Mixed With Aldehyde Or Aldehyde Derivative Reactant Or Polymer Therefrom Patents (Class 525/405)
  • Patent number: 10138369
    Abstract: The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron-containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups.
    Type: Grant
    Filed: May 9, 2012
    Date of Patent: November 27, 2018
    Assignee: Saudi Aramco Technologies Company
    Inventors: Scott D. Allen, Christopher A. Simoneau, Jay J. Farmer
  • Patent number: 9096718
    Abstract: Provided is a method for improving thermal stability of polypropylene carbonate and, more particularly, a method of end capping a molecular chain of polypropylene carbonate using a urethane group by adding isocyanates or diisocyanates to a polypropylene carbonate resin, which may optionally be a mixture containing tertiary polyol, so as to delay thermal degradation of the polypropylene carbonate at a high temperature, thereby securing desired thermal stability. Especially, the method capable of being easily applied to reactive extrusion after preparing the polypropylene carbonate has been proposed, thus simplifying production processes and ensuring economical advantages. Moreover, the above method does not deteriorate transparency and specific smoke density characteristics at combustion, which are advantages of the polypropylene carbonate.
    Type: Grant
    Filed: September 8, 2014
    Date of Patent: August 4, 2015
    Assignee: SK Innovation Co., Ltd.
    Inventors: Seung Gweon Hong, Jae Young Park, HyeLim Kim, KwangJin Chung, MyungAhn Ok
  • Patent number: 8518541
    Abstract: A process for producing and a powdery water-absorbing polymers comprising: about 0.01 to 20 wt. % of a fine particle with a particle size of less than about 200 ?m; about 0.001 to 10 wt. % of a thermoplastic adhesive; and about 60 to 99.998 wt. % of a water-absorbing polymer particle with a particle size of about 200 ?m and above, wherein the powdery water-absorbing polymers have: a flow value (FFC) within the range from about 1 to 13, and/or a dust portion of at most about 6 are disclosed. Also disclosed are a transport process, a composite, chemical products, and a use of a thermoplastic adhesive.
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: August 27, 2013
    Assignee: Evonik Stockhausen GmbH
    Inventors: Frank Loeker, Heinz Bremus, Scott Smith
  • Patent number: 8492503
    Abstract: Provided herein are polymeric ?-hydroxy aldehyde or ?-hydroxy ketone reagents which can be conjugated to amine-containing compounds to form stable conjugates in a single-step reaction. In selected embodiments, the polymeric reagent itself incorporates an internal proton-abstracting (basic) functional group, to promote more efficient reaction. The substituent is appropriately situated, via a linker if necessary, to position the group for proton abstraction, preferably providing a 4- or 5-bond spacing between the abstracting atom and the hydrogen atom on the ?-carbon. Also provided are methods of using the reagents and stable, solubilized conjugates of the reagents with biologically active compounds. In preferred embodiments, the polymeric component of the reagent or conjugate is a polyethylene glycol.
    Type: Grant
    Filed: September 11, 2009
    Date of Patent: July 23, 2013
    Assignee: Nektar Therapeutics
    Inventors: Sean M. Culbertson, Xiaoming Shen, Antoni Kozlowski, Samuel P. McManus
  • Patent number: 8318866
    Abstract: Molding materials and the moldings produced therefrom, containing a) polyoxymethylene in which at least 50% of the terminal groups are hydroxyl groups, which has a melt volume rate MVR of less than 20 cm3/10 minutes, measured according to ISO 1133 at 190° C. and 2.16 kg, and whose proportion of low molecular weight constituents having low molecular weights below 10 000 dalton is less than 15% by weight, based on the total mass of the polyoxymethylene, and b) a thermoplastic elastomer, are described. The moldings produced from these molding materials are distinguished by a very high notch impact strength.
    Type: Grant
    Filed: April 14, 2009
    Date of Patent: November 27, 2012
    Assignee: Ticona GmbH
    Inventors: Klaus Kurz, Christine Koestler, Lowell Larson
  • Patent number: 8288002
    Abstract: A process for producing and a powdery water-absorbing polymers comprising: about 0.01 to 20 wt. % of a fine particle with a particle size of less than about 200 ?m; about 0.001 to 10 wt. % of a thermoplastic adhesive; and about 60 to 99.998 wt. % of a water-absorbing polymer particle with a particle size of about 200 ?m and above, wherein the powdery water-absorbing polymers have: a flow value (FFC) within the range from about 1 to 13, and/or a dust portion of at most about 6 are disclosed. Also disclosed are a transport process, a composite, chemical products, and a use of a thermoplastic adhesive.
