Solid Polymer Derived From Aldehyde Or Derivative Containing Halogen Patents (Class 525/402)
  • Patent number: 9018346
    Abstract: The present invention provides a method for removing unreacted monomer in polymer using a SCC comprising a housing having a rotation axis; a supply part of at least one polymer formed inside of the housing; at least two spinning cones that are installed so as to have a constant gradient from the upper part to the lower part to the rotation axis, move polymer supplied through the polymer supply part, and rotate around the rotation axis; a fixed cone that is fixed and formed on the inner side of the housing, and provides a pathway for sequentially moving polymer from a spinning cone at the upper part to a spinning cone at the lower part; a product collection part for collecting polymer moved through the spinning cone and the fixed cone; and a driving part for rotating the spinning cone.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: April 28, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Eun-Jung Joo, Dong-Kwon Lee, Dae-Young Shin, Jong-Ku Lee, Chang-Hoe Heo
  • Publication number: 20150017410
    Abstract: A resin binder for use in formaldehyde emission-free stator insulation. The resin binder includes an epoxy, a catalyst, and a polymer material. The polymer material is hydroxyl-terminated. The resin binder is used in mica tape for groundwall insulation for stator windings.
    Type: Application
    Filed: July 10, 2013
    Publication date: January 15, 2015
    Inventors: James Jun Xu, Jeffrey David Sheaffer
  • Patent number: 8871872
    Abstract: Provided is a method for a poly(GAP-co-THF)diol prepolymer in which THF monomer units are copolymerized to GAP, having high difunctionality, a reduced amount of cyclic oligomer side products having a small molecular weight, a wide copolymer composition and controlled molecular weight. The resulted poly(GAP-co-THF)diol prepolymer according to the present invention is used as a binder for a high-energy PBX or composite propellant, specifically used as a binder in the preparation of polyurethane having excellent mechanical properties.
    Type: Grant
    Filed: May 15, 2013
    Date of Patent: October 28, 2014
    Assignee: Agency For Defense Development
    Inventors: Bum Jae Lee, In Joo Bae, Jin Seuk Kim, Seung Hee Kim
  • Publication number: 20140287241
    Abstract: Provided is an epoxy resin allowing a cured product that is less changed in terms of heat resistance due to thermal history and has low thermal expansion, the epoxy resin having high solvent solubility. The epoxy resin is a polyglycidyl ether of a naphthol-novolac resin including, at predetermined proportions, a trimer and a dimer that have specific structures.
    Type: Application
    Filed: July 11, 2012
    Publication date: September 25, 2014
    Applicant: DIC CORPORATION
    Inventor: Yutaka Satou
  • Patent number: 8318866
    Abstract: Molding materials and the moldings produced therefrom, containing a) polyoxymethylene in which at least 50% of the terminal groups are hydroxyl groups, which has a melt volume rate MVR of less than 20 cm3/10 minutes, measured according to ISO 1133 at 190° C. and 2.16 kg, and whose proportion of low molecular weight constituents having low molecular weights below 10 000 dalton is less than 15% by weight, based on the total mass of the polyoxymethylene, and b) a thermoplastic elastomer, are described. The moldings produced from these molding materials are distinguished by a very high notch impact strength.
    Type: Grant
    Filed: April 14, 2009
    Date of Patent: November 27, 2012
    Assignee: Ticona GmbH
    Inventors: Klaus Kurz, Christine Koestler, Lowell Larson
  • Patent number: 8252892
    Abstract: A process for obtaining an elastomer in solid phase from its polymer solution which comprises: (a) optionally pre-concentrating the polymer solution coming from the production system by a flash process; (b) subjecting the polymer solution to a concentrating stripping operation by water vapor in a mixing device comprising internal moveable mixing parts which transfer minimal mechanical energy to the solution in the form of friction heat; and (c) subjecting the concentrated polymer phase coming from (b) to devolatilization by mechanical energy and/or vapor flow to remove residual solvent.
    Type: Grant
    Filed: November 5, 2009
    Date of Patent: August 28, 2012
    Assignee: Polimeri Europa S.p.A.
