Mixed With Ethylenically Unsaturated Reactant Or Polymer Therefrom Patents (Class 525/404)
  • Patent number: 5334681
    Abstract: Fluorine and/or silicone containing block copolymers are described which are the copolymerization product of mono; di- or trivinyl substituted poly(ethylene oxide) prepolymers (A) and fluoroalkyl-alkylene acrylates or methacrylates (B1), oligosiloxy-silyl alkyl-acrylates or methacrylates (B2), ether copolymerizable comonomers (C), and 0.1 to 10% of a di- or polyvinyl crosslinking comonomer (D) of 200 to 1000 molecular weight. The novel block copolymers are prepared in solution or bulk and form hydrogels, which are characterized by high oxygen permeability, resiliency, flexibility and wettability and are therefore well suited as biocompatible polymers, especially as contact lenses.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: August 2, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Karl F. Mueller, Walter L. Plankl
  • Patent number: 5321077
    Abstract: A polymer polyol composition comprising a continuous phase, a disperse phase within the continuous phase, and a dispersant to enhance the stability of the polymer polyol is disclosed. The dispersant is a grafted polyol-polyacrylate dispersant comprised of a isocyanate vinyl monomer/ethylenically unsaturated monomer random copolymer and a polyoxyalkylene polyether, wherein the random copolymer and the polyoxyalkylene polyether are connected through at least one urethane graft site.Methods of preparing the polymer polyol composition and the grafted polyol-polyacrylate dispersant are provided. The polymer polyol compositions have low viscosities as well as high stability and may be prepared with high levels of dispersed vinyl polymer and high styrene:acrylonitrile ratios in the dispersed vinyl polymer. The polymer polyol compositions are useful for the preparation of polyurethanes, particularly polyurethane foams.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: June 14, 1994
    Assignee: Arco Chemical Technology, L.P.
    Inventors: John E. Hayes, Robert G. Gastinger
  • Patent number: 5321095
    Abstract: Water-soluble azlactone activated polyalkylene oxides having improved hydrolytic stability and conjugates of the azlactone activated polyalkylene oxides with biologically active nucleophiles are disclosed. Methods of forming and conjugating the activated polyalkylene oxides with biologically active nucleophiles are also disclosed.
    Type: Grant
    Filed: February 2, 1993
    Date of Patent: June 14, 1994
    Assignee: Enzon, Inc.
    Inventor: Richard B. Greenwald
  • Patent number: 5319006
    Abstract: Polyesters are prepared by a new ester-insertion reaction of a polyether and a cyclic anhydride in the presence of a Lewis acid catalyst. The process is advantageously used to convert polyether polyols recovered from polyurethanes into curable unsaturated polyester resins.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: June 7, 1994
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Lau S. Yang, Diane A. Macarevich
  • Patent number: 5318719
    Abstract: This invention relates to a novel class of biodegradable water-soluble graft copolymers having building, anti-filming, dispersing and threshold crystal inhibiting properties comprising (a) an acid functional monomer and optionally (b) other water-soluble, monoethylenically unsaturated monomers copolymerizable with (a) grafted to a biodegradable substrate comprising polyalkylene oxides and/or polyalkoxylated materials.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: June 7, 1994
    Assignee: Rohm and Haas Company
    Inventors: Kathleen A. Hughes, Graham Swift
  • Patent number: 5288789
    Abstract: A method is disclosed for controlling foam in a fermentation broth by adding to the fermentation broth an effective amount of a composition comprising a compound corresponding to the formula: ##STR1## wherein AO is an oxyalkylene copolymer moiety of oxypropylene and oxyethylene units, each oxyalkylene copolymer moiety having a molecular weight of at least about 300 and an oxypropylene to oxyethylene molar ratio of from about 2:1 to about 10:1, n is an integer from about 1 to about 20, R is an alkyl group of from about three to about twelve carbon atoms, and R' is methylene or substituted methylene. The composition can be added to fermentation broths to prevent the formation of foam or to reduce foam which has already formed. The above defined composition is also disclosed in a form free of solvent, such as xylene.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: February 22, 1994
    Assignee: Petrolite Corporation
    Inventor: Kevin J. McCarthy
  • Patent number: 5277945
    Abstract: A resin composition for coating, comprising as main components:(A) a graft polymer obtained by reacting(a) at least one polymer polyol selected from polyester polyols, polyether polyols and polyether polyester polyolshaving a number-average molecular weight of 500-6,000,(b) a polymer having two hydroxyl one end, and(c) a polyisocyanate compound, and(B) a crosslinking agent selected from polyisocyanate compounds and amino resins.This composition gives a coating film excellent in flexibility, hardness, stain resistance, etc.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: January 11, 1994
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Noboru Takoh, Shingo Matsukawa, Masafumi Kawamura
  • Patent number: 5272204
    Abstract: Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer in situ in a polyol in the presence of inner-olefin containing at least 5 carbon atoms, are of lower viscosity and can provide polyurethanes having improved properties. Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer, in situ in a polyol in the presence of an azo compound and a peroxide having a 10 hours half-life period temperature which is lower by at least 10.degree. C. than that of the azo compound, have improved stability even at higher styrene content.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: December 21, 1993
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Keiichi Akimoto, Takeshi Sumita, Masahiro Matsuoka
  • Patent number: 5252694
    Abstract: Polymerizable compositions having at least one cationically polymerizable monomer; an optional free radically polymerizable monomer; an energy-polymerizable catalyst system wherein the catalyst system comprises an organometallic complex salt; a thermally decomposable ester reaction product of a tertiary alkyl alcohol and an acid that forms a chelation complex with the metal ion of the organometallic complex salt; optionally, a peroxide. The polymerized compositions are useful as cured adhesive films, pressure sensitive adhesives, protective coatings, liquid adhesives, structural and semi-structural adhesives, and free standing films.
