Polymer Derived From Carboxylic Acid Or Derivative Monomer Other Than: Vinyl Acetate; Or Acrylic-or-methacrylic-acid, Or Derivatives Patents (Class 525/329.5)
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Patent number: 11865815Abstract: Provided is a resin composition containing polymethallyl alcohol (A) having a repeating structural unit represented by the following formula (1) in an amount of greater than or equal to 30 mol %, and a component (B) that is at least one of an acid component having a pKa of 3.5 to 7.5 and an anion of the acid component, the pKa being a logarithmic value of a reciprocal of an acid dissociation constant at 25° C., a content of the component (B) being greater than or equal to 0.01 ?mol per 1 g of the polymethallyl alcohol (A); a method of producing the resin composition; and a molding containing the resin composition.Type: GrantFiled: December 24, 2015Date of Patent: January 9, 2024Assignee: KURARAY CO., LTD.Inventors: Yasuhiro Nonaka, Yasutaka Inubushi
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Patent number: 11535775Abstract: An adhesive film and a display member, the adhesive film being formed of an adhesive composition that includes a monomer mixture comprising a hydroxyl group-containing (meth)acrylate and a comonomer, wherein the adhesive film has a recovery rate of about 40% to about 99%, the recovery rate being determined according to Method A as described herein, and wherein the adhesive film has a bubble generation area of about 0%, the bubble generation area being determined according to Method B as described herein.Type: GrantFiled: December 17, 2015Date of Patent: December 27, 2022Assignees: SAMSUNG SDI CO., LTD., SAMSUNG ELECTRONICS CO., LTD.Inventors: Sung Hyun Mun, Byeong Do Kwak, Il Jin Kim, Ji Ho Kim, Hyung Rang Moon, Gwang Hwan Lee, Ik Hwan Cho, Jae Hyun Han
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Patent number: 11492516Abstract: An adhesive film is formed of an adhesive composition that includes a monomer mixture including a hydroxyl group-containing (meth)acrylate and a comonomer, and nanoparticles. The adhesive film has a glass transition temperature (Tg) of about ?20° C. or less, an index of refraction of about 1.40 to about 1.55, and a haze of about 3% or less at a thickness of 100 ?m.Type: GrantFiled: December 21, 2015Date of Patent: November 8, 2022Assignees: Samsung SDI Co., Ltd., Samsung Electronics Co., Ltd.Inventors: Jae Hyun Han, Hyung Rang Moon, Byeong Do Kwak, Il Jin Kim, Ji Ho Kim, Sung Hyun Mun, Gwang Hwan Lee
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Patent number: 11384014Abstract: A glass mat is provided. The glass mat includes an assembly of glass fibers; and a binder composition including a polymer resin and a crosslinker. The polymer resin has a pH of at least about 5.0. The polymer resin includes a styrenic copolymer, an acrylic copolymer, or combination thereof having at least one functional group of a carboxylic acid, a salt of a carboxylic acid, an anhydride, a salt of an anhydride, or combination thereof. The crosslinker includes a polyol, a polyepoxy, a polycarbodiimide, a polyaziridine, a bivalent metal carbonate, or combination thereof. Further provided is a method of making the glass mat.Type: GrantFiled: May 26, 2016Date of Patent: July 12, 2022Assignee: SAINT-GOBAIN ADFORS CANADA, LTD.Inventors: Camila A. Garces, Tao Yu, Choung-Houng Lai
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Patent number: 10851209Abstract: A manufacturing method of amphiphilic macromolecules is provided. The method includes: reacting the first acrylic acid with N,N?-carbonyldiimidazole to obtain a modified acrylic acid derivative; and reacting the modified acrylic acid derivative with the siloxane derivative to obtain amphiphilic macromolecules. Wherein, the terminal of the first acrylic acid has a hydroxyl group. Wherein, the siloxane derivative is a hydroxyl-terminated, acrylamide-terminated, epoxy-terminated or amine-terminated polysiloxane molecule.Type: GrantFiled: January 23, 2019Date of Patent: December 1, 2020Assignee: NATIONAL CHIAO TUNG UNIVERSITYInventors: Yun-Ru Hsieh, Dean-Mo Liu, Yu-Cheng Chien
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Patent number: 10829671Abstract: An adhesive film and a display member including the same are disclosed. The adhesive film is formed of an adhesive composition including: a copolymer of a monomer mixture including a hydroxyl group-containing (meth)acrylate and a comonomer; and nanoparticles. The adhesive film has a creep at ?20° C. of about 50 ?m to about 100 ?m and a gel fraction of about 50% to about 75%.Type: GrantFiled: June 30, 2016Date of Patent: November 10, 2020Assignees: Samsung SDI Co., Ltd., Samsung Electronics Co., Ltd.Inventors: Ik Hwan Cho, Ji Ho Kim, Jee Hee Kim, Ji Won Kang, Byeong Do Kwak, Yong Tae Kim, Il Jin Kim, Sung Hyun Mun, Hyung Rang Moon, Seon Hee Shin, Gwang Hwan Lee, Woo Jin Lee, Jae Hyun Han
