Organic Amine Patents (Class 525/379)
  • Patent number: 11807704
    Abstract: Disclosed herein are a functionalized diene monomer-containing polymer containing first and second functionalizing groups, processes for preparing the functionalized polymer, and rubber compositions containing the functionalized polymer. The functionalized polymer contains polymer chains comprises of at least one conjugated diene monomer optionally in combination with at least one vinyl aromatic monomer wherein each polymer chain is functionalized at its chain end with at least the first functionalizing group and is coupled via the first functionalizing group to the second functionalizing group.
    Type: Grant
    Filed: December 13, 2018
    Date of Patent: November 7, 2023
    Assignee: Bridgestone Corporation
    Inventors: Yuan-Yong Yan, Zengquan Qin, Koichi Saito, Rita E. Cook
  • Patent number: 11807600
    Abstract: When a healthy and balanced diet is not achieved, nutritional supplements are used to help deal with the resulting health issues and enhance the body's performance. The present invention relates to a novel category of molecules that combine the properties of both ketone bodies and ?-Hydroxy ?-Methylbutyrate (HMB) that can be used as supplements for treating a wide range of health-related issues. Acetoacetate and ?-Hydroxybutrate along with isopentyldiol were used as the sources of ketone bodies and HMB, respectively. The present invention provides a method of synthesis for a new group of compounds that incorporate the properties found in acetoacetate and 3-hydroxybutyrate molecules with that of ?-hydroxy ?-methylbutyrate.
    Type: Grant
    Filed: November 12, 2021
    Date of Patent: November 7, 2023
    Inventors: Samuel J. Rozzoni, Daryl R. Sauer
  • Patent number: 11795315
    Abstract: This application pertains to group 5 metal complexes having the structure of Formula I: and their potential utility in catalyzing amination of polyolefins having alkene groups.
    Type: Grant
    Filed: January 11, 2019
    Date of Patent: October 24, 2023
    Inventors: Laurel L. Schafer, Sorin-Claudiu Rosca, Sabrina Scott
  • Patent number: 11733192
    Abstract: A sensor for carbon dioxide can include an amidine functional group.
    Type: Grant
    Filed: September 17, 2019
    Date of Patent: August 22, 2023
    Assignee: Massachusetts Institute of Technology
    Inventors: Timothy Swager, Bora Yoon, Gary Walsh
  • Patent number: 11639436
    Abstract: A high melt strength resin composition includes at least a) non-functionalized polypropylene, b) at least one acrylate such as zinc diacrylate, calcium diacrylate or aluminum triacrylate in a total amount of from 0.1 to 5% by weight based on the weight of non-functionalized polypropylene, and c) at least one acid neutralizer in a total amount of from 0.005 to 5% by weight based on the total weight of the at least one acrylate. The resin composition is compounded at a processing temperature between 185° C. and 260° C. to obtain the high melt strength polypropylene.
    Type: Grant
    Filed: March 25, 2021
    Date of Patent: May 2, 2023
    Inventors: Brett Robb, Steven A. Schwartz
  • Patent number: 11597796
    Abstract: An ionic aqueous epoxy curing agent, a preparation method therefor and the use thereof. The aqueous epoxy curing agent is prepared by reacting the following raw materials in parts by weight: a) 1 part of a polyepoxy compound, b) 1.3-6 parts of a multifunctional compound, c) 0.2 to 1.25 parts of a monoepoxy compound, and d) 0.01 to 0.23 parts of a sultone, wherein the multifunctional compound has four or more active hydrogens. The curing agent obtained has a good hydrophilic effect and very good thinning performance, the paint film prepared by mixing same with an epoxy dispersion has the following advantages: excellent salt spray resistance and water resistance, strong adhesion, high hardness, etc.; in addition, the preparation process of the curing agent is simple, the conditions are mild, and room temperature curing is carried out.
    Type: Grant
    Filed: April 19, 2019
    Date of Patent: March 7, 2023
    Assignees: WANHUA CHEMICAL GROUP CO., LTD., WANHUA CHEMICAL (NINGBO) CO., LTD.
    Inventors: Xiao Wang, Xueshun Ji, Weifei Li, Rui Qu, Chengbin Zhang, Junying Deng, Jiakuan Sun, Bin Zhou, Qiao Wang, Ji Gong
  • Patent number: 11498994
    Abstract: Provided is a block copolymer composition which contains a block copolymer having a specific molecular structure and has a molecular weight distribution within an appropriate range. A polymerizable composition containing a macromonomer (A) which has a group having a radical-reactive unsaturated double bond at one terminal of a poly(meth)acrylate segment, a vinyl monomer (B), and an organic iodine compound (C), or a polymerizable composition containing a macromonomer (A), a vinyl monomer (B), an azo-based radical polymerization initiator (E), and iodine is polymerized to obtain a block copolymer composition containing a block copolymer in which constitutional units of all blocks are derived from vinyl monomers and at least one block has a branched structure.