    Type: Grant
    Filed: September 15, 2010
    Date of Patent: October 16, 2012
    Assignee: Evonik Stockhausen GmbH
    Inventors: Frank Loeker, Heinz Bremus, Scott Smith
  • Patent number: 8258238
    Abstract: The invention relates to an actuator for converting between mechanical and electrical energy comprising—at least two electrodes; and—an electroactive polymer, comprising aromatic moieties in the chain and flexible moieties in the chain, the polymer further comprising side groups bound to the chain, which side groups are selected from the group consisting of polar side groups and side groups comprising an aromatic moiety. The invention further relates to a novel electroactive polymer comprising polar side groups bound to the chain.
    Type: Grant
    Filed: April 4, 2007
    Date of Patent: September 4, 2012
    Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO
    Inventor: Arjen Boersma
  • Patent number: 8178627
    Abstract: Provided is an oxymethylene copolymer composition for a stretched material having a high strength and a high elastic modulus, the composition including: an oxymethylene copolymer; and a crosslinkable compound to be blended with the oxymethylene copolymer in an amount of 0.001 to 0.05 part by mass with respect to 100 parts by mass of the oxymethylene copolymer. The present invention also relates to a stretched material obtained by using the oxymethylene copolymer composition. Further, the present invention relates to a structure obtained by the secondary processing of the above stretched material, and a structure obtained by using the above oxymethylene copolymer composition in a bonding layer of the structure. The present invention also relates to a method of producing a structure, the method including: using the oxymethylene copolymer composition in a bonding layer of the structure; and removing a polyalkylene glycol component with water or a solvent.
    Type: Grant
    Filed: December 3, 2007
    Date of Patent: May 15, 2012
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akira Okamura, Satoshi Nagai
  • Publication number: 20120095156
    Abstract: Provided are a method for producing a phosphorus-containing phenolic compound in which reactivity is considerably excellent in the reaction between a phosphorus-containing compound and an aromatic nucleus of a phenol; in the case of using a polyhydric phenol or a phenolic resin as the phenol, a novel phosphorus-containing phenolic compound that serves as a curing agent for an epoxy resin and imparts excellent heat resistance to a cured product; a curable resin composition containing the novel phosphorus-containing phenolic compound; a cured product of the curable resin composition; a printed wiring board; and a semiconductor sealing material. An aromatic aldehyde (a1) having an alkoxy group as a substituent on an aromatic nucleus is allowed to react with an organic phosphorus compound (a2) intramolecularly having a P—H group or a P—OH group. The resultant reaction product is then allowed to react with a phenol (a3).
    Type: Application
    Filed: August 5, 2009
    Publication date: April 19, 2012
    Applicant: DIC Corporation
    Inventors: Koji Hayashi, Yoshiyuki Takahashi, Ichirou Ogura
  • Patent number: 8106098
    Abstract: The present invention broadly relates to the field of protein modification, and, more specifically, to conjugates of proteins or analogs thereof to a water-soluble biocompatible polymer and methods of making and using the same.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: January 31, 2012
    Assignee: The General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Publication number: 20110224383
    Abstract: The present invention provides bifunctional polymers, methods of preparing the same, and intermediates thereto. These compounds are useful in a variety of applications including the PEGylation of biologically active molecules. The invention also provides methods of using said compounds and compositions thereof.
    Type: Application
    Filed: March 11, 2011
    Publication date: September 15, 2011
    Applicant: INTEZYNE TECHNOLOGIES, INC.
    Inventors: Kevin N. Sill, Gregoire Cardoen
  • Patent number: 8008428
    Abstract: The invention provides water-soluble compounds that include a polymer and at least one terminal azide or acetylene moiety. Also provided are highly efficient methods for the selective modification of proteins with PEG derivatives, which involves the selective incorporation of non-genetically encoded amino acids, e.g., those amino acids containing an azide or acetylene moiety, into proteins in response to a selector codon and the subsequent modification of those amino acids with a suitably reactive PEG derivative.
    Type: Grant
    Filed: January 24, 2007
    Date of Patent: August 30, 2011
    Assignee: Ambrx, Inc.
