Mixed With A Solid Polymer Or Specified Intermediate Condensation Product Derived From At Least One Amine-, N-c(=x)- Or N-s-(=o)- Containing Reactant And At Least One Aldehyde Or Aldehyde-type Reactant (x Is Chalcogen) Patents (Class 525/30)
  • Patent number: 9833034
    Abstract: Electrically conductive vulcanized epoxidized natural rubber [ENR]-carbon black blends can be produced by using either internal mechanical mixing method or open milling method. These two methods are commercially friendly due to their practicability and high production rate. The addition of vulcanization system, either sulfur or peroxide type does not affect the electrical properties of the vulcanized blends. All vulcanized blends prepared in this innovation show useful electrical properties with electrical volume resistances as low as the order of 101 ohms. All these vulcanized blends also exhibit good mechanical properties with tensile strengths up to 26.0 MPa and Dunlop rebound resiliencies of 14.0% (i.e. high damping property). The black color level of all these vulcanized blends is adjustable. As a result of good electrical and mechanical properties (especially high damping property), they have good potential to be used for antistatic footwear manufacturing and application.
    Type: Grant
    Filed: March 7, 2012
    Date of Patent: December 5, 2017
    Assignee: Lembaga Getah Malaysia
    Inventors: Yong Kok Chong, Ahmad Mohamad Asri
  • Patent number: 9798184
    Abstract: A pressure-sensitive adhesive composition is provided. The pressure-sensitive adhesive composition shows stable antistatic performance, and in particular, stably maintains its antistatic performance even when the pressure-sensitive adhesive composition is kept for an extended time under extreme conditions or conditions in which environmental changes are severe, and also has excellent general physical properties such as pressure-sensitive adhesive properties, durability and workability.
    Type: Grant
    Filed: September 18, 2013
    Date of Patent: October 24, 2017
    Assignee: LG CHEM, LTD.
    Inventors: Sung Soo Yoon, No Ma Kim, Kee Young Kim, Min Ki Lee, Han Na Chi
  • Patent number: 9481155
    Abstract: A method for producing a laminate for configuring an image display device is provided, capable of realizing simultaneously unevenness followability and anti-bubble reliability. A method for producing a laminate for configuring an image display device is proposed, comprising the following steps (1) and (2): (1) The step of forming an adhesive composition into the form of a monolayer or a multilayer sheet, and by UV-crosslinking, primary-curing this thereby forming a pre-secondary curing transparent double-sided adhesive sheet. (2) The step of layering two image display device-constituting members via the pre-secondary curing transparent double-sided adhesive sheet and then irradiating ultraviolet light from at least a first image display device-constituting member side, UV-crosslinking through this member and secondary-curing the pre-secondary curing transparent double-sided adhesive sheet.
    Type: Grant
    Filed: February 12, 2014
    Date of Patent: November 1, 2016
    Assignee: MITSUBISHI PLASTICS, INC.
    Inventors: Kahoru Niimi, Makoto Inenaga, Takahisa Uchida
  • Patent number: 9429695
    Abstract: Provided is a polarizing plate with a pressure-sensitive adhesive layer which is excellent in reliability of optical properties and durability of pressure-sensitive adhesion. The polarizing plate with a pressure-sensitive adhesive layer comprises a polarizing film and a pressure-sensitive adhesive layer provided directly on at least one surface of the polarizing film. The pressure-sensitive adhesive layer comprises a pressure-sensitive adhesive composition containing a pressure-sensitive adhesive polymer, and an amount of an acid component in a total monomer component constituting the pressure-sensitive adhesive polymer is less than 8 wt %.
    Type: Grant
    Filed: May 24, 2012
    Date of Patent: August 30, 2016
    Assignee: NITTO DENKO CORPORATION
    Inventors: Yuusuke Toyama, Tomoyuki Kimura, Atsushi Yasui, Masayuki Satake, Shusaku Goto, Takeharu Kitagawa, Minoru Miyatake, Tomohiro Mori, Takashi Kamijo
  • Patent number: 9377570
    Abstract: A pressure-sensitive adhesive layer-attached polarizing film of the present invention includes a polarizing film and a pressure-sensitive adhesive layer provided on the polarizing film, wherein the polarizing film includes a polarizer with a thickness of 10 ?m or less and a transparent protective film or films provided on one or both sides of the polarizer, and the pressure-sensitive adhesive layer is formed from a pressure-sensitive adhesive composition containing a (meth)acryl-based polymer (A) and an ionic compound (B). The pressure-sensitive adhesive layer-attached polarizing film has an antistatic function and exhibits durability.
