Mixed With Ethylenically Unsaturated Reactant Or Polymer Therefrom Patents (Class 525/426)
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Patent number: 5580931Abstract: A method for property modification of bulk polymers, by initially treating a short chain monomeric organic acid, having a carboxylic group (with dissociation constant between 10.sup.-2 to 10.sup.-6 cm.sup.-1, and less than 8 carbons); with a Group IA, IIA or IIB metal, metal oxide, peroxide, hydroxide, or halogens, for forming a metal ligand or complex metal salt of the acid. The bulk polymers are mixed with the complex metal salts and free radicals are introduced into the mixture by means of oxidizing materials, to functionalize the bulk polymer with ionic polymerization sites. A copolymer formation is effected between the monomeric organic metal salt anion and the bulk polymer, as catalyzed by the metal cation, at such sites. The polymerization is a substantially non-cross linked ionic one resulting from the dissociation parameters and the short chain length of the complex metal salt, which is maintained prior to copolymer formation.Type: GrantFiled: March 2, 1994Date of Patent: December 3, 1996Assignee: Nathaniel H. GarfieldInventor: Juan E. Aguirre
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Patent number: 5578677Abstract: A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.Type: GrantFiled: December 27, 1995Date of Patent: November 26, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5571869Abstract: Grafted polymer particles are prepared by a free-radical addition polymerization mechanism using a flame produced by igniting a mixture of a combustible gas and an oxidant to heat at least a portion of the surface of a solid polymer particle to produce free-radicals thereon. At least one polymerizable ethylenically unsaturated monomer is contacted and reacted with the free-radicals formed on the surface of the polymer to form a graft thereon.Type: GrantFiled: April 25, 1995Date of Patent: November 5, 1996Assignee: The University of AkronInventors: Sunggyu Lee, Ramesh Rengarajan
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Patent number: 5560973Abstract: A process for preparing melt spun polymeric fiber made from polymerized amide monomers includes the steps of pigmenting the polymer, incorporating within the polymer sufficient SO.sub.3 H groups or salts thereof to give the polymer a sulphur content of between about 10 and about 160 equivalents per 10.sup.6 grams polymer and thereafter chemically blocking with a chemical blocking agent a portion of amino end groups present in the sulphonated polymer.Type: GrantFiled: May 22, 1995Date of Patent: October 1, 1996Assignee: BASF CorporationInventors: Matthew B. Hoyt, Andrew M. Coons, III, David N. Dickson
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Patent number: 5549932Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: March 9, 1995Date of Patent: August 27, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5548037Abstract: A process for preparing melt spun polymeric fiber made from polymerized amide monomers includes the steps of pigmenting the polymer, incorporating within the polymer sufficient SO.sub.3 H groups or salts thereof to give the polymer a sulphur content of between about 10 and about 160 equivalents per 10.sup.6 grams polymer and thereafter chemically blocking with a chemical blocking agent a portion of amino end groups present in the sulphonated polymer.Type: GrantFiled: May 22, 1995Date of Patent: August 20, 1996Assignee: BASF CorporationInventors: Matthew B. Hoyt, Andrew M. Coons, III, David N. Dickson
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Patent number: 5536785Abstract: A thermosetting powder coating composition resistant to overspray incompatibility defects that comprises solid particulates of a uniform mixture of (a) a polyester resin having an average of two or more carboxyl groups, (b) a first crosslinker that is reactive toward the carboxyl groups of the polyester resin, (c) from 1% to 20% of a reactive acrylic copolymer having a weight average molecular weight of from 10,000 to 40,000, and (d) a second crosslinker that is reactive toward the reactive functionality of the acrylic copolymer is described.Type: GrantFiled: April 7, 1995Date of Patent: July 16, 1996Assignee: BASF CorporationInventors: Richard J. Foukes, Cynthia A. Stants
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Patent number: 5516839Abstract: A thermal latent compound which is prepared by a reaction of a polycarboxyl compound having two or more carboxyl groups in the molecule, having an acid equivalent of not more than 1000 g/mole and a number average molecular weight of not more than 4000, with a monovinyl ether compound, wherein at least two carboxyl groups are transformed into a functional group of the formula (1): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each a hydrogen atom or an organic group of 1 to 18 carbon atoms, R.sup.4 is an organic group of 1 to 18 carbon atoms, Y.sup.1 is an oxygen atom or R.sup.3 and R.sup.4 are bonded together to form a heterocyclic with Y.sup.1 as a heteroatom.Type: GrantFiled: June 15, 1994Date of Patent: May 14, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5506310Abstract: A thermoplastic film, adapted for adhesion, composed of a compound of polyamide-based thermoplastic elastomers and of copolymers of olefins, the latter preferably being constituted of at least two different monomers of olefins. The composition of the thermoplastic film is such that the thermoplastic elastomers represent at least 50% and preferably 60% of the total weight of the compound.Type: GrantFiled: June 8, 1994Date of Patent: April 9, 1996Assignee: Elf Atochem S.A.Inventors: Thierry Vasselin, Michel Vuachet, Gilles Recher
