Mixed With Silicon-containing Reactant Or Polymer Derived Therefrom Patents (Class 525/29)
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Patent number: 12258484Abstract: The present disclosure provides a process. In an embodiment, the process includes forming an aqueous matte coating composition including A1) beads of a first acrylic polymer having an average particle diameter from 0.1 ?m to 2 ?m; A2) beads of a second acrylic polymer having an average particle diameter from 0.5 ?m to 30 ?m; B) an acrylic polymer binder; C) from 0.15 wt % to 2.5 wt % of a slip additive; D) from 0.10 wt % to 0.30 wt % of a defoaming agent; E) from 0.8 wt % to 1.5 wt % of a rheology modifier; and F) from 0.01 wt % to 0.1 wt % of at least one wetting agent. The aqueous matte coating composition is applied to a substrate and then dried to form a coating on the substrate.Type: GrantFiled: October 2, 2019Date of Patent: March 25, 2025Assignee: Dow Global Technologies LLCInventors: Yinzhong Guo, Manesh Nadupparambil Sekharan, Yuming Lai
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Patent number: 11773013Abstract: A coating material for the production of a UV-curing primer coating. The coating material includes at least 60 to 90 wt.-% of at least one monofunctional cycloaliphatic acrylate monomer or at least one monofunctional aryloxy alkyl acrylate monomer, 1 to 10 wt.-% of at least one amino-functional silane, 1 to 10 wt.-% of at least one photoinitiator, and up to 10 wt.-% of at least one of at least one acrylate oligomer and at least one methacrylate oligomer, each based on a total weight of the coating material.Type: GrantFiled: August 14, 2018Date of Patent: October 3, 2023Assignee: MANKIEWICZ GEBR. & CO. (GMBH & Co. KG)Inventors: Umberto De Rossi, Oliver Bolender, Timo Steffen
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Patent number: 9893307Abstract: A composition for encapsulation of an organic light emitting diode comprising a photocurable monomer, a silicon-containing monomer, and an initiator, wherein the silicon-containing monomer is represented by Formula 1, and an organic light emitting diode display are disclosed.Type: GrantFiled: March 27, 2015Date of Patent: February 13, 2018Assignee: SAMSUNG SDI CO., LTD.Inventors: Seong Ryong Nam, Chang Soo Woo, Chang Min Lee, Sung Min Ko, Han Sung Yu, Ji Yeon Lee, Kyoung Jin Ha
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Patent number: 9017818Abstract: The present invention relates to coating compositions comprising (A) at least one hydroxyl-containing polyacrylate and/or at least one hydroxyl-containing polymethacrylate and (B) at least one compound containing isocyanate groups and having at least one structural unit (I) of the formula (I) —NR—(X—SiR?x(OR?)3-x)??(I), and having at least one structural unit (II) of the formula (II) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(II), where (i) (A) has a glass transition temperature of less than 10° C., (ii) (B) contains more than 10 to more than 90 mol %, of at least one structural unit of the formula (I) and 10 to less than 90 mol % of at least one structural (II), based on the entirety of the structural units (I) and (II), and (iii) 10 to 60 mol % of the isocyanate groups of the diisocyanate and/or polyisocyanate parent structure of (I) and (II). The invention provides multistage coating processes using these coating compositions.Type: GrantFiled: March 8, 2010Date of Patent: April 28, 2015Assignee: BASF Coatings GmbHInventor: Matthijs Groenewolt
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Publication number: 20130137801Abstract: A flame retardant polycarbonate resin composition that can have excellent scratch resistance and impact resistance includes: (A) about 10 to about 89 wt % of a polycarbonate resin; (B) about 10 to about 89 wt % of a polycarbonate-polysiloxane copolymer; (C) about 1 to about 70 wt % of a modified (meth)acrylic copolymer resin; and (D) about 1 to about 50 parts by weight of a phosphorus-based flame retardant, based on about 100 parts by weight of components (A)+(B)+(C).Type: ApplicationFiled: January 29, 2013Publication date: May 30, 2013Applicant: Cheil Industries Inc.Inventor: Cheil Industries Inc.
