Imide Patents (Class 525/282)
  • Patent number: 5977261
    Abstract: Living random (meth)acrylic copolymers, facilely converted into random co(meth)acrylates and block copolymers thereof, comprise the anionic copolymerizates of at least one comonomer A with at least one comonomer B selected from among the (meth)acrylates and maleimides, at least one of the comonomers A and B comprising a (meth)acrylate, in the presence of (i) at least one alkali or alkaline earth metal, mono- or difunctional initiator and (ii) at least one ligand, for example a nonnitrogenous macrocyclic complexant, e.g., a crown ether, or an alkali metal alcoholate.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: November 2, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Jin-shan Wang, Philippe Bayard, Philippe Teyssie, Bruno Vuillemin, Philippe Heim
  • Patent number: 5874389
    Abstract: A grafted polyolefin containing one or more of N-vinylimidazole, 4-vinylpyridine, or other ethylenically-unsaturated nitrogen-containing or oxygen-containing graftable monomers grafted to a polyolefin copolymer is disclosed. The grafted polyolefin preferably has a weight average molecular weight of from about 20,000 to about 500,000, a polydispersity of less than about 10, and an ADT value of at least about 8. The grafted polyolefin can be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin, or as containing at least about 13 moles of graftable monomers per mole of polyolefin, or as having an asphaltene dispersancy test (ADT) value of at least about 8. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant viscosity index improver.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: February 23, 1999
    Assignee: Castrol Limited
    Inventors: Frederick J. Boden, Richard P. Sauer, Irwin L. Goldblatt, Michael E. McHenry
  • Patent number: 5852123
    Abstract: A polymeric dispersant for pigments based on an acrylic graft copolymer wherein the graft copolymer has a weight average molecular weight of at least 1500 and has 2 to 97% by weight of a polymeric backbone and 97-2% by weight of macromonomer side chains attached to the backbone and wherein the graft copolymer has at least about 1 weight percent of an imid or urea functional dispersing substituent attached to the backbone, the macromonomer, or both the backbone and the macromonomer.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: December 22, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Jozef Huybrechts
  • Patent number: 5817720
    Abstract: Polyolefins modified by radical grafting with an unsaturated polyfunctional compound containing an imide group and an ester group having general formula (I): ##STR1##
    Type: Grant
    Filed: February 11, 1997
    Date of Patent: October 6, 1998
    Assignee: Enichem S.p.A.
    Inventors: Giuliana Schimperna, Maria Antonella Pastorino, Maria Caldararo, Francesco Toscani, Maurizio Sguaita
  • Patent number: 5814586
    Abstract: A grafted polyolefin containing at least about 13 moles of N-vinylimidazole or other ethylenically-unsaturated nitrogen-containing and/or oxygen-containing monomers per mole of a grafted polyolefin backbone is disclosed. The graft polyolefin has a weight average molecular weight of from about 20,000 to about 500,000 and a polydispersity of less than about 10. The grafted polyolefin can alternatively be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant-viscosity index improver. N-vinylimidazole or other ethylenically unsaturated nitrogen-containing and/or oxygen-containingmonomers and a graftable polyolefin are reacted with enough of an initiator to graft at least about 13 moles of the monomer to each mole of the polyolefin.
    Type: Grant
    Filed: May 7, 1996
    Date of Patent: September 29, 1998
    Assignee: Castrol Limited
    Inventors: Frederick J. Boden, Richard P. Sauer, Irwin L. Goldblatt, Michael E. McHenry
  • Patent number: 5744513
    Abstract: Photolytically crosslinkable thermally stable compositions comprising at least one crosslinkable polymer and a crosslinkable quantity of a multifunctional 3,4-disubstituted maleimide. The compositions may be employed to prepare adhesives and photo printing mats.
    Type: Grant
    Filed: October 29, 1991
    Date of Patent: April 28, 1998
    Assignee: The Dow Chemical Company
    Inventors: Jerry E. White, Mary K. Dehnke, Lu Ho Tung
  • Patent number: 5728775
    Abstract: A heat-resistant high-nitrile polymer composition obtained by the graft copolymerization of 100 parts by weight of a monomer mixture comprising 50 to 80% by weight of an unsaturated nitrile monomer, a maleimide monomer, an aromatic vinyl monomer, and a monomer copolymerizable with the foregoing monomers, in the presence of 1 to 40 parts by weight of a conjugated diene-based synthetic rubber containing not less than 50% by weight of a conjugated diene monomer unit, wherein the concentration of residual maleimide monomer in the polymer composition is not greater than 200 ppm by weight. This polymer composition is suitable for use as a molding material for extrusion molding, blow molding, injection molding and the like, and is useful in applications which require gas barrier properties, chemical resistance, non-adsorptive properties and the like, and which require use in automobiles, heat resistance sufficient for heat filling, and safety and hygienic properties.