    Type: Grant
    Filed: January 22, 1992
    Date of Patent: October 12, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Peggy S. Willett, Janis Robins, Kent S. Tarbutton, Michael A. Kropp
  • Patent number: 5250581
    Abstract: Novel polymer polyols based on halogenated aromatic monomers such as tribromostyrene give polyurethane foams with improved flame retardant properties. For example, replacing conventional SAN polymer polyols with tribromostyrene (TBS)/acrylonitrile polymer polyols allows the preparation of polyurethane foams passing British Standard 5852, Part 2, Ignition Source 5 Combustion Test and having better ASTM E-906 values without the need for solid fillers such as melamine or aluminum trihydrate, although these and other flame retardant additives may be optionally employed as well. Elimination of these fillers also provides other improvements such as superior strength and better compression set properties. The TBS dispersions may also be used in conjunction with melamine to eliminate the need for liquid fire retardant additives.
    Type: Grant
    Filed: September 26, 1990
    Date of Patent: October 5, 1993
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Robert G. Gastinger, John E. Hayes, Philippe C. Motte
  • Patent number: 5247020
    Abstract: Disclosed is a process for producing a styrene polymer composition, which comprises polymerizing styrene monomer using a catalyst comprising (A) aluminoxane and (B) a compound of the group IV B transition metal in the periodic table, in the presence of rubber-like elastomer.The resin composition obtained thereby is superior in heat resistance, and impact strength, and utilized as the starting material for various moldings.
    Type: Grant
    Filed: December 28, 1990
    Date of Patent: September 21, 1993
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Hideo Teshima, Masahiko Kuramoto
  • Patent number: 5241016
    Abstract: The invention is an epoxy resin adhesive composition. The composition comprises:A. An epoxy resin component; andB. A curative component comprising:a curing amount of a polyamine curing agent and 2 to 30 phr. of an adhesion enhancer of comprising a partially hindered polyetherpolyamine.The fast curing adhesive offers high lap shear strength and relatively high peel strength.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: August 31, 1993
    Assignee: Texaco Chemical Company
    Inventors: Harold G. Waddill, Robert A. Grigsby, Jr., Michael Cuscurida, Robert L. Zimmerman
  • Patent number: 5225491
    Abstract: This invention relates to a comb-shaped graft copolymer, to a process for making the comb, and to a polymer blend made with the comb. The comb is made by a free radical polymerization of an ethylenically unsaturated monomer with a macromolecular monomer ("macromer" for brevity) of a haloalkylene oxide ("HAO" for brevity) homopolymer, random or block copolymer. The comb copolymer and blends of the comb with a polymer(s) may be cured. A comb with a terminal acrylyl or methacrylyl group or "head" and pendant polyether chains, which always include some HAO repeating units, may be made in an emulsion or suspension polymerization process which provides a comb having adequately high molecular weight so that the comb may be used in blends. The preferred comb of epichlorohydrin has a (meth)acrylyl head at one end, through which it (the macromer) is polymerizable, and a terminal hydroxyl (OH) group, or an end-capping group derived from the OH group at the other end.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: July 6, 1993
    Assignee: The B. F. Goodrich Company
    Inventor: Simon H. Yu
  • Patent number: 5225285
    Abstract: Comb-shaped polymers, comprised of hydrophilic backbones and dye-containi hydrophobic side chains are fabricated into multilayered, polarized, noncentrosymmetric, thin films by means of Langmuir-Blodgett processing techniques. These films exhibit harmonic, generated by shining a laser through the film, increases quadratically with the number of layers of polymeric dye in the film.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: July 6, 1993
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Robert C. Hall, Geoffrey A. Lindsay, James M. Hoover
  • Patent number: 5223583
    Abstract: A process for producing an unsaturated group-terminated polyalkylene oxide, which comprises subjecting a monoepoxide having at least 3 carbon atoms to ringopening addition polymerization to an initiator in the presence of a double metal cyanide complex catalyst, followed by converting terminal hydroxyl groups of the resulting hydroxyl group terminated polyalkylene oxide to unsaturated groups.