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Patent number: 10323185Abstract: A method for preparing a hybrid inorganic-organic nanostructured inhibitive pigment, includes premixing a first stock solution containing one or more cations and a second stock solution containing one or more oxoanions to form a premixture under pH control in the presence of polymers as surface modifiers. The premixture is then reacted to form a slurry. The slurry is then quenched to separate nanoparticles from the slurry, followed by surface functionalization in organic inhibitors.Type: GrantFiled: June 30, 2015Date of Patent: June 18, 2019Assignee: United Technologies CorporationInventor: Weilong Zhang
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Patent number: 10273176Abstract: The present invention relates to partial decarboxylation of polyitaconic acid polymers or copolymers. The partially decarboxylated resins are suitable for use in preparation of dispersions as well as for anti-scaling applications.Type: GrantFiled: October 4, 2016Date of Patent: April 30, 2019Assignee: Itaconix CorporationInventors: Yvon Durant, Brian Luthi, John Shaw
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Patent number: 10131766Abstract: A process to use an unsaturated polyester resin system comprising preparing a curable cumene-quat curing system. The cumene-quat curing system can comprise an unsaturated polyester resin, a peroxide initiator, a quaternary ammonium salt component, a 2,4-pentanedione component, and an inhibitor component. The peroxide initiator can comprise a cumene hydroperoxide component. The process can further comprise applying the curable cumene-quat curing system in a cured-in-place pipe rehabilitation process.Type: GrantFiled: December 21, 2017Date of Patent: November 20, 2018Assignee: Interplastic CorporationInventors: Benjamin R. Hazen, David J. Herzog, Louis R. Ross, Joel R. Weber
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Patent number: 9937482Abstract: Disclosed herein are a superabsorbent polymer resin comprising agglomerated particles with a size of 450 ?m or less, and a method for preparing the same. The superabsorbent polymer resin exhibits significant improvement in absorption rate and permeability.Type: GrantFiled: December 10, 2014Date of Patent: April 10, 2018Assignee: LG Chem, Ltd.Inventors: Gi Cheul Kim, Sung Soo Park
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Patent number: 9796890Abstract: A modified acrylic block copolymer is obtained by a method comprising subjecting a block copolymer (C) to a reaction with an amine compound, wherein the block copolymer comprises a polymer block (A) comprising a (meth)acrylic acid ester unit (a) and a polymer block (B?) comprising a (meth)acrylic acid ester unit (b?), the (meth)acrylic acid ester unit (a) is structurally different from the (meth)acrylic acid ester unit (b?), thereby partly or entirely converting the (meth)acrylic acid ester unit (b?) into at least one selected from the group consisting of an N-substituted (meth)acrylamide unit (d), a (meth)acrylic acid unit (c), and an N-substituted bis((meth)acryl)amide unit (e).Type: GrantFiled: August 29, 2014Date of Patent: October 24, 2017Assignee: KURARAY Co., Ltd.Inventors: Masahiro Kawasaki, Isamu Okamoto, Eiji Nakamura
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Patent number: 9708515Abstract: The present invention relates to a process for the preparation of a radiation curable composition comprising at least one (meth)acrylic copolymer A and at least one radiation curable compound B, said process comprising a first copolymerization step, and a subsequent ring opening step.Type: GrantFiled: July 6, 2012Date of Patent: July 18, 2017Assignee: Henkel AG & Co. KGaAInventors: Graham Clark, Jurgen Van Holen
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Patent number: 9593173Abstract: A polymerization initiator system for reactive monomers and unsaturated polymers which is contains a Group 4 transition metal or Group 4 transition metal-containing compound, peroxide or diazo compound that is capable of being reduced by the Group 4 transition metal or Group 4 transition metal-containing compound, and pinacol compound is disclosed. Further disclosed are methods for preparing the polymerization initiator and using the polymerization initiator for low temperature curing.Type: GrantFiled: February 28, 2014Date of Patent: March 14, 2017Assignee: ELANTAS PDG, Inc.Inventors: Thomas James Murray, Heta S. Raval
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Patent number: 9487423Abstract: The present invention relates to partial decarboxylation of polyitaconic acid polymers or copolymers. The partially decarboxylated resins are suitable for use in preparation of dispersions as well as for anti-scaling applications.Type: GrantFiled: September 16, 2015Date of Patent: November 8, 2016Assignee: Itaconix CorporationInventors: Yvon Durant, Brian Luthi, John Shaw
