At Least One Of These Polymers Is Derived From Two Or More Reactants Patents (Class 525/237)
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Patent number: 6894122Abstract: This invention relates to a tire having at least one component (e.g. tread) of a rubber composition comprised of a carbon black and precipitated silica reinforced elastomer blend comprised of a combination of hydroxyl functionalized aqueous emulsion polymerization prepared styrene/butadiene copolymer elastomer (E-SBR) and tin coupled organic solvent solution polymerization prepared styrene/butadiene copolymer elastomer (S-SBR) and/or isoprene/butadiene copolymer elastomer. Preferably, said E-SBR is exclusive of functional groups reactive with alkoxy groups other than said hydroxyl functional groups. A coupling agent as bis(3-triethoxysilylpropyl)polysulfide having an average of from only 2 to 2.6 connecting sulfur atoms in its polysulfidic bridge is used. The invention further relates to an article of manufacture, such as for example a tire, having at least one component of a rubber composition comprised of said elastomer blend.Type: GrantFiled: August 29, 2003Date of Patent: May 17, 2005Assignee: The Goodyear Tire & Rubber CompanyInventors: David John Zanzig, Brian David Holden
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Patent number: 6869685Abstract: The process of this invention can be utilized to improve the adhesion between rubber components. It is generally most useful for improving the adhesion between two different pre-cured rubber components or for improving the adhesion between a pre-cured rubber component and an uncured (green) rubber component. However, the technique of this invention can also be employed to improve the adhesion between two uncured rubber components. The technique of this invention is based upon the unexpected discovery that low molecular weight trans-1,4-polybutadiene containing rubber compounds can be used to improve the adhesion between rubber components.Type: GrantFiled: July 30, 2003Date of Patent: March 22, 2005Assignee: The Goodyear Tire & Rubber CompanyInventors: Bruce Raymond Hahn, Adel Farhan Halasa, Wen-Liang Hsu
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Patent number: 6863944Abstract: Improved single ply, water proof roof coverings having an extruded pressure sensitive rubber-based adhesive backing for attachment to a substrate such as the roof of a building or a transport vehicle, the adhesive comprising a thermoplastic rubber containing at least 25% butyl rubber in combination with polyisobutylene and low molecular weight polybutene.Type: GrantFiled: January 27, 2003Date of Patent: March 8, 2005Assignee: Building Materials Investment CorporationInventors: Michael P. Naipawer, III, Anthony Ruffine
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Patent number: 6815023Abstract: A polymer blend and mono-and multilayer films made therefrom suitable for processing or packaging articles which have an improved combination of properties e.g. such as lower tear strength and higher puncture resistance, or higher puncture resistance at both room temperature in air and at elevated temperatures in contact with water wherein the blend preferably has a first copolymer of ethylene and hexene-1 having a copolymer melting point of 80 to 98° C., preferably of 80 to 92° C.; a second copolymer of ethylene and at least one &agr;-olefin having a copolymer melting point of 115 to 128° C.; and a third copolymer of ethylene and a vinyl ester or alkyl acrylate and having a melting point of 60 to 110° C., and a process for making such films, especially shrink films having at least 40% shrink at 90° C. in at least one direction.Type: GrantFiled: September 22, 1999Date of Patent: November 9, 2004Assignee: Curwood, Inc.Inventors: Paul David Tatarka, Paul Nick Georgelos, Scott Allan Idlas
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Patent number: 6800689Abstract: There is provided a process for producing polymer rubber, which comprises the step of polymerizing a conjugated diene monomer or a combination of a conjugated diene monomer with an aromatic vinyl monomer in the presence of (1) an organolithium compound, (2) a solvent, (3) tetrahydrofuran in an amount of 0.0106 to 0.1060% by weight, and (4) ethylene glycol diethyl ether in an amount of 0.02 to 0.30% by weight, wherein the polymer rubber satisfies the conditions of (a) a vinyl group content in the polymer rubber is not less than 60% by weight, and (b) a Q value (Mw/Mn) of the polymer rubber is not more than 1.35.Type: GrantFiled: October 16, 2002Date of Patent: October 5, 2004Assignee: Sumitomo Chemical Company, LimitedInventors: Katsunari Inagaki, Seiichi Mabe
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Patent number: 6784255Abstract: This invention relates to a rubber composition for extrusion and molding comprising 100 weight parts of ethylene/&agr;-olefin/non-conjugated polyene copolymer (A) composed of ethylene, &agr;-olefin having carbon atoms of 3-20 and non-conjugated polyene, and at least 30-300 weight parts of carbon black (B), and 1.0×10−5-5.0×10−3 mol of an alkoxysilane compound shown by the following formula (I): wherein, R is alkyl or alkoxy, R1 is alkyl or phenyl, n is 0, 1 or 2, R2 is a bivalent hydrocarbon, R3 is arylene group, m and p are 0 or 1 respectively, and m and p are not 0 at a same time, q is 1 or 2, and D is —SCN or —SH when q is 1, and —Sx— when q is 2 (wherein x is an integer of 2-8).Type: GrantFiled: June 3, 2002Date of Patent: August 31, 2004Assignees: Mitsui Chemicals Inc., Degussa AGInventors: Hidenari Nakahama, Yuji Ishii, Mikio Hosoya, Masaaki Kawasaki
