Mixed With Carboxylic Acid Or Derivative Reactant Or Polymer Derived Therefrom Patents (Class 525/400)
  • Patent number: 6528582
    Abstract: A one-step, in-situ, process for producing a high solids content emulsion or dispersion of partially or totally crosslinked urea formaldehyde (UF), melamine formaldehyde (MF), or melamine urea formaldehyde (MUF) resin droplets or particles, by forming a reaction mixture of (i) aqueous formaldehyde (formalin), (ii) at least one water-soluble protective colloid, (iii) water and (iv) optionally a surfactant, and mixing the reaction mixture in a reaction vessel; optionally adjusting the initial pH of the reaction mixture according to a desired value as needed; adding (i) urea or substituted urea, (ii) melamine or substituted melamine, or (iii) a mixture thereof, to the reaction mixture; and heating the reaction mixture to a temperature at which condensation takes place between the (i) urea or substituted urea, (ii) the melamine or substituted melamine, or (iii) the mixture thereof, and the formaldehyde to form a urea formaldehyde, melamine formaldehyde or melamine urea formaldehyde resin, and holding the reaction
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: March 4, 2003
    Assignee: Neste Resins Canada
    Inventors: Kwok Tang, Guomin Bian, Leena Matilainen, Sinikka Ingelin
  • Patent number: 6512047
    Abstract: A polyoxymethylene resin composition, having enhanced tensile elongation, thermal stability, processibility and impact resistance, comprises: (i) from 45 to less than 97% % by weight of a polyoxymethylene resin (Component A); (ii) from 1 to less than 20% by weight of a thermoplastic polyester elastomer (Component B); (iii) from 2 to 35% by weight of a thermoplastic polyurethane elastomer (Component C); and (iv) from 0.1 to less than 10% by weight of a maleic anhydride-grafted aliphatic polyolefinic rubbery polymer (Component D), based on the total weight of Components A, B, C and D.
    Type: Grant
    Filed: May 15, 2001
    Date of Patent: January 28, 2003
    Assignee: Korea Engineering Plastics Co., Ltd.
    Inventors: Tak-Kyu Kim, Jong-Taek Lee, Ki-Chang Hong
  • Patent number: 6506838
    Abstract: Modified oxymethylene polymers comprising a linear polymer of oxymethylene repeat units, blocked at one end by at least one terminal group selected from the group consisting of an alkylene oxide as an adduct to alcohol and an alkylene oxide as an adduct to carboxylic acid, the linear polymer excluding the terminal group having a number average molecular weight of 10,000-500,000 and the modified oxymethylene polymer having a molecular weight distribution (Mw/Mn) of not more than 2.5, obtained by anionic polymerization of formaldehyde and the alkylene oxide as an adduct to alcohol and/or carboxylic acid. The present modified oxymethylene polymers can give moldings with improved repeated impact resistance at the welded parts and controlled smell generation, and improved sliding characteristics, wherein the sliding characteristics are further improved upon combination with an olefinic polymer.
    Type: Grant
    Filed: October 25, 2000
    Date of Patent: January 14, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventor: Toshiharu Seyama
  • Patent number: 6441104
    Abstract: The present invention provides: a process for producing a high molecular weight thermoplastic resin composition, which can give the high molecular weight thermoplastic resin composition with good reproducibility and stably; and uses of the resultant resin composition. The process for producing a high molecular weight thermoplastic resin composition comprises the step of mixing a thermoplastic resin with pyromellitic dianhydride to carry out a reaction therebetween to convert the thermoplastic resin into a high molecular weight one, and this process is characterized in that the pyromellitic dianhydride has at least one of the following properties in particle form: (1) intrinsically linear or needle-like particle forms; (2) a bulk density of 0.4˜0.9 g/ml; and (3) a rest angle of 50˜70 degrees.
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: August 27, 2002
    Assignee: Nippon Shokubai Co., Ltd.
