Mixed With Aldehyde Or Aldehyde Derivative Reactant Or Polymer Therefrom Patents (Class 525/405)
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Patent number: 10138369Abstract: The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron-containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups.Type: GrantFiled: May 9, 2012Date of Patent: November 27, 2018Assignee: Saudi Aramco Technologies CompanyInventors: Scott D. Allen, Christopher A. Simoneau, Jay J. Farmer
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Patent number: 9096718Abstract: Provided is a method for improving thermal stability of polypropylene carbonate and, more particularly, a method of end capping a molecular chain of polypropylene carbonate using a urethane group by adding isocyanates or diisocyanates to a polypropylene carbonate resin, which may optionally be a mixture containing tertiary polyol, so as to delay thermal degradation of the polypropylene carbonate at a high temperature, thereby securing desired thermal stability. Especially, the method capable of being easily applied to reactive extrusion after preparing the polypropylene carbonate has been proposed, thus simplifying production processes and ensuring economical advantages. Moreover, the above method does not deteriorate transparency and specific smoke density characteristics at combustion, which are advantages of the polypropylene carbonate.Type: GrantFiled: September 8, 2014Date of Patent: August 4, 2015Assignee: SK Innovation Co., Ltd.Inventors: Seung Gweon Hong, Jae Young Park, HyeLim Kim, KwangJin Chung, MyungAhn Ok
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Patent number: 8518541Abstract: A process for producing and a powdery water-absorbing polymers comprising: about 0.01 to 20 wt. % of a fine particle with a particle size of less than about 200 ?m; about 0.001 to 10 wt. % of a thermoplastic adhesive; and about 60 to 99.998 wt. % of a water-absorbing polymer particle with a particle size of about 200 ?m and above, wherein the powdery water-absorbing polymers have: a flow value (FFC) within the range from about 1 to 13, and/or a dust portion of at most about 6 are disclosed. Also disclosed are a transport process, a composite, chemical products, and a use of a thermoplastic adhesive.Type: GrantFiled: September 7, 2012Date of Patent: August 27, 2013Assignee: Evonik Stockhausen GmbHInventors: Frank Loeker, Heinz Bremus, Scott Smith
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Patent number: 8492503Abstract: Provided herein are polymeric ?-hydroxy aldehyde or ?-hydroxy ketone reagents which can be conjugated to amine-containing compounds to form stable conjugates in a single-step reaction. In selected embodiments, the polymeric reagent itself incorporates an internal proton-abstracting (basic) functional group, to promote more efficient reaction. The substituent is appropriately situated, via a linker if necessary, to position the group for proton abstraction, preferably providing a 4- or 5-bond spacing between the abstracting atom and the hydrogen atom on the ?-carbon. Also provided are methods of using the reagents and stable, solubilized conjugates of the reagents with biologically active compounds. In preferred embodiments, the polymeric component of the reagent or conjugate is a polyethylene glycol.Type: GrantFiled: September 11, 2009Date of Patent: July 23, 2013Assignee: Nektar TherapeuticsInventors: Sean M. Culbertson, Xiaoming Shen, Antoni Kozlowski, Samuel P. McManus
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Patent number: 8318866Abstract: Molding materials and the moldings produced therefrom, containing a) polyoxymethylene in which at least 50% of the terminal groups are hydroxyl groups, which has a melt volume rate MVR of less than 20 cm3/10 minutes, measured according to ISO 1133 at 190° C. and 2.16 kg, and whose proportion of low molecular weight constituents having low molecular weights below 10 000 dalton is less than 15% by weight, based on the total mass of the polyoxymethylene, and b) a thermoplastic elastomer, are described. The moldings produced from these molding materials are distinguished by a very high notch impact strength.Type: GrantFiled: April 14, 2009Date of Patent: November 27, 2012Assignee: Ticona GmbHInventors: Klaus Kurz, Christine Koestler, Lowell Larson
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Patent number: 8288002Abstract: A process for producing and a powdery water-absorbing polymers comprising: about 0.01 to 20 wt. % of a fine particle with a particle size of less than about 200 ?m; about 0.001 to 10 wt. % of a thermoplastic adhesive; and about 60 to 99.998 wt. % of a water-absorbing polymer particle with a particle size of about 200 ?m and above, wherein the powdery water-absorbing polymers have: a flow value (FFC) within the range from about 1 to 13, and/or a dust portion of at most about 6 are disclosed. Also disclosed are a transport process, a composite, chemical products, and a use of a thermoplastic adhesive.Type: GrantFiled: September 15, 2010Date of Patent: October 16, 2012Assignee: Evonik Stockhausen GmbHInventors: Frank Loeker, Heinz Bremus, Scott Smith