    Type: Grant
    Filed: May 18, 2012
    Date of Patent: June 28, 2016
    Assignee: NITTO DENKO CORPORATION
    Inventors: Atsushi Yasui, Yuusuke Toyama, Tomoyuki Kimura, Masayuki Satake, Shusaku Goto, Takeharu Kitagawa, Minoru Miyatake, Tomohiro Mori, Takashi Kamijo, Arata Fujihara
  • Patent number: 9120934
    Abstract: This invention discloses an antistatic coating composition and antistatic film coated with the same. The antistatic coating composition comprises a hard coating solution and an antistatic solution. The hard coating solution comprises from 20 to 35 parts by weight of an acrylic oligomer, from 5 to 10 parts by weight of an acrylic monomer, from 40 to 60 parts by weight of a solvent and from 1 to 5 parts by weight of a photoinitiator. The antistatic solution comprises from 0.5 to 5 parts by weight of polyacrylic acid and from 1 to 20 parts by weight of ionic liquid. The antistatic film formed by coating the antistatic coating composition has a pencil hardness of 2H and an initial surface resistivity in the range of 108˜1011?/?, and the surface resistivity will maintain in the range of 1010˜1012?/? after isopropanol (IPA) washing.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: September 1, 2015
    Assignee: Benq Materials Corporation
    Inventors: Cheng-Hsin Tsai, Yu-Chen Yeh
  • Publication number: 20030191239
    Abstract: Stabilizer mixture comprising, for example, a compound of the formula
    Type: Application
    Filed: November 11, 2002
    Publication date: October 9, 2003
    Inventor: Francois Gugumus
  • Publication number: 20030125460
    Abstract: This invention provides a clear paint composition for motorcars which contains 10-80% by weight of polyester resin containing units derived from alicyclic polybasic acid and/or alicyclic polyhydric alcohol, 5-50% by weight of polyisocyanate compound and 0-50% by weight of acrylic resin; and which forms coating having Universal Hardness (HU) of not more than 500 N/mm2.
    Type: Application
    Filed: July 5, 2002
    Publication date: July 3, 2003
    Inventors: Kazuhiro Kato, Kazuaki Kitazono, Yoshizumi Matsuno, Hiroshi Igarashi
  • Publication number: 20030055162
    Abstract: Fibers having improved resistance to moisture at elevated temperatures comprise at least two elastic polymers, one polymer heat-settable and the other polymer heat-resistant, the heat-resistant polymer comprising at least a portion of the exterior surface of the fiber. The fibers typically have a bicomponent and/or a biconstituent core/sheath morphology. Typically, the core comprises an elastic thermoplastic urethane, and the sheath comprises a homogeneously branched polyolefin, preferably a homogeneously branched substantially linear ethylene polymer.
    Type: Application
    Filed: July 15, 2002
    Publication date: March 20, 2003
    Inventors: Ashish Sen, John Klier, Rajen M. Patel, Hongyu Chen, Thoi H. Ho
  • Publication number: 20030022988
    Abstract: Compound containing polyurethane and hydrotalcite to give elastic thread resistance to the action of the chlorine by means of dry or fused spinning, or spinning from solution in which the average grain size of the hydrotalcite added to the polyurethane is less than 1 micron and preferably less than 0.8 micron.
    Type: Application
    Filed: May 30, 2002
    Publication date: January 30, 2003
    Inventors: Vincenzo Iati, Luca Ricci
  • Publication number: 20020193515
    Abstract: There is provided a polarization film for near ultra-violet polarization plate manifesting high polarization ability at the near ultra-violet range of 370-400 nm, having sufficient endurance, and containing a monoazo compound represented by the following formula (I) or a salt thereof: 1
    Type: Application
    Filed: March 25, 2002
    Publication date: December 19, 2002
    Inventors: Yoshiteru Ohta, Toru Ashida, Narutoshi Hayashi
  • Publication number: 20020123564
    Abstract: The rubber mixtures according to the present invention consisting of uncrosslinked, double bond-containing rubbers (A), crosslinked rubber particles (B) and multifunctional isocyanates based on polyuret (C), wherein, based on 100 parts by weight (phr) of the rubber components (A) respectively, the component (B) content in the mixture is 1 to 150 parts by weight and the multifunctional isocyanate content based on polyuret (component C) is 1 to 100 parts by weight, can be used to produce rubber vulcanizates and rubber molded articles of all kinds, the vulcanizates produced therefrom exhibiting an advantageous combination of mechanical properties, such as modulus at 300% elongation, elongation at break, tear strength and abrasion resistance.