    Type: Grant
    Filed: May 3, 1990
    Date of Patent: June 29, 1993
    Assignee: Asahi Glass Company Ltd.
    Inventors: Toshihiko Higuchi, Shigeyuki Kozawa
  • Patent number: 5217798
    Abstract: Nonwoven assemblies bonded with water dispersible or sensitive hot melt adhesives comprising 50-100 parts of a graft copolymer of about 40-85% of at least one vinyl monomer and about 15-60% of at least one water soluble polyalkylene oxide polymer, and about 0-50 parts by weight of tackifying resin. The compositions may also be employed as water sensitive binders in the manufacture of the nonwoven. Vinyl acetate is the preferred vinyl monomer whereas ethylene oxide homo- or copolymers are the preferred polyalkylene oxide. The use of tackifying resin is optional and may be undesirable for many of the applications.
    Type: Grant
    Filed: May 7, 1991
    Date of Patent: June 8, 1993
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Francis Brady, Gary Raykovitz, Paul Puletti, Thomas Kauffman, Jules Schoenberg
  • Patent number: 5198509
    Abstract: A composition comprising a lactone-modified alicyclic compound (I), or an epoxidized lactone-modified alicyclic compound (II) of the following formulae: ##STR1## wherein R is an alkyl group, an aromatic group or an alkenyl group having carbon number of from 1 to 30, Y.sup.1 is at least one of the structural groups; ##STR2## Y.sup.2 is at least one of the structural group; ##STR3## X is the structural group; ##STR4## R.sup.a and R.sup.b each independently is hydrogen or a methyl group, c and c' represent a number of from 4 to 8, from n1 to nL represents 0 or a number of more than 0, respectively, and n1+n2+n3+. . . +nL corresponds to the total mole numbers of a lactone introduced into one molecule.These compositions can be made into a heat-curable composition, a photo-curable composition, a polymerizable composition and another photo-curable composition.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: March 30, 1993
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Takaaki Fujiwa, Shin Takemoto, Tomohisa Isobe, Yoshiyuki Harano
  • Patent number: 5191032
    Abstract: A heterofunctional macromer represented by the formula: ##STR1## in which R.sub.1 is H or C.sub.1 -C.sub.4 alkyl; R.sub.2 is a (poly) lactone or (poly) ether chain;X.sub.1 is --COO--, --COOCH.sub.2 CH.sub.2 OCO--, --CONHCOO--, --COOCH.sub.2 CH.sub.2 NH--COO-- or ##STR2## X.sub.2 is --O--, --COO-- or --OCO--NH--R.sub.3 --NHCOO-- group; R.sub.3 is C.sub.1 -C.sub.6 alkylene, aromatic or alicyclic group;A is --CH.sub.2 --, --C(CH.sub.3).sub.2 -- or ##STR3## group; and reactive polymers derived from said macromer.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: March 2, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Mitsuo Yamada, Kei Aoki
  • Patent number: 5177151
    Abstract: This invention relates to a comb-shaped graft copolymer, to a process for making the comb, and to a polymer blend made with the comb. The comb is made by a free radical polymerization of an ethylenically unsaturated monomer with a macromolecular monomer ("macromer" for brevity) of a haloalkylene oxide ("HAO" for brevity) homopolymer, random or block copolymer. The comb copolymer and blends of the comb with a polymer(s) may be cured. A comb with a terminal acrylyl or methacrylyl group or "head" and pendant polyether chains, which always include some HAO repeating units, may be made in an emulsion or suspension polymerization process which provides a comb having adequately high molecular weight so that the comb may be used in blends. The preferred comb of epichlorohydrin has a (meth)acrylyl head at one end, through which it (the macromer) is polymerizable, and a terminal hydroxyl (OH) group, or an end-capping group derived from the OH group at the other end.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: January 5, 1993
    Assignee: The B. F. Goodrich Company
    Inventor: Simon H. Yu
  • Patent number: 5175217
    Abstract: The invention relates to a method for the photochemical conversion of tachysterol compounds into previtamin D compounds and of trans-vitamin D compounds into cis-vitamin D compounds under the influence of radiation, by exposing the tachysterol compound and trans-vitamin D compound, respectively, dissolved in a suitable solvent system, in the presence of a polymeric photosensitizer consisting of a polymer chain ("backbone") comprising covalently bound sensitizers suitable for the photochemical conversion, to light with a wavelength of preferably between approx. 300 and approx.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: December 29, 1992
    Assignee: Duphar International Research B.V.