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Patent number: 8258238Abstract: The invention relates to an actuator for converting between mechanical and electrical energy comprising—at least two electrodes; and—an electroactive polymer, comprising aromatic moieties in the chain and flexible moieties in the chain, the polymer further comprising side groups bound to the chain, which side groups are selected from the group consisting of polar side groups and side groups comprising an aromatic moiety. The invention further relates to a novel electroactive polymer comprising polar side groups bound to the chain.Type: GrantFiled: April 4, 2007Date of Patent: September 4, 2012Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNOInventor: Arjen Boersma
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Patent number: 8178627Abstract: Provided is an oxymethylene copolymer composition for a stretched material having a high strength and a high elastic modulus, the composition including: an oxymethylene copolymer; and a crosslinkable compound to be blended with the oxymethylene copolymer in an amount of 0.001 to 0.05 part by mass with respect to 100 parts by mass of the oxymethylene copolymer. The present invention also relates to a stretched material obtained by using the oxymethylene copolymer composition. Further, the present invention relates to a structure obtained by the secondary processing of the above stretched material, and a structure obtained by using the above oxymethylene copolymer composition in a bonding layer of the structure. The present invention also relates to a method of producing a structure, the method including: using the oxymethylene copolymer composition in a bonding layer of the structure; and removing a polyalkylene glycol component with water or a solvent.Type: GrantFiled: December 3, 2007Date of Patent: May 15, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Akira Okamura, Satoshi Nagai
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Publication number: 20120095156Abstract: Provided are a method for producing a phosphorus-containing phenolic compound in which reactivity is considerably excellent in the reaction between a phosphorus-containing compound and an aromatic nucleus of a phenol; in the case of using a polyhydric phenol or a phenolic resin as the phenol, a novel phosphorus-containing phenolic compound that serves as a curing agent for an epoxy resin and imparts excellent heat resistance to a cured product; a curable resin composition containing the novel phosphorus-containing phenolic compound; a cured product of the curable resin composition; a printed wiring board; and a semiconductor sealing material. An aromatic aldehyde (a1) having an alkoxy group as a substituent on an aromatic nucleus is allowed to react with an organic phosphorus compound (a2) intramolecularly having a P—H group or a P—OH group. The resultant reaction product is then allowed to react with a phenol (a3).Type: ApplicationFiled: August 5, 2009Publication date: April 19, 2012Applicant: DIC CorporationInventors: Koji Hayashi, Yoshiyuki Takahashi, Ichirou Ogura
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Patent number: 8106098Abstract: The present invention broadly relates to the field of protein modification, and, more specifically, to conjugates of proteins or analogs thereof to a water-soluble biocompatible polymer and methods of making and using the same.Type: GrantFiled: January 9, 2007Date of Patent: January 31, 2012Assignee: The General Hospital CorporationInventor: Mikhail I. Papisov
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Publication number: 20110224383Abstract: The present invention provides bifunctional polymers, methods of preparing the same, and intermediates thereto. These compounds are useful in a variety of applications including the PEGylation of biologically active molecules. The invention also provides methods of using said compounds and compositions thereof.Type: ApplicationFiled: March 11, 2011Publication date: September 15, 2011Applicant: INTEZYNE TECHNOLOGIES, INC.Inventors: Kevin N. Sill, Gregoire Cardoen
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Patent number: 8008428Abstract: The invention provides water-soluble compounds that include a polymer and at least one terminal azide or acetylene moiety. Also provided are highly efficient methods for the selective modification of proteins with PEG derivatives, which involves the selective incorporation of non-genetically encoded amino acids, e.g., those amino acids containing an azide or acetylene moiety, into proteins in response to a selector codon and the subsequent modification of those amino acids with a suitably reactive PEG derivative.Type: GrantFiled: January 24, 2007Date of Patent: August 30, 2011Assignee: Ambrx, Inc.Inventor: Troy E. Wilson