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Patent number: 5504158Abstract: There is provided in accordance with the present invention polyphenylene ether/polyalkyleneterephthalamide compositions of high dimensional stabilities that are suitable for high temeprature applications comprising from about 20 to about 70 weight % of a functionalized polyphenylene ether; from about 20 to about 70 weight % of a polyalkyleneterephthalamide, wherein the polyalkyleneterephthalamide is derived from terephthalic acid and an .alpha.,.omega.-alkanediamine having 10 to 14 methylene groups; and from about 0 to about 20 weight % of a functionalized elastomeric polymer, wherein the blend absorbs less than 2 wt % of moisture and has a dimensional growth in water of less than 0.5%.Type: GrantFiled: January 10, 1995Date of Patent: April 2, 1996Assignee: AlliedSignal Inc.Inventors: Murali K. Akkapeddi, Jeffrey H. Glans
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Patent number: 5498783Abstract: A thermosetting powder coating composition resistant to overspray incompatibility defects that comprises solid particulates of a uniform mixture of (a) a polyester resin having an average of two or more carboxyl groups, (b) a first crosslinker that is reactive toward the carboxyl groups of the polyester resin, (c) from 1% to 20% of a reactive acrylic copolymer having a weight average molecular weight of from 10,000 to 40,000, and (d) a second crosslinker that is reactive toward the reactive functionality of the acrylic copolymer is described.Type: GrantFiled: August 22, 1994Date of Patent: March 12, 1996Assignee: BASF CorporationInventors: Richard J. Foukes, Cynthia A. Stants
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Patent number: 5491201Abstract: Novel cyclic imino ether compositions containing one or more mesogenic moieties, when polymerized, result in products having improved properties.Type: GrantFiled: February 16, 1995Date of Patent: February 13, 1996Assignee: The Dow Chemical CompanyInventors: Robert E. Hefner, Jr., Jimmy D. Earls
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Patent number: 5488084Abstract: Disclosed is a polyphenylene sulfide resin composition having a superior heat resistance and impact resistance obtained by melt-kneading a modified polyphenylene sulfide resin obtained by reacting a polyphenylene sulfide resin with a carboxylic acid anhydride, with at least one thermoplastic resin selected from a polyamide resin, a polyester resin, a polycarbonate resin, a polysulfone resin, and a polyamide-imide resin.Type: GrantFiled: December 14, 1993Date of Patent: January 30, 1996Assignee: Toray Industries, Inc.Inventors: Sho Kadoi, Hidemi Yabe, Kazuhiko Kobayashi
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Patent number: 5486594Abstract: It is disclosed a toughened polyamide comprising a polyamide, such as Nylon 6, and a minor amount of a linear alternating polymer of carbon monoxide and at least one or more ethylenically unsaturated hydrocarbon. The toughened polyamide has and exhibits improved properties such as Notched Izod strength and flexural modulus and can be used in the manufacture of articles suitable in many applications.Type: GrantFiled: July 11, 1994Date of Patent: January 23, 1996Assignee: Shell Oil CompanyInventors: Randall P. Gingrich, Michelle Londa, John E. Flood
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Patent number: 5482995Abstract: A grafted block copolymer having a backbone and grafts produced by monomers, the backbone consisting of sequentially distributed units wherein at least one block of the backbone is soluble in the monomer composition from which the grafts are produced and in that at-least one block of the said backbone is insoluble in the said monomer composition and the process of making such grafted block copolymer by radical grafting and radical polymerization of a monomer on the backbone are preformed.Type: GrantFiled: January 5, 1995Date of Patent: January 9, 1996Assignee: Elf Atochem S.A.Inventor: Nicolas Krantz
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Patent number: 5470920Abstract: The present invention relates to impregnating solutions consisting:of an active principle A+B in which: A denotes at least one thermoplastic poly(imide-amide) oligomer functionalized at the chain ends with an alkenyloxy, maleimido or nadimido group, B denotes a coreactant chosen from: B1=an imide ingredient, B2=an acrylate ingredient, B3=an alkenylphenol ingredient, B4=a novolac resin, B5=a vinyl ingredient, B6=an epoxy resin, B7=an amino ingredient and B8=a mixture of a number of ingredients B1 to B7;and of one or a number of aprotic polar solvent(s), the concentration of the active principle in the solution being between 2 and 80% by weight.These solutions are employed especially for the production of preimpregnated intermediate articles.Type: GrantFiled: October 1, 1993Date of Patent: November 28, 1995Assignee: Ciba-Geigy CorporationInventors: Yves Camberlin, Rene Dien, Philippe Michaud