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Patent number: 8273801Abstract: The invention is a composition comprising: a) one or more film forming resins having at least one functional group capable of polymerization; b) one or more reactive diluents capable of reacting with the film forming resin; c) one or more silicon, titanium, zirconium, aluminum or metal containing compounds capable of promoting adhesion of the composition to glass; d) one or more fillers capable of imparting abrasion resistance to the composition when cured; and e) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety. The composition of the invention is useful as a frit on the window of a vehicle.Type: GrantFiled: November 2, 2011Date of Patent: September 25, 2012Assignee: Dow Global Technologies LLCInventors: Kiran Baikerikar, Syed Z. Mahdi
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Patent number: 8147974Abstract: A composition comprising: a)one or more film forming resins having at least one functional group capable of polymerization; b) one or more adhesion promoters comprising compounds containing one or more unsaturated groups capable of free radical polymerization and one or more trialkoxy silane groups; c) one or more fillers capable of imparting abrasion resistance to the composition; d) one or more compounds which is reactive with the film forming resin which also contains an acidic moiety; and e) one or more compounds comprising a siloxane backbone and one or more active hydrogen groups capable of reacting with the functional groups on a glass bonding adhesive: one or more second adhesion promoters comprising one or more silicon, titanium, zirconium, aluminum, or metal containing compounds; organic materials having reactive groups reactive with reactive groups on the surface of substrates or adhesives; or mixtures thereof.Type: GrantFiled: December 18, 2008Date of Patent: April 3, 2012Assignee: Dow Global Technologies LLCInventors: Kiran Baikerikar, Syed Z. Mahdi, Ben W. Schaefer
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Patent number: 8093588Abstract: Dielectric compositions comprising siloxane and polymeric components, as can be used in a range of transistor and related device configurations.Type: GrantFiled: September 18, 2009Date of Patent: January 10, 2012Assignee: Northwestern UniversityInventors: Tobin J. Marks, Antonio Facchetti, Myung-Han Yoon, He Yan
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Silane-based gradient-initiating solution for thermoplastic core having a positive hardness gradient
Patent number: 7927526Abstract: A golf ball comprising a thermoplastic core having an outer diameter of 1.51 inches to 1.59 inches and having an outer surface and a geometric center, each having a hardness; an outer cover layer; and an inner cover layer disposed between the core and the outer cover layer; wherein the thermoplastic core has been exposed to a gradient-initiating solution comprising a silane having the formula: wherein R? is a non-hydrolysable organofunctional group, X is a hydrolysable group, and n is 0-24, such that the hardness of the outer surface is greater than the hardness of the geometric center to define a positive hardness gradient of 5 Shore C or greater.Type: GrantFiled: November 14, 2007Date of Patent: April 19, 2011Assignee: Acushnet CompanyInventors: Michael J. Sullivan, David A. Bulpett, Brian Comeau -
Patent number: 7838603Abstract: The invention describes novel silicone-containing graft copolymers and processes for their preparation. In particular, it relates to silicone-containing graft copolymers P, which are obtained by grafting olefinic monomers M onto polyether-containing radicals of polyoxyalkylene-polysiloxane block copolymers S with (AB)n structure.Type: GrantFiled: August 31, 2007Date of Patent: November 23, 2010Assignee: Evonik Goldschmidt GmbHInventors: Peter Schwab, Philippe Favresse, Tobias Maurer, Matthias Pascaly
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Patent number: 7786183Abstract: The invention is a composition comprising: a) one or more film forming resins having at least one functional group capable of polymerization; b) one or more reactive diluents capable of reacting with the film forming resin; c) one or more silicon, titanium, zirconium, aluminum or metal containing compounds capable of promoting adhesion of the composition to glass; d) one or more fillers capable of imparting abrasion resistance to the composition when cured; and e) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety. The composition of the invention is useful as a frit on the window of a vehicle. Furthermore, the invention relates to a method for applying the coatings to glass and a method for bonding the coated glass to a structure or substrate, for instance, a building.Type: GrantFiled: December 20, 2006Date of Patent: August 31, 2010Assignee: Dow Global Technologies Inc.Inventors: Kiran K. Baikerikar, Syed Z. Mahdi, Dominic J. Allam, Marcy N. Burris, Andrew R. Kneisel
