Abstract: A polymer formed by controlled radical polymerization includes groups that can be modified after controlled radical polymerization to form a radical. The polymer can be the reaction product of a controlled radical polymerization of radically polymerizable monomers, wherein at least one of the radically polymerizable monomers includes at least one group that can be modified after the controlled radical polymerization to form a radical.

Abstract: Disclosed is a curable resin composition comprising a polymer (A) that has a main chain comprising carbon atoms and a side chain having a polymerizing unsaturated linking group and has a cyclic structure in the main chain and/or the side chain, and a compound having a polymerizing unsaturated group. The curable resin composition has good optical characteristics, good heat resistance and good moldability.

Abstract: The invention provides a rubber composition for golf balls which includes (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %, (B) an unsaturated carboxylic acid and/or a metal salt thereof, and (C) a diphenylamine of the general formula wherein R1 and R2 are each independently a hydrogen atom or a hydrocarbon group of 1 to 20 carbons, m is an integer from 1 to 5, and n is an integer from 1 to 4, with the proviso that if m and/or n is 2 or more, each occurrence of R1 and R2 may be the same or different. The golf ball rubber composition of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

Abstract: A conjugated diene polymer is provided that comprises a conjugated diene-based constituent unit and a constituent unit of formula (I) below, at least one terminus of the polymer being modified by a compound having a linkage of formula (II) below. wherein X1, X2, and X3 independently denote a group as defined in the specification.

Abstract: A process for producing a modified polymer rubber comprising the steps of: (1) polymerizing a conjugated diene monomer or a combination thereof with an aromatic vinyl monomer in a hydrocarbon solvent, in the presence of an alkali metal catalyst or a specified alkali metal compound, to form an alkali metal end-carrying active polymer, and (2) reacting the alkali metal end-carrying active polymer with a specified isocyanurate compound or a combination thereof with a specified coupling agent in a hydrocarbon solvent.

Abstract: The invention relates to a process for preparing (meth)acrylate-based ABA triblock copolymers with a silyl functionalization of the A blocks.

Abstract: A photosemiconductor protective material comprising a chain olefin-cyclic olefin copolymer elastomer composed of a chain olefin and a cyclic olefin as polymerizable components is prepared. The elastomer may comprise an ?-chain C2-4olefin and a polycyclic olefin as polymerizable components, and the molar ratio of the ?-chain C2-4olefin relative to the polycyclic olefin may be 80/20 to 99/1 in a ratio of the ?-chain C2-4olefin/the polycyclic olefin. The photosemiconductor protective material may further contain an organic silicon compound having a hydrolytically condensable group. The organic silicon compound may be a silane coupling agent having a (meth)acryloyl group. A photosemiconductor protective material 1 as the protective material is suitable as a solar cell encapsulant or filler 3 for encapsulating a solar cell 4. The photosemiconductor protective material has a high transparency and a high weather resistance and a proper elasticity and effectively protects a photosemiconductor.

Abstract: Brush copolymers containing (a) monomeric units derived from an ethylenically unsaturated-containing monomer containing one or more boronic acid moieties; and (b) monomeric units derived from an ethylenically unsaturated-containing macromonomer having hydrophilic units and boronic acid units are disclosed.

Abstract: An object of the present invention is to provide a conjugated diene-based polymer capable of providing a polymer composition which is excellent in a reduction in fuel consumption when silica is incorporated as a filler, a process for producing the conjugated diene-based polymer, and a polymer composition comprising said conjugated diene-based polymers and silica.

Abstract: The invention relates to novel crosslinkable copolymers which are obtainable by (a) copolymerizing at least two different hydrophilic monomers selected from the group consisting of N,N-dimethyl acrylamide (DMA), 2-hydroxyethyl acrylate (HEA), glycidyl methacrylate (GMA), N-vinylpyrrolidone (NVP), acrylic acid (AA) and a C1-C4-alkoxy polyethylene glycol (meth)acrylate having a weight average molecular weight of from 200 to 1500, and at least one crosslinker comprising two or more ethylenically unsaturated double bonds in the presence of a chain transfer agent having a functional group; and (b) reacting one or more functional groups of the resulting copolymer with an organic compound having an ethylenically unsaturated group.