    Inventor: Troy E. Wilson
  • Patent number: 7951878
    Abstract: The invention relates to a method for preparing halogen-free flameproof epoxy resins, in which a halogen-free epoxy resin is reacted with a polyfunctional aldehyde or ketone and a phosphinic acid derivative, wherein the phosphinic acid derivative contains at least one P—H-active structural unit of the formula ?PH(O) and is used in an amount equivalent to the polyfunctionality of the aldehyde or ketone, to a halogen-free flameproof epoxy resin obtainable by this method, to the use of the epoxy resin as a base material for the manufacture of printed circuit boards and printed circuits and to intermediates used to prepare the epoxy resins.
    Type: Grant
    Filed: December 12, 2006
    Date of Patent: May 31, 2011
    Assignee: Schill + Seilacher “Struktol” Aktiengesellschaft
    Inventors: Berthold Just, Holger Keller, Manfred Doering, Uwe Storzer, Sebastian Seibold
  • Patent number: 7851585
    Abstract: The invention relates to polyacetal compositions comprising a mixture of (i) a polyacetal resin, (ii) p-aramid particles and (III) a vinyl-terminated dimethyl siloxane polymer. These compositions are useful in preparing molded articles exhibiting a good balance between high self-lubricating properties and wear resistance, and especially useful in articles that are in motion with respect to other parts they are in contact with.
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: December 14, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Anne-Laure Brison, Andreas Renken
  • Patent number: 7842756
    Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.
    Type: Grant
    Filed: March 17, 2008
    Date of Patent: November 30, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan T. Martz, Erick B. Iezzi
  • Patent number: 7834098
    Abstract: The invention relates to new compositions having good binder, wetting, and dispersing properties for virtually foam-free aqueous and also solventborne and solvent-free pigment preparations.
    Type: Grant
    Filed: January 25, 2006
    Date of Patent: November 16, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Andreas Wenning, Dietmar Loest
  • Patent number: 7812114
    Abstract: Disclosed is a process for preparing copolymer dispersions made of alkylene oxides and glycidyl ethers according to formula (I) in which R1 is hydrogen or a C1-C4-alkyl radical, R2 and R4 are an alkyl or aryl radical having 1 to 30 carbon atoms, and R3 is an alkyl or aryl radical having 1 to 50 carbon atoms, which may also contain heteroatoms. A is an alkylene unit having 2 to 6 carbon atoms. In formula (1), x is a number from 0 to 10, y is a number from 0 to 10, n is a number from 0 to 100, k is a number from 1 to 100, R5 is an acid group or hydrogen, and m is a number from 1 to 500, with the proviso that (y+n) must be at least 1.
    Type: Grant
    Filed: September 4, 2009
    Date of Patent: October 12, 2010
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Uwe Falk, Hendrik Roland Ahrens, Klaus Xaver Poellmann, Martin Glos, Eckart Kraemer
  • Patent number: 7605224
    Abstract: Disclosed are copolymers made of alkylene oxides and glycidyl ethers according to formula (I) in which R1 is hydrogen or a C1-C4-alkyl radical, R2 and R4 are an alkyl or aryl radical having 1 to 30 carbon atoms, and R3 is an alkyl or aryl radical having 1 to 50 carbon atoms, which may also contain heteroatoms. A is an alkylene unit having 2 to 6 carbon atoms. In formula (1), x is a number from 0 to 10, y is a number from 0 to 10, n is a number from 0 to 100, k is a number from 1 to 100, R5 is an acid group or hydrogen, and m is a number from 1 to 500, with the proviso that (y+n) must be at least 1.
    Type: Grant
    Filed: May 14, 2008
    Date of Patent: October 20, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Uwe Falk, Hendrik Ahrens, Klaus Poellmann, Martin Glos, Eckart Kraemer
  • Patent number: 7538162
    Abstract: This invention relates to a one-stage process for the production of polyoxyalkylene containing polyols having equivalent weights of about 150 to about 6000 and functionalities of about 2 to 8. The process comprises (1) mixing (a) an organic compound having a hydroxyl functionality of about 2 to about 8 and an equivalent weight of about 35 to about 575, with (b) a hydroxyl functional compound having an equivalent weight of about 100 to about 6000 and a functionality of about 2 to 8; and (2) alkoxylating the mixture with (c) one or more alkylene oxides, in the presence of (d) one or more double metal cyanide catalysts. Suitable compounds to be used as (a) the organic compound having a hydroxyl functionality of about 2 to about 8 and an equivalent weight of about 35 to about 575 in the present invention include bisphenol-A, Bisphenol TMC, tetrabromobisphenol A, and novolak phenolic resins.
