Abstract: The present application relates to a block copolymer and its use. The present application can provides a block copolymer that has an excellent self assembling property or phase separation property and therefore can be used in various applications and its use.

Abstract: A power cable comprising: (A) a conductor, (B) an insulation layer, and (C) a semiconductor layer comprising in weight percent based on the weight of the semiconductor layer: (1) 49-98% of a crosslinked olefin block copolymer (OBC) having a density less than (<) 0.9 grams per cubic centimeter (g/cm3), a melt index greater than (>) 1, and comprising in weight percent based on the weight of the OBC: (a) 35-80% soft segment that comprises 5-50 mole percent (mol %) of units derived from a monomer comprising 3 to 30 carbon atoms; and (b) 20-65% hard segment that comprises 0.2-3.5 mol % of units derived from a monomer comprising 3 to 30 carbon atoms; (2) 2-51% conductive filler, the insulation layer and semiconductor layer in contact with one another, is degassed by a process comprising the step of exposing the cable to a temperature of at least 80° C. for a period of time of at least 24 hours.

Abstract: A graft copolymer comprising polyolefin and engineering thermoplastic components, wherein the thermoplastic component is a polymer comprising heteroatoms or heteroatom containing moieties in its backbone and phenyl or substituted phenyl groups, the polyolefin component covalently bound to the engineering thermoplastic component. The graft copolymer is the reaction product of an engineering thermoplastic having at least one phenylene in the polymer backbone, and a vinyl/vinylidene terminated polyolefin having a weight average molecular weight of at least 300 g/mole, wherein the vinyl/vinylidene terminated polyolefin is selected from polyethylenes, polypropylenes, ethylene-propylene copolymers, polyisobutylenes, polydienes, propylene-based elastomers, ethylene-based plastomers, and combinations thereof.

Abstract: The invention relates to polymer compounds containing A) 0 to 98 parts by weight, based on the sum of A and B, of a thermoplastic polymer, or a mixture of a plurality of thermoplastic polymers differing from B, and B) 2 to I 00 parts by weight, based on the sum of A and B, of B I) at least one graft polymer produced by an emulsion polymerisation process, B2) optionally at least one graft polymer produced in a mass, suspension or solution polymerisation process, B3) optionally at least one rubber-free vinyl (co)polymer and (C) 0 to 30 parts by weight of at least one commercially available polymer additive, wherein the total of parts by weight A and B is 100.

Abstract: An ostomy appliance includes a sound absorbing film comprising a triblock copolymer including polystyrene blocks and vinyl-bond rich rubber mid-block, and a sound absorbing non-woven material comprising the triblock copolymer including polystyrene blocks and vinyl-bond rich rubber mid-block. The ostomy appliance has improved sound absorbing properties to insulate flatulence noise.

Abstract: Farnesene interpolymer comprises units derived from a farnesene (e.g., ?-farnesene or ?-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an ?-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.

Abstract: The invention relates to a method for producing polyacrylate adhesive compounds with a narrow molar mass distribution by means of a radical polymerization and a subsequent increase of the molar masses by reacting with bis- or multi-dienyl compounds, in particular with ?,?-bis-dienyl compounds, in order to increase the cohesion in particular.

Abstract: The invention relates to polymers selected from among polypropylene (PP), polycarbonate (PC), acrylonitrile-butadiene-styrene (ABS), polyvinylchloride (PVC) and polyethylene terephthalate (PET), nylon and polystyrene, having antibacterial properties, wherein the antibacterial effect is obtained by adding a zinc salt selected from among: zinc PCA, zinc oxide, zinc hydroxide, zinc pyrrolidone or zinc pyrithione during the process of polymerization of the monomers. The antibacterial polymers are used to prepare products intended to enter into contact with the skin.

Abstract: The present invention provides a method of preparing a polymer particle. More precisely, the invention provides a polymer particle having optimum impact strength and improved elastic recovery rate by forming the brush having softness on the surface of the monodisperse polymer particle by the anion dispersion polymerization using a conjugated diene monomer.