    Inventor: Hiroyuki Ishida
  • Patent number: 6403725
    Abstract: Disclosed is a metal containing polymer composition comprising; a metal overbased imide or ester functionalized polymer prepared by reacting (A) a polymer comprising (A1) an acidic functionalized polymer or ester functionalized polymer; (A2) an acidic mixed ester-acid of a carboxy containing interpolymer; or (A3) an ester functionalized polymer comprising a lactone and (B) a metal overbased composition that contains a reactive basic functionality comprising (B1) a metal overbased amine wherein the reactive basic functionality is a primary or secondary amino group; (B2) a metal overbased hydroxy substituted carboxylic acid wherein the reactive basic functionality is a hydroxy group; or (B3) a metal overbased dispersant wherein the reactive basic functionality is a primary or secondary amino group.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: June 11, 2002
    Assignee: The Lubrizol Corporation
    Inventors: Nai Z. Huang, Richard M. Lange
  • Patent number: 6369183
    Abstract: A composition of matter, comprising: a chemically functionalized carboxylate-alumoxane that is functionalized with a chemically reactive substituent, and a reactive compound, wherein the chemically reactive substituent reacts with the reactive compound so as to link the carboxylate-alumoxane to the reactive compound and form a polymer matrix. The functional groups on the carboxylate-alumoxane can vary depending on the desired properties of the matrix. Also, the composition of matter may comprise a cross-linked matrix in which the cross-linked components consist of functionalized alumoxanes.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: April 9, 2002
    Assignee: Wm. Marsh Rice University
    Inventors: Ronald Lee Cook, Andrew Ross Barron, Kevin Joseph Gleason, David Brent MacQueen, Georgette Laila Siparsky, Yoshihiro Koide, Cullen Taylor Vogelson
  • Publication number: 20020040110
    Abstract: This invention involves a carbamate functional polymer or oligomer made by reacting a cyclic carbonate with ammonia or a primary amine, then reacting the resulting hydroxycarbamate with a polyfucnctional material containing groups reactive with hydroxyl groups to form a polyfunctional carbamate. The polymer formed is mixed with an aminoplast, coated on a substrate and cured to form a crosslinked coating.
    Type: Application
    Filed: December 22, 2000
    Publication date: April 4, 2002
    Inventors: Dean C. Webster, Allen L. Crain
  • Patent number: 6245853
    Abstract: A one-step, in-situ, process for producing a high solids content emulsion or dispersion of partially or totally crosslinked urea formaldehyde or melamine formaldehyde resin droplets or particles, by forming a reaction mixture of (i) aqueous formaldehyde (formalin), (ii) at least one water-soluble protective colloid, (iii) water and (iv) optionally a surfactant, and mixing the reaction mixture in a reaction vessel; optionally adjusting the initial pH of the reaction mixture according to a desired value as needed; adding (a) urea, substituted urea, or a mixture thereof, or (b) melamine, substituted melamine, or a mixture thereof, to the reaction mixture; and heating the reaction mixture to a temperature at which condensation takes place between the (a) urea, substituted urea, or the mixture thereof, or (b) melamine substituted melamine, or the mixture thereof, and the formaldehyde to form a urea formaldehyde or melamine formaldehyde resin, and holding the reaction mixture at that temperature or a higher tempera
    Type: Grant
    Filed: May 16, 2000
    Date of Patent: June 12, 2001
    Assignee: Neste Resins Canada
    Inventors: Kwok Tang, Guomin Bian, Leena Matilainen, Sinikka Ingelin
  • Patent number: 6200683
    Abstract: The invention pertains to compositions which can be coated onto substrates. These compositions include a combination of a resin blend comprising a first polyester resin and a second polyester resin, wherein the first polyester is different from the second polyester, an aminoplast crosslinking resin, an acid catalyst, and a urea-aldehyde resin. Films prepared from coating compositions made in accordance with the present invention having improved stain resistance. In many instances, films prepared from coating compositions made in accordance with the present invention not only have improved stain resistance, but also have low temperature flexibility.
    Type: Grant
    Filed: December 16, 1994
    Date of Patent: March 13, 2001
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Robert A. Montague, W. Scott Huffman, Jamel S. Richardson, Padmanabhan Sundararaman
  • Patent number: 6046285
    Abstract: Polymer blends obtainable by thermal treatment, at not less than 150.degree. C., of a mixture containing at least one high-performance polymer and from 15 to 99 parts by weight or preferably from 40 to 90 parts by weight and particularly preferably from 55 to 75 parts by weight, of a polymer containing sulfoxide groups, and crosslinked or partly crosslinked polymer blend obtainable by thermal treatment, at not less than 150.degree. C., of a mixture containing at least one of the high-performance polymers polyesters, partly fluorinated polymers, polyethersulfones, polysulfones, polyetherimides, polyamidoimides or polyacetals and at least one polymer containing sulfoxide groups, are distinguished by high thermal and chemical stability. Polymers containing sulfoxide groups are polyarylene sulfoxides, in particular polyphenylene sulfoxide. The polymer blends are used for the production of fibers, films or shaped articles.