    Type: Grant
    Filed: November 22, 2018
    Date of Patent: November 15, 2022
    Assignees: Mitsubishi Chemical Corporation, Nanyang Technological University
    Inventors: Hiroshi Niino, Shunsuke Chatani, Shuyao Hsu, Atsushi Goto, Longqiang Xiao, Jun Jie Chang
  • Patent number: 11466110
    Abstract: The present invention relates to a semi-crystalline polyolefinic ionomer and a process for the preparation of a semi-crystalline polyolefinic ionomer.
    Type: Grant
    Filed: December 24, 2018
    Date of Patent: October 11, 2022
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Lidia Jasinska-Walc, Robbert Duchateau, Miloud Bouyahyi, Anton Ginzburg, Enrico Troisi
  • Patent number: 11447585
    Abstract: The present invention relates to a process for the manufacture of a functionalized ethylene and propylene copolymer composition. The invention further relates to such functionalized ethylene and propylene copolymer composition.
    Type: Grant
    Filed: December 24, 2018
    Date of Patent: September 20, 2022
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Miloud Bouyahyi, Lidia Jasinska-Walc, Robbert Duchateau
  • Patent number: 11440986
    Abstract: Provided are a solid electrolyte composition including: an inorganic solid electrolyte having conductivity of an ion of metal belong to Group 1 or 2 in the periodic table; and a high polymer binder, in which the high polymer binder is formed of a polymer having a hard segment and a soft segment, a binder for all-solid-state secondary batteries, and an electrode sheet for batteries and an all-solid-state secondary battery each using the solid electrolyte composition.
    Type: Grant
    Filed: January 30, 2020
    Date of Patent: September 13, 2022
    Assignee: FUJIFILM Corporation
    Inventors: Masaomi Makino, Hiroaki Mochizuki, Tomonori Mimura
  • Patent number: 11370852
    Abstract: Provided is method of treating a collection of resin beads (a) comprising the steps of (a) providing the collection of resin beads (a), wherein the resin beads (a) comprise one or more vinyl polymers having quaternary ammonium groups; wherein 90 mole % or more of the quaternary ammonium groups are each associated with a chloride anion; (b) bringing the collection of resin beads (a) into contact with an aqueous solution (b) comprising one or more dissolved (M)nXq to form a mixture (b), (c) separating water and compounds dissolved in the water from the mixture (b), to form resin beads (c) and waste solution (bw); (d) bringing resin beads (c) into contact with an aqueous solution (c) comprising dissolved (M3)(OH)p, to form a mixture (d).
    Type: Grant
    Filed: October 8, 2018
    Date of Patent: June 28, 2022
    Inventors: John C. Rohanna, Marvin H. Tegen, Alfred K. Schultz
  • Patent number: 10435550
    Abstract: Disclosed is a vapor permeable composition comprising a copolymer comprising copolymerized units of ethylene and copolymerized units of a comonomer providing an amine-reactive site; a short chain polymer having one primary amine active amine site, and comprising propylene oxide, ethylene oxide, or mixture thereof. The composition is useful as a vapor barrier for moisture control of buildings. Also disclosed are articles comprising the vapor permeable composition and methods of their use.
    Type: Grant
    Filed: December 18, 2014
    Date of Patent: October 8, 2019
    Assignee: PERFORMANCE MATERIALS NA, INC.
    Inventors: Richard T Chou, Loic Pierre Rolland
  • Patent number: 9546938
    Abstract: A composition, a kit, and a method of isolating a vesicle from a sample using a compound comprising zwitterion moieties, which may be used to analyze vesicles, and proteins, glycoprotein, lipids, or nucleic acids thereof.
    Type: Grant
    Filed: April 4, 2013
    Date of Patent: January 17, 2017
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Ga-hee Kim, Chang-eun Yoo, Ye-ryoung Yong, Myo-yong Lee
  • Patent number: 9309399
    Abstract: The present invention is to provide a pigment dispersion liquid which has excellent pigment dispersion stability and high productivity even in the case of using a fine pigment and having high pigment concentration; a method for producing the pigment dispersion liquid; a color resin composition which has excellent pigment dispersion stability, causes no clogging problem, has excellent adhesion, and is able to form color layers with high pigment concentration, with accuracy; and a color filter comprising the resin composition. Disclosed is a method for producing a pigment dispersion liquid, comprising the step of dispersing a pigment by mixing at least a pigment (A), a polymer (B) having tertiary or lower amines, an amine-reactive low molecular compound (C), and a dispersion medium (D), and dispersing the pigment (A) while reacting the polymer (B) with the low molecular compound (C), and a pigment dispersion liquid produced by the production method.