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Patent number: 7781493Abstract: The invention is a composition comprising: a) one or more film forming resins having at least one functional group capable of polymerization; b) one or more reactive diluents capable of reacting with the film forming resin; c) one or more silicon, titanium, zirconium, aluminum or metal containing compounds capable of promoting adhesion of the composition to glass; d) one or more fillers capable of imparting abrasion resistance to the composition when cured; and e) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety. The composition of the invention is useful as a frit on the window of a vehicle.Type: GrantFiled: June 20, 2006Date of Patent: August 24, 2010Assignee: Dow Global Technologies Inc.Inventors: Kiran Baikerikar, Syed Z. Mahdi
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Patent number: 7129023Abstract: Photoresist polymers and photoresist compositions are disclosed. A photoresist polymer comprising a polymerization repeating unit represented by Formula 1 is less sensitive to change in the amount of energy due to its higher active energy than that of a conventional photoresist polymer. As a result, a phenomenon that a pattern of an outer field region that receives a relatively large amount of light becomes too thin is alleviated without additional dummy patterns when pattern is formed, and pattern collapse caused by a high aspect ratio due to high etching resistance is prevented. Formula 1 wherein R1–R12, a, b, c and d are as defined in the description.Type: GrantFiled: May 9, 2005Date of Patent: October 31, 2006Assignee: Hynix Semiconductor Inc.Inventor: Min Seok Son
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Patent number: 6433041Abstract: An efficient method is provided for producing water based coating compositions that are capable of forming highly scratch and abrasion resistant matte coatings in which crosslinked silicone particles are well dispersed. The method involves addition to a water based coating composition of a waterborne suspension of crosslinked silicone particles having an average diameter of 0.1-200 &mgr;m. The method is characterized in that the suspension is a waterborne crosslinked silicone particle suspension provided by effecting crosslinking of a condensation reaction crosslinkable silicone composition comprising (A) an organopolysiloxane containing at least two silanol groups in each molecule, (B) a crosslinker, and (C) a condensation reaction catalyst. The crosslinking is effected in the emulsified composition in an aqueous solution of an anionic surfactant.Type: GrantFiled: January 3, 2001Date of Patent: August 13, 2002Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Kazuo Kobayashi, Yoshitsugu Morita, Ken Tanaka
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Publication number: 20020082344Abstract: It is an object of the invention to provide a clear coating composition, which can give coating films showing good water repellency, in other words a factor giving a care-free and deluxe feeling to car owners, and which are excellent in non-sanding recoatability in recoating dirtied coatings after due repair, as well as a method of forming a coating film and a multilayerd coating film.Type: ApplicationFiled: July 31, 2001Publication date: June 27, 2002Inventors: Tatsuya Ishihara, Masahiko Yamanaka, Tetsuji Mizuno, Takashi Moriwake, Hisaki Tanabe, Goro Nagao
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Patent number: 6407158Abstract: The present invention relates to a water-soluble or water-dispersible polymeric salt, to a cosmetic or pharmacuetical composition which comprises at least one such polymeric salt, and to the use of the polymeric salts.Type: GrantFiled: March 20, 2000Date of Patent: June 18, 2002Assignee: BASF AktiengesellschaftInventors: Son Nguyen Kim, Axel Sanner, Peter Hössel
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Publication number: 20020055557Abstract: Water base coating material compositions form coating films of superior flat finish properties. They contain silicone particles with at least two kinds of different average particle size. According to the method of making the composition, a water base coating material composition can be formed by adding an aqueous suspension of silicone particles to a water base coating material composition where the aqueous suspension contains at least two kinds of silicone particles with different average particle size.Type: ApplicationFiled: August 27, 2001Publication date: May 9, 2002Inventors: Yoshitsugu Morita, Kazuo Kobayashi, Ken Tanaka
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Patent number: 6359081Abstract: A functional block copolymer useful as a compatibilizing agent for a blend of a condensation polymer and vinyl polymer comprises segments of a condensation polymer and a vinyl polymer derived from a reactive functional group-containing monomer or a functions-imparting monomer such as ultraviolet absorption or flame retardant functions. The block copolymer can further include a segment of a lower cohesive energy polymer. The condensation or vinyl polymer segment, or the lower cohesive energy polymer segment contains azo or peroxide groups which act as a polymerization initiator for the copolymerization of the vinyl monomer forming the vinyl polymer segment.Type: GrantFiled: April 19, 2000Date of Patent: March 19, 2002Assignees: Takiron Co., Ltd., Osaka Municipal GovernmentInventors: Masayuki Shimada, Yasuyuki Agari, Yoichiro Makimura