Abstract: A modified natural rubber particle having carbon-carbon double bands assigned to multifunctional vinyl monomers graft-copolymerized onto the surface of the modified natural rubber particle, which is prepared by graft-copolymerization of multifunctional vinyl monomers having two or more carbon-carbon double bonds onto natural rubber particles or deproteinized natural rubber particles. One of the methods for producing a modified natural rubber particle includes the steps of: forming inclusion complex of the multifunctional vinyl monomers having two or more carbon-carbon double bonds with a guest-protecting agent to protect at least one of the double bonds of the multifunctional vinyl monomers; graft-copolymerizing the resulting inclusion complex onto natural rubber particles or deproteinized natural rubber particles; and deprotecting the protected double bonds by removing the guest-protecting agent from the obtained graft-copolymer.

Abstract: Provided is a block copolymer of a conjugated diene compound and a non-conjugated olefin, a rubber composition including the block copolymer, a crosslinked rubber obtained by crosslinking the rubber composition, and a tire using the rubber composition or the crosslinked rubber composition. The copolymer of the present invention is a block copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer having a peak area in a temperature range in a range of 70° C. to 110° C. that accounts for at least 60% of a peak area in a range of 40° C. to 140° C. and a peak area in a range of 110° C. to 140° C. that accounts for 20% or less of a peak area in a range of 40° C. to 140° C., the peak areas being measured by the differential scanning calorimetry (DSC) according to JIS K 7121-1987.

Abstract: Thermoplastic elastomer compositions are described comprising multigraft copolymers. The multigraft copolymers can comprise a rubbery polymeric backbone and a plurality of glassy polymeric side chains, each attached at one of a plurality of branch points randomly spaced along the backbone. The copolymer materials have high tensile strength, high strain at break, and low residual strain after elongation. The compositions can be used as adhesives and in a wide variety of high tech, medical, and commodity applications.

Abstract: A method for producing thermoplastic elastomer is disclosed and comprises the step of: blending a mixture including particles of vulcanized rubber material and a molten thermoplastic material such that the rubber material is subjected to mechanical shearing forces and the surfaces of the rubber particles undergo homolytic bond scission to form chains of free radicals which cross-link with the thermoplastic material. Apparatus for carrying out the method, elastomers produced by the method and articles produced from the elastomers are also disclosed.

Abstract: The present invention relates to a compounding method for producing impact-modified thermoplastic compositions with a low content of volatile organic compounds (hereinafter VOCs), wherein relatively inexpensive polymer raw materials with a comparatively elevated initial VOC content may be used, resulting in lowered production costs for producing such VOC-reduced polymer compositions.

Abstract: The present invention relates to an elastomeric thermoplastic composition characterized in that it has compression resistance at temperatures between 20° C. and 100° C., comprising hydrogenated styrene-butadiene block copolymers, and to the copolymers that form said composition. Furthermore, the present invention relates to a product that has been obtained by means of the molding or extrusion of the composition described above.

Abstract: This invention relates to an adhesive comprising an olefin polymer composition comprising a first amorphous polymer having a crystallinity of 5% or less, prepared with a first catalyst; and a second crystalline polymer, differing in chemical and physical properties from the first polymer, having a crystallinity of 20% or more, prepared with a second catalyst; and where the olefin polymer composition has a Dot T-Peel of 1 Newton or more on Kraft paper; an Mw of at least 7,000 to 80,000; a branching index (g?) of from 0.4 to 0.90 measured at the Mz of the polymer composition; and a crystallinity of between 5 and 40%.

Abstract: Disclosed herein are polybutadiene grafted isoprene rubber, processes for preparing polybutadiene grafted isoprene rubber, mixed compositions and vulcanized forms thereof.