    Type: Grant
    Filed: June 23, 2006
    Date of Patent: May 26, 2009
    Assignee: Bayer MaterialScience LLC
    Inventors: Karl W. Haider, Stanley L. Hager, Jack R. Reese, II
  • Patent number: 7425594
    Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: September 16, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan T. Martz, Stephen J. Thomas
  • Publication number: 20080200617
    Abstract: The invention relates to a method for preparing halogen-free flameproof epoxy resins, in which a halogen-free epoxy resin is reacted with a polyfunctional aldehyde or ketone and a phosphinic acid derivative, wherein the phosphinic acid derivative contains at least one P—H-active structural unit of the formula ?PH(O) and is used in an amount equivalent to the polyfunctionality of the aldehyde or ketone, to a halogen-free flameproof epoxy resin obtainable by this method, to the use of the epoxy resin as a base material for the manufacture of printed circuit boards and printed circuits and to intermediates used to prepare the epoxy resins.
    Type: Application
    Filed: December 12, 2006
    Publication date: August 21, 2008
    Inventors: Berthold Just, Holger Keller, Manfred Doering, Uwe Storzer, Sebastian Seibold
  • Patent number: 7323521
    Abstract: Comb polymers prepared by reacting an epoxy resin and a lactone are disclosed. These comb polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described comb polymers are also disclosed.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: January 29, 2008
    Assignee: PP6 Industries Ohio, Inc.
    Inventors: Michael J. Ziegler, Anthony M. Chasser, Jackie L. Kulfan
  • Patent number: 7230068
    Abstract: The invention provides water-soluble compounds that include a polymer and at least one terminal azide or acetylene moiety. Also provided are highly efficient methods for the selective modification of proteins with PEG derivatives, which involves the selective incorporation of non-genetically encoded amino acids, e.g., those amino acids containing an azide or acetylene moiety, into proteins in response to a selector codon and the subsequent modification of those amino acids with a suitably reactive PEG derivative.
    Type: Grant
    Filed: October 7, 2004
    Date of Patent: June 12, 2007
    Assignee: Ambrx, Inc.
    Inventor: Troy E. Wilson
  • Patent number: 7217769
    Abstract: A medical device with a hydrophilic and lubricious coating, wherein the coating includes a hydrophilic polymeric unit layer deposited on the medical device and cross-linked with a plasma deposited double bond monomer. The hydrophilic polymeric unit can include ethylene oxide with one or more primary or secondary alcohol groups or glycosaminoglycans such as hyaluronic acid, and the double bond monomer includes monomers containing at least one double bond, preferably a C?C, C?N or C?O bond, including N-trimethylsilyl-allylamine, ethylene, propylene and allyl alcohol.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: May 15, 2007
    Assignee: BioSurface Engineering Technologies, Inc.
    Inventors: Paul O. Zamora, Meng Chen, Shigemasa Osaki, Ting-Ting Hsieh, Ray Tsang
  • Patent number: 7160924
    Abstract: The present invention broadly relates to the field of protein modification, and, more specifically, to conjugates of proteins or analogs thereof to a water-soluble biocompatible polymer and methods of making and using the same.
    Type: Grant
    Filed: July 18, 2003
    Date of Patent: January 9, 2007
    Assignees: The General Hospital Corporation, Amgen, Inc.
    Inventors: Olaf B. Kinstler, David L. Ladd, Mikahil I. Papisov
  • Patent number: 7109258
    Abstract: A polymeric material with antistatic properties, characterised by comprising a dispersion of ions within a polymeric matrix containing heteroatoms.
    Type: Grant
    Filed: January 5, 2000
    Date of Patent: September 19, 2006
    Assignees: Cryvet S.R.L.
    Inventors: Gualtiero Valeri, Vito Di Noto
  • Patent number: 6962958
    Abstract: A reaction product is useful as a crosslinking agent for polymers having functional groups reactive with the reaction product such as hydroxyl, carboxylic acid, amide, thiol, urea, carbamate and/or thiocarbamate groups, wherein the polymer includes an acrylic, polyester, polyether and/or polyurethane. The reaction product is derived from a) a polyisocyanate or polyisocyanurate, b) a hydroxyalkyl carbamate, c) an aldehyde and d) at least one monohydric alcohol.