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Patent number: 5462996Abstract: A thermosettable resin composition is prepared by admixing a liquid mixture of thermosettable resins such as a polyepoxide and amorphous thermoplastic polymer particles such as a polyetherimide to form a homogeneous cured resin composition. The particles have an average diameter of from 0.5-50 micrometers, a surface area of at least 1.0 m.sup.2 /g, a dissolution temperature of at least 50.degree. C., and are essentially insoluble in the thermosettable resin at temperatures of up to 15.degree. C. below the dissolution temperature but are completely dissolved at a temperature of at least 20.degree. C. below the cure temperature of the resin.Type: GrantFiled: February 6, 1995Date of Patent: October 31, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Gene B. Portelli, William J. Schultz, John T. Boden, Daniel M. Kaufer
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Patent number: 5455308Abstract: Thermosettable composition suitable for the production of endless objects without the use of continuous carrier material, whereby the composition comprises an epoxy resin or an unsaturated polyester and a high molecular weight thermoplastic polymer which has a weight-average molecular weight of at least 1,000,000 g/mol in an amount to make the composition spinnable, the amount ranging from at least 0.1% where the polymer has a molecular weight of 5,000,000 g/mol or more or less than 2% where the polymer has the weight-average molecular weight of 1,000,000 g/mol, the amount decreasing as the weight-average molecular weight increases.Type: GrantFiled: August 16, 1994Date of Patent: October 3, 1995Assignee: DSM N.V.Inventor: Cornelis W. M. Bastiaansen
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Patent number: 5453467Abstract: A graft polymer obtainable by grafting a polymer substrate with a compound of formula (I), in which the groups R are the same or different and each is a straight or branched C.sub.1 -C.sub.4 alkyl group; X is an aryl group or a straight or branched C.sub.1 -C.sub.20 alkylene group, optionally containing one or more carbon-carbon double or triple bonds, ether linkages or aryl groups; the aryl groups being unsubstituted or substituted by one or more C.sub.1-4 alkyl groups; n is from 2 to 4; and A is a reactive group, is useful as a biocompatible material in contact lenses, biomedical devices and blood-containing devices. In a preferred embodiment A is a polymerizable group and the graft polymer is produced by radical initiated polymerization of the compound of formula (I) on the substrate which is initiated by a radical-forming group on the substrate.Type: GrantFiled: April 28, 1994Date of Patent: September 26, 1995Assignee: Biocompatibles LimitedInventors: Clement H. Bamford, Kadem G. Al-Lamee, Yiannakis Yianni, Martin C. Wiles, Trevor O. Glasbey
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Patent number: 5439737Abstract: A fusible interlining has a textile substrate employed with a single adhesive layer and is intended to be bonded to drapery. The adhesive layer includes a first phase in the form of thermoplastic powder of dense granules whose primary function is to ensure the adhesion of the fusible interlining to the drapery at the time of bonding. A second phase of the adhesive layer is a crosslinkable system including a crosslinkable resin and a hardener in the form of a homogeneous matrix whose main function is to coat the granules of the thermoplastic powder of the bonding system.Type: GrantFiled: March 19, 1993Date of Patent: August 8, 1995Assignee: Lainiere de PicardieInventor: Mohamed F. Trabelsi
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Patent number: 5439986Abstract: A thermo-curable resin composition which contains (a) an aromatic polyamide oligomer having polymerizable unsaturated group(s) at both terminals or within side chain(s), (b) a maleimide compound and (c) an epoxy resin; and a copper foil laminate which comprises impregnating said composition into substrates, followed by bonding by co-pressing copper foils is provided. The copper-clad laminate of the present invention has excellent adhesiveness to copper foil, heat resistance and electrical properties.Type: GrantFiled: November 16, 1993Date of Patent: August 8, 1995Assignee: Showa Highpolymer Co., Ltd.Inventors: Tadayuki Hosogane, Hiroshi Nakajima, Eiichiro Takiyama
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Patent number: 5438104Abstract: A maleimide resin composition which gives a cured plastic having high toughness, high elastic modulus, high thermal resistance, high thermal decomposition resistance, low water absorption and high solvent resistance, as well as a prepreg and a fiber-reinforced plastic having the maleimide resin composition of the present invention as a matrix resin is disclosed. The maleimide resin composition of the present invention comprises a maleimide resin [A]; and a polyimide resin [B] containing a recurring unit of the formula [I] and/or [II]: ##STR1## (wherein Z represents a tetracarboxylic acid dianhydride residue) ##STR2## (wherein Z represents the same meaning as in formula [I]) said polyimide has amino groups and/or maleimide groups at the ends of the polyimide molecules.Type: GrantFiled: October 22, 1992Date of Patent: August 1, 1995Assignee: Toray Industries, Inc.Inventors: Hajime Kishi, Masazumi Tokunoh, Nobuyuki Odagiri
