Abstract: Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.

Abstract: The present invention provides novel, modified polydicyclopentadienes and methods to prepare modified polydicyclopentadienes. The modified polydicyclopentadienes prepared by the methods of the invention are useful in many applications including new and useful solid phases for chromatography.

Abstract: Described are a particular group of novel aromatic hydrocarbon telomers that, on bromination, result in the formation of novel flame retardants having a uniquely beneficial combination of properties. The resultant flame retardants and uses thereof are also described. The disclosure includes descriptions of methods for preparing both the aromatic hydrocarbon telomers and the brominated flame retardant polymers.

Abstract: A compound useful for reducing fouling in a hydrocarbon refining process is provided. A method for preparing the compound includes hydrohalogenating a polymer having a vinyl chain end to obtain a halogen-containing terminal group, and reacting the terminal group with a polyamine. Methods of using the compound and compositions thereof are also provided.

Abstract: The present invention relates to a method of reducing the amount of silicon on a surface of a contact lens, wherein the method includes reacting the surface of a contact lens containing at least one silicone component with a fluoride reagent.

Abstract: This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)?83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.

Abstract: The invention concerns polymer systems comprising at least one polymer with a plurality of pores where the polymer is initially functionalized on substantially all surfaces followed by a stepwise surface specific functionalization such that a different functional group resides on the external or internal pore surface of the bead. The invention also concerns use of such polymer systems in blood, blood product, or physiologic fluid purification.

Abstract: A flame retardant brominated rubber polymeric composition, wherein the composition can include ethylene propylene ethylidene norbornene rubber polymer and from 12 weight percent to 55 weight percent of bromine covalently bonded thereto. The method can include dissolving a liquid ethylene propylene ethylidene norbornene rubber polymer in hexane with myrcene, forming the composition. The method can include dissolving ethylene propylene ethylidene norbornene rubber polymer in hexane, forming a solution, and adding bromine, or blending N-bromo-succinimide into the solution, forming a suspension. The method can include heating the suspension and stifling the suspension until all bromine in the N-bromo-succinimide has reacted with the ethylene propylene ethylidene norbornene rubber polymer, forming the composition as a solid in a liquid. The method can include removing the liquid from the solid, and flashing off the hexane from the liquid to extract the composition.

Abstract: A process for the hydrolysis of polymers comprising vinylcarboxamide units by heating polymers comprising vinylcarboxamide units in an aqueous medium in the presence of acids or bases, wherein an aqueous solution or dispersion of a polymer comprising vinylcarboxamide units and an aqueous solution or a base or acid are fed continuously to a tubular reactor at elevated pressure, from 0.05 to less than one equivalent of a base or acid being used per vinylcarboxamide equivalent and the mixture being passed through the tubular reactor at a temperature of >100° C. to 250° C., depressurized and cooled.

Abstract: The invention relates to an energy efficient, environmentally favourable process for the preparation of halogenated rubbers, in particular chloro- and bromobutyl rubber, that uses a common aliphatic medium of specific composition for both solution polymerization and subsequent halogenation of the rubber. More particularly, the invention relates to a process that employs a common aliphatic medium for both solution polymerization and halogenation of rubber with intermediate removal of un-reacted monomers.

Abstract: Provided herein are telechelic polymers and methods for producing the same. In some embodiments, provided herein are compounds having the formula and methods for producing the same.

Abstract: A modified polysiloxane compound represented by formula (I): X(Y)n (I), where X represents a polymer block having a repeating unit represented by formula (II), Y represents a polymer block having a repeating unit represented by formula (III), and n represents 1 or 2, and having an X to Y weight ratio of 1/99?X/Y?90/10 and a number-average molecular weight of 1,000 to 100,000 is subjected to treat for elimination of a protecting group for a hydroxyl group by adding a non-aqueous solution containing hydrogen chloride in the presence of a non-aqueous solvent so that hydrogen chloride is 0.9 to 1.3 equivalents with respect to 1 equivalent of the repeating unit represented by formula (II).