    Type: Grant
    Filed: February 5, 2004
    Date of Patent: November 8, 2005
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Michael A. Mayo, Steven V. Barancyk, Jane N. Valenta, Sherry M. Gaggini, William A. Humphrey
  • Patent number: 6903165
    Abstract: A process for producing an epoxidized diene polymer includes: dispersing or suspending a diene polymer (C) having a ball-reduced particle size of 0.05-20 mm in a medium (A) in the presence of powder particles (B) insoluble in the medium (A), or in an aqueous medium in the presence of a phenol-based stabilizer and/or a phosphorus-based stabilizer; and epoxidizing the diene polymer (C) by an epoxidizing agent, therefore, problems associated with epoxidation performed by dissolving diene polymer in a solvent are eliminated; an economical method for epoxidizing, producing, and purifying a diene polymer (C) in a solid form is provided; and the epoxidized diene polymer having an excellent heat stability can be obtained.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: June 7, 2005
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Akihiro Yabui, Yoshihiro Ohtsuka
  • Patent number: 6830815
    Abstract: The present invention relates to an anti-friction and anti-wear liquid coating composition for use with parts made of materials that have softening points below about 300° F. and articles so coated. The present invention also relates to a method of coating parts made from a low softening point materials with an anti-friction and anti-wear hard coating composition. The coating composition comprises a mixture of (i) solid lubricants comprising boron nitride, graphite and molybdenum disulfide, (ii) a thermoset resin system, (iii) catalyst for curing the resin system and (iv) a solvent system comprising highly volatile solvents. The coating composition is applied to the part and cured to form a coating on the part.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: December 14, 2004
    Assignee: Ford Motor Company
    Inventor: V. Durga Nageswar Rao
  • Publication number: 20040171760
    Abstract: A process for preparing thermoplastic poly(3-hydroxyalkanoates) with a molar mass greater than 6 000 g/mol and a melting point in the range from 70 to 170° C., by reacting an oxirane compound with carbon monoxide in the presence of a transition metal catalyst which has rhodium(0), nickel(0), iron(0), cobalt(0) or palladium(0) as central metal and has been chelated with neutral Lewis bases, and also in the presence of diisocyanates, ortho esters, acetals, anhydrides, P2O5, MgO, MgCl2, MgSO4, zeolites, or a mixture of these, at a pressure in the range from 1 to 250 bar and at from room temperature to 150° C.
    Type: Application
    Filed: January 20, 2004
    Publication date: September 2, 2004
    Inventors: Michael Slany, Gerrit Luinstra, Xavier Sava
  • Patent number: 6765069
    Abstract: A method for making a hydrophilic and lubricious coating, the coating so made and a medical device including such coating, wherein the coating includes a hydrophilic polymeric unit layer cross-linked with a plasma deposited double bond monomer. The hydrophilic polymeric unit can include ethylene oxide with one or more primary or secondary alcohol groups or glycosaminoglycans such as hyaluronic acid, and the double bond monomer includes monomers containing at least one double bond, preferably a C═C, C═N or C═O bond, including N-trimethylsilyl-allylamine, ethylene, propylene and allyl alcohol. The invention also provides products containing such coatings and their uses in medical, pharmaceutical and cosmetic applications.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: July 20, 2004
    Assignee: BioSurface Engineering Technologies, Inc.
    Inventors: Paul O. Zamora, Meng Chen, Shigemas Osaki, Ting-Ting Hsieh, Ray Tsang
  • Patent number: 6734260
    Abstract: The present invention provides a cationic coating composition capable of forming a coating film which is excellent in an electrodepositablly coating property and an adhesive property toward a rust preventive steel plate, a corrosion resistance and a low temperature curability. The cationic coating composition described above comprises as a vehicle component, a xylene-formaldehyde resin-modified, amino group-containing epoxy resin obtained by reacting an epoxy resin (A) having an epoxy equivalent of 180 to 2500 with a xylene-formaldehyde resin (B) and an amino group-containing compound (C).
