Mixed With Ethylenically Unsaturated Reactant Or Polymer Therefrom Patents (Class 525/426)
  • Patent number: 4251419
    Abstract: The products of the invention are vinyl end-capped oligomers which have the structure as shown in FIG. 3. The products are prepared from either of two (2) precursors. The first precursor is a compound which has the structure as shown in FIG. 2. The second precursor is a complex amine salt which has the structure shown in FIG. 5.
    Type: Grant
    Filed: April 5, 1979
    Date of Patent: February 17, 1981
    Assignee: Gulf Oil Corporation
    Inventors: William J. Heilman, Daniel J. Hurley
  • Patent number: 4251420
    Abstract: The products of the invention are end-capped polyimide oligomers prepared from a dianhydride of an aromatic tetracarboxylic acid such as 3,3'4,4'-benzophenonetetracarboxylic acid, an aromatic triamine, and a 1-(aminoaryl)-3-hydroxy-3-methyl-1-butyne. The structure of the polyimide oligomers is shown in FIG. 3.
    Type: Grant
    Filed: April 23, 1979
    Date of Patent: February 17, 1981
    Assignee: Gulf Oil Corporation
    Inventors: Patricia A. Antonoplos, William J. Heilman
  • Patent number: 4251418
    Abstract: The products of the invention are acetylene end-capped polyimide oligomers prepared from a dianhydride of an aromatic tetracarboxylic such as 3,3', 4,4'-benzophenonetetracarboxylic acid, an aromatic diamine, and a propargyl ester of an amino-substituted aromatic acid such as aminobenzoic acid. The structure of the polyimide oligomers is shown in FIG. 3.
    Type: Grant
    Filed: April 27, 1979
    Date of Patent: February 17, 1981
    Assignee: Gulf Oil Corporation
    Inventors: Wai Y. Chow, S. Paul Thackaberry
  • Patent number: 4242251
    Abstract: A composition comprising a thermoplastic resin and an activated mineral filler, said mineral filler consisting of particles of at least one aluminosilicate-type mineral containing alakali metal ions as cations in its crystal structure, the surfaces of said particles being covered monomolecularly with at least one ethylenically unsaturated organic acid, having 10 or less carbon atoms, which is bonded to the metal ions on the surfaces of said particles and retains ethylenic double bonds unreacted. On being mixed under application of heat to cause reaction, this composition gives a molded article excellent in compatibility and physical properties such as stiffness, toughness, ductility, fatigue properties, water resistance, transparency, etc.
    Type: Grant
    Filed: July 26, 1979
    Date of Patent: December 30, 1980
    Assignees: Asahi Kasei Kogyo Kabushiki Kaisha, Shiraishi Central Laboratories Co., Ltd.
    Inventors: Itsuho Aishima, Junji Seki, Koichi Matsumoto, Yonemasa Furusawa, Ryogo Tsukisaka, Yuhachi Takahashi
  • Patent number: 4228062
    Abstract: Disclosed is a rapid setting adhesive of low toxicity having high bond strength to a variety of metals and plastics, and particularly to stainless steel, polycarbonate plastics and tooth enamel. The composition consists essentially of (A) a resin which is formed from an ester of methacrylic acid with a monoalcohol containing at least one epoxy group and (B) a filler which may be any of a plurality of finely divided materials that are insoluble in ambient fluids or a mixture of such fillers, parts (A) and (B) being present in a weight ratio such that the initial mixture at ambient temperature and pressure is a viscous liquid or paste. Also included are minor amounts of a conventional polymerization catalyst and a conventional polymerization accelerator. Preferably parts (A) and (B) are packaged separately, with polymerization catalyst included in only one package.