    Type: Grant
    Filed: October 19, 2010
    Date of Patent: April 12, 2016
    Assignee: DNP FINE CHEMICALS CO., LTD.
    Inventors: Masayo Konno, Yukie Kawazu, Yumi Saiki, Shoichi Komatsu, Syuichi Mitsuhashi, Shunsuke Shinozaki
  • Patent number: 9018267
    Abstract: Articles that contain a solid support with a grafted chain extending from the solid support, methods of making these articles, and various uses of the articles are described. More specifically, the grafted chain has a functional group that can react with or interact with target compound. Alternatively, the functional group on the grafted chain can react with a modifying agent to provide another group that can react with or interact with the target compound. The grafted chains are attached to the solid support through a ring-opened azlactone group. The articles can be used to purify the target compound or to separate the target compound from other molecules in a sample.
    Type: Grant
    Filed: April 16, 2014
    Date of Patent: April 28, 2015
    Assignee: 3M Innovative Properties Company
    Inventors: Simon K. Shannon, Catherine A. Bothof, Babu N. Gaddam, Jerald K. Rasmussen, Richard B. Ross
  • Patent number: 8981012
    Abstract: The present invention provides novel, modified polydicyclopentadienes and methods to prepare modified polydicyclopentadienes. The modified polydicyclopentadienes prepared by the methods of the invention are useful in many applications including new and useful solid phases for chromatography.
    Type: Grant
    Filed: July 8, 2009
    Date of Patent: March 17, 2015
    Assignee: University of Iowa Research Foundation
    Inventors: Ned B. Bowden, Mathew Perring
  • Publication number: 20150017459
    Abstract: There is described a method of preparing a post-modified polymer the method comprising the steps of: (1) polymerising a monomer composition comprising from 2.5 to 75% by weight of the total monomer composition of at least one itaconic anhydride, precursor thereof and/or derivative thereof in a polymerisation method to obtain an itaconate Polymer A; (2) reacting in a post modification step at least 10 mole-% of the anhydride groups, anhydride precursor groups and/or anhydride derived groups of the Polymer A obtained from step (1) with a Nucleophile B to form a post-modified Polymer C, and optionally using said polymer C as seed or stabiliser in a further step (3) to form a sequential Polymer D.
    Type: Application
    Filed: February 4, 2013
    Publication date: January 15, 2015
    Inventors: Tijs Nabuurs, Gerardus Cornelis Overbeek, Jeffrey Stubbs, Matthew Stewart Gebhard
  • Patent number: 8911516
    Abstract: A quaternized copolymer obtainable by: (A) copolymerization of straight-chain, branched or cyclic, ethylenically unsaturated C2 to C100 hydrocarbons, which may bear oxygen- or nitrogen-functional substituents which cannot be reacted with amines to give amides or imides or with alcohols to give esters, with ethylenically unsaturated C3- to C12-mono- or dicarboxylic acids or acid derivatives, which can be reacted with amines to give amides or imides or with alcohols to give esters, to give a copolymer with a number-average molecular weight of 500 to 20 000; (B) partial or full amidation or imidation or esterification of the carboxylic acid functions by reacting them with oligoamines having 2 to 6 nitrogen atoms or alcoholamines, each of which comprises primary or secondary nitrogen atom or a hydroxyl group and a quaternizable tertiary nitrogen atom; (C) partial or full quaternization of the tertiary nitrogen atom with a quaternizing agent.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: December 16, 2014
    Assignee: Basf SE
    Inventors: Wolfgang Grabarse, Hannah Maria Koenig, Christian Tock, Cornelia Roeger-Goepfert, Ludwig Voelkel, Harald Boehnke
  • Publication number: 20140350182
    Abstract: The invention provides for a process for removing thiocarbonylthio groups from polymer prepared by RAFT polymerisation, the process comprising: introducing into a flow reactor a solution comprising the RAFT polymer in solvent; and promoting a reaction within the flow reactor that removes the thiocarbonylthio groups so as to form a solution that flows out of the reactor comprising the RAFT polymer absent the thiocarbonylthio groups.
    Type: Application
    Filed: December 14, 2012
    Publication date: November 27, 2014
    Inventors: John Chiefari, Christian Hornung, Almar Postma, Simon Saubern
  • Patent number: 8895672
    Abstract: Provided herein are methods for preparing vinylidene-terminated polyolefins. Further provided herein are sulfide-terminated polyolefins.
    Type: Grant
    Filed: August 9, 2013
    Date of Patent: November 25, 2014
    Assignee: Chevron Oronite Company LLC
    Inventor: Casey D. Stokes
  • Patent number: 8883916
    Abstract: Disclosed is cross-linking process for cross-linking polymeric chains in a coating composition. In one embodiment the process utilizes a Hantzsch dihydropyridine reaction to form reaction products including cross-linking polymeric resin chains having beta-keto ester functions using a source of aldehyde and a source of ammonia or a primary amine to form a permanent dihydropyridine bond between the beta-keto ester functions. The novel cross-linking reaction can occur at lower temperatures compared to typical cross-linking reactions and can occur in aqueous solutions that have a neutral to mildly alkaline pH of from 6 to 11. The novel cross-linking reaction provides many advantages to performing cross-linking of polymeric chains in coating resins.