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Patent number: 6228281Abstract: A sizing composition for coating glass and carbon fibers. The composition comprises low concentrations of a cationic and nonionic lubricant, a film-forming polymer, and preferably a coupling agent and a hydrolyzing agent. Use of the sizing composition reduces fuzz development, increases wettability, and improves roving package stability.Type: GrantFiled: October 30, 1998Date of Patent: May 8, 2001Assignee: Owens Corning Fiberglas TechnologyInventor: Donald B. Sage
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Patent number: 5719230Abstract: The present invention provides a powder coating having an excellent curability which can be baked without evaporation of a blocking agent as compared with the conventional powder coating to provide a coat having an excellent yellowing resistance an improved smoothness and weather resistance. A novel powder coating containing, as a main component, a polyester resin composition is provided, comprising (A) an alkenyl group-containing polyester resin with a number-average molecular weight of from 500 to 100,000 having at least 1.2 alkenyl groups on the average per molecule, (B) a Si--H group-containing curing agent having at least two Si--H groups per molecule, and (C) a catalyst active in hydrosilylation.Type: GrantFiled: October 25, 1995Date of Patent: February 17, 1998Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Hiroshi Ando, Toshinobu Nakata, Masato Kusakabe, Shigeki Hamaguchi
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Patent number: 5708057Abstract: A silicone-modified water-based coating composition is disclosed wherein a suspension of silicone rubber particles in water is added to a water-based coating composition such that the resulting system is storage-stable and forms a mat film when dried or cured, which film is soft to the touch.Type: GrantFiled: June 18, 1992Date of Patent: January 13, 1998Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Yoshitsugu Morita, Atsushi Sakuma, Noriyasu Yokoyama, Keiji Yoshida
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Patent number: 5648169Abstract: Aqueous peroxide-free size compositions for application to glass fibers contain, as essential components, a reaction product of a polymeric amine and an amine-reactable organosilane, a film-forming polymer and an emulsified polyolefin. The reaction product can be preformed or made in situ, and is preferably the product of a polyalkylene polyamine and an epoxy-functional alkoxysilane. An optional added component is a water-soluble, non-volatile carboxylic acid. Glass fibers treated with the size composition can be made into mats, especially continuous strand, needled mats, useful for reinforcing thermoplastic polymers such as polypropylene in laminates which then can be used in molding processes to make articles of good physical properties.Type: GrantFiled: May 3, 1995Date of Patent: July 15, 1997Assignee: PPG Industries, Inc.Inventors: Thomas V. Thimons, Robert G. Swisher, Yongsheng Hou
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Patent number: 5605757Abstract: An aqueous glass fiber sizing composition is provided which provides high strength and wet-out to composites prepared using glass fibers having the sizing composition of the present invention applied thereto. When used to reinforce a thermosetting polymeric material, the glass fibers sized with this composition provide a composite useful in making pultrusion profiles having high compressive, shear and flexural strengths. The aqueous composition includes a non-ionic thermosetting urethane-modified epoxy polymer; a water soluble, dispersible or emulsifiable epoxy film-forming polymer different from the urethane-modified epoxy polymer; an emulsifying agent; an organo functional silane coupling agent; and a fiber lubricant.Type: GrantFiled: December 20, 1994Date of Patent: February 25, 1997Assignee: PPG Industries, Inc.Inventor: Michael W. Klett
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Patent number: 5587405Abstract: A radiation-curable ink composition contains a vehicle mixture comprising: (A) at least one linear polyester oligomer and/or polymer substantially free of an acid group and free of a polymerizable double bond in a molecule, wherein 1 to 10 double bonds are pendent from the linear polyester chain, and/or mixture thereof, (B) at least one single double bond-containing carboxylic acid wherein the acid has at least one acid group, and/or carboxylic ester of the said acid, and/or carboxylic amide of the said acid, and/or mixture thereof, (C) a double bond-containing polycarboxylic ester, wherein 2 to 10 acid groups are present and at least 2 double bonds are pendent from the ester having 2 to 10 acid groups, (D) at least one double bond-containing fluorinated carboxylic ester, and/or block copolymer comprising a fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and/or block copolymer comprising a siloxane group-containing polymer segment and a (meth)acrylic polymer segment, anType: GrantFiled: June 6, 1995Date of Patent: December 24, 1996Assignees: Yoshino Kogyosho Co., Ltd., Hayakawa Rubber Co., Ltd.Inventors: Ban Tanaka, Hiroki Nii, Kosaku Yamada, Hideo Kushida, Takashi Miya, Shuichi Koshio, Tadashi Hayakawa