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Publication number: 20150126657Abstract: The present invention includes a process for producing treated filler that includes (a) treating a slurry that includes untreated filler where the untreated filler has not been previously dried, with a treating composition that includes a treating agent, thereby forming a treated filler slurry, and (b) drying the treated filler slurry to produce treated filler. The treating agent can include a polymer having (i) at least one first group that interacts with the untreated filler and (ii) at least one second group that interacts with a rubber matrix into which the treated filler is incorporated. The present invention also is directed to treated filler prepared by the process, as well as rubber compounding compositions and tires including the treated filler.Type: ApplicationFiled: October 7, 2014Publication date: May 7, 2015Inventors: Timothy Allen Okel, Peter Lawrence Votruba-Drzal, Justin Jonathan Martin, Raphael O. Kollah, Truman Wilt, Brian K. Rearick, Clint Steven Edelman, Linda K. Anderson, Feng Wang, Kurt G. Olson
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Patent number: 9000086Abstract: The present invention relates to a thermally curable resin composition for a protective film including an alkoxy group-containing silane-modified epoxy resin as an essential component, a protective film of a color filter prepared from the same, and a liquid crystal display device including the same. The thermally curable resin composition for a protective film of the present invention includes an alkoxy group-containing silane-modified epoxy resin as an essential component to have excellent film strength and adhesive strength, and thus may be effectively used in a protective film of a color filter for a liquid crystal display device.Type: GrantFiled: July 12, 2011Date of Patent: April 7, 2015Assignee: LG Chem, Ltd.Inventors: Soon Chun Mok, Seung Hee Lee, Jong Hwi Hwang, Beom Su Park, Sung Hyun Kim
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Publication number: 20150080517Abstract: A method for making a thermoplastic material includes: (a) partially crosslinking an elastomer composition at a first crosslinking temperature to form a thermoplastic, partially crosslinked elastomer composition; (b) mixing a thermoplastic polymer composition with the thermoplastic, partially crosslinked elastomer composition and heating the mixture to a second crosslinking temperature higher than the first crosslinking temperature, wherein the thermoplastic polymer composition is liquid at the second crosslinking temperature; and (c) continuously mixing the mixture while further crosslinking the elastomer composition to form a thermoplastic material having a dispersed phase of crosslinked elastomer composition in the thermoplastic polymer composition. The elastomer composition may include an elastomer compounded with a curing agent and optionally additional components.Type: ApplicationFiled: September 17, 2013Publication date: March 19, 2015Applicant: NIKE, Inc.Inventor: John C. Chen
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Patent number: 8937133Abstract: The present invention discloses a dissoluble PDMS-modified p(HEMA-MAA) amphiphilic copolymer and the method of fabricating the same. The amphiphilic copolymer of the present invention is fabricated via chemically bonding HEMA, MAA, and poly(dimethylsiloxane), bis(3-aminopropyl) terminated (PDMS) in aqueous solution. The PDMS-modified p(HEMA-MAA) amphiphilic copolymer can be dissolved completely in polar solvents, particularly alcohol solvents, to facilitate subsequent processing. The amphiphilic copolymer features adjustable hydrophobic-hydrophilic properties and exhibits excellent biocompatibility. Thus, it can be utilized in a number of advanced applications, including anti-fouling and drug delivery.Type: GrantFiled: April 17, 2014Date of Patent: January 20, 2015Assignee: National Chiao Tung UniversityInventors: Dean-Mo Liu, Yun-Chun Huang, Chung-Yu Hsu
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Publication number: 20150014819Abstract: Provided is an underlying film composition for imprints showing a good adhesiveness with a base and capable of reducing failure or defect of resist pattern. The underlying film composition for imprints comprising a curable main component and a urea-based crosslinking agent.Type: ApplicationFiled: September 24, 2014Publication date: January 15, 2015Applicant: FUJIFILM CORPORATIONInventors: Akiko HATTORI, Hirotaka KITAGAWA, Yuichiro ENOMOTO, Tadashi OOMATSU