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: November 11, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Thomas S. Smith, II, Brian D. Bammel
  • Publication number: 20140329143
    Abstract: In a lithium ion battery, one or more chelating agents may be attached to a microporous polymer separator for placement between a negative electrode and a positive electrode or to a polymer binder material used to construct the negative electrode, the positive electrode, or both. The chelating agents may comprise, for example, at least one of a crown ether, a crown ether, a podand, a lariat ether, a calixarene, a calixcrown, or mixtures thereof. The chelating agents can help improve the useful life of the lithium ion battery by complexing with unwanted metal cations that may become present in the battery's electrolyte solution while, at the same time, not significantly interfering with the movement of lithium ions between the negative and positive electrodes.
    Type: Application
    Filed: July 21, 2014
    Publication date: November 6, 2014
    Inventors: Ion C. Halalay, Stephen J. Harris, Timothy J. Fuller
  • Publication number: 20140308503
    Abstract: A material for a surface modifying agent with which the problems of insufficient durability as abrasion and chemical resistances of surface modification effect in polyurethane surface modification by the prior surface modifying agent are resolved, and is immobilized in a matrix resin firmly and improved in durability. A reactive fluorine-containing highly branched polymer obtained by: polymerizing monomer A having in a molecule two or more radically polymerizable double bonds, monomer B having in a molecule a fluoroalkyl group and at least one radically polymerizable double bond, and monomer C having in a molecule an alcoholic hydroxy group and minimum, one radically polymerizable double bond, in presence of a polymerization initiator D in an amount of 5% to 200% by mole with respect to the number of moles of the monomer A; a curable composition containing the reactive fluorine-containing highly branched polymer; and a cured film obtained from the composition.
    Type: Application
    Filed: November 26, 2012
    Publication date: October 16, 2014
    Inventors: Hiroyasu Tamura, Masayuki Haraguchi, Masaaki Ozawa
  • Patent number: 8846823
    Abstract: A water absorbing agent and a method for producing the water absorbing agent are disclosed. Water absorbent resin particles having an internal cross-linked structure obtained by polymerizing a water-soluble unsaturated monomer, organic acid, and water-soluble multivalent metal salt are mixed, so that it is possible to provide a water absorbing agent which suppresses permeation of metal components into the water absorbent resin particles and enables the metal components to evenly adhere to an entire surface of the water absorbent resin in a dot manner.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: September 30, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Masatoshi Nakamura, Koji Miyake, Hirofumi Shibata
  • Patent number: 8840994
    Abstract: Methods for applying a liner-free, or liner-less label, to a substrate, particularly glass or plastic (e.g., PET) substrates are described herein. The method includes applying an adhesive composition, such as a polymeric coating, to a label face sheet, activating the adhesive composition with an activating fluid, and contacting the label to the substrate. The activating fluid is preferably a mixture of water and one or more organic solvents, such as low molecular weight alcohols. In some embodiments, the labels exhibit a percent fiber tear greater than about 50, 55, 60, 65, 70, 75, 80, 85, 90, or 95% after one, two, three, four, or five minutes. In particular embodiments, the labels exhibits a percent fiber tear greater than 60, 65, 70, 75, 80, 85, 90, or 95% after two minutes.
    Type: Grant
    Filed: January 10, 2013
    Date of Patent: September 23, 2014
    Assignee: NuLabel Technologies, Inc.
    Inventors: Daniel Cho, David A. Sonshine, Heidi Munnelly, Benjamin Lux
  • Patent number: 8822604
    Abstract: The invention provides a rubber composition for golf balls which includes: (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %; (B) an unsaturated carboxylic acid and/or a metal salt thereof; (C) an anthranilic acid derivative of the general formula wherein R1 and R2 are each independently a hydrogen atom or a hydrocarbon group of 1 to 20 carbons, m is an integer from 1 to 4, and n is an integer from 1 to 3, with the proviso that if m and/or n is 2 or more, each occurrence of R1 and R2 may be the same or different; and (D) sulfur. The rubber composition for golf balls of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.