    Inventors: Fabio Montanari, Federica Mainardi, Gabriele Veneri
  • Patent number: 7928184
    Abstract: The present invention provides a method of manufacturing a stabilized polyacetal resin, comprising the step of applying a heat treatment to a polyacetal resin having an unstable terminal group in the presence of an unstable terminal group decomposer selected from the following Group I, Group II and Group III, thereby decreasing the unstable terminal group: unstable terminal group decomposer of Group I: (I) a quaternary ammonium salt of an acidic cyclic amide compound, unstable terminal group decomposer of Group II: (II) a quaternary ammonium salt of a polycarboxylic acid intramolecularly having four or more carboxyl groups and/or a quaternary ammonium salt of an aminocarboxylic acid intramolecularly having one or more carboxyl group(s), unstable terminal group decomposer of Group III: (III) a quaternary ammonium salt, wherein a compound providing a counter-anion of a quaternary ammonium salt is at least one selected from the group consisting of the following (i) to (v): (i) a carbonic acid monoester
    Type: Grant
    Filed: March 7, 2006
    Date of Patent: April 19, 2011
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Hiroaki Nakao
  • Patent number: 7851585
    Abstract: The invention relates to polyacetal compositions comprising a mixture of (i) a polyacetal resin, (ii) p-aramid particles and (III) a vinyl-terminated dimethyl siloxane polymer. These compositions are useful in preparing molded articles exhibiting a good balance between high self-lubricating properties and wear resistance, and especially useful in articles that are in motion with respect to other parts they are in contact with.
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: December 14, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Anne-Laure Brison, Andreas Renken
  • Patent number: 7659051
    Abstract: A naphthalene-backbone polymer represented by Formula 1: wherein n and m are independently at least 1 and less than about 190, R1 is a hydrogen, a hydroxyl, a hydrocarbon group of about 10 carbons or less, or a halogen, R2 is methylene or includes an aryl linking group, R3 is a conjugated diene group, and R4 is an unsaturated dienophile group.
    Type: Grant
    Filed: December 31, 2007
    Date of Patent: February 9, 2010
    Assignee: Cheil Industries, Inc.
    Inventors: Kyong Ho Yoon, Jong Seob Kim, Dong Seon Uh, Chang Il Oh, Kyung Hee Hyung, Min Soo Kim, Jin Kuk Lee
  • Patent number: 7619020
    Abstract: The present invention provides a polyacetal resin composition having excellent mechanical characteristics with reduced generation of formaldehyde. To 100 parts by weight of (A1) a polyacetal resin having substantially straight chain molecular structure, there are added 0.1-20 parts by weight of (A2) a polyacetal resin having a branched or cross-linked molecular structure, 3-200 parts by weight of (B) a glass-base inorganic filler, and 0.001 to 3 parts by weight of (C) a boric acid compound.
    Type: Grant
    Filed: August 8, 2007
    Date of Patent: November 17, 2009
    Assignee: Polyplastics Co., Ltd.
    Inventors: Akihide Shimoda, Hiraku Iketani
  • Publication number: 20040132919
    Abstract: To provide an antistatic polymer composition that can manifest a uniform antistatic effect permanently with little change in the surface resistance of moldings owing to humidity.
    Type: Application
    Filed: November 24, 2003
    Publication date: July 8, 2004
    Inventor: Toshikazu Kobayashi
  • Patent number: 6437053
    Abstract: A process for the continuous preparation of a thermoplastic molding composition with narrow scatter of the melt flow index, which comprises mixing two or more chemically identical starting materials of different melt flow index in a pelletizing extruder fitted with an on-line melt flow index meter and adjustable metering systems.
    Type: Grant
    Filed: June 13, 2000
    Date of Patent: August 20, 2002
    Assignee: Ticona GmbH
    Inventor: Gerhard Reuschel
  • Patent number: 6426393
    Abstract: To provide polyacetal which has excellent shock resistance, rigidity and creep resistance as essential properties of the polymer and makes a high flowability and an excellent molding property upon molding possible by improving the thermal stability. In the manufacture of a polyacetal copolymer by a copolymerization of 100 parts by weight of trioxane (a) with 0.05-20 parts by weight of a cyclic ether compound (b) which is copolymerizable with trioxane and 0.001-10 parts by weight of a mono-functional glycidyl compound (c), the mono-functional glycidyl compound (c) having a chlorine content of not more than 0.3% by weight is used.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: July 30, 2002
    Assignee: Polyplastics Co., Ltd.
    Inventors: Yoshihisa Tajima, Hidetoshi Okawa
  • Patent number: 6384179
    Abstract: A polyacetal resin composition comprising 30-90% by weight of polyacetal copolymer (A) having a melt index of less than 1.0 g/10 min. and 70-10% by weight of polyacetal copolymer (B) having a melt index of 1.0-100 g/10 min., both melting points of (A) and (B) being 155°-162° C., or a difference in melting point between (A) and (B) being not less than 6° C., has distinguished toughness and creep resistance.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: May 7, 2002
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Noritaka Tanimura, Tadao Matsushika
  • Publication number: 20010009929
    Abstract: A process for preparing multi-stage emulsion polymers is provided. The process is capable of producing multi-stage emulsion polymers having low dry-bulk density. These polymers are useful in coating compositions such as paints and paper coatings.