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Patent number: 7951878Abstract: The invention relates to a method for preparing halogen-free flameproof epoxy resins, in which a halogen-free epoxy resin is reacted with a polyfunctional aldehyde or ketone and a phosphinic acid derivative, wherein the phosphinic acid derivative contains at least one P—H-active structural unit of the formula ?PH(O) and is used in an amount equivalent to the polyfunctionality of the aldehyde or ketone, to a halogen-free flameproof epoxy resin obtainable by this method, to the use of the epoxy resin as a base material for the manufacture of printed circuit boards and printed circuits and to intermediates used to prepare the epoxy resins.Type: GrantFiled: December 12, 2006Date of Patent: May 31, 2011Assignee: Schill + Seilacher “Struktol” AktiengesellschaftInventors: Berthold Just, Holger Keller, Manfred Doering, Uwe Storzer, Sebastian Seibold
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Patent number: 7851585Abstract: The invention relates to polyacetal compositions comprising a mixture of (i) a polyacetal resin, (ii) p-aramid particles and (III) a vinyl-terminated dimethyl siloxane polymer. These compositions are useful in preparing molded articles exhibiting a good balance between high self-lubricating properties and wear resistance, and especially useful in articles that are in motion with respect to other parts they are in contact with.Type: GrantFiled: October 16, 2008Date of Patent: December 14, 2010Assignee: E. I. du Pont de Nemours and CompanyInventors: Anne-Laure Brison, Andreas Renken
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Patent number: 7842756Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.Type: GrantFiled: March 17, 2008Date of Patent: November 30, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan T. Martz, Erick B. Iezzi
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Patent number: 7834098Abstract: The invention relates to new compositions having good binder, wetting, and dispersing properties for virtually foam-free aqueous and also solventborne and solvent-free pigment preparations.Type: GrantFiled: January 25, 2006Date of Patent: November 16, 2010Assignee: Evonik Degussa GmbHInventors: Andreas Wenning, Dietmar Loest
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Patent number: 7812114Abstract: Disclosed is a process for preparing copolymer dispersions made of alkylene oxides and glycidyl ethers according to formula (I) in which R1 is hydrogen or a C1-C4-alkyl radical, R2 and R4 are an alkyl or aryl radical having 1 to 30 carbon atoms, and R3 is an alkyl or aryl radical having 1 to 50 carbon atoms, which may also contain heteroatoms. A is an alkylene unit having 2 to 6 carbon atoms. In formula (1), x is a number from 0 to 10, y is a number from 0 to 10, n is a number from 0 to 100, k is a number from 1 to 100, R5 is an acid group or hydrogen, and m is a number from 1 to 500, with the proviso that (y+n) must be at least 1.Type: GrantFiled: September 4, 2009Date of Patent: October 12, 2010Assignee: Clariant Produkte (Deutschland) GmbHInventors: Uwe Falk, Hendrik Roland Ahrens, Klaus Xaver Poellmann, Martin Glos, Eckart Kraemer
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Patent number: 7605224Abstract: Disclosed are copolymers made of alkylene oxides and glycidyl ethers according to formula (I) in which R1 is hydrogen or a C1-C4-alkyl radical, R2 and R4 are an alkyl or aryl radical having 1 to 30 carbon atoms, and R3 is an alkyl or aryl radical having 1 to 50 carbon atoms, which may also contain heteroatoms. A is an alkylene unit having 2 to 6 carbon atoms. In formula (1), x is a number from 0 to 10, y is a number from 0 to 10, n is a number from 0 to 100, k is a number from 1 to 100, R5 is an acid group or hydrogen, and m is a number from 1 to 500, with the proviso that (y+n) must be at least 1.Type: GrantFiled: May 14, 2008Date of Patent: October 20, 2009Assignee: Clariant Produkte (Deutschland) GmbHInventors: Uwe Falk, Hendrik Ahrens, Klaus Poellmann, Martin Glos, Eckart Kraemer