    Type: Grant
    Filed: September 3, 1997
    Date of Patent: April 4, 2000
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Helmut Scheckenbach
  • Patent number: 6010760
    Abstract: A thermoplastic resin composition comprising a thermoplastic resin (A) not forming an anisotropic melt phase and a liquid crystal polymer (B) capable of forming an anisotropic melt phase, an injection molding method thereof and an injection molded article capable of providing a thin molded article having excellent mechanical strength. A thermoplastic resin composition (C) comprises 99 to 50 wt. % of the thermoplastic resin (A) and 1 to 50 wt. % of the liquid crystal polymer (B). The liquid crystal polymer (B) is microscopically dispersed in an island form in the matrix phase of the thermoplastic resin (A) so that when the composition (C) is heat-treated at a temperature not lower than the melting point of the liquid crystal polymer (B) under a non-load state and is then cooled, the liquid crystal polymer (B) has a weight average particle diameter within the range of 10 to 40 micrometers and at least 80 wt. % thereof has a particle diameter within the range of 0.5 to 60 micrometers.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: January 4, 2000
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hirotaka Miyazaki, Tomoyuki Aketa, Haruji Murakami, Takayuki Ishikawa, Kazuhito Kobayashi, Ayako Migita
  • Patent number: 5973081
    Abstract: A modified polyacetal is obtainable by heating 0.1 to 30 parts by weight of (B) a polymerizable compound having a modifying group such as an epoxy group, a carboxyl group or an acid anhydride group relative to 100 parts by weight of (A) a base polyacetal and introducing the modifying group of the polymerizable compound to the base polyacetal. The base polyacetal (A) includes (A1) a polyacetal selected from polyoxymethylene homopolymers and copolymers, and (A2) a polymerizable polyacetal having a functional group comprising a polymerizablly unsaturated bond. The introduction efficiency of the modifying group can be enhanced by adding 0.01 to 2.5 parts by weight of (C) a free-radical initiator relative to 100 parts by weight of the total amount of the components (A) and (B), and mixing the resultant mixture under a molten state of the polyacetal. According to such method, the affinity of the polyacetal is improved by introducing the modifying group to the base polyacetal with ease and high efficiency.
    Type: Grant
    Filed: June 7, 1996
    Date of Patent: October 26, 1999
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hiroyuki Kanai, Hajime Serizawa, Katsuhei Ohnishi, Eiji Masuda, Kaoru Yamamoto
  • Patent number: 5965670
    Abstract: Curable film-forming compositions comprising acrylic polyols, aminoplast and carbamoyl triazines are disclosed. The compositions are useful as clear coats in composite color-plus-clear coatings.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: October 12, 1999
    Assignee: PPG Industries Ohio, Inc.
    Inventors: George W. Mauer, William E. Michael, John W. Burgman, Leigh-Ann Humbert
  • Patent number: 5958398
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: September 28, 1999
    Assignee: The General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5955561
    Abstract: Novel hydroxy ester, hydroxy amide, and amide functional compounds are provided comprising the reaction product of:(a) an active ester functional material having the structure: ##STR1## wherein R.sup.1 is derived from a polyisocyanate; m is at least 2; R.sup.2 is a lower alkyl or alkoxy group; and R.sup.3 is a lower alkyl group; and(b) ammonia, a diol, or an amino functional material having the structure:R.sup.4 --NH--(R.sup.5).sub.x --(R.sup.6 OR.sup.7).sub.ywherein R.sup.4 is --H or alkanol; R.sup.5 is a polyvalent linking group comprising alkylene, alkylamino, urethane, or amido; x is 0 or 1; R.sup.6 is a divalent linking group comprising alkylene, silane, or siloxane; R.sup.7 is H or a lower alkyl; and y is 1 to 3. The compound is useful in curable film-forming compositions.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: September 21, 1999
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Padmanabhan Sundararaman
  • Patent number: 5863879
    Abstract: The use of polymers which are preparable by reaction of(a) polymers that contain vinylamine units, with(b) compounds that contain aldehyde or keto groups, and optionally(c) NH- and/or OH-containing compoundsand which contain aminal, hemiaminal and/or aminal-acetal structures with or without unconverted vinylamine units, as detergent additive for inhibiting dye transfer during the wash, and polymers containing aminal, hemiaminal and/or aminal-acetal structures, obtainable by reaction of(a) polymers that contain vinylamine units, with(b) compounds that contain aldehyde or keto groups, and(c) NH- and/or OH-containing compounds,and detergents which contain the abovementioned polymers in amounts from 0.05 to 10% by weight.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: January 26, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Zirnstein, Wolfgang Trieselt, Knut Oppenlander, Claudia Nilz, Michael Kroner, Wolfgang Gunther
  • Patent number: 5863990
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: June 9, 1997
    Date of Patent: January 26, 1999