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: May 11, 2004
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Shigeo Nishiguchi, Koji Kamikado, Susumu Midogochi, Akira Tominaga, Akihiko Shimasaki, Hideki Iijima
  • Patent number: 6706850
    Abstract: A polyether copolymer comprising (A) an aromatic polyether block and (B) an aliphatic polyether block is provided.
    Type: Grant
    Filed: April 13, 2001
    Date of Patent: March 16, 2004
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yuji Yoshida, Akira Yokota, Hyuncheol Choi
  • Patent number: 6670041
    Abstract: Water-dilutable binders which are self-crosslinking at room temperature, comprising reaction products ABF with epoxy-amine adducts A and formaldehyde resin formers B selected from phenols B1, (substituted) ureas B2, melamine B3, guanamines B4, and mixtures of said resin formers, with formaldehyde F or compounds which give off formaldehyde under the reaction conditions, may be formulated, following at least partial neutralization, to give aqueous coating materials which give coatings affording outstanding corrosion protection.
    Type: Grant
    Filed: November 2, 2001
    Date of Patent: December 30, 2003
    Assignee: Solutia Austria GmbH
    Inventors: Willibald Paar, Roland Feola, Johann Gmoser, Michael Gobec
  • Patent number: 6576740
    Abstract: A polyoxymethylene having enhanced thermal stability and resistance to depolymerization is obtained by using an alkylated melamine compound of formula (1) as a polymerization terminating agent in a polymerization of formaldehyde or a cyclic oligomer thereof and an optional comonomer in the presence of an acid catalyst: wherein, R1 to R6 are each independently H, C1-4 alkyl or CH2OR7; R7 is H, C1-4 alkyl or R8COOR9; R8 is —(CH2)n—, n being an integer of 1 to 4; and R9 is C1-4 alkyl.
    Type: Grant
    Filed: January 9, 2002
    Date of Patent: June 10, 2003
    Assignee: Korea Engineering Plastics Co., Ltd.
    Inventors: Chong-Won Chin, Young-Heup Kim, Kyung-Seob Byun
  • Patent number: 6492462
    Abstract: The rheological properties of a crosslinkable resin system are modified by the presence of a side chain crystalline (SCC) polymer (or a similar crystalline polymer which melts over a narrow temperature range). The polymer dissolves in the curable system at temperatures above the melting point of the crystalline polymer (Tp), but when the system is then cooled to a temperature below Tp, at least partially forms a separate phase in the curable system. Below Tp, this separate phase substantially increases the viscosity of the curable system (i.e. makes it thicker than the same system without the crystalline polymer). This is particularly valuable for sheet molding composites (SMCs) in which the increase in viscosity makes the composites less tacky, and for dry film resists (DFRs). Above Tp, the curable system containing the dissolved crystalline polymer has a viscosity which is substantially less than its viscosity below Tp.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: December 10, 2002
    Assignee: Landec Corporation
    Inventors: Steven P. Bitler, David D. Taft, Ray F. Stewart
  • Publication number: 20010016624
    Abstract: A heterobifunctional poly(ethylene glycol) is provided having a hydrolytically degradable linkage, a first terminus comprising an acrylate group, and a second terminus comprising a target such as a protein or pharmaceutical agent or a reactive moiety capable of coupling to a target. Hydrogels can be prepared. The hydrogels can be used as a carrier for a protein or a pharmaceutical agent that can be readily released in a controlled fashion.
    Type: Application
    Filed: April 2, 2001
    Publication date: August 23, 2001
    Applicant: Debio Recherche Pharmaceutique S.A.