Abstract: The extensional viscosity of a styrenic resin is enhanced by increasing the Z+1 average molecular weight (Mz+1) of the resin. In one embodiment, an enhanced extensional viscosity resin is provided that has an Mz+1 molecular weight of at least approximately 745,000 and an extensional viscosity having a minimum value of approximately 360,000 Pascal-seconds (Pa-sec).

Abstract: The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.

Abstract: The present invention relates to structural, radically curable resin compositions suitable for (re)lining containing a. 30-70 wt. % of a resin characterized by (i) a molecular weight Mn between 500 and 3000 and (ii) an acid value between 0 and 30 mg KOH/g resin, and wherein at least 80 % of the total amount of resin is vinyl ester resin, b. 30-70 wt. % of at least one reactive diluent, characterized in that at least 25% of the reactive diluent is a difunctional diluent having a molecular weight Mn between 200 and 500 and the optional monofunctional diluent having a molecular weight Mn between 100 and 200, c. 0.00001-5 wt. % initiator, d. 0.00001-5 wt. % inhibitor further characterized in that the average molecular weight per reactive unsaturation (WPU) of the components (a) and (b) is equal or greater than 190 Dalton and that the amount of styrene in the resin composition is less than 5 wt. % (calculated as wt. % of the total weight of the components (a), (b), (c) and (d)).

Abstract: The present invention relates to arborescent polymers and to a process for making same. In one embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with a polymer or copolymer having a low glass transition temperature (Tg), and to a process for making such arborescent polymers. In another embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with less than about 5 weight percent end blocks derived from a polymer or copolymer having a high glass transition temperature (Tg), and to a process for making such arborescent polymers.

Abstract: The present invention relates to arborescent polymers comprising isoolefins and styrenic monomers, as well as processes for making same. In particular, the invention relates to highly branched block copolymers comprising an arborescent core with a high glass-transition temperature (Tg) and branches attached to the core terminated in polymer endblock segments with a low Tg. The copolymers of the invention desirably exhibit thermoplastic elastomeric properties and, in one embodiment, are desirably suited to biomedical applications.

Abstract: It has been found that certain cells in culture can convert more than about 0.002 percent of the carbon available in the cell culture medium into isoprene. These cells have a heterologous nucleic acid that (i) encodes an isoprene synthase polypeptide and (ii) is operably linked to a promoter. The isoprene produced in such a cultured medium can then be recovered and polymerized into synthetic rubbers and other useful polymeric materials. The synthetic isoprene containing polymers of this invention offer the benefit of being verifiable as to being derived from non-petrochemical based resources. They can also be analytically distinguished from rubbers that come from natural sources. The present invention more specifically discloses a polyisoprene polymer which is comprised of repeat units that are derived from isoprene monomer, wherein the polyisoprene polymer has ?13C value of greater than ?22‰.

Abstract: A composition for film formation which can form a film suitable for use as an interlayer dielectric in a semiconductor device, etc. and having an appropriate even thickness and can give a film having excellent characteristics including permittivity and Young's modulus; and a dielectric film obtained from the film-forming composition. The composition contains a compound (X) having a functional group which is partly eliminated by heating, irradiation with light, irradiation with radiation, or a combination thereof to generate volatile matter and yield an unsaturated group in the remaining part of the functional group.

Abstract: The polymerisation of material contained within and/or added to high temperature reactor produced carbon nanotube fibre wherein the contained material is crosslinked.

Abstract: The present invention provides a method of preparing a polymer particle. More precisely, the invention provides a polymer particle having optimum impact strength and improved elastic recovery rate by forming the brush having softness on the surface of the monodisperse polymer particle by the anion dispersion polymerization using a conjugated diene monomer.

Abstract: The present invention provides a polymer particle and a method of preparing the same. More precisely, the invention provides a polymer particle having optimum impact strength and improved elastic recovery rate by forming the brush having softness on the surface of the monodisperse polymer particle by the anion dispersion polymerization using a conjugated diene monomer.

