Dicyclopentadiene-containing Group Patents (Class 525/290)
  • Patent number: 4362848
    Abstract: Cycloalphatic acrylate compositions and methods of making them are disclosed. The compositions are mixtures containing dicyclopentadiene (meth) acrylate and (meth) acrylates such as the mono and di (meth) acrylates of tri, and tetracyclopentadiene and a mixture of the copolymers of (meth) acrylic acid with adducts of cyclopentadiene with isoprene and/or piperylene and a mixture of poly (meth) acrylates having the repeating unit ##STR1## Where R.sup.1 is hydrogen or ##STR2## R.sup.2 is CH.sub.2 .dbd.CZ--C(O)--O-- Z is H, or methyln is 0, 1 or 2 andm is 0 or 1 and when m is 0 there isa double bond present.The compositions are useful to make cross-linkable blends with unsaturated resins or monomers and to make laminates.
    Type: Grant
    Filed: May 29, 1981
    Date of Patent: December 7, 1982
    Assignee: The Dow Chemical Co.
    Inventors: Hans R. Friedli, Donald L. Nelson, John L. Massingill, Jr.
  • Patent number: 4360638
    Abstract: This invention is directed to compositions useful as ionomeric hot melt pressure sensitive adhesive compositions. These compositions comprise a polymer containing carboxylic acid, a miscible metal salt, and an o-methoxy-substituted aryl acid. These compositions display low melt viscosity, simplifyingapplication, as well as improved adhesive properties, especially shear resistance.
    Type: Grant
    Filed: January 13, 1982
    Date of Patent: November 23, 1982
    Assignee: Rohm and Haas Company
    Inventor: Benjamin Bartman
  • Patent number: 4345048
    Abstract: Brominated cycloaliphatic (meth) acrylate compositions are prepared by the reaction of bromine at a temperature in the range from -30.degree. C. to 50.degree. C. with compositions made by reacting (meth) acrylic acid with dicyclopentadiene compositions in the presence of a Friedel-Crafts catalyst such as BF.sub.3.The brominated compositions are useful to make copolymers which find use as metal coatings, laminates, ultraviolet light curable coatings and the like.
    Type: Grant
    Filed: January 21, 1980
    Date of Patent: August 17, 1982
    Assignee: The Dow Chemical Company
    Inventors: Hans R. Friedli, Clinton J. Boriack
  • Patent number: 4340689
    Abstract: A process for grafting functional organic groups onto EPM and EPDM polymers wherein the grafting reaction is carried out in the cement in which the polymer is originally formed by solution polymerization.
    Type: Grant
    Filed: September 17, 1979
    Date of Patent: July 20, 1982
    Assignee: Copolymer Rubber & Chemical Corporation
    Inventor: Ralph K. Joffrion
  • Patent number: 4336349
    Abstract: Chlorinated cycloaliphatic (meth) acrylate compositions are prepared by the reaction of chlorine at a temperature in the range from -30.degree. C. to 50.degree. C. with compositions made by reacting (meth) acrylic acid with crude dicyclopentadiene in the presence of a Friedel-Crafts catalyst such as BF.sub.3. The chlorinated compositions have a pleasant fruity odor and are useful to make homopolymers or copolymers which find use as metal coatings, inks, ultraviolet light curable coatings and the like.
    Type: Grant
    Filed: December 22, 1980
    Date of Patent: June 22, 1982
    Assignee: The Dow Chemical Company
    Inventors: Hans R. Friedli, Clinton J. Boriack
  • Patent number: 4319009
    Abstract: Cycloalphatic acrylate compositions and methods of making them are disclosed. The compositions are mixtures containing dicyclopentadiene (meth) acrylate and (meth) acrylates such as the mono and di (meth) acrylates of tri, and tetracyclopentadiene and a mixture of the copolymers of (meth) acrylic acid with adducts of cyclopentadiene with isoprene and/or piperylene and a mixture of poly (meth) acrylates having the repeating unit ##STR1## where R.sup.1 is hydrogen or ##STR2## R.sup.2 is CH.sub.2 .dbd.CZ-C(O)--O-- Z is H, or methyln is 0, 1 or 2 andm is 0 or 1 and when m is 0 there isa double bond present.The compositions are useful to make crosslinkable blends with unsaturated resins or monomers and to make laminates.
    Type: Grant
    Filed: October 13, 1978
    Date of Patent: March 9, 1982
    Assignee: The Dow Chemical Company
    Inventors: Hans R. Friedli, Donald L. Nelson, John L. Massingill, Jr.