    Assignee: The General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5859147
    Abstract: A polyamide composition which is amorphous and transparent, which has reduced flammability, and which has reduced migration of flame-retardant additive so that it is film-free, includes at least one polyamide which contains cycloaliphatic monomer units and which is amorphous and transparent; and a flame-retardant additive which is present in an amount effective to reduced flammability of the polyamide composition, which is dissolved in the at least one polyamide, and which is at least one alkyl phosphonic acid compound having a general formula: ##STR1## wherein R and R' each represent, independent of each other, an alkyl group having from 1 to 4 carbon atoms, and x=0 or 1. An article molded from this composition is transparent, has reduced flammability, and has reduced migration of flame-retardant additive so that it is film-free.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: January 12, 1999
    Assignee: EMS-Inventa AG
    Inventors: Hans Dalla Torre, Manfred Hewel
  • Patent number: 5852135
    Abstract: A resin composition comprises (1) a thermoplastic resin and (2) a modified polyacetal wherein a residue of a polymerizable compound having a functional group such as an epoxy group, a carboxyl group, an acid anhydride group or others is introduced to a base polyacetal in a proportion of 0.1 to 30% by weight relative to the base polyacetal. The thermoplastic resin includes various polymers such as an olefinic polymer, a styrenic polymer, a polyester, a polyamide and so on. The thermoplastic resins can be used singly or in combination, and the latter combination includes a combination of two or more species of resins being immiscible with each other, a combination of a polyacetal and a resin except for a polyacetal (e.g. an elastomer, etc.) and other combinations. The relative ratio of (1) the thermoplastic resin to (2) the modified polyacetal is such that the former/the latter equals about 1/99 through 99/1 (by weight).
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: December 22, 1998
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hiroyuki Kanai, Hajime Serizawa, Mitsunori Matsushima
  • Patent number: 5811510
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: April 14, 1995
    Date of Patent: September 22, 1998
    Assignee: General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5756594
    Abstract: Polymers which contain polyacetal blocks are obtainable by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the polymers with at least bifunctional crosslinking agents in the presence of acids or Lewis acids and, if required hydrolyzing the ester groups present as polymerized units, process for the preparation of the polymers containing polyacetal blocks by polymerizing carboxylates containing aldehyde groups in the presence of initiators and reacting the resulting polyacetals containing terminal hydroxyl groups with at least bifunctional crosslinking agents in the presence of acids or Lewis acids, and the use of the resulting polymers as additives in phosphate-free and reduced phosphate detergents and cleaning agents, as scale inhibitors and as dispersants for pigments.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: May 26, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Dieter Boeckh, Matthias Kroner, Richard Baur, Alexander Kud, Gunnar Schornick, Volker Schwendemann
  • Patent number: 5723243
    Abstract: An electrophotographic photoconductor includes an electroconductive support, and a photoconductive layer formed thereon containing as an effective component an aromatic polycarbonate resin having a repeat unit of formula (I), or two repeat units of formula (II) and formula (III): ##STR1## wherein n, Ar.sup.1, Ar.sup.2, Ar.sup.3, R.sup.1, R.sup.2 and X are as specified in the specification, ##STR2## wherein k and j are also as specified in the specification.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: March 3, 1998
    Assignees: Ricoh Company, Ltd., Hodogaya Chemical Co., Ltd.
    Inventors: Masaomi Sasaki, Hiroshi Tamura, Tomoyuki Shimada, Tetsuro Suzuki, Chiaki Tanaka, Kouji Kishida, Akira Katayama, Kazukiyo Nagai, Chihaya Adachi, Nozomu Tamoto, Mitsutoshi Anzai, Akihiro Imai
  • Patent number: 5686532
    Abstract: A binder composition, a coating composition containing this binder, a process for its production and use to produce single or multi-layer lacquer coatings, particularly in the automotive sector, are described. The binder composition containsA) 25 to 75 wt. % of the reaction product of one or more carboxy-functionalised poly(meth)acrylic copolymers and/or one or more carboxy-functionalised polyesters, each with an acid value of 15 to 200 mg KOH/g, with one or more lactones,B) 25 to 75 wt. % of one or more epoxy-functionalised crosslinking agents with at least two epoxy functional groups per molecule, with a number average molecular weight (Mn) of 200 to 10000 g/mol,C) 0 to 60 wt. % of one or more polyols with at least two hydroxyl functional groups per molecule,D.sub.1) 0 to 20 wt. % of one or more melamine resins,D.sub.2) 0 to 40 wt. % of one or more capped polyisocyanates, wherein the sum of the weight percentages of components A), B), C), D.sub.1) and D.sub.2) is 100 wt. %, together withE) 0 to 10 wt.