    Inventors: Eric Goethals, Sebastianus J. Halkes, Robert B. Koolstra
  • Patent number: 5175207
    Abstract: A diallyl aromatic dicarboxylate derivative of the formula ##STR1## wherein Y is hydrogen atom or perfluoroalkenyl group having 6 to 14 carbon atoms, is a novel compound. The compound (1) is a starting material for a prepolymer containing a repeating unit derived from diallyl aromatic fluorine-containing dicarboxylate and represented by the formula ##STR2## wherein X is perfluoroalkenyl group having 6 to 14 carbon atoms.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: December 29, 1992
    Assignee: Daikin Industries Ltd.
    Inventors: Sinji Tamaru, Motonobu Kubo
  • Patent number: 5173538
    Abstract: A quick-setting, moisture-curing hot-melt polyurethane composition having a first polyether-based polyurethane prepolymer having a Tg above room temperature and a second polyurethane prepolymer with a Tg below room temperature, the first prepolymer being prepared from a low molecular weight polyether; preferably the second prepolymer is also polyether based and prepared from a high molecular weight polyether.
    Type: Grant
    Filed: October 17, 1989
    Date of Patent: December 22, 1992
    Assignee: Bostik, Inc.
    Inventors: Heinz G. Gilch, Walter Rath
  • Patent number: 5162453
    Abstract: Comb-shaped polymers, comprised of hydrophilic backbones and dye-containi hydrophobic side chains are synthesized for use in multilayered, noncentrosymmetric, thin films by means of Langmuir-Blodgett processing techniques. The second harmonic signal generation exhibited by these films increases quadratically with the number of layers of polymeric dye in the film.
    Type: Grant
    Filed: November 29, 1990
    Date of Patent: November 10, 1992
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Robert C. Hall, Geoffry A. Lindsay, James M. Hoover
  • Patent number: 5140069
    Abstract: Curable compositions containingA) an epoxy resin having on average more than one epoxy group per molecule,B) a carboxylic anhydride curing agent for component A) andC) about 5 to 40% by weight, relative to the amount of the components A), B) and C), of a liquid mixture of C1) a polyalkylene glycol based on polypropylene glycol or polybutylene glycol having two to about six hydroxyl, carboxyl, carboxylic anhydride or glycidyl end groups and of C2) an elastomeric copolymer based on butadiene, a polar, ethylenically unsaturated comonomer and, if appropriate, further ethylenically unsaturated comonomers having carboxylic acid, hydroxyl, mercapto or glycidyl ether end groups are described. Components C1) and C2) can also occur together in a segmented copolymer.
    Type: Grant
    Filed: February 16, 1990
    Date of Patent: August 18, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Werner Rufenacht
  • Patent number: 5139631
    Abstract: A cationic electrodeposition coating resin composition composed mainly of(A) a resin containing a primary hydroxyl group and a cationic group, and(B) an epoxy resin which is a copolymer comprising recurring units represented by formula (I) ##STR1## and recurring units represented by formula (II) ##STR2## wherein R denotes a C.sub.3 -C.sub.35 alkyl group, the proportion of the recurring units of formula being 1 to 75% by weight.
    Type: Grant
    Filed: December 9, 1991
    Date of Patent: August 18, 1992
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Reiziro Mishida, Akira Tominaga
  • Patent number: 5138009
    Abstract: A curable composition comprises an organopolysiloxane-polyoxyalkylene block copolymer terminated at both ends of a molecular chain with a lower aliphatic unsaturated group and consists essentially of organopolysiloxane units having a main chain of the formula, (R.sup.1 R.sup.2 SiO)m, and polyoxyalkylene units of the formula, (R.sup.3 O)n. The organopolysiloxane units and the polyoxyalkylene units are bonded through R.sup.1 R.sup.2 SiR.sup.4 groups, wherein R.sup.1 and R.sup.2 independently represent an unsubstituted or substituted monovalent hydrocarbon group except for an aliphatic unsaturated group, R.sup.3 and R.sup.4 independently represent a divalent hydrocarbon group, and m and n are, respectively, defined integers. The composition further comprises an organohydrogenpolysiloxane having at least two .tbd.SiH groups in one molecule and a curing agent therefor.