    Type: Grant
    Filed: December 11, 2012
    Date of Patent: September 2, 2014
    Assignees: Bridgestone Sports Co., Ltd., Bridgestone Corporation
    Inventors: Yuichiro Ozawa, Tsuyoshi Nakajima, Yusuke Yamagata, Teppei Mori, Takahiro Iwai
  • Patent number: 8816005
    Abstract: The present invention provides a method for making a composition comprising an amphiphilic polymeric material which comprises a straight or branched chain carbon-carbon backbone and a multiplicity of side chains attached to the backbone; wherein in the method, backbone precursors comprising acylating groups are mixed with side chain precursors which comprise a nucleophilic group at at least one terminus, to form a reaction mixture; the backbone precursors, side chain precursors and/or the reaction mixture are heated; the reaction mixture is stirred; and the nucleophilic groups react with the acylating groups to form the amphiphilic polymeric material wherein the side chains are linked to the backbone via acyl linkages; characterized in that the reaction mixture does not comprise organic solvent.
    Type: Grant
    Filed: October 15, 2008
    Date of Patent: August 26, 2014
    Assignee: Revolymer Limited
    Inventors: Terence Cosgrove, Roger Pettman, Erol Hasan
  • Patent number: 8802788
    Abstract: Rubber composition for golf balls which includes: (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %; (B) an unsaturated carboxylic acid and/or a metal salt thereof; (C) an anthranilic acid derivative of the general formula wherein R1 and R2 are each independently a hydrogen atom or a hydrocarbon group of 1 to 20 carbons, m is an integer from 1 to 4, and n is an integer from 1 to 3, with the proviso that if m and/or n is 2 or more, each occurrence of R1 and R2 may be the same or different; and (D) an organic peroxide having a one-minute half-life temperature which is at least 158° C. and less than 175° C. The rubber composition for golf balls of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.
    Type: Grant
    Filed: December 11, 2012
    Date of Patent: August 12, 2014
    Assignees: Bridgestone Sports Co., Ltd., Bridgestone Corporation
    Inventors: Tsuyoshi Nakajima, Yuichiro Ozawa, Yusuke Yamagata, Teppei Mori, Takahiro Iwai
  • Patent number: 8779069
    Abstract: Disclosed herein are functionalized polymers comprising ethylene and substituted ethylene segments, which have been modified by epoxidation to enhance their crosslinking ability. These functionalized polymers are useful as film forming resins in cathodic electrocoating compositions. Also disclosed herein are aqueous dispersion compositions comprising the functionalized polymers and a process for coating various electrically conductive substrates.
    Type: Grant
    Filed: December 12, 2011
    Date of Patent: July 15, 2014
    Assignee: Axalta Coating Systems IP Co., LLC
    Inventors: Simona Percec, Susan H. Tilford
  • Patent number: 8742006
    Abstract: A cross-linkable nitrile rubber composition comprising a nitrile rubber (A1) including an ?,?-ethylenically unsaturated nitrile monomer unit and having iodine value of 120 or less, silica (B1) having CaO value determined by X-ray fluorescence composition analysis of 0.5 wt % or more, and a crosslinking agent (C1). According to the present invention, a cross-linkable nitrile rubber composition, capable of giving a highly-saturated cross-linked nitrile rubber having excellent mechanical properties such as elongation and small compression set, and excellent in workability, and a cross-linked rubber obtained by crosslinking the rubber composition can be provided.
    Type: Grant
    Filed: April 16, 2007
    Date of Patent: June 3, 2014
    Assignee: Zeon Corporation
    Inventors: Hiroyasu Nagamori, Shigeru Fujita
  • Patent number: 8735455
    Abstract: Articles that contain a solid support with a grafted chain extending from the solid support, methods of making these articles, and various uses of the articles are described. More specifically, the grafted chain has a functional group that can react with or interact with target compound. Alternatively, the functional group on the grafted chain can react with a modifying agent to provide another group that can react with or interact with the target compound. The grafted chains are attached to the solid support through a ring-opened azlactone group. The articles can be used to purify the target compound or to separate the target compound from other molecules in a sample.
    Type: Grant
    Filed: October 21, 2013
    Date of Patent: May 27, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Simon K. Shannon, Catherine A. Bothof, Babu N. Gaddam, Jerald K. Rasmussen, Richard B. Ross
  • Publication number: 20140142254
    Abstract: A method of forming a particle includes, in a disperse phase within an aqueous suspension, polymerizing a plurality of mer units of a hydrophilic monomer having a hydrophobic protection group, thereby forming a polymeric particle including a plurality of the hydrophobic protection groups. The method further includes converting the polymeric particle to a hydrophilic particle.