Abstract: An aromatic ring-containing polymer for an underlayer of a resist, including a unit structure represented by Chemical Formula 1:

Abstract: The method for producing a modified conjugated diene based (co)polymer, according to the present invention comprises (a) obtaining a primarily modified polymer by carrying out a primary modification reaction wherein at least one member selected from the group consisting of an alkoxysilane compound and a silanol compound is introduced into the active alkali metal terminal of a conjugated diene based (co)polymer having an active alkali metal terminal, and (b) obtaining a secondarily modified polymer (a modified conjugated diene based (co)polymer) by subjecting the above-obtained primarily modified polymer to reactions comprising (b1) and (b2). (b1): a reaction with a condensation accelerator comprising a metal element. (b2): a reaction with at least one member selected from the group consisting of inorganic acids and metal halides.

Abstract: Butadiene polymers are brominated using tetraethylammonium tribromide as the brominating agent. The bromination is performed in a solvent for the starting polymer and for the tetraethylammonium bromide that is formed as a reaction byproduct. The process proceeds easily under mild conditions. In some cases, a solution of the brominated polymer and the tetraethylammonium monobromide is produced; this solution separates into a layer that contains the brominated polymer and another layer that contains most or all of the tetraethylammonium monobromide salt. In other cases, the brominated polymer precipitates from the reaction mixture and is separated from the tetraethylammonium monobromide salt in that manner. This process therefore permits the tetraethylammonium monobromide reaction by-product to be separated easily from the brominated product, and allows aqueous washing steps to be reduced or eliminated.

Abstract: A novel process of manufacturing sevelamer carbonate from a polyallylamine carbonate or bicarbonate chloride salt. Process for manufacture of carbonate and/or bicarbonate salts of water insoluble polymers containing amino groups that are useful as anion binders in the gastrointestinal (GI) system. The process arranges the polyallylamine chain in a solution in such a way that the cross-linking reaction with epichlorohydrin can be controlled at a desired reaction rate.

Abstract: A foamable fluoropolymer composition containing foam cell nucleating agent is provided, wherein the fluoropolymer comprises melt-fabricable tetrafluoroethylene-/hexafluoropropylene copolymer and tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, wherein the alkyl contains 1 to 4 carbon atoms, wherein the melting temperature of said tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer is no more than 35° C. greater than the melting temperature of said tetrafluoroethylene/hexafluoropropylene copolymer, and/or wherein said tetrafluoroethylene/hexafluoropropylene copolymer and said tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer each have a melt flow rate (MFR) within the range of 1 to 40 g/10 min and the MFR of one of said copolymers is at least twice that of the other of said copolymers.

Abstract: This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94(mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)?83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.

Abstract: The invention discloses improved processes to halogenate polymers. In particular, the invention discloses to improved processes to halogenate polymers made from C4-1012 isoolefins.

Abstract: Brominated styrenic polymer is recovered from solution in a vaporizable solvent by converting the solution in a devolatilization extruder into a brominated styrenic polymer melt or flow and a separate vapor phase comprised predominately of vaporizable solvent, recovering the melt or flow from the devolatilization extruder, and allowing or causing the melt or flow to solidify. The solidified brominated styrenic polymer can be subdivided into a powder or pelletized form. Pellets so made have improved hardness and/or crush strength properties along with reduced formation of fines. Brominated anionic styrenic polymer is preferably used in the process.

Abstract: Brominated styrenic polymer is recovered from solution in a vaporizable solvent by converting the solution in a devolatilization extruder into a brominated styrenic polymer melt or flow and a separate vapor phase comprised predominately of vaporizable solvent, recovering the melt or flow from the devolatilization extruder, and allowing or causing the melt or flow to solidify. The solidified brominated styrenic polymer can be subdivided into a powder or pelletized form. Pellets so made have improved hardness and/or crush strength properties along with reduced formation of fines. Brominated anionic styrenic polymer is preferably used in the process.

Abstract: An object of the present invention is to provide a rubber composition for a tire, which can achieve well-balanced improvement in fuel economy, abrasion resistance, and performance on ice and snow, and a studless tire for a passenger vehicle using the rubber composition. The present invention relates to a rubber composition for a tire, including a rubber component and silica, wherein the rubber component contains a modified natural rubber with a phosphorus content of 200 ppm or less, and butadiene rubber, and the silica has a CTAB specific surface area of 180 m2/g or more and a BET specific surface area of 185 m2/g or more.