    Inventors: J. Milton Harris, Xuan Zhao
  • Patent number: 5969054
    Abstract: The present invention relates to binder compositions containingA) 40 to 95 parts by weight of OH-functional graft copolymer resins prepared by copolymerizinga) 0.1 to 10 parts by weight of polybutadienes containing at least 20% of 1,2-vinyl groups,b) 5 to 30 parts by weight of aliphatic .alpha.-olefins,c) 0.1 to 35 parts by weight of glycidyl esters of .alpha.-alkylalkane-monocarboxylic acids,d) 10 to 70 parts by weight of unsaturated, aromatic monomers,e) 5 to 60 parts by weight of hydroxyalkyl esters of acrylic and/or methacrylic acid having primary hydroxyl groups,f) 0 to 50 parts by weight of (cyclo)aliphatic esters of acrylic and/or methacrylic acid,g) 0.1 to 20 parts by weight of .alpha.,.beta.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: October 19, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Michael Sonntag, Dieter Margotte
  • Patent number: 5965671
    Abstract: Modified resole and novolac type phenolic resins which are toughened by poly(alkylene oxide) are disclosed. The modified resole type phenolic resin is prepared by the following steps: mixing a poly(alkylene oxide) having a weight average molecular weight of 100,000.about.8,000,000 and phenol in a weight ratio of poly(alkylene oxide): phenol=1.5:1.about.1:1 at an elevated temperature to form a glutinous mixture; mixing the glutinous mixture with an acid catalyst to obtain a viscous mixture having a relatively low viscosity compared to the glutinous mixture; and mixing the viscose mixture with a resole type phenolic resin. The modified novolac type phenolic resin is prepared by directly mixing the glutinous mixture with a liquid novolac type phenolic resin. The amount of the poly(alkylene oxide) mixed is 2.about.10 wt % based on the phenolic resin.
    Type: Grant
    Filed: March 5, 1998
    Date of Patent: October 12, 1999
    Assignee: National Science Council
    Inventors: Chen-Chi Martin Ma, Hew-Der Wu, Chih-Tsung Lee
  • Patent number: 5958398
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: September 28, 1999
    Assignee: The General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5912305
    Abstract: Thermoplastic molding materials containA) from 50 to 99% by weight, based on the total weight of the molding material, of a toughened polymer,B) from 1 to 20% by weight, based on the total weight of the molding material, of a blend ofB.sub.1) a copolymer comprising polymerized units which are derived from a polymerizable carboxylic acid or derivatives thereof andB.sub.2) a polyamide,C) from 0 to 40% by weight of a fibrous or particulate filler or of a mixture thereof andD) from 0 to 20% by weight of conventional additives and processing assistants.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: June 15, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham Edmund Mc Kee, Jurgen Koch, Wolfgang Fischer, Axel Gottschalk, Norbert Guntherberg, Bernhard Rosenau
  • Patent number: 5889124
    Abstract: A curable resin composition containing (a) an oxyalkylene polymer which comprises at least one silicon-containing group having at least one hydroxyl or hydrolyzable group bonded to a silicon atom, (b) an epoxy resin, (c) a ketimine compound and (d) a carbonyl compound, which has improved storage stability.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: March 30, 1999
    Assignee: Kaneka Corporation
    Inventors: Katsuhiro Ando, Jun Hattori, Toshifumi Hirose
  • Patent number: 5854324
    Abstract: A polyacetal resin composition having excellent friction resistance and abrasion resistance performances is provided by improving the compatibility, dispersibility and interfacial adhesiveness between the polyacetal resin and an olefinic polymer.To a polyacetal resin (A), 1 to 100 parts by weight based on 100 parts by weight of the resin (A) of a modified olefinic polymer (B) modified with at least one member selected from the group consisting of an unsaturated carboxylic acid and an acid anhydride thereof, and their derivatives, and 0.1 to 100% by weight based on component (B) of an alkylene glycol polyme (C)r having a primary or secondary amino group(s) and having a number-average molecular weight of 400 to 500,000 are blended.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: December 29, 1998
    Assignee: Polyplastics Co., Ltd.
    Inventors: Yoshihisa Tajima, Hiroyuki Sano, Katsunori Takayama
  • Patent number: 5844059
    Abstract: To prepare a thermally very stable polyacetal copolymer containing a very small amount of unstable parts in a high yield according to a simple process wherein an isopolyacid or an acid salt thereof is used as the polymerization catalyst in the copolymerization of trioxane as the principal monomer with a comonomer copolymerizable therewith, and wherein deactivation of the catalyst can be effected simply without fail through contact with a basic gas after polymerization without the necessity for any washing step. In the preparation of a polyacetal copolymer by the copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon--carbon bond as a comonomer, the copolymerization is effected using an isopolyacid or an acid salt thereof as the polymerization catalyst, followed by contact with a basic gas as a deactivator to deactivate the catalyst, and subsequent heat-melting treatment of the resulting crude polymer intact without washing thereof.