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: March 17, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hiroaki Narisawa, Masahiro Kaneko, Mitsuo Kawata, Syuichi Yamaguchi, Shinichi Asai, Makoto Someda
  • Patent number: 5717034
    Abstract: In accordance with the present invention, it has been discovered that perfluorinated hydrocarbon polymers can be used as fillers for the preparation of adhesive formulations having excellent dielectric properties, i.e., very low conductivities. Invention compositions display excellent rheological properties, in addition to low dielectric constants. Invention formulations can be used for a variety of purposes, such as, for example, for the preparation of filled adhesive formulations with a reduced propensity to settle out, excellent dispensing characteristics due to the thixotropic nature thereof, and the like.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: February 10, 1998
    Assignee: Quantum Materials, Inc.
    Inventors: Stephen M. Dershem, Deborah D. Forray
  • Patent number: 5708128
    Abstract: Novel thermoset polyimide and composite materials comprising the thermoset polyimides and a fibrous reinforcement are prepared according to this invention. The thermoset polyimides are obtained by heat-treating a linear polyamic acid or a linear polyimide prepared by using 4,4'-bis(3-aminophenoxy)biphenyl and pyromellitic dianhydride as essential monomers or by adding 4,4'-diaminodiphenyl ether or 3,3',4,4'-biphenyltetracarboxylic dianhydride to the essential monomers and by end-capping the molecular chain end with an aromatic dicarboxylic anhydride having a carbon-carbon triple bond. The thermoset polyimides have essential excellent properties of thermoplastic polyimide and additionally has enhanced heat resistance and improved mechanical properties. The thermoset polyimide can be used to provide various kinds of composite materials for aircraft matrices, electric and electronic appliances and others.
    Type: Grant
    Filed: June 24, 1996
    Date of Patent: January 13, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hideaki Oikawa, Shoji Tamai, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5698636
    Abstract: An ocular lens material containing a polymer having a maleimide derivative-.alpha.-methylstyrene unit and N,N-dimethylacrylamide unit, which is excellent in optical property, has a high water-absorptive property and a high mechanical strength and further only shows an extremely small size change based on pH change of a solution under the hydrated state, and which can be preferably used for, in particular, water-absorptive contact lenses and the like, and a process for producing the same.
    Type: Grant
    Filed: February 5, 1997
    Date of Patent: December 16, 1997
    Assignee: Tomey Technology Corporation
    Inventor: Hideaki Kamiya
  • Patent number: 5668231
    Abstract: Novel N-substituted maleimide homopolymers having a number-average molecular weight ranging from 12,000 to about 100,000 are prepared by anionically polymerizing an N-substituted maleimide monomer, in solvent phase, in the presence of at least one organometallic polymerization initiator which comprises sec-butyllithium, a sodium alcoholate, diphenylmethylpotassium, naphthalenelithium or naphthalenesodium, and novel N-substituted maleimide homopolymers having a polydispersity index ranging from 1.1 to 1.5 are prepared by anionically polymerizing an N-substituted maleimide monomer, in solvent phase, in the presence of at least one alkali metal organometallic polymerization initiator and at least one inorganic or organic salt of an alkali or alkaline earth metal; novel block copolymers include blocks of the above maleimido homopolymers and, e.g., blocks of an acrylic or methacrylic polymer.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: September 16, 1997
    Assignee: Atochem
    Inventors: Sunil K. Varshney, Philippe Teyssie, Roger Fayt
  • Patent number: 5663126
    Abstract: A grafted polyolefin containing N-vinylimidazole, 4-vinylpyridine, or other ethylenically-unsaturated nitrogen- or oxygen-containing graftable monomers grafted to a polyolefin copolymer. The grafted polyolefin preferably has a weight average molecular weight of from about 20,000 to about 500,000 and a polydispersity of less than about 10. The grafted polyolefin can contain more than about 1.2% by weight of grafted monomer or 13 or more moles of graftable monomers per mole of polyolefin and have an asphaltene dispersancy test (ADT) value of at least about 8. Also described is a lubricating oil comprising such a grafted polyolefin. Also described is a method of making a grafted polyolefin dispersant viscosity index improver by adding the graft monomer or the initiator slowly during the reaction. The present reaction can optionally be carried out by providing a melted reactant composition in an extruder or other polymeric mixer.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: September 2, 1997
    Assignee: Castrol Limited
    Inventors: Frederick J. Boden, Richard P. Sauer, Irwin L. Goldblatt, Michael E. McHenry
  • Patent number: 5635565
    Abstract: A rubber-modified thermoplastic resin is obtained by polymerizing (b) an aromatic vinyl compound and (c) a vinyl cyanide compound in the presence of (a) a rubbery polymer, and in which the content of the component (a) is 50 to 85% by weight, the content of the component (b) is 5 to 48% by weight and the content of the component (c) is 2 to 45% by weight, and which resin has a Q value of 30.times.10.sup.-4 to 50.times.10.sup.-3 and a grafting degree of 5% by weight or more. A thermoplastic resin composition comprising the above rubber-modified thermoplastic resin and at least one other thermoplastic resin is prepared.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: June 3, 1997
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hajime Miyajima, Tsugio Asakawa, Noriaki Ijuin, Hiroo Nakamura, Toshihiro Ogawa, Shinichi Kimura
  • Patent number: 5627222
    Abstract: The subject invention pertains to toughened thermosetting resin systems useful as structural adhesives and as matrix resins for thermosetting fiber-reinforced prepregs. These toughened resins employ a most minor amount of functionalized elastomeric particles having a T.sub.g of 10.degree. C. or below dispersed in a thermosetting base resin system.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: May 6, 1997
    Assignee: Cytec Technology Corp.