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Patent number: 8907017Abstract: The present invention relates to a process for the preparation of water-absorbing polymer structures, comprising the following process steps: I) providing an untreated, water-absorbing polymer structure; and II) bringing the untreated, water-absorbing polymer structure into contact with a salt comprising a divalent or higher-valent cation of a metal and at least one organic base as anion. The invention relates also to the water-absorbing polymer structures obtainable by that process, to water-absorbing polymer structures, to a composite comprising a water-absorbing polymer structure and a substrate, to a process for the preparation of a composite, to the composite obtainable by that process, to chemical products, such as foams, molded articles and fibers comprising water-absorbing polymer structures or a composite, to the use of water-absorbing polymer structures or of a composite in chemical products and to the use of a salt in the treatment of the surface of water-absorbing polymer structures.Type: GrantFiled: April 20, 2007Date of Patent: December 9, 2014Assignee: Evonik Degussa GmbHInventors: Mirko Walden, Harald Schmidt, Rainer Teni, Armin Reimann, Franck Furno, Jörg Issberner, Peter Herbe, Ursula Nielinger, Michael Keup
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Patent number: 8901223Abstract: This invention relates to polymers containing structural units derived from itaconic acid which are useful as binders for fiberglass.Type: GrantFiled: December 1, 2011Date of Patent: December 2, 2014Assignee: Lubrizol Advanced Materials, Inc.Inventors: John Ta-Yuan Lai, Gary A. Anderle, Ti Chou
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Patent number: 8883946Abstract: Here is provided a charge control resin which is prompt in charge rising up, excellent in electrostatic charging propensity and easy in manufacturing. This charge control resin contains a polymer as an active ingredient having a constituent unit represented by following Formula (1) in the Formula (1), R1 is independent of one another, and is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; R2 is a hydrogen atom, a hydroxyl group, a halogen atom, a carboxy-containing group, a straight-chained or branched alkyl group having 1-18 carbon atoms, or a straight-chained or branched alkoxy group having 1-18 carbon atoms; g is a number of 1-3; h is a number of 1-3; and M is a hydrogen atom, an alkali metal, a straight-chained or branched alkyl group having 1-18 carbon atoms, an ammonium radical or a mixture of any of these.Type: GrantFiled: May 17, 2012Date of Patent: November 11, 2014Assignee: Orient Chemical Industries Co., Ltd.Inventors: Masashi Yasumatsu, Kaori Inoue, Satoko Ozaki
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Publication number: 20140329961Abstract: Interpolymer resins having ethylene monomer residues and residues of a non-conjugated diene comonomer. The non-conjugated diene comonomer can be a dialkenyl phthalate. Incorporation of non-conjugated diene comonomers into interpolymers can provide additional labile unsaturation sites for cross-linking. The interpolymers and cross-linked variations thereof can be employed in a variety of articles of manufacture, such as, for example, as insulation material for power cables.Type: ApplicationFiled: November 21, 2012Publication date: November 6, 2014Applicant: Dow Global Technologies LLCInventors: Saurav S. Sengupta, Michael L. Smith, John O. Osby
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Publication number: 20140303315Abstract: The compositions of the present invention for accelerating the curing of thermosetting resins, including a) an organophosphine metal complex, optionally with a transition metal salt essentially free of cobalt; b) a tertiary amine, optionally with a quaternary ammonium or phosphonium salt; and c) a peroxide initiator.Type: ApplicationFiled: March 28, 2014Publication date: October 9, 2014Inventors: Hildeberto Nava, Anthony Skrobacki
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Patent number: 8816004Abstract: Oxazolinyl-containing compounds having a single oxazolinyl group plus a first polymeric group are described. Grafted compounds are also described that are the product of a reaction of an oxazolinyl-containing compound with a second compound that has one or more acidic groups to form a grafted compound. In some embodiments, the second compound is a polymeric material having at least one acidic group and the reaction product is a grafted copolymer. Blended compositions of the grafted copolymer with a polyamide are also described.Type: GrantFiled: December 7, 2011Date of Patent: August 26, 2014Assignee: 3M Innovative Properties CompanyInventors: Jason D. Clapper, Kevin M. Lewandowski