    Type: Grant
    Filed: March 20, 1991
    Date of Patent: August 11, 1992
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Yoshio Inoue
  • Patent number: 5133316
    Abstract: The present invention provides a cylinder head cover for an internal combustion engine having excellent vibration-damping properties which is prepared by molding a composition comprising 75 to 30% by weight, based on the composition, of resin components comprising 50 to 80% by weight of a polyamide resin and 50 to 20% by weight of a modified polyolefin resin modified with an unsaturated acid or its derivative, the total of both the resins being 100% by weight, 15 to 30% by weight of glass fibers based on the composition, and 10 to 40% by weight of mica based on the composition.
    Type: Grant
    Filed: May 20, 1991
    Date of Patent: July 28, 1992
    Assignees: Chisso Corporation, Daihatsu Motor Co., Ltd., Toyoda Gosei Co., Ltd.
    Inventors: Michio Kasai, Rikio Yonaiyama, Hirotoshi Fujikawa, Hidetoshi Ishihara, Joji Kasugai, Junji Koizumi
  • Patent number: 5115056
    Abstract: Fluorine and/or silicone containing block copolymers are described which are the copolymerization product of mono; di- or trivinyl substituted poly(alkylene oxide) prepolymers (A) and fluoroalkyl-alkylene acrylates or methacrylates (B1), oligosiloxy-silyl alkyl-acrylates or methacrylates (B2), and optionally other copolymerizable comonomers (C). The novel block copolymers are prepared in solution or bulk and are characterized by high oxygen permeability, flexibility and wettability and are therefore well suited as biocompatible polymers, especially as contact lenses.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: May 19, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Karl F. Mueller, Walter L. Plankl
  • Patent number: 5110881
    Abstract: A photochromic article having improved pohotochromic equilibrium response is described. In particular, a phtochromic compound is incorporation into or applied to an article, e.g., matrix, of a synthetic organic resin prepared from a composition comprising from about 55 to about 90 weight percent of a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), from about 10 to about 40 weight percent of an aliphatic polyurethane having terminal ethylenic unsaturation, e.g., an aliphatic polyesterurethane diacrylate, and from about 0 to about 5 weight percent of a difunctional monomer selected from the group consisting of allyl methacrylate and allyl acrylate. Such photochromic articles have an improved photochromic equilibrium response at ambient temperatures compared to the response of a comparable photochromic article prepared from a polyol(allyl carbonate) homopolymer, e.g., homopolymers of diethylene glycol bis(allyl carbonate), at the same ambient temperatures.
    Type: Grant
    Filed: January 10, 1991
    Date of Patent: May 5, 1992
    Assignee: PPG Industries, Inc.
    Inventors: Douglas S. McBain, John C. Crano
  • Patent number: 5109075
    Abstract: A copolymer of an olefinically unsaturated monomer and an allylically headed macromolecular monomer ("macromer") of a ring-openable cyclic ether ("CE") is prepared as a comb-shaped graft copolymer of macromer. A wide variety of olefinically unsaturated monomers may be used to form the copolymer. The macromer, having an allylic group near one end and a hydroxyl group at the other, is first produced by cationic ring-opening polymerization of the CE in conjunction with an unsaturated alcohol (propagator) having an allyl double bond. The polymerization to form the graft copolymer proceeds either by free radical polymerization or by metathesis polymerization. The graft copolymer of macromer has a hydrocarbon backbone and pendant chains of polymerized CE, each pendant chain terminating with an OH group.