    Inventors: Hans G. Recker, Volker Altsaedt, Helmut Tesch, Thomas Weber
  • Patent number: 5602205
    Abstract: Novel polyfunctional maleimides as well as novel compositions based on mono- and polyfunctional maleimides are provided. Also provided are heat resistance resin compositions and curable compositions incorporating the same. The monofunctional maleimide is N-(2,3-dimethylphenyl)maleimide, and the polyfunctional maleimides are bis- and higher functional variations thereof.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: February 11, 1997
    Assignee: Cytec Technology Corp.
    Inventors: Balwant Singh, Robert J. Tynik
  • Patent number: 5594093
    Abstract: A nonlinear optical polymer material comprising at least one polymer selected from the group consiting of polyimides, acrylic resins and benzocyclobutene resins containing, as a guest molecule, as a side chain, or in the main chain, a molecule or a chemical moiety having a basic structure of merocyanine dye represented by the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 independently represent hydrogen or an organic group, provided that R.sup.1 and R.sup.2 or R.sup.3 and R.sup.5 may independently combine together to form an organo ring structure, and n is an integer of 1 to 3.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 14, 1997
    Assignee: Fujitsu Limited
    Inventors: Wataru Sotoyama, Satoshi Tatsuura, Tetsuzo Yoshimura, Azuma Matsuura, Tomoaki Hayano
  • Patent number: 5589550
    Abstract: A polyacrylate made from a monomer mixture containing alkyl acrylates and optionally ethylene, propylene, and acrylonitrile, and/or an alkoxyl alkyl or alkythioalkyl acrylate is cured with 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane and m-phenylenediamine maleimide.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: December 31, 1996
    Assignee: Zeon Chemicals Incorporated
    Inventors: Paul E. Manley, Richard J. Flecksteiner
  • Patent number: 5578682
    Abstract: The present invention provides a post-polymerization process for modifying the molecular weight distribution of a polymer having a monomodal molecular weight distribution, which polymer normally exhibits a decrease in molecular weight when subjected to high shear mixing in the presence of a free radical initiator, to produce a polymer having a bimodal molecular weight distribution. The process comprises:(a) heating a mixture of the polymer, a polyunsaturated crosslinking agent and, optionally, a free radical initiator, to form a uniform mixture; and(b) subjecting said mixture to high shear mixing conditions until a polymer having a bimodal molecular weight distribution is obtained. In the more preferred embodiment, the shear mixing is conducted in the presence of a free radical initiator such as an organic peroxide and the crosslinking agent is a difunctional compound containing diallyl, divinyl or diethylenic unsaturation.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: November 26, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Donald A. White
  • Patent number: 5567800
    Abstract: Controlled molecular weight phenylethynyl terminated imide oligomers (PETIs) have been prepared by the cyclodehydration of precursor phenylethynyl terminated amic acid oligomers. Amino terminated amic acid oligomers are prepared from the reaction of dianhydride(s) with an excess of diamine(s) and subsequently endcapped with phenylethynyl phthalic anhydride(s) (PEPA). The polymerizations are carried out in polar aprotic solvents such as N-methyl-2-pyrrolidinone or N,N-dimethylacetamide under nitrogen at room temperature. The amic acid oligomers are subsequently cyclodehydrated either thermally or chemically to the corresponding imide oligomers. Direct preparation of PETIs from the reaction of dianhydride(s) with an excess of diamine(s) and endcapped with phenylethynyl phthalic anhydride(s) has been performed in m-cresol. Phenylethynyl phthalic anhydrides are synthesized by the palladium catalyzed reaction of phenylacetylene with bromo substituted phthalic anhydrides in triethylamine.
