater than 1.5 to less than or equal to 3.5, and a comonomer content of from greater than or equal to 20 mol % to less than 70 mol %; and optionally, C) from 0 to 20 wt % of a thermoplastic polypropylene modifier compound other than that of B).
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: July 3, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Patrick Brant
  • Patent number: 7235609
    Abstract: A thermoplastic olefin (TPO) composition comprises (1) a major amount by weight of (a) a substantially linear homopolymer or copolymer of a C2–C10 ?-olefin in major proportion to (b) a long chain branched a linear homopolymer or copolymer of a C2–C10 ?-olefin, (2) a minor amount by weight of a cross linkable elastomer, and (3) at least one thermally decomposing free radical generating agent present in an amount sufficient to promote an increase in melt strength of the composition over that of the melt strength of the linear homopolymer or copolymer of a C2–C10 ?-olefin alone and insufficient to substantially degrade the ?-olefinic polymers. The TPO composition is prepared by melt blending the components at a temperature sufficient to melt said homopolymers or copolymers of a C2–C10 ?-olefin and thermally decompose said agent. Articles are thermoformed from the thermoplastic olefin.
    Type: Grant
    Filed: January 14, 2004
    Date of Patent: June 26, 2007
    Inventors: Amitkumar Dharia, Jerry Wayne Rodrigue
  • Patent number: 7235612
    Abstract: This invention is a method for manufacturing a polymer alloy, by making at least two resins used as components miscible, and inducing the spinodal decomposition for causing phase separation, for forming a co-continuous structure with a wavelength of concentration fluctuation of 0.001 to 1 ?m or a dispersed structure with a distance between particles of 0.001 to 1 ?m. This invention is also a polymer alloy manufactured by the method. The polymer alloy of this invention can provide a molded article, film, fibers and the like respectively with excellent mechanical properties at high productivity.
    Type: Grant
    Filed: January 29, 2004
    Date of Patent: June 26, 2007
    Assignee: Toray Industries, Inc.
    Inventors: Sadayuki Kobayashi, Jiro Kumaki, Akira Hirai, Toru Nishimura
  • Patent number: 7226974
    Abstract: A vulcanized thermoplastic olefinic rubber composition comprising at least one vulcanizable rubber (A) selected from the group consisting of ethylene-?-olefin copolymers, which contain an ethylene unit and a unit of an ?-olefin having 3 to 20 carbon atoms, and which are produced with use of a metallocene catalyst, and an olefinic resin (B), wherein X and Y as defined below of said (A) are from 1 to 40% and from 0.02 to 0.5, respectively, X=(W2/W0)×100(%) Y=W2/W1 wherein W1 is a weight of a swollen vulcanized rubber (A), which is obtained when (A) in an amount of W0 is extracted with hot xylene, and W2 is a weight measured after drying of the above-mentioned swollen vulcanized rubber (A).
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: June 5, 2007
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventor: Hajime Nishihara
  • Patent number: 7217747
    Abstract: The plastics additives powder compositions of the present invention are provided as powder particles having impact modifier particles and processing aid particles which are coagulated and dried. When blended in thermoplastic resins, such as PVC, the subject plastics additives powders both increase the impact strength and improve process efficiency and melt strength. The impact and processing properties achieved by the present invention are more efficient than using separate impact modifier and processing aid powders. The method of preparing the powder compositions of the present invention also enable impact modifier particles having rubber weight fractions greater than 88% to be isolated as free-flowing powders.
    Type: Grant
    Filed: July 24, 2003
    Date of Patent: May 15, 2007
    Assignee: Rohm and Haas Company
    Inventors: Jane Elizabeth Weier, Morris Christopher Wills, Robert William Coyle
  • Patent number: 7199189
    Abstract: This invention relates generally to polymers suitable for making elastomeric films, membranes or sheets. More specifically, this invention is directed to polymers of the ethylene, alpha-olefin, diene terpolymer type that are reactor blends of two components, an amorphous major component and semicrystalline minor component, wherein the viscosity of the major component is less than one fourth the viscosity of minor component. These polymers are particularly suitable for elastomeric membranes such as roofing membranes.
    Type: Grant
    Filed: October 16, 2002
    Date of Patent: April 3, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Periagaram S. Ravishankar, Narayanaswami R. Dharmarajan
  • Patent number: 7199191
    Abstract: Physical blends of solid particulates of chlorinated polyolefins and elastomeric ethylene copolymers yield a blended product with anti-blocking characteristics superior to that defined by the weight proportion-based linear interpolation of either blend component. The blend compositions are useful as impact modifiers for polyvinyl chloride compositions.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: April 3, 2007
    Assignee: Dow Global Technologies Inc.
    Inventors: Gregory Earl Johnson, Shrikant V. Dhodapkar
  • Patent number: 7176262
    Abstract: The hydrogenated vinyl-polybutadienes according to the present invention have degrees of hydrogenation of from 20 to 100%, Mooney viscosities in the range of from 10 to 150 Mooney units (ML 1+4/100° C.), glass transition temperatures (Tg) of ??57° C. and enthalpies of fusion (?H) of ?30 J/g and having a microstructure with a) from 0 to 44 wt. % 1,2-vinyl-butadiene units of the formula b) from 20 to 64 wt. % 1,2-butylene units of the formula c) from 0 to 60 wt. % 1,4-butenylene units of the formula CH2—CH?CH—CH2 and d) from 0 to 60 wt. % 1,4-butylene units of the formula CH2—CH2—CH2—CH2 are outstandingly suitable for the production of rubber molded bodies of any kind, especially for the production of industrial rubber articles and of tires and tire components. The rubber molded bodies produced from the hydrogenated vinyl-polybutadienes according to the present invention have good resistance to ageing and good elasticity at low temperatures.