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Patent number: 6777046Abstract: A polymer blend and mono-and multilayer films made therefrom having an improved combination of properties such as high shrinkage values and high puncture resistance wherein the blend has a first copolymer of ethylene and octene-1 having a copolymer melting point of from 55 to 95° C., preferably of from 80 to 92° C.; a second copolymer of ethylene and at least a &agr;-olefin having a copolymer melting point of from 115 to 128° C.; and a third copolymer of ethylene and a vinyl ester or alkyl acrylate and having a melting point of from 60 to 110° C., and a process for making such films, which preferably have at least 45% shrinkage at 90° C. in at least one direction.Type: GrantFiled: November 1, 1999Date of Patent: August 17, 2004Assignee: Curwood, Inc.Inventors: Paul David Tatarka, Paul Nick Georgelos, Scott Allan Idlas
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Patent number: 6750281Abstract: A golf ball and a method of manufacturing thereof are provided, the golf ball having a core containing a Mg vulcanized rubber powder crosslinked by a magnesium salt of an unsaturated carboxylic acid and another vulcanized rubber powder crosslinked by a co-crosslinking agent other than the magnesium salt of the unsaturated carboxylic acid. Preferably, the ratio &agr;/&bgr; between the content &agr; of the Mg vulcanized rubber powder and the content &bgr; of another vulcanized rubber powder is 1/4 to 4, and the total content &agr;+&bgr; of the vulcanized rubber powders based on 100 parts by mass of a base rubber of the core is 5 to 30 parts by mass.Type: GrantFiled: October 9, 2002Date of Patent: June 15, 2004Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tsutomu Hirau, Hiroaki Tanaka
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Patent number: 6750297Abstract: The present invention relates to an artificial pigment and a method of preparing the same, specifically, to an artificial pigment with excellent dry pick resistance and to a method of preparing the same. In order to accomplish the present invention, there is provided an artificial pigment of inverted core-shell structure comprising: a) a shell of butadiene polymer including: i) a seed of butadiene polymer having glass transition temperature of −10 to 50° C.; and ii) a seed covering of butadiene polymer having a glass transition temperature of −10 to 20° C.; and b) a core of styrene polymer having a glass transition temperature of 40 to 120° C. Also provided is method of preparing artificial pigment comprising: a) preparing a shell of butadiene polymer; and b) preparing a core of styrene polymer on the inner side of said shell of step a).Type: GrantFiled: July 29, 2002Date of Patent: June 15, 2004Assignee: LG Chem, Ltd.Inventors: Seung-Uk Yeu, Ho-Yeul Choi, Chang-Sun Han, Wan-Sik Cha
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Publication number: 20040024129Abstract: The process of this invention can be utilized to improve the adhesion between rubber components. It is generally most useful for improving the adhesion between two different pre-cured rubber components or for improving the adhesion between a pre-cured rubber component and an uncured (green) rubber component. However, the technique of this invention can also be employed to improve the adhesion between two uncured rubber components. The technique of this invention is based upon the unexpected discovery that low molecular weight trans-1,4-polybutadiene containing rubber compounds can be used to improve the adhesion between rubber components.Type: ApplicationFiled: July 30, 2003Publication date: February 5, 2004Applicant: The Goodyear Tire & Rubber CompanyInventors: Bruce Raymond Hahn, Adel Farhan Halasa, Wen-Liang Hsu
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Patent number: 6686419Abstract: This invention relates generally to synthetic polymers, generally with improved balance of processability, resilience and durability. These polymers are generally of the ethylene, alpha-olefin, diene terpolymer type.Type: GrantFiled: February 7, 2003Date of Patent: February 3, 2004Assignee: ExxonMobil Chemical Patents Inc.Inventors: Guy Joseph Wouters, Periagaram S Ravishankar, Kent L. Chasey, Eric P. Jourdain
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Patent number: 6646054Abstract: The process of this invention can be utilized to improve the adhesion between rubber components. It is generally most useful for improving the adhesion between two different pre-cured rubber components or for improving the adhesion between a pre-cured rubber component and an uncured (green) rubber component. However, the technique of this invention can also be employed to improve the adhesion between two uncured rubber components. The technique of this invention is based upon the unexpected discovery that low molecular weight trans-1,4-polybutadiene containing rubber compounds can be used to improve the adhesion between rubber components.Type: GrantFiled: May 30, 1997Date of Patent: November 11, 2003Assignee: The Goodyear Tire & Rubber CompanyInventors: Bruce Raymond Hahn, Adel Farhan Halasa, Wen-Liang Hsu