    Type: Application
    Filed: November 18, 2013
    Publication date: May 22, 2014
    Applicants: LIFE TECHNOLOGIES AS, LIFE TECHNOLOGIES CORPORATION
    Inventors: Geir FONNUM, Grete I. MODAHL, Nini H. KJUS, Astrid E. MOLTEBERG, Diem TRAN, Jo AASERUD, Talha M. GOKMEN, Steven M. MENCHEN, Carl FULLER, Luisa ANDRUZZI, Wolfgang HINZ
  • Patent number: 8728995
    Abstract: A polyalkenyl succinic anhydride is prepared with low amounts of resinous or chlorinated byproducts in a two-step process whereby a polyalkene is first reacted with an unsaturated organic acid in a thermal ene reaction, followed with exposure to a gaseous halogen in presence of an additional amount of the unsaturated organic acidic reagent. The foregoing process produces a polyisobutenyl succinic anhydride having a high ratio of succinic anhydride functional groups to polyisobutenyl backbone groups. Such a polyisobutenyl succinic anhydride is particular suitable for the production of oil-soluble hydrocarbyl succinimides that have good dispersant properties when added to lubricating oil compositions.
    Type: Grant
    Filed: January 19, 2011
    Date of Patent: May 20, 2014
    Assignee: Afton Chemical Corporation
    Inventors: Chente Huang, John T. Loper
  • Patent number: 8710156
    Abstract: The invention relates to functionalized, telechelic polymers synthesized by enzymatic catalysis and methods, and the functionalization of polymers via Michael addition with a lipase catalyst, and the crosslinking of mono- or difunctional (telechelic) polymers made by enzymatic catalysis, such as by using multifunctional coupling agents and enzyme catalysts. Quantitative transesterification of vinyl methacrylate with poly(ethylene glycol), poly(isobutylene) and poly(dimethylsiloxane) was achieved using Candida antarctica lipase B. In addition, methacrylate-functionalized poly(ethylene glycol) monomethyl ether has been successfully coupled to aminoethoxy poly(ethylene glycol) monomethyl ether via Michael addition using Candida antarctica lipase B. Amine-functionalized poly(ethylene glycol)s have also been used for the preparation of poly(ethylene glycol)-based dendrimers and gels through Michael addition of the polymer onto triacryloyl hexahydro-triazine using the same enzyme.
    Type: Grant
    Filed: March 26, 2010
    Date of Patent: April 29, 2014
    Inventors: Judit E. Puskas, Mustafa Yasin Sen
  • Patent number: 8703890
    Abstract: This invention provides a polyfunctional polymer having high stereoregularity, in particular, isotacticity, and provides a production process thereof. The present invention relates to a polymer having, in a molecule, a repeating unit represented by General Formula (2): wherein R1 and R2 are different, and each represents a hydrogen atom, an alkyl group and an aryl group; * represents an asymmetrical carbon, the polymer containing meso diad (m) and racemo diad (r) at a proportion of 60:40 to 100:0 (m:r). The invention also relates to chemical modifications and a production process of the polymer.
    Type: Grant
    Filed: January 25, 2010
    Date of Patent: April 22, 2014
    Assignee: The University of Tokushima
    Inventor: Hitoshi Tanaka
  • Publication number: 20140088262
    Abstract: This invention relates to a polyolefin comprising one or more aromatic moieties according to the following formulae: wherein the PO is the residual portion of a vinyl terminated macromonomer (VTM) having had a terminal unsaturated carbon of an allylic chain and a vinyl carbon adjacent to the terminal unsaturated carbon; Ar is attached to the terminal portion of the VTM to provide PO—Ar or at the vinylidene carbon of the VTM to provide PO—CH(Ar)CH3; and Ar is a substituted or unsubstituted aromatic group.
    Type: Application
    Filed: September 20, 2013
    Publication date: March 27, 2014
    Applicant: ExxonMobil Chemical Patent Inc.
    Inventors: Donna J. Crowther, Man Kit Ng, Suzzy C.H. Ho, Elizabeth L. Walker, Hong Cheng, Patrick Brant
  • Patent number: 8652335
    Abstract: A scavenger support and a process for removing metal from solution by contacting the solution with the scavenger support, whereby the scavenger support binds to at least some of the metal in solution thereby decreasing the amount of metal in solution. The scavenger support is a functionalised support having pendant groups selected from 1,3-ketoesters or 1,3-ketoamides or mixtures thereof having a structure according to formula 1, wherein a number of the pendant groups are reacted with an amine: wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; and R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group.
    Type: Grant
    Filed: May 2, 2012
    Date of Patent: February 18, 2014
    Assignee: Johnson Matthey Finland OY
    Inventors: David Alan Pears, Kevin Edward Treacher
  • Publication number: 20140046000
    Abstract: A method of accelerating a curing process in resin overflow systems for use in casting processes includes the step of adding a curing accelerator for the resin into the resin overflow system. In addition, a resin overflow container and a compartment with a curing accelerator for use in casting processes are provided.