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Patent number: 5426156Abstract: Previous two-component coatings with enamine components cured very slowly at low temperatures and led to yellowed products. A binder composition is prepared which cures rapidly at low temperatures and leads to non-yellowing products. It contains as CH-acid component a polymer with at least two enamine functions in the molecule, obtained byA) transesterification of a .beta.-keto-ester with hydroxyl-group-containing compounds or polymers which contain at least two hydroxyl groups in the molecule, with an OH value of at least 50 and a number-average molecular weight of 500 to 10,000, followed by reaction with ammonia or primary and/or secondary amines, andB) as .alpha.,.beta.-unsaturated component a compound with at least two groups of the general formula R.sub.1 R.sub.2 C.dbd.CR.sub.3 --X; in which X signifies --CO-- which is bonded via the residue of a di- or polyhydric alcohol, a di- or polyamine or an aminoalcohol to a further R.sub.1 R.sub.2 C.dbd.CR.sub.3 --X group, where R.sub.1, R.sub.2 and R.sub.Type: GrantFiled: November 16, 1994Date of Patent: June 20, 1995Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Klaus Bederke, Hermann Kerber, Walter Schubert, Gerhard Bremer, Thomas Brock, Fritz Sadowski
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Patent number: 5416171Abstract: The invention relates blending compositions comprising (a) a polyamide and (b) a block copolyetheramide with hard polyamide segments and soft polyether segments. The block copolyetheramide is defined by the formula:--[--CO--R.sup.1 --CO--(NHR.sup.2 CO).sub.m --O--(R.sup.3 --O--).sub.p --(CO--R.sup.2 --NH).sub.q --].sub.n --wherein R represents the alkylene group of an aliphatic diacid having between about 2 and about 18 carbon atoms; R.sup.2 represents an alkylene group having between about 3 and about 11 carbon atoms; R.sup.3 represents an alkylene group having between about 2 and about 4 carbon atoms; m and q independently range between about 2 and about 40; p ranges between about 10 and about 100; and n ranges between about 2 and about 50, said blending composition containing a polyether content ranging between about 1 and about 50%. The blocking copolyetheramides may be prepared by reacting a polyetherdiol, caprolactam and an aliphatic diacid in a two-stage method.Type: GrantFiled: August 11, 1994Date of Patent: May 16, 1995Assignee: Industrial Technology Research InstituteInventors: Lie-Zen Chung, De-Lun Kuo, Hong-Bing Tsai
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Patent number: 5416136Abstract: A catalyst-free single-component coating agent containing (A) one or more compounds acting as cross-linking agents and with on average at least two CH-azide hydrogen atoms, (B) one or more (meth)acrylate copolymers, polyester resins and/or polyurethane resins capable of Michael addition, with .alpha., .beta.-unsaturated groups bonded via carbonyl, carboxyl and/or carboxylic amide groups, a C.dbd.C equivalent weight of 85-1800 and a weight average molecular weight of 170-50000. The equivalent ratio of A to B is 2:1 to 1:2. The coating agent contains solvents and conventional lacquer additives, and optionally contains water, pigments and/or fillers. It results in particularly acid-resistant coatings and is particularly suitable for producing covering lacquer and clear lacquer coatings in the motor-vehicle sector.Type: GrantFiled: April 29, 1994Date of Patent: May 16, 1995Assignee: Herberts GmbHInventors: Heinz Konzmann, Friedrich Herrmann, Wolfgang Diener
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Patent number: 5408002Abstract: An azlactone-functional thermoplastic composition is disclosed. The composition is a blend of an azlactone-functional composition and a thermoplastic polymer. A method of making azlactone-functional homopolymers by bulk homopolymerization is disclosed, optionally also concurrent or sequential blending of a thermoplastic polymer. A method of blending azlactone-functional compositions and thermoplastic polymers is disclosed. Molded articles and adduct molded articles formed from the thermoplastic composition are disclosed.Type: GrantFiled: September 9, 1993Date of Patent: April 18, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Patrick L. Coleman, Steven M. Heilmann, Steven L. Kangas, Robert H. Menzies, Jerald K. Rasmussen, Richard J. Rolando, Jennifer J. Sahlin, Julie B. Stahl
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Patent number: 5401812Abstract: A thermosetting polyimide composition is provided with a sufficient heat resistance and excellent mechanical and electrical characteristics in toughness, flexibility and so on and under severe environmental conditions, by adding to a polyfunctional unsaturated imide a thermosetting resin selected from the group consisting of polyetherimide, polyarylate and polyamideimide which are in a miscibility region with the polyfunctional unsaturated imide and have an excellent glass transition point and a number-average molecular weight of more than 10,000.Type: GrantFiled: December 21, 1992Date of Patent: March 28, 1995Assignee: Matsushita Electric Works, Ltd.Inventors: Hiroshi Yamamoto, Taro Fukui