    Type: Grant
    Filed: June 16, 1995
    Date of Patent: November 11, 1997
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Bederke, Volker Duecoffre, Carmen Flosbach, Eva Frigge, Walter Schubert, Friedrich Herrmann
  • Patent number: 5681906
    Abstract: The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di- or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a crosslinking agent such as a methylol (alkoxymethyl) amino crosslinking agent, and a reactive additive which is the ester reaction product of a phenol carboxylic acid, preferably para-hydroxybenzoic acid, and an epoxy compound selected from glycidyl ethers, glycidyl esters, linear epoxies and aromatic epoxies. The crosslinkable compositions of this invention may be used to prepare curable coating and paint formulations, and also may contain other ingredients such as a crosslinking catalyst, fillers, pigments and the like. When cured, the coatings of this invention exhibit improved physical and chemical properties when compared with cured coatings which do not contain the ester reaction product additive.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: October 28, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Albert Ilya Yezrielev, Vijay Swarup, Konstantinos R. Rigopoulos
  • Patent number: 5646214
    Abstract: An adherent film-forming composition comprising a carbamate-functional polyester polymer or oligomer, a hydroxy functional polymer derived from ethylenically unsaturated monomers and an aminoplast crosslinking agent is disclosed. The coating composition can be used to produce clear coats in composite color plus clear coatings exhibiting good levels of acid etch resistance as well as high intercoat adhesion. Also disclosed are a method of applying a composite color plus clear coating to a substrate and the coated article prepared by such a method.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: July 8, 1997
    Assignee: PPG Industries, Inc.
    Inventor: Michael A. Mayo
  • Patent number: 5623020
    Abstract: This invention provides a novel cross-linked polyaniline derivative soluble or capable of swelling in general organic solvents, which forms an elastic self-standing film or fibers. The polyaniline derivative substantially comprises a polyaniline having number average molecular weight in a range of from 2,000 to 500,000 represented by the following formula (I) as the main polymer chain, ##STR1## wherein m and n are 0 or an integer of at least 1, m/(m+n)=0-1, and m+n=10-5,000, and cross-linking units represented by the following formula (II) ##STR2## wherein X is a direct bond, a substituted or unsubstituted divalent C.sub.1 -C.sub.30 aliphatic hydrocarbon group, a substituted or unsubstituted divalent aromatic hydrocarbon group, a divalent polysiloxane group or a group derived therefrom, or a divalent group derived from a compound having 2 or more repeating structural units, y.sup.1 and y.sup.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: April 22, 1997
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventor: Osamu Oka
  • Patent number: 5580931
    Abstract: A method for property modification of bulk polymers, by initially treating a short chain monomeric organic acid, having a carboxylic group (with dissociation constant between 10.sup.-2 to 10.sup.-6 cm.sup.-1, and less than 8 carbons); with a Group IA, IIA or IIB metal, metal oxide, peroxide, hydroxide, or halogens, for forming a metal ligand or complex metal salt of the acid. The bulk polymers are mixed with the complex metal salts and free radicals are introduced into the mixture by means of oxidizing materials, to functionalize the bulk polymer with ionic polymerization sites. A copolymer formation is effected between the monomeric organic metal salt anion and the bulk polymer, as catalyzed by the metal cation, at such sites. The polymerization is a substantially non-cross linked ionic one resulting from the dissociation parameters and the short chain length of the complex metal salt, which is maintained prior to copolymer formation.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: December 3, 1996
    Assignee: Nathaniel H. Garfield
    Inventor: Juan E. Aguirre
  • Patent number: 5559180
    Abstract: A polyacetal composition is provided for use in plastic-plastic wear applications, said composition containing about 85 to 99 weight percent polyacetal, about 0 to 5 weight percent polytetrafluoroethylene fibers, about 0.5 to 5 weight percent ethylene methyl acrylate copolymer, and about 0.5 to 5 weight percent of at least one lubricant. The compositions are particularly useful in forming shaped articles for use especially in conveyor chain applications and gear applications.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: September 24, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Tatsuhiro Takahashi, Edmund A. Flexman, Robert J. Kassal
  • Patent number: 5492998
    Abstract: Novel polymers of general formula: ##STR1## wherein R is an alkyl or aryl group that contains an active hydrogen atom (as determined by the Zerewitinoff test); A is a spacing group having at least one carbon atom; B is a spacing group having at least two carbon atoms; and R and R' are alkyl or aryl groups. The polymer is synthesized via the Mannich pathway, involving formation of an imine intermediate.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: February 20, 1996
    Assignees: Lifesource International, Ltd., Jojani Inc.