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: October 22, 1996
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Paul M. Hergenrother, Joseph G. Smith, Jr.
  • Patent number: 5556913
    Abstract: The present invention provides a cationic electrocoating composition which cures at the preferred curing temperature range and provides superior curing properties and cured film properties. The cationic electrocoating composition of the present invention comprises a resinous component and an aqueous medium, wherein the resinous component is composed of one or more polymers and has as a whole an active hydrogen containing group, a cationic group and a substituted group and at least one of the polymers comprises a vinyl polymer which has 5 to 1,000 substituted acylamide groups.
    Type: Grant
    Filed: January 3, 1994
    Date of Patent: September 17, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Kenshiro Tobinaga, Hiroyuki Sakamoto, Shinsuke Shirakawa, Satoshi Urano, Yasuyuki Tsuchiya
  • Patent number: 5523008
    Abstract: A grafted polyolefin containing at least about 13 moles of N-vinylimidazole or other ethylenically-unsaturated nitrogen-containing and/or oxygen-containing monomers per mole of a grafted polyolefin backbone is disclosed. The graft polyolefin has a weight average molecular weight of from about 20,000 to about 500,000 and a polydispersity of less than about 10. The grafted polyolefin can alternatively be defined as containing more than about 1.2% by weight of grafted monomer on a polyolefin. Also described is a lubricating oil comprising a lubricant base oil and a grafted polyolefin as described above. Also described is a method of making a dispersant-viscosity index improver. N-vinylimidazole or other ethylenically unsaturated nitrogen-containing and/or oxygen-containing monomers and a graftable polyolefin are reacted with enough of an initiator to graft at least about 13 moles of the monomer to each mole of the polyolefin.
    Type: Grant
    Filed: October 21, 1994
    Date of Patent: June 4, 1996
    Assignee: Castrol Limited
    Inventors: Frederick J. Boden, Richard P. Sauer, Irwin L. Goldblatt, Michael E. McHenry
  • Patent number: 5512628
    Abstract: This invention is to provide a liquid adhesive of the present invention can be adhered and cured at a relatively low temperature and have sufficient heat resistance and reliability, etc., and an adhesive tape using the same.The liquid adhesive of this invention is obtainable by dissolving (a) a piperazinylethylaminocarbonyl-containing butadiene-acrylonitrile copolymer having a weight average molecular weight of 10,000-200,000, an acrylonitrile content of 5-50% by weight, and an amino equivalent of 500-10,000, represented by the following formula (I): ##STR1## wherein, k, m, and n are molar ratios and taking n as 1, k is a number of 3-175, and m is a number of 0.3 to 93; and (b) a compound having at least two maleimide groups, the ratio of component (b) based on 100 parts by weight of component (a) being in the range of 10 to 900 parts by weight.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 30, 1996
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Yukinori Sakumoto, Takeshi Hashimoto, Katsuji Nakaba, Masaharu Kobayashi, Takeshi Nishigaya, Fumiyoshi Yamanashi
  • Patent number: 5508354
    Abstract: Novel metal salts of (poly)citraconimide and (poly)itaconimide carboxylic acids, and a vulcanizable rubber composition comprising these novel metal salts and which, upon vulcanization, exhibits improved dynamic properties, are disclosed. Also disclosed are a sulfur-vulcanization process carried out in the presence of these metal salts and the product of said vulcanization process. The novel metal salts are represented by formulas (I) and (II), wherein R.sub.1, R.sub.2 and R.sub.3 are independently selected from hydrogen, C.sub.1 -C.sub.18 alkyl groups, C.sub.3 -C.sub.18 cycloalkyl groups, C.sub.6 -C.sub.18 aryl groups, C.sub.7 -C.sub.30 aralkyl groups and C.sub.7 -C.sub.30 alkaryl groups and R.sub.2 and R.sub.3 may combine to form a ring when R.sub.1 is hydrogen; R.sub.4 is selected from divalent, trivalent or tetravalent linear or branched radical chosen from a C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.2 -C.sub.18 alkynyl, C.sub.3 -C.sub.18 cycloalkyl, C.sub.3 -C.sub.18 polycycloalkyl, C.sub.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: April 16, 1996
    Assignee: Akzo Nobel N.V.