Abstract: Disclosed therein is method for preparing novel suspension polymer comprising tetrafluoroethylene polymer, and powders or granules produced by the method. The suspension polymer of the present invention can be obtained by suspension polymerization of a styrene-based monomer, an acrylic monomer or a mixed monomer thereof in the presence of PTFE, followed by filtering and drying, and can be used as flame retarding properties improver of engineering plastic and the like.

Abstract: A pre-cursor block copolymer for sulfonation which, prior to hydrogenation, has the general configuration A-B-A, A-B-A-B-A, (A-B-A)nX, (A-B)nX, A-D-B-D-A, A-B-D-B-A, (A-D-B)nX, (A-B-D)nX or mixtures thereof, wherein A, B and D blocks do not contain any significant levels of olefinic unsaturation. Each A and D block is a polymer block resistant to sulfonation, and each B block is a polymer block susceptible to sulfonation. Each A block is a segment of one or more polymerized para-substituted styrene monomers, each B block contains segments of one or more vinyl aromatic monomers selected from polymerized (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) 1,1-diphenylethylene, (vi) 1,2-diphenylethylene and (vii) mixtures thereof, and each D block contains polymers having a glass transition temperature less than 20° C. and a number average molecular weight of between 1,000 and 50,000.

Abstract: A sulfur-containing anionic polymerization initiator defined by the formula: R1S—R2aR3?Li? where R1 is a monovalent organic group, R2 is a divalent organic group, R3 is a divalent organic group or a bond, and a is an integer from 1 to about 5.

Abstract: An elastic material for use in an absorbent article is provided. The elastic material contains a crosslinked network formed from a linear block copolymer having a monoalkenyl aromatic midblock positioned between conjugated diene endblocks (e.g., butadiene-styrene-butadiene (“B-S-B”) triblock copolymer). Prior to crosslinking, such linear block copolymers have a relatively low viscosity and thus may be readily formed into a precursor elastic material (e.g., film, strands, web, etc.) that is subsequently crosslinked to achieve the desired elastic and mechanical properties. Crosslinking is typically achieved through the formation of free radicals (unpaired electrons) that link together to form a plurality of carbon-carbon covalent bonds at the conjugated diene endblocks.

Abstract: A fluororubber composition according to the present invention contains 0.1 to 3 parts by weight of a polyol compound, 0.1 to 4 parts by weight of a peroxide crosslinking agent, and 1 to 9 parts by weight of a co-crosslinking agent per 100 parts by weight of a peroxide-crosslinkable fluoropolymer. A crack-resistant seal according to the present invention contains a crosslinked fluoropolymer and a polyol compound. The crack-resistant seal according to the present invention can be formed by crosslinking the fluororubber composition, and the resultant crack-resistant seal has particularly high crack resistance. With the fluororubber composition according to the present invention, a durable crack-resistant seal having high plasma resistance, crack resistance, and compression set and that produces few particles can be formed at low cost.

Abstract: A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer comprising a rigid matrix consisting of vinylaromatic polymers or copolymers and of an elastomeric phase dispersed in the matrix in form of particles with a strictly bimodal distribution which comprises the functionalization of a first elastomeric fraction by means of a catalytic system containing a stable free radical initiator and subsequently the polymerization of the thus obtained mixture also in presence of a second non functionalized elastomeric fraction.

Abstract: A sulfonated block copolymer which is solid and non-dispersible in water having at least two polymer end blocks A and at least one interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, wherein the A and B blocks do not contain any significant levels of olefinic unsaturation. Each A block includes one or more segments selected from polymerized (i) ethylene, (ii) monomers of conjugated dienes having a vinyl content less than 35 mol percent prior to hydrogenation, and (iii) mixtures thereof; and each B block comprising segments of one or more polymerized vinyl aromatic monomers selected from (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) 1,1-diphenylethylene, (vi) 1,2-diphenylethylene and (vii) mixtures thereof.