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Patent number: 5552223Abstract: The present invention relates to a novel organopolysiloxane-modified polyester and a method for the preparation thereof. The organopolysiloxane-modified polyester polymer comprises a polyester segment having a number average molecular weight of 300 to 15,000, a silicon-bonded hydrolyzable group-free organopolysiloxane segment, and a silicon-bonded hydrolyzable group-containing silicone segment. The compositions of the present invention are characterized by their ability to cure at room temperature in the presence of a condensation reaction-accelerating catalyst.Type: GrantFiled: May 19, 1995Date of Patent: September 3, 1996Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Ryuzo Mikami, Isao Ona
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Patent number: 5549932Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: March 9, 1995Date of Patent: August 27, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5437928Abstract: Aqueous size compositions for application to glass fibers contain, as essential components, a reaction product of a polymeric amine and an amine-reactable organosilane, a film-forming polymer and an emulsified polyolefin. The reaction product can be preformed or made in situ, and is preferably the product of a polyalkylene polyamine and an epoxy-functional alkoxysilane. An optional added component is a water-soluble, non-volatile carboxylic acid. Glass fibers treated with the size composition can be made into mats, especially continuous strand, needled mats, useful for reinforcing thermoplastic polymers such as polypropylene in laminates which then can be used in molding processes to make articles of good physical properties.Type: GrantFiled: October 29, 1993Date of Patent: August 1, 1995Assignee: PPG Industries, Inc.Inventors: Thomas V. Thimons, Robert G. Swisher, Yongsheng Hou
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Patent number: 5416147Abstract: A blend of (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule, (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule, and (C) a hydrosilylaion catalyst is blended with (D) an organic iron or aluminum compound to form a hydrosilylative composition. Component (D) scavenges a catalyst poison, permitting components (A) and (B) to undergo hydrosilylation reaction with the aid of catalyst (C).Type: GrantFiled: December 14, 1993Date of Patent: May 16, 1995Assignees: Shin-Etsu Chemical Co., Ltd., Nippon Paint Co., Ltd.Inventors: Mitsuhiro Takarada, Yuji Yoshikawa, Hiroharu Ohsugi, Yoshio Eguchi
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Patent number: 5401580Abstract: By curing either one of an organic peroxide-curable silicone rubber composition and an organic peroxide-curable unsaturated polyester resin composition and then curing the other composition while placing it in close contact with the cured composition, there is obtained a composite material in which an organic peroxide-cured silicone rubber is closely and firmly joined with an organic peroxide-cured unsaturated polyester resin.Type: GrantFiled: September 16, 1993Date of Patent: March 28, 1995Assignee: Shin Etsu Chemical Co., Ltd.Inventors: Noriyuki Meguriya, Takeo Yoshida
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Patent number: 5254606Abstract: A graft type silicone-modified polyester forms a base for a surface-protective agent which has excellent water-repellency properties as well as retention of said properties after exposure to the environment.Type: GrantFiled: September 12, 1991Date of Patent: October 19, 1993Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Ryuzo Mikami, Tadashi Okawa
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Patent number: 5175206Abstract: A silyl group-containing, polyester-modified vinyl resin comprising(A) 3 to 45% by weight of units of a polyester resin including a polymerizable unsaturated group,(B) 5 to 30% by weight of units having a group of the formula (I): ##STR1## wherein R.sup.1 is hydrogen atom or a monovalent hydrolyzable group having 1 to 10 carbon atoms selected from the group consisting of an alkyl group, an aryl group and an aralkyl group, R.sup.2 is an organic residue having a polymerizable double bond, X is a hydrolyzable group and n is an integer of 1 to 3, and(C) 25 to 92% by weight of units of a copolymerizable vinyl monomer. The vinyl resin has excellent dispersibility, color match stability and storage stability.Type: GrantFiled: October 31, 1990Date of Patent: December 29, 1992Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Yasushi Kato, Hisao Furukawa, Shinji Kagitani, Shoichi Matsumura
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Patent number: 5153261Abstract: Polyester-polyurethane hybrid resin molding compositions having a first, soft polyurea phase within a second, more rigid polyester-polyurethane phase are disclosed. The compositions are formed by the reaction of an A side composition and a B side composition. The A side composition comprises a polyfunctional isocyanate compound and a free radical polymerization catalyst. The B side composition comprises a mixture of (i) an ethylenically unsaturated monomer solution having dissolved therein about 40-90 weight percent of a substantially water-free, unsaturated polyester polyol having at least one dicarboxylic alkene moiety and having an acid number less than five; and (ii) a polyfunctional nitrogen-containing compound having at least one active hydrogen atom on each of at least two nitrogen atoms in each molecule, which, when reacted with the A side composition, has a molecular weight sufficient to form the first, soft polyurea phase.Type: GrantFiled: August 30, 1990Date of Patent: October 6, 1992Assignee: Amoco CorporationInventor: Gary T. Brooks