Abstract: The present invention relates to modified polyolefins having a propylene content of at least 50 ma-% and a maximum of 75 ma-%, being determined by means of 13C-NMR spectroscopy, and having a poly(ethylene) triad content of a maximum of 2.5 ma-%, being determined by means of 13C-NMR spectroscopy, relative to the total detected ethylene content, a melting heat of at least 9 and a maximum of 20 J/g, determined by means of differential calorimetry, and a solubility in xylol at ambient temperature of at least 96 ma-%, and a solubility in THF at ambient temperature of at least 67 ma-%, wherein one or multiple silanes are grafted onto the polymer. The invention further relates to a method for the production of the polyolefins, and to the use thereof, particularly in or as an adhesive.

Abstract: The present invention relates to a composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups (A), (ii) a silanol condensation catalyst (B), and (iii) a silicon containing compound (C) according to the formula (R1)x[Si(R2)yR3)z]m (I) wherein R1, which may be the same or different if more than one such group is present, is a monofunctional, or, if m=2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms and at least one heteroatom; R2, which may be the same or different if more than one such group is present, is a hydrocarbyloxy residue comprising from 1 to 100 carbon atoms; R3, is —R4SiR1pR2q, wherein p is 0 to 3, q is 0 to 3, with the proviso that p+q is 3, and R4 is —(CH2)rYs(CH2)t— where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from —O—, —O—(CO)—, —NH—, —NH2, —NH—(CO)—NH2, —NH—(CO)—OCH3, an epoxy group, a carbamate group, —S—, —SO—, —SO2—, —NR—, —PR—, where R is a hydrocarbon or a hydrogen and where

Abstract: A conjugated diene polymer is provided that comprises a conjugated diene-based constituent unit and a constituent unit of formula (I) below, at least one terminus of the polymer being modified by a compound having a linkage of formula (II) below. wherein X1, X2, and X3 independently denote a group as defined in the specification.

Abstract: A high refractive index composition comprising a reaction product of one or more first organic compounds capable of undergoing polymerization and one or more second compounds with high refractive index, and the method of making and using the composition. A composition comprising an organic compound obtained by coupling two reactive groups (a) and (b), wherein a. the reactive group (a) is Y—(CH2)n-M(O—R)3, wherein R is CH3, C2H5, C3H8, C4H10; and Y is —NH2, —COOH, —NCO, or epoxy; and wherein M is selected from the group consisting of Ti, Zr, V, Mg, Al, Mn, Sb, Ba, Ca, Ce, Si, and Sn; and b. the reactive group (b) is selected from the group consisting of carbazole, fluorene, imidazole with one or more functional groups selected from —OH, —NH2, —COOH, —NCO, -epoxy, -vinyl, -acrylic, -acyl, -alkyl, -halide, -amino, -ketone, -allyl, -allylic, -thiol, -isocyanate, and a mixture thereof; and the method of making and using the composition.

Abstract: Polyethylene homo or copolymers which further contain grafted or copolymerized vinyldiacyloxysilanes are easily processable without premature crosslinking, are easily formed into shaped articles by conventional processing methods, and yet rapidly crosslink to form crosslinked polymers.

Abstract: A treatment method for treating an elastomer surface of a fluid dispenser device, the method including the step of using chemical grafting to form a thin film on at least one support surface of at least one elastomer surface of the dispenser device, the thin film avoiding the elastomer surfaces sticking during the manufacturing and assembly stages.

Abstract: Disclosed are an alkoxysilyl-containing A-B block copolymer formed from (meth)acrylate monomers as constituent monomers, characterized in that a polymer block of A chain has a number average molecular weight (Mn) of from 1,000 to 50,000 and a molecular weight distribution (Mw/Mn) of not greater than 1.6, a polymer block of B chain comprises alkoxysilyl-containing (meth)acrylate units as constituent monomer units, and the A-B block copolymer as a whole has a molecular weight distribution of not greater than 1.6, a process for the production of the block copolymer, a resin-treated pigment, and a pigment dispersion.

Abstract: The present invention is concerned with curable adhesive compositions for anchoring elements in a structural body that exhibit low temperature versus standard temperature degree of cures that are at least 50% or higher. The compositions include, in a first component, a reactive resin, an acetoacetoxy functional monomer and a silane monomer. By using phthalate-free constituents in the formulation, a further 10% increase in strength and durability of the resins at standard temperatures may be realized after curing at low temperatures.

Abstract: The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.