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Patent number: 7538162Abstract: This invention relates to a one-stage process for the production of polyoxyalkylene containing polyols having equivalent weights of about 150 to about 6000 and functionalities of about 2 to 8. The process comprises (1) mixing (a) an organic compound having a hydroxyl functionality of about 2 to about 8 and an equivalent weight of about 35 to about 575, with (b) a hydroxyl functional compound having an equivalent weight of about 100 to about 6000 and a functionality of about 2 to 8; and (2) alkoxylating the mixture with (c) one or more alkylene oxides, in the presence of (d) one or more double metal cyanide catalysts. Suitable compounds to be used as (a) the organic compound having a hydroxyl functionality of about 2 to about 8 and an equivalent weight of about 35 to about 575 in the present invention include bisphenol-A, Bisphenol TMC, tetrabromobisphenol A, and novolak phenolic resins.Type: GrantFiled: June 23, 2006Date of Patent: May 26, 2009Assignee: Bayer MaterialScience LLCInventors: Karl W. Haider, Stanley L. Hager, Jack R. Reese, II
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Patent number: 7425594Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.Type: GrantFiled: November 23, 2005Date of Patent: September 16, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan T. Martz, Stephen J. Thomas
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Publication number: 20080200617Abstract: The invention relates to a method for preparing halogen-free flameproof epoxy resins, in which a halogen-free epoxy resin is reacted with a polyfunctional aldehyde or ketone and a phosphinic acid derivative, wherein the phosphinic acid derivative contains at least one P—H-active structural unit of the formula ?PH(O) and is used in an amount equivalent to the polyfunctionality of the aldehyde or ketone, to a halogen-free flameproof epoxy resin obtainable by this method, to the use of the epoxy resin as a base material for the manufacture of printed circuit boards and printed circuits and to intermediates used to prepare the epoxy resins.Type: ApplicationFiled: December 12, 2006Publication date: August 21, 2008Inventors: Berthold Just, Holger Keller, Manfred Doering, Uwe Storzer, Sebastian Seibold
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Patent number: 7323521Abstract: Comb polymers prepared by reacting an epoxy resin and a lactone are disclosed. These comb polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described comb polymers are also disclosed.Type: GrantFiled: March 19, 2004Date of Patent: January 29, 2008Assignee: PP6 Industries Ohio, Inc.Inventors: Michael J. Ziegler, Anthony M. Chasser, Jackie L. Kulfan
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Patent number: 7230068Abstract: The invention provides water-soluble compounds that include a polymer and at least one terminal azide or acetylene moiety. Also provided are highly efficient methods for the selective modification of proteins with PEG derivatives, which involves the selective incorporation of non-genetically encoded amino acids, e.g., those amino acids containing an azide or acetylene moiety, into proteins in response to a selector codon and the subsequent modification of those amino acids with a suitably reactive PEG derivative.Type: GrantFiled: October 7, 2004Date of Patent: June 12, 2007Assignee: Ambrx, Inc.Inventor: Troy E. Wilson
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Patent number: 7217769Abstract: A medical device with a hydrophilic and lubricious coating, wherein the coating includes a hydrophilic polymeric unit layer deposited on the medical device and cross-linked with a plasma deposited double bond monomer. The hydrophilic polymeric unit can include ethylene oxide with one or more primary or secondary alcohol groups or glycosaminoglycans such as hyaluronic acid, and the double bond monomer includes monomers containing at least one double bond, preferably a C?C, C?N or C?O bond, including N-trimethylsilyl-allylamine, ethylene, propylene and allyl alcohol.Type: GrantFiled: July 16, 2004Date of Patent: May 15, 2007Assignee: BioSurface Engineering Technologies, Inc.Inventors: Paul O. Zamora, Meng Chen, Shigemasa Osaki, Ting-Ting Hsieh, Ray Tsang
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Patent number: 7160924Abstract: The present invention broadly relates to the field of protein modification, and, more specifically, to conjugates of proteins or analogs thereof to a water-soluble biocompatible polymer and methods of making and using the same.Type: GrantFiled: July 18, 2003Date of Patent: January 9, 2007Assignees: The General Hospital Corporation, Amgen, Inc.Inventors: Olaf B. Kinstler, David L. Ladd, Mikahil I. Papisov
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Patent number: 7109258Abstract: A polymeric material with antistatic properties, characterised by comprising a dispersion of ions within a polymeric matrix containing heteroatoms.Type: GrantFiled: January 5, 2000Date of Patent: September 19, 2006Assignees: Cryvet S.R.L.Inventors: Gualtiero Valeri, Vito Di Noto