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Patent number: 5070121Abstract: The invention concerns a solvent-free, polymerizing hotmelt substance free of, or low in monomers, for corrosion- and/or abrasion proofing and/or forming a protective film with barrier properties on a real substrates and molded bodies made of metal, plastic, cellulose materials and/or inorganic materials, in particular for wrapping purposes, and consisting of(a) one or more polymerizing polymers containing hydroxyls with an average molecular weight (M.sub.w) between 1,000 and 500,000 and with a glass transition temperature (T.sub.g).gtoreq.20.degree. C., and/or(b) one or more polymerizing, linear, unbranched and/or unbranched polyesters and/or their copolymers with an average molecular weight (M.sub.w) between 900 and 50,000 and with a glass transition temperature (T.sub.g).gtoreq.-50.degree. C.Type: GrantFiled: April 25, 1989Date of Patent: December 3, 1991Assignee: Schmalbach Lubeca AGInventors: Rudolf Hinterwaldner, Georg Bolte
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Patent number: 5004765Abstract: A molding additive composition comprising a mixture of low profile additive and a surfactant additive containing a silicon-oxyalkylene copolymer flow control agent and surface modifying agent; and a molding composition comprising a polyester molding resin, a low profile additive, a silicon-oxyalkylene copolymer flow control agent and surface modifying agent and a crosslinking monomer. In another embodiment, the invention embraces a molding composition comprising a polyester molding resin, a crosslinking monomer, a low profile additive, a reinforcing fiber, and a silicon-oxyalkylene copolymer flow control agent and surface modifying agent.Type: GrantFiled: November 6, 1989Date of Patent: April 2, 1991Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Kenneth E. Atkins, Robert R. Gentry, Raymond C. Gandy
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Patent number: 4968750Abstract: Block copolymers composed of recurrent structural units belonging to the series comprising polysiloxanes and recurring structural units belonging to the series comprising homopolymers, copolymers or terpolymers of vinyl-aromatic compounds and acrylic monomers of mixtures thereof.Type: GrantFiled: October 25, 1989Date of Patent: November 6, 1990Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Christian Lindner, Karl-Heinz Ott
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Patent number: 4929651Abstract: A process is provided for manufacturing ballistic resistant composites of an isophthalic thermoset polyester and woven roving made of magnesia aluminosilicate glass fibers. An impregnating solution is provided whereby pregregs can be conveniently formed and then vacuum bag molded. The ingredients in the impregnating solution are critically selected to provide prescribed viscosities after the elapse of certain periods of time and thereby allow the final articles to be formed in an economical and expedient manner.Type: GrantFiled: November 10, 1988Date of Patent: May 29, 1990Assignee: Owens-Corning Fiberglas CorporationInventors: James V. Gauchel, Edward L. Wilson, Edward J. Kerle
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Patent number: 4889768Abstract: A silicon-urethane (meth) acrylate which is a reaction product of an isocyanato-alkylsilane compound represented by the following general formula: ##STR1## wherein R.sub.1 represents an alkylene group having 2 to 5 carbon atoms, R.sub.2 represents an alkyl group having 1 to 5 carbon atoms or alkoxy group having 1 to 5 carbon atoms, and R.sub.3 and R.sub.4 each represents an alkyl group having 1 to 5 carbon atoms, and a hydroxyl group-containing ester of (meth) acrylic acid, a resin composition and a coating material for optical glass fiber comprising said silicon-urethane (meth) acrylate.Type: GrantFiled: April 14, 1987Date of Patent: December 26, 1989Assignee: Nippon Kayaku Kabushiki KaishaInventors: Minoru Yokoshima, Tetsuo Ohkubo
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Patent number: 4888399Abstract: Hydroxy functional polyester graft copolymers are provided. The copolymer is crosslinkable by hydroxy-reactive crosslinking agent and, in particular, is suitable for use in thermosetting coating compositions adapted to form a flexible cured coating over a variety of substrates, such as metal and plastic. The copolymer has a number average molecular weight between about 1300 and about 15,000, has a hydroxyl number between about 30 and about 300, and is the reaction product of carbon-carbon double bond-reactive monoethylenically unsaturated monomer with hydroxy functional carbon-carbon double bond-bearing branched polyester macromer. The macromer is the reaction product of (i) hydroxy functional polyester reactant containing 0-10 urethane linkages per molecule with (ii) silane compound having the general chemical formula: ##STR1## wherein X is an organic group of (--Si--O--).sub.Type: GrantFiled: October 3, 1988Date of Patent: December 19, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: Rose A. Ryntz