Abstract: There is provided a ring-opening polymer of cyclopentene wherein a cis ratio of cyclopentene-derived structural units is 30% or more, the weight average molecular weight (Mw) is 100,000 to 1,000,000, and an oxysilyl group is included at an end of the polymer chain. For example, the ring-opening polymer of cyclopentene can be obtained by ring opening polymerization of cyclopentene in the presence of a compound of a transition metal belonging to Group 6 in the Periodic Table, an organoaluminum compound represented by the following general formula (1), and an olefinically unsaturated hydrocarbon containing an oxysilyl group. (R1)3-xAl(OR2)x??(1) (in the general formula (1), R1 and R2 represent a hydrocarbon group having 1 to 20 carbon atoms and x satisfies the requirement 0<x<3.

Abstract: A process for crosslinking polymers employs a silane crosslinker which, upon hydrolysis, produces a reduced quantity of volatile organic compound.

Abstract: Two-component or multi-component fixing mortar, based on a free-radical-hardening unsaturated reactive resin, for embedding anchoring means in mortar in holes or crevices, which fixing mortar includes silanes which may or may not have reactive groups capable of participating in the polymerisation with a synthetic resin based on free-radical-hardening unsaturated reactive resins but do in any case have Si-bonded hydrolysable groups, and, physically separate therefrom, a hardener.

Abstract: The use of a functionalized organosilicon compound as a coupling agent between an inorganic filler and an elastomer in an elastomer composition including an isoprene elastomer and a reinforcing inorganic filler is disclosed. The compound is selected among functionalized organosilicon compounds including at least one double bond C?C or C?N, and not including any C?C—C?O bonds or N?N bonds, and reacting with the isoprene units according to an electrocyclic reaction, in particular according to a standard cycloaddition reaction [2+1], [2+2], [3+2] or a Diels-Alder reaction [4+2] or an ene-synthesis reaction other than an ene-synthesis reaction between an isoprene unit and a C?C—C?O or N?N function. Also described, are elastomer composition(s) obtained and items manufactured using such compositions.

Abstract: Disclosed are copolymers which comprise: a) an isobutylene copolymer having grafted polymer groups, b) optionally a tackifier, and c) optionally a non-functionalized poly(isobutylene) polymer. The compositions are useful in adhesives and coatings.

Abstract: To provide a resist polymer comprising, as a structural unit, an acid-decomposable unit having a structure represented by formula (1) or (2) which exhibits a small line edge roughness and produces little defects in DUV excimer laser lithography or the like.

Abstract: A conjugated diene polymer is provided that comprises a conjugated diene-based constituent unit and a constituent unit of formula (I) below, at least one terminus of the polymer being modified by a compound having a linkage of formula (II) below. wherein X1, X2, and X3 independently denote a group as defined in the specification.

Abstract: The present invention is concerned with curable adhesive compositions for anchoring elements in a structural body that exhibit low temperature versus standard temperature degree of cures that are at least 50% or higher. The compositions include, in a first component, a reactive resin, an acetoacetoxy functional monomer and a silane monomer. By using phthalate-free constituents in the formulation, a further 10% increase in strength and durability of the resins at standard temperatures may be realized after curing at low temperatures.

Abstract: The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.

Abstract: The present invention relates to polymer blends comprising: (a) from 5 wt % to 95 wt % of a HDPE having a density from 0.941 g/cm3 to 0.980 g/cm3 and an I22 of 10 dg/min or more; and (b) from 95 wt % to 5 wt % of a grafted mPE, which is a reaction product of (i) a mPE having a density from 0.860 g/cm3 to 0.935 g/cm3 and an I2 from 0.7 dg/min to 5.0 dg/min, and (ii) a silicon-containing grafting component, wherein the blend exhibits a high-temperature creep after extrusion that is at least 20% lower than a blend of the HDPE and the mPE that has not been grafted with a silicon-containing grafting component. These blends can advantageously comprise at least one layer of a film, e.g., made via extrusion.

Abstract: Provided are an olefin composition, filler and an optoelectronic device. One illustrative olefin composition may be effectively used as a filling material for various optoelectronic devices.

Abstract: The invention relates to highly branched polymers (P) comprising at least one silane group, wherein at least one silicon atom carries a hydrolysable group of the general formula (I): RA[(CH2)(CHRa)]p?h[(CH2)k(CRcRd)]m?gRuqRot[(CH2)l(CR?fRsi)]g+hRB, where RA, RB, Ra, Rc, Rd, Ru, Ro, Rf, Rsi, g, h, k, l, m, p, q, t have the meanings indicated in claim 1, the relationship m?g=r×(ra+p+q+t) applies, and r has a value greater than or equal to 0.