    Type: Application
    Filed: August 14, 2001
    Publication date: September 5, 2002
    Inventors: Werner Obrecht, Martin Mezger, Anthony Sumner
  • Publication number: 20020091194
    Abstract: Mixtures of primary amines of the formula (I)
    Type: Application
    Filed: January 3, 2002
    Publication date: July 11, 2002
    Inventors: Joachim Pfeffinger, Michael Hullmann, Arthur Hohn, Frank Funke, Frank Ohlbach, Till Gerlach
  • Publication number: 20020061963
    Abstract: Disclosed is a carboxyl capped polyester powder coating composition, where the polyester has an acid number of 10 to 100 mg KOH/g, characterized by improved flexibility without significant loss of other properties, said powder coating prepared by substituting 5 to 90 mole % of the aliphatic diol in the polyester resin with 1,3-propanediol, and reacting with one or more dicarboxylic acids and trimethylolpropane, and formulating into a powder coating with a triglycidyl isocyanurate resin.
    Type: Application
    Filed: August 28, 2001
    Publication date: May 23, 2002
    Inventors: Shelby Freland Thames, Oliver Wendell Smith, Lichang Zhou, Wyndham Henry Boon, Thomas Clayton Forschner, David Eric Gwyn
  • Publication number: 20020061962
    Abstract: The present invention is a polyurethane prepolymer comprising the reaction product of:
    Type: Application
    Filed: August 7, 2001
    Publication date: May 23, 2002
    Inventor: Lirong Zhou
  • Publication number: 20020022689
    Abstract: A process for the preparation of water soluble polypyrrole is provided. The process comprises admixing pyrrole, water, and an effective amount of an electroinactive water soluble polycation to form an initial composition. That initial composition is admixed with an effective amount of an oxidizer to form a reacting composition, which is allowed to react for a time sufficient until substantially no decrease in potential occurs, whereby the polypyrrole is formed.
    Type: Application
    Filed: August 14, 2001
    Publication date: February 21, 2002
    Inventors: Vinod P. Menon, Patrick John Kinlen
  • Publication number: 20010016623
    Abstract: Mixtures comprise
    Type: Application
    Filed: January 30, 2001
    Publication date: August 23, 2001
    Applicant: BASF Aktiengesellschaft
    Inventors: Bernd Bruchmann, Gunter Mohrhardt, Hans Renz, Jaochim Jahme
  • Patent number: 6265588
    Abstract: A compound of the formula where R1 is the radical of the formula II or III is suitable for the production of a pharmaceutical for the treatment of inflammations, carcinomatous diseases, or autoimmune diseases. A compound of the formula IV is suitable for the production of specific antibodies against a compound of the formula I for the discovery of specific-binding proteins from cell extracts, serum, blood, or synovial fluids, for the purification of proteins, for the modification of microtiter plates, or for the preparation of chromatography material, in particular of affinity chromatography material, and for use in diagnostics.
    Type: Grant
    Filed: May 30, 2000
    Date of Patent: July 24, 2001
    Assignee: Aventis Pharma Deutschland GmbH
    Inventors: Stefan Müllner, Bernd Kirschbaum, Wilfried Schwab
  • Patent number: 5859127
    Abstract: Disclosed is a novel thermosetting resin composition suitable for the preparation of an integrally molded two-parts composite body consisting of a first part of a cured silicone rubber and a second part of a cured thermosetting resin without intervention of an adhesive layer at the interface. The thermosetting resin composition comprises:(a) 100 parts by weight of an unsaturated polyester resin;(b) from 20 to 50 parts by weight of an ethylenically unsaturated polymerizable compound such as diallyl phthalate;(c) from 5 to 30 parts by weight of an epoxy resin;(d) from 2 to 20 parts by weight of a melamine resin;(e) from 0.1 to 2 parts by weight of a radical-reactive curing agent which is an organic peroxide; and(f) from 0.1 to 2 parts by weight of an acidic catalyst such as aromatic sulfonic acid derivatives.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: January 12, 1999
    Assignee: Shin-Etsu Polymer Co., Ltd.