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Publication number: 20030199636Abstract: This invention is based upon the unexpected discovery that the reactivity of the most important monomers commonly used in synthesizing tackifier resins with aluminum halide catalysts can be enhanced by conducting the polymerization in the presence of an allylic halide. For instance, the conversions of 2-methyl-2-butene, cis-piperylene, and cyclopentene that are attained in polymerizations that are catalyzed with aluminum halide catalysts are increased by conducting the polymerization in the presence of an allylic halide, such as allyl chloride. Increased monomer conversion is of great commercial importance because it leads to an increased level of efficiency and reactor capacity.Type: ApplicationFiled: June 10, 2003Publication date: October 23, 2003Inventor: Kirkwood Storer Cottman
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Patent number: 6632888Abstract: The invention relates to rubber mixtures which contain microgels and isocyanatosilanes and vulcanisates produced therefrom. By adding isocyanatosilanes the mechanical properties of the vulcanisates, in particular the elongation properties and the abrasion resistance, are improved without the difference in rebound resilience at 70° C. and 23° C. being reduced.Type: GrantFiled: August 3, 2001Date of Patent: October 14, 2003Assignee: Bayer AktiengesellschaftInventors: Werner Obrecht, Martin Mezger, Anthony Sumner
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Publication number: 20030191246Abstract: The invention relates to a golf ball comprising a core, an intermediate layer disposing around the core, and a cover including at least one layer that includes a polyurethane or polyurea polymer. The intermediate layer is preferably rigid and has a durometer hardness of greater than at least 80 Shore C or at least 55 Shore D. The intermediate layer preferably includes a diene polymer. Alternatively, the intermediate layer includes a cast or RIM thermoset polyurethane, polyurea, polyurethane-ionomer, epoxy or blends thereof.Type: ApplicationFiled: March 28, 2003Publication date: October 9, 2003Inventors: William E. Morgan, Michael J. Sullivan, Derek A. Ladd
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Patent number: 6620873Abstract: A rubber composition containing (A) an ethylene-&agr;-olefin based copolymer rubber having an intrinsic viscosity [&eegr;] of 2.0-10.0 as determined in xylene at 70° C., (B) a softening agent, and (C) a filler, which composition is superior in heat resistance and fatigue resistance, is obtained by a process including the steps of dividing component (A) into portions (A1) and (A2), dividing component (B) into portions (B1) and (B2), dividing component (C) into portions (C1) and (C2), kneading portions (A1), (B1) and (C1) together to obtain a first blend, adding portions (A2), (B2) and (C2) to the first blend to obtain a second blend and kneading the second blend to obtain the rubber composition.Type: GrantFiled: March 15, 2001Date of Patent: September 16, 2003Assignees: Sumitomo Chemical Company, Limited, Nobukawa Rubber Industrial Co., Ltd.Inventors: Sadayuki Nakano, Takashi Nishida
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Patent number: 6605671Abstract: The invention discloses an improved process for the production of cross-linked rubber particles. The cross-linking agents are added to the aqueous rubber dispersions and converted at relatively high temperatures without inertization of the reaction mix and without pressurizing of an inert gas. The cross-linked rubber particles are suitable, for example, for the production of technical rubber products and for various tire components.Type: GrantFiled: July 17, 2001Date of Patent: August 12, 2003Assignee: Bayer AktiengesellschaftInventor: Werner Obrecht
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Patent number: 6599984Abstract: A blend of a rubber and a rubber modifier, the rubber modifier comprising an ethylene/&agr;-olefin copolymer rubber (A) composed of one or more copolymers selected from the group consisting of a copolymer of ethylene and an &agr;-olefin having 3-20 carbon atoms and a copolymer of ethylene, an &agr;-olefin having 3-20 carbon atoms and a non-conjugated polyene, the copolymer rubber (A) having the parameters: an ethylene/&agr;-olefin mole ratio in the range of 51/49 to 87/13, an intrinsic viscosity [&eegr;] determined in decahydronaphthalene at 135° C. in the range of 0.8 to 2.5 dl/g and an iodine value in the range of 0 to 40.Type: GrantFiled: April 21, 2000Date of Patent: July 29, 2003Assignee: Mitsui Chemicals, Inc.Inventors: Masaaki Kawasaki, Taku Koda, Takashi Hakuta, Tetsuo Tojo
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Patent number: 6589630Abstract: The present invention provides performance enhancing shoe components and methods of using those shoe components to increase exercise performance. The shoe components comprise a layer of 1,4-polybutadiene and, optionally, a high energy returning rubber. A second layer of an energy returning rubber and/or a coating is optionally applied to the first layer. The invented shoe components may be formed as shoe inserts, insoles, midsoles, soles, or portions thereof.Type: GrantFiled: June 23, 2000Date of Patent: July 8, 2003Inventor: William R. Crow