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Patent number: 4810759Abstract: Hydroxy functional polyester graft copolymers are provided. The copolymer is crosslinkable by hydroxy-reactive crosslinking agent and, in particular, is suitable for use in thermosetting coating compositions adapted to form a flexible cured coating over a variety of substrates, such as metal and plastic. The copolymer has a number average molecular weight between about 1300 and about 15,000, has a hydroxyl number between about 30 and about 300, and is the reaction product of carbon-carbon double bond-reactive monoethylenically unsaturated monomer with hydroxy functional carbon-carbon double bond-bearing branched polyester macromer. The macromer is the reaction product of (i) hydroxy functional polyester reactant containing 0-10 urethane linkages per molecule with (ii) silane compound having the general chemical formula: ##STR1## wherein X is an organic group or (--Si--O--).sub.Type: GrantFiled: December 16, 1986Date of Patent: March 7, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: Rose A. Ryntz
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Patent number: 4724248Abstract: Esters and urethanes of certain polydialkylsiloxanepolyoxyalkylene block and graft copolymers which impart high voltage stabilization to dielectric olefin polymers, the stabilized olefin polymer insulating materials resulting therefrom and electric wire or cable insulated therewith.Type: GrantFiled: July 2, 1986Date of Patent: February 9, 1988Assignee: Ciba-Geigy CorporationInventors: Martin Dexter, David H. Steinberg
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Patent number: 4561950Abstract: Radiation curable, post-formable liquid coating compositions which cure on radiation exposure to provide coatings which resist exterior exposure are disclosed. These comprise:(1) a silicone dicarbinol diurethane diacrylate or dimethacrylate in which the carbinol groups are carried by an ethoxylate constituting from 30% to 70% of the silicone dicarbinol;(2) a linear dihydroxy-functional C.sub.4 -C.sub.8 dicarboxylic acid-C.sub.2 -C.sub.4 diol polyester diurethane diacrylate or dimethacrylate based on a polyester having an average molecular weight in the range of 600 to 2000;(3) isobornyl acrylate or methacrylate; and(4) acrylic or methacrylic acid.Components 1 and 2 together provide from 30% to 50% of the composition, with component 2 being present in an amount of from 0% to 65% of the total of components 1 and 2, component 3 is present in an amount of at least 30% of the composition and provides coating viscosity, and component 4 is present in an amount of at least 3% of the composition.Type: GrantFiled: April 2, 1984Date of Patent: December 31, 1985Assignee: DeSoto, Inc.Inventor: A. Frank Leo
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Patent number: 4552910Abstract: An aqueous organosilicon composition is prepared by mixing water with an organopolysiloxane having at least one ##STR1## group and having aliphatic radicals which are bonded to silicon via oxygen, a polyvinyl alcohol and/or a water-soluble cellulose ether containing hydroxyl groups in the presence of sufficient acid to provide a composition having an acid pH. The resultant composition may be neutralized and used as additives in aqueous paint compositions.Type: GrantFiled: June 4, 1984Date of Patent: November 12, 1985Assignee: Wacker-Chemie GmbHInventors: Bernward Deubzer, Hermann Wilhelm
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Patent number: 4451638Abstract: Alkali metal polyester silicate resinous products are produced by mixing a polyhydroxy organic compound, an alkali metal silicate and a polycarboxylic acid, then heating the mixture to a temperature between the melting point of the polycarboxylic acid and the boiling temperature of the polyol while agitating until the reaction is complete.Type: GrantFiled: February 19, 1980Date of Patent: May 29, 1984Inventor: David H. Blount
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Patent number: 4444946Abstract: The invention relates to special stable dispersions which crosslink at room temperature upon exposure to moisture in the atmosphere. The dispersions comprise polysiloxanes, vinyl-grafted polysiloxanes and condensation products, e.g. by weight approximately comprisingI. 20-90% of at least one diorganopolysiloxane optionally terminated by OH,II. 5-85% of at least one aliphatic or mixed aliphatic/aromatic polycondensation product or polyaddition product, polyether, or vinyl polymer with a glass temperature T.sub.G of up to 40.degree. C. and/or a vinyl monomer-grafted derivative thereof, andIII. 5-85% of at least one organopolysiloxane modified by grafting with at least one vinyl monomer and comprising(A) 10-90% of a diorganopolysiloxane optionally terminated by OH,(B) 10-90% of polymerized units of at least one vinyl compound, and(C) 0-80% of at least one aliphatic or mixed aliphatic/aromatic polycondensation product or polyaddition product, polyether, or vinyl polymer with a glass temperature T.sub.Type: GrantFiled: January 29, 1982Date of Patent: April 24, 1984Assignee: Bayer AktiengesellschaftInventors: Heinrich Alberts, Hans Friemann, Hans-Heinrich Moretto, Hans Sattlegger