    Inventors: Sadao Nakano, Susumu Iwama, Mikio Kiyosawa
  • Patent number: 5747548
    Abstract: Apparatus and method for the production of hopper feedable thermoplastic pellets having zones or compartments which contain physically separated reactants which react only after being melt-mixed, as in a screw type extruder, reciproscrew injection machine, or similar device which heat forms pellets into a larger mass. This new class of thermoplastic molding materials relies mainly on the relatively slow reaction kinetics of contained large molecule molding materials to provide a time interval after melt-mixing of zoned pelletized reactants in an extruder barrel or injection molding machine. During this time period, the thermoplastic molding material is easily filled into injection molds. As the reaction progresses, the material becomes more viscous and such flow is difficult or impossible. The involved reactions may continue after demolding at room temperature during a post molding cure, or appliance service generated heat may cause post molding cure.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: May 5, 1998
    Assignee: Materials Research Innovations Corporation
    Inventor: Rexford H. Bradt
  • Patent number: 5705275
    Abstract: Disclosed is a novel thermosetting resin composition suitable for the preparation of an integrally molded two-parts composite body consisting of a first part of a cured silicone rubber and a second part of a cured thermosetting resin without intervention of an adhesive layer at the interface. The thermosetting resin composition comprises:(a) 100 parts by weight of an unsaturated polyester resin;(b) from 20 to 50 parts by weight of an ethylenically unsaturated polymerizable compound such as diallyl phthalate;(c) from 5 to 30 parts by weight of an epoxy resin;(d) from 2 to 20 parts by weight of a melamine resin;(e) from 0.1 to 2 parts by weight of a radical-reactive curing agent which is an organic peroxide; and(f) from 0.1 to 2 parts by weight of an acidic catalyst such as aromatic sulfonic acid derivatives.
    Type: Grant
    Filed: November 29, 1996
    Date of Patent: January 6, 1998
    Assignee: Shin-Etsu Polymer Co., Ltd.
    Inventors: Sadao Nakano, Susumu Iwama, Mikio Kiyosawa
  • Patent number: 5648410
    Abstract: The invention relates to an aqueous polyester- and acrylate-based polymer dispersion, obtainable by free radical-initiated polymerization of at least(a) one (meth)acrylic acid ester,(b) one ethylenically unsaturated, at least monofunctional acid, and optionally(c) one ethylenically unsaturated monomer other than (a) and (b),or mixtures thereof with a polyester resin capable of undergoing a free radical-initiated polymerization. The invention further relates to the production of these aqueous polymer dispersions, to aqueous clear coat compositions containing said dispersions, and to the use thereof.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 15, 1997
    Assignee: Bollig & Kemper KG
    Inventors: Hans Dieter Hille, Horst Muller
  • Patent number: 5549932
    Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: August 27, 1996
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5480726
    Abstract: The hardness and appearance of an in-mold coating for a molded article of cured unsaturated polyester are improved by the addition of melamine and/or benzoguanamine to an unsaturated polyester powder coating composition and subjecting the modified powder coating to a molding temperature of from about 260.degree. F. to about 340.degree. F. and a pressure of from about 650 psi to about 2000 psi for from 1 to 12 minutes. From about 5 to about 40 parts of the melamine and/or benzoguanamine per hundred parts by weight of the coating resin is used.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: January 2, 1996
    Assignee: Morton International, Inc.
    Inventor: Douglas S. Richart
  • Patent number: 5475040
    Abstract: Filled, thermoplastic-modified thermosetting polyester resin formulations are provided as encapsulants for microelectronics devices. The polyester encapsulant formulations include either a low profile thermoplastic resin additive or a combination of polyethylene and a low shrink thermoplastic additive. In preferred embodiments the polyester encapsulant formulations are of low viscosity and can be utilized in various pressure molding protocols. The encapsulant matrix is characterized by a low coefficient of thermal expansion, very low shrinkage, low modulus, and good thermal conductivity. Microelectronics devices encapsulated with the polyester resin formulation exhibit good resistance to moisture related and stress-induced failure.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: December 12, 1995
    Assignee: Thermoset Plastics, Inc.