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Publication number: 20140228522Abstract: The present invention discloses a dissoluble PDMS-modified p(HEMA-MAA) amphiphilic copolymer and the method of fabricating the same. The amphiphilic copolymer of the present invention is fabricated via chemically bonding HEMA, MAA, and poly(dimethylsiloxane), bis(3-aminopropyl) terminated (PDMS) in aqueous solution. The PDMS-modified p(HEMA-MAA) amphiphilic copolymer can be dissolved completely in polar solvents, particularly alcohol solvents, to facilitate subsequent processing. The amphiphilic copolymer features adjustable hydrophobic-hydrophilic properties and exhibits excellent biocompatibility. Thus, it can be utilized in a number of advanced applications, including anti-fouling and drug delivery.Type: ApplicationFiled: April 17, 2014Publication date: August 14, 2014Applicant: National Chiao Tung UniversityInventors: Dean-Mo LIU, Yun-Chun HUANG, Chung-Yu HSU
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Patent number: 8801955Abstract: Disclosed are water-soluble nanoparticles. The water-soluble nanoparticles are each surrounded by a multifunctional group ligand including an adhesive region, a cross linking region, and a reactive region. In the water-soluble nanoparticles, the cross-linking region of the multifunctional group ligand is cross-linked with another cross-linking region of a neighboring multifunctional group ligand.Type: GrantFiled: July 16, 2012Date of Patent: August 12, 2014Assignee: Industry-Academic Cooperation Foundation, Yonsei UniversityInventors: Jin-Woo Cheon, Young-Wook Jun, Jin-Sil Choi
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Patent number: 8742013Abstract: The present disclosure provides polymer compounds binding with lipoamide produced by the reaction of the primary amine group of lipoamide with the carboxy group of polysaccharide compounds such as chondroitin sulfates, carboxymethyl celluloses, or hyaluronic acids; functional compounds such as peptides, proteins, growth factors; or drugs; or biocompatible polymers such as poly(ethylene oxide), poly(vinyl alcohol), or poly(vinyl pyrrolidone). The present disclosure also provides their synthesis methods, products of hydrogels and films using the same as and methods for manufacturing the products.Type: GrantFiled: October 29, 2009Date of Patent: June 3, 2014Assignee: Seoul National University of Technology Center for Industrial CollaborationInventors: Insup Noh, Seongyeun Jo, Doyeon Kim, Junghoon Woo
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Patent number: 8742027Abstract: The present invention relates to processes for manufacturing comb polymers having a principal (meth)acrylic chain and polyoxyalkylated lateral groupings, obtained by drying of a solution containing at least one homopolymer of (meth)acrylic acid and/or at least one copolymer of (meth)acrylic acid with at least one other monomer, followed by functionalisation of the intermediate dry product by esterification with at least one alkoxy polyoxyalkylene glycol, and/or amidification with at least one alkoxy polyoxyalkylene amine, or ethoxylation with at least one alkylene oxide.Type: GrantFiled: May 4, 2007Date of Patent: June 3, 2014Assignee: CoatexInventors: Jean Moro, Jean-Marc Suau, Yves Kensicher
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Patent number: 8716404Abstract: Disclosed is a thermoplastic composition comprising a poly(trimethylene terephthalate), or poly(butylene terephthalate), and about 0.2 to about 30 weight % of a modifier comprising fatty acid-modified ionomer where the ionomer is derived from an ethylene acid copolymer in which the combined acid moieties of the fatty acid and acid copolymer are at least partially neutralized with cations of magnesium, calcium, zinc, or a combination thereof.Type: GrantFiled: June 18, 2012Date of Patent: May 6, 2014Assignee: E I du Pont de Nemours and CompanyInventor: Charles John Talkowski
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Patent number: 8716421Abstract: This invention discloses and claims a series of polycyclic monomers and polymers useful in the production of optical waveguides. The polymers of the invention comprise one or more repeating units represented by the formula (IV): Wherein m, X, R1 and R2 are as defined herein. The films formed from the polymers of this invention exhibit significant changes in refractive index (greater than or equal to 0.5%) after exposure to suitable actinic or thermal energy thereby having superior optical transmission performance, which is of importance for modern optical applications such as wave guiding and optical data storage.Type: GrantFiled: May 23, 2013Date of Patent: May 6, 2014Assignees: Promerus, LLC, Sumitomo Bakelite Co., LtdInventors: Kazuyoshi Fujita, Nanae Kawate, Mari Ueda, Larry F Rhodes