    Inventor: Nicholas M. Irving
  • Patent number: 5489448
    Abstract: A water-free, water-free reducible primer composition having a volatile organic content of less than 3 pounds per gallon yields a tough, flexible, and weatherable film when applied to metal or plastic substrates. The base resin is a polyester having an acid number of from about 50 to about 60 and a hydroxyl number of from about 160 to about 200. The polyester is the reaction product of from about 0.45 to about 0.5 mole % of adipic acid, from about 0.35 to about 0.4 mole % of neopentyl glycol, and from about 0.15 to about 0.2 mole % of trimethylolpropane.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: February 6, 1996
    Assignee: Bee Chemical Company
    Inventors: Michael L. Jackson, Frank A. Stubbs, Joseph M. Mecozzi, Dean T. Smith
  • Patent number: 5478888
    Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: December 26, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Naoya Ogata, Takehisa Nakanishi, Tadashi Asanuma
  • Patent number: 5418299
    Abstract: Blends can be formed which comprise a flexible coil polymer substrate, e.g., of a poly(alkylene terephthalate), and a thermotropic, essentially liquid crystalline oligomer which comprises aromatic units and at least one linear polyalkylene spacer. These blends can be used to form fibers or molded articles.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: May 23, 1995
    Assignee: Akzo Nobel N.V.
    Inventors: Ki-Soo Kim, Sophia Dashevsky, Jian-Lin Liu, Stanley W. Palmaka
  • Patent number: 5354798
    Abstract: An engineering polyacetal resin composition comprising 0.05-20 parts by weight of a dispersant (B) and 5-40 parts by weight of a filler (C), and 100 parts by weight of a resin ingredient (A) which comprises 90-50% by weight of a polyacetal resin (a) and 10-50% by weight of a polyamide resin (b) having a melting point of up to 230.degree. C., a maximum particle diameter of 0.03-10 .mu.m and a maximum aspect ratio of up to 2, and is dispersed in a matrix of said polyacetal resin (a).
    Type: Grant
    Filed: August 16, 1991
    Date of Patent: October 11, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Tsukahara, Masahiko Niino
  • Patent number: 5346737
    Abstract: Incorporation of at least one lubricant and an ethylene-based polymer of the formula E/X/Y wherein E is ethylene, X is methyl acrylate, butyl acrylate, or ethyl acrylate, and Y is glycidyl methacrylate, glycidyl acrylate, or glycidyl vinyl ether into polyacetal compositions results in compositions having good wear resistance and good melt processing thermal stability. The compositions are useful, for example, when molded into parts to be used in sliding applications, such as gears, cams, and conveyor chains.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: September 13, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Tatsu-Hiro Takahashi, Toshikazu Kobayashi
  • Patent number: 5344875
    Abstract: The present invention provides a polyoxymethylene resin composition which is excellent in wear resistance and is suitable as materials for various sliding parts. The composition comprises (A) 65-98.8% by weight of a polyoxymethylene resin, (B) 0.2-5.0% by weight of a polyfunctional isocyanate compound, (C) 0.5-20% by weight of an olefin polymer containing 30% by weight or more of ethylene and a functional group containing an active hydrogen, and (D) 0.2-10% by weight of polyethylene.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: September 6, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Masahiko Niino
  • Patent number: 5344882
    Abstract: Incorporation of a thermoplastic polyurethane and at least one thermoplastic crystalline polymer selected from nylon 6, nylon 612, polypropylene, and polyalkylene terephthalates containing at least one ethylene copolymer into polyacetal polymer results in blends characterized as having improved toughness, or impact strength, and improved elongation over that of a comparable blend of polyacetal and at least one of said crystalline polymers alone.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: September 6, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Edmund A. Flexman
  • Patent number: 5321087
    Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: June 14, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Naoya Ogata, Takehisa Nakanishi, Tadashi Asanuma
  • Patent number: 5317050
    Abstract: Compositions containing an aryl phosphite and water to hydrolyze the aryl phosphite provide controlled and extended work time when used as hardening agents for the ambient temperature hardening of phenolic resins and for rapid hardening of such resins at modestly elevated temperatures. Pre-solvolysis with small quantities of water, alkanols of 1 to 4 carbon atoms or alkylene glycols of 2 to 4 carbon atoms improve compatibility of trisubstituted phosphites with the resin. Pre-hydrolysis of the phosphites as well as addition of furfuryl alcohol or alkylene glycols of 2 to 4 carbon atoms accelerate the hardening (curing) of the resin. Various compounds such as: carboxylic acid amides, urea, dicyandiamide, N-methylolated amides, N-alkyl 2-pyrrolidinones having 1 to 4 carbon atoms in the alkyl group, those having an internal epoxide group, alkanols, and Schiff bases retard the ambient temperature hardening of the resin with the aryl phosphite hardening agents.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: May 31, 1994
    Assignee: Borden, Inc.