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Patent number: 6586533Abstract: Articles are formed from a thermosetting composition based on polybutadiene or polyisoprene resins which are subjected to a high temperature cure step of greater than 250° C. The thermosetting compositions may include fillers such as particulate ceramic fillers and may also include woven webs for improved dimensional stability and decreased brittleness. The formation process of this invention is particularly well suited for making electrical circuit substrates for microwave and digital circuits, typically in the form of the thermosetting composition being laminated on one or both opposed surfaces to metal conductive foil (e.g., copper).Type: GrantFiled: May 4, 1994Date of Patent: July 1, 2003Assignee: World Properties, Inc.Inventors: Vincent R. Landi, J. Mark Mersereau, Walter A. Robbins, Michael E. St. Lawrence
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Patent number: 6562909Abstract: The invention relates to a golf ball having a core and two or more cover layers. The outer cover layer includes a thin castable material and the inner cover layer a polyisoprene based material.Type: GrantFiled: June 18, 2001Date of Patent: May 13, 2003Assignee: Acushnet CompanyInventor: William E. Morgan
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Patent number: 6521733Abstract: A tapered aromatic vinyl-conjugated diene copolymer rubber having a ratio W0.6Mp/WMp in the range of 0.65-0.9 or 1.1-1.3 wherein Mp is molecular weight of a copolymer molecule corresponding to the peak of a molecular weight distribution curve obtained by gel permeation chromatography, WMp is a weight fraction of aromatic vinyl monomer units in the copolymer molecule having a molecular weight Mp, and W0.6Mp is a weight fraction of aromatic vinyl monomer units in a copolymer molecule having a molecular weight of Mp×0.6. A coupled tapered rubber comprised of a plurality of tapered copolymer molecules which are bound together at molecule terminal. A rubber composition comprising this tapered rubber or coupled tapered rubber and natural rubber or a synthetic rubber. This rubber composition exhibits reduced heat build-up, and high wet skid resistance, tensile strength and abrasion resistance.Type: GrantFiled: February 11, 2002Date of Patent: February 18, 2003Assignee: Zeon CorporationInventor: Takeshi Karato
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Patent number: 6512053Abstract: This invention discloses an emulsion styrene-butadiene rubber (SBR) that can be employed in manufacturing tire tread formulations that have rolling resistance and treadwear characteristics that are similar to those made with solution SBR but with improved traction characteristics. Thus, the emulsion SBR of this invention is superior in many respects for use in tire tread compounds to conventional solution SBR and conventional emulsion SBR. This invention more specifically discloses a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene, 1,3-butadiene, and a hydroxy alkyl acrylate monomer, wherein the styrene-butadiene rubber composition has a number average molecular weight as determined by field flow fractionation which is within the range of about 50,000 to 150,000, and wherein the styrene-butadiene rubber has a light scattering to refractive index ratio which is within the range of 1.8 to 3.9.Type: GrantFiled: June 20, 2002Date of Patent: January 28, 2003Assignee: The Goodyear Tire & Rubber CompanyInventors: Howard Allen Colvin, Michael Leslie Senyek, Jr.
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Patent number: 6500900Abstract: An olefinic thermoplastic elastomer capable of producing a sheet applicable for preparing a covering skin sheet for interior furnishings in automobile superior in the formability, heat resistance, mechnical properties, tensile characteristics, strain restorability and repulsive elasticity together with superior grain retention performance upon a male vacuum forming of the sheet, the said olefinic thermoplastic elastomer comprising an olefinic resin and an olefinic copolymer rubber and having a characteristic feature that it satisfies, when a grained sheet made of the said elatomer is subjected to a male vacuum forming at least at a point of sheet temperature within the range of 130-150° C., the condition that the grain retention rate expressed by the proportion of the grain depth of the sheet retained after the male vacuum forming relative to the grain depth before the male vacuum forming represented by percent meets the relation defind by the following equation (1) % retention of grain≧100−2.Type: GrantFiled: October 25, 2000Date of Patent: December 31, 2002Assignee: Mitsui Chemicals, Inc.Inventor: Yuichi Itoh
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Patent number: 6482892Abstract: An olefinic thermoplastic elastomer composition which does not exhibit problems due to a softening agent such as an oil is superior in molding processability. The thermoplastic elastomer composition is produced by a heat crosslinking process of a resin-rubber composition that contains an olefinic and/or diene rubber, an olefinic resin, and a vinyl copolymer. The vinyl copolymer is obtained by copolymerizing 20 wt % or more of a vinyl monomer represented by CH2═CHOCOR1 or CH2═CHOR2 wherein R1 and R2 are alkyl groups having 1-6 carbon atoms. The thermoplastic elastomer composition can include a vinyl copolymer that has not undergone a heat crosslinking process.Type: GrantFiled: June 27, 2000Date of Patent: November 19, 2002Assignee: JSR Elastomix Co., Ltd.Inventors: Seizo Katayama, Kazuo Kimura, Kazuhiro Ohashi, Minoru Horie