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Publication number: 20140121328Abstract: A variety of polymers and copolymers suitable for use as biologically compatible constructs and, as a non-limiting specific example, in the formation of degradable tissue scaffolds as well methods for synthesizing these polymers and copolymers are described. The polymers and copolymers have degradation rates that are substantially faster than those of previously described polymers suitable for the same uses. Copolymers having a synthesis route which enables one to fine tune the degradation rate by selecting the specific stoichiometry of the monomers in the resulting copolymer are also described. The disclosure also provides a novel synthesis route for maleoyl chloride which yields monomers suitable for use in the copolymer synthesis methods described herein.Type: ApplicationFiled: January 6, 2014Publication date: May 1, 2014Applicant: STC.UNMInventors: Elizabeth L Hedberg-Dirk, Shawn Dirk, Kirsten Cicotte
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Publication number: 20140113990Abstract: The present invention provides a durable, external surfactant free, anionic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable acid-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.Type: ApplicationFiled: October 17, 2013Publication date: April 24, 2014Applicant: PENN COLOR, INC.Inventors: Michael D. Spiegel, Charles B. Rybny
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Patent number: 8697804Abstract: Disclosed is a composition comprising or produced from poly(trimethylene terephthalate), an ionomer of an ethylene acid copolymer comprising copolymerized units of at least one ?,?-ethylenically unsaturated carboxylic acid comonomer, a nucleating agent and optionally an ethylene ester copolymer. Also disclosed are articles prepared from the composition. Also disclosed is a process for preparing the compositions, including methods for controlling the melt viscosity and strain hardening of the compositions.Type: GrantFiled: December 16, 2010Date of Patent: April 15, 2014Assignee: E I du Pont de Nemours and CompanyInventor: Charles John Talkowski
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Publication number: 20140088259Abstract: The present invention discloses a dissoluble PDMS-modified p(HEMA-MAA) amphiphilic copolymer and the method of fabricating the same. The amphiphilic copolymer of the present invention is fabricated via chemically bonding HEMA, MAA, and poly(dimethylsiloxane), bis (3-aminopropyl) terminated (PDMS) in aqueous solution. The PDMS-modified p(HEMA-MAA) amphiphilic copolymer can be dissolved completely in polar solvents, particularly alcohol solvents, to facilitate subsequent processing. The amphiphilic copolymer features adjustable hydrophobic-hydrophilic properties and exhibits excellent biocompatibility. Thus, it can be utilized in a number of advanced applications, including anti-fouling and drug delivery.Type: ApplicationFiled: January 17, 2013Publication date: March 27, 2014Applicant: NATIONAL CHIAO TUNG UNIVERSITYInventors: Dean-Mo LIU, Yun-Chun HUANG, Chung-Yu HSU
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Patent number: 8658077Abstract: Oligoamines, such as a compound of the formula H2N(CH2CH2NH)nH in which n is an integer of 2-10, crosslink polymers containing carboxyl functionality unexpectedly faster than conventional diamines such as 1,6-diaminohexane. The combination of an ethylene-acrylic acid copolymer with an oligoamine of this type is useful for, among other things, the production of crosslinked wire and cable insulation.Type: GrantFiled: August 5, 2009Date of Patent: February 25, 2014Assignee: Dow Global Technologies LLCInventors: Bharat I. Chaudhary, Eric P. Wasserman
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Patent number: 8648150Abstract: The present invention is a method for producing a water absorbent resin which method is a method for producing surface cross-linked water absorbent resin particles, the method including the successive steps of: (a) adding a surface cross-linking agent and water to a particulate water absorbent resin in a mixer; and (b) reacting the resulting water absorbent resin mixture taken out from the mixer with the surface cross-linking agent in a reactor by heating or active energy ray irradiation, water vapor being used as part or all of the water added in the mixer. This makes it possible to provide a method for producing a water absorbent resin in which method a surface cross-linked water absorbent resin that has excellent properties can be obtained efficiently at low cost with high productivity.Type: GrantFiled: March 4, 2010Date of Patent: February 11, 2014Assignee: Nippon Shokubai Co., Ltd.Inventors: Kenji Kadonaga, Kenji Tada, Masazumi Sasabe, Seiji Kato