  • Patent number: 4287317
    Abstract: A continuous process for producing rubber-modified methyl methacrylate syrups which comprises continuously supplying a material liquor comprising 1 to 20 parts by weight of a rubbery polymer dissolved in 100 parts by weight of a monomer comprising 60 to 100% by weight of methyl methacrylate, and a radical-polymerization initiator to the first reaction zone, continuously polymerizing at such a stationary conversion that the rubber polymer is dispersed in the form of particles form while maintaining the temperature and residence time in the zone so that a steady state is achieved in the zone and the steady-state concentration of the initiator in the zone is 1/2 to 1/1,000 time as much as the concentration of initiator supplied, continuously taking out the resulting reaction mixture from the zone, and passing it through the second reaction zone having a volume of 0 to 5 times as much as that of the first reaction zone, to obtain a stable syrup comprising a disperse phase and a continuous phase, the former phase
    Type: Grant
    Filed: April 22, 1980
    Date of Patent: September 1, 1981
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshihiko Kitagawa, Yoshimi Hanamura, Masahiro Yuyama, Masahiko Moritani, Akira Sakuramoto, Mikio Suzuki
  • Patent number: 4261872
    Abstract: The invention is concerned with novel autoxidizable compositions comprising an unsaturated acid ester of a glycol monodicyclopentenyl ether, a condensation or vinyl addition polymer, a siccative and a volatile stabilizer, which compositions are uniquely adapted to be formulated with high solids and practical viscosity ranges for coating and/or impregnating purposes.
    Type: Grant
    Filed: May 22, 1978
    Date of Patent: April 14, 1981
    Assignee: Rohm and Haas Company
    Inventors: William D. Emmons, Kayson Nyi
  • Patent number: 4235981
    Abstract: Coating compositions which are free of volatile organic solvents and curable under the action of heat or radiation without undesirable evaporation of organic solvents, prepared by reacting a copolymer resin of a cyclopentadiene type compound such as dicyclopentadiene and maleic anhydride, with at least one compound represented by the formula ##STR1## or the like wherein X is H or --CH.sub.3 and R is --CH.sub.2 CH.sub.2 OH or the like to produce a resin which is then dissolved in a reactive solvent such as a (meth)acrylate type monomer or ammonia water; and a process for preparing the coating compositions.
    Type: Grant
    Filed: September 13, 1978
    Date of Patent: November 25, 1980
    Assignee: Nippon Oil Co., Ltd.
    Inventor: Shozo Tsuchiya
  • Patent number: 4205144
    Abstract: Graft copolymers comprising a crosslinked, saturated, elastomeric grafting base and a hard shell are prepared by incorporating thermolabile comonomers, as copolymerized units, into the grafting base during the preparation of the latter, in particular at a conversion of from 50 to 90%. During the subsequent grafting of the shell, the conditions used are such that the thermolabile comonomers incorporated as copolymerized units into the grafting base decompose into free radicals. This gives graft copolymers having improved mechanical properties, which copolymers also prove advantageous for the preparation of mixtures with other thermoplastics compatible with the graft copolymers.
    Type: Grant
    Filed: October 19, 1978
    Date of Patent: May 27, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Graham E. McKee, Burghard Schmitt
  • Patent number: 4163763
    Abstract: The present invention provides a method for producing curable resin which comprises reacting acrylic acid and/or methacrylic acid [which is hereinafter cited as (metha-) acrylic acid] with hydroxyl group-containing resin (I) obtained by reacting a five-member cyclic compound having an unsaturated conjugated double bond represented by the general formula (A) given below; ##STR1## (WHEREIN R is an organic residue having from 1 to 3 carbon atoms; m and n are integers and are in the relation of m+n=6) or the Diels-Alder addition product thereof (A) and a compound (B) having both reactive carbon-carbon double bond or bonds and towo or more hydroxyl groups within one and the same molecule thereof. In accordance with the present invention, curable coating composition comprising said curable resin can also be obtained. The resin of this invention can be very quickly cured by the exposure to heat or radiation.
    Type: Grant
    Filed: December 16, 1977
    Date of Patent: August 7, 1979
    Assignee: Nippon Oil Company, Limited
    Inventors: Shozo Tsuchiya, Hideo Hayashi, Makoto Sasaki, Kiyoshi Goto, Toru Matsubara