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Patent number: 4433070Abstract: Cultured onyx, cultured marble, and like mineral-appearing products are provided, as well as intermediates and components and methods therefor through the combination of a locally discontinuous phase comprising a synthetic organic resin portion hardened to a predetermined hardness and a visually distinguishable continuous phase comprising a synthetic organic resin portion separately hardened to the predetermined hardness with the discontinuous phase intimately distributed therein, to form shaped structures having surfaces simulative of onyx, marble, or like naturally occurring mineral in appearance, which surfaces are uniformly polishable in phase undifferentiated relation.Type: GrantFiled: May 5, 1980Date of Patent: February 21, 1984Inventors: Gilbert B. Ross, Theodore E. Stevens
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Patent number: 4376185Abstract: A co-grafted polymer comprising units of organopolysiloxanes with OH functional groups, polyesters and vinyl monomers, polymeric units of the vinyl monomers being linked to the organopolysiloxane and polyester units, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.Type: GrantFiled: November 14, 1980Date of Patent: March 8, 1983Assignee: Bayer AktiengesellschaftInventors: Heinrich Alberts, Hans Friemann, Hans-Heinrich Moretto, Hans Sattlegger
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Patent number: 4368290Abstract: A graft copolymer comprising (I) as a first polymeric moiety an organopolysiloxane with OH functional groups, (II) as a second polymeric moiety a polyether, and (III) units of vinyl monomer which have been polymerized in the presence of mixtures of the first and second polymeric moieties which moieties are linked via vinyl polymer bridges, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.Type: GrantFiled: November 14, 1980Date of Patent: January 11, 1983Assignee: Bayer AktiengesellschaftInventors: Heinrich Alberts, Hans Friemann, Hans-Heinrich Moretto, Hans Sattlegger
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Patent number: 4365047Abstract: A crystalline unsaturated polyester composition for binding foundry sand, said composition comprising:(A) 100 parts by weight of an unsaturated polyester resin which is a mixture of 100 parts by weight of a normally solid, substantially tack-free, crystalline unsaturated polyester and 0 to 50 parts by weight of an unsaturated prepolymer or monomer copolymerizable with said unsaturated polyester or both, and(B) 0.1 to 10 parts by weight of a mixture of at least two of (1) a radical polymerization catalyst which requires a temperature of at least 70.degree. C. but below 90.degree. C. to obtain a half-period value of 10 hours, (2) a radical polymerization catalyst which requires a temperature of at least 90.degree. C. but below 110.degree. C. to obtain a half-period value of 10 hours and (3) a radical polymerization catalyst which requires a temperature of at least 110.degree. C. but not exceeding 130.degree. C. to obtain a half-period value of 10 hours.Type: GrantFiled: May 30, 1980Date of Patent: December 21, 1982Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Koue Ohkawa, Shin Fujii, Takashi Seino
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Patent number: 4354019Abstract: An oxidated silicon compound will react with a substituted organic compound in the presence of an alkali compound to produce organic alkali metal silicate products which may be used as molding powders, as adhesives, as coating agents and be reacted with polyisocyanates to produce insulating foams.Type: GrantFiled: December 10, 1981Date of Patent: October 12, 1982Inventor: David H. Blount
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Patent number: 4338234Abstract: An aqueous sizing composition, glass fiber strands having the dried residue of the aqueous sizing composition and processes for producing these articles are provided that enable the production of glass fiber reinforced polymeric materials having improved properties. In addition, improvements are obtained in the processability of using glass fiber roving in the production of sheet molding compound, bulk molding compound and thick molding compound. The sizing composition, sized glass fiber strands, processes, reinforced polymeric materials and improvements of this invention emanate from the use of epoxidized polar thermoplastic copolymers in aqueous sizing compositions that are substantially insoluble in the matrix polymer. The aqueous sizing composition has one or more cross-linkable film formers, one or more organosilane coupling agents and about 3 to about 12 weight percent of the aqueous sizing composition of the epoxidized polar thermoplastic copolymer.Type: GrantFiled: June 4, 1980Date of Patent: July 6, 1982Assignee: PPG Industries, Inc.Inventors: L. Dow Moore, Balbhadra Das