Abstract: The present invention relates to polymer compositions comprising a grafted and at least partially crosslinked mLLDPE that is the reaction product of: (i) a mLLDPE having a density from 0.910 g/cm3 to less than 0.940 g/cm3 and an I2 from 0.7 dg/min to 5.0 dg/min; (ii) a silicon-containing grafting component; and (iii) a crosslinking agent, wherein the composition exhibits a die shrinkage upon extrusion that is at least 10% lower than the composition, prior to grafting and crosslinking of the mLLDPE. These compositions can optionally be blended with HDPE. The compositions can also comprise at least one layer of a film, e.g., made via extrusion.

Abstract: A combination of vinyl trimethoxysilane and vinyl triethoxysilane can be grafted onto polyethylene to produce a polyethylene graft terpolymer that can be crosslinked without a significant reduction in crosslinking rates relative to vinyl triemethoxysilane grafted polyethylene. The combination of vinyl trimethoxysilane and vinyl triethoxysilane apparently act synergistically. While byproduct methanol from crosslinking with trimethoxysilane is very undesirable in some products, byproduct ethanol from crosslinking is less hazardous, especially at ppm levels.

Abstract: According to an aspect of the present invention, implantable or insertable medical devices are provided, which contain one or more polymeric regions. These polymeric regions, in turn, contain one or more polymers, at least one of which is a copolymer that includes the following: (a) one or more unsaturated hydrocarbon monomer species and (b) one or more heteroatom-containing monomer species.

Abstract: The purpose of the present invention is to provide an ethylene resin composition which has excellent properties including adhesion properties, electrically insulating properties, transparency, moldability and process stability and can be produced without requiring any cross-linking procedure if necessary to improve productivity; and others. The ethylene resin composition contains a modified product produced by modifying an ethylene polymer (A) that meets all of the requirements a) to e) mentioned below with an ethylenically unsaturated silane compound (B). a) The density is 900 to 940 kg/m3. b) The melting peak temperature is 90 to 125 DEG C as determined by DSC. c) The melt flow rate (MFR2) is 0.1 to 100 g/10 minutes as measured at 190° C. and a load of 2.16 kg in accordance with JIS K-6721. d) The Mw/Mn ratio is 1.2 to 3.5. e) The content of metal residues is 0.1 to 50 ppm.

Abstract: The present invention relates to an electronic device comprising at least one dielectric layer, said dielectric layer comprising a crosslinked organic compound based on at least one compound which is radically crosslinkable and a method of making the electronic device.

Abstract: This invention relates to the modification of elastomers by reaction with unsaturated silanes, to the modified elastomers produced and to articles produced by shaping and curing modified elastomer compositions. It also relates to the use of unsaturated silanes as coupling agents in filled elastomer compositions. In a process according to the present invention, the silane has the formula: R?—CH?CH—C(O)X—Y—SiRaR?(3-a) (I) or R?—C?C—C(O)X—Y—SiRaR?(3-a) (II) in which R represents a hydrolysable group; R? represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; Y represents a divalent organic spacer linkage comprising at least one carbon atom separating the linkage —C(O)X— from the Si atom, X is selected from S or O; and R? represents hydrogen or a group having an electron withdrawing effect with respect to the —CH?CH— or —C?C— bond. This provides silanes able to react efficiently with a diene elastomer in the presence of a free radical initiator.

Abstract: This invention relates to the modification of elastomers by reaction with unsaturated silanes, to the modified elastomers produced and to articles produced by shaping and curing modified elastomer compositions. In a process according to the present, the silane has the formula: R?—CH?CH—C(O)X—Y—SiRaR?(3-a) (I) or R?—C?C—C(O)X—Y—SiRaR?(3-a) (II) in which R represents a hydrolysable group; R? represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; Y represents a divalent organic spacer linkage comprising at least one carbon atom separating the linkage —C(O)X— from the Si atom, X is S or O; and R? represents hydrogen or a group having an electron withdrawing effect with respect to the —CH?CH— or —C?C— bond; and the silane is reacted with the diene elastomer in the absence of any free radical initiator. This is advantageous because free radical initiators such as peroxides tend to degrade diene elastomers.

Abstract: The present invention achieves increased filler interaction by incorporating a small amount (a few units per chain of rubbery polymer) of a conjugated triene monomer, such as alloocimene, randomly throughout the polymer chain of a rubbery polymer or at the chain ends of the rubbery polymer. The incorporation of the conjugated triene monomer leads to the formation of a polymer containing highly reactive conjugated diene units. These conjugated diene units can chemically react with carbon black leading to superior reinforcement. Alternatively, these conjugated diene units can be used for functionalization of the polymer with silica interactive/reactive groups using Diels Alder reactions. This functionalization of the rubbery polymer can conveniently be conducted in a mixer, such as a Banbury mixer, a mill mixer, or the like.