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Patent number: 8629218Abstract: The present invention is directed to curable film-forming compositions comprising a film-forming resin and a crosslinking agent. The film-forming resin contains a polymer having functional aromatic groups derived from functional aromatic acids. The present invention further provides multi-component composite coating compositions comprising a first film-forming composition applied to a substrate to form a primer or base coat, and a second film-forming composition applied on top of the primer or base coat to form a top coat, the top coat comprising the composition described above. Coating compositions prepared from the curable compositions of the present invention demonstrate superior gloss and acid etch resistance properties, making them ideally suited for automotive applications.Type: GrantFiled: May 13, 2010Date of Patent: January 14, 2014Assignee: PPG Industries Ohio, Inc.Inventors: Charles M. Kania, Lyle L. Foringer, Shiryn Tyebjee, Leigh Ann Humbert, Kevin C. Olson
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Patent number: 8618206Abstract: A process for producing water-absorbing polymer particles with low caking tendency and high absorption under pressure, comprising polymerization of a monomer solution or suspension, drying of the resulting polymer gel, grinding, classifying, thermal surface postcrosslinking and coating with silicon dioxide, wherein the water-absorbing polymer particles have been coated, before, during or after the surface postcrosslinking with aluminum cations.Type: GrantFiled: March 11, 2013Date of Patent: December 31, 2013Assignee: BASF SEInventors: Thomas Daniel, Christophe Bauduin, Norbert Herfert
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Patent number: 8604130Abstract: An adhesive composition includes a (meth)acrylic copolymer, the (meth)acrylic copolymer containing about 92 to about 99.7 parts by weight of a moiety derived from a (meth)acrylic acid ester monomer, and about 0.3 to about 8 parts by weight of at least one of a moiety derived from a carboxyl group-containing monomer and a moiety derived from a hydroxyl group-containing (meth)acrylic acid monomer, the (meth)acrylic copolymer having a weight average molecular weight of about 500,000 g/mol to about 2,000,000 g/mol, a carbodiimide curing agent, and an oligomeric silane coupling agent.Type: GrantFiled: July 5, 2011Date of Patent: December 10, 2013Assignee: Cheil Industries, Inc.Inventors: Hiroshi Ogawa, Tatsuhiro Suwa, Cheong Hun Song
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Patent number: 8579428Abstract: Disclosed are colorants comprising a colored laked complex of (a) a chromogen molecule having at least one (i) carboxylic acid group, (ii) carboxylate group, (iii) sulfonic acid group, (iv) sulfonate group, or (v) combination thereof, and (b) a polymer, said chromogen molecule and said polymer each being complexed to (c) a metal. Also disclosed are phase change inks containing the colorants.Type: GrantFiled: January 18, 2012Date of Patent: November 12, 2013Assignee: Xerox CorporationInventors: Jeffery H. Banning, Kelley A. Moore, Randall R. Bridgeman, Scott M. Broce, Stephan V. Drappel, Michael B. Meinhardt, Jule W. Thomas, Jr.
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Patent number: 8580898Abstract: The present invention relates to a copolymer polyester resin and a molded product using the same, and more specifically to a copolymer polyester resin that contains 10˜80 mol % of 1,4-cyclohexane dimethanol, 0.1˜50 mol % of a diol compound expressed as HO—(CH2)a—CO—(CH2)b—OH (where a and b are integers in the range 1˜5), and ethylene glycol or other diols so that the sum of its entire diol composition is 100 mol % based on dicarboxylic acid. The copolymer polyester resin of the present invention enables reduction of cycle time, improvement of product processability and prevention of PET bottle deformation during mold processing with a heat-shrinking label by complementing low temperature shrinkage, maintaining a high shrinkage rate, and reducing shrinkage stress.Type: GrantFiled: November 20, 2009Date of Patent: November 12, 2013Assignee: SK Chemicals Co., Ltd.Inventors: Myoung Ruoul Lee, Jong Ryang Kim
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Publication number: 20130273384Abstract: Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid.Type: ApplicationFiled: March 15, 2013Publication date: October 17, 2013Applicant: THE PROCTER & GAMBLE COMPANYInventors: Jane Ellen Godlewski, Janette Villalobos, Dimitris Ioannis Collias, Axel Meyer, Peter Dziezok, Juan Estaban Velasquez
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Publication number: 20130248753Abstract: This invention relates to polymers containing structural units derived from itaconic acid which are useful as binders for fiberglass.Type: ApplicationFiled: December 1, 2011Publication date: September 26, 2013Applicant: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: John Ta-Yuan Lai, Gary A. Anderle, Ti Chou