    Inventors: Auke G. Talma, Rabindra N. Datta
  • Patent number: 5500251
    Abstract: N-(4-alkylphenyl)acrylamides, N-(4-alkylphenyl)methacrylamides and N-(4-alkylphenyl)maleimides, when co-polymerized into conventional polymer systems promote adhesion of such systems to low energy polyolefin surfaces. These compounds are effective in increasing the adhesive coating properties of both solution polymer and emulsion polymer systems.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: March 19, 1996
    Assignee: Air Products and Chemicals, Inc.
    Inventors: William F. Burgoyne, Jr., Wiley E. Daniels, Dennis Sagl, Heueh-Chi Lee, Menas S. Vratsanos
  • Patent number: 5494757
    Abstract: This invention is to provide a liquid adhesive of the present invention can be adhered and cured at a relatively low temperature and have sufficient heat resistance and reliability, etc., and an adhesive tape using the same.The liquid adhesive of this invention is obtainable by dissolving (a) a piperazinylethylaminocarbonyl-containing butadiene-acrylonitrile copolymer having a weight average molecular weight of 10,000-200,000, an acrylonitrile content of 5-50% by weight, and an amino equivalent of 500-10,000, represented by the following formula (I): ##STR1## wherein, k, m, and n are molar ratios and taking n as 1, k is a number of 3-175, and m is a number of 0.3 to 93; and (b) a compound having at least two maleimide groups, the ratio of component (b) based on 100 parts by weight of component (a) being in the range of 10 to 900 parts by weight.
    Type: Grant
    Filed: October 20, 1994
    Date of Patent: February 27, 1996
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Yukinori Sakumoto, Takeshi Hashimoto, Katsuji Nakaba, Masaharu Kobayashi, Takeshi Nishigaya, Fumiyoshi Yamanashi
  • Patent number: 5489657
    Abstract: A bulk process is provided for making maleimide copolymers. The process involves reacting a monomer mixture comprising a maleimide monomer compound, a vinyl aromatic compound and a vinyl cyanide compound in a continuous stirred tank reactor, and then further reacting the material in a plug flow reactor to obtain a desired conversion level, and then devolatizing the product. The process provides enhanced oligomer control and enhanced levels of glass transition temperature and other properties. The maleimide copolymer obtained by the process may be further blended with impact modifiers to produce thermoplastic compositions which are useful for making molded articles such as automotive parts for under the hood applications, such as distributor caps.
    Type: Grant
    Filed: October 21, 1994
    Date of Patent: February 6, 1996
    Assignee: General Electric Company
    Inventors: Chen-Youn Sue, Gregory R. Prince, Stephen M. Campbell
  • Patent number: 5466753
    Abstract: Grafted propylene copolymers having a melt flow index of from 0.1 to 100 g/10 min, at 230.degree. C. and under a weight of 2.16 kg, comprisinga.sub.1) a polymer comprising from 25 to 97% by weight of a propylene copolymer (I), which contains from 0.1 to 15% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes, and from 3 to 75% by weight of a further propylene copolymer (II) which contains from 15 to 80% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes, or comprisinga.sub.2) a polymer comprising from 25 to 97% by weight of a propylene homopolymer and from 3 to 75% by weight of a propylene copolymer containing copolymerized C.sub.2 -C.sub.10 -alk-1-enes, the comonomer content being from 15 to 80% by weight, based on the latter component, andb) a monomaleimide compound of the following formula (I) ##STR1## where R has the following meanings: C.sub.1 -C.sub.10 -alkyl, it being possible for the alkyl radical to be interrupted by one or more oxygen atoms, C.sub.5 -C.sub.10 -cycloalkyl, C.sub.6 -C.sub.