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Patent number: 6962958Abstract: A reaction product is useful as a crosslinking agent for polymers having functional groups reactive with the reaction product such as hydroxyl, carboxylic acid, amide, thiol, urea, carbamate and/or thiocarbamate groups, wherein the polymer includes an acrylic, polyester, polyether and/or polyurethane. The reaction product is derived from a) a polyisocyanate or polyisocyanurate, b) a hydroxyalkyl carbamate, c) an aldehyde and d) at least one monohydric alcohol.Type: GrantFiled: February 5, 2004Date of Patent: November 8, 2005Assignee: PPG Industries Ohio, Inc.Inventors: Michael A. Mayo, Steven V. Barancyk, Jane N. Valenta, Sherry M. Gaggini, William A. Humphrey
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Patent number: 6903165Abstract: A process for producing an epoxidized diene polymer includes: dispersing or suspending a diene polymer (C) having a ball-reduced particle size of 0.05-20 mm in a medium (A) in the presence of powder particles (B) insoluble in the medium (A), or in an aqueous medium in the presence of a phenol-based stabilizer and/or a phosphorus-based stabilizer; and epoxidizing the diene polymer (C) by an epoxidizing agent, therefore, problems associated with epoxidation performed by dissolving diene polymer in a solvent are eliminated; an economical method for epoxidizing, producing, and purifying a diene polymer (C) in a solid form is provided; and the epoxidized diene polymer having an excellent heat stability can be obtained.Type: GrantFiled: May 13, 2002Date of Patent: June 7, 2005Assignee: Daicel Chemical Industries, Ltd.Inventors: Akihiro Yabui, Yoshihiro Ohtsuka
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Patent number: 6830815Abstract: The present invention relates to an anti-friction and anti-wear liquid coating composition for use with parts made of materials that have softening points below about 300° F. and articles so coated. The present invention also relates to a method of coating parts made from a low softening point materials with an anti-friction and anti-wear hard coating composition. The coating composition comprises a mixture of (i) solid lubricants comprising boron nitride, graphite and molybdenum disulfide, (ii) a thermoset resin system, (iii) catalyst for curing the resin system and (iv) a solvent system comprising highly volatile solvents. The coating composition is applied to the part and cured to form a coating on the part.Type: GrantFiled: April 2, 2002Date of Patent: December 14, 2004Assignee: Ford Motor CompanyInventor: V. Durga Nageswar Rao
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Publication number: 20040171760Abstract: A process for preparing thermoplastic poly(3-hydroxyalkanoates) with a molar mass greater than 6 000 g/mol and a melting point in the range from 70 to 170° C., by reacting an oxirane compound with carbon monoxide in the presence of a transition metal catalyst which has rhodium(0), nickel(0), iron(0), cobalt(0) or palladium(0) as central metal and has been chelated with neutral Lewis bases, and also in the presence of diisocyanates, ortho esters, acetals, anhydrides, P2O5, MgO, MgCl2, MgSO4, zeolites, or a mixture of these, at a pressure in the range from 1 to 250 bar and at from room temperature to 150° C.Type: ApplicationFiled: January 20, 2004Publication date: September 2, 2004Inventors: Michael Slany, Gerrit Luinstra, Xavier Sava
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Patent number: 6765069Abstract: A method for making a hydrophilic and lubricious coating, the coating so made and a medical device including such coating, wherein the coating includes a hydrophilic polymeric unit layer cross-linked with a plasma deposited double bond monomer. The hydrophilic polymeric unit can include ethylene oxide with one or more primary or secondary alcohol groups or glycosaminoglycans such as hyaluronic acid, and the double bond monomer includes monomers containing at least one double bond, preferably a C═C, C═N or C═O bond, including N-trimethylsilyl-allylamine, ethylene, propylene and allyl alcohol. The invention also provides products containing such coatings and their uses in medical, pharmaceutical and cosmetic applications.Type: GrantFiled: September 27, 2002Date of Patent: July 20, 2004Assignee: BioSurface Engineering Technologies, Inc.Inventors: Paul O. Zamora, Meng Chen, Shigemas Osaki, Ting-Ting Hsieh, Ray Tsang
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Patent number: 6734260Abstract: The present invention provides a cationic coating composition capable of forming a coating film which is excellent in an electrodepositablly coating property and an adhesive property toward a rust preventive steel plate, a corrosion resistance and a low temperature curability. The cationic coating composition described above comprises as a vehicle component, a xylene-formaldehyde resin-modified, amino group-containing epoxy resin obtained by reacting an epoxy resin (A) having an epoxy equivalent of 180 to 2500 with a xylene-formaldehyde resin (B) and an amino group-containing compound (C).Type: GrantFiled: November 15, 2002Date of Patent: May 11, 2004Assignee: Kansai Paint Co., Ltd.Inventors: Shigeo Nishiguchi, Koji Kamikado, Susumu Midogochi, Akira Tominaga, Akihiko Shimasaki, Hideki Iijima