    Type: Application
    Filed: July 25, 2013
    Publication date: February 13, 2014
    Inventors: Martin Jensen, Simon Kwiatkowski Pedersen
  • Patent number: 8642705
    Abstract: A process for producing a conjugated diene-based polymer which comprises, in the first modification, modifying a conjugated diene-based polymer having active chain ends, which is obtained by polymerizing a diene-based monomer singly or with other monomers and has a content of a cis-1,4 unit of 75% by mole or greater in the conjugated diene portion of the main chain, by reacting the active chain ends with a hydrocarbyloxysilane compound and reacting the modified polymer with a specific compound such as a hydrocarbyloxysilane compound, and a rubber composition containing the polymer modified in accordance with the above process and, preferably, 10 to 100 parts by weight of silica and/or carbon black per 100 parts by weight of the rubber component containing the modified polymer, are provided. The rubber composition containing silica and/or carbon black exhibits improved fracture properties, abrasion resistance, low heat buildup property and excellent workability.
    Type: Grant
    Filed: July 2, 2010
    Date of Patent: February 4, 2014
    Assignee: Bridgestone Corporation
    Inventors: Youichi Ozawa, Hajime Kondou, Noriko Endou
  • Publication number: 20140011961
    Abstract: The present invention relates to a solid precursor in the form of an organic salt, the solid precursor having a solid support, a method for manufacturing same, and an application thereof. The solid precursor of the present invention enables omission of the [18F]fluoride refining process using additional cartridge, and the use of excessive phase-transfer catalyst, and can easily remove remaining substance after reaction through the solid support inside the precursor. The solid precursor of the present invention is very appropriate for an automated synthesis device as an all-in-one system that can carry out overall process of [18F]fluorosis reaction, when used by charging in a cartridge.
    Type: Application
    Filed: December 13, 2011
    Publication date: January 9, 2014
    Inventors: Dae-Yoon Chi, Byoung-Se Lee, Jae-Hak Lee, So-Young Chu, Woon-Jung Jung, Hye-Rim Kwon
  • Patent number: 8623964
    Abstract: A room temperature crosslinkable polymer system comprising an anhydride containing polymer and an oxyalkylene amine and a polymer electrolyte derived therefrom are prepared and employed as ion conducting materials for batteries such as lithium ion battery, solar cells and electrochromic devices is disclosed.
    Type: Grant
    Filed: September 19, 2011
    Date of Patent: January 7, 2014
    Assignee: BASF SE
    Inventors: Zhiquang Song, Suruliappa G. Jeganathan, Jacqueline Lau, Rakesh Gupta
  • Publication number: 20130344023
    Abstract: A polymer includes at least one monomeric unit represented by Formula I, II, or III: where X is CH2 or O; R1 is H, COOR2, COCH3, CONHR2, OR2 or SR2; L is a bond or a linker group; AA is a group derived from an active agent; each R2 is independently H, a cation, an alkyl, an alkenyl, an alkynyl, COCH3, CH2CH2OH, CH2CH2OR3, an amino acid, a small peptide, a large peptide, enzyme, protein, growth factor, cytokine, antibody, single chain antibody, antibody fragment, COCCH3?CH2, COCH?CH2, CH2CO2H, CH2CH2CO2H, CH2CH2SH, CH2CH2SR3 or (CH2CH2O)n?R4; n? is an integer from 1 to 2000; each R3 is independently trityl, 4-methyltrityl or 2 pyridyl; each R4 is independently H, an alkyl, an alkenyl, an alkynyl, COCCH3?CH2, COCH?CH2, CH2CHO, CH2CH2CHO, CO2H, CO2R5, CH2CO2H, CH2CH2CO2H, CH2NH2, CH2NHR5, CH2N(R5)2, CH2CH2NH2, CH2CH2NHR, CH2CH2N(R5)2, SH, CH2CO2R5, or CH2CH2CO2R5; and each R5 is independently maleimide, a cation, an amino acid, a small peptide, a large peptide, protein, enzyme, growth factor, cytokine, antibody,
    Type: Application
    Filed: January 11, 2012
    Publication date: December 26, 2013
    Applicant: Flex-Biomedical
    Inventors: Michel Wathier, Hideki Suzuki
  • Publication number: 20130345367
    Abstract: The present invention relates to novel graft copolymers of functionalized poly(isoolefin-co-conjugated diolefin, and a process of preparing such graft copolymers. The present invention also relates to a method of preparing functionalized copolymers of isoolefins and conjugated diolefins.
    Type: Application
    Filed: August 11, 2011
    Publication date: December 26, 2013
    Applicants: UNIVERSITY OF WESTERN ONTARIO, LANXESS INC.
    Inventors: Goran Stojcevic, Lorenzo P. Ferrari, Dana K. Adkinson, Elizabeth R. Gillies, Collin V. Bonduelle, Solmaz Karamdoust
  • Publication number: 20130324665
    Abstract: A PIB derivative suitable for use as a fuel additive or lubricant additive prepared from a reactive low molecular weight polyisobutylene composition comprising at least 50 mol percent alpha vinylidene terminated polyisobutylene molecules, the composition having a polydispersity of no more than 1.5 and a number average molecular weight of at least 500 Daltons and no more than 1000 Daltons. The derivative is selected from the group consisting of: alkyl hydroxyaromatic compounds; alkyl alkoxy aromatic compounds; polyisobutenylsuccinic anhydrides; polyisobutenylsuccinimides; PIB-amine compounds; sulfurized PIB compounds; and Mannich condensation products of an alkylated hydroxyaromatic compound.