    Inventors: William L. Jamison, William H. Jenson, George E. Sears, Jr.
  • Patent number: 5399611
    Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: March 21, 1995
    Assignee: The Sherwin-Williams Company
    Inventor: John Mathai
  • Patent number: 5336716
    Abstract: The invention relates to paints comprising(i) a resin (A) which contains hydroxyl groups and .alpha.,.beta.-unsaturated carbonyl groups or a mixture of such resins, and/or(ii) a mixture consisting ofa) a hydroxyl-containing resin (B) or a mixture of such resins andb) a crosslinking agent (C) which contains .alpha.,.beta.-unsaturated carbonyl groups or a mixture of such crosslinking agents and(iii) a catalyst (D) which catalyzes the reaction of hydroxyl groups with .alpha.,.beta.-unsaturated carbonyl groups or a mixture of such catalysts.The invention is characterized in that the catalyst (D) is a Bronsted acid.
    Type: Grant
    Filed: February 25, 1993
    Date of Patent: August 9, 1994
    Assignee: BASF Lacke + Farben Aktiengesellschaft
    Inventors: Elisabeth Kappes, Ulrich Poth
  • Patent number: 5212234
    Abstract: The invention relates to a moulding compound based on thermosetting resin material and optionally fibers, fillers, curing catalysts and further usual additives, and is characterized in that the moulding compound comprises a mixture of at least two thermosetting resins of which a first resin is in a partly cured state, and of which a second resin is not, or less than the first resin in a partly cured state.
    Type: Grant
    Filed: April 23, 1991
    Date of Patent: May 18, 1993
    Assignee: DSM Resins B.V.
    Inventors: Rene L. E. Van Gasse, Andreas N. J. Verwer
  • Patent number: 5182335
    Abstract: The addition of elastomeric thermoplastic polymers and melamine resin to the polymer matrix of composite materials for the moulding of fibre-reinforced unsaturated polyester resin improves the surface characteristics, resilience, and mouldabilty and heat resistance thereof.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: January 26, 1993
    Assignee: Fiat Auto SpA
    Inventor: Mario Da Re'
  • Patent number: 5087690
    Abstract: Hybrid curable compositions comprising components curable by condensation, and components curable by free-radical initiated polymerization, cure being catalyzed by a metal sulfonate. The components curable by condensation comprise amino resins and co-reactants. The components curable by free radical initiated polymerization comprise acryloyl compounds and allylic or vinylenearylenemethylidyne compounds.
    Type: Grant
    Filed: January 24, 1989
    Date of Patent: February 11, 1992
    Assignee: Monsanto
    Inventor: David W. Demarey
  • Patent number: 5084494
    Abstract: A polyester resin and reinforcement composite for use in the manufacture of glass fiber-reinforced polyester products is disclosed. The composite is prepared using an initiator which has been microencapsulated in order to prevent initiator-induced cross-linking of the resin reactants. The initiator is released during the molding of the composite by rupture of the microcapsules due to internal vapor pressure developed at a preselected temperature. The encapsulation of the initiator increases the storage life and temperature stability of the composites prior to molding. The encapsulation of the initiator also provides improved homogeneity and increased flowability of the composites during molding, an enables the provision of molded polyester products having higher degrees of cure and more defect-free finish surfaces.
    Type: Grant
    Filed: September 8, 1989
    Date of Patent: January 28, 1992
    Inventor: McDougal: John R.
  • Patent number: 5079315
    Abstract: Hybrid curable compositions comprising components curable by condensation and components curable by free radical initiated polymerization. The components curable by condensation reaction comprise amino resins and co-reactants, the condensation reaction being optionally catalyzed by acid catalysts. The components curable by free radical initiated polymerization comprise acryloyl compounds and allylic or vinylenearylenemethylidyne compounds.
    Type: Grant
    Filed: January 24, 1989
    Date of Patent: January 7, 1992
    Assignee: Monsanto Company
    Inventor: David W. Demarey
  • Patent number: 5070183
    Abstract: Highly branched, functionalized, wholly aromatic poly(arylenes) are prepared by the polymerization of AB.sub.n -type aromatic monomers.