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Patent number: 6706850Abstract: A polyether copolymer comprising (A) an aromatic polyether block and (B) an aliphatic polyether block is provided.Type: GrantFiled: April 13, 2001Date of Patent: March 16, 2004Assignee: Sumitomo Chemical Company, LimitedInventors: Yuji Yoshida, Akira Yokota, Hyuncheol Choi
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Patent number: 6670041Abstract: Water-dilutable binders which are self-crosslinking at room temperature, comprising reaction products ABF with epoxy-amine adducts A and formaldehyde resin formers B selected from phenols B1, (substituted) ureas B2, melamine B3, guanamines B4, and mixtures of said resin formers, with formaldehyde F or compounds which give off formaldehyde under the reaction conditions, may be formulated, following at least partial neutralization, to give aqueous coating materials which give coatings affording outstanding corrosion protection.Type: GrantFiled: November 2, 2001Date of Patent: December 30, 2003Assignee: Solutia Austria GmbHInventors: Willibald Paar, Roland Feola, Johann Gmoser, Michael Gobec
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Patent number: 6576740Abstract: A polyoxymethylene having enhanced thermal stability and resistance to depolymerization is obtained by using an alkylated melamine compound of formula (1) as a polymerization terminating agent in a polymerization of formaldehyde or a cyclic oligomer thereof and an optional comonomer in the presence of an acid catalyst: wherein, R1 to R6 are each independently H, C1-4 alkyl or CH2OR7; R7 is H, C1-4 alkyl or R8COOR9; R8 is —(CH2)n—, n being an integer of 1 to 4; and R9 is C1-4 alkyl.Type: GrantFiled: January 9, 2002Date of Patent: June 10, 2003Assignee: Korea Engineering Plastics Co., Ltd.Inventors: Chong-Won Chin, Young-Heup Kim, Kyung-Seob Byun
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Patent number: 6492462Abstract: The rheological properties of a crosslinkable resin system are modified by the presence of a side chain crystalline (SCC) polymer (or a similar crystalline polymer which melts over a narrow temperature range). The polymer dissolves in the curable system at temperatures above the melting point of the crystalline polymer (Tp), but when the system is then cooled to a temperature below Tp, at least partially forms a separate phase in the curable system. Below Tp, this separate phase substantially increases the viscosity of the curable system (i.e. makes it thicker than the same system without the crystalline polymer). This is particularly valuable for sheet molding composites (SMCs) in which the increase in viscosity makes the composites less tacky, and for dry film resists (DFRs). Above Tp, the curable system containing the dissolved crystalline polymer has a viscosity which is substantially less than its viscosity below Tp.Type: GrantFiled: December 19, 2000Date of Patent: December 10, 2002Assignee: Landec CorporationInventors: Steven P. Bitler, David D. Taft, Ray F. Stewart
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Publication number: 20010016624Abstract: A heterobifunctional poly(ethylene glycol) is provided having a hydrolytically degradable linkage, a first terminus comprising an acrylate group, and a second terminus comprising a target such as a protein or pharmaceutical agent or a reactive moiety capable of coupling to a target. Hydrogels can be prepared. The hydrogels can be used as a carrier for a protein or a pharmaceutical agent that can be readily released in a controlled fashion.Type: ApplicationFiled: April 2, 2001Publication date: August 23, 2001Applicant: Debio Recherche Pharmaceutique S.A.Inventors: J. Milton Harris, Xuan Zhao
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Patent number: 5969054Abstract: The present invention relates to binder compositions containingA) 40 to 95 parts by weight of OH-functional graft copolymer resins prepared by copolymerizinga) 0.1 to 10 parts by weight of polybutadienes containing at least 20% of 1,2-vinyl groups,b) 5 to 30 parts by weight of aliphatic .alpha.-olefins,c) 0.1 to 35 parts by weight of glycidyl esters of .alpha.-alkylalkane-monocarboxylic acids,d) 10 to 70 parts by weight of unsaturated, aromatic monomers,e) 5 to 60 parts by weight of hydroxyalkyl esters of acrylic and/or methacrylic acid having primary hydroxyl groups,f) 0 to 50 parts by weight of (cyclo)aliphatic esters of acrylic and/or methacrylic acid,g) 0.1 to 20 parts by weight of .alpha.,.beta.Type: GrantFiled: July 7, 1997Date of Patent: October 19, 1999Assignee: Bayer AktiengesellschaftInventors: Christian Wamprecht, Michael Sonntag, Dieter Margotte