    Inventor: Arthur H. Gerber
  • Patent number: 5312877
    Abstract: A coating composition having a total solids content of at least about 85 wt. %, based on the weight of the composition, a volatile organic chemical content of less than about 15 wt. %, based on the weight of the composition and a Brookfield viscosity of about 500-2,000 centipoises at 25.degree. C. The composition contains a polyester polyol having a weight average molecular weight of about 300-900 and a hydroxy number of about 150-400; at least one thermosettable polyester; an alkoxy aminoplast resin; a reactive diluent present in an amount of 0-30 wt. %, based on the weight of the composition; and an acid catalyst curing agent.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: May 17, 1994
    Assignee: Sun Chemical Corporation
    Inventors: Selcuk Avci, Narendra M. Patel, Leonard Di Leo, Ralph H. Reiter
  • Patent number: 5310823
    Abstract: A polyacetal resin composition having a volume resistivity lower than 10.sup.14 [.OMEGA..multidot.cm], which comprises (A) 100 parts by weight of a polyacetal resin and (B) 1 to 100 parts by weight of a polyether ester block copolymer which is derived from (a) a dicarboxylic acid component composed mainly of terephthalic acid, (b) a glycol component composed mainly of 1,4-butanediol and (c) a poly(ethylene oxide)glycol having a number average molecular weight of 500 to 20,000 and has a poly(ethylene oxide) dicarboxylate unit content of 20 to 95% by weight, has excellent antistatic characteristics and mechanical characteristics, and especially a high impact resistance.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: May 10, 1994
    Assignee: Toray Industries, Inc.
    Inventors: Masaki Kunitomi, Hiromitsu Ishii, Yoshiyuki Yamamoto
  • Patent number: 5294670
    Abstract: The present invention relates to a polyacetal copolymer comprising a polyoxymethylene group (A) and a vinyl polymer group (B), the copolymer having a structure of the formula (I):A.sub.n --X--B (I)wherein X is a terminal group of B and represents a binding group derived from a compound having at least two carbon atoms and 1 to 4 groups selected from hydroxyl, carboxyl, ester, amino and alkoxy groups, and A.sub.n means that A is present in the quantity of n times in number, and bonds to X, in which n=1 to 4, and the copolymers has a number average molecular weight of 10,000 to 500,000; a process for the production of said copolymer; and a composition comprising said copolymer and a polyvinyl polymer and/or polyoxymethylene.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: March 15, 1994
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tadashige Hata, Kazuhiko Matsuzaki
  • Patent number: 5266633
    Abstract: The invention relates to a mixture composed essentially of polyoxymethylene (component A), a rubber-elastic graft copolymer in which the particles have been formed from a rubber-elastic, single-phase core based on polydiene and a hard graft shell (component B) and, if appropriate, a polymeric third component (component C). The invention also relates to a three-component mixture of the components A, B' and C, the core, in the case of B', being preponderantly or entirely composed of poly(meth)acrylic acid ester or silicone rubber instead of polydiene.The shaped articles produced from these mixtures are particularly distinguished by good low-temperature impact strength.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: November 30, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karlheinz Burg, Harald Cherdron, Friedrich Kloos, Helmut Schlaf
  • Patent number: 5260378
    Abstract: The invention relates to a block copolymer according to the general formula A-b-B on the basis of a furan derivative as binding group (b) and the process for the preparation hereof. The furan derivative as binding group (b) is a compound according to formula (I). ##STR1## The block copolymer can simply be prepared in one single reactor and is suitable for use as compatibilizer.
    Type: Grant
    Filed: January 18, 1990
    Date of Patent: November 9, 1993
    Assignee: Stamicarbon B.V.
    Inventors: Alessandro Gandini, Marie C. Salon
  • Patent number: 5250606
    Abstract: The present invention pertains to thermoplastic polymer blends which comprise a monovinylidene aromatic copolymer, an acetal polymer and a thermoplastic polycarbonate resin or a polyester resin derived from the reaction of a dicarboxylic acid and a glycol, and which may also optionally contain an elastomeric material such as a thermoplastic polyurethane or an elastomeric copolyester. The resulting polymer blends have good processability and a beneficial combination of physical and chemical properties including thermal/dimensional stability, impact resistance, chemical resistance and environmental stress crack resistance. Said polymer blends are suitable for use in the preparation of a variety of molded utilitarian articles having good appearance and paintability.