    Type: Grant
    Filed: September 20, 1994
    Date of Patent: November 14, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd L. Marczinke, Hans-Joachim Muller
  • Patent number: 5461125
    Abstract: The present invention provides:A core-shell insert latex composition comprising latex particles, each latex particle comprising:(a) a core comprising a (co)polymer comprising (meth)acrylate ester;(b) a shell, surrounding the core, comprising a copolymer, wherein the copolymer comprises:(i) a nitrogen-bearing ethylenically-unsaturated free-radically polymerizable monomer;(ii) at least one (meth)acrylate ester of about a C.sub.1 to about a C.sub.14 alcohol; and(iii) an optional ethylenically-unsaturated free-radically polymerizable silane monomer; wherein the nitrogen-bearing ethylenically-unsaturated free-radically polymerizable monomer comprises from about 15 to about 60 percent by weight of the shell and further wherein the core comprises from about 40 to about 85 percent of the weight of the total core-shell latex particle.The invention also relates to the use of the core-shell latex composition as a binder or primer for coatings and adhesives.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: October 24, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ying-Yuh Lu, Chi-Ming Tseng, James E. Bunker, Terrence E. Cooprider, Ronald W. Most, Gregory J. Stanich
  • Patent number: 5446103
    Abstract: Graft copolymerized maleimide-modified, impact resistant monovinylidene aromatic copolymer compositions have substantially improved impact strength and fatigue resistance properties when the swelling index thereof is 12 or greater and when the numerical difference in maleimide monomer content as between the grafted copolymer and matrix copolymer portions thereof differ by no more than 9 percentage points from each other. Such compositions are conveniently prepared by mass, solution or mass/suspension graft copolymerization processes and by deferring the addition of at least about 30 percent of the maleimide monomer ingredient to a point in the process after (and preferably only shortly after) phase inversion of the dissolved impact modifying rubbery polymer ingredient.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: August 29, 1995
    Assignee: The Dow Chemical Company
    Inventors: Thomas D. Traugott, Shari L. Workentine
  • Patent number: 5439981
    Abstract: Graft polymers which comprise 20 to 99.9% by weight of an ethylene copolymer (base polymer) and 0.1 to 80% by weight of a graft component. The base polymer includes 30% to 95% by weight of ethylene and (1) 5% to 70% by weight of vinyl esters of saturated aliphatic C.sub.2 - to C.sub.18 -monocarboxylic acids or (2) 4% to 50% by weight of vinyl esters of saturated aliphatic C.sub.2 - to C.sub.18 -monocarboxylic acids and 1% to 20% by weight of linear or branched C.sub.3 - to C.sub.18 -monoolefins. Graft components are N-substituted alpha,beta-unsaturated dicarboxylic acid imides, dicarboxylic acid amides, dicarboxylic acid half-amides, or ammonium salts of the half-amides. The graft polymers are employed for improving the flow properties of paraffin-containing mineral oils, mineral oil distillates, and middle distillates.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: August 8, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Juliane Balzer, Michael Feustel, Matthias Krull, Werner Reimann
  • Patent number: 5432237
    Abstract: Disclosed is a radical polymerizable composition comprised of a polymer having a .pi.-electron conjugated structure having repeating units of a mono-substituted or di-substituted isothianaphthene structure, which is represented by the formula [Ia] and/or [Ib]: ##STR1## wherein R.sup.1 and R.sup.2 represent hydrogen, C1-C18 alkoxy group, or --O(CH.sub.2 CH.sub.2 O).sub.n CH.sub.3 [n: 1 to 4] with the proviso that the case where both R.sup.1 and R.sup.2 represent hydrogen is excluded, X is an anion, y is from 0.01 to 1, and m is from 5 to 5,000,and a radical polymerizable compound. The radical polymerizable composition has a very stable electroconductivity in air and can be molded into an optional shape.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: July 11, 1995
    Assignee: Showa Denko K.K.
    Inventors: Reiko Otsuka, Yoshiaki Ikenoue, Yoshihiro Saida, Masao Kobayashi
  • Patent number: 5424364
    Abstract: The polymeric pigment dispersants of this invention are polyester/acrylic comb polymers which are the reaction product of 20-85% of a carboxylic functional polyester copolymer, 10-50% of an oxirane substituted acrylic copolymer, and 2 to 20% of an imide compound. These materials disperse a wide variety of pigments and are useful in solvent borne coatings where they can provide improved efficiency of pigment use, lower paint viscosity, and reduced emission of volatile organic solvent.