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Patent number: 6476143Abstract: A method of preparing a functionalized polymer comprising the steps of initiating the formation and propagation of an anionically-polymerized living polymer, and terminating the propagation of the living polymer by reacting the polymer with a terminating agent selected from the group of agents defined by the formulas (III), (IV), and (V) where C is a carbon atom, S is a sulfur atom, X is a halogen atom, R2 and R4 are independently selected from hydrogen and carbon-based moieties, and where the phenyl groups are selected from unsubstituted and substituted phenyl groups.Type: GrantFiled: June 8, 2001Date of Patent: November 5, 2002Assignee: Bridgestone CorporationInventors: David F. Lawson, Mark L. Stayer, Thomas A. Antkowiak
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Patent number: 6458894Abstract: A rubber modifier comprises an ethylene/&agr;-olefin copolymer rubber (A) composed of one or more copolymers selected from the group consisting of a copolymer of ethylene and an &agr;-olefin having 3-20 carbon atoms and a copolymer of ethylene, an &agr;-olefin having 3-20 carbon atoms and a non-conjugated polyene, the copolymer rubber (A) having the parameters: an ethylene/&agr;-olefin mole ratio in the range of 51/49 to 87/13, an intrinsic viscosity [&eegr;] determined in decahydronaphthalene at 135° C. in the range of 0.8 to 2.5 dl/g and an iodine value in the range of 0 to 40.Type: GrantFiled: September 11, 1997Date of Patent: October 1, 2002Assignee: Mitsui Chemicals, Inc.Inventors: Masaaki Kawasaki, Taku Koda, Takashi Hakuta, Tetsuo Tojo
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Patent number: 6437205Abstract: A process for polymerizing 1,3-butadiene into a low molecular weight high-cis polybutadiene is described using a catalyst system comprising: (a) a neodymium-containing compound, (b) an aluminoxane or a trialkyl aluminum compound, (c) an organoaluminum hydride, and (d) a halogen source. A blend of a high molecular weight high-cis polybutadiene and the low molecular weight high-cis polybutadiene is also disclosed for use in pneumatic tire treads. Desirably both the high and the low molecular weight polymers have high cis contents, with the low molecular weight polymer being at least 70 percent cis and the high molecular weight polymer being at least 92 percent cis. Desirably both polymers are made with a neodymium catalyst system. The blends provide a balance of properties including good snow traction, wet traction, and rolling resistance while providing a balance of good physical properties including tension at break, modulus etc.Type: GrantFiled: July 10, 2000Date of Patent: August 20, 2002Assignee: Bridgestone CorporationInventors: H. Jerrold Miller, Tatsuro Hamada, Yoichi Ozawa, Peyman Pakdel
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Patent number: 6420484Abstract: Tire rubbers which are prepared by anionic polymerization are frequently coupled with a suitable coupling agent, such as a tin halide, to improve desired properties. It has been unexpectedly found that greatly improved properties for tire rubbers, such as lower hysteresis, can be attained by asymmetrically coupling the rubber.Type: GrantFiled: October 1, 2001Date of Patent: July 16, 2002Assignee: The Goodyear Tire & Rubber CompanyInventors: Wen-Liang Hsu, Adel Farhan Halasa, Barry Allen Matrana
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Patent number: 6410624Abstract: Rubber compositions comprised of novel blends of segmented styrene-rich styrene/isoprene/butadiene terpolymer elastomer and at least one additional elastomer and tires with treads comprised of such rubber composition. Such tires may exhibit increased traction and reduced rolling resistance.Type: GrantFiled: September 14, 1999Date of Patent: June 25, 2002Assignee: The Goodyear Tire & Rubber CompanyInventors: Neil Arthur Maly, Paul Harry Sandstrom, Wen-Liang Hsu, Adel Farhan Halasa
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Patent number: 6403716Abstract: A thermoplastic rubber composition prepared by crosslinking 1-99 parts by weight of a crosslinkable rubbery polymer (A) and 1-99 parts by weight of a polypropylene resin (B) (total amount of (A) and (B) being 100 parts by weight), wherein said (B) comprises a polypropylene resin (B-1) characterized by generation of a torque higher than Mo after melting and a polypropylene resin (B-2) characterized by generation of a torque not higher than Mo after melting, in a melting test of said (B) in the presence of an organic peroxide (temperature condition being at 200° C.), and Mo being a torque right after complete melting.Type: GrantFiled: July 12, 2000Date of Patent: June 11, 2002Assignee: Asahi Kasei Kabushiki KaishaInventor: Hajime Nishihara
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Patent number: 6399706Abstract: The present invention relates to rubber compounds comprising at least one rubber which contains double bonds, at least one rubber gel, and at least one sulfur-containing organosilicon compound. Vulcanized materials which can be employed in particular for the production of tire treads can be produced from the rubber compounds according to the invention.Type: GrantFiled: June 20, 2000Date of Patent: June 4, 2002Assignee: Bayer AktiengesellschaftInventors: Werner Obrecht, Winfried Jeske