    Type: Grant
    Filed: May 2, 1978
    Date of Patent: October 14, 1980
    Assignee: Lee Pharmaceuticals
    Inventors: Henry L. Lee, Jr., Jan A. Orlowski
  • Patent number: 4224427
    Abstract: The disclosure describes an improved process for the preparation of uniform, spherical beads of up to 5 mm diameter of a crosslinked, water-insoluble hydrogel by suspension polymerization in a concentrated aqueous salt solution of 95-30% by weight of a monoolefinic water-soluble monomer containing at least 5% of a hydroxy substituted hydrophilic vinyl monomer with 5-70% by weight of a terminal diolefinic macromer crosslinking agent in the presence of water-insoluble, gelatinous, strong water-bonding inorganic metal hydroxides as suspending agents in the absence of excess alkali. The hydrogels have a host of pharmaceutical and industrial uses.
    Type: Grant
    Filed: June 1, 1978
    Date of Patent: September 23, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Karl F. Mueller, Sonia J. Heiber, Walter L. Plankl
  • Patent number: 4223112
    Abstract: Lactam-polyol-polyacyl lactam block terpolymers having both ester linkages and amide linkages between the monomeric segments of the terpolymer are disclosed. Also disclosed is a process for preparing the above block terpolymers comprising reacting together a lactam, polyol and polyacyl lactam in the presence of a basic lactam polymerization catalyst to form a lactam-polyol-polyacyl lactam block terpolymer.
    Type: Grant
    Filed: March 3, 1975
    Date of Patent: September 16, 1980
    Assignee: Monsanto Company
    Inventors: Ross M. Hedrick, James D. Gabbert
  • Patent number: 4218294
    Abstract: Release coatings are provided by including in a liquid monomer or prepolymer polymerizable by electromagnetic or ionizing radiation a waxy material of limited compatibility therein. Upon application of a film of such material by casting, coating or printing, a thin layer of the waxy material migrates to the surface to provide, after cure, the desired release properties. The thin surface layer of waxy material also tends to exclude oxygen from the film to permit radiant curing in air. Preferably the polymerizable liquid comprises acrylate monomers with or without unsaturated prepolymers co-polymerizable therewith dissolved therein. Novel prepolymers especially useful for providing release films and other radiation curable coatings are described, including the reaction product of polyamides, containing primary and secondary amine groups with unsaturated polybasic carboxylic acids and particular reaction products of polyether triols with toluene diisocyanate, modified with unsaturated monomers.
    Type: Grant
    Filed: September 21, 1977
    Date of Patent: August 19, 1980
    Assignee: Design Cote Corp.
    Inventor: Karl Brack
  • Patent number: 4207404
    Abstract: Thermoplastic compositions are described comprising blends of chlorinated polyethylene rubber and nylon. Cured compositions in which the rubber is cross-linked are also described. The cured compositions are either thermoplastic or thermosets depending upon the curing process used in their preparation.
    Type: Grant
    Filed: December 6, 1978
    Date of Patent: June 10, 1980
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Raman Patel
  • Patent number: 4203723
    Abstract: A process for producing aromatic polyamides having improved nonflammability characteristics in which a polyamide substrate is contacted with a gaseous medium comprising a minor amount of a haloolefinic material and an inert diluent in the presence of light having sufficient energy to effect chemical addition of the haloolefin to said polyamide substrate.
    Type: Grant
    Filed: December 6, 1976
    Date of Patent: May 20, 1980
    Inventors: James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher, Madeline S. Toy, Roger S. Stringham
  • Patent number: 4201703
    Abstract: Intimate blends of polypivalolactone resin and polycarbonate resin enable the production of molded articles exhibiting low warpage properties.
    Type: Grant
    Filed: June 8, 1978
    Date of Patent: May 6, 1980
    Assignee: Ethyl Corporation
    Inventors: Paul A. Zorzi, Jesse D. Jones, Michael E. Kucsma
  • Patent number: 4196236
    Abstract: A process is disclosed for fabricating a thermoplastic, which thermoplastic is either a thermoplastic ionomer or a multiphase graft or block copolymer of the ABA (AB).sub.n, or ##STR1## wherein n is greater than 1 and wherein the polymer blocks, A and B, are each thermoplastic resins having softening points substantially above room temperature with the B block being present in at least about 30 wt. % of the total polymer. The thermoplastic composition is first suspended in finely divided form in a liquid medium in a sufficient amount such that the solids content of the resulting suspension is in the range of from about 15 to about 75 wt. %. The liquid medium must be nonvolatile and must be capable of plasticizing the B block (or the backbone if the ionomer is employed) of the thermoplastic composition above the softening point of that block but must not be capable of plasticizing the A block to a substantial extent. The suspension is then applied as a coating to any desired surface, e.g.
