Abstract: The products of the invention are vinyl end-capped oligomers which have the structure as shown in FIG. 3. The products are prepared from either of two (2) precursors. The first precursor is a compound which has the structure as shown in FIG. 2. The second precursor is a complex amine salt which has the structure shown in FIG. 5.
Abstract: The products of the invention are end-capped polyimide oligomers prepared from a dianhydride of an aromatic tetracarboxylic acid such as 3,3'4,4'-benzophenonetetracarboxylic acid, an aromatic triamine, and a 1-(aminoaryl)-3-hydroxy-3-methyl-1-butyne. The structure of the polyimide oligomers is shown in FIG. 3.
Type:
Grant
Filed:
April 23, 1979
Date of Patent:
February 17, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Patricia A. Antonoplos, William J. Heilman
Abstract: The products of the invention are acetylene end-capped polyimide oligomers prepared from a dianhydride of an aromatic tetracarboxylic such as 3,3', 4,4'-benzophenonetetracarboxylic acid, an aromatic diamine, and a propargyl ester of an amino-substituted aromatic acid such as aminobenzoic acid. The structure of the polyimide oligomers is shown in FIG. 3.
Abstract: A composition comprising a thermoplastic resin and an activated mineral filler, said mineral filler consisting of particles of at least one aluminosilicate-type mineral containing alakali metal ions as cations in its crystal structure, the surfaces of said particles being covered monomolecularly with at least one ethylenically unsaturated organic acid, having 10 or less carbon atoms, which is bonded to the metal ions on the surfaces of said particles and retains ethylenic double bonds unreacted. On being mixed under application of heat to cause reaction, this composition gives a molded article excellent in compatibility and physical properties such as stiffness, toughness, ductility, fatigue properties, water resistance, transparency, etc.
Abstract: Disclosed is a rapid setting adhesive of low toxicity having high bond strength to a variety of metals and plastics, and particularly to stainless steel, polycarbonate plastics and tooth enamel. The composition consists essentially of (A) a resin which is formed from an ester of methacrylic acid with a monoalcohol containing at least one epoxy group and (B) a filler which may be any of a plurality of finely divided materials that are insoluble in ambient fluids or a mixture of such fillers, parts (A) and (B) being present in a weight ratio such that the initial mixture at ambient temperature and pressure is a viscous liquid or paste. Also included are minor amounts of a conventional polymerization catalyst and a conventional polymerization accelerator. Preferably parts (A) and (B) are packaged separately, with polymerization catalyst included in only one package.
Abstract: The disclosure describes an improved process for the preparation of uniform, spherical beads of up to 5 mm diameter of a crosslinked, water-insoluble hydrogel by suspension polymerization in a concentrated aqueous salt solution of 95-30% by weight of a monoolefinic water-soluble monomer containing at least 5% of a hydroxy substituted hydrophilic vinyl monomer with 5-70% by weight of a terminal diolefinic macromer crosslinking agent in the presence of water-insoluble, gelatinous, strong water-bonding inorganic metal hydroxides as suspending agents in the absence of excess alkali. The hydrogels have a host of pharmaceutical and industrial uses.
Type:
Grant
Filed:
June 1, 1978
Date of Patent:
September 23, 1980
Assignee:
Ciba-Geigy Corporation
Inventors:
Karl F. Mueller, Sonia J. Heiber, Walter L. Plankl
Abstract: Lactam-polyol-polyacyl lactam block terpolymers having both ester linkages and amide linkages between the monomeric segments of the terpolymer are disclosed. Also disclosed is a process for preparing the above block terpolymers comprising reacting together a lactam, polyol and polyacyl lactam in the presence of a basic lactam polymerization catalyst to form a lactam-polyol-polyacyl lactam block terpolymer.
Abstract: Release coatings are provided by including in a liquid monomer or prepolymer polymerizable by electromagnetic or ionizing radiation a waxy material of limited compatibility therein. Upon application of a film of such material by casting, coating or printing, a thin layer of the waxy material migrates to the surface to provide, after cure, the desired release properties. The thin surface layer of waxy material also tends to exclude oxygen from the film to permit radiant curing in air. Preferably the polymerizable liquid comprises acrylate monomers with or without unsaturated prepolymers co-polymerizable therewith dissolved therein. Novel prepolymers especially useful for providing release films and other radiation curable coatings are described, including the reaction product of polyamides, containing primary and secondary amine groups with unsaturated polybasic carboxylic acids and particular reaction products of polyether triols with toluene diisocyanate, modified with unsaturated monomers.