Abstract: Provided is a process for making a saturated star hydrocarbon polymer. The process has the following steps: (A) hydrosilylating tetraethylene silicon with methyldichlorosilane in the presence of a hydrosilylating catalyst to form a chlorosilane dendrimer; (B) reacting the chlorosilane dendrimer with vinylmagnesium bromide in the presence of a lithium and/or organolithium initiator stepwise to build a higher generation chlorosilane dendrimer; (C) anionically polymerizing polybutadiene in the presence of a lithium and/or organolithium initiator to form living poly(butadienyl)lithium; (D) attaching the living poly(butadienyl)lithium to the higher generation dendrimer to form a star polybutadiene; and (E) hydrogenating the star polybutadiene to form the saturated star hydrocarbon polymer. There is also provided a saturated star hydrocarbon polymer made according to the above process and a polymer composition of a matrix ethylene polymer and the saturated star hydrocarbon polymer.

Abstract: The present invention relates to an elastomeric thermoplastic composition characterized in that it has compression resistance at temperatures between 20° C. and 100° C., comprising hydrogenated styrene-butadiene block copolymers, and to the copolymers that form said composition. Furthermore, the present invention relates to a product that has been obtained by means of the moulding or extrusion of the composition described above.

Abstract: The instant invention is a crosslinkable polyethylene composition obtained via a process comprising the steps of (1) providing a polyethylene component; (2) providing an organic peroxide crosslinking agent,(3) providing a crosslinking coagent which comprises at least two terminal carbon-carbon double bonds and is an alkadiene, alkatriene, or alkatetraene compound; (4) melt blending the polyethylene component, the crosslinking agent, and the crosslinking coagent at a temperature less than the decomposition temperature of the crosslinking agent; and (5) thereby forming the crosslinkable polyethylene composition. The crosslinkable polyethylene composition may further include a scorch inhibitor, a cure booster, a stable free radical, one or more conventional additives, and/or combinations thereof. The instant invention further includes articles comprising the crosslinked product of the crosslinkable polyethylene composition.

Abstract: Farnesene interpolymer comprises units derived from a farnesene (e.g., ?-farnesene or ?-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an ?-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.

Abstract: The invention relates to a continuous process for preparing polyolefins having a bimodal or multimodal molar mass distribution in suspension in at least two reactors R1, R2.x, R3.y which are connected in series and in which different reaction conditions are set. In this process, the offgases A1, A2.x, A3.y, A4 and A5 leaving all the reactors connected in series are firstly collected, the collected offgases are then compressed in a compression stage 10, the compressed offgases are subsequently cooled and the cooled material is separated into a gaseous fraction and a liquid fraction. The separated fractions are then recirculated to the polymerization process at different points. The process of the invention allows the total conversion of the polymerization, based on monomer and comonomer used, to be increased to a surprising extent.

Abstract: The present invention provides a process for producing a block copolymer in high productivity, by anionic polymerization by use of a lithium initiator, and also to provide the block copolymer and a hydrogenated product thereof, the block copolymer having a conjugated diene block portion with a high vinyl bond content and a vinyl aromatic block portion with a narrow molecular weight distribution and exhibiting a narrow molecular weight distribution and high strength. A conjugated diene monomer and a vinyl aromatic monomer by use of a lithium initiator, are block copolymerized by making a tertiary amine compound and (2) sodium alkoxide coexist, wherein (2)/(1) (a molar ratio)=from 0.01 or more to less than 0.1.

Abstract: A method for varying the transport properties of a film cast from a polymer having at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. The method includes casting the polymer using a solvent mixture having two or more solvents selected from the group consisting of polar solvents and non-polar solvents.

Abstract: An adhesive composition comprising an amount of an adhesive, and an amount of an additive which is selected from the group of homopolymers of acrylic acid, copolymers of acrylic acid, and polyacrylates, polyurethanes, cellulose thickening agent, natural or synthetic gum, natural or synthetic resin, silica or an inorganic minerals having a layered structure.