    Type: Grant
    Filed: March 27, 1990
    Date of Patent: April 28, 1992
    Assignee: The B. F. Goodrich Company
    Inventor: Simon H. Yu
  • Patent number: 5109064
    Abstract: A curable composition formed from:(A) a copolymer that has silicon-containing functional groups capable of crosslinking by forming siloxane bonds and molecular chain containing:(1) at least one monomeric unit selected from the group consisting of short chain alkyl acrylate esters and short chain alkyl methacrylate esters, said short chain alkyl groups having 1 to 8 carbon atoms, and(2) at least one monomeric unit selected from the group consisting of long chain alkyl acrylate esters and long chain alkyl methacrylate esters, said long chain alkyl groups having 10 to 30 carbon atoms;wherein the total amount of the monomeric units (1) and (2) in said copolymer is at least 50 weight %, and(B) an oxyalkylene polymer having silicon-containing functional groups that are capable of crosslinking by forming siloxane bonds; and(C) a curing accelerator,wherein copolymer (A) is present in an amount of 5 to 5,000 parts by weight per 100 parts by weight of oxyalkylene polymer (B), and curing acelerator is present in an amou
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: April 28, 1992
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Wakabayashi, Katsuhiko Isayama
  • Patent number: 5082891
    Abstract: The curable resin composition of the present invention consists of a curable resin having uniformly dispersed therein particles of a cured silicone rubber obtained from an organosiloxane composition curable by a platinum-catalyzed hydrosilation reaction, wherein said organosiloxane composition contains reaction products of an ethylenically unsaturated epoxy compound and an ethylenically unsaturated aromatic compound with the organohydrogenpolysiloxane present in said organosiloxane composition. Either or both of the epoxy compound and the aromatic compound can be prereacted with a portion of the silicon-bonded hydrogen atoms of the organohydrogenpolysiloxane.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: January 21, 1992
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yoshitsugu Morita, Noriyasu Yokoyama, Keiji Yoshida
  • Patent number: 5071923
    Abstract: The present invention is directed to novel surface active copolymers and the use thereof in the production of polyurethane powders. More particularly, the copolymers comprise have a substantially linear structure and are obtained by copolymerization ofA) a partial reaction product of1) (meth)acrylic acid or a derivative thereof and2) a macromolecular compound substituted by at least two functional groups selected from OH and NH.sub.2, the functional groups not reacted with Al) being irreversibly blocked, withB) a urethane of 1) a long-chain alkyl isocyanate and 2) a hydroxyalkyl (meth)acrylate.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: December 10, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Tillmann Hassel, Hanns P. Muller, Hugo Vernaleken, Helmut Kipphardt, Rolf Dhein
  • Patent number: 5070166
    Abstract: Contact lenses which are optically clear, wettable, flexible, and of high oxygen permeability in the aqueous ocular environment of use, of a polymer containing polyoxyalkylene backbone units are disclosed, as well as the preparation thereof and methods of treating vision defects therewith.
    Type: Grant
    Filed: October 2, 1989
    Date of Patent: December 3, 1991
    Inventors: Kai C. Su, Frank Molock
  • Patent number: 5059641
    Abstract: Very low viscosity polymer polyols having high styrene/acrylonitrile ratios and good stability may be achieved by the use of epoxy modified polyols as dispersants. The epoxy modified polyols useful as dispersants may be made by one of three methods: (1) adding the epoxy resin internally to the modified polyol, (2) capping or coupling a polyol not containing an epoxy resin with such a resin, and (3) providing the epoxy resin both internally to the polyol and as a cap or coupler. Epoxy modified polyols having a hydroxyl to epoxy ratio of about 8 or less, made by one of these techniques, are superior dispersants and provide polymer polyols having higher styrene contents, and improved stability and viscosity properties. In one aspect, the epoxy modified polyols contain a significant amount of high moleular weight polyol adducts; generally from about 5 to about 30 wt. % of materials having a GPC molecular weight of greater than 100,000; and at least greater than 80,000.
    Type: Grant
    Filed: January 10, 1990
    Date of Patent: October 22, 1991
    Assignee: ARCO Chemical Technology, Inc.
    Inventors: John E. Hayes, Robert G. Gastinger
  • Patent number: 5041496
    Abstract: The present invention relates to hydrophilic, swellable graft copolymers composed, in random distribution, of 0.5 to 20% by weight of radicals of the general formula I ##STR1## of 79 to 99% by weight of radicals containing an acidic group, of the general formula II ##STR2## and of 0.1 to 2% by weight of radicals of a crosslinking agent which are derived from monomers having at least two olefinically unsaturated double bonds, and the radicals X, Z, m, n, z and also R.sup.1 to R.sup.4 are defined as given in the description, a process for the preparation of these graft copolymers and also their use as absorbents for water and aqueous solutions.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: August 20, 1991
    Assignee: Cassella AG
    Inventors: Friedrich Engelhardt, Ulrich Riegel, Jurgen Kuhlwein
  • Patent number: 5039769
    Abstract: Contact lenses which are optically clear, wettable, flexible, of high oxygen permeability and substantially non-swellable in the aqueous ocular environment of use, of a polymer containing polyoxyalkylene backbone units are disclosed, as well as the preparation thereof and methods of treating vision defects therewith.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: August 13, 1991
    Assignee: Ciba-Geigy Coproation
    Inventors: Frank Molock, Kai C. Su
  • Patent number: 5030691
    Abstract: A curable polymer composition which comprises:(A) a copolymer comprising a backbone which comprises (1) repeating units derived from at least one monomer selected from the group consisting of alkyl acrylates having 1 to 8 carbon atoms in the alkyl group and alkyl methacrylates having 1 to 8 carbon atoms in the alkyl group and (2) repeating units derived from at least one monomer selected from the group consisting of alkyl acrylates having at least 10 carbon atoms in the alkyl group and alkyl methacrylate having at least 10 carbon atoms in the alkyl groups and (B) an oxyalkylene base polymer having at least one silicon-containing group to the silicon atom of which at least one hydroxyl group or hydrolyzable group is bonded and which is cross linkable through formation of a siloxane bond, which composition has improved transparency and storage stability and can provide a cured material having good weather resistance.