Abstract: It is an object of the present invention to provide a modified polyolefin resin adhesive agent which is excellent in adhesiveness to a nonpolar substrate, particularly a poorly adhesive polyolefin substrate to which no surface treatment has been given and to a polar substrate, develops the excellent adhesiveness by drying or thermal compression bonding at relatively low temperature, and exhibits a low tack. That is, the present invention provides the modified polyolefin resin obtained by modifying a polyolefin resin with (A) a polarity imparting agent which is at least one selected from chlorine, unsaturated carboxylic acid, derivatives and anhydrides of unsaturated carboxylic acid and radical polymerizable monomers; and (B) an ethylene-?-olefin copolymer having an unsaturated bond at one end, and use of said modified polyolefin resin as an aqueous resin composition or an organic solvent resin composition.

Abstract: Butadiene copolymers are brominated using certain quaternary ammonium tribromides as the brominating agent. The bromination process proceeds easily under mild conditions, and produces a brominated product that has excellent thermal stability.

Abstract: Butadiene copolymers are brominated using certain quaternary ammonium tribromides as the brominating agent. The bromination process proceeds easily under mild conditions, and produces a brominated product that has excellent thermal stability. A quaternary ammonium monobromide salt is produced as a reaction by-product. A solvent for the monobromide salt is added to the reaction after 25-90% bromination of the aliphatic carbon-carbon double bonds. This provides for significantly shorter reaction times while providing a product with few impurities.

Abstract: A foamable fluoropolymer composition containing foam cell nucleating agent is provided, wherein the fluoropolymer comprises melt-fabricable tetrafluoroethylene-/hexafluoropropylene copolymer and tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, wherein the alkyl contains 1 to 4 carbon atoms, wherein the melting temperature of said tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer is no more than 35° C. greater than the melting temperature of said tetrafluoroethylene/hexafluoropropylene copolymer, and/or wherein said tetrafluoroethylene/hexafluoropropylene copolymer and said tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer each have a melt flow rate (MFR) within the range of 1 to 40 g/10 min and the MFR of one of said copolymers is at least twice that of the other of said copolymers.

Abstract: The method for producing a modified conjugated diene based (co)polymer, according to the present invention comprises a step of reacting a conjugated diene based (co)polymer with a metal halide compound to obtain a modified conjugated diene based (co)polymer, the conjugated diene based (co)polymer having a weight-average molecular weight of 150,000 to 2,000,000 and being obtained by bonding, to a polymer having at least a conjugated diene unit, an alkoxysilyl group and an optionally protected primary amino group. The method can satisfactorily produce a conjugated diene based (co)polymer which has a high Mooney viscosity, excellent shape stability and good processability.

Abstract: Processes for preparing Sevelamer Hydrochloride and Sevelamer Carbonate are described.

Abstract: Butadiene copolymers are brominated in solution using bromine as the brominating agent. The bromination is conducted in the presence of an excess of an aliphatic alcohol, relative to the amount of bromine that is used. The bromination proceeds rapidly at mild conditions, and is selective in that only aliphatic carbon-carbon double bonds are brominated, and unwanted bromination at tertiary carbon atoms is largely or completely avoided. The resulting brominated polymers are characterized in having very good thermal stability.

Abstract: The present invention is aimed to provide a highly-productive method for producing a stabilized fluoropolymer. The present invention relates to a method for producing a stabilized fluoropolymer, comprising the step of bringing a fluoropolymer to be treated into contact with a fluorinating agent to produce a stabilized fluoropolymer, while maintaining the concentration of hydrogen fluoride present in a reaction vessel at not higher than 1.0% by volume.

Abstract: Concurrently fed into a reaction zone held at about 10° C. or less are brominating agent, aluminum halide catalyst, and a solution of anionic styrenic polymer having a GPC Mn about 2000-30,000. The components are in at least two separate feed streams. The feeds are proportioned to maintain (a) the amount of aluminum halide being fed at about 0.8 mole percent or less based on the amount of aromatic monomeric units in the polymer being fed, and (b) amounts of brominating agent and unbrominated polymer in the reaction zone that produce a final washed and dried polymer product containing about 60-71 wt % bromine. The catalyst is deactivated, bromide ions and catalyst residues are washed away from the reaction mixture, and the brominated anionic styrenic polymer is recovered and dried. The dried polymer has a volatile bromobenzene content of about 600 ppm (wt/wt) or less as well as other beneficial properties.