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: December 1, 1998
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kaoru Yamamoto, Hiroyuki Kanai
  • Patent number: 5811510
    Abstract: The present invention relates to biodegradable biocompatible polyacetals, methods for their preparation, and methods for treating mammals by administration of biodegradable biocompatible polyacetals. A method for forming the biodegradable biocompatible polyacetals combines a glycol-specific oxidizing agent with a polysaccharide to form an aldehyde intermediate which is combined with a reducing agent to form the biodegradable biocompatible polyacetal. The resultant biodegradable biocompatible polyacetals can be chemically modified to incorporate additional hydrophilic moieties. A method for treating mammals includes the administration of the biodegradable biocompatible polyacetal in which biologically active compounds or diagnostic labels can be disposed.
    Type: Grant
    Filed: April 14, 1995
    Date of Patent: September 22, 1998
    Assignee: General Hospital Corporation
    Inventor: Mikhail I. Papisov
  • Patent number: 5760142
    Abstract: Epoxide-amine dendrimers synthesized by a repetitive and step-wise addition reaction of epoxides comprising functional moieties which are available for conversion into amino groups followed by a reaction of these groups to primary amino moieties. The amino terminated dendrimers are reacted with (2,3-epoxypropoxy) methacrylate, a monoepoxide and/or a monoisocyante. The methacrylate terminated dendrimers are polymerizable using redox initiators and/or photoinitiators. The resulting dendrimers show a very low volume shrinkage from that of the starting materials, on the order of less than about 5 percent by volume.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: June 2, 1998
    Assignee: Dentsply DeTrey G.m.b.H.
    Inventor: Joachim E. Klee
  • Patent number: 5723142
    Abstract: A method of masking the cornea of an eye during surgical application of laser energy by forming an ablatable mask on the eye.
    Type: Grant
    Filed: October 11, 1994
    Date of Patent: March 3, 1998
    Inventor: Barry L. Bowyer
  • Patent number: 5693709
    Abstract: Polyoxymethylene with improved acid stability, process for production and use thereof. By adding 0.01 to 5 parts of an alkali metal salt of a polybasic acid, for example oxalic acid, citric acid and/or 0.01 to 5 parts of a polyalkylene glycol, for example polyethylene glycol and/or 0.1 to 100 parts of a thermoplastic polyurethane, each related to 100 parts of a polyoxymethylene, this polymer is stabilized against attack by acids, wherein in particular the combination of an alkali metal salt, in particular an oxalate, with small proportions of a thermoplastic polyurethane is advantageous. The proportion of thermoplastic polyurethane may be reduced when the thermoplastic polyurethane has a Shore A hardness of 70 to 96. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The products are useful when exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: December 2, 1997
    Assignee: Degussa Aktiengesellschaft
    Inventors: Edwin Nun, Stephanie Schauhoff, Detlef Arnoldi
  • Patent number: 5688897
    Abstract: The present invention provides a method for producing an oxymethylene copolymer, which comprises:copolymerizing trioxane and a cyclic ether and/or a cyclic formal in the presence of at least one selected from the group consisting of boron trifluoride, boron trifluoride hydrate, and a coordination compound of an organic compound having an oxygen or a sulphur atom with boron trifluoride,volatilizing the residual polymerization catalyst to decrease its amount, by heating the obtained oxymethylene copolymer in an atmosphere of inert gas at or below its melting point, and/or reducing the pressure, without conducting any operation of deactivating the residual polymerization catalyst before volatilizing the residual polymerization catalyst, andstabilizing terminal moities of the oxymethylene copolymer after deactivating residual catalyst or stabilizing terminal moieties of the oxymethylene copolymer directly.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: November 18, 1997
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Noritaka Tanimura, Yukio Tanigawa, Sumio Komatsu
  • Patent number: 5591808
    Abstract: A composition of acetal resin infused with one or more polyglycols to impart an improved tribological property. The composition is produced by mixing a powdered or granulated polyoxymethylene homopolymer (or copolymer) in the range from about 75% to about 95% by weight, with from about 25 to about 5% by weight of one or more polyglycols. Examples disclosed include compositions in which the single polyglycol comprises a polyethylene glycol, an ethylene oxide-propylene glycol monobutyl ether, a diethylene glycol n-butyl ether, an ethylene oxide-propylene oxide polyglycol, and a propylene glycol monobutyl ether. Preferably, if an oil soluble polyglycol is added, either a polyethylene glycol or a propylene glycol monobutyl ether is included to serve as a compatibilizer for the oil soluble polyglycol.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: January 7, 1997
    Assignee: E/M Corporation
    Inventor: Warren E. Jamison