    Type: Grant
    Filed: April 26, 1989
    Date of Patent: July 9, 1991
    Assignee: Kanegafuchi Chemical Industry Co., Ltd.
    Inventors: Shintaro Kohmitsu, Hiroshi Wakabayashi, Toshifumi Hirose, Katsuhiko Isayama
  • Patent number: 5023284
    Abstract: This invention is directed to a stabilizer useful to retard transesterification in moldable polymer blends containing polyester(s) during processing of the blends at elevated temperatures, particularly at high temperatures above about 285.degree. C. More particularly, the stabilizer comprises a phosphate-epoxy adduct. The stabilizer may optionally further comprise a reactive functionality component comprising a compound having a imide or oxazoline functionality and/or a hindered phenol component. The invention is also directed to a composition comprising the stabilizer and a particularly defined polymer blend.
    Type: Grant
    Filed: August 9, 1989
    Date of Patent: June 11, 1991
    Assignee: Ford Motor Company
    Inventors: Mo-Fung Cheung, Amos Golovoy, Henk van Oene
  • Patent number: 5019100
    Abstract: The invention relates to the use of a polymer network comprising a poly(meth) acrylate which is linked by means of oligomer chains which contain chemically bound ethylene oxide units as hydratable groups, the ethylene oxide units being present in the form of oligomer blocks containing 5/14 200 ethylene oxide units, for coating and/or impregnating a substrate or for manufacturing products such as eye lenses and matrices for immobilizing and/or the regulated release of active substances. The polymer network has improved mechanical properties and a desirable permeability to water or water vapour.
    Type: Grant
    Filed: July 1, 1988
    Date of Patent: May 28, 1991
    Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek TNO
    Inventors: Wilhelmus E. Hennink, Leendert Huizer
  • Patent number: 5011892
    Abstract: The present invention relates to hydrophilic, swellable graft copolymers composed, in random distribution, of 0.5 to 20% by weight of radicals of the general formula I ##STR1## 79 to 99% by weight of radicals containing an acidic group, of the general formula II ##STR2## and 0.1 to 2% by weight of crosslinking structures which are derived from monomers having at least two olefinically unsaturated double bonds, where the radicals X, Y, R.sup.1 to R.sup.4 and n have the meanings given in claim 1, and which are used as absorbents for water and aqueous solutions.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: April 30, 1991
    Assignee: Cassella AG
    Inventors: Friedrich Engelhardt, Ulrich Riegel
  • Patent number: 4996243
    Abstract: A composition of matter comprising an acrylamido-acyl or methacrylamido-acyl oligomer derived from at least one nucleophilic oligomer having at least one amino-, hydroxyl-, or thiol-substituted polyoxyalkylene, polyalkyleneimine, polyester, polyolefin, polyacrylate, or polysiloxane oligomer, said nucleophilic oliogmer having a molecular weight in the range of 200 to 20,000 is disclosed. Also disclosed are free radially polymerizable monomer-containing compositions containing said oligomers as well as acrylamido- and methacrylamido-acylated polymers which are the thermal or photocured products of said oligomers. In addition, a process is disclosed for providing said acrylamido- and methacrylamido-acylated oligomers which are useful, for example, in coatings, films, printing inks, adhesives, and saturants.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: February 26, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Jerald K. Rasmussen, Steven M. Heilmann, Frederick J. Palensky
  • Patent number: 4994208
    Abstract: A photochromic article having improved photochromic equilibrium response is described. In particular, a photochromic compound is incorporated into or applied to an article, e.g., matrix, of a synthetic organic resin prepared from a composition comprising from about 55 to about 90 weight percent of a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), from about 10 to about 40 weight percent of an aliphatic polyurethan having terminal ethylenic unsaturation, e.g., an aliphatic polyesterurethan diacrylate, and from about 0 to about 5 weight percent of a difunctional monomer selected from the group consisting of allyl methacrylate and allyl acrylate. Such photochromic articles have an improved photochromic equilibrium response at ambient temperatures compared to the response of a comparable photochromic article prepared from a polyol(allyl carbonate) homopolymer, e.g., homopolymers of diethylene glycol bis(allyl carbonate), at the same ambient temperatures.