    Type: Application
    Filed: February 21, 2001
    Publication date: July 26, 2001
    Inventors: Robert Mitchell Blankenship, James Keith Bardman
  • Patent number: 6225416
    Abstract: The novel molding made from a combination of polyacetal with directly molded-on function elements is distinguished by the fact that the function elements comprise one or more elastomers. Such elastomers comprise partially or fully hydrogenated nitrile rubbers, one- or multicomponent silicone rubbers or sulfur-containing rubbers.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: May 1, 2001
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Frank Reil, Frank Reuter, Ulrich Haack, Gerhard Reuschel
  • Patent number: 6111029
    Abstract: The novel molding made from a combination of polyacetal with directly molded-on function elements is distinguished by the fact that the function elements comprise one or more elastomers. Such elastomers comprise partially or fully hydrogenated nitrile rubbers, one- or multi-component silicone rubbers or sulfur-containing rubbers.
    Type: Grant
    Filed: April 23, 1999
    Date of Patent: August 29, 2000
    Inventors: Frank Reil, Frank Reuter, Ulrich Haack, Gerhard Reuschel
  • Patent number: 5977266
    Abstract: The novel molding made from a combination of polyacetal with directly molded-on function elements is distinguished by the fact that the function elements comprise one or more elastomers. Such elastomers comprise partially or fully hydrogenated nitrile rubbers, one- or multi-component silicone rubbers or sulfur-containing rubbers.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: November 2, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Frank Reil, Frank Reuter, Ulrich Haack, Gerhard Reuschel
  • Patent number: 5973081
    Abstract: A modified polyacetal is obtainable by heating 0.1 to 30 parts by weight of (B) a polymerizable compound having a modifying group such as an epoxy group, a carboxyl group or an acid anhydride group relative to 100 parts by weight of (A) a base polyacetal and introducing the modifying group of the polymerizable compound to the base polyacetal. The base polyacetal (A) includes (A1) a polyacetal selected from polyoxymethylene homopolymers and copolymers, and (A2) a polymerizable polyacetal having a functional group comprising a polymerizablly unsaturated bond. The introduction efficiency of the modifying group can be enhanced by adding 0.01 to 2.5 parts by weight of (C) a free-radical initiator relative to 100 parts by weight of the total amount of the components (A) and (B), and mixing the resultant mixture under a molten state of the polyacetal. According to such method, the affinity of the polyacetal is improved by introducing the modifying group to the base polyacetal with ease and high efficiency.
    Type: Grant
    Filed: June 7, 1996
    Date of Patent: October 26, 1999
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hiroyuki Kanai, Hajime Serizawa, Katsuhei Ohnishi, Eiji Masuda, Kaoru Yamamoto
  • Patent number: 5563235
    Abstract: Fluorinated aldehydes are made by reacting a fluorinated acyl chloride with a silicon hydride in the presence of palladium. Also disclosed are fluorinated ether aldehydes and their polymers, a process for making fluorinated aldehydes polymers using titanium or aluminum alkoxide catalysts, and a process for endcapping fluorinated polymers using perfluoroallyl fluorosulfate or fluorine.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: October 8, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: William B. Farnham
  • Patent number: 5310828
    Abstract: Novel polymeric compositions are provided for polyamide fibers or fibers having terminal amino groups that impart stain resistance and are resistant to discoloration.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: May 10, 1994
    Assignee: Peach State Labs, Inc.
    Inventors: Michael S. Williams, Thomas H. Moss, III
  • Patent number: 5218038
    Abstract: The invention relates to the modification of a curable phenolic resin system by the incorporation of alkylphenol, alkoxyphenol, arylphenol or aryloxyphenol. The resulting resin has reduced water soluble leachates which, in turn, improves the break time when the resin is used to coat proppants for treating subterranean formations.
    Type: Grant
    Filed: November 14, 1991
    Date of Patent: June 8, 1993
    Assignee: Borden, Inc.
    Inventors: Calvin R. Johnson, Kwok-tuen Tse, Charles J. Korpics
  • Patent number: 5061763
    Abstract: A stain resistant composition for fibers having polyamide linkages prepared by polymerizing an .alpha.-substituted acrylic acid or ester in the presence of a sulfonated aromatic formaldehyde condensation plymer, or by polymerization of a sulfonated hydroxyaromatic ester of an .alpha.-substituted acrylic acid or acrylic acid, and methods for making and applying the composition.
    Type: Grant
    Filed: December 27, 1989
    Date of Patent: October 29, 1991
    Assignee: Peach State Labs, Inc.
    Inventors: Thomas H. Moss, III, Ralph R. Sargent, Michael S. Williams
  • Patent number: 5030726
    Abstract: The present invention relates to polymerizable cyclic urea derivatives which can be thermally split to give rise to an isocyanate group; and to a polymer having cyclic urea pendant groups, which can be cured by heating without any additional curing agent such as an isocyanate blocked with a volatile lower molecular weight material, so that volatile material is not released in a thermal curing process.