    Type: Grant
    Filed: January 27, 1978
    Date of Patent: April 1, 1980
    Inventors: Robert D. Lundberg, Henry S. Makowski
  • Patent number: 4190567
    Abstract: A curable film-forming cationic polyurethane emulsion containing a compound having an epoxide group, as a curing agent.
    Type: Grant
    Filed: December 2, 1977
    Date of Patent: February 26, 1980
    Assignee: Kao Soap Co., Ltd.
    Inventors: Hidemasa Ohmura, Masahiro Saito
  • Patent number: 4189468
    Abstract: A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di-carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis-primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of (a') simple bi-functional compounds selected from bis-halohydrins, bis-azetidinium, bis-haloacyl diamine and alkyl bis-halides, (b') oli
    Type: Grant
    Filed: February 27, 1978
    Date of Patent: February 19, 1980
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Henri Sebag, Jean-Francois Grollier, Alexandre Zysman
  • Patent number: 4168360
    Abstract: Novel, unsaturated polyimide-polyester polymerization products and processes for their preparation are disclosed herein. The polyimide-esters from which the polymerization products are derived are derivatives of anhydride-terminated aromatic polyimides, from which they are prepared by esterification to provide unsaturated ester groups having a terminal --CH.dbd.CH.sub.2 group. These new compositions are crosslinked, insoluble, infusible polymers produced without by-product formation.
    Type: Grant
    Filed: July 25, 1978
    Date of Patent: September 18, 1979
    Assignee: Plastics Engineering Company
    Inventor: Gaetano F. D'Alelio
  • Patent number: 4168366
    Abstract: Novel, unsaturated polyimide-polyesters and processes for their preparation are disclosed herein. These new polyimides are derivatives of anhydride-terminated aromatic polyimides, from which they are prepared by esterification to provide unsaturated ester groups of a terminal --CH.dbd.CH.sub.2 group. These new compositions are more tractable than the original anhydride-terminated polyimides and can be converted at appropriate lower temperatures to crosslinked, insoluble, infusible polymers without by-product formation, thereby extending greatly the applications for which the aromatic polyimides can be employed.
    Type: Grant
    Filed: July 25, 1978
    Date of Patent: September 18, 1979
    Assignee: Plastics Engineering Company
    Inventor: Gaetano F. D'Alelio
  • Patent number: 4166168
    Abstract: Novel, unsaturated polyimide-polyester polymerization products and processes for their preparation are disclosed herein. The polyimide-esters from which the polymerization products are derived are derivatives of anhydride-terminated aromatic polyimides, from which they are prepared by esterification to provide unsaturated ester groups having a terminal --C.tbd.CH group. These new compositions are crosslinked, insoluble, infusible polymers produced without by-product formation.
    Type: Grant
    Filed: July 25, 1978
    Date of Patent: August 28, 1979
    Assignee: Plastics Engineering Company
    Inventor: Gaetano F. D'Alelio
  • Patent number: RE30217
    Abstract: We have disclosed a new class of thermosetting copolymers derived from terephthalonitrile N,N'-dioxide and polyimide oligomer that cure through addition reactions to form essentially void-free cured resins that exhibit outstanding high temperature stability. These copolymers may be formed from either acetylene terminated polyimide oligomers or nitrile terminated polyimide oligomers. Copolymers prepared in accordance with our invention exhibit little or no outgassing during cure and are extremely useful in the preparation of laminates where high temperature stability and high strength is required.
    Type: Grant
    Filed: April 24, 1978
    Date of Patent: February 19, 1980
    Assignee: Hughes Aircraft Company
    Inventors: Norman Bilow, Abraham L. Landis, Leroy J. Miller