Abstract: The present invention provides solvent- and water-based primer compositions that include at least one chlorinated carboxylated polyolefin that has been modified with one or more polyfunctional alcohols. The chlorinated carboxylated polyolefins are obtained by the reaction of polyolefins with at least one of unsaturated carboxylic esters, unsaturated carboxylic acids, unsaturated carboxylic anhydrides, acrylic monomers, and mixtures thereof then chlorinated. The chlorinated carboxylated polyolefins are then further modified by reaction with one or more polyfunctional alcohols. These polyfunctional alcohol-modified chlorinated carboxylated polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines or inorganic bases, thereby rendering the polyfunctional alcohol-modified chlorinated carboxylated polyolefins water-dispersible.

Abstract: Brominated polybutadiene polymers are recovered from a bromination reaction solution by forming the solution into droplets, thermally stripping the solvent from the droplets, and then washing the resulting particles. The washed particles are then recovered from the washing liquid. The droplets can be dispersed into a gaseous medium such as air and then transferred into a nonsolvent liquid for washing, or can be formed directly into the nonsolvent liquid. The process forms a particulate polymer material that is easily filterable and has low levels of volatile impurities and inorganic salts. Brominated polybutadiene polymers recovered in this manner are often very thermally stable.

Abstract: An emulsion aggregation polyester toner including a polyester resin having modified end groups, wherein the polyester resin includes at least one carboxylic end group. A process of making the toner by oxidation of a polyester resin including reacting the polyester with a hypohalite and a phase transfer catalyst results in a polyester resin endcapped with at least one acidic group. Stable xerographic charging in all ambient environments for all colors, and excellent resistivity and cohesion of the toner, may be achieved.

Abstract: The present invention provides a novel production process by which unstable terminal groups can be sufficiently stabilized under mild conditions. The present invention is related to a method for producing an —SO3H group-containing fluoropolymer wherein a fluoropolymer to be treated having a —SO2X group-containing monomer unit (X representing F or Cl) is subjected to a procedure comprising at least the steps A, B and C defined below in that order: A: Step of reacting with a halogenating agent; B: Step of reacting with a decomposition treatment agent; C: Step of reacting with a fluorinating agent.

Abstract: They are mixtures of (a) from 1 to 99.9% by weight of a water-soluble epihalohydrin-crosslinked polyamidoamine and (b) from 0.1 to 20% by weight of at least one other cationic polymer.

Abstract: Nonconjugated conductive polymers, which are all polymers that have a ratio of double bonds to total bonds of less than ½ are doped with iodine to produce compositions with unexpected characteristics in this invention. The mechanical and elastomeric properties of a nonconjugated polymer can be enhanced by doping the polymer with an electron acceptor such as iodine, in order to cure the polymer. Among the nonconjugated polymers are the cis-1,4-polyisoprene, cis-1,4 polybutadiene, styrene-butadiene copolymers (SBR), ethylene-propylene-diene monomer and poly (?-pinene). A heated mixture of iodine and sulfur produces a faster rate of vulcanization of rubber than using sulfur alone.

Abstract: At least partially hydrolyzed chlorosulfonated polyolefin elastomers containing 0.5-10 weight percent chlorine and 0.25 to 5 weight percent sulfur are prepared from low density polyethylene or from linear ethylene/alpha-olefin copolymer base resins having a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) less than 3.5.

Abstract: The present invention provides a method for producing a stabilized fluoropolymer which comprises producing the stabilized fluoropolymer by subjecting a treatment target substance containing a sulfonic-acid-derived-group-containing fluoropolymer to a fluorination treatment, wherein the sulfonic-acid-derived-group-containing fluoropolymer is a fluoropolymer containing —SO3M (in which M represents H, NR1R2R3R4 or M11/L; R1, R2, R3 and R4 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms; and M1 represents an L-valent metal), and the treatment target substance has a moisture content of not higher than 500 ppm by mass.

Abstract: The invention discloses improved processes to halogenate polymers. In particular, the invention discloses to improved processes to halogenate polymers made from C4-1012 isoolefins.