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Patent number: 5389705Abstract: Novel polymers which are suitable as binders are obtainable by reacting(A) a base resin which has an average molecular weight M.sub.w of from 200 to 5,000 and contains on average from 1 to 3 epoxy or isocyanato groups as the reactive groups per moleculewith(B) a mixture of(B1) 5 to 50% by weight of polyisobutylene which is terminated with primary amino groups and has an average molecular weight M.sub.w of from 500 to 5,000 and(B2) 5-95% by weight of an amidoamine which carries primary amino groups and is obtainable by condensation of diprimary diamines of 2 to 20 carbon atoms with aliphatic C.sub.2 -C.sub.44 -dicarboxylic acids,the amounts being such that from 1 to 5 equivalents of primary amino groups of (B) are present per equivalent of reactive groups of (A).Type: GrantFiled: August 6, 1993Date of Patent: February 14, 1995Assignee: BASF Lacke + Farben AktiengesellschaftInventors: Klaus Huemke, Helmut Fobbe, Konrad Knoll
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Patent number: 5385687Abstract: An oil soluble dispersant additive useful in oleaginous compositions selected from fuels and lubricating oils comprising the reaction products of:(i) at least one intermediate adduct comprised of the reaction products of(a) at least one polyanhydride, and(b) at least one member selected from the group consisting of polyamines, polyols, and amino alcohols; and(ii) at least one member selected from the group consisting of(a) at least one long chain hydrocarbyl substituted C.sub.4 -C.sub.10 dicarboxylic acid producing material;(b) at least one long chain hydrocarbyl substituted hydroxy aromatic material and at least one aldehyde; or(c) at least one aldehyde and at least one reaction product of a hydrocarbyl substituted C.sub.3 -C.sub.10 monocarboxylic or C.sub.4 -C.sub.10 dicarboxylic acid or anhydride and an amine substituted hydroxy aromatic compound.Also disclosed are oleaginous compositions, particularly lubricating oil compositions, containing these oil soluble dispersants.Type: GrantFiled: August 4, 1993Date of Patent: January 31, 1995Assignee: Exxon Chemical Patents Inc.Inventors: Jacob Emert, Robert D. Lundberg, Antonio Gutierrez
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Patent number: 5376499Abstract: Cost-effective, highly heat-resistant positive resists based on oligomer and/or polymer polybenzoxazole precursors and diazo quinones possess a high [level of] stability in storage when the polybenzoxazole precursors are hydroxypolyamides of the following structure: ##STR1## whereby R, R*, R.sub.1, R*.sub.1, and R.sub.2 are aromatic groups, R.sub.3 is an aliphatic, cycloaliphatic or aromatic group having at least one alkenyl or alkynyl grouping and, with respect to n.sub.1, n.sub.2 and n.sub.3, the following applies:n.sub.1 =1 to 100, n.sub.3 and n.sub.3 =0 orn.sub.1 and n.sub.2 =1 to 100, n.sub.3 =0 orn.sub.2 =1 to 100, n.sub.1 and n.sub.3 =0 orn.sub.1, n.sub.2 and n.sub.3 =1 to 100 (whereby R.noteq.R* and/or R.noteq.R*.sub.1) orn.sub.1 and n.sub.3 =1 to 100, n.sub.2 =0 (whereby R.noteq.R* and/or R.sub.1 .noteq.R*.sub.1) ,provided that: n.sub.1 +n.sub.2 +n.sub.3 >3.Type: GrantFiled: May 7, 1992Date of Patent: December 27, 1994Assignee: Siemens AktiengesellschaftInventors: Albert Hammerschmidt, Siegfried Birkle, Hellmut Ahne
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Patent number: 5372891Abstract: An improved polyimide-based coating composition comprising a polyimide upper layer and a polyimide-modified bismaleimide lower layer for use as a coating on metal substrate, such as an electrolytic copper foil. The polyimide are prepared from reactions between diamines, such as p-phenylene diamine and 4-4'-diaminodiphenyl ether, and dianhydrides, such as 3,3',4,4'-benzophenone tetracarboxylic dianhydride and biphenyl-3,3',4,4'-tetracarboxylic dianhydride. The modified bismaleimide can be prepared from reacting an N,N',4,4'-diphenyl bismaleimide with a barbituric acid or its derivative. A double-layered extrusion coating technique having a double-layered extrusion die is utilized to apply the coating composition onto the metal substrate. The final laminated products show improved peel strength between the polyimide coating and the substrate, as well as improved dimensional stability and surface flatness thereof.Type: GrantFiled: December 16, 1992Date of Patent: December 13, 1994Assignee: Industrial Technology Research InstituteInventors: Tsai-An Yu, Jing-Pin Pan, Han-Lung Chen, Jinn-Shing King, Tsung-Hsiung Wang
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Patent number: 5373087Abstract: A process for preparing a polyaminopolymer which contains functionality comprises the steps of (a) contacting a polyfunctional amine with an unsaturated alkylating agent under reaction conditions to form an amine/unsaturated alkylating agent adduct; (b) contacting the adduct with a polyfunctional compound such that a polyaminopolymer is formed: (e) contacting the polyaminopolymer with a halogen, hypohalous acid or precursor thereof such that a polyaminopolymer having halohydrin or dihalo functionality is formed, and (d) raising the pH of the polyaminopolymer having halohydrin or vicinal dihalo functionality sufficiently to cause an increase in molecular weight. Alternatively, the invention is a process having steps (a), (b), (c) and optionally (d), but with a step (h) between steps (b) and (c) of contacting the polyaminopolymer with a crosslinking agent therefor having at least two functional groups reactive with amine groups such that a crosslinked polyaminopolymer is formed.Type: GrantFiled: November 8, 1993Date of Patent: December 13, 1994Assignee: The Dow Chemical CompanyInventors: Otha G. Weaver, Jr., Wanda G. Buckner, Terry W. Glass