    Type: Grant
    Filed: May 26, 2004
    Date of Patent: February 13, 2007
    Assignee: Bayer Aktiengesellschaft
    Inventors: Cristina Stere, Werner Obrecht
  • Patent number: 7173093
    Abstract: The invention relates to a novel, impact-resistant polymer based on PMMA.
    Type: Grant
    Filed: January 15, 2003
    Date of Patent: February 6, 2007
    Assignee: Roehm GmbH & Co. KG
    Inventors: Klaus Kabs, Oliver Mueck
  • Patent number: 7157521
    Abstract: A gel composition that is the combination of or reaction product of ingredients comprising a thermoplastic elastomer copolymer, a functionalized polyolefin, an extender, and optionally a fatty acid.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: January 2, 2007
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Victor Foltz, James E. Hall
  • Patent number: 7147913
    Abstract: The present invention relates to a display strip to hold commodity-containing bags. It can facilitate to make a process of attaching the bags thereto automate. It enables commodity-containing bags to be removed therefrom without having their appearance degraded. The display strip according to the present invention is utilized to hold and align a plurality of commodity-containing bags vertically for the display. It comprises at least a substrate layer and a sealant layer with the sealant layer containing an ethylene-vinyl acetate copolymer and an adhesive promoting tackifier.
    Type: Grant
    Filed: January 7, 2004
    Date of Patent: December 12, 2006
    Assignee: Ishida Co. Ltd.
    Inventors: Yoshio Iwasaki, Yukio Nakagawa, Tadao Oota, Naoji Ichise
  • Patent number: 7148291
    Abstract: The thermoplastic elastomer composition of this invention includes 2 through 14 mass % of PP; 19 through 35 mass % of PB-1; and 30 through 52 mass % of olefin-based rubber, and a weight ratio of PB-1/(PP+PB-1) is 56 through 90% and a weight ratio of PB-1/(PP+(PB-1)+olefin-based rubber) is 25 through 47%.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: December 12, 2006
    Assignee: Mazda Motor Corporation
    Inventors: Chikara Tanaka, Masaaki Onishi
  • Patent number: 7138458
    Abstract: A method is provided for preparing an adhesive composition that contains both a hydrophobic phase and a hydrophilic phase, wherein the hydrophobic phase is composed of a crosslinked hydrophobic polymer composition and the hydrophilic phase is a water-absorbent blend of a hydrophilic polymer and a complementary oligomer capable of crosslinking the hydrophilic polymer through hydrogen bonding, ionic bonding, and/or covalent bonding. The composition is useful as a bioadhesive, for affixing drug delivery systems, wound dressings, bandages, cushions, or the like to a body surface such as skin or mucosal tissue.
    Type: Grant
    Filed: October 12, 2004
    Date of Patent: November 21, 2006
    Assignees: Corium International, Inc., A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
    Inventors: Gary W. Cleary, Mikhail M. Feldstein, Valery G. Kulichikhin, Danir F. Bairamov
  • Patent number: 7135214
    Abstract: Textile floorcoverings composed of more than one layer have their layers bonded by an adhesive which comprises, as binder, an aqueous dispersion of a mixture made from a polymer A) at least 60% by weight of which is composed of ethylene and from a polymer B) at least 60% by weight of which is composed of vinylaromatics, dienes or mixtures of these.
    Type: Grant
    Filed: February 21, 2000
    Date of Patent: November 14, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: James Arthur Smith, Bernard Schott, Leonardus Aan de Meulen
  • Patent number: 7122601
    Abstract: A polymer blend and a method of making the same are provided. The polymer blend includes an ethylene-propylene (C2–C3) random copolymer and a modifier selected from the group consisting of a metallocene-catalyzed polyethylene-based copolymer, a metallocene-catalyzed polyethylene-based terpolymer, and a syndiotactic polypropylene homopolymer. The polymer blend may also include an organic peroxide for visbreaking the polymer blend. An end use article is made from the foregoing polymer blend. The end use article may be, for example, a film, an injection molded article, a compression molded article, a thermoformed article, and a fiber. The end use article is desirably a film having an Elmendorf tear strength of at least about 300 g/ply in the machine and transverse directions.
    Type: Grant
    Filed: July 28, 2003
    Date of Patent: October 17, 2006
    Assignee: Fina Technology, Inc.
    Inventors: Michael Musgrave, Likuo Sun, Mark Miller
  • Patent number: 7112632
    Abstract: A process for the preparation of low branch content polybutadiene comprising: (a) a first butadiene polymerisation stage; (b) treatment of the polymer solution obtained upon completion of stage (a) with a coupling agent selected from: (i) polyunsaturated natural oils; (ii) butadiene and/or isoprene oligomers; (iii) butadiene and/or isoprene co-polymers with vinylarene monomers; the unsaturations present in compounds (i)–(iii) being at least partially substituted with groups selected from epoxides, anhydrides and esters; (c) recovery of the low branch content polybutadiene obtained upon completion of stage (b).
    Type: Grant
    Filed: October 17, 2005
    Date of Patent: September 26, 2006
    Assignee: Polimeri Europa S.p.A.
    Inventors: Gian Tommaso Viola, Fabio Bacchelli, Silvia Valenti