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Patent number: 5965671Abstract: Modified resole and novolac type phenolic resins which are toughened by poly(alkylene oxide) are disclosed. The modified resole type phenolic resin is prepared by the following steps: mixing a poly(alkylene oxide) having a weight average molecular weight of 100,000.about.8,000,000 and phenol in a weight ratio of poly(alkylene oxide): phenol=1.5:1.about.1:1 at an elevated temperature to form a glutinous mixture; mixing the glutinous mixture with an acid catalyst to obtain a viscous mixture having a relatively low viscosity compared to the glutinous mixture; and mixing the viscose mixture with a resole type phenolic resin. The modified novolac type phenolic resin is prepared by directly mixing the glutinous mixture with a liquid novolac type phenolic resin. The amount of the poly(alkylene oxide) mixed is 2.about.10 wt % based on the phenolic resin.Type: GrantFiled: March 5, 1998Date of Patent: October 12, 1999Assignee: National Science CouncilInventors: Chen-Chi Martin Ma, Hew-Der Wu, Chih-Tsung Lee
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Patent number: 5958398Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.Type: GrantFiled: December 7, 1998Date of Patent: September 28, 1999Assignee: The General Hospital CorporationInventor: Mikhail I. Papisov
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Patent number: 5912305Abstract: Thermoplastic molding materials containA) from 50 to 99% by weight, based on the total weight of the molding material, of a toughened polymer,B) from 1 to 20% by weight, based on the total weight of the molding material, of a blend ofB.sub.1) a copolymer comprising polymerized units which are derived from a polymerizable carboxylic acid or derivatives thereof andB.sub.2) a polyamide,C) from 0 to 40% by weight of a fibrous or particulate filler or of a mixture thereof andD) from 0 to 20% by weight of conventional additives and processing assistants.Type: GrantFiled: December 29, 1997Date of Patent: June 15, 1999Assignee: BASF AktiengesellschaftInventors: Graham Edmund Mc Kee, Jurgen Koch, Wolfgang Fischer, Axel Gottschalk, Norbert Guntherberg, Bernhard Rosenau
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Patent number: 5889124Abstract: A curable resin composition containing (a) an oxyalkylene polymer which comprises at least one silicon-containing group having at least one hydroxyl or hydrolyzable group bonded to a silicon atom, (b) an epoxy resin, (c) a ketimine compound and (d) a carbonyl compound, which has improved storage stability.Type: GrantFiled: March 4, 1997Date of Patent: March 30, 1999Assignee: Kaneka CorporationInventors: Katsuhiro Ando, Jun Hattori, Toshifumi Hirose
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Patent number: 5854324Abstract: A polyacetal resin composition having excellent friction resistance and abrasion resistance performances is provided by improving the compatibility, dispersibility and interfacial adhesiveness between the polyacetal resin and an olefinic polymer.To a polyacetal resin (A), 1 to 100 parts by weight based on 100 parts by weight of the resin (A) of a modified olefinic polymer (B) modified with at least one member selected from the group consisting of an unsaturated carboxylic acid and an acid anhydride thereof, and their derivatives, and 0.1 to 100% by weight based on component (B) of an alkylene glycol polyme (C)r having a primary or secondary amino group(s) and having a number-average molecular weight of 400 to 500,000 are blended.Type: GrantFiled: September 24, 1997Date of Patent: December 29, 1998Assignee: Polyplastics Co., Ltd.Inventors: Yoshihisa Tajima, Hiroyuki Sano, Katsunori Takayama
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Patent number: 5844059Abstract: To prepare a thermally very stable polyacetal copolymer containing a very small amount of unstable parts in a high yield according to a simple process wherein an isopolyacid or an acid salt thereof is used as the polymerization catalyst in the copolymerization of trioxane as the principal monomer with a comonomer copolymerizable therewith, and wherein deactivation of the catalyst can be effected simply without fail through contact with a basic gas after polymerization without the necessity for any washing step. In the preparation of a polyacetal copolymer by the copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon--carbon bond as a comonomer, the copolymerization is effected using an isopolyacid or an acid salt thereof as the polymerization catalyst, followed by contact with a basic gas as a deactivator to deactivate the catalyst, and subsequent heat-melting treatment of the resulting crude polymer intact without washing thereof.Type: GrantFiled: January 27, 1997Date of Patent: December 1, 1998Assignee: Polyplastics Co., Ltd.Inventors: Kaoru Yamamoto, Hiroyuki Kanai