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Patent number: 5367003Abstract: Environmentally friendly, disposable, degradable and/or recyclable plastic articles are made from water soluble, miscible, high molecular weight, thermoplastic, polymeric resin blends that are comprised by weight of about 65% to 95% high molecular weight water soluble thermoplastic resin having an inverse solubility characteristic and about 35% to 5% of at least one of certain high molecular weight thermoplastic polymers that are functionally compatible (miscible) with the inversely soluble resin. The articles are insoluble when used for their intended purposes, but become soluble when exposed to tepid or cool water and degradable when buried in a land fill or compost. The inversely soluble resin comprises high molecular weight poly(ethylene oxide). The compatible polymer is selected from the group consisting of Nylon 11, Nylon 12, polycaprolactone, polycaprolactone, polyethylene-co-acrylic acid, polyethylene-co-methacrylic acid, polyethylene-co-vinylacetate and polyethylene-co-vinylalcohol.Type: GrantFiled: June 18, 1993Date of Patent: November 22, 1994Inventor: Robert J. Petcavich
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Patent number: 5352742Abstract: Fluorinated styrenes of the formula I: ##STR1## where R.sub.1 is a C.sub.1 -C.sub.6 alkyl and R.sub.2 is the repeating unit ##STR2## where x is zero or any positive integer, which are useful as compatibilizing and toughening agents for various polymers such as styrene, dienes (butadiene, isoprene, etc.) acrylates, polymethacrylates, polycarbonates, polyesters, polyamides, etc. Particularly preferred are p-(1,1,1,3,3,3-hexafluoro-2-hydroxy isopropyl)-.alpha.-methylstyrene, polymers thereof, block and random copolymers thereof and polymer blends incorporating the same.Type: GrantFiled: December 7, 1993Date of Patent: October 4, 1994Assignee: The United States of America as represented by the Secretary of CommerceInventors: Charles C. Han, Manjun He, Yongming Liu, Yi Feng, Ming Jiang
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Patent number: 5344894Abstract: Polyimide oligomers include (1) linear, monofunctional crosslinking oligomers prepared by condensing a monoanhydride end cap with a diamine that includes alternating ether and "sulfone" (--SO.sub.2 --, --S--, --CO--, --(CF.sub.3).sub.2 C--, or --(CH.sub.3).sub.2 C--) linkages connecting alternating aromatic radicals and with a dianhydride (or dianhydride mixture), particularly the unsaturated, aliphatic dianhydride commonly known as MCTC; (2) linear, mono- or difunctional crosslinking oligomers prepared by condensing an amine end cap with a diamine and a dianhydride; and (3) multidimensional, crosslinking oligomers having an aromatic hub and at least three radiating arms connected to the hub, each arm including a crosslinking end cap at its distal end and at least one imide linkage.Blends, prepregs, and composites can be prepared from the oligomers.Type: GrantFiled: November 23, 1992Date of Patent: September 6, 1994Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard
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Patent number: 5342875Abstract: Polycationic wet-strength materials such as KYMENE are chemically modified to provide unsaturated hydrocarbon substituents. The modified KYMENE is cross-linked onto and into latex particles to provide improved wet-strength agents for use in paper treatments. Thus, KYMENE is reacted, for example, with acrylic acid and cross-linked with styrene/butadiene to provide a polycationic latex wet-strength agent.Type: GrantFiled: April 7, 1993Date of Patent: August 30, 1994Assignee: The Procter & Gamble CompanyInventor: Isao Noda
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Patent number: 5340886Abstract: A process for preparing melt spun polymeric fiber made from polymerized amide monomers includes the steps of pigmenting the polymer, incorporating within the polymer sufficient SO.sub.3 H groups or salts thereof to give the polymer a sulphur content of between about 10 and about 160 equivalents per 10.sup.6 grams polymer and thereafter chemically blocking with a chemical blocking agent a portion of amino end groups present in the sulphonated polymer.Type: GrantFiled: June 2, 1993Date of Patent: August 23, 1994Assignee: BASF CorporationInventors: Matthew B. Hoyt, Andrew M. Coons, III, David N. Dickson
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Patent number: 5332777Abstract: Unreinforced polyamide molding materials containA) from 60 to 100% by weight of a mixture consisting ofA.sub.1) from 97.5 to 99.85% by weight of one or more polyamides,A.sub.2) from 0.05 to 0.5% by weight of aluminum hydroxide andA.sub.3) from 0.1 to 2% by weight of one or more esters or amides of saturated or unsaturated aliphatic carboxylic acids of 10 to 40 carbon atoms with aliphatic saturated alcohols or amines of 2 to 40 carbon atomsand, based on the total weight of the polyamide molding material,B) from 0 to 40% by weight of a toughened polymer andC) from 0 to 10% by weight of conventional additives in effective amounts.Type: GrantFiled: September 25, 1992Date of Patent: July 26, 1994Assignee: BASF AktiengesellschaftInventors: Walter Goetz, Walter Betz