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Patent number: 6399710Abstract: Random thermoplastic ethylene copolymers can be used to increase the elongation to break and toughness of thermoplastic vulcanizates. Polypropylene is a preferred thermoplastic phase. The rubber can be olefinic rubbers. Random thermoplastic ethylene copolymers are different from Ziegler-Natta ethylene copolymers as the compositional heterogeneity of the copolymer is greater with Ziegler-Natta copolymers. This difference results in substantial differences in properties (elongation to break and toughness) between thermoplastic vulcanizates modified with random thermoplastic ethylene and those modified with Ziegler-Natta ethylene copolymers. An increase in elongation to break results in greater extensibility in the articles made from a thermoplastic vulcanizate.Type: GrantFiled: July 3, 2000Date of Patent: June 4, 2002Assignee: Advanced Elastomer Systems, L.P.Inventors: Terry M. Finerman, Maria D. Ellul, Sabet Abdou-Sabet
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Patent number: 6388014Abstract: A latex or fiber comprising a blend of polymeric materials consisting of one or more &agr;-olefin/ vinylidene monomer non-crosslinked substantially random interpolymers, wherein the distribution of the monomers of said interpolymers can be described by the Bernoulli statistical model or by a first or second order Markovian statistical model, and one or more homopolymers or copolymers of monomer components comprising aliphatic &agr;-olefins having from 2 to 20 carbon atoms, or aliphatic &agr;-olefins having from 2 to 20 carbon atoms and containing polar groups.Type: GrantFiled: April 27, 2001Date of Patent: May 14, 2002Assignee: The Dow Chemical CompanyInventors: Chung P. Park, Rene Broos, Johan Thoen, Martin J. Guest, Yunwa W. Cheung, John J. Gathers, Bharat I Chaudhary, Lawrence S. Hood
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Patent number: 6384179Abstract: A polyacetal resin composition comprising 30-90% by weight of polyacetal copolymer (A) having a melt index of less than 1.0 g/10 min. and 70-10% by weight of polyacetal copolymer (B) having a melt index of 1.0-100 g/10 min., both melting points of (A) and (B) being 155°-162° C., or a difference in melting point between (A) and (B) being not less than 6° C., has distinguished toughness and creep resistance.Type: GrantFiled: December 15, 2000Date of Patent: May 7, 2002Assignee: Asahi Kasei Kabushiki KaishaInventors: Noritaka Tanimura, Tadao Matsushika
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Patent number: 6378582Abstract: The present invention relates to a tire tread compound that is highly loaded with silica. This compound offers the advantages of silica compounding without the need for solution SBR. More specifically, the tire tread rubber formulations of this invention offer an excellent combination of traction, treadwear and rolling resistance characteristics. The subject invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (1) 10 phr to 35 phr of high vinyl polybutadiene rubber having a glass transition temperature which is within the range of −40° C. to 10° C., (2) 65 phr to 90 phr of tin-coupled isoprene-butadiene rubber having a glass transition temperature which is within the range of −90° C.Type: GrantFiled: September 20, 2000Date of Patent: April 30, 2002Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Adel Farhan Halasa, Wen-Liang Hsu, Edward John Blok
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Patent number: 6376610Abstract: Elastomeric polymers including ethylene, alpha-olefin and vinyl norbornene are shown to have improved extrusion characteristics, improved electrical properties, improved cure characteristics compared to ethylene, alpha-olefin, non-conjugated diene elastomeric polymers containing non-conjugated dienes other than vinyl norbornene. The elastomeric polymers containing vinyl norbornene generally have a branching index below 0.5. Such elastomeric polymers are combined with up to 30 parts of metallocene catalyzed ethylene, alpha-olefin copolymers to improve physical properties.Type: GrantFiled: September 12, 2000Date of Patent: April 23, 2002Assignee: Exxon Mobil Chemical Patents, Inc.Inventors: Narayanaswami Raja Dharmarajan, Periagaram Srinivasan Ravishankar, Charles Douglas Burrage
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Patent number: 6354523Abstract: An apparatus and method for forming superfine particles of rubber powder suitable for recycling, as by incorporation into new rubber production, is shown. Coarsely ground rubber particles, formed in a conventional manner, are mixed in a soaking vessel with a reagent which causes the rubber particles to swell. The swollen, reagent-impregnated rubber is less elastic and more easily ground. The reagent-impregnated particles are then transported to a grinder which reduces the size of the particles to 200 &mgr;m or less. The ground particles are then heated to drive off the reagent which is recovered in a reagent recovery system. The dried particles are then sorted according to size. The process is conveniently automated and provides the ability to economically recycle rubber.Type: GrantFiled: April 4, 2000Date of Patent: March 12, 2002Inventor: Yangsheng Liu