    Type: Grant
    Filed: April 20, 1989
    Date of Patent: December 3, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Young H. Kim
  • Patent number: 5068299
    Abstract: A metal treatment solution comprising an effective amount of a soluble or dispersible compound which is a derivative of a polyphenol. Novel derivatives of polyphenol compounds useful in the treatment of the surface of metal articles is provided. Novel surface treatment solutions or dispersions, and methods for using these solutions is provided. Carbohydrate-modified polyphenol compounds are utilized in the present invention. The molecular weight of the polyphenols used in the preperation of derivatives of the present invention are in the range of about 360 to about 30,000 or greater. The resulting derivatives will typically have a molecular weight of up to about 2,000,000 with molecular weight within the range of about 700 to about 70,000 being preferred.
    Type: Grant
    Filed: August 24, 1990
    Date of Patent: November 26, 1991
    Assignee: Henkel Corporation
    Inventors: Andreas Lindert, John R. Pierce, David R. McCormick, William D. Zimmermann
  • Patent number: 5039762
    Abstract: Hybrid curable compositions comprising components curable by condensation and components curable by the free radical initiated polymerization. The components curable by condensation reaction comprise amino resins and co-reactants, the condensation reaction being optionally catalyzed by acid catalysts. The components curable by free radical initiated polymerization comprise acryloyl compounds.
    Type: Grant
    Filed: January 24, 1989
    Date of Patent: August 13, 1991
    Assignee: Monsanto Company
    Inventor: David W. Demarey
  • Patent number: 5028456
    Abstract: A curable polyester composition having improved properties is described, and the curable polyester composition comprises:(A) at least one unsaturated polyester resin;(B) at least one hydrocarbon monomer copolymerizable with the polyester; and(C) at least one aryl sulfonamide-aldehyde resin.When the curable polyester composition is to be used as a plastic body filler, the curable polyester composition generally will be modified to include (D) at least one inorganic filler which may comprise a mixture of an inorganic powder and inorganic hollow microspheres.The curable polyester resin compositions of the invention are useful as plastic body fillers for repairing metal surfaces, and the curable compositions have been found to be particularly useful and advantageous as plastic body fillers for galvanized steel.
    Type: Grant
    Filed: September 28, 1990
    Date of Patent: July 2, 1991
    Assignee: Oatey Company
    Inventor: Paul E. Naton
  • Patent number: 4980414
    Abstract: A curable polyester composition having improved properties is described, and the curable polyester composition comprises:(A) at least one unsaturated polyester resin;(B) at least one hydrocarbon monomer copolymerizable with the polyester; and(C) at least one aryl sulfonamide-aldehyde resin.When the curable polyester composition is to be used as a plastic body filler, the curable polyester composition generally will be modified to include (D) at least one inorganic filler which may comprise a mixture of an inorganic powder and inorganic hollow microspheres.The curable polyester resin compositions of the invention are useful as plastic body fillers for repairing metal surfaces, and the curable compositions have been found to be particularly useful and advantageous as plastic body fillers for galvanized steel.
    Type: Grant
    Filed: April 6, 1989
    Date of Patent: December 25, 1990
    Assignee: Oatey Company
    Inventor: Paul E. Naton
  • Patent number: 4963220
    Abstract: A composition providing a two-part adhesive consists of an acrylate monomer and perester catalyst, comprising the polymerizable part, and a ferric ion-accelerated butyraldehyde/aniline activator comprising the other.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: October 16, 1990
    Assignee: Dymax Corporation
    Inventors: Andrew G. Bachmann, Robert F. Bickley
  • Patent number: 4963596
    Abstract: A metal treatment solution comprising an effective amount of a soluble or dispersible compound which is a derivative of a polyphenol. Novel derivatives of polyphenol compounds useful in the treatment of the surface of metal articles is provided. Novel surface treatment solutions or dispersions, and methods for using these solutions is provided. Carbohydrate-modified polyphenol compounds are utilized in the present invention. The molecular weight of the polyphenols used in the preparation of derivatives of the present invention are in the range of about 360 to about 30,000 or greater. The resulting derivatives will typically have a molecular weight of up to about 2,000,000 with molecular weights within the range of about 700 to about 70,000 being preferred.