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Publication number: 20130253137Abstract: Oxazolinyl-containing compounds having a single oxazolinyl group plus a first polymeric group are described. Grafted compounds are also described that are the product of a reaction of an oxazolinyl-containing compound with a second compound that has one or more acidic groups to form a grafted compound. In some embodiments, the second compound is a polymeric material having at least one acidic group and the reaction product is a grafted copolymer. Blended compositions of the grafted copolymer with a polyamide are also described.Type: ApplicationFiled: December 7, 2011Publication date: September 26, 2013Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Jason D. Clapper, Kevin M. Lewandowski
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Publication number: 20130236528Abstract: The present invention provides an allergen inhibitor which effectively prevents allergens from reacting with specific antibodies, mitigates the allergic symptoms or prevents appearance thereof, and is less likely to cause unpredictable discoloration and discoloration under usual conditions. The allergen inhibitor of the present invention comprises an allergen-inhibiting compound including a linear polymer having at least one of substituents represented by the formulas (1) to (3) at a side chain. Thus, the allergen inhibitor of the present invention shows excellent allergen-inhibiting effects.Type: ApplicationFiled: April 25, 2013Publication date: September 12, 2013Applicant: Sekisui Chemical Co., Ltd.Inventors: Akihiko FUJIWARA, Taro SUZUKI, Mitsuhito TERAMOTO, Taro SUZUKI, Mitsuhito TERAMOTO
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Patent number: 8501308Abstract: Thermoplastic polymer compositions, films, continues, closures, laminates can comprise a modified vinyl polymer said modified polymer having a moiety comprising a cyclodextrin compound. The cyclodextrin compound, locked into the polymer structure, can absorb impurities, permeants, or other undesirable volatile materials. The cooperation between the cyclodextrin grafted onto the thermoplastic polymer and the polymer structure can provide barrier properties to a film, web or other polymer structure. A permeant or a contaminant can be complexed or trapped within the polymer and held within the film or Web preventing the permeant or contaminant from passing into the interior of a container or enclosure.Type: GrantFiled: April 13, 2006Date of Patent: August 6, 2013Assignee: Cellresin Technologies, LLCInventors: Willard E. Wood, Neil J. Beaverson, Kasyap V. Seethamraju
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Publication number: 20130184388Abstract: Disclosed are colorants comprising a colored laked complex of (a) a chromogen molecule having at least one (i) carboxylic acid group, (ii) carboxylate group, (iii) sulfonic acid group, (iv) sulfonate group, or (v) combination thereof, and (b) a polymer, said chromogen molecule and said polymer each being complexed to (c) a metal. Also disclosed are phase change inks containing the colorants.Type: ApplicationFiled: January 18, 2012Publication date: July 18, 2013Applicant: Xerox CorporationInventors: Jeffery H. Banning, Kelley A. Moore, Randall R. Bridgeman, Scott M. Broce, Stephan V. Drappel, Michael B. Meinhardt, Jule W. Thomas, JR.
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Patent number: 8487049Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.Type: GrantFiled: November 9, 2012Date of Patent: July 16, 2013Assignee: Evonik Stockhausen, LLCInventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
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Publication number: 20130172109Abstract: An object of the present invention is to provide a golf ball resin composition excellent in shot feeling and resilience. The golf ball resin composition includes (A) at least one resin component selected from the group consisting of (a-1) a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, (a-2) an ionomer resin consisting of a metal ion-neutralized product of the binary copolymer components, (a-3) a ternary copolymer composed of the binary copolymer components and an ?,?-unsaturated carboxylic acid ester, and (a-4) an ionomer resin consisting of a metal ion-neutralized product of the ternary copolymer components; and (B) a basic metal salt of a fatty acid, and having a storage modulus E? (Pa) and a loss modulus E? (Pa) satisfying a following expression; log(E?/E?2)??5.84 when measured in a tensile mode using a dynamic viscoelasticity measuring apparatus.Type: ApplicationFiled: December 27, 2012Publication date: July 4, 2013Applicant: DUNLOP SPORTS CO. LTD.Inventor: Dunlop Sports Co. Ltd.