    Type: Grant
    Filed: May 17, 1994
    Date of Patent: June 13, 1995
    Assignee: E. I. Du Pont de Nemours & Company
    Inventors: John A. Simms, Michael W. J. West
  • Patent number: 5420210
    Abstract: A novel formamide group-containing copolymer, or a salt thereof, which can be used as a high-molecular weight amino reagent, a starting material for functional high-molecular weight compounds, a starting material for adhesives, a polymer compatibilizer, a resin modifier, etc., and can undergo hydrolysis to give a copolymer containing a primary amino group, and a novel copolymer containing a primary amino group obtained by hydrolysis.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: May 30, 1995
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Naoki Kitazawa, Hiroshi Hotta, Hideyuki Sumi, Manabu Kikuta
  • Patent number: 5412036
    Abstract: Graft copolymerized maleimide-modified, impact resistant monovinylidene aromatic copolymer compositions have substantially improved impact strength and fatigue resistance properties when the swelling index thereof is 12 or greater and when the numerical difference in maleimide monomer content as between the grafted copolymer and matrix copolymer portions thereof differ by no more than 9 percentage points from each other. Such compositions are conveniently prepared by mass, solution or mass/suspension graft copolymerization processes and by deferring the addition of at least about 30 percent of the maleimide monomer ingredient to a point in the process after (and preferably only shortly after) phase inversion of the dissolved impact modifying rubbery polymer ingredient.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: May 2, 1995
    Assignee: The Dow Chemical Company
    Inventors: Thomas D. Traugott, Shari L. Workentine
  • Patent number: 5408023
    Abstract: Addition polymers of ethylenically unsaturated monomers are provided comprising a 5-, 6- or 7-membered polymer unit formed from a copolymerizable, unsaturated, chain transfer agent containing a labile hydrogen and capable of forming by means of a hydrogen shift mechanism a free radical having 5, 6 or 7 atoms between and including the .alpha.-carbon of the ethylenically unsaturated group and the labile hydrogen.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: April 18, 1995
    Assignee: The Dow Chemical Company
    Inventors: Duane B. Priddy, Brian R. Maurer
  • Patent number: 5397844
    Abstract: Polyacrylates and their use for powder coatings are disclosed. In order to prepare the polyacrylates, acrylic acid, methacrylic acid, their esters with C.sub.1 -C.sub.4 alcohols, and/or fumaric acid, maleic acid, and their anhydrides are first polymerized. The polymers are then reacted with long chain alcohols, one alcohol having an aliphatic chain with 6 to 36 carbon atoms and a second alcohol having a cyclic amide structure. This polyacrylate is suitable as a levelling agent for powder coatings, in particular for powder lacquers. It improves the flowing behavior by reducing the orange peel effect and improves flowability.
    Type: Grant
    Filed: February 7, 1994
    Date of Patent: March 14, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Herbert Fischer, Wolfgang Gress, Doris Oberkobusch
  • Patent number: 5373065
    Abstract: A process for producing a novel formamide group-containing copolymer, or a salt thereof, which can be used as a high-molecular weight amino reagent, a starting material for functional high-molecular weight compounds, a starting material for adhesives, a polymer compatibilizer, a resin modifier, etc.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: December 13, 1994
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Naoki Kitazawa, Hiroshi Hotta, Yasuhisa Sugita, Katsutoshi Ohta
  • Patent number: 5364700
    Abstract: Described herein are novel rubber modified bismaleimide resins and prepregable resin compositions comprising these bismaleimides and one or more liquid co-reactants and optionally, one or more other additives.
    Type: Grant
    Filed: December 27, 1985
    Date of Patent: November 15, 1994
    Assignee: Amoco Corporation
    Inventor: Linda A. Domeier
  • Patent number: 5362807
    Abstract: An acrylic molded product comprising an acrylic polymer coagulated material having excellent characteristics in impact resistance, optical properties, and hydrothermal resistance; an acrylic polymer coagulated material used for the preparation thereof; an composition comprising thereof; and a process for manufacture thereof; characterized by using an emulsion polymerization and a polymer with multiphase structured material comprising a hard phase and a soft phase and being freeze-coagulated.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: November 8, 1994
    Assignee: Kuraray Co., Ltd.
    Inventors: Kouichi Nogura, Kouichi Fujie, Chouji Suga, Naokiyo Inomata, Mitsuo Ootani
  • Patent number: 5356950
    Abstract: A grafted polymer of an isomonoolefin and an alkylstyrene, such as a maleic anhydride-grafted copolymer of isobutylene and para-methylstyrene, is provided. Processes for preparing the grafted polymer are also provided.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: October 18, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Donald A. White, Hsien C. Wang
  • Patent number: 5346964
    Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above. Said hydrogenated diene block copolymer is useful as a modifier for polar resins, non-polar resins or both of them.
    Type: Grant
    Filed: June 23, 1993
    Date of Patent: September 13, 1994
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Tooru Shibata, Toshio Teramoto, Yoshiharu Hashiguchi, Kunio Goshima
  • Patent number: 5328963
    Abstract: The present invention relates to a sulfur vulcanized rubber composition containing 0.1 to 10.0 phr of an oligomeric maleimide of the formula: ##STR1## or a maleamic acid of the formula: ##STR2## wherein R and R.sup.1 are individually selected from the group of radicals consisting of hydrogen, an alkyl having 1 to 4 carbon atoms or a halogen; R.sup.2 is selected from the group of radicals consisting of 1 to 12 carbon atoms; X has a value of from 1 to 146 and n has a value of from 0 to 4.The presence of the maleimide oligomer or maleamic acid improve cord adhesion to the sulfur vulcanized rubber compound.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: July 12, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Joel Muse, Paul H. Sandstrom, Lawson G. Wideman
  • Patent number: 5328962
    Abstract: Miscible polymer blends of high heat resistant acrylate-maleimide polymers containing from 1 to 99% or more by weight of the maleimided polymer with conventional poly (methyl methacrylate) polymer, the blends having higher glass transition temperatures than poly (methyl methacrylate) but substantially the same optical and mechanical properties as poly (methyl methacrylate) and compatible blends of high heat resistant acrylate-maleimide polymers, conventional acrylic impact modifier, and, optionally, conventional poly (methyl methacrylate).