Abstract: Presently described are dental adhesive compositions and methods of use. The dental adhesive compositions described herein comprises a major amount of a hardenable component comprising a polymerizable organic component (i.e. having ethylenically unsaturated moieties) and a minor amount of a (e.g. water dispersible) polymer that comprises repeating units comprising polar or polarizable groups and repeating units comprising hydrophobic hydrocarbon groups.

Abstract: The present invention relates to a composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups (A), (ii) a silanol condensation catalyst (B), and (iii) a silicon containing compound (C) according to the formula (R1)x[Si(R2)yR3)z]m (I) wherein R1, which may be the same or different if more than one such group is present, is a monofunctional, or, if m=2, is a bifunctional, hydrocarbyl residue comprising from 1 to 100 carbon atoms and at least one heteroatom; R2, which may be the same or different if more than one such group is present, is a hydrocarbyloxy residue comprising from 1 to 100 carbon atoms; R3, is —R4SiR1pR2q, wherein p is 0 to 3, q is 0 to 3, with the proviso that p+q is 3, and R4 is —(CH2)rYs(CH2)t— where r and t independently are 1 to 3, s is 0 or 1 and Y is a difunctional heteroatomic group selected from —O—, —O—(CO)—, —NH—, —NH2, —NH—(CO)—NH2, —NH—(CO)—OCH3, an epoxy group, a carbamate group, —S—, —SO—, —SO2—, —NR—, —PR—, where R is a hydrocarbon or a hydrogen and where

Abstract: High refractive index copolymers with reduced glistenings are disclosed. The copolymers, which are particularly suitable for use as ophthalmic device materials, comprise a high molecular weight, reactive, linear polyethylene glycol component.

Abstract: Disclosed is a moisture curable sealant composition that includes silane functional poly-?-olefin polymer, thermoplastic elastomer, and tackifying agent.

Abstract: Acid-labile poly(N-vinyl formamide) (“PNVF”) nanocapsules were synthesized by free radical polymerization of N-vinyl formamide with optional active ingredients on the surface of silica nanoparticles. Polymerization in the presence of a novel cross-linker that contains an acid-labile ketal facilitated stable etching of silica nanoparticle templates using sodium hydroxide and recovery of PNVF nanocapsules. The formamido side group of PNVF was then hydrolyzed by extended exposure to sodium hydroxide to produce polyvinylamine (“PVAm”) nanocapsules. PNVF and PVAm nanoparticles are also synthesized that form nanogels with optional active ingredients.

Abstract: The invention relates to a controlled polymerization process for preparing (meth)acrylate-based AB diblock copolymers with a B block which has a narrow monomodal molecular weight distribution, and an A block which has a broad monomodal molecular weight distribution, and to the use thereof, for example, as a binder in adhesives or sealants.

Abstract: The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks having a narrow, monomodal molecular weight distribution, and a B-block having a wide, monomodal molecular weight distribution. The invention further relates to the use thereof as binders in glues or sealing compounds.

Abstract: A proton conductive membrane displays sufficient proton conductivity even at low humidities and low temperatures. The proton conductive membrane includes: a block copolymer including an ion conductive polymer segment (A) and an ion nonconductive polymer segment (B), the segment (A) and the segment (B) being covalently bound in a manner such that main chain skeletons of the segments are covalently bound at aromatic rings thereof through binding groups, (i) the membrane having a morphology including a microphase separated structure, (ii) the ion conductive polymer segment (A) forming a continuous phase.

Abstract: A process for producing low molecular weight polymers, the process comprising partially hydrogenating an unsaturated polymer to form a partially hydrogenated polymer, and reacting the partially hydrogenated polymer with an acyclic alkene in the presence of a metathesis catalyst.

Abstract: Terminally functionalized polymers that are living or pseudo-living polymers reacted with certain allyl glycidyl ethers, or certain allylhalosilanes or combinations thereof, and a process for preparing the terminally functionalized polymers. Rubber-modified polymeric compositions comprising the terminally functionalized polymers.

Abstract: The present invention provides marble chips produced by hardening or molding a resin composition including a binder and a reactive monomer, wherein the binder comprises a halogenated alkoxylated diacrylate oligomer. The marble chips of the present invention can be formed into a uniform pattern, so that an artificial marble made using the marble chips of the present invention may have an outer appearance and texture similar to that of engineered stone.