    Type: Application
    Filed: May 28, 2013
    Publication date: December 5, 2013
    Applicant: TPC Group LLC
    Inventors: Sohel K. Shaikh, Jennifer Leigh Sengstock
  • Patent number: 8598280
    Abstract: Process for preparing molding materials MM with improved optical and color properties, consisting of a polymer PM which contains units of the formula I in which R1 and R2 are each hydrogen and methyl and R3 is hydrogen, C1-C18-alkyl, C5-C8-cycloalkyl, C6-C10-aryl, C6-C10-aryl-C1-C4-alkyl, where these radicals may be up to trisubstituted by radicals selected from the group consisting of C1-C4-alkoxy and halogen, prepared in an imidation reaction known per se in a reactive extruder, in which, on completion of the imidation reaction, an amount of one or more reducing phosphorus compounds P which is effective for color stabilization is added to the polymer PM, characterized in that the phosphorus compounds are organic phosphorus compounds OP selected from the group consisting of compounds of the formula II in which R4 and R5 are each independently hydrogen or an aromatic 6-membered ring which may be up to pentasubstituted by a C1-C4-alkyl and/or C5-C8-cycloalkyl groups.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: December 3, 2013
    Assignee: Evonik Roehm GmbH
    Inventors: Victor Khrenov, Krzysztof Sado, Nils Mehler, Klaus Schultes, Klaus Albrecht
  • Patent number: 8592493
    Abstract: Articles that contain a solid support with a grafted chain extending from the solid support, methods of making these articles, and various uses of the articles are described. More specifically, the grafted chain has a functional group that can react with or interact with target compound. Alternatively, the functional group on the grafted chain can react with a modifying agent to provide another group that can react with or interact with the target compound. The grafted chains are attached to the solid support through a ring-opened azlactone group. The articles can be used to purify the target compound or to separate the target compound from other molecules in a sample.
    Type: Grant
    Filed: May 11, 2009
    Date of Patent: November 26, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: Simon K. Shannon, Catherine A. Bothof, Babu N. Gaddam, Jerald K. Rasmussen, Richard B. Ross
  • Patent number: 8586338
    Abstract: Ligand functionalized substrates, methods of making ligand functionalized substrates, and methods of using functionalized substrates are disclosed.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: November 19, 2013
    Assignees: 3M Innovative Properties Company, Wisconsin Alumni Research Foundation
    Inventors: Mark R. Etzel, Yi He, Steven M. Heilmann, Jerald K. Rasmussen, Kannan Seshadri, Simon K. Shannon, Clinton P. Waller, Jr., Douglas E. Weiss
  • Patent number: 8546492
    Abstract: The present invention provides a surface treatment method for a water-absorbing resin comprising three steps of: 1) a humidifying and mixing step for mixing a base polymer and a surface cross-linking agent solution to obtain a “humidified substance”; 2) a pretreatment step for raising temperature of said humidified substance to obtain a “pretreated substance”; and 3) a surface cross-linking reaction step for cross-linking said pretreated substance to obtain a surface cross-linked “water-absorbing resin”; wherein dew point in the pretreatment step of the above 2) is from 50° C. to 95° C., and temperature of said humidified substance is raised from temperature below the dew point up to a temperature of 10° C. higher than the dew point.
    Type: Grant
    Filed: April 10, 2009
    Date of Patent: October 1, 2013
    Assignee: Nippon Shokubai, Co., Ltd.
    Inventors: Atsushi Motoyama, Seiji Kato, Makoto Matsumoto, Takaaki Kawano, Yoshio Irie
  • Patent number: 8507641
    Abstract: Provided herein are methods for preparing vinylidene-terminated polyolefins. Further provided herein are sulfide-terminated polyolefins.
    Type: Grant
    Filed: February 12, 2013
    Date of Patent: August 13, 2013
    Assignee: Chevron Oronite Company LLC
    Inventor: Casey D. Stokes
  • Patent number: 8491770
    Abstract: Disclosed herein are functionalized polymers comprising ethylene and substituted ethylene segments. These functionalized polymers are useful as film forming resins in cathodic electrocoating compositions. Also disclosed herein are aqueous dispersion compositions comprising the functionalized polymers and a process for coating various electrically conductive substrates.
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: July 23, 2013
    Assignee: Axalta Coating Systems IP Co. LLC
    Inventors: Stephen Neal Bair, Simona Percec, Susan H. Tilford