Abstract: Thermoplastic compositions are described comprising blends of chlorinated polyethylene rubber and nylon. Cured compositions in which the rubber is cross-linked are also described. The cured compositions are either thermoplastic or thermosets depending upon the curing process used in their preparation.
Abstract: A process for producing aromatic polyamides having improved nonflammability characteristics in which a polyamide substrate is contacted with a gaseous medium comprising a minor amount of a haloolefinic material and an inert diluent in the presence of light having sufficient energy to effect chemical addition of the haloolefin to said polyamide substrate.
Type:
Grant
Filed:
December 6, 1976
Date of Patent:
May 20, 1980
Inventors:
James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher, Madeline S. Toy, Roger S. Stringham
Abstract: Intimate blends of polypivalolactone resin and polycarbonate resin enable the production of molded articles exhibiting low warpage properties.
Type:
Grant
Filed:
June 8, 1978
Date of Patent:
May 6, 1980
Assignee:
Ethyl Corporation
Inventors:
Paul A. Zorzi, Jesse D. Jones, Michael E. Kucsma
Abstract: A process is disclosed for fabricating a thermoplastic, which thermoplastic is either a thermoplastic ionomer or a multiphase graft or block copolymer of the ABA (AB).sub.n, or ##STR1## wherein n is greater than 1 and wherein the polymer blocks, A and B, are each thermoplastic resins having softening points substantially above room temperature with the B block being present in at least about 30 wt. % of the total polymer. The thermoplastic composition is first suspended in finely divided form in a liquid medium in a sufficient amount such that the solids content of the resulting suspension is in the range of from about 15 to about 75 wt. %. The liquid medium must be nonvolatile and must be capable of plasticizing the B block (or the backbone if the ionomer is employed) of the thermoplastic composition above the softening point of that block but must not be capable of plasticizing the A block to a substantial extent. The suspension is then applied as a coating to any desired surface, e.g.
Abstract: A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di-carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis-primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of (a') simple bi-functional compounds selected from bis-halohydrins, bis-azetidinium, bis-haloacyl diamine and alkyl bis-halides, (b') oli
Type:
Grant
Filed:
February 27, 1978
Date of Patent:
February 19, 1980
Assignee:
L'Oreal
Inventors:
Guy Vanlerberghe, Henri Sebag, Jean-Francois Grollier, Alexandre Zysman
Abstract: Novel, unsaturated polyimide-polyester polymerization products and processes for their preparation are disclosed herein. The polyimide-esters from which the polymerization products are derived are derivatives of anhydride-terminated aromatic polyimides, from which they are prepared by esterification to provide unsaturated ester groups having a terminal --CH.dbd.CH.sub.2 group. These new compositions are crosslinked, insoluble, infusible polymers produced without by-product formation.
Abstract: Novel, unsaturated polyimide-polyesters and processes for their preparation are disclosed herein. These new polyimides are derivatives of anhydride-terminated aromatic polyimides, from which they are prepared by esterification to provide unsaturated ester groups of a terminal --CH.dbd.CH.sub.2 group. These new compositions are more tractable than the original anhydride-terminated polyimides and can be converted at appropriate lower temperatures to crosslinked, insoluble, infusible polymers without by-product formation, thereby extending greatly the applications for which the aromatic polyimides can be employed.
Abstract: Novel, unsaturated polyimide-polyester polymerization products and processes for their preparation are disclosed herein. The polyimide-esters from which the polymerization products are derived are derivatives of anhydride-terminated aromatic polyimides, from which they are prepared by esterification to provide unsaturated ester groups having a terminal --C.tbd.CH group. These new compositions are crosslinked, insoluble, infusible polymers produced without by-product formation.
Abstract: We have disclosed a new class of thermosetting copolymers derived from terephthalonitrile N,N'-dioxide and polyimide oligomer that cure through addition reactions to form essentially void-free cured resins that exhibit outstanding high temperature stability. These copolymers may be formed from either acetylene terminated polyimide oligomers or nitrile terminated polyimide oligomers. Copolymers prepared in accordance with our invention exhibit little or no outgassing during cure and are extremely useful in the preparation of laminates where high temperature stability and high strength is required.
Type:
Grant
Filed:
April 24, 1978
Date of Patent:
February 19, 1980
Assignee:
Hughes Aircraft Company
Inventors:
Norman Bilow, Abraham L. Landis, Leroy J. Miller