Abstract: In one aspect, the invention relates to silicone prepolymer compositions comprising a silicone prepolymer and a solvent. A soluble silicone prepolymer can be provided having increased average silicon content, thereby attaining a desired oxygen permeability. A solvent can be provided with a desired balance between hydrophilicity and hydrophobicity by selection and modification of the solvent molecular structure, resulting in molded polymer films and articles that exhibit minimal or nonexistent eye irritation and exhibit highly transparent products. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: Water-soluble functionalized cationic copolymers obtainable by a process which comprises reacting a cationic base polymer which contains amino groups with at least one functional compound reactive to at least a part of the amino groups on the base polymer, are useful in personal care and cosmetic formulations.

Abstract: A thermally stable brominated butadiene copolymer, such as brominated styrene/butadiene block copolymer, brominated random styrene/butadiene copolymer or brominated styrene/butadiene graft copolymer, preparation of the brominated butadiene copolymers, use of the brominated butadiene copolymers as a flame retardant additive and polymeric compositions, both foamed and non-foamed, that incorporate a flame-retarding amount of brominated butadiene copolymer.

Abstract: Partially neutralized chlorosulfonated polyolefin elastomers containing 0.5-10 weight percent chlorine and 0.25 to 5 weight percent sulfur are prepared from polyolefin elastomer base resins selected from the group consisting of propylene/ethylene copolymers, ethylene/propylene/diene copolymers, isobutylene/diene copolymers, isobutylene homopolymers, hydrogenated styrene/butadiene block copolymers and hydrogenated styrene/isoprene block copolymers.

Abstract: The present invention relates to compositions comprising poly-HEMA having a peak molecular weight between about 25,000 and about 100,000, preferably between 25,000 and 80,000 and a polydispersity of less than about 2 to less than about 3.8 respectively and covalently bonded thereon, at least one cross-linkable functional group. The present invention further relates to low polydispersity poly-HEMA suitable for making the crosslinkable prepolymers, processes for functionalizing and purifying said poly-HEMA to form said crosslinkable prepolymers, viscous solutions made from said crosslinkable prepolymers, hydrogels made from said viscous solutions and articles made from said crosslinkable polymers, hydrogels and viscous solutions.

Abstract: The present invention provides a novel production process by which unstable terminal groups can be sufficiently stabilized under mild conditions. The present invention is related to a method for producing an —SO3H group-containing fluoropolymer wherein a fluoropolymer to be treated having a —SO2X group-containing monomer unit (X representing F or Cl) is subjected to a procedure comprising at least the steps A, B and C defined below in that order: A: Step of reacting with a halogenating agent; B: Step of reacting with a decomposition treatment agent; C: Step of reacting with a fluorinating agent.

Abstract: It is an object of the present invention to provide a novel method for producing a fluoropolymer according to which unstable terminal groups can be sufficiently stabilized under mild conditions. This invention is related to a method for producing a stabilized fluoropolymer comprising subjecting a fluoropolymer to be treated containing no —SO2X (X representing F or Cl) group-containing monomer units to the following step A, step B and step C in that order: A: Step of reacting with a halogenating agent; B: Step of reacting with a degradation treatment agent; C: Step of reacting with a fluorinating agent.

Abstract: Brominated butadiene polymers are recovered from a bromination reaction solution by partially stripping the solvent to form a concentrated solution or slurry, and then recovering the brominated butadiene polymer from the concentrated solution or slurry. The process allows for a simplified, effective an economical recovery of the brominated butadiene polymer. Brominated butadiene polymers recovered in this manner are often very thermally stable.

Abstract: The residual chlorine content of a polyolefin-substituted carboxylic acylating agent formed by a halogen-assisted reaction of a polyalkene and at least one olefinic, monounsaturated mono- or dicarboxylic acid, anhydride or ester, is reduced when the reaction is conducted in the presence of a controlled amount of a metal compound.

Abstract: Disclosed is a composition, which may be melt extrudable, comprising polyvinylpyrrolidone-iodine complex in at least one polymer. Also disclosed is a process for preparing the composition or shaped articles, including films, made therefrom. The composition can be extruded, blown film extruded, or molded into films, fibers, tubing, and shaped articles thermoformed or molded shapes, including containers, usable, for instance, as catheters, in delivery systems for drugs and nutrients, specimen containers, or surgical devices.