    Type: Grant
    Filed: December 4, 1987
    Date of Patent: October 16, 1990
    Assignee: Henkel Corporation
    Inventors: Andreas Lindert, John R. Pierce, David R. McCormick, William D. Zimmermann
  • Patent number: 4873285
    Abstract: Hydroxy functional polyester graft copolymers are provided. The copolymer is crosslinkable by hydroxy-reactive crosslinking agent and, in particular, is suitable for use in thermosetting coating compositions adapted to form a flexible cured coating over a variety of substrates, such as metal and plastic. The copolymer has a number average molecular weight between about 1,300 and about 15,000, has a hydroxyl number between about 30 and about 300, and is the reaction product of carbon-carbon double bond-reactive monoethylenically unsaturated monomer with hydroxy functional carbon-carbon double bond-bearing branched polyester macromer.
    Type: Grant
    Filed: August 11, 1988
    Date of Patent: October 10, 1989
    Assignee: E. I. Du Pont De Nemours and Company
    Inventor: Rose A. Ryntz
  • Patent number: 4786682
    Abstract: A coating composition contains;A. an ungelled Michael adduct formed by reacting, under conditions sufficient to form a Michael adduct,(a) a material containing one or more primary and/or secondary amino groups and at least two hydroxyl groups;(b) a material containing at least two alpha,beta-ethylenically unsaturated moieties; with the proviso that the reactants (a) and (b) are selected such that the resultant Michael adduct contains hydroxyl functionality; andB. a curing agent adapted to crosslink with the hydroxyl functionality present on the Michael adduct; said adduct being stable under the curing conditions for the coating composition.The aforedescribed coating compositions are particularly useful as anti-chip primers.
    Type: Grant
    Filed: June 25, 1987
    Date of Patent: November 22, 1988
    Assignee: PPG Industries, Inc.
    Inventors: Leon A. Perez, H. Hayne Crum, III
  • Patent number: 4520161
    Abstract: A fluid, highly heat stable, insulating composition is made by admixing: (A) from 9 mole % to 12 mole % of selected unsaturated cyclic dicarboxylic acid; (B) from about 15 mole % to about 20 mole % of an unsaturated aliphatic dicarboxylic acid; (C) from about 35 mole % to about 40 mole % of an aliphatic dihydric alcohol; (D) from about 25 mole % to about 40 mole % of diallyl phthalate copolymerizable monomer; and (E) an inhibiting agent, to provide a polyester; and from 15 parts by weight to 30 parts by weight of hexa methoxy methyl melamine per 100 parts by weight of polyester.
    Type: Grant
    Filed: June 14, 1984
    Date of Patent: May 28, 1985
    Assignee: Westinghouse Electric Corp.
    Inventor: Daniel R. Sassano
  • Patent number: 4461870
    Abstract: A high solid coating composition comprising(A) a film-forming polymer having functional group(s) capable of reacting with the crosslinking agent (D) hereinafter referred to,(B) a volatile organic liquid diluent in which the polymer (A) is carried,(C) polymer microparticles having an average diameter of from 0.02 to 40 microns, which are insoluble in the combination of the film-forming polymer (A) and the diluent (B) and are maintained in a stabilized state of dispersion therein, and(D) a crosslinking agent dissolved in the diluent (B),which is characterized in that the microparticles (C) are composed of crosslinked copolymer of .alpha.,.beta.-ethylenically unsaturated monomers carrying thereon a resinous portion having an amphoionic group of the formula: ##STR1## wherein R is a member selected from optionally substituted alkylene having 1 to 6 carbon atoms and phenylene group and Y is --COOH or --SO.sub.3 H.
    Type: Grant
    Filed: January 25, 1983
    Date of Patent: July 24, 1984
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Kazunori Kanda, Keizou Ishii, Katsuaki Kida, Shinichi Ishikura, Ryuzo Mizuguchi
  • Patent number: 4433070
    Abstract: Cultured onyx, cultured marble, and like mineral-appearing products are provided, as well as intermediates and components and methods therefor through the combination of a locally discontinuous phase comprising a synthetic organic resin portion hardened to a predetermined hardness and a visually distinguishable continuous phase comprising a synthetic organic resin portion separately hardened to the predetermined hardness with the discontinuous phase intimately distributed therein, to form shaped structures having surfaces simulative of onyx, marble, or like naturally occurring mineral in appearance, which surfaces are uniformly polishable in phase undifferentiated relation.