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: July 12, 1994
    Assignee: ICI Acrylics, Inc.
    Inventor: Jyi-Sheng J. Shen
  • Patent number: 5321078
    Abstract: A thermoplastic resin composition comprising (A) 45 to 99% by weight of a graft copolymer obtained by special graft polymerization of a monomer (b) such as an aromatic vinyl compound, a methacrylic ester, etc. in the presence of grafted polymer rubber (a), and (B) 55 to 1% by weight of a thermoplastic aromatic polyester resin can yield shaped articles excellent in impact resistance, chemical resistance, etc. with excellent processability.
    Type: Grant
    Filed: September 25, 1992
    Date of Patent: June 14, 1994
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Kiyotaka Mashita, Tatsuo Ishikawa, Susumu Era, Isamu Hattori
  • Patent number: 5314963
    Abstract: Graft Polymers of a cross-linked copolymer of compounds of formula (I) or (II) ##STR1## and another vinyl compound as graft basis, and a polymerized vinyl group-containing phosphonic acid derivative as graft.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: May 24, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Dieter Wittmann
  • Patent number: 5306779
    Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above and in which hydrogenation product at least 80% of the double bonds of the conjugated diene portion is saturated by the hydrogenation.
    Type: Grant
    Filed: September 1, 1992
    Date of Patent: April 26, 1994
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Tooru Shibata, Toshio Teramoto, Yoshiharu Hashiguchi, Kunio Goshima
  • Patent number: 5306778
    Abstract: A process for producing a rubber-modified thermoplastic resin, which comprises polymerizing (B) 30-100% by weight of an aromatic alkenyl compound monomer and/or an alkyl (meth)acrylate monomer and (C) 70-0% by weight of at least one other monomer compound copolymerizable therewith, in the presence of (A) a hydrogenated diene copolymer obtained by hydrogenating a diene copolymer comprising a rndom copolymer of 50% by weight or more of at least one conjugated diene and 50% by weight or less of an alkenyl aromatic compound until at least 70% by weight of the olefinic unsaturation of the diene copolymer is hydrogenated.
    Type: Grant
    Filed: February 11, 1993
    Date of Patent: April 26, 1994
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Atushi Ishida, Katsuro Oomura, Yuji Yamamoto, Yuji Nakagawa, Tateki Furuyama, Hisao Nagai, Toshio Teramoto, Yasuo Takahashi, Hideki Ueda, Kazuhiko Yamamoto, Toshihiro Shimamura, Yoshinobu Suzuki
  • Patent number: 5302661
    Abstract: A composition which contains thermosettable monomers from which continuous products can be made without using continuous carrier material, the composition containing bismaleimide monomers and a thermoplastic polymer having a high molecular weight.Products made from a composition of the present invention are suitable for use in those fields where good temperature resistance, good fire resistance and/or good corrosion and solvent resistance are required in addition to good mechanical properties. Examples are cable sheathing, fire-resistant clothing, asbestos substitutes, high-temperature filters, aircraft interiors, precursors for carbon fiber , food packagings (for example, for use in a microwave oven), capacitor films and filament winding products.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: April 12, 1994
    Assignee: DSM N.V.
    Inventor: Cornelius W. M. Bastiaansen
  • Patent number: 5298560
    Abstract: A partially crosslinked thermoplastic resin composition is prepared by dynamically heat-treating a thermoplastic resin (A) in the presence of a carbon radical inducing agent (B) comprising a charge transfer complex or a combination of a hydrogen donating compound and a hydrogen accepting compound.
    Type: Grant
    Filed: May 14, 1991
    Date of Patent: March 29, 1994
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Fuyuki Aida, Masaaki Miyazaki, Mamoru Nagai
  • Patent number: 5298565
    Abstract: A graft polymer is prepared by grafting, onto a polymeric substantially saturated hydrocarbon backbone, a free-radical polymerizable vinyl nitrogen monomer, which grafting takes place with improved efficiency in the presence of minor amounts of a volatile aliphatic hydrocarbon substituted aromatic solvent capable of free-radical hydrogen atom chain transfer. The modified hydrocarbon based polymer finds utility as an additive for lubricating oils, particularly as dispersant-viscosity improvers for engine oils.
    Type: Grant
    Filed: June 1, 1993
    Date of Patent: March 29, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Richard M. Lange, Carmen V. Luciani