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Patent number: 5331063Abstract: This invention is a semi-interpenetrating polymer network which includes a high performance thermosetting polyimide having a nadic end group acting as a crosslinking site and a high performance linear thermoplastic polyimide having the following repeating unit. ##STR1## wherein Z=C or SO.sub.2. Provided is an improved high temperature matrix resin which is capable of performing in the 200.degree. to 300.degree. C. range. This resin has significantly improved toughness and microcracking resistance, excellent processability, mechanical performance and moisture and solvent resistances.Type: GrantFiled: October 27, 1992Date of Patent: July 19, 1994Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Ruth H. Pater, Norman J. Johnston
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Patent number: 5302661Abstract: A composition which contains thermosettable monomers from which continuous products can be made without using continuous carrier material, the composition containing bismaleimide monomers and a thermoplastic polymer having a high molecular weight.Products made from a composition of the present invention are suitable for use in those fields where good temperature resistance, good fire resistance and/or good corrosion and solvent resistance are required in addition to good mechanical properties. Examples are cable sheathing, fire-resistant clothing, asbestos substitutes, high-temperature filters, aircraft interiors, precursors for carbon fiber , food packagings (for example, for use in a microwave oven), capacitor films and filament winding products.Type: GrantFiled: December 16, 1991Date of Patent: April 12, 1994Assignee: DSM N.V.Inventor: Cornelius W. M. Bastiaansen
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Patent number: 5300548Abstract: Disclosed herein are a novel graft copolymer comprising a stock copolymer (A) of at least one monomer selected from esters of unsaturated carboxylic acids and vinyl esters (a), ethylene (b) and carbon monoxide (c), and a polyamide oligomer having a primary amino group at one end of its molecule (B) grafted on said stock copolymer, and a process for the preparation thereof. The proposed graft copolymer, when used as an adhesive, in particular for adhesion of polyvinyl chloride, exhibits excellent heat resistance and adhesion properties.Type: GrantFiled: October 27, 1992Date of Patent: April 5, 1994Assignee: Du Pont-Mitsui Polychemicals Co., Ltd.Inventors: Hideo Akimoto, Shiro Narasaki, Reiji Miyamoto
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Patent number: 5298334Abstract: An improved saponified ethylene-vinyl acetate copolymer composition comprising(A) 50 to 99.5 weight % of a saponified ethylene-vinyl acetate copolymer,(B) 0.4 to 50 weight % of an ethylene copolymer having a density of 0.90.about.0.94 g/cm.sup.3, and(C) a graft polymer obtainable by grafting an ethylenically unsaturated carboxylic acid or a derivative thereof to a polyolefin resin and reacting the adduct with a polyamide oligomer or polyamide.Type: GrantFiled: August 21, 1991Date of Patent: March 29, 1994Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki KaishaInventors: Takamasa Moriyama, Hiroshi Takida, Tomoyoshi Uemura
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Patent number: 5296559Abstract: A composition that includes a finely divided, fully imidized, polyimide dispersed in a non-volatile, fluidizing resin that is a liquid or low viscosity semi-solid at room temperature. The fluidizing resin is substantially insoluble in the polyimide at room temperature, but soluble in the polyimide at the elevated temperatures during thermal processing. The composition has the flow characteristics of a highly filled liquid. The composition if useful, e.g., as an adhesive.Type: GrantFiled: December 19, 1991Date of Patent: March 22, 1994Assignee: Dexter-Hysol Aerospace, Inc.Inventors: Manette M. Gebhardt, Yesh P. Sachdeva
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Patent number: 5284922Abstract: In a second-order or third-order organic nonlinear optical material, one of compounds represented by the following formulas (1) and (2) is bonded to a polymer: ##STR1## wherein each of .pi..sub.1 to .pi..sub.n independently represents a cyclic compound of a .pi. electron conjugate system, at least one of R.sub.11 to R.sub.n4 represents an alkyl substituting group derivative and others represent hydrogen, each of X.sub.1 to X.sub.n-1 and Y.sub.1 to Y.sub.n-1 represents one member selected from the group consisting of CH, N, and N.fwdarw.O, A represents an electron acceptor group, D represents an electron donor group, and n is an integer of 3 or more.Type: GrantFiled: March 23, 1993Date of Patent: February 8, 1994Assignee: Nippon Telegraph and Telephone CorporationInventors: Michiyuki Amano, Yoshito Shuto, Toshikuni Kajno