    Type: Grant
    Filed: December 29, 1989
    Date of Patent: July 9, 1991
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Tsuboniwa Noriyuki, Urano Satoshi, Umemoto Hirotoshi, Sakamoto Hiroyuki, Tobinaga Kenshiro, Tsuchiya Yasuyuki
  • Patent number: 5015259
    Abstract: A stain resistant composition for fibers having polyamide linkages prepared by polymerizing an .alpha.-substituted acrylic acid or ester in the presence of a sulfonated aromatic formaldehyde condensation polymer, and methods for making and applying the composition.
    Type: Grant
    Filed: May 10, 1990
    Date of Patent: May 14, 1991
    Assignee: Peach State Labs, Inc.
    Inventors: Thomas H. Moss, III, Ralph R. Sargent, Michael S. Williams
  • Patent number: 5011907
    Abstract: Highly conjugated organic polymers typically have large non-resonant electronic susceptibilities, which give the molecules unusual optical properties. To enhance these properties, "defects" are introduced into the polymer chain. Examples include light doping of the conjugated polymer and synthesis, conjugated polymers which incorporate either electron donating or accepting groups, and conjugated polymers which contains a photoexcitable species capable of reversibly transferring its electron to an acceptor. Such defects in the chain permit enhancement of the second hyperpolarizability by at least an order of magnitude.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: April 30, 1991
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventor: David N. Beratan
  • Patent number: 4940757
    Abstract: A stain resistant composition for fibers having polyamide linkages prepared by polymerizing an .alpha.-substituted acrylic acid or ester in the presence of a sulfonated aromatic formaldehyde condensation polymer, and methods for making and applying the composition.
    Type: Grant
    Filed: April 20, 1989
    Date of Patent: July 10, 1990
    Assignee: Peach State Labs, Inc.
    Inventors: Thomas H. Moss, III, Ralph R. Sargent, Michael S. Williams
  • Patent number: 4855365
    Abstract: There is disclosed a novel poly-.beta.-alanine compound comprising monomeric units of the formula (CH.sub.2 CH.sub.2 CONH) and monomeric units of the formula ##STR1## in a specific proportion, having a high degree of polymerization and which is essentially free from metal contamination. The novel poly-.beta.-alanine is produced by polymerizing acrylamide using an alkaline earth metal alcoholate catalyst in an extremely limited amount. The novel compound has a wide variety of uses, and is especially useful as a thermal stabilizer for a polyacetal resin.
    Type: Grant
    Filed: May 8, 1987
    Date of Patent: August 8, 1989
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Fumihiko Yamamoto, Teruyuki Misumi
  • Patent number: 4758634
    Abstract: Electroactive polymers of the structure and formula ##STR1## in their neutral and ionized forms, where the backbone group R.sub.b is selected from or is a combination of five- and six-membered rings capable of aromatic and quinonoid bonding structures, R.sub.s is selected from aliphatic, aromatic and heterocyclic groups and x, y are positive integers from 1 to 5 and m is a positive integer from 2 to about 10,000, together with a method of making them are disclosed.
    Type: Grant
    Filed: September 8, 1986
    Date of Patent: July 19, 1988
    Assignee: Honeywell Inc.
    Inventor: Samson A. Jenekhe
  • Patent number: 4600767
    Abstract: Thermostable hydroxystyrylaza compounds are prepared by reacting methylated pyridines and/or pyrazines with one or more monohydroxy aromatic aldehydes having the ortho and para positions to the hydroxy group block with groups inert to condensation reactions. These compounds are useful to make unsaturated derivatives which can cure into high temperature resistant polymers and/or laminates without giving off condensation products.
    Type: Grant
    Filed: August 16, 1985
    Date of Patent: July 15, 1986
    Assignee: The Dow Chemical Company
    Inventors: Tim R. Diephouse, Randy J. LaTulip, John W. Robinson, Gary R. Gantt
  • Patent number: 4181685
    Abstract: Thermoplastic molding compositions having improved properties are composed of a mixture of from 99.999 to 90% by weight of a linear polyoxymethylene and from 0.001 to 10% by weight of a branched or cross-linked polyoxymethylene. The linear polyoxymethylenes are homopolymers of formaldehyde or of trioxane or copolymers of trioxane and at least one compound of monofunctional reaction which can be copolymerized with trioxane. The branched or cross-linked polyoxymethylenes are copolymers of trioxane and a multifunctionally reacting compound, or copolymers of trioxane, a monofunctionally reacting compound and a branched or cross-linked polyether. The molding compositions yield shaped articles having improved mechanical properties.
    Type: Grant
    Filed: April 14, 1976
    Date of Patent: January 1, 1980
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudolf Kern, Heinz Schmidt, Karlheinz Burg, Ernst Wolters, Gunter Sextro