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Patent number: 6335095Abstract: A thermoplastic elastomer composition powder comprising a thermoplastic elastomer composition represented by the following (A), having a sphere-reduced average diameter of not more than 1.2 mm and a bulk specific gravity of not less than 0.38: (A) a thermoplastic elastomer composition comprising (a) 100 parts by weight of a polyolefin resin; (b) 20 to 250 parts by weight of a conjugated diene polymer of hydrogenated conjugated diene copolymer having a hydrogenation degree of not less than 70%, which is prepared by hydrogenating a conjugated diene-vinyl aromatic compound random copolymer in which the content of a vinyl aromatic compound unit is not more than 25% by weight; and (c) 0 to 500 parts by weight of an ethylene/&agr;-olefin copolymer rubber. This powder can give a molded article having excellent appearance and flexibility, which does not cause whitening easily on bending, according to the powder molding method.Type: GrantFiled: March 16, 1998Date of Patent: January 1, 2002Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroyuki Sugimoto, Yoshihiro Nakatsuji
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Patent number: 6331594Abstract: A process for preparing blends of syndiotactic 1,2-polybutadiene and rubbery elastomers comprising the steps of (1) providing a mixture of high cis-1,4-polybutadiene rubber cement and 1,3-butadiene monomer, and (2) combining (a) an iron-containing compound, (b) a hydrogen phosphite, and (c) an organoaluminum compound to form a catalyst composition outside the presence of the mixture of rubber cement and monomer, and (3) adding the catalyst composition to the mixture and thereby polymerizing the 1,3-butadiene monomer into syndiotactic 1,2-polybutadiene within the rubber cement.Type: GrantFiled: January 23, 2001Date of Patent: December 18, 2001Assignee: Bridgestone CorporationInventor: Steven Luo
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Patent number: 6329466Abstract: A foam comprising a blend of polymeric materials consisting of one or more &agr;-olefin/vinylidene monomer non-crosslinked substantially random interpolymers, wherein the distribution of the monomers of said interpolymers can be described by the Bernoulli statistical model or by a first or second order Markovian statistical model, and one or more homopolymers or copolymers of monomer components comprising aliphatic &agr;-olefins having from 2 to 20 carbon atoms, or aliphatic &agr;-olefins having from 2 to 20 carbon atoms and containing polar groups.Type: GrantFiled: October 12, 2000Date of Patent: December 11, 2001Assignee: The Dow Chemical CompanyInventors: Chung P Park, Rene Broos, Johan Thoen, Martin J. Guest, Yunwa W. Cheung, John J. Gathers, Bharat I Chaudhary, Lawrence S. Hood
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Patent number: 6323284Abstract: The present invention is broadly directed to a process for copolymerizing one or more alpha-olefins and one or more di-olefin monomers in the presence of at least one stereospecific metallocene catalyst system and at least one non-stereospecific metallocene catalyst system. Crosslinking of at least a portion of the mixture of polymer segments is accomplished during the polymerization of the composition by incorporation of single di-olefin comonomers into two polymer segments.Type: GrantFiled: December 10, 1999Date of Patent: November 27, 2001Assignee: ExxonMobil Chemical Patents, Inc.Inventor: Andrew J. Peacock
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Publication number: 20010044503Abstract: One-component, heat-curing reactive compositions based on liquid rubbers containing reactive olefinic double bonds and optionally solid rubbers and vulcanization systems based on sulfur have high maxima of the acoustic loss factor over a broad in-use temperature range of around +10° C. to +40° C. in their vulcanized state. These compositions optionally contain fine-particle thermoplastic polymers as an additional component. The compositions are suitable for use as acoustically damping adhesives, sealing compounds or coating compositions.Type: ApplicationFiled: January 26, 2001Publication date: November 22, 2001Inventors: Peter Born, Hubert Schenkel
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Patent number: 6316508Abstract: The present invention provides a rubber composition containing a reclaimed rubber and a method for producing the same. A rubber molded article having excellent rubber properties can be obtaining and the recycling of a used rubber product can be promoted by the present invention. A rubber composition of the present invention is a blend comprising a reclaimed rubber obtained by applying a heat and a shear stress to a vulcanized rubber, a non-vulcanized virgin rubber or/and a thermoplastic resin, wherein the reclaimed rubber contains 40% by weight or more of a residual toluene-insoluble gel component and the network chain density of the rubber in the component is 1/20 to 1/4 based on the network chain density of the rubber of the vulcanized rubber.Type: GrantFiled: November 27, 2000Date of Patent: November 13, 2001Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Toyoda Gosei Co., Ltd.Inventors: Mitsumasa Matsushita, Makoto Mouri, Hirotaka Okamoto, Norio Sato, Yasuyuki Suzuki, Masao Owaki, Noriyuki Suzuki, Katsumi Nakashima, Hidenobu Honda, Toru Yoshida, Katsumasa Takeuchi