    Type: Grant
    Filed: May 5, 1980
    Date of Patent: February 21, 1984
    Inventors: Gilbert B. Ross, Theodore E. Stevens
  • Patent number: 4391947
    Abstract: A fluid, polyester insulating composition is made by admixing: (A) about 15 mole % to about 40 mole % of unsaturated cyclic dicarboxylic acid; (B) about 5 mole % to about 20 mole % of an unsaturated aliphatic dicarboxylic acid; (C) about 35 mole % to about 60 mole % aliphatic dihydric alcohol; (D) about 25 mole % to 35 mole % copolymerizable monomer; and (E) an active dual inhibiting agent combination of hydroquinone and mono tert butyl hydroquinone, and up to about 10 parts by weight melamine per 100 parts by weight polyester.
    Type: Grant
    Filed: November 6, 1980
    Date of Patent: July 5, 1983
    Assignee: Westinghouse Electric Corp.
    Inventor: Daniel R. Sassano
  • Patent number: 4336297
    Abstract: An electrical laminate comprising layers of a polyester resin-impregnated fibrous cellulosic substrate is disclosed. The substrate is preimpregnated with a nitrogen-containing composition having (a) an N-methylol or N-lower alkoxymethyl group attached to said nitrogen atom, and (b) an unsaturated group capable of copolymerizing with a cross-linking monomer present in the polyester resin.
    Type: Grant
    Filed: April 23, 1980
    Date of Patent: June 22, 1982
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yasuo Fushiki, Masaharu Abe, Masakazu Uekita
  • Patent number: 4296020
    Abstract: Ethylenically unsaturated monomer solutions of ethylenically unsaturated polyester, polyester urethane and polyisocyanurate resins are quickly converted to moldable gels by the homogeneous formation therein of polyurea resins by the interaction of polyamines and polyisocyanates. Tack-free handleable moldable gels are formed within minutes which can be stored under normal conditions for long periods of time until molded. Fully cured intractable articles are formed by the polymerization of the ethylenically unsaturated ingredients.
    Type: Grant
    Filed: October 29, 1979
    Date of Patent: October 20, 1981
    Assignee: ICI Americas Inc.
    Inventor: Juan J. Magrans, Jr.
  • Patent number: 4273632
    Abstract: Liquid ultraviolet-curable coating compositions are provided by mixing a polyethylenically unsaturated compound, such as pentraerythritol triacrylate, with a liquid monoethylenically unsaturated hydroxy functional polyether, such as the reaction product of propylene oxide with hydroxyethylacrylate. An aminoplast is included in the mixture so that a thermal cure, following the radiation cure, will result in a cured coating having increased ability to withstand fabrication stresses without loss of adhesion to the substrate.
    Type: Grant
    Filed: April 18, 1979
    Date of Patent: June 16, 1981
    Assignee: Mobil Oil Corporation
    Inventor: Bizhan M. Zarnegar
  • Patent number: 4259457
    Abstract: There are disclosed graft polyesters useful as adhesives and coatings and especially useful in processes for sizing spun and continuous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer. Desizing can be accomplished by partial neutralization of the size to a pH of at least 6 by reacting the size with a base to render the graft polyester water-dispersible or water-soluble.
    Type: Grant
    Filed: July 23, 1979
    Date of Patent: March 31, 1981
    Assignee: BASF Wyandotte Corporation
    Inventor: Robert B. Login
  • Patent number: 4225681
    Abstract: A cross-linked graft polyester comprising the reaction product of an aminoplast and a graft polyester, said graft polyester comprising the reaction product of (1) an unsaturated polyester which is the reaction product of at least one polycarboxylic acid reactant, preferably a dicarboxylic acid reactant and at least one polyhydric alcohol reactant, preferably a diol, wherein a minor effective proportion of at least one of said reactants is .alpha.,.beta.-ethylenically unsaturated with (2) at least one monovinyl monomer reactant comprising at least one acidic monovinyl monomer containing at least one carboxyl group or a mixture of said vinyl monomer with any monovinyl monomer.
    Type: Grant
    Filed: July 25, 1979
    Date of Patent: September 30, 1980
    Assignee: BASF Wyandotte Corporation
    Inventor: Robert B. Login