    Type: Grant
    Filed: April 7, 1992
    Date of Patent: October 5, 1993
    Assignee: The Dow Chemical Company
    Inventors: Martin J. Guest, P. F. M. v/d Berghen, Ludo M. Aerts, Antonios Gkogkidis, Abraham F. de Bert
  • Patent number: 5244946
    Abstract: Thermoplastic polymer blends comprising a monovinylidene aromatic copolymer, an acetal polymer and an elastomeric material such as a thermoplastic polyurethane or an elastomeric copolyester have good processability and a beneficial combination of physical and chemical properties including thermal/dimensional stability, impact resistance, chemical resistance and creep resistance. Said polymer blends are suitable for use in the preparation of a variety of molded utilitarian articles having good appearance and paintability.
    Type: Grant
    Filed: April 8, 1992
    Date of Patent: September 14, 1993
    Assignee: The Dow Chemical Company
    Inventors: Martin J. Guest, P. F. M. v/d Berghen, Ludo M. Aerts, Antonios Gkogkidis, Abraham F. de Bert
  • Patent number: 5236988
    Abstract: An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition contains an engineering plastic material and an aliphatic polyester.
    Type: Grant
    Filed: September 25, 1990
    Date of Patent: August 17, 1993
    Assignees: Sekisui Chemical Co., Ltd., Kabushiki Kaisha Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Kazuo Doyama, Makoto Yamaguchi, Makoto Ohsuga, Akihiro Niki, Toranosuke Saito, Hiroki Tsunomachi, Daishiro Kishimoto
  • Patent number: 5218041
    Abstract: Polyoxymethylene molding materials having improved thermal stability and reduced formaldehyde emission consisting essentially of a polyoxymethylene as the main component and containing in addition, relative in each instance to the weight of the polyoxymethylene, 0.1 to 10% by weight of an endocopolymerizate, 0.05 to 3% by weight of a phenolic antioxidant, 0 to 5% by weight carbon black and 0 to 3% by weight of further additives customary in polyoxymethylene molding materials.
    Type: Grant
    Filed: October 7, 1991
    Date of Patent: June 8, 1993
    Assignee: Degussa Aktiengesellschaft
    Inventors: Detlef Arnoldi, Edwin Nun
  • Patent number: 5183858
    Abstract: This invention relates to a core-shell polymer which is useful for polyoxymethylene resin, a polyoxymethylene resin composition containing the core-shell polymer and a molded article made of the polyoxymethylene resin composition.The core-shell polymer comprises a rubbery polymer core and a glassy polymer shell and has substantially no detectable anion.This core-shell polymer makes the molded articles be improved on the impact strength, elongation at the weld line, etc. The molded articles is used as various products (such as gears, reels, etc.).
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: February 2, 1993
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Ichiro Sasaki, Junji Oshima, Minoru Yamada
  • Patent number: 5162451
    Abstract: A homogeneous composition having improved curability contains an organopolysiloxane having at least two carboxyl group-containing hydrocarbon groups in each molecule, a polymeric compound which contains at least 2 hydroxyl groups and at least one oxyalkylene unit and a catalytic quantity of an esterification reaction catalyst. The curable composition has good standing compatiblity and experiences a high degree of curing. When cured the composition is useful, for example, as an antistatic additive.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: November 10, 1992
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventor: Takashi Nakamura
  • Patent number: 5143982
    Abstract: A polyoxymethylene resin composition excellent in decorative property and hot-stampability comprising 50-97% by weight of polyoxymethylene resin and 3-50% by weight of polyester random copolymer comprising a diol residue A and a dicarboxylic acid residue B,said diol residue A being represented by the formula --O--R--O , wherein R is an alkyl group of 2-12 carbon atoms, andsaid dicarboxylic acid residue B being represented by at least one of formulae (1), (2) and (3), ##STR1## wherein n is an integer of 2-6, l is an integer of 7-24, and Ph is an aromatic hydrocarbon residue, the proportion of (1) to the sum of (1), (2) and (3) being 5-100% by mol, provided that when said proportion is 100% by mol, (1) consist of at least two different types of (1).
    Type: Grant
    Filed: April 24, 1991
    Date of Patent: September 1, 1992
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Masahiko Niino