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Patent number: 5278255Abstract: The present invention is a process for preparing a polyaminopolymer which contains functionality comprising the steps of (a) contacting a polyfunctional amine with an unsaturated alkylating agent under reaction conditions to form an amine/unsaturated alkylating agent adduct; (b) contacting the adduct with a polyfunctional compound such that a polyaminopolymer is formed; (c) contacting the polyaminopolymer with a halogen, hypohalous acid or precursor thereof such that a polyaminopolymer having halohydrin or dihalo functionality is formed; and (d) raising the pH of the polyaminopolymer having halohydrin or vicinal dihalo functionality sufficiently to cause an increase in molecular weight. Alternatively, the invention is a process having steps (a), (b), (c) and optionally (d), but with a step (h) between steps (b) and (c) of contacting the polyaminopolymer with a crosslinking agent therefor having at least two functional groups reactive with amine groups such that a crosslinked polyaminopolymer is formed.Type: GrantFiled: August 11, 1992Date of Patent: January 11, 1994Assignee: The Dow Chemical CompanyInventors: Otha G. Weaver, Jr., Terry W. Glass, Wanda G. Buckner
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Patent number: 5278257Abstract: Compositions containing A) a copolymer based on at least one 1,3-diene and at least one polar, ethylenically unsaturated comonomer and B) a phenol-terminated polyurethane, polyurea or polyurea-urethane of the formula I ##STR1## in which m is 1 or 2, n is 2 to 6, R.sup.1 is the n-valent radical of an elastomeric prepolymer which is soluble or dispersible in epoxide resins, X and Y independently of one another are --O-- or --NR.sup.3 --, it being necessary for one of these groups to be --NR.sup.3 --, R.sup.2 is an m+1-valent radical of a polyphenol or aminophenol after the removal of the phenolic hydroxy group(s) or the amino group or both the amino group and the phenolic hydroxyl group, respectively, and R.sup.3 is hydrogen, C.sub.1 -C.sub.6 alkyl or phenyl, are described.Compounds containing the components A) and B) as well as an epoxide resin C) are also described.The cured products are distinguished by a high peel strength and high resistance to crack propagation.Type: GrantFiled: January 21, 1992Date of Patent: January 11, 1994Assignee: Ciba-Geigy CorporationInventors: Rolf Mulhaupt, Jeremy H. Powell, Christopher S. Adderley, Werner Rufenacht
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Patent number: 5276106Abstract: A thermosettable resin composition having a viscosity that decreases during processing temperatures and increases as the temperature is raised to curing temperatures is provided The composition comprises thermosettable resins and thermoplastic particles that are insoluble in the thermosettable resins at processing temperatures but soluble in the thermosettable resins at curing temperatures. Prepregs prepared from the thermosettable resin composition are also provided.Type: GrantFiled: December 13, 1991Date of Patent: January 4, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Gene B. Portelli, William J. Schultz, John T. Boden, Daniel M. Kaufer
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Patent number: 5274028Abstract: In an improved method for producing a surface graft of a hydrophilic polymer upon a preformed solid or semi-solid polymer substrate having hydroperoxide groups along its surface, n-vinyl pyrrolidone is utilized as the surface-grafting monomer, the substrate is selected to be insoluble in n-vinyl pyrrolidone, and the polymerization is carried out in aqueous alkaline conditions utilizing a combination of metal salts to provide a variable valence metal ion in a reduced state capable of oxidizing to suppress homopolymerization of the monomer in the solution.When the substrate is at least partially soluble in the n-vinyl pyrrolidone, an ethylenically unsaturated monomer having a higher reactivity with the substrate than n-vinyl pyrrolidone is added to the alkaline polymerization solution as a "seeding" monomer. Addition of the "seeding" monomer results in a surface-grafted copolymer effectively externalized from the substrate.Type: GrantFiled: December 6, 1990Date of Patent: December 28, 1993Assignee: Baxter International Inc.Inventors: William J. Bertrand, Stephen L. Coulter, Cary Reich, Paul DeAntonio
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Patent number: 5270401Abstract: Disclosed is a plastics composition comprising a thermoplastic blend comprising: (1) 5-95 wt % of a polyamide (PA) and 95-5 wt % of a polyester (PE) incorporating 1-50 wt % of an aliphatic dimer fatty acid, (2) 0.01-30 parts by weight of a compound having at least one ethylenically unsaturated group or propylene group and further having a carboxylic, acid anhydride, acid amide, imido, carboxylic ester, amino or hydroxyl group per 100 parts by weight based on the combined weight of PA and PE, (3) 0-90 parts by weight of a polyester not modified with dimer fatty acid per 100 parts by weight based on the combined weight of PA and PE. Preferably the polyester (PE) is a polyethylene terephthalate or polybutylene terephthalate modified with di-oleic acid. The blends have a greatly improved elongation at break and are readily spinnable.Type: GrantFiled: October 11, 1991Date of Patent: December 14, 1993Assignee: DSM N.V.Inventors: Chi K. Sham, Wilhelmus T. M. Jansen, Martin A. Doherty
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Patent number: H1601Abstract: A blend of polyketone and polycarbonate polymers is presented. The polymer blend is produced by blending polyketone polymer, polycarbonate polymer, and a reactive graft compatibilizer. The a reactive graft compatibilizer compatibilizes the blend.Type: GrantFiled: March 2, 1995Date of Patent: October 1, 1996Assignee: Shell Oil CompanyInventors: Joseph M. Machado, Randall P. Gingrich