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Patent number: 5811510Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.Type: GrantFiled: April 14, 1995Date of Patent: September 22, 1998Assignee: General Hospital CorporationInventor: Mikhail I. Papisov
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Patent number: 5760142Abstract: Epoxide-amine dendrimers synthesized by a repetitive and step-wise addition reaction of epoxides comprising functional moieties which are available for conversion into amino groups followed by a reaction of these groups to primary amino moieties. The amino terminated dendrimers are reacted with (2,3-epoxypropoxy) methacrylate, a monoepoxide and/or a monoisocyante. The methacrylate terminated dendrimers are polymerizable using redox initiators and/or photoinitiators. The resulting dendrimers show a very low volume shrinkage from that of the starting materials, on the order of less than about 5 percent by volume.Type: GrantFiled: December 4, 1996Date of Patent: June 2, 1998Assignee: Dentsply DeTrey G.m.b.H.Inventor: Joachim E. Klee
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Patent number: 5723142Abstract: A method of masking the cornea of an eye during surgical application of laser energy by forming an ablatable mask on the eye.Type: GrantFiled: October 11, 1994Date of Patent: March 3, 1998Inventor: Barry L. Bowyer
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Patent number: 5693709Abstract: Polyoxymethylene with improved acid stability, process for production and use thereof. By adding 0.01 to 5 parts of an alkali metal salt of a polybasic acid, for example oxalic acid, citric acid and/or 0.01 to 5 parts of a polyalkylene glycol, for example polyethylene glycol and/or 0.1 to 100 parts of a thermoplastic polyurethane, each related to 100 parts of a polyoxymethylene, this polymer is stabilized against attack by acids, wherein in particular the combination of an alkali metal salt, in particular an oxalate, with small proportions of a thermoplastic polyurethane is advantageous. The proportion of thermoplastic polyurethane may be reduced when the thermoplastic polyurethane has a Shore A hardness of 70 to 96. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The products are useful when exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.Type: GrantFiled: August 26, 1996Date of Patent: December 2, 1997Assignee: Degussa AktiengesellschaftInventors: Edwin Nun, Stephanie Schauhoff, Detlef Arnoldi
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Patent number: 5688897Abstract: The present invention provides a method for producing an oxymethylene copolymer, which comprises:copolymerizing trioxane and a cyclic ether and/or a cyclic formal in the presence of at least one selected from the group consisting of boron trifluoride, boron trifluoride hydrate, and a coordination compound of an organic compound having an oxygen or a sulphur atom with boron trifluoride,volatilizing the residual polymerization catalyst to decrease its amount, by heating the obtained oxymethylene copolymer in an atmosphere of inert gas at or below its melting point, and/or reducing the pressure, without conducting any operation of deactivating the residual polymerization catalyst before volatilizing the residual polymerization catalyst, andstabilizing terminal moities of the oxymethylene copolymer after deactivating residual catalyst or stabilizing terminal moieties of the oxymethylene copolymer directly.Type: GrantFiled: July 10, 1996Date of Patent: November 18, 1997Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Noritaka Tanimura, Yukio Tanigawa, Sumio Komatsu
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Patent number: 5591808Abstract: A composition of acetal resin infused with one or more polyglycols to impart an improved tribological property. The composition is produced by mixing a powdered or granulated polyoxymethylene homopolymer (or copolymer) in the range from about 75% to about 95% by weight, with from about 25 to about 5% by weight of one or more polyglycols. Examples disclosed include compositions in which the single polyglycol comprises a polyethylene glycol, an ethylene oxide-propylene glycol monobutyl ether, a diethylene glycol n-butyl ether, an ethylene oxide-propylene oxide polyglycol, and a propylene glycol monobutyl ether. Preferably, if an oil soluble polyglycol is added, either a polyethylene glycol or a propylene glycol monobutyl ether is included to serve as a compatibilizer for the oil soluble polyglycol.Type: GrantFiled: October 3, 1994Date of Patent: January 7, 1997Assignee: E/M CorporationInventor: Warren E. Jamison