Abstract: A method for forming a polymer including a sulfur-containing functional group, the method comprising introducing a sulfur-containing initiator defined by the formula with conjugated diene monomer and optionally copolymerizable monomer within a polymerization medium and allowing the sulfur-containing initiator to initiate the polymerization of the conjugated diene monomer and the optional copolymerizable monomer, where R1 is a monovalent organic group, R2 is a divalent organic group, R3 is a divalent organic group or a bond, and a is an integer from 1 to about 5.

Abstract: A process for forming a nanoparticle composition is provided. The process includes polymerizing conjugated diene monomer in a hydrocarbon solvent to form a first reaction mixture, and charging excess alkenylbenzense monomer and anionic catalyst to form mono-block and diblock polymers. Micelles of said mono-block and diblock polymers are formed, and at least one crosslinking agent is added to cross-link the micelles and form nanoparticles. The nanoparticles preferably have a poly(alkenylbenzene) core and an outer layer including monomer units selected from the group consisting of conjugated dienes, alkenylbenzenes, alkylenes, and mixtures thereof, and a size distribution of between about 1 and 1000 nm.

Abstract: A sulfonated block copolymer which is solid and non-dispersible in water having at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer containing essentially no sulfonic acid or sulfonate functional groups and each B block is a polymer block containing 10 to 100 mol percent sulfonic acid or sulfonate functional groups based on the number of monomer units of the B block, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. Also claimed are processes for making such block copolymers, and the various end uses and applications for such block copolymers.

Abstract: The present invention provides a low viscosity block copolymer for non-wovens construction adhesives of the formula [A?(A/B)]nX, wherein A represents an aromatic vinyl compound and (A/B) represents a polymer block obtained by random copolymerization of a mixture of a aromatic vinyl compound and butadiene in a weight ratio in the range of from 2:98 to 30:70, wherein n is an integer in the range of from 1 to 5, and wherein X is the remainder of the coupling agent.

Abstract: A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer in a controlled way, comprising the dissolving of an elastomer, such as polibutadiene, in a mixture consisting of a monomer and of a solvent in the presence of a polymerization catalytic system, which comprises an initiator of free radicals and a stable initiator of free radicals. The mixture obtained in this way is heated to a temperature of about 100° C. to functionalize the rubber, then more monomer is added and the temperature is raised to start the polymerization reaction.

Abstract: Provided are a method of producing a graft copolymer, the method involving subjecting a radically polymerizable monomer to living radical graft polymerization with a rubber component formed of a natural rubber and/or a synthetic diene-based rubber in an aqueous medium in the presence of a polymerization control agent, a rubber composition containing the graft copolymer obtained by the method, and a tire obtained by using the rubber composition in any one of its tire members.

Abstract: A process for preparing sulfonated block copolymers that are solid in water having at least two polymer end blocks A and at least one polymer interior block B involving sulfonating the interior block B until substantially sulfonated. Each A block having one or more segments selected from polymerized (i) para-substituted styrene monomers, (ii) ethylene, (iii) alpha olefins of 3 to 18 carbon atoms; (iv) hydrogenated 1,3-cyclodiene monomers, (v) hydrogenated monomers of conjugated dienes having a vinyl content less than 35 mol percent prior to hydrogenation, (vi) acrylic esters, (vii) methacrylic esters, and (viii) mixtures thereof. Each B block having segments of one or more polymerized vinyl aromatic monomers selected from (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) 1,1-diphenylethylene, (vi) 1,2-diphenylethylene and (vii) mixtures thereof.

Abstract: The present invention relates to a precipitation process for removing transition metals from polymer solutions. Specifically, it comprises the removal of transition metal complexes which usually comprise copper from polymer solutions after a completed atom transfer radical polymerization.