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Patent number: 6303694Abstract: A process for the preparation of a sealant composition by mixing an elastomer in the substantial absence of an organic solvent and separately dispersing a quinoid curing agent in a polymer having a molecular weight below about 5,000 to form a curing agent concentrate. Thereafter, combining the curing agent concentrate with the elastomer to form the sealant composition. The composition is a rubber masterbatch having many applications and is advantageously, substantially free from organic solvents.Type: GrantFiled: February 18, 2000Date of Patent: October 16, 2001Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William L. Hergenrother, Christine Morehart
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Patent number: 6297324Abstract: A cured adhesive tape composition for adhering together roofing materials such as synthetic EPDM rubber and which provides long term water tightness is provided. The adhesive composition includes a) a rubbery polymer comprising a blend of (i) from about 12% or less by weight of the total composition of an ethylene-propylene-diene terpolymer, (ii) a halogenated butyl rubber or a halogenated copolymer of p-methylstyrene and isobutylene, (iii) polyisobutylene, and (iv) a butyl terpolymer, and b) a compatible tackifier, and c) an accelerator/cure package for the rubbery polymer. The cured composition exhibits a peel strength of at least 1000 grams/cm at room temperature, at least 500 grams/cm at 70° C., and supports a static load of at least 300 grams at 70° C.Type: GrantFiled: March 31, 1995Date of Patent: October 2, 2001Assignee: Adco Products, Inc.Inventors: Brian Jonathon Briddell, Dennis Keith Fisher, James Fredrick Wood
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Publication number: 20010012875Abstract: This invention is based upon the discovery that cyclized polyisoprene polymers can be incorporated into tire tread compounds to improve traction, treadwear, and resistance to tear. It is further based upon the discovery that cyclized polyisoprene polymers can be blended with halobutyl rubber and/or natural rubber and can be utilized in tire innerliner formulations. The present invention more specifically discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidwalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of a sulfur cured rubber composition which is comprised of about 5 phr to about 50 phr of cyclized polyisoprene and about 50 phr to about 95 phr of at least one other rubbery polymer.Type: ApplicationFiled: April 2, 2001Publication date: August 9, 2001Applicant: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Joseph Frank Geiser, Judy Chu, David John Zanzig, Richard George Bauer
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Patent number: 6262175Abstract: A thermoplastic elastomer composition containing in percentages by weight based on the total weight of the composition, about 5% to about 90% vulcanized rubber crumb; about 5% to about 60% polyolefin; about 2% to about 30% uncured rubber or styrene-based thermoplastic elastomer; and about 2% to about 30% vinyl polymer selected from vinyl homopolymers, copolymers and mixtures. The composition in total contains less than 15% styrene block copolymer.Type: GrantFiled: May 1, 1998Date of Patent: July 17, 2001Assignee: NRI Technology Inc.Inventors: James R. Jury, Alfred Wing Yan Chien
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Patent number: RE37683Abstract: A cured adhesive tape composition for adhering together roofing materials such as synthetic EPDM rubber and which provides long term water tightness is provided. The adhesive composition includes substantially equal amounts by weight of a) a rubbery polymer comprising a blend of an ethylene-propylenediene terpolymer, a halogenated butyl rubber or a halogenated copolymer of p-methylstyrene and isobutylene, and polyisobutylene b) a compatible tackifier, and c) an accelerator/cure package for the rubbery polymer. The cured composition exhibits a peel strength of at least 715 grams/cm at room temperature, at least 300 grams/cm at 70° C., and supports a static load of at least 300 grams at 70° C.Type: GrantFiled: January 26, 2001Date of Patent: April 30, 2002Assignee: Adco Products, Inc.Inventors: Brian J. Briddell, Michael J. Hubbard
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Patent number: H2036Abstract: This invention relates to blends of a specific type of cis-l,4-polybutadiene rubber with other rubbery polymers, such as natural rubber, synthetic polyisoprene rubber, styrene-butadiene rubber, isoprene-butadiene rubber and/or styrene-isoprene- butadiene rubber. The cis-1,4-polybutadiene rubber utilized in the blends of this invention is synthesized by polymerizing 1,3-butadiene in the presence of (a) an organonickel compound, (b) an organoaluminum compound, (c) a fluorine containing compound and (d) para-styrenated diphenylamine; wherein the organoaluminum compound and the fluorine containing compound are brought together in the presence of the para-styrenated diphenylamine. The cis-1,4-polybutadiene rubber blends of this invention offer improved processability and enhanced physical properties. For instance, improved mixing which results in better incorporation of pigments and fillers, such as carbon black and silica, at lower levels of power consumption is realized.Type: GrantFiled: June 2, 1999Date of Patent: July 2, 2002Assignee: The Goodyear Tire & Rubber CompanyInventor: Jerry Levi Bush