    Type: Grant
    Filed: April 18, 1989
    Date of Patent: February 19, 1991
    Assignee: PPG Industries, Inc.
    Inventors: Douglas S. McBain, John C. Crano
  • Patent number: 4985473
    Abstract: Radiation curable coating compositions for providing solvent-resistant abhesive coatings comprise polyfluorinated acrylates and methacrylates, polyethylenically unsaturated crosslinking agents and a film-forming organic polymer. The compositions can be used after radiation curing to render substrates oil, soil, and water repellent. The cured compositions have particular use as release coatings in image transfer systems wherein a fused xerographic image is transferred from the release coated surface, to another surface due to the particular characteristics of the coatings. Novel poly(fluorooxyalkylene)urethane acrylate compounds are also disclosed.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: January 15, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Brian Howard Williams, Chung-I Young
  • Patent number: 4975524
    Abstract: Graft polymers which are obtainable from(A) 2%-30% by weight of an addition product from alkylene oxide onto an aliphatic alcohol which is at least trihydric having 3 to 10 carbon atoms and(B) 70%-98% by weight of a grafted-on monomer mixture of(1) 20% to 50% by weight of an N-substituted or N-unsubstituted acrylamide or methacrylamide and(2) 50% to 80% by weight of an N-vinyl-substituted amide or of a vinyl ester, derived in each case from a saturated aliphatic monocarboxylic acid,where the sums of (A) and (B), and (1) and (2) in each case add up to 100%.These novel graft polymer are suitable as dyeing assistants, particularly as padding assistants or liquor binders when dyeing cellulose fibre materials.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: December 4, 1990
    Assignee: Ciba-Geigy Corporation
    Inventor: Hans-Ulrich Berendt
  • Patent number: 4963220
    Abstract: A composition providing a two-part adhesive consists of an acrylate monomer and perester catalyst, comprising the polymerizable part, and a ferric ion-accelerated butyraldehyde/aniline activator comprising the other.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: October 16, 1990
    Assignee: Dymax Corporation
    Inventors: Andrew G. Bachmann, Robert F. Bickley
  • Patent number: 4962160
    Abstract: This invention provides novel side chain liquid crystalline polymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in electrooptic light modulator devices.
    Type: Grant
    Filed: December 1, 1987
    Date of Patent: October 9, 1990
    Assignee: Hoechst Celanese Corporation
    Inventors: Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff, Alan Buckley
  • Patent number: 4942202
    Abstract: A rubber composition that is prepared by reacting an organic peroxide, under shear deformation, with 3-70 parts by weight of silicone rubber (I), 30-97 parts by weight of a saturated elastomer (II) that substantially fails to be crosslinked with an organic peroxide when it is used alone, and 0-20 parts by weight of another elastomer (III) that is co-crosslinkable with component (I) in the presence of an organic peroxide and which is also co-crosslinkable or highly miscible with component (II) [where (I)+(II)+(III)=100 parts by weight].
    Type: Grant
    Filed: October 28, 1988
    Date of Patent: July 17, 1990
    Assignees: Japan Synthetic Rubber Co., Ltd., Toshiba Silicon Co., Ltd.
    Inventors: Yoshiaki Zama, Itsuki Umeda, Yasuhiko Takemura, Masaaki Takashima, Yuichi Funabashi, Junichiro Watanabe, Kiyoshi Takeda, Hiromichi Yoshida
  • Patent number: 4937287
    Abstract: Novel thermoplastic elastomeric graft copolymers, formed via a cycloaddition reaction of an elastomer containing carbon-carbon double bonds with an aromatic polyether, end-capped with a 1,2-dihydroarylcyclobutenyl moiety, are described. The materials exhibit improved UV and thermal oxidative stability, attractive mechanical properties, and superior heat resistance. They are uniquely suited for impact modification of various thermoplastics such as polyesters, polyether imides, and the like.
    Type: Grant
    Filed: February 17, 1988
    Date of Patent: June 26, 1990
    Assignee: Amoco Corporation
    Inventor: Barry D. Dean
  • Patent number: 4929676
    Abstract: Impact resistant polycarbonate blends, which may be extruded without pre-drying, are prepared from an aromatic polycarbonate, an aromatic polyester, a carbon monoxide polymer and a polyalkyleneoxide rubber, and optionally, a grafted copolymer or mixture of grafted copolymers.
    Type: Grant
    Filed: April 24, 1989
